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Flexible Throat Patch for Phonetic Recognition and Ingestion Monitoring via Sensory Transition based on Machine Learning (Adv. Mater. Technol. 10/2024) 通过基于机器学习的感官转换实现语音识别和摄入监测的柔性喉贴(Adv. Mater. Technol.)
IF 6.8 3区 材料科学 Q1 Engineering Pub Date : 2024-05-22 DOI: 10.1002/admt.202470047
Wonki Hong

Flexible Throat Patch

In article number 2400059, Wonki Hong proposes a sensory transformation approach for machine learning-based dietary analysis and voice recognition. Based on a flexible patch that converts the sense of tactile into hearing and taste, it analyzes the vibrations and movements of the laryngeal muscles to understand pronunciation and peristalsis to determine the type of food consumed.

柔性喉部贴片在第 2400059 号文章中,Wonki Hong 提出了一种感官转换方法,用于基于机器学习的饮食分析和语音识别。该方法基于一种可将触觉转化为听觉和味觉的柔性贴片,通过分析喉部肌肉的振动和运动来理解发音和蠕动,从而确定所吃食物的类型。
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引用次数: 0
An Untethered Magnetic Microgripper for High-Throughput Micromanipulation (Adv. Mater. Technol. 10/2024) 用于高通量微操作的无系绳磁性微夹具(材料技术进展 10/2024)
IF 6.8 3区 材料科学 Q1 Engineering Pub Date : 2024-05-22 DOI: 10.1002/admt.202470046
Dineshkumar Loganathan, Ying Chaung, Yueh-Hsun Lu, Chia-Hsin Cheng, Chia-Yuan Chen

Magnetic Microgrippers

In article number 2400292, Chia-Yuan Chen and co-workers develop a magnetic microgripper to grasp particles with different sizes per cycle. Precise control over the gripper's motion is achieved through the in-house magnetic coil system. The gripper arms can exhibit sequentially opening and closing to facilitate the concurrent release and capture of particles for various biomedical applications.

磁性微型机械手在文章编号 2400292 中,Chia-Yuan Chen 及其合作者开发了一种磁性微型机械手,可在每个周期内抓取不同大小的颗粒。通过内部磁性线圈系统实现了对机械手运动的精确控制。抓手臂可按顺序打开和关闭,以便同时释放和捕捉颗粒,用于各种生物医学应用。
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引用次数: 0
A Smart Self-Healing Material with Reversible Optical, Mechanical, and Electrical Transition Induced by Humidity and Temperature 一种由湿度和温度诱发可逆光学、机械和电气转变的智能自愈材料
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-21 DOI: 10.1002/admt.202400214
Junqiang Justin Koh, Xuan Zhang, Shaohua Ling, Ximeng Liu, Lili Zhou, Zhi Qiao, Yu Jun Tan

Smart responsive materials that can alter their function in response to environmental changes are attractive for their potential applications in intelligent devices and products. Herein, a smart material that exhibits reversible changes in multiple properties upon variations in humidity or temperature is created. The material spontaneously transits between hydrated and dehydrated states in response to fluctuations in the surrounding humidity or temperature. Consisting of a mixture of poly(propylene glycol) (PPG) with urea linkages (PPGurea) and ionic liquid [EMIM][TFSI], the transition is attributed to a series of synergetic interactions among various chemical components and groups, including ether-cation coordination, water-anion complex, urea-urea bidentate hydrogen bonds, and cation–anion electrostatic interactions. In the hydrated state, with a very small amount (4–5 wt%) of spontaneously absorbed moisture content, the smart material is soft, transparent, and conductive, and possesses rapid self-healing ability. Upon dehydration, the material transits into a phase-separated system with PPG-rich and IL-rich phases, resulting in opacity, severely reduced ionic conductivity, yet significantly enhanced stiffness, strength, and toughness. The drastic change in multiple properties makes it an intelligent material well-suited for various smart applications such as sensors, 3D printed optoelectronics and smart windows, which can automatically alter their functions to adapt to environmental changes.

能够根据环境变化改变自身功能的智能响应材料因其在智能设备和产品中的潜在应用而备受青睐。在这里,我们创造了一种在湿度或温度变化时多种特性发生可逆变化的智能材料。这种材料会根据周围湿度或温度的波动自发地在水合态和脱水态之间转换。这种材料由具有脲键的聚丙二醇(PPG)和离子液体[EMIM][TFSI]的混合物组成,其转变归因于各种化学成分和基团之间的一系列协同作用,包括醚阳离子配位、水阴离子复合物、脲双叉氢键和阳离子静电作用。在水合状态下,自发吸收的水分含量极少(4-5 wt%),智能材料柔软、透明、导电,并具有快速自我修复能力。脱水后,材料转变为富含 PPG 相和富含 IL 相的相分离体系,导致不透明、离子导电性严重降低,但硬度、强度和韧性显著增强。多种性能的急剧变化使其成为一种智能材料,非常适合用于各种智能应用,如传感器、3D 打印光电元件和智能窗户,它们可以自动改变功能以适应环境变化。
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引用次数: 0
Uniaxial-Stress Driven Performance Enhancement of Multi-Beam Spark Plasma Sintered BiSbTe/Epoxy Flexible Films 多束火花等离子烧结 BiSbTe/Epoxy 柔性薄膜的单轴应力驱动性能提升
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-21 DOI: 10.1002/admt.202302226
Xiaoling Ai, Shaoqiu Ke, Xiaolei Nie, Tiantian Chen, Dong Liang, Kai Fu, Wanting Zhu, Ping Wei, Wenyu Zhao, Qingjie Zhang

The multi-beam discharge plasma sintering (MB-SPS) method is successfully applied to the preparation of Bi2Te3-based thermoelectric (TE) films with insulating substrates. Herein, the impact of uniaxial stress on the microstructure evolution and TE performance are explored systematically. The results indicate that the increase of uniaxial stress promotes the preferential growth of Bi0.5Sb1.5Te3 (BST) grains along the (000l) crystal plane, leading to the remarkable increase in carrier mobility. The maximum (000l) preferential orientation factor reaches 80% for the BST/epoxy (EP) film sintered under 25 MPa, which is 3.08 times higher than that of BST/EP film sintered at 10 MPa. While the highest power factor reaches 2.36 mW m−1 K−2 at 300 K for the BST/EP film sintered under 20 MPa, increased by 97% as compared with that of the film sintered under 10 MPa. This work once again confirms that the MB-SPS technology is an effective approach to prepare high-performance Bi2Te3-based films with insulating substrates and demonstrates that the (000l) preferential orientation and TE performance of the films can be further enhanced by an appropriate uniaxial stress.

多束放电等离子烧结(MB-SPS)方法被成功应用于制备基于 Bi2Te3 的绝缘基底热电(TE)薄膜。本文系统地探讨了单轴应力对微结构演变和 TE 性能的影响。结果表明,单轴应力的增加促进了沿 (000l) 晶面的 Bi0.5Sb1.5Te3 (BST) 晶粒的优先生长,从而显著提高了载流子迁移率。在 25 MPa 下烧结的 BST/epoxy (EP) 薄膜的最大(000l)优先取向因子达到 80%,是在 10 MPa 下烧结的 BST/EP 薄膜的 3.08 倍。而在 20 兆帕下烧结的 BST/EP 薄膜在 300 K 时的最高功率因数达到 2.36 mW m-1 K-2,比在 10 兆帕下烧结的薄膜提高了 97%。这项工作再次证实,MB-SPS 技术是制备具有绝缘基底的高性能 Bi2Te3 基薄膜的有效方法,并证明了通过适当的单轴应力可以进一步提高薄膜的(000l)优先取向和 TE 性能。
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引用次数: 0
Emerging Trends and Future Prospects in Microfluidic Systems for Prevention and Diagnosis of Infection Pathogens 用于预防和诊断感染病原体的微流控系统的新趋势和未来展望
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-19 DOI: 10.1002/admt.202400134
Farnaz Dabbagh Moghaddam, Maedeh Rafiee, Atousa Setayeshfar, Arman Moradi, Yasaman Esmaeili, Francesca Romana Bertani, Rasoul Esmaeely Neisiany, Zhengwei You, Ehsan Nazarzadeh Zare

Infectious diseases caused by bacteria, viruses, fungi, and parasites pose a significant societal challenge. In response, scientists are developing advanced technology to enhance the prevention, diagnosis, and treatment of such diseases. One such promising technology is microfluidic systems, which are utilized in organ-on-a-chip systems to replicate the microenvironments of organs. These systems have potential applications in drug screening, disease modeling, and personalized medicine. This review provides an overview of recent advances in organ-on-a-chip platforms and their potential for preventing and diagnosing various infections. After discussing traditional techniques employed in studying infectious diseases, the role of microfluidic platforms in detecting infections is delved in. It is expound on advanced microfluidic-based strategies for infection diagnosis, such as the polymerase chain reaction-based microfluidic devices, enzyme linked immunosorbent assay-based microfluidic devices, hierarchical nanofluidic molecular enrichment systemand µWestern blotting-based microfluidic devices, and smartphone-based microfluidic devices. Additionally, future research challenges and perspectives are discussed on microfluidic systems in biomedical and regenerative medicine applications. Consequently, microfluidic platforms have the potential to serve as fundamental frameworks for understanding infectious diseases, thereby leading to personalized regenerative medicine.hierarchical nanofluidic molecular enrichment system

由细菌、病毒、真菌和寄生虫引起的传染病是一项重大的社会挑战。为此,科学家们正在开发先进技术,以加强对这类疾病的预防、诊断和治疗。微流体系统就是其中一项前景广阔的技术,它被用于器官芯片系统,以复制器官的微环境。这些系统在药物筛选、疾病建模和个性化医疗方面具有潜在的应用前景。本综述概述了器官芯片平台的最新进展及其在预防和诊断各种感染方面的潜力。在讨论了研究传染病的传统技术后,深入探讨了微流控平台在检测感染中的作用。报告阐述了基于微流控芯片的先进感染诊断策略,如基于聚合酶链反应的微流控芯片设备、基于酶联免疫吸附试验的微流控芯片设备、分层纳米微流控芯片分子富集系统和基于µWestern 印迹技术的微流控芯片设备,以及基于智能手机的微流控芯片设备。此外,还讨论了微流控系统在生物医学和再生医学应用中的未来研究挑战和前景。因此,微流控平台有可能成为了解感染性疾病的基本框架,从而实现个性化再生医学。
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引用次数: 0
Surface-Level Muscle Deformation as a Correlate for Joint Torque 与关节扭矩相关的表面肌肉变形
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-19 DOI: 10.1002/admt.202400444
Jonathan T. Alvarez, Ariane de Marcillac, Yichu Jin, Lucas F. Gerez, Oluwaseun A. Araromi, Conor J. Walsh

Wearable technology excels in estimating kinematic and physiological data, but estimating biological torques remains an open challenge. Deformation of the skin above contracting muscles—surface-level muscle deformation—has emerged as a promising signal for joint torque estimation. However, a lack of ground-truth measures of surface-level muscle deformation has complicated the evaluation of wearable sensors designed to measure surface-level muscle deformation. A non-contact methodology is proposed for ground-truth measurement of surface-level muscle deformation using a 2D laser profilometer. It shows how three metrics of surface-level muscle deformation—peak radial displacement: r = 0.94 ± 0.05, surface curvature: r = 0.78 ± 0.10, surface strain: r = 0.83 ± 0.12—correlate strongly to changes in volitional elbow torque, further exploring the impact of measurement location or joint angle on these relationships. A nonlinear, lead-lag relationship between surface-level muscle deformation and torque is also found. The findings suggest that surface-level muscle deformation is a promising signal for non-invasive, real-time estimates of torque. By standardizing measurement, the methodology can help inform the design of future wearable sensors.

可穿戴技术在估算运动学和生理学数据方面表现出色,但估算生物扭矩仍是一项挑战。收缩肌肉上方皮肤的形变--表面肌肉形变--已成为关节扭矩估算的一个有前途的信号。然而,由于缺乏对表面肌肉变形的地面实况测量,使得对用于测量表面肌肉变形的可穿戴传感器进行评估变得更加复杂。本文提出了一种使用二维激光轮廓仪对表面肌肉变形进行地面实况测量的非接触方法。它显示了表面肌肉变形的三个指标--峰值径向位移:r = 0.94 ± 0.05;表面曲率:r = 0.78 ± 0.10;表面应变:r = 0.83 ± 0.12--如何与肘关节扭力的变化密切相关,并进一步探讨了测量位置或关节角度对这些关系的影响。研究还发现,表面肌肉变形与扭矩之间存在非线性的滞后关系。研究结果表明,表面肌肉变形是一种很有前景的信号,可用于非侵入式实时估算扭矩。通过标准化测量,该方法有助于为未来可穿戴传感器的设计提供参考。
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引用次数: 0
Thermal Annealing Impact on the Sensitivity of Piezomagnetic Surface Acoustic Waveguide to Applied Magnetic Field 热退火对压电磁性表面声波导体对外加磁场灵敏度的影响
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-17 DOI: 10.1002/admt.202400306
Othmane Marbouh, Aurélien Mazzamurro, Olivier Bou Matar, Vincent Maurice, Mohamed Boutghatin, Yannick Dusch, Ahmed Addad, Romain Viard, Phillipe Pernod, Rachid Sbiaa, Abdelmounaim Tounzi, Abdelkader Benabou, Nicolas Tiercelin, Abdelkrim Talbi

Magnetostrictive thin films, exhibit significant utility as functionalization materials for Surface acoustic wave sensors designed for magnetic field measurements. This research investigates the influence of annealing under vacuum and magnetic field at various temperatures on the magnetic properties of the FeCo/TbCo2 thin film and therefore on the sensitivity of shear and Rayleigh acoustic waveguides functionalized with these magnetic layers. The observed effects include a reduction in magnetic anisotropy field and an increase in magnetostriction. XPS and TEM coupled with EDS microanalysis provide insights into the variations in the properties of the nanostructured magnetic film. To safeguard the magnetic film, a thin layer of SiO2 is deposited on top, serving as a protective shield. The inclusion of this layer amplifies sensitivity to applied magnetic fields for modes with shear polarization while reducing sensitivity for Rayleigh mode. In ST-cut Quartz, the shear waves become waveguided upon the incorporation of magnetic thin films, with further enhancement achieved by introducing a SiO2 layer. Rayleigh waves are evanescent modes, the penetration depth is in the order of wavelength, and the addition of SiO2 decrease the wave confinement and therefore the sensitivity. The findings are supported by a theoretical model and experimentally validated results.

磁致伸缩薄膜作为用于磁场测量的表面声波传感器的功能化材料具有重要用途。这项研究调查了在真空和磁场下进行不同温度的退火对 FeCo/TbCo2 薄膜磁性能的影响,以及因此对使用这些磁性层的剪切声波和瑞利声波导管灵敏度的影响。观察到的影响包括磁各向异性场减小和磁致伸缩增加。XPS 和 TEM 以及 EDS 显微分析有助于深入了解纳米结构磁性薄膜的特性变化。为了保护磁性薄膜,在其顶部沉积了一层薄薄的二氧化硅作为保护层。这一层的加入会放大剪切极化模式对外加磁场的灵敏度,同时降低瑞利模式的灵敏度。在 ST 切割石英中,加入磁性薄膜后,剪切波会变成波导,而引入二氧化硅层后,剪切波会进一步增强。瑞利波是蒸发模式,穿透深度与波长相当,加入二氧化硅会降低波的约束,从而降低灵敏度。这些发现得到了理论模型和实验验证结果的支持。
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引用次数: 0
Performance Optimization for Multicolor Electrochromic Devices: Morphology and Composition Regulation of Inorganic Electrochromic Materials and Selectivity of Ions 多色电致变色装置的性能优化:无机电致变色材料的形态和成分调节以及离子选择性
IF 6.4 3区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-16 DOI: 10.1002/admt.202302139
Yinghui Tang, Hui Qiao, Xueqi Chen, Zongyu Huang, Xiang Qi

In recent years, multicolor electrochromic devices (ECDs) have attracted much attention due to their application potential for rich color similar to RGB mode. Although organic electrochromic (EC) materials are widely used in multicolor electrochromism because of their multicolor properties, remarkable weatherability remains challenging. Inorganic EC materials especially transition metal oxide are particularly attractive for excellent weatherability in ECD fabrication. Moreover, by selection of electrolytes, better ionic transfer efficiency can be rendered in the EC process. Although the morphology regulation of the EC film and the selection of electrolytes in the ion transmission layer play important roles in optimizing EC performance and have been extensively studied, a systematic and comprehensive review is lacking. In this review, the morphology regulation of the EC film and selection rules of electrolytes in the multicolor ECDs is focused, and the advantages and disadvantages of existing ways are discussed. The current application of multicolor ECDs is also outlined and it is hoped that this review can contribute some inspiration to designing and improving multicolor ECDs.

近年来,多色电致变色器件(ECD)因其与 RGB 模式类似的丰富色彩应用潜力而备受关注。尽管有机电致变色(EC)材料因其多色特性而被广泛应用于多色电致变色领域,但其出色的耐候性仍然是一项挑战。无机电致发光材料,尤其是过渡金属氧化物,在 ECD 制造中具有出色的耐候性,因此特别具有吸引力。此外,通过选择电解质,还能在电致发光过程中实现更好的离子转移效率。虽然电解质薄膜的形态调节和离子传输层中电解质的选择在优化电解质性能方面发挥着重要作用,并已得到广泛研究,但目前还缺乏系统全面的综述。本综述重点探讨了多色电致发光器件中电致发光膜的形态调控和电解质的选择规则,并讨论了现有方法的优缺点。此外,还概述了多色 ECD 的应用现状,希望本综述能为设计和改进多色 ECD 带来一些启发。
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引用次数: 0
Selective and Real‐Time Ion Monitoring with Integrated Floating‐Gate Organic Electrochemical Transistor Sensing Circuits 利用集成浮动栅有机电化学晶体管传感电路进行选择性实时离子监测
IF 6.8 3区 材料科学 Q1 Engineering Pub Date : 2024-05-16 DOI: 10.1002/admt.202400301
Giulia Frusconi, Z. Kovács-Vajna, F. Torricelli
Ion‐selective transistor‐based sensors play a pivotal role in quantifying ion concentrations in aqueous media. Existing solutions rely on direct coupling between ion‐selective membrane and channel, requiring bulky electrolyte reservoirs or complex technological approaches and material interfaces. This work introduces a transformative paradigm with ion‐selective floating‐gate organic electrochemical transistors (ISFG‐OECTs) and their integration in sensing circuits. ISFG‐OECTs feature spatial separation between ion‐selective gating and ionic‐electronic current modulation. Leveraging volumetric capacitance and solid‐state ionic liquid, efficient ionic coupling with the channel is obtained. These distinctive features make them an ideal solution for streamlined materials integration, eliminating the need for liquid reservoirs. Theoretical foundations and design guidelines for efficient ISFG‐OECT implementation are elucidated. Experimental results demonstrate the effectiveness of ISFG‐OECTs in both transistor‐sensors and current‐driven circuit configurations, revealing highly selective detection of K+ ions with a limit of detection as low as 11 × 10−6 m, even in the presence of interfering Na+ ions at concentrations two orders of magnitude higher. The proposed approach is simple, reliable, and scalable, offering opportunities for a broad range of fields, such as medical diagnostics, precision agriculture, and environmental monitoring.
基于离子选择晶体管的传感器在量化水介质中的离子浓度方面发挥着举足轻重的作用。现有的解决方案依赖于离子选择膜和通道之间的直接耦合,需要笨重的电解质容器或复杂的技术方法和材料界面。这项研究引入了离子选择浮动栅有机电化学晶体管(ISFG-OECTs)及其与传感电路的集成这一变革性范例。ISFG-OECTs 的特点是离子选择门控和离子电子电流调制之间的空间分离。利用体积电容和固态离子液体,可实现与通道的高效离子耦合。这些显著特点使它们成为简化材料集成的理想解决方案,无需使用储液器。本文阐明了高效实现 ISFG-OECT 的理论基础和设计指南。实验结果证明了 ISFG-OECTs 在晶体管传感器和电流驱动电路配置中的有效性,揭示了对 K+ 离子的高选择性检测,检测限低至 11 × 10-6 m,即使存在浓度高出两个数量级的 Na+ 离子干扰。所提出的方法简单、可靠、可扩展,为医疗诊断、精准农业和环境监测等广泛领域提供了机会。
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引用次数: 0
Femtosecond Laser Nanomachining of High‐Aspect‐Ratio Channels in Bulk Fused Silica 在块状熔融石英中用飞秒激光纳米加工高宽比通道
IF 6.8 3区 材料科学 Q1 Engineering Pub Date : 2024-05-16 DOI: 10.1002/admt.202400240
Pasquale Barbato, R. Osellame, R. Martínez Vázquez
Thee‐dimensional nano‐structuring of bulk fused silica glass remains a challenging issue due to limitations of traditional fabrication methods. In the present work the fabrication of hollow mm‐length channels is demonstrated in bulk fused silica by femtosecond laser irradiation followed by chemical etching, achieving feature sizes of 300 nm. The tight focusing and threshold energy conditions allow to reveal unexplored fabrication regimes. The robustness and repeatability of the process are demonstrated through the fabrication of fused silica diffraction gratings, made of parallel hollow channels with variable pitches even in the sub‐wavelength regime.
由于传统制造方法的局限性,大块熔融石英玻璃的三维纳米结构仍然是一个具有挑战性的问题。在本研究中,通过飞秒激光辐照和化学蚀刻,在块状熔融石英中制造出了毫米长的空心通道,特征尺寸达到 300 纳米。严格的聚焦和阈值能量条件揭示了尚未探索的制造机制。该工艺的稳健性和可重复性通过熔融石英衍射光栅的制造得到了证明,该光栅由平行中空通道组成,即使在亚波长范围内也具有可变的间距。
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引用次数: 0
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Advanced Materials Technologies
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