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Enhanced anti-breast cancer activity of green synthesized selenium nanoparticles by PEGylation: induction of apoptosis and potential anticancer drug delivery system 通过 PEG 化增强绿色合成硒纳米粒子的抗乳腺癌活性:诱导细胞凋亡和潜在的抗癌药物输送系统
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-05-27 DOI: 10.1088/2043-6262/ad4bae
Samer Y Al-Qaraleh, Wael A Al-Zereini, Sawsan A Oran, Osama Y Al-Madanat, Aiman I Al-Qtaitat and Abdalrahim Alahmad
Breast cancer is a disease associated with high morbidity and mortality rates worldwide. The potential use of biogenic nanoparticles as alternative anticancer agents has been immensely acknowledged in several studies, particularly selenium nanoparticles (SeNPs). Nanoparticles were synthesised using the aqueous extract of Moringa peregrine (MPM-SeNPs) and were PEGylated (PEG-MPM-SeNPs). MPM-SeNPs were characterised by chemical and physical techniques. The successful capping of MPM-SeNPs with PEG was confirmed by spectrophotometric measurements and via Fourier-transform infrared spectroscopy (FT-IR) analysis. Furthermore, the effect of PEGylation of MPM-SeNPs on enhancing their anti-breast cancer activity and as a drug delivery agent was evaluated. Therefore, the loading efficiency and release of DOX at different pH values were measured; the antiproliferative activity of PEG-MPM-SeNPs against the adenocarcinoma breast cancer cell line (MDA-MB-231) was evaluated and compared with that of biogenic MPM-SeNPs and DOX-conjugated PEG-MPM-SeNPs. PEG-MPM-SeNPs and DOX-PEG-MPM-SeNPs had reduced IC50 values compared to MPM-SeNPs; IC50 of 11.54 ± 1.74 and 31.27 ± 2.9 μg mL−1 compared to 71.4 ± 3.4 μg mL−1, respectively. MPM-SeNPs and PEG-MPM-SeNPs caused apoptosis to MDA-MB-231 cells with a significant decrease in the mitochondrial membrane potential (MMP), increase in the released cytochrome C (Cyt C), and activation of caspase-3/9 (P < 0.05). Linking DOX to PEG-MPM-SeNPs led to an increase in caspase-3/8 concentrations and an increase in the released Cyt C, but there were non-significant differences in MMP (P > 0.1) between treated and untreated control cancer cells. MPM-SeNPs and PEG-MPM-SeNPs caused apoptotic reactions via an intrinsic pathway, while linking DOX to PEG-MPM-SeNPs caused apoptosis in cancer cells through an extrinsic pathway.
乳腺癌是全世界发病率和死亡率都很高的一种疾病。生物纳米粒子(尤其是硒纳米粒子(SeNPs))作为替代抗癌剂的潜在用途已在多项研究中得到广泛认可。研究人员使用辣木的水提取物合成了纳米颗粒(MPM-SeNPs),并对其进行了 PEG 化处理(PEG-MPM-SeNPs)。MPM-SeNPs 采用化学和物理技术进行表征。通过分光光度测量和傅立叶变换红外光谱(FT-IR)分析,证实了 MPM-SeNPs 与 PEG 的成功封装。此外,还评估了 PEG 化 MPM-SeNPs 对提高其抗乳腺癌活性和作为药物递送剂的效果。因此,测量了 DOX 在不同 pH 值下的负载效率和释放量;评估了 PEG-MPM-SeNPs 对腺癌乳腺癌细胞系(MDA-MB-231)的抗增殖活性,并与生物源 MPM-SeNPs 和 DOX 共轭 PEG-MPM-SeNPs 的抗增殖活性进行了比较。与 MPM-SeNPs 相比,PEG-MPM-SeNPs 和 DOX-PEG-MPM-SeNPs 的 IC50 值有所降低;IC50 分别为 11.54 ± 1.74 和 31.27 ± 2.9 μg mL-1 ,而 MPM-SeNPs 为 71.4 ± 3.4 μg mL-1。MPM-SeNPs 和 PEG-MPM-SeNPs 可导致 MDA-MB-231 细胞凋亡,线粒体膜电位(MMP)显著降低,释放的细胞色素 C(Cyt C)增加,Caspase-3/9 被激活(P < 0.05)。将 DOX 与 PEG-MPM-SeNPs 连接会导致 Caspase-3/8 浓度增加和释放的细胞色素 C 增加,但在处理过的和未处理过的对照组癌细胞之间,MMP 的差异并不显著(P > 0.1)。MPM-SeNPs和PEG-MPM-SeNPs通过内在途径导致凋亡反应,而将DOX与PEG-MPM-SeNPs连接则通过外在途径导致癌细胞凋亡。
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引用次数: 0
A current review on boron nitride nanotubes and their applications 氮化硼纳米管及其应用综述
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-06 DOI: 10.1088/2043-6262/ad22d6
Adithya Lenin Tamilkovan, Pandurangan Arumugam
BNNTs are the tubular variants of the ceramic compound hexagonal boron nitride (hBN) and are known for their high thermal and chemical stability. The research on BNNTs is ever-evolving, researchers are on a quest to optimise the synthesis procedure for the nanomaterial. Here a variety of currently followed synthesis techniques were discussed and compared. X-ray diffraction patterns and electron microscopy results of BNNTs synthesised by various techniques were compared, this would give the pros and cons of each synthesis technique. Based on this, suggestions for the best-suited synthesis technique from an academic as well as industrial perspective were given. The individual properties of these nanotubes, along with their potential applications in the field of spintronics, surface wetting, and radiation capture were delineated.
BNNTs 是陶瓷化合物六方氮化硼(hBN)的管状变体,以其高度的热稳定性和化学稳定性而著称。有关 BNNTs 的研究一直在不断发展,研究人员一直在努力优化这种纳米材料的合成过程。在此,我们对目前采用的各种合成技术进行了讨论和比较。通过比较各种技术合成的 BNNT 的 X 射线衍射图样和电子显微镜结果,可以看出每种合成技术的优缺点。在此基础上,从学术和工业角度对最适合的合成技术提出了建议。此外,还介绍了这些纳米管的特性,以及它们在自旋电子学、表面润湿和辐射捕获领域的潜在应用。
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引用次数: 0
A review on the types of nanomaterials and methodologies used for the development of biosensors 纳米材料类型及生物传感器开发方法综述
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-02 DOI: 10.1088/2043-6262/ad21e8
Sourav Ghosh, K Martin Sagayam, Dibyajyoti Haldar, A Amir Anton Jone, Biswaranjan Acharya, Vassilis C Gerogiannis, Andreas Kanavos
Biosensors have gained significant attention in various fields such as food processing, agriculture, environmental monitoring, and healthcare. With the continuous advancements in research and technology, a wide variety of biosensors are being developed to cater to diverse applications. However, the effective development of nanobiosensors, particularly the synthesis of nanomaterials, remains a crucial step. Many nanobiosensors face challenges related to instability and selectivity, making it difficult to achieve proper packaging. While some biosensors have been successfully implemented in commercial settings, there is a pressing need to address their limitations and advance their capabilities. The next generation of biosensors, based on nanomaterials, holds promise in overcoming these challenges and enhancing the overall performance of biosensor devices. The commercial viability of these biosensors will rely on their accuracy, reliability, and cost-effectiveness. This review paper provides an overview of various types of nanomaterials and their applications in the development of nanobiosensors. The paper highlights a comparison of different nanomaterial-based biosensors, discussing their advantages, limitations, and performance characteristics.
生物传感器在食品加工、农业、环境监测和医疗保健等各个领域都获得了极大的关注。随着研究和技术的不断进步,各种生物传感器正被开发出来,以满足不同的应用需求。然而,纳米生物传感器的有效开发,尤其是纳米材料的合成,仍然是至关重要的一步。许多纳米生物传感器面临着与不稳定性和选择性有关的挑战,因此很难实现适当的封装。虽然一些生物传感器已成功应用于商业环境,但仍迫切需要解决其局限性并提高其能力。基于纳米材料的下一代生物传感器有望克服这些挑战,并提高生物传感器设备的整体性能。这些生物传感器的商业可行性将取决于其准确性、可靠性和成本效益。本综述概述了各种类型的纳米材料及其在纳米生物传感器开发中的应用。本文重点比较了不同的纳米材料生物传感器,讨论了它们的优势、局限性和性能特点。
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引用次数: 0
Biogenic synthesis of silver, gold, and palladium nanoparticles using moringa oleifera seeds: exploring photocatalytic, catalytic, and antimicrobial activities 利用油茶籽生物合成银、金和钯纳米粒子:探索光催化、催化和抗菌活性
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-19 DOI: 10.1088/2043-6262/ad1a9b
M S Anandha Prabhu, G Edwin Sheela, Abeer M Mohammad, Rabab A Hegazy, S Sasi Florence, V Sarojini
In this study, we explored the green synthesis of metal nanoparticles (Ag-NPs, Au-NPs, and Pd-NPs) using Moringa oleifera seed (MOS) extract, which is known for its nutrient density, antioxidant properties, anti-inflammatory effects, and potential benefits in managing cholesterol, blood sugar levels, as well as promoting digestion, skin, and hair health. The nanoparticles’ size was controlled by varying the concentration of MOS extract. The successful formation of Au-NPs and Ag-NPs was confirmed through surface plasmon resonance (SPR), while the absence of absorption at 420 nm indicated the reduction of Pd2+ ions to Pd0, affirming the synthesis of Pd-NPs. The nanoparticles exhibited mono-dispersed, spherical shapes with confirmed crystallinity. Sizes were determined as 28 nm for Pd-NPs, 5 nm for Au-NPs, and 19 nm for Ag-NPs. The MOS extract’s phenols and proteins played a crucial role in reducing and stabilising Ag-NPs, Au-NPs, and Pd-NPs. Notably, the synthesised nanoparticles demonstrated strong antimicrobial activity, particularly against Salmonella typhi, making them potential antibacterial agents. The catalytic efficiency of Au-NPs, Ag-NPs and Pd-NPs was studied using the reduction of 4-Nitrophenol (4-NP) by NaBHto 4-Aminophenol. Additionally, Au-NPs showed enhanced photocatalytic degradation rate constant and catalytic reaction rate constant of 0.0038/min and 0.261/min respectively, due to their small size and increased surface area. By combining a green synthesis approach with an in-depth analysis of properties and diverse applications, this study provides valuable insights into the immense potential of MOS-assisted metal nanoparticles for various technological and environmental advancements.
在本研究中,我们探索了利用油辣木籽(MOS)提取物绿色合成金属纳米粒子(Ag-NPs、Au-NPs 和 Pd-NPs)的方法。油辣木籽因其营养密度高、抗氧化性强、抗炎效果好以及在控制胆固醇和血糖水平、促进消化、皮肤和头发健康方面具有潜在益处而闻名。通过改变 MOS 提取物的浓度来控制纳米粒子的大小。通过表面等离子体共振(SPR)证实了 Au-NPs 和 Ag-NPs 的成功形成,而 420 纳米处没有吸收表明 Pd2+ 离子被还原成 Pd0,从而证实了 Pd-NPs 的合成。纳米粒子呈单分散球形,结晶度得到证实。经测定,Pd-NPs 的尺寸为 28 nm,Au-NPs 为 5 nm,Ag-NPs 为 19 nm。MOS 提取物中的酚类和蛋白质在还原和稳定 Ag-NPs、Au-NPs 和 Pd-NPs 方面发挥了重要作用。值得注意的是,合成的纳米粒子具有很强的抗菌活性,特别是对伤寒沙门氏菌,使其成为潜在的抗菌剂。利用 NaBH4 将 4-硝基苯酚(4-NP)还原为 4-氨基苯酚,研究了 Au-NPs、Ag-NPs 和 Pd-NPs 的催化效率。结果表明,Ag-NPs 和 Pd-NPs 的光催化降解率常数和催化反应率常数分别为 0.0038/min 和 0.261/min,而 Au-NPs 的光催化降解率常数和催化反应率常数分别为 0.0038/min 和 0.261/min。通过将绿色合成方法与对其特性和多样化应用的深入分析相结合,本研究为 MOS 辅助金属纳米粒子在各种技术和环境进步方面的巨大潜力提供了宝贵的见解。
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引用次数: 0
Synthesis and application of ZSM-5/Graphene composite for photocatalytic degradation of industrial dyes 用于光催化降解工业染料的 ZSM-5/Graphene 复合材料的合成与应用
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-19 DOI: 10.1088/2043-6262/ad1a9e
Veena Sodha, Mahuya Bandyopadhyay, Rama Gaur, Rajib Bandyopadhyay, Syed Shahabuddin
Various materials and technologies are being employed to address the concern of increased wastewater generation. In this work, the synthesis of ZSM-5 (Zeolite Socony Mobil-5) and graphene (GR) composite, their characterisation, and application for the removal of dyes are presented. Two composites of ZSM-5 and GR composites were prepared via the hydrothermal method by varying the loading amount of GR, i.e. 1% and 5%, and labelled as GZ1 and GZ5. The parent and composite materials were characterised using field emission scanning electron microscope (FE-SEM), x-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), x-ray photoelectrons spectroscopy (XPS), Raman, and Fourier transform infrared (FTIR). The materials were then employed for the photodegradation of methyl orange (MO) dye. The adsorption efficiencies for ZSM-5, GR, GZ1, and GZ5 were found as 0%, 17.8%, 0%, and 16% respectively. According to photodegradation results, the GZ1 composite exhibits the maximum degradation efficiency of 75.3% for 20 ppm of MO, within 180 min of light exposure. The scavenger studies were performed to evaluate the role of active oxygen species (AOS) in the photocatalysis mechanism. All studies were performed with the catalyst dosage of 0.5 mg ml−1. The degradation efficiencies for GR, GZ5, and Z5 were reported as 34.2%, 20.8%, and 17.5%, respectively. On increasing the irradiation time to 240 min, the degradation efficiency of GZ1 reached 92%. The removal efficiencies for MO (7 ppm) and methyl blue (5 ppm) in a 12-ppm dye mixture were observed to be 98% and 97.2% respectively within 180 min of light exposure with GZ1 composite.
目前正在采用各种材料和技术来解决废水产生量增加的问题。本研究介绍了 ZSM-5(沸石 Socony Mobil-5)和石墨烯(GR)复合材料的合成、特性及其在去除染料方面的应用。通过水热法制备了两种 ZSM-5 和石墨烯复合材料,改变了石墨烯的负载量,即 1%和 5%,并标记为 GZ1 和 GZ5。使用场发射扫描电子显微镜 (FE-SEM)、X 射线衍射 (XRD)、漫反射光谱 (DRS)、X 射线光电子能谱 (XPS)、拉曼光谱和傅立叶变换红外光谱 (FTIR) 对母体材料和复合材料进行了表征。然后将这些材料用于甲基橙(MO)染料的光降解。ZSM-5、GR、GZ1 和 GZ5 的吸附效率分别为 0%、17.8%、0% 和 16%。光降解结果显示,GZ1 复合材料在光照 180 分钟内对 20 ppm MO 的降解效率最高,达到 75.3%。为了评估活性氧(AOS)在光催化机理中的作用,进行了清除剂研究。所有研究都是在催化剂用量为 0.5 mg ml-1 的条件下进行的。据报告,GR、GZ5 和 Z5 的降解效率分别为 34.2%、20.8% 和 17.5%。将辐照时间延长至 240 分钟后,GZ1 的降解效率达到了 92%。在使用 GZ1 复合材料对 12ppm 的染料混合物进行光照射 180 分钟后,对 MO(7 ppm)和甲基蓝(5 ppm)的去除率分别达到 98% 和 97.2%。
{"title":"Synthesis and application of ZSM-5/Graphene composite for photocatalytic degradation of industrial dyes","authors":"Veena Sodha, Mahuya Bandyopadhyay, Rama Gaur, Rajib Bandyopadhyay, Syed Shahabuddin","doi":"10.1088/2043-6262/ad1a9e","DOIUrl":"https://doi.org/10.1088/2043-6262/ad1a9e","url":null,"abstract":"Various materials and technologies are being employed to address the concern of increased wastewater generation. In this work, the synthesis of ZSM-5 (Zeolite Socony Mobil-5) and graphene (GR) composite, their characterisation, and application for the removal of dyes are presented. Two composites of ZSM-5 and GR composites were prepared via the hydrothermal method by varying the loading amount of GR, i.e. 1% and 5%, and labelled as GZ1 and GZ5. The parent and composite materials were characterised using field emission scanning electron microscope (FE-SEM), x-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), x-ray photoelectrons spectroscopy (XPS), Raman, and Fourier transform infrared (FTIR). The materials were then employed for the photodegradation of methyl orange (MO) dye. The adsorption efficiencies for ZSM-5, GR, GZ1, and GZ5 were found as 0%, 17.8%, 0%, and 16% respectively. According to photodegradation results, the GZ1 composite exhibits the maximum degradation efficiency of 75.3% for 20 ppm of MO, within 180 min of light exposure. The scavenger studies were performed to evaluate the role of active oxygen species (AOS) in the photocatalysis mechanism. All studies were performed with the catalyst dosage of 0.5 mg ml<sup>−1</sup>. The degradation efficiencies for GR, GZ5, and Z5 were reported as 34.2%, 20.8%, and 17.5%, respectively. On increasing the irradiation time to 240 min, the degradation efficiency of GZ1 reached 92%. The removal efficiencies for MO (7 ppm) and methyl blue (5 ppm) in a 12-ppm dye mixture were observed to be 98% and 97.2% respectively within 180 min of light exposure with GZ1 composite.","PeriodicalId":7359,"journal":{"name":"Advances in Natural Sciences: Nanoscience and Nanotechnology","volume":"103 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139508268","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hetero-epitaxial grown Pt@Au core-shell bimetallic nanoparticles on reduced graphene oxide (RGO) as electrocatalyst for oxygen reduction reaction in alkaline media 还原型氧化石墨烯 (RGO) 上异质外延生长的 Pt@Au 核壳双金属纳米粒子作为碱性介质中氧还原反应的电催化剂
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-17 DOI: 10.1088/2043-6262/ad1a9d
P Raghavendra, Y Chandra Sekhar, G Vishwakshan Reddy, P Sri Chandana, L Subramanyam Sarma
The core-shell structured Pt@Aubimetallic nanoparticles (NPs) were decorated on the reduced graphene oxide (RGO) surface by a heteroepitaxial growth method. The morphological details of Pt@Au/RGO core/shell bimetallic NPs were assessed by high-resolution transmission electron microscopy (HR-TEM), x-ray diffraction (XRD), and energy-dispersive x-ray spectroscopy (EDS). Electron microscopy results revealed that Pt@Au particles of 3.4 nm were firmly attached to RGO sheets. The electrochemical response of Pt@Au/RGO nanostructured electrocatalyst was measured through cyclic voltammetry (CV) at room temperature in 0.1 M KOH solution. Oxygen reduction reaction (ORR) efficacies of Pt@Au/RGO were evaluated by linear sweep voltammetry (LSV) by rotating catalyst-coated glassy carbon (GC) electrode at different rotation speeds in oxygen saturated 0.1 M KOH solution. The electrochemical activity descriptors (half-wave potential, onset potential, limiting current density) were assessed from ORR polarisation curves. The results revealed that Pt@Au/RGO bimetallic NPs showed enhanced higher catalytic activity towards ORR compared to commercial Pt/C catalyst as well as similarly synthesised Pt/RGO and Au/RGO. The enhanced catalytic activity of Pt@Au/RGO electrocatalyst might result from the core/shell structure with a tiny Pt core and a thin Au shell, as well as the synergistic effects of Au and Pt.
采用异质外延生长法在还原氧化石墨烯(RGO)表面装饰了核壳结构的 Pt@Aubimetallic 纳米粒子(NPs)。通过高分辨率透射电子显微镜(HR-TEM)、X 射线衍射(XRD)和能量色散 X 射线光谱(EDS)评估了 Pt@Au/RGO 核/壳双金属 NPs 的形态细节。电子显微镜结果显示,3.4 nm 的 Pt@Au 颗粒牢固地附着在 RGO 片上。室温下,在 0.1 M KOH 溶液中,通过循环伏安法(CV)测量了 Pt@Au/RGO 纳米结构电催化剂的电化学响应。在氧气饱和的 0.1 M KOH 溶液中,以不同的转速旋转涂有催化剂的玻璃碳(GC)电极,通过线性扫描伏安法(LSV)评估了 Pt@Au/RGO 的氧还原反应(ORR)效率。根据 ORR 极化曲线评估了电化学活性描述因子(半波电位、起始电位、极限电流密度)。结果表明,与商用 Pt/C 催化剂以及类似合成的 Pt/RGO 和 Au/RGO 相比,Pt@Au/RGO 双金属 NPs 在 ORR 方面表现出更高的催化活性。Pt@Au/RGO 电催化剂催化活性的增强可能是由于其具有微小的铂核和较薄的金壳的核/壳结构,以及金和铂的协同效应。
{"title":"Hetero-epitaxial grown Pt@Au core-shell bimetallic nanoparticles on reduced graphene oxide (RGO) as electrocatalyst for oxygen reduction reaction in alkaline media","authors":"P Raghavendra, Y Chandra Sekhar, G Vishwakshan Reddy, P Sri Chandana, L Subramanyam Sarma","doi":"10.1088/2043-6262/ad1a9d","DOIUrl":"https://doi.org/10.1088/2043-6262/ad1a9d","url":null,"abstract":"The core-shell structured Pt@Aubimetallic nanoparticles (NPs) were decorated on the reduced graphene oxide (RGO) surface by a heteroepitaxial growth method. The morphological details of Pt@Au/RGO core/shell bimetallic NPs were assessed by high-resolution transmission electron microscopy (HR-TEM), x-ray diffraction (XRD), and energy-dispersive x-ray spectroscopy (EDS). Electron microscopy results revealed that Pt@Au particles of 3.4 nm were firmly attached to RGO sheets. The electrochemical response of Pt@Au/RGO nanostructured electrocatalyst was measured through cyclic voltammetry (CV) at room temperature in 0.1 M KOH solution. Oxygen reduction reaction (ORR) efficacies of Pt@Au/RGO were evaluated by linear sweep voltammetry (LSV) by rotating catalyst-coated glassy carbon (GC) electrode at different rotation speeds in oxygen saturated 0.1 M KOH solution. The electrochemical activity descriptors (half-wave potential, onset potential, limiting current density) were assessed from ORR polarisation curves. The results revealed that Pt@Au/RGO bimetallic NPs showed enhanced higher catalytic activity towards ORR compared to commercial Pt/C catalyst as well as similarly synthesised Pt/RGO and Au/RGO. The enhanced catalytic activity of Pt@Au/RGO electrocatalyst might result from the core/shell structure with a tiny Pt core and a thin Au shell, as well as the synergistic effects of Au and Pt.","PeriodicalId":7359,"journal":{"name":"Advances in Natural Sciences: Nanoscience and Nanotechnology","volume":"10 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139508267","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on immobilisation process on lateral flow assay test strip for detection of Enrofloxacin antibiotic by inkjet printing 通过喷墨打印固定化工艺研究用于检测恩诺沙星抗生素的横向流动检测试纸
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-17 DOI: 10.1088/2043-6262/ad1aa0
Duc Minh Trinh Dinh, Anh Van Thi Le, Phuong Hong Lam, Mai Thi Le, Dung My Thi Dang, Chien Mau Dang, Ngan Nguyen Le
Enrofloxacin has been widely and increasingly used in veterinary medicine to treat infection on animals which could lead to antibiotic resistance for the consumer. Among the available detection techniques for Enrofloxacin, immunoassay lateral flow test strip is realised to be a rapid and accurate detection method for on-site analysis of Enrofloxacin antibiotic. The current study aims to analyse the application of inkjet printing technology on the immobilisation of biological substances at the test line and control line position of the test strip. With the printing parameters value at 35 °C, 35 °C, 7 layers and 15 μm for cartridge temperature, substrate temperature, printing layers and drop spacing, respectively, the fabricated test strips show correlation coefficient R2 at 0.993 for the test with Enrofloxacin samples in the concentration range from 0 to 100 ppb. Compared to conventional fabrication method, the immobilisation process utilising inkjet printing technology is considered to be superior in printing patterns with a simple and material-saving process, which holds a potential of innovative and financially beneficial approach for on-site detection of Enrofloxacin antibiotic.
恩诺沙星越来越广泛地应用于兽医治疗动物感染,这可能会导致消费者对抗生素产生抗药性。在现有的恩诺沙星检测技术中,免疫测定侧流试纸被认为是现场分析恩诺沙星抗生素的一种快速准确的检测方法。本研究旨在分析喷墨打印技术在测试条测试线和控制线位置固定生物物质的应用。在墨盒温度、基底温度、打印层数和墨滴间距分别为 35 °C、35 °C、7 层和 15 μm 的条件下,制成的试纸与恩诺沙星样品在 0 至 100 ppb 浓度范围内的测试相关系数 R2 为 0.993。与传统的制造方法相比,利用喷墨打印技术的固定化工艺在打印图案方面更胜一筹,而且工艺简单、节省材料,是一种具有创新潜力和经济效益的现场检测恩诺沙星抗生素的方法。
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引用次数: 0
Highly uniform core/shell structures AuR/Ag and AuR/Ag@BSA with various shell thicknesses for surface-enhanced Raman scattering 用于表面增强拉曼散射的具有不同壳厚度的高度均匀核/壳结构 AuR/Ag 和 AuR/Ag@BSA
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-16 DOI: 10.1088/2043-6262/ad1a9a
Khac Khoi Tran, Tien Ha Le, Viet Ha Chu, Thi Hue Do
This work indicates the synthesis of uniform core/shell nanostructures (AuR/Ag) with different thicknesses of Ag shell by the double seed method. This method consists of two self-sufficient progresses, one seed for the formation of gold nanorods (AuRs) and one for the formation of the Ag shell for the gold nanorods to form the AuR/Ag. Acid ascorbic (L-AA) acts as a weak reducing agent and hexadecyltrimethylammonium chloride (CTAC) acts as a surfactant for Ag shell. The formation and growth of the Ag shell were carefully investigated by changing the reaction factors such as temperature, time, and concentration of AgNO3. The greater the concentration of AgNO3 shelling precursor, the thicker the shell and therefore the more high-energy vibrational modes appear in the near-ultraviolet region. In survey of surface-enhanced Raman scattering effect of AuRs and AuR/Ag with Rhodamine B (RB) detector, the results show that AuR/Ag has the ability to enhance Raman signal much better than AuRs. At the same time, the thicker the Ag shell, the better the Raman signal enhancement ability.
这项研究表明,利用双种子法合成了具有不同厚度银壳的均匀核/壳纳米结构(AuR/Ag)。该方法包括两个自给自足的过程,一个种子用于形成金纳米棒(AuRs),另一个种子用于形成金纳米棒的银壳,从而形成 AuR/Ag。抗坏血酸(L-AA)作为弱还原剂,十六烷基三甲基氯化铵(CTAC)作为银壳的表面活性剂。通过改变温度、时间和 AgNO3 浓度等反应因素,仔细研究了银壳的形成和生长过程。AgNO3 脱壳前驱体的浓度越高,外壳越厚,因此在近紫外区出现的高能振动模式也越多。在利用罗丹明 B(RB)探测器对 AuRs 和 AuR/Ag 的表面增强拉曼散射效应进行研究时,结果表明 AuR/Ag 比 AuRs 具有更好的增强拉曼信号的能力。同时,银壳越厚,拉曼信号增强能力越强。
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引用次数: 0
Synthesis and mechanistic approach to investigate crystallite size of NbSe2 nanoparticles 研究 NbSe2 纳米粒子晶粒尺寸的合成和机理方法
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-16 DOI: 10.1088/2043-6262/ad1a9c
Shivani R Bharucha, Mehul S Dave, Ranjan Kr Giri, Sunil H Chaki, Tushar A Limbani
Niobium diselenide (NbSe2) belongs to the class of transition metal dichalcogenides (TMDCs) and exhibits peculiar features such as charge density waves, superconductivity, and periodic crystal lattice distortion. The main focus of the article is the synthesis and characterisation of NbSe2 NPs utilising the wet chemical precursor solution route at room temperature, followed by in-depth x-ray diffraction (XRD) characterisation and analysis using the aforementioned techniques. The EDS result demonstrated that the NbSe2 NPs are devoid of impurities and close to stoichiometry. The sample has a crystalline hexagonal structure with the lattice constants a = b = 3.443Å, c = 12.576 Å, and α = β = 90°, γ = 120°, according to the XRD results. The work emphasises the need of comprehending how lattice strain and crystallite size affect physical attributes. x-ray peak broadening was used to study the epitaxial crystallisation of NbSe2 NPs. Various methods for determining crystallite size, such as the Williamson–Hall (W-H) method, Debye–Scherrer plots, uniform deformation model (UDM), uniform stress deformation model (USDM), uniform deformation energy density model (UDEDM), size strain plot (SSP) method, and Halder-Wagner (H-W) method, are employed to comprehensively analyse the nanoparticle characteristics, and additionally, high-resolution transmission electron microscopy (HRTEM) is employed to visualise the morphology and particle size distribution of the synthesised NbSe2 NPs. Physical parameters, including lattice stress, strain, and energy density, are also evaluated more precisely from the XRD pattern reflection peaks. The outcomes shed light on the interplay between crystallite size, lattice strain, and their effects on the material’s properties and showed excellent intercorrelation of the average crystallite sizes as estimated by employing various methods.
二硒化铌(NbSe2)属于过渡金属二硒化物(TMDCs),具有电荷密度波、超导性和周期性晶格畸变等奇特特征。文章的重点是利用湿化学前驱体溶液路线在室温下合成 NbSe2 NPs 并对其进行表征,然后利用上述技术对其进行深入的 X 射线衍射(XRD)表征和分析。EDS 结果表明,NbSe2 NPs 不含杂质,接近化学计量。根据 XRD 结果,该样品具有晶格常数 a = b = 3.443 Å、c = 12.576 Å 和 α = β = 90°、γ = 120°的结晶六边形结构。这项工作强调了理解晶格应变和晶粒大小如何影响物理属性的必要性。X 射线峰展宽用于研究 NbSe2 NPs 的外延结晶。确定晶体尺寸的方法有多种,如威廉森-霍尔(W-H)法、德拜-舍勒图、均匀变形模型(UDM)、均匀应力变形模型(USDM)、均匀变形能量密度模型(UDEDM)、尺寸应变图(SSP)法、此外,还采用了高分辨率透射电子显微镜(HRTEM)来观察合成 NbSe2 NPs 的形貌和粒度分布。物理参数,包括晶格应力、应变和能量密度,也通过 XRD 图谱反射峰得到了更精确的评估。研究结果揭示了晶粒尺寸、晶格应变之间的相互作用及其对材料特性的影响,并显示了通过各种方法估算出的平均晶粒尺寸之间的良好相互关系。
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引用次数: 0
Synthesis, evaluation, and monitoring of red amaranth extract for power production 用于发电的红苋菜提取物的合成、评估和监测
IF 2.1 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-16 DOI: 10.1088/2043-6262/ad1a9f
N Y Tanisa, K A Khan, M Salahuddin
The scientific paper describes the synthesis of silver nanoparticles (Ag NPs) using a fresh red amaranth preparation and explores their potential to enhance the output current of a red amaranth bio-electrolytic cell. The study employed various analytical techniques such as x-ray diffraction (XRD), Fourier transform infrared (FTIR), ultraviolet-visible spectroscopy (UV–vis), dynamic light scattering (DLS), and Raman spectroscopy to characterise and detect the nanoparticles. The UV–vis analysis of the dripping media containing silver nanoparticles exhibited an absorption peak, indicating the presence of the nanoparticles. FTIR was utilised to examine the interaction between the biomaterial components and the oxidation and wrapping of silver nanoparticles. XRD analysis revealed that the synthesised nanoparticles possessed a naturally columnar shape and a face-centered cubic (FCC) structure. The average size and morphology of the nanoparticles were characterised by dynamic light scattering (DLS). Raman spectra revealed the unique surface-enhancing properties of synthesised Ag NPs. The research presented in the paper highlights the remarkable performance of silver nanoparticles in bio-electrolyte power generation systems. It emphasises a straightforward, cost-effective, and environmentally friendly method for producing Ag NPs using red amaranth extract. These findings contribute to the development of a novel framework for bio-electrochemical cells and emphasise the importance of further research on the effects of Ag NPs on these cells. It is found that the open circuit voltage is 3.254 V, short circuit current is 2.256 mA, and load current is 1.987 mA before using the Ag NPs and open circuit voltage is 5.678 volts, short circuit current is 4.212 mA, and load current is 2.887 mA after using the Ag NPs. It is seen that the values of the three parameters have been increased after using the Ag NPs, which ensured the significance of the use of Ag NPs.
这篇科学论文介绍了利用新鲜红苋菜制剂合成银纳米粒子(Ag NPs)的情况,并探讨了其增强红苋菜生物电解池输出电流的潜力。研究采用了多种分析技术,如 X 射线衍射 (XRD)、傅立叶变换红外 (FTIR)、紫外-可见光谱 (UV-vis)、动态光散射 (DLS) 和拉曼光谱来表征和检测纳米颗粒。对含有纳米银颗粒的滴注介质进行的紫外可见光谱分析显示出一个吸收峰,表明纳米颗粒的存在。傅立叶变换红外光谱用于检测生物材料成分之间的相互作用以及纳米银颗粒的氧化和包裹。XRD 分析表明,合成的纳米粒子具有自然柱状和面心立方(FCC)结构。动态光散射(DLS)表征了纳米颗粒的平均尺寸和形态。拉曼光谱显示了合成银纳米粒子独特的表面增强特性。论文中介绍的研究强调了银纳米粒子在生物电解质发电系统中的卓越性能。它强调了一种利用红苋菜提取物生产银纳米粒子的简单、经济、环保的方法。这些发现有助于开发生物电化学电池的新型框架,并强调了进一步研究银氧化物对这些电池的影响的重要性。使用 Ag NPs 前,开路电压为 3.254 V,短路电流为 2.256 mA,负载电流为 1.987 mA;使用 Ag NPs 后,开路电压为 5.678 V,短路电流为 4.212 mA,负载电流为 2.887 mA。可以看出,使用银氧化物后,三个参数的值都有所提高,这确保了使用银氧化物的重要性。
{"title":"Synthesis, evaluation, and monitoring of red amaranth extract for power production","authors":"N Y Tanisa, K A Khan, M Salahuddin","doi":"10.1088/2043-6262/ad1a9f","DOIUrl":"https://doi.org/10.1088/2043-6262/ad1a9f","url":null,"abstract":"The scientific paper describes the synthesis of silver nanoparticles (Ag NPs) using a fresh red amaranth preparation and explores their potential to enhance the output current of a red amaranth bio-electrolytic cell. The study employed various analytical techniques such as x-ray diffraction (XRD), Fourier transform infrared (FTIR), ultraviolet-visible spectroscopy (UV–vis), dynamic light scattering (DLS), and Raman spectroscopy to characterise and detect the nanoparticles. The UV–vis analysis of the dripping media containing silver nanoparticles exhibited an absorption peak, indicating the presence of the nanoparticles. FTIR was utilised to examine the interaction between the biomaterial components and the oxidation and wrapping of silver nanoparticles. XRD analysis revealed that the synthesised nanoparticles possessed a naturally columnar shape and a face-centered cubic (FCC) structure. The average size and morphology of the nanoparticles were characterised by dynamic light scattering (DLS). Raman spectra revealed the unique surface-enhancing properties of synthesised Ag NPs. The research presented in the paper highlights the remarkable performance of silver nanoparticles in bio-electrolyte power generation systems. It emphasises a straightforward, cost-effective, and environmentally friendly method for producing Ag NPs using red amaranth extract. These findings contribute to the development of a novel framework for bio-electrochemical cells and emphasise the importance of further research on the effects of Ag NPs on these cells. It is found that the open circuit voltage is 3.254 V, short circuit current is 2.256 mA, and load current is 1.987 mA before using the Ag NPs and open circuit voltage is 5.678 volts, short circuit current is 4.212 mA, and load current is 2.887 mA after using the Ag NPs. It is seen that the values of the three parameters have been increased after using the Ag NPs, which ensured the significance of the use of Ag NPs.","PeriodicalId":7359,"journal":{"name":"Advances in Natural Sciences: Nanoscience and Nanotechnology","volume":"16 1","pages":""},"PeriodicalIF":2.1,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139508260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Advances in Natural Sciences: Nanoscience and Nanotechnology
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