Emad Kadum Njim, Hussam Raad Hasan, Muhsin J. Jweeg, Muhannad Al-Waily, Alaa Ali Hameed, Ahmed M. Youssef, Fahmi M. Elsayed
In the field of lighter substitute materials, sandwich plate models of composite and hybrid foam cores are used in this study. Three core structures: composite core structure and then the core is replaced by a structure of a closed and open repeating cellular pattern manufactured with 3D printing technology. It finally integrated both into one hybrid open-cell core filled with foam and employed the same device (WBW-100E) to conduct the three-point bending experiment. The test was conducted based on the international standard (ASTM-C 393-00) to perform the three-point bending investigation on the sandwich structure. Flexural test finding, with the hybrid polyurethane/polytropic acid (PUR/PLA) core, the ultimate bending load is increased by 127.7% compared to the open-cell structure core. In addition, the maximum deflection increased by 163.3%. The simulation results of three-point bending indicate that employing a hybrid combination of PUR-PLA led to an increase of 382.3%, and for PUR–TPU by 111.8%; however, the highest value recorded with PUR/PLA, which has the slightest stress error among the tests. Also, it is reported that when the volume fraction of reinforced aluminum particles is increased, the overall deformation becomes more sufficient, and the test accuracy improves; for example, rising from 0.5% to 3%, the midspan deflection of composite (foam-Al) is increased by 40.34%. There were noticeable improvements in mechanical properties in the 2.5% composite foam-Al.
{"title":"Mechanical Properties of Sandwiched Construction with Composite and Hybrid Core Structure","authors":"Emad Kadum Njim, Hussam Raad Hasan, Muhsin J. Jweeg, Muhannad Al-Waily, Alaa Ali Hameed, Ahmed M. Youssef, Fahmi M. Elsayed","doi":"10.1155/2024/3803199","DOIUrl":"10.1155/2024/3803199","url":null,"abstract":"<p>In the field of lighter substitute materials, sandwich plate models of composite and hybrid foam cores are used in this study. Three core structures: composite core structure and then the core is replaced by a structure of a closed and open repeating cellular pattern manufactured with 3D printing technology. It finally integrated both into one hybrid open-cell core filled with foam and employed the same device (WBW-100E) to conduct the three-point bending experiment. The test was conducted based on the international standard (ASTM-C 393-00) to perform the three-point bending investigation on the sandwich structure. Flexural test finding, with the hybrid polyurethane/polytropic acid (PUR/PLA) core, the ultimate bending load is increased by 127.7% compared to the open-cell structure core. In addition, the maximum deflection increased by 163.3%. The simulation results of three-point bending indicate that employing a hybrid combination of PUR-PLA led to an increase of 382.3%, and for PUR–TPU by 111.8%; however, the highest value recorded with PUR/PLA, which has the slightest stress error among the tests. Also, it is reported that when the volume fraction of reinforced aluminum particles is increased, the overall deformation becomes more sufficient, and the test accuracy improves; for example, rising from 0.5% to 3%, the midspan deflection of composite (foam-Al) is increased by 40.34%. There were noticeable improvements in mechanical properties in the 2.5% composite foam-Al.</p>","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"2024 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1155/2024/3803199","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139500232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Infectious diseases caused by microorganisms have gained worldwide attention in recent years. According to data compiled by the World Health Organization, the number of deaths resulting from infectious diseases is on the rise. In light of these dangers, the study of antibacterial materials has become increasingly vital. In this research, an antibacterial polymer was developed using poly(vinyl chloride) (PVC) and 4,4-diamminodiphenylmethane (DDM). The produced polymer’s chemical structure and thermal properties were investigated using Fourier-transform infrared spectroscopy, nuclear magnetic resonance, and thermo-gravimetric analysis. The antibacterial activity of the resulting PVC-g-DDM polymer was effective in killing both Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli. The antimicrobial efficacy was tested using a spread plate method, demonstrating its potential utility in a variety of applications like biomedical, coatings, water purification systems, and others. Antimicrobial resistance is increasing, especially among bacteria that have acquired resistance to multiple therapeutics. To fully optimize and explore the polymer’s potential and its usage, more research is needed.
{"title":"Synthesis and Antibacterial Activity of Grafted Poly(Vinyl Chloride) Polymer against Gram-Positive and Gram-Negative Bacteria","authors":"Shrajan Kotian, Sonali Gupta, Yashoda Malgar Puttaiahgowda, Sanmit Shetty","doi":"10.1155/2024/9941516","DOIUrl":"10.1155/2024/9941516","url":null,"abstract":"<p>Infectious diseases caused by microorganisms have gained worldwide attention in recent years. According to data compiled by the World Health Organization, the number of deaths resulting from infectious diseases is on the rise. In light of these dangers, the study of antibacterial materials has become increasingly vital. In this research, an antibacterial polymer was developed using poly(vinyl chloride) (PVC) and 4,4-diamminodiphenylmethane (DDM). The produced polymer’s chemical structure and thermal properties were investigated using Fourier-transform infrared spectroscopy, nuclear magnetic resonance, and thermo-gravimetric analysis. The antibacterial activity of the resulting PVC-g-DDM polymer was effective in killing both Gram-positive <i>Staphylococcus aureus</i> and Gram-negative <i>Escherichia coli</i>. The antimicrobial efficacy was tested using a spread plate method, demonstrating its potential utility in a variety of applications like biomedical, coatings, water purification systems, and others. Antimicrobial resistance is increasing, especially among bacteria that have acquired resistance to multiple therapeutics. To fully optimize and explore the polymer’s potential and its usage, more research is needed.</p>","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"2024 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1155/2024/9941516","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139481282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Josette Vigil, Kailey Lewis, Nicholas Norris, Alp Karakoç, Timothy A. Becker
The present work investigates the influence of material phases and their volume fractions on the elastic behavior of triply periodic minimal surface (TPMS) scaffolds for the potential modeling of bone scaffolds. A graphical tool using TPMS functions, namely Schwarz-D (diamond), gyroid, and modified gyroid, was developed and used to design and additively manufacture 3D multiphase scaffold models. A PolyJet, UV-cured 3D-printer system was used to fabricate the various TPMS scaffold models using three polymer materials with high, medium, and low stiffness properties. All TPMS models had the same volume fractions of the three polymer materials. Final models were printed into cylinders with a diameter of 20 mm and a height of 8 mm for mechanical testing. The models were subjected to compressive and shear testing using a dynamic mechanical analysis rheometer. All samples were tested at physiologically relevant temperature (37°C) to provide detailed structural characterizations. Microscopic imaging of 3D-printed scaffold longitudinal and cross sections revealed that additive manufacturing adequately recreated the TPMS functions, which created anisotropic materials with variable structures in the longitudinal and transverse directions. Mechanical testing showed that all three TPMS 3D-printed scaffold types exhibited significantly different shear and compressive properties (verifying anisotropic properties) despite being constructed of the same volume fractions of the three UV-printed polymer materials. The gyroid and diamond scaffolds demonstrated complex moduli values that ranged from 1.2 to 1.8 times greater than the modified gyroid scaffolds in both shear and compression. Control scaffolds printed from 100% of each of the three polymers had statistically similar mechanical properties, verifying isotropic properties.
{"title":"Design, Fabrication, and Characterization of 3D-Printed Multiphase Scaffolds Based on Triply Periodic Minimal Surfaces","authors":"Josette Vigil, Kailey Lewis, Nicholas Norris, Alp Karakoç, Timothy A. Becker","doi":"10.1155/2024/4616496","DOIUrl":"10.1155/2024/4616496","url":null,"abstract":"<p>The present work investigates the influence of material phases and their volume fractions on the elastic behavior of triply periodic minimal surface (TPMS) scaffolds for the potential modeling of bone scaffolds. A graphical tool using TPMS functions, namely Schwarz-D (diamond), gyroid, and modified gyroid, was developed and used to design and additively manufacture 3D multiphase scaffold models. A PolyJet, UV-cured 3D-printer system was used to fabricate the various TPMS scaffold models using three polymer materials with high, medium, and low stiffness properties. All TPMS models had the same volume fractions of the three polymer materials. Final models were printed into cylinders with a diameter of 20 mm and a height of 8 mm for mechanical testing. The models were subjected to compressive and shear testing using a dynamic mechanical analysis rheometer. All samples were tested at physiologically relevant temperature (37°C) to provide detailed structural characterizations. Microscopic imaging of 3D-printed scaffold longitudinal and cross sections revealed that additive manufacturing adequately recreated the TPMS functions, which created anisotropic materials with variable structures in the longitudinal and transverse directions. Mechanical testing showed that all three TPMS 3D-printed scaffold types exhibited significantly different shear and compressive properties (verifying anisotropic properties) despite being constructed of the same volume fractions of the three UV-printed polymer materials. The gyroid and diamond scaffolds demonstrated complex moduli values that ranged from 1.2 to 1.8 times greater than the modified gyroid scaffolds in both shear and compression. Control scaffolds printed from 100% of each of the three polymers had statistically similar mechanical properties, verifying isotropic properties.</p>","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"2024 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2024-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1155/2024/4616496","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139094529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Viscosity is a prominent rheological property of polymer, which is affected by temperature, pressure, shear rate, molecular structure, and other factors. Despite the importance of the pressure effect, there remains a paucity of investigations on the dependence of pressure on viscosity compared with other factors, such as shear rate and temperature. Previous research has established that the correlation between pressure and viscosity is usually expressed by the pressure coefficient. In this paper, different measurement techniques and methods for the pressure coefficient of viscosity of polymer melts are reviewed and evaluated on the basis of published experimental data. The capillary rheometer with a pressurized exit chamber is widely employed because of its accuracy and simple use. Besides, the accuracy and relationship of pressure coefficients determined by different methods are discussed.
{"title":"Measurement Techniques and Methods for the Pressure Coefficient of Viscosity of Polymer Melts","authors":"Yang Liao, Yeyuan Hu, Yunxiang Tan, Kosuke Ikeda, Ryoji Okabe, Ruifen Wu, Ryota Ozaki, Qingyan Xu","doi":"10.1155/2023/2020247","DOIUrl":"https://doi.org/10.1155/2023/2020247","url":null,"abstract":"Viscosity is a prominent rheological property of polymer, which is affected by temperature, pressure, shear rate, molecular structure, and other factors. Despite the importance of the pressure effect, there remains a paucity of investigations on the dependence of pressure on viscosity compared with other factors, such as shear rate and temperature. Previous research has established that the correlation between pressure and viscosity is usually expressed by the pressure coefficient. In this paper, different measurement techniques and methods for the pressure coefficient of viscosity of polymer melts are reviewed and evaluated on the basis of published experimental data. The capillary rheometer with a pressurized exit chamber is widely employed because of its accuracy and simple use. Besides, the accuracy and relationship of pressure coefficients determined by different methods are discussed.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"26 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138717126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The influence of nonrelaxation on the Payne effect of carbon black-filled rubber is studied. The prestrain is introduced in the Kraus model in the form of exponential growth. Combined with studies of temperature correlations, an explicit model for predicting the Payne effect at different prestrains and temperatures is developed. Dynamic mechanical analyses are performed to determine model parameters and validate the proposed model. To further verify the proposed model, the heat buildup of rubber columns under dynamic tensile load is tested and simulated. The comparison between simulated and measured data shows that the simulation considering nonrelaxation is more accurate than without considering. With the increase of prestrain, the accuracy of considering nonrelaxation becomes more obvious.
{"title":"Characterization of Viscoelastic Properties Considering the Nonrelaxation for Filled Rubber","authors":"Xinyi Lin, Mengxi Huang, Yang Wang, Ziran Li","doi":"10.1155/2023/1604326","DOIUrl":"https://doi.org/10.1155/2023/1604326","url":null,"abstract":"The influence of nonrelaxation on the Payne effect of carbon black-filled rubber is studied. The prestrain is introduced in the Kraus model in the form of exponential growth. Combined with studies of temperature correlations, an explicit model for predicting the Payne effect at different prestrains and temperatures is developed. Dynamic mechanical analyses are performed to determine model parameters and validate the proposed model. To further verify the proposed model, the heat buildup of rubber columns under dynamic tensile load is tested and simulated. The comparison between simulated and measured data shows that the simulation considering nonrelaxation is more accurate than without considering. With the increase of prestrain, the accuracy of considering nonrelaxation becomes more obvious.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"80 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138690381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bambang Afrinaldi, Frita Yuliati, Hermawan Judawisastra, Lia A. T. W. Asri
Polymeric materials have been employed in a wide range of applications in both dry and wet environments. When these materials suffer damage, it becomes crucial to initiate repairs in order to mitigate further losses. The use of self-healing materials emerges as a promising strategy not only to address this issue but also possess the advantage of prolonging the product’s lifespan. Nevertheless, the development of self-healing materials tailored for wet environments presents a set of obstacles and complexities. The review examines the current state of research in the field and highlights the challenges associated with developing self-healing materials that can effectively repair damage in such environments. We discuss the self-healing mechanisms and various polymers that are extensively employed in the advancement of self-healing materials. We study the progress made in the research and development of self-healing materials specifically designed for wet environments. Furthermore, it provides a summary of various applications of self-healing materials in wet environments.
{"title":"Self-Healing Polymers Designed for Underwater Applications","authors":"Bambang Afrinaldi, Frita Yuliati, Hermawan Judawisastra, Lia A. T. W. Asri","doi":"10.1155/2023/6614326","DOIUrl":"https://doi.org/10.1155/2023/6614326","url":null,"abstract":"Polymeric materials have been employed in a wide range of applications in both dry and wet environments. When these materials suffer damage, it becomes crucial to initiate repairs in order to mitigate further losses. The use of self-healing materials emerges as a promising strategy not only to address this issue but also possess the advantage of prolonging the product’s lifespan. Nevertheless, the development of self-healing materials tailored for wet environments presents a set of obstacles and complexities. The review examines the current state of research in the field and highlights the challenges associated with developing self-healing materials that can effectively repair damage in such environments. We discuss the self-healing mechanisms and various polymers that are extensively employed in the advancement of self-healing materials. We study the progress made in the research and development of self-healing materials specifically designed for wet environments. Furthermore, it provides a summary of various applications of self-healing materials in wet environments.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"148 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138560515","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m2, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56.
{"title":"Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy","authors":"Yunsheng Chong, Liyan Wang, Xiangming Xu, Xiao Zhuang, Rongrong Zheng, Di Cao, Yanming Chen","doi":"10.1155/2023/3114639","DOIUrl":"https://doi.org/10.1155/2023/3114639","url":null,"abstract":"Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m<sup>2</sup>, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"23 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138541387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Polymer dissolution and precipitation are two common processes for the production of polymer powders, especially for cases where usual means of comminution are not applicable. I investigated six dissolution–precipitation processes based on high-boiling sustainable green organic solvents and antisolvents for the polypropylene and polyethylene terephthalate with respect to apparent particle morphology for a closed loop production scheme. Of the investigated processes two are considered antisolvent-induced precipitations whereas the other four can be considered temperature induced. The applied solvents included p-cymene, dibutoxymethane, ethylbenzoate, γ-valerolactone, ethanol, and hexanol. All processes yielded powders consisting of agglomerated primary particles at a powder dry substance of less than 25% by weight. The produced powders consist in all cases of agglomerates of smaller primary particles.
{"title":"Precipitation of Polypropylene and Polyethylene Terephthalate Powders Using Green Solvents via Temperature and Antisolvent-Induced Phase Separation","authors":"Benedikt Hanschmann","doi":"10.1155/2023/7651796","DOIUrl":"https://doi.org/10.1155/2023/7651796","url":null,"abstract":"Polymer dissolution and precipitation are two common processes for the production of polymer powders, especially for cases where usual means of comminution are not applicable. I investigated six dissolution–precipitation processes based on high-boiling sustainable green organic solvents and antisolvents for the polypropylene and polyethylene terephthalate with respect to apparent particle morphology for a closed loop production scheme. Of the investigated processes two are considered antisolvent-induced precipitations whereas the other four can be considered temperature induced. The applied solvents included p-cymene, dibutoxymethane, ethylbenzoate, <i>γ</i>-valerolactone, ethanol, and hexanol. All processes yielded powders consisting of agglomerated primary particles at a powder dry substance of less than 25% by weight. The produced powders consist in all cases of agglomerates of smaller primary particles.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"7 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138541388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Laise Maia Lopes, Mariana Agostini de Moraes, Marisa Masumi Beppu
Silk fibroin (SF) and sodium alginate (SA) are natural polymers with interesting properties to produce biomaterials. Blends of these polymers form a complex protein–polysaccharide system where phase separation can be observed. Therefore, the thermodynamic analysis of this system is important to understand the interaction between the polymers and predict the final state and composition of the phases found in these blends. This study explored blends with a different initial composition of SF, SA, and water at 25°C and neutral pH. The influence of the proportion between mannuronic and guluronic acids on SA composition was investigated. After phase separation, two phases were identified, and the equilibrium data were fitted on three different thermodynamic models: Flory–Huggins, non-random two-liquids, and universal quasichemical. Cohn equation was also used to investigate the potential of SA to precipitate the SF in solution. The results show that the proportion of mannuronic and guluronic acids on the SA can significantly influence on equilibrium data and on the SF/SA interaction parameter, hence, becoming a variability factor if this parameter is not under control in formulations.
{"title":"Influence of Guluronic and Mannuronic Groups in Sodium Alginate Blends with Silk Fibroin: Phase Equilibrium and Thermodynamic Modeling","authors":"Laise Maia Lopes, Mariana Agostini de Moraes, Marisa Masumi Beppu","doi":"10.1155/2023/4986453","DOIUrl":"https://doi.org/10.1155/2023/4986453","url":null,"abstract":"Silk fibroin (SF) and sodium alginate (SA) are natural polymers with interesting properties to produce biomaterials. Blends of these polymers form a complex protein–polysaccharide system where phase separation can be observed. Therefore, the thermodynamic analysis of this system is important to understand the interaction between the polymers and predict the final state and composition of the phases found in these blends. This study explored blends with a different initial composition of SF, SA, and water at 25°C and neutral pH. The influence of the proportion between mannuronic and guluronic acids on SA composition was investigated. After phase separation, two phases were identified, and the equilibrium data were fitted on three different thermodynamic models: Flory–Huggins, non-random two-liquids, and universal quasichemical. Cohn equation was also used to investigate the potential of SA to precipitate the SF in solution. The results show that the proportion of mannuronic and guluronic acids on the SA can significantly influence on equilibrium data and on the SF/SA interaction parameter, hence, becoming a variability factor if this parameter is not under control in formulations.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"57 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138541419","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bone defects have recently surfaced as an important topic to discuss in orthopedic clinics, and as a result, they have captured the attention of the biomedical community as well as the general public. Because of their unique characteristics, such as high water content, softness, flexibility, and biocompatibility, hydrogels are gaining more and more traction in the field of tissue regeneration research within the medical industry. Intelligent biomaterials, like hydrogels, are much better than their predecessors because they can respond to new stimuli on multiple levels, such as the physical, chemical, and biological. Because they are sensitive to different outside cues, like shape in three dimensions and conditions between solid and liquid phases, they show certain traits. This indicates that they have the capability of developing into a more efficient material in the future, which would make them better suited to facilitate the localized repair of bone lesions. This article takes a look at hydrogels that alter their shape in response to the environment they are in. Some of the topics covered in this article include the classification of these materials, the concepts that underlie their synthesis, and the current state of research in this potentially fruitful field. This research was conducted with the intention of finding novel ways to treat severe bone defects.
{"title":"Recent Progress in Stimuli-Responsive Hydrogels Application for Bone Regeneration","authors":"Hamza Abu Owida, Feras Alnaimat","doi":"10.1155/2023/2934169","DOIUrl":"https://doi.org/10.1155/2023/2934169","url":null,"abstract":"Bone defects have recently surfaced as an important topic to discuss in orthopedic clinics, and as a result, they have captured the attention of the biomedical community as well as the general public. Because of their unique characteristics, such as high water content, softness, flexibility, and biocompatibility, hydrogels are gaining more and more traction in the field of tissue regeneration research within the medical industry. Intelligent biomaterials, like hydrogels, are much better than their predecessors because they can respond to new stimuli on multiple levels, such as the physical, chemical, and biological. Because they are sensitive to different outside cues, like shape in three dimensions and conditions between solid and liquid phases, they show certain traits. This indicates that they have the capability of developing into a more efficient material in the future, which would make them better suited to facilitate the localized repair of bone lesions. This article takes a look at hydrogels that alter their shape in response to the environment they are in. Some of the topics covered in this article include the classification of these materials, the concepts that underlie their synthesis, and the current state of research in this potentially fruitful field. This research was conducted with the intention of finding novel ways to treat severe bone defects.","PeriodicalId":7372,"journal":{"name":"Advances in Polymer Technology","volume":"7 1","pages":""},"PeriodicalIF":3.1,"publicationDate":"2023-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138541371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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