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Time-resolved experiments on gas-phase atoms and molecules with XUV and X-ray free-electron lasers XUV和X射线自由电子激光器对气相原子和分子的时间分辨实验
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-10-13 DOI: 10.1080/23746149.2022.2132182
D. Rolles
ABSTRACT Over the last 20 years, XUV and X-ray free-electron lasers have enabled a wide variety of time-resolved experiments that have dramatically advanced our understanding of ultrafast molecular dynamics on atomic length scales and femtosecond time scales. This review focuses on experimental studies of ultrafast dynamics of atoms and molecules in the gas phase, tracing the development of the field from early proof-of-principle studies to recent pump-probe experiments that elucidate the coupled electronic and nuclear dynamics during photochemical reactions with a temporal resolution that is now extending into the attosecond domain. Graphical abstract
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引用次数: 6
Bulk strong matter: the trinity 散装强物质:三位一体
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-10-04 DOI: 10.1080/23746149.2022.2137433
X. Lai, C. Xia, Renxin Xu
Our world is wonderful because of the normal but negligibly small baryonic part (i.e., atoms) although unknown dark matter and dark energy dominate the Universe. A stable atomic nucleus could be simply termed as ``strong matter'' since its nature is dominated by the fundamental strong interaction. Is there any other form of strong matter? Although nuclei are composed of 2-flavoured (i.e., up and down flavours of valence quarks) nucleons, it is conjectured that bulk strong matter could be 3-flavoured (with additional strange quarks) if the baryon number exceeds the critical value, $A_{rm c}$, in which case quarks could be either free (so-called strange quark matter) or localized (in strangeons, coined by combining ``strange nucleon''). Bulk strong matter could be manifested in the form of compact stars, cosmic rays, and even dark matter. This trinity will be explained in this brief review, that may impact dramatically on today's physics, particularly in the era of multi-messenger astronomy after the discovery of gravitational wave.
尽管未知的暗物质和暗能量主宰着宇宙,但我们的世界之所以美好,是因为有正常但可忽略的小重子部分(即原子)。稳定的原子核可以简单地称为“强物质”,因为它的性质由基本的强相互作用决定。还有其他形式的强物质吗?尽管原子核是由2味(即价夸克的上下味)核子组成的,但如果重子数超过临界值$A_,在这种情况下,夸克可以是自由的(所谓的奇异夸克物质),也可以是定域的(在奇异子中,由“奇异核子”组合而成)。大体积强物质可以以致密恒星、宇宙射线甚至暗物质的形式表现出来。这三位一体将在这篇简短的综述中得到解释,这可能会对今天的物理学产生巨大影响,特别是在引力波发现后的多信使天文学时代。
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引用次数: 4
Charge carrier dynamics in 2D materials probed by ultrafast THzspectroscopy 超快太赫兹光谱探测二维材料中的载流子动力学
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-09-30 DOI: 10.1080/23746149.2022.2120416
E. Cinquanta, Eva A. A. Pogna, L. Gatto, S. Stagira, C. Vozzi
ABSTRACT In this review, we discuss the rich ultrafast response at terahertz (THz) frequencies of two-dimensional (2D) materials. Thanks to their unique optoelectronic properties and exceptional tunability, van der Waals organic and inorganic 2D materials, such as graphene, transition metal dichalcogenides (TMDs), and 2D perovskites, are emerging as promising platforms for the development of nano-electronic and nano-photonic devices in the THz range. The investigation of the ultrafast charge carriers dynamics resulting from their reduced dimensionality is crucial for guiding the engineering route towards novel nanotechnologies. Here, we first give a brief overview of the state-of-the-art experimental schemes for inspecting the ultrafast response of 2D materials in the THz range, including the generation and the detection of THz light and the prototypical optical pump THz probe setup. Then, we present and discuss the most relevant results, reviewing the THz ultrafast signatures of charge carriers and excitons dynamics in graphene, TMDs, and 2D perovskites. Finally, we provide a vision of the emerging tools for characterizing the ultrafast THz dynamics at the nanoscale. Graphical Abstract
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引用次数: 2
Strain engineering in alloy nanoparticles 合金纳米颗粒的应变工程
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-09-29 DOI: 10.1080/23746149.2022.2127330
D. Nelli, Cesare Roncaglia, C. Minnai
ABSTRACT The deformation of interatomic distances with respect to those of the perfect crystal generates atomic-level strain. In nanoalloys, strain can arise because of finite size, morphology, domain structure and lattice mismatch between their atomic compounds. Strain can strongly affect the functional properties of nanoalloys, as it alters their electronic energy levels. Moreover, atomic-level strain generates atomic-level stress, which in turn results in distortions induced by strain. When the stress accumulated in a nanoalloy exceeds a certain level, the particle can relax that stress by undergoing structural transitions such as shape and/or chemical ordering transitions. Atomic-level strain is then a powerful tool to control and manipulate the structural and functional properties of nanoalloys. This requires a combined theoretical and experimental approach both to deeply understand the physical origin of strain, and to characterize it with a sub-angstrom resolution. Here, we present a theoretical analysis of the main sources of strain in nanoalloys, we analyse how atomic-level strain can be experimentally measured with transmission electron microscopy, we discuss its effect on the functional properties of nanoalloys, finally we describe how atomic-level stress arises from atomic-level strain, and how stress can induce structural transformations at the nanoscale. Graphical abstract
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引用次数: 12
Ultrafast dynamics in molecular ions following UV and XUV excitation: a perspective UV和XUV激发下分子离子的超快动力学
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-09-12 DOI: 10.1080/23746149.2022.2123283
M. Hervé, A. Boyer, R. Brédy, I. Compagnon, F. Lépine
ABSTRACT Gas phase experiments combined with ultrafast technologies can provide information on the intrinsic properties of molecular systems at picosecond, femtosecond, or even attosecond timescales. However, these experiments are often limited to relatively simple model systems. In this context, electrospray ionization sources (ESI) have offered new perspectives as they allow to produce large or fragile molecular ions in the gas phase, mimicking molecules in their natural environment. While time-resolved UV-visible ultrafast experiments on molecular ions have been successfully developed over the past decades, efforts are still required to perform experiments using ultrashort extreme ultraviolet (XUV) pulses with the goal of reaching attosecond resolution. In this article, we present recent results obtained using the combination of ultrafast technologies and ESI sources. We show that ultrafast dynamics experiments can be performed on molecular ions without ion trapping devices and can reveal UV-induced charge transfer in small peptides with controlled micro-environment. Non-adiabatic relaxation dynamics in large (bio)molecular ions is also presented. Such experiments are compatible with high harmonic generation XUV sources as shown here in the case of a metal complex. These ultrafast dynamics studies on large molecular ions offer new perspectives in attosecond science. Graphical abstract
摘要气相实验与超快技术相结合,可以在皮秒、飞秒甚至阿秒时间尺度上提供分子系统固有特性的信息。然而,这些实验通常局限于相对简单的模型系统。在这种情况下,电喷雾电离源(ESI)提供了新的视角,因为它们可以在气相中产生大的或脆弱的分子离子,模仿自然环境中的分子。尽管在过去几十年中已经成功地开发了分子离子的时间分辨紫外-可见超快实验,但仍需要努力使用超短极紫外(XUV)脉冲进行实验,以达到阿秒分辨率。在这篇文章中,我们介绍了使用超快技术和ESI源相结合获得的最新结果。我们表明,在没有离子捕获装置的情况下,可以在分子离子上进行超快动力学实验,并且可以在受控的微环境下揭示小肽中紫外线诱导的电荷转移。还介绍了大分子(生物)离子中的非绝热弛豫动力学。这样的实验与高谐波产生XUV源兼容,如这里在金属络合物的情况下所示。这些对大分子离子的超快动力学研究为阿秒科学提供了新的视角。图形摘要
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引用次数: 0
Group III-V semiconductors as promising nonlinear integrated photonic platforms III-V族半导体作为有前途的非线性集成光子平台
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-07-27 DOI: 10.1080/23746149.2022.2097020
Kaustubh Vyas, D. Espinosa, Daniel Hutama, S. K. Jain, Rania Mahjoub, E. Mobini, Kashif M. Awan, J. Lundeen, K. Dolgaleva
ABSTRACT Group III–V semiconductors are based on the elements of groups III and V of the periodic table. The possibility to grow thin-films made of binary, ternary, and quaternary III–V alloys with different fractions of their constituent elements allows for the precise engineering of their optical properties. In addition, since many III–V compounds are direct-bandgap semiconductors, they are suitable for the development of photonic devices and integrated circuits, especially when monolithic integration is required. Moreover, the strong optical nonlinearities of III–V materials enable a fertile field of research in photonic devices for all-optical signal processing, wavelength conversion, and frequency generation. Experimentally accessing the plethora of nonlinear optical phenomena in these materials considerably facilitates the exploration of light-matter interactions. Several demonstrations have explored the optical nonlinearities in waveguides, microring resonators, photonic crystal structures, quantum dots, and lasers. In this review, we survey numerous nonlinear optical studies performed in III–V semiconductor waveguide platforms. In particular, we discuss linear and nonlinear optical properties, material growth and fabrication processes, newer hybrid material platforms, and several nonlinear optical applications of III–V semiconductor integrated optical platforms. Graphical abstract
III - V族半导体是基于元素周期表中III族和V族的元素。由二元、三元和四元III-V合金制成的薄膜,其组成元素的不同比例使得其光学特性的精确工程成为可能。此外,由于许多III-V化合物是直接带隙半导体,因此它们适用于光子器件和集成电路的开发,特别是当需要单片集成时。此外,III-V材料的强光学非线性为全光信号处理、波长转换和频率产生的光子器件的研究提供了肥沃的领域。通过实验获取这些材料中大量的非线性光学现象,极大地促进了光-物质相互作用的探索。一些演示已经探索了波导、微环谐振器、光子晶体结构、量子点和激光器中的光学非线性。在这篇综述中,我们调查了在III-V半导体波导平台上进行的许多非线性光学研究。我们特别讨论了线性和非线性光学特性,材料生长和制造工艺,新型混合材料平台,以及III-V半导体集成光学平台的几种非线性光学应用。图形抽象
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引用次数: 9
William Shakespeare’s advice on our journal 威廉·莎士比亚对我们日记的建议
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-07-26 DOI: 10.1080/23746149.2022.2099635
Richard E Palmer
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引用次数: 0
Topological data analysis and machine learning 拓扑数据分析和机器学习
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-06-30 DOI: 10.1080/23746149.2023.2202331
D. Leykam, D. Angelakis
ABSTRACT Topological data analysis refers to approaches for systematically and reliably computing abstract ‘shapes’ of complex data sets. There are various applications of topological data analysis in life and data sciences, with growing interest among physicists. We present a concise review of applications of topological data analysis to physics and machine learning problems in physics including the unsupervised detection of phase transitions. We finish with a preview of anticipated directions for future research. Graphical abstract
拓扑数据分析是指系统可靠地计算复杂数据集的抽象“形状”的方法。拓扑数据分析在生命科学和数据科学中有各种各样的应用,物理学家对此越来越感兴趣。我们简要回顾了拓扑数据分析在物理和物理中的机器学习问题中的应用,包括相变的无监督检测。最后,我们展望了未来研究的预期方向。图形抽象
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引用次数: 6
Advances in nonlinear spectroscopy using phase modulated light fields: prospective applications in perturbative and non-perturbative regimes 相位调制光场非线性光谱学研究进展:在微扰和非微扰领域的应用前景
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-06-22 DOI: 10.1080/23746149.2022.2090856
K. Karki, M. Ciappina
ABSTRACT Since its first implementation in 2006, in fluorescence detected Fourier transform excitation spectroscopy of rubidium atoms, phase modulation is being increasingly used in nonlinear spectroscopy. Some of the important features of the technique are the excitation spectroscopy using signals that are relevant to photoactive devices (fluorescence and photocurrent), prospect of nonlinear spectroscopy of isolated systems such as single quantum dots or molecules, multidimensional spectroscopy, investigation of higher order recombination processes in semiconductors, etc. Although most of applications of phase modulated light fields have been on nonlinear spectroscopy in the perturbative regime, few efforts have been made recently to use it in the nonperturbative regime. In this review, we discuss the development of the technique since its inception, recent advances and future applications in strong field laser–matter interactions. GRAPHICAL ABSTRACT
自2006年首次实现以来,在荧光检测铷原子的傅里叶变换激发光谱中,相位调制越来越多地用于非线性光谱。该技术的一些重要特点是使用与光活性器件(荧光和光电流)相关的信号的激发光谱,孤立系统(如单量子点或分子)的非线性光谱的前景,多维光谱,半导体中高阶复合过程的研究等。虽然相位调制光场的大部分应用都是在微扰条件下的非线性光谱学上,但在非微扰条件下的应用却很少。在本文中,我们讨论了该技术的发展,自成立以来,最近的进展和未来的应用在强场激光物质相互作用。图形抽象
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引用次数: 6
Optical tweezers for a bottom-up assembly of few-atom systems 用于自底向上组装少原子系统的光镊子
IF 6 2区 物理与天体物理 Q1 Physics and Astronomy Pub Date : 2022-05-19 DOI: 10.1080/23746149.2022.2064231
M. Andersen
ABSTRACT Tightly focused laser beams form optical tweezers that can hold and manipulate individual atoms. They give superb control over microscopic quantum systems and have paved the way for bottom up assembly of few-atom systems. Such assembled systems provide an ideal starting point for many fundamental studies of atomic interactions and few-atom phenomena. Here we review the present stage of these fields, as well as some of the basic experimental techniques required for these experiments Figure from [74]. GRAPHICAL ABSTRACT
紧密聚焦的激光束形成光学镊子,可以夹住和操纵单个原子。它们对微观量子系统提供了极好的控制,并为少数原子系统的自下而上组装铺平了道路。这样的组装系统为原子相互作用和少原子现象的许多基础研究提供了理想的起点。在这里,我们回顾了这些领域的当前阶段,以及这些实验所需的一些基本实验技术图[74]。图形摘要
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引用次数: 3
期刊
Advances in Physics: X
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