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Optoelectronic Properties of F-co-doped PTO Thin Films Deposited by Spray Pyrolysis 喷雾热解法沉积f共掺杂PTO薄膜的光电性能
Pub Date : 2013-08-01 DOI: 10.5923/J.MATERIALS.20130304.05
Benjamin Odari, Robinson Musembi, M. Mageto, H. Othieno, F. Gaitho, M. Mghendi, Valentine Muramba
F-co-doped Palladiu m Tin Oxide (PTO) thin films were pyrolytically deposited on glass substrate at 450 0 C using an alcoholic precursor solution consisting of Tin (IV) Chloride (SnCl4.5H2O), Palladiu m Ch loride (Pd Cl2) and Ammoniu m Fluoride (NH4F). A resistivity of 0.3-6.9×10 -2 Ωcm was obtained in F-co-doped PTO films prepared with a Pd content of 3.68at% and F content of 0 - 23.96at% under optimized conditions. The optical properties were studied in the UV/ VIS/ NIR region. The optical bandgap of the films laid in the range 3.945 - 4.014 eV. Using dispersion analysis with Drude and Kim terms, optical constants were determined fro m spectro-photometric measurements for films on glass.
采用由氯化锡(SnCl4.5H2O)、氯化钯(Pd Cl2)和氟化氨(NH4F)组成的酒精前驱体溶液,在450℃下在玻璃衬底上热解制备了f共掺杂氧化钯(PTO)薄膜。在优化条件下,Pd含量为3.68at%, F含量为0 ~ 23.96at%,共掺F的PTO薄膜的电阻率为0.3-6.9×10 -2 Ωcm。在紫外/可见/近红外光谱下研究了其光学性质。薄膜的光学带隙分布在3.945 ~ 4.014 eV之间。利用Drude项和Kim项的色散分析,测定了玻璃薄膜的光学常数。
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引用次数: 7
Material Processing Technology for Soft Ferrites Manufacturing 软铁氧体制造的材料加工技术
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.01
D. Bhalla, D. Singh, Swati Singh, D. Seth
In this paper efforts have been made to explain the manufacturing method of Manganese-Zinc (Mn-Zn) soft ferrites in detail along with its uses and applications. The same method is applicable to Nickel-Zinc (Ni-Zn) and Lithium Titanium (Li-Ti or Microwave) ferrites also. A process flow chart is shown. The manufacturing steps like-mixing of powders, calcination of powder, grinding of powder, granules making, pressing of components, sintering in tunnel kiln or box furnace and machining on rotary table grinding machine, have been explained. Effect of atmosphere (oxygen), when the components are sintered at high temperature, is discussed. The temperature profiles of muffle furnace and tunnel kilns have also been discussed. The variation in temperature within the muffle furnace (900×900×800 mm) has been studied with the help of a sliding thermocouple. Temperature gradient within the furnace volume has been plotted on graph. A mathematical relation has been found using curve fitting equation. Actual and mathematical results have been compared.
本文详细介绍了锰锌软铁氧体的制备方法及其用途和应用。同样的方法也适用于镍锌(Ni-Zn)和锂钛(Li-Ti或微波)铁氧体。显示了工艺流程图。介绍了粉料混合、粉料煅烧、粉料研磨、制粒、组分压制、隧道窑或箱式炉烧结、转台磨床加工等生产步骤。讨论了高温烧结时气氛(氧)的影响。讨论了马弗炉和隧道窑的温度分布。在滑动热电偶的帮助下,研究了马弗炉(900×900×800 mm)内的温度变化。炉体内的温度梯度已绘制在图形上。利用曲线拟合方程找到了一种数学关系。对实际结果和数学结果进行了比较。
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引用次数: 19
Characteristics Study of Silicon Nanoparticles Produced by Physical Vapour Deposition 物理气相沉积制备纳米硅的特性研究
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.07
Wafaa M. S. Al-Khayat, G. Wilde
SiliconNanoparticles with thickness ranging between 40 to 50 nm and an average diameter of 80 nm were prepared by Physical Vapour Deposition (electron beam). The Nanoparticles showed blue and visible light emission from 300 A o to 900 A o , with peak intensity at 350-700 A o .Also AFM measurements were carried out and the regularity of silicon Nanoparticles was calculated and found to be equal to 0.3858 according to a quantitative hexagonal regularity calculation.
采用物理气相沉积(电子束)法制备了厚度为40 ~ 50 nm、平均直径为80 nm的硅纳米颗粒。纳米硅在300 ~ 900 μ A范围内发射蓝光和可见光,峰值强度在350 ~ 700 μ A之间。原子力显微镜(AFM)对纳米硅进行了测量,并根据定量六边形正则性计算计算出其正则性为0.3858。
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引用次数: 0
Design and Simulation of MEMS Based Piezoelectric Shear Actuated Beam 基于MEMS的压电剪切驱动梁的设计与仿真
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.04
K. S. Rao, G. Srinivas, M. Prasad, Y. Srinivas, B. Shudheer, A. Rao
Now-a-days, there has been growing demand for the development of micro scale devices, due to its less cost, space requirements, high dimensional stability and especially manufacturing time. This paper reports the modeling of MEMS based Piezoelectric shear actuated beam by using COMSOL Multiphysics software of version 4.2a.The dimensions of the model beam is of 100-mm long, 30-mm width, 10-mm thickness. In this paper, we analysed the deflection of beam under different voltages. In the first step, deflection of beam is analysed by changing the material of sandwiched beam. In the second step deflection of beam is explored by changing material of electrodes. In the third step, deflection of beam is analysed by changing both materials of sandwiched beam and electrodes. In the final step defection of beam is explored by changing both thickness and material of electrodes. Finally, the results of analysis allowed to conclude us to design a piezo electric shear actuated beam with different ranges and resolutions, under the condition of changing both thickness and material of electrodes gives the optimum deflection of 216nm under 30v excited input voltage.
如今,由于其成本低,空间要求高,尺寸稳定性高,特别是制造时间短,对微型器件的开发需求日益增长。本文利用COMSOL 4.2a版本的Multiphysics软件对基于MEMS的压电剪切驱动梁进行建模。模型梁的尺寸为长100mm,宽30mm,厚10mm。本文分析了在不同电压下梁的挠度。首先,通过改变夹梁的材料,分析了夹梁的挠度。第二步,通过改变电极材料来研究梁的挠度。第三步,通过改变夹梁材料和电极,分析了夹梁的挠度。最后,通过改变电极的厚度和材料来研究梁的缺陷。最后,分析结果表明,在改变电极厚度和材料的条件下,我们设计了不同范围和分辨率的压电剪切驱动梁,在30v的激励输入电压下,得到了216nm的最佳挠度。
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引用次数: 6
Thermodynamic Research of Solubility of Irradiate Cross-linked Copolymers in Mix Butadiene Nitrile with Polyvinylchloride 辐照交联共聚物在丁腈-聚氯乙烯混合物中溶解度的热力学研究
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.03
S. Mammadov, S. A. Rzayeva, A. Garibov, E. Akperov, J. Mammadov
As shown, Energy effect have definition role for solubility of irradiate copolymer in mix butadiene nitrile rubber with polyvinylchloride, entropic effect remaining negative in initial polymer do not promote to solubility process. The experiments showed that increasing of radiation dosage during cross linking reduces characteristic viscosity of solutions and influence to change other physical-chemical properties of cross- linked copolymers.
结果表明,能量效应对辐照共聚物在丁腈橡胶-聚氯乙烯混合体系中的溶解度起决定性作用,初始聚合物中的熵效应为负,对其溶解度无促进作用。实验表明,交联过程中辐射剂量的增加会降低溶液的特性粘度,并影响交联共聚物的其他理化性质的变化。
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引用次数: 3
Observation of Conductivity Type Change in Swift Heavy Ion Irradiated Metal/Semiconductor Devices 快速重离子辐照金属/半导体器件电导率类型变化的观察
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.08
S. P. Pandey
Metal/Semiconductor (n-type & p-type) devices were irradiated with Au(7+) and Si(8+) ions of energy ~100MeV with different fluencies (10 10 - 10 13 ions/cm 2 ). Electronic properties have been studied from I-V and C-V characteristics of the devices before and after the irradiation. Hydrogenation of the irradiated devices has also been performed to investigate the hydrogen passivation effect of the irradiation induced defects. The devices were annealed upto 400°C and Infrared spectroscopic studies have been carried out at each annealing temperatures to study the nature of irradiation induced defects. The result has been discussed in the realm of radiation hardness and the conductivity type change of the irradiated electronic devices.
用能量~100MeV的Au(7+)和Si(8+)离子(10 10 ~10 13离子/ cm2)辐照金属/半导体(n型和p型)器件。从辐照前后器件的I-V和C-V特性研究了器件的电子特性。对辐照后的器件进行了氢化处理,以研究辐照诱导缺陷的氢钝化效应。将器件退火至400°C,并在每个退火温度下进行红外光谱研究,以研究辐照诱导缺陷的性质。本文从辐照后电子器件的辐射硬度和电导率类型变化的角度对结果进行了讨论。
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引用次数: 1
New Concepts for Improved Durability of MOM Total Hip Endoprostheses. A Review 改良MOM全髋关节内假体耐久性的新概念。回顾
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.05
L. Căpitanu, V. Florescu
Analyzing some hip prostheses retrieved by revision, the appearance of some forms of polishing of the femoral head were observed, as well as significant plastic deformations followed by local hardening. At the same time, obvious traces of wearing through fretting of the acetabular cup of UHMWPE, which in some studies are confounded or assimilated with the adhesive wear. Starting with the well-known fact that the rolling movement always has a lower friction compared to sliding friction, the authors have conceived and realized a pivoting movement joint on a "layer of balls" with "compensation space", placed between the acetabular cup and the femoral head. This technical MOM solution allows free self-directed migration of the balls, depending on the resistance opposed, with successive occupation of the "compensation space". As a concept, the proposed technical solution excludes the existence of a cage for maintaining the spheres relative positions.
分析一些翻修后取出的髋关节假体,观察到股骨头出现某些形式的抛光,以及明显的塑性变形,随后出现局部硬化。同时,超高分子量聚乙烯髋臼杯有明显的微动磨损痕迹,一些研究将其与黏着磨损混淆或同化。众所周知,与滑动摩擦相比,滚动运动总是具有更低的摩擦,从这一事实出发,作者构想并实现了一种旋转运动关节,该关节位于髋臼杯和股骨头之间,具有“补偿空间”的“球层”上。这种技术MOM解决方案允许球的自由自我定向移动,这取决于反对的阻力,并连续占用“补偿空间”。作为一个概念,提议的技术解决方案不包括用于保持球体相对位置的笼子的存在。
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引用次数: 9
Features of the Solid Solution (Mo 0.9 ,Cr 0.1 )Si 2 Formation Depending on the State of Initial Mixture 初始混合状态下固溶体(Mo 0.9,Cr 0.1) si2形成的特征
Pub Date : 2013-01-07 DOI: 10.5923/J.MATERIALS.20120206.06
I. Kud’, L. Ieremenko, L. S. Likhoded, I. Uvarova, D. P. Zyatkevich
The regularities of solid state synthesis of the solid solution (Mo0.9 ,Cr0.1)Si2 in vacuum have been investigated in the temperature range 400-1200℃ depending on the dispersity and energetic state of the init ial powders, namely mo lybdenum, chro miu m and silicon. The energetic state of the in itial mixture was established to be a determin ing factor which affects the principal features of solid state interaction whereas an increase in dispersity only influences the temperature of the interaction start. When non-activated initial mixtures and ones mechanically activated in a p lanetary mill with lo w number of dru m revolutions were used, the solid solution formation proceeded owing to diffusion of silicon into metals through successive formation of lo wer and higher molybdenum-based silicide phases followed by their interaction. Mechanical activation in a planetary mill with high number of dru m revolutions was accompanied by not only decrease in particle size but also changes in the energetic state of the reaction mixture, which resulted in changing the regularities of the solid solution formation. Herein solid solutions on the basis of two higher molybdenum silicide phases, tetra- and hexagonal mod ifications, were formed with further poly morphic transition of the unstable high temperature hexagonal β-MoSi2 phase into the lo w temperature tetragonal α-MoSi2 phase. It has been established that temperature of the beginning of interaction decreases by 100℃ as compared with non-activated initial mixtures and temperature of the end of the process depends on the amount of accu mu lated energy: under low energy mechanical activation the process is co mplete at 1200℃, while a h igh energy activation decreases this temperature by 200-400℃ depending on the duration of activation.
在400 ~ 1200℃的真空条件下,研究了(Mo0.9,Cr0.1)Si2固溶体的固态合成规律,这取决于初始粉末(钼、钼、铬、硅)的分散性和能态。初始混合物的能态是影响固态相互作用主要特征的决定因素,而分散度的增加只影响相互作用开始时的温度。当使用非活化的初始混合物和在行星磨机中机械活化的初始混合物时,通过低转速和高转速的钼基硅化物相的连续形成以及它们之间的相互作用,硅扩散到金属中,从而形成固溶体。在高转数的行星磨机中,机械活化不仅伴随着颗粒尺寸的减小,而且伴随着反应混合物能态的变化,从而改变了固溶体形成的规律。在高温不稳定的六方型β-MoSi2相向低温四方型α-MoSi2相进一步多晶化转变的基础上,形成了四方型和六方型两种较高硅化钼相的固溶体。结果表明,与未活化的初始混合物相比,作用开始时的温度降低了100℃,过程结束时的温度取决于累积能量的多少:在低能机械活化下,该过程在1200℃时完成,而高能活化则根据活化时间的长短使该温度降低了200-400℃。
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引用次数: 3
Study of the WSe2 Layered Compound Semi Conductors Useful for Photoeletrochemical Solar Cells 光化学太阳能电池用WSe2层状复合半导体材料的研究
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1007
P. R. Patel, V. Pathak
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引用次数: 1
LOW-PRESSURE AIR PLASMA INFLUENCE ON COTTON TEXTILE SURFACE MORPHOLOGY AND evaporated COPPER COATING ADHESION 低压空气等离子体对棉织物表面形貌及蒸发铜涂层附着力的影响
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1001
S. Vihodceva, S. Kukle
The present study evaluates the influence of low-pressure air plasma before vacuum evaporation process on the cotton textile surface morphology, as well as evaporated copper coating adhesion. During the experiment, commercial cotton textile was functionalized with vacuum evaporation technique with or without low– pressure air plasma pre-treatment. Surface analysis of the cotton textile treated with low-pressure air plasma and evaporated copper was carried out using Scanning electron microscope. As shown in the experimental results, modification of cotton textile surface by applying low-pressure air plasma noticeably deteriorates adhesion of the evaporated copper coating to the cotton textile substrate. These can be explained as morphological changes of the cotton textile surface resulting from its modification with low-pressure air plasma. Scanning electron microscope micrographs reveal that low-pressure air plasma changes cotton textile surface morphology, i.e. the original cotton fibre surface generally becomes smoother, whereas some fibres become completely even.
研究了真空蒸发前低压空气等离子体对棉织物表面形貌及蒸发后铜涂层附着力的影响。在实验中,采用真空蒸发技术对商品棉织物进行了功能化处理,并对有无低压空气等离子体预处理进行了研究。用扫描电镜对低压空气等离子体和蒸发铜处理后的棉织物进行了表面分析。实验结果表明,使用低压空气等离子体对棉织物表面进行改性,明显降低了蒸发铜涂层对棉织物基材的附着力。这可以解释为低压空气等离子体对棉织物表面的改性引起了棉织物表面的形态变化。扫描电镜显微照片显示,低压空气等离子体改变了棉织物表面形态,即原棉纤维表面普遍变得光滑,而有些纤维则变得完全均匀。
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引用次数: 7
期刊
American Journal of Materials Science
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