首页 > 最新文献

American Journal of Materials Science最新文献

英文 中文
P3HT:PCBM/TiOx Interface Modification through Annealing for Improvement in Organic Solar Cell Performance P3HT:PCBM/TiOx界面退火改性提高有机太阳能电池性能
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1010-1
Sanjay S. Ghosh, Ganesh S. Lonakar, Mrunal S. Mahajan, S. Jadkar, J. Sali
We describe the study of annealing after coating a TiOx film over P3HT:PCBM bulk heterojunction layer to improve the interface in order to improve the solar cell performance. We demonstrate that annealing after coating the TiOx interfacial film improves the interface between the bulk-heterojunction and TiOx layers and hence the device performance. However upon annealing the devices before coating the TiOx layer results in highly degraded performance. A systematic explanation of the improved device performance is
本文研究了在P3HT:PCBM本体异质结层上涂覆TiOx薄膜后的退火工艺,以改善其界面,从而提高太阳能电池的性能。我们证明了涂覆TiOx界面膜后的退火改善了本体异质结和TiOx层之间的界面,从而提高了器件性能。然而,在涂层TiOx层之前对器件进行退火会导致性能严重下降。对器件性能改进的系统解释如下
{"title":"P3HT:PCBM/TiOx Interface Modification through Annealing for Improvement in Organic Solar Cell Performance","authors":"Sanjay S. Ghosh, Ganesh S. Lonakar, Mrunal S. Mahajan, S. Jadkar, J. Sali","doi":"10.7726/AJMST.2013.1010-1","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1010-1","url":null,"abstract":"We describe the study of annealing after coating a TiOx film over P3HT:PCBM bulk heterojunction layer to improve the interface in order to improve the solar cell performance. We demonstrate that annealing after coating the TiOx interfacial film improves the interface between the bulk-heterojunction and TiOx layers and hence the device performance. However upon annealing the devices before coating the TiOx layer results in highly degraded performance. A systematic explanation of the improved device performance is","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91351932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, Magnetic and Electronic Properties of ErN in Three Structural Phases: First Principal Calculations 三个结构相中ErN的结构、磁性和电子性质:第一主要计算
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1005
S. Dergal, A. Merad, B. N. Brahmi
Structural, magnetic and electronic properties of the Erbium nitride (ErN) compound were studied by first-principles FP-LAPW calculations within SIC-PBE-sol+ U (the generalized gradient approximation GGA of PBE developed for solids with the self-interaction corrected (SIC) and addition of Hubbard U corrections). Three possible potential structures were considered: known phases, NaCl and CsCl, and an unknown phase, ZnS. Our results show that ErN is a ferromagnet (FM) in all studied phases. Our calculations of electronic properties showed for both NaCl and CsCl phases a metal behavior for spin up and spin down, and for ZnS phase, a semiconductor (metal) behavior for spin up (spin down) (2.1eV) respectively. To our knowledge, there is no data for comparison in ZnS structure; therefore we consider our results as predictions.
通过第一性原理FP-LAPW计算,研究了氮化铒(ErN)化合物在SIC-PBE-sol+ U (PBE的广义梯度近似GGA,用于自相互作用校正(SIC)和加入Hubbard U校正的固体)中的结构、磁性和电子性质。考虑了三种可能的电位结构:已知相NaCl和CsCl,以及未知相ZnS。结果表明,ErN在所有相中均为铁磁体(FM)。我们的电子性质计算表明,NaCl和CsCl相的自旋向上和自旋向下为金属行为,ZnS相的自旋向上(自旋向下)为半导体(金属)行为(2.1eV)。据我们所知,在ZnS结构中没有可以比较的数据;因此,我们认为我们的结果是预测。
{"title":"Structural, Magnetic and Electronic Properties of ErN in Three Structural Phases: First Principal Calculations","authors":"S. Dergal, A. Merad, B. N. Brahmi","doi":"10.7726/AJMST.2013.1005","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1005","url":null,"abstract":"Structural, magnetic and electronic properties of the Erbium nitride (ErN) compound were studied by first-principles FP-LAPW calculations within SIC-PBE-sol+ U (the generalized gradient approximation GGA of PBE developed for solids with the self-interaction corrected (SIC) and addition of Hubbard U corrections). Three possible potential structures were considered: known phases, NaCl and CsCl, and an unknown phase, ZnS. Our results show that ErN is a ferromagnet (FM) in all studied phases. Our calculations of electronic properties showed for both NaCl and CsCl phases a metal behavior for spin up and spin down, and for ZnS phase, a semiconductor (metal) behavior for spin up (spin down) (2.1eV) respectively. To our knowledge, there is no data for comparison in ZnS structure; therefore we consider our results as predictions.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82685229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Hole Dangling Bond Capture Cross-Sections in a-Si:H a-Si:H的孔悬空键捕获截面
Pub Date : 2013-01-01 DOI: 10.5923/J.MATERIALS.20130304.02
D. Goldie
It is demonstrated that the occupation statistics for a Gaussian distribution of dangling bond states may account for the measured variation of hole mob ility-lifetime values in hydrogenated amorphous silicon as the Fermi energy is systematically varied by doping fro m about 0.55 eV to 1.05 eV belo w the conduction band edge. An assessment of how the deduced dangling bond parameters may be influenced by underlying doping effects suggests that the min imu m cross-section ratio for hole capture into charged (σh - ) and neutral (σh 0 ) dangling bond states requires that σh - /σh 0 ≥ 5. The capture of holes is consequently dominated by charged dangling bonds provided the Fermi energy lies within the upper half of the band-gap. Both σh - and σh 0 are observed to depend upon temperature (T) as σh ∝ T -β wh ich may indicate the presence of tunnelling
结果表明,悬空键态高斯分布的占位统计量可以解释在氢化非晶硅中,当费米能在导带边缘下从0.55 eV到1.05 eV之间系统地变化时,空穴能谱寿命值的测量变化。分析了掺杂对悬空键参数的影响,发现空穴捕获到带电(σh -)和中性(σh 0)悬空键态的最小横截面比要求σh - /σh 0≥5。因此,如果费米能量位于带隙的上半部分,则空穴的捕获由带电的悬空键主导。σh -和σh 0随温度(T)的变化而变化,σh∝T -β,这可能表明存在隧道效应
{"title":"Hole Dangling Bond Capture Cross-Sections in a-Si:H","authors":"D. Goldie","doi":"10.5923/J.MATERIALS.20130304.02","DOIUrl":"https://doi.org/10.5923/J.MATERIALS.20130304.02","url":null,"abstract":"It is demonstrated that the occupation statistics for a Gaussian distribution of dangling bond states may account for the measured variation of hole mob ility-lifetime values in hydrogenated amorphous silicon as the Fermi energy is systematically varied by doping fro m about 0.55 eV to 1.05 eV belo w the conduction band edge. An assessment of how the deduced dangling bond parameters may be influenced by underlying doping effects suggests that the min imu m cross-section ratio for hole capture into charged (σh - ) and neutral (σh 0 ) dangling bond states requires that σh - /σh 0 ≥ 5. The capture of holes is consequently dominated by charged dangling bonds provided the Fermi energy lies within the upper half of the band-gap. Both σh - and σh 0 are observed to depend upon temperature (T) as σh ∝ T -β wh ich may indicate the presence of tunnelling","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84642560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Use of Nonionic Tween-80 Surfactant Mobile Phase in Thin Layer Chromatography of Heavy Metal Cations 非离子型吐温-80表面活性剂流动相在重金属阳离子薄层色谱中的应用
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1002
Sarang S. Dhote, L. Deshmukh, L. Paliwal
The analytical potential of Tween-80, a nonionic surfactant used as a mobile phase in the thin layer chromatographic separation of heavy metal cations, is assessed. The surfactant concentrations, acidity and basicity of Tween-80solutions are investigated for the migration behavior of heavy metal cations on aminoplast+ cellulose mixture thin layer. The influence of weak or strong electrolyte and alkanol additives in the surfactant-containing mobile phase on the mobility of heavy metal cations on the aminoplast+ cellulose mixture thin layer is examined.
本文评价了作为流动相的非离子表面活性剂Tween-80在重金属阳离子薄层色谱分离中的分析潜力。研究了tween -80溶液中表面活性剂的浓度、酸度和碱度对重金属阳离子在氨质体+纤维素混合物薄层上的迁移行为。考察了含表面活性剂流动相中强弱电解质和醇类添加剂对氨基质体+纤维素混合物薄层重金属阳离子迁移率的影响。
{"title":"Use of Nonionic Tween-80 Surfactant Mobile Phase in Thin Layer Chromatography of Heavy Metal Cations","authors":"Sarang S. Dhote, L. Deshmukh, L. Paliwal","doi":"10.7726/AJMST.2013.1002","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1002","url":null,"abstract":"The analytical potential of Tween-80, a nonionic surfactant used as a mobile phase in the thin layer chromatographic separation of heavy metal cations, is assessed. The surfactant concentrations, acidity and basicity of Tween-80solutions are investigated for the migration behavior of heavy metal cations on aminoplast+ cellulose mixture thin layer. The influence of weak or strong electrolyte and alkanol additives in the surfactant-containing mobile phase on the mobility of heavy metal cations on the aminoplast+ cellulose mixture thin layer is examined.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78229999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Synthesis and Characterization of Magnesium Perchlorate Doped Polyaniline- PVC Films 高氯酸镁掺杂聚苯胺-聚氯乙烯薄膜的合成与表征
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1006
G. Rani, H. Kumar, Renu Rani
Spectroscopic characterization explores the possibility of potential applications of organic conducting polymers in electronic device fabrication. In this work FTIR and SEM (Scanning Electron Microscopy) techniques are used for characterization of the prepared conducting polyaniline PVC films by changing the concentration of dopant. FTIR study indicates the presence of injected charge species that may lead the possibility of existence of both singlet and triplet excitation states. These types of measurements of [Mg (ClO4)2] doped Polyaniline system will be helpful for preparing polyaniline-PVC blend/conducting polymeric materials.
光谱表征探索了有机导电聚合物在电子器件制造中的潜在应用的可能性。本文采用FTIR和SEM(扫描电子显微镜)技术,通过改变掺杂剂的浓度,对制备的导电聚苯胺PVC薄膜进行了表征。FTIR研究表明,注入电荷的存在可能导致单线态和三重态激发态的存在。这些对[Mg (ClO4)2]掺杂聚苯胺体系的测定将有助于制备聚苯胺- pvc共混/导电高分子材料。
{"title":"Synthesis and Characterization of Magnesium Perchlorate Doped Polyaniline- PVC Films","authors":"G. Rani, H. Kumar, Renu Rani","doi":"10.7726/AJMST.2013.1006","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1006","url":null,"abstract":"Spectroscopic characterization explores the possibility of potential applications of organic conducting polymers in electronic device fabrication. In this work FTIR and SEM (Scanning Electron Microscopy) techniques are used for characterization of the prepared conducting polyaniline PVC films by changing the concentration of dopant. FTIR study indicates the presence of injected charge species that may lead the possibility of existence of both singlet and triplet excitation states. These types of measurements of [Mg (ClO4)2] doped Polyaniline system will be helpful for preparing polyaniline-PVC blend/conducting polymeric materials.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88024885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Morphology and Optical Properties of Template Synthesized Copper-Telluride Nanowires 模板合成碲化铜纳米线的形貌和光学性质
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1009
Suresh Kumar, V. Singh, A. Vohra, S. Chakarvarti
Copper tellurides (CuxTe) are important class of materials suitable for use as active components in CdTe based solar cells. Among all these wide band gap materials, copper telluride is a very important material for wide range of applications. Copper tellurides (CuxTe) have different crystal structures depending upon the value of x (1
碲化铜(CuxTe)是一类重要的材料,适合用作CdTe基太阳能电池的活性成分。在这些宽禁带材料中,碲化铜是一种具有广泛应用前景的重要材料。碲化铜(CuxTe)的晶体结构随x (1
{"title":"Morphology and Optical Properties of Template Synthesized Copper-Telluride Nanowires","authors":"Suresh Kumar, V. Singh, A. Vohra, S. Chakarvarti","doi":"10.7726/AJMST.2013.1009","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1009","url":null,"abstract":"Copper tellurides (CuxTe) are important class of materials suitable for use as active components in CdTe based solar cells. Among all these wide band gap materials, copper telluride is a very important material for wide range of applications. Copper tellurides (CuxTe) have different crystal structures depending upon the value of x (1<x<2) and are usually p-type compound semiconductors. Copper tellurides (CuxTe) are widely used as back-contact materials to CdS/CdTe photovoltaic devices for higher efficiency and stability of the device.Cu2Te/n-CdTe hetero-junction solar cells have been reported with an efficiency reaching 7.5%. We report here the morphological and optical properties of template synthesized copper-telluride nanowires. The copper tellurides (CuxTe) nanowires were synthesized on copper and ITO-coated glass (with ITO thickness of 1500A and resistivity of 15-20 Ohm-cm) substrates via template-assisted (polycarbonate tracketch membrane) electrodeposition technique at room temperature (303K). The morphologies of copper telluride nanowires were studied by scanning electron microscopy which reveals the uniform growth of standing nanowires of identical diameter equal to the diameter of the template used. The electrodeposited nanowires are found to be highly ordered, vertically aligned and of high aspect ratio. To investigate the optical properties of as-synthesized copper telluride nanowires, we performed UV-Vis measurements at room temperature (303K). It is found from the absorption spectra that the optical absorption edge moves to shorter wavelength region with decrease in diameter. The band gap energy is found to be 2.78, 3.10 and 3.37eV for 200, 100 and 50nm copper telluride nanowires, respectively. The change in the band gap with diameter shows the “blue shift” in copper telluride nanowires which can be attributed to the quantum size effect in nanowires. We found broad PL emission spectra of 200, 100 and 50nm copper telluride nanowires and photoluminescence emission peak at around 456nm in the blue region (450-475nm) with excitation wavelength of 220nm were observed. The other emission peak at around 555nm is also observed in all copper telluride nanowires respectively which attributed to the green emission in the visible region.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73951043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Photophysical Properties of Eosin Y in Aqueous Glycol Oligomer Mixtures 乙二醇低聚物水溶液中伊红Y的光物理性质
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1004
B. Ganguly, R. K. Nath
{"title":"Photophysical Properties of Eosin Y in Aqueous Glycol Oligomer Mixtures","authors":"B. Ganguly, R. K. Nath","doi":"10.7726/AJMST.2013.1004","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1004","url":null,"abstract":"","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87394617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adjusted Adashi's Model of Exciton Bohr Parameter and New Proposed Models for Optical Properties of III-V Semiconductors 修正的Adashi激子玻尔参数模型及III-V型半导体光学性质新模型
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1008
Nawal Korti-Baghdadli, A. Merad, T. Benouaz
The energy gap of the semiconductor changes dramatically with its size. Consequently the determination of the correlation between the exciton Bohr parameter (aB), which is a size parameter, and the energy gap (Eg) is a main property for understanding the behaviour of the nanostructure properties. In this work, we propose the adjustment of Adashi’s model of exciton Bohr parameter with energy band gap to III-V family of semiconductors and propose new numerical models linking the exciton Bohr parameter (aB) to the optical properties such as the refractive index (n) and the dielectric constant (e). We found that our predictions will be more accurate for this family of semiconductors. Our objective is to propose some models which corresponding to bulk semiconductors and giving predictions to semiconductor nanostructures.
半导体的能隙随其尺寸的变化而急剧变化。因此,确定激子玻尔参数(aB)与能隙(Eg)之间的相关性是理解纳米结构性质行为的主要性质。在这项工作中,我们提出将Adashi的激子玻尔参数随能带隙的模型调整到III-V族半导体,并提出了将激子玻尔参数(aB)与折射率(n)和介电常数(e)等光学性质联系起来的新的数值模型。我们发现我们的预测将更准确地适用于这类半导体。我们的目标是提出一些与体半导体相对应的模型,并对半导体纳米结构进行预测。
{"title":"Adjusted Adashi's Model of Exciton Bohr Parameter and New Proposed Models for Optical Properties of III-V Semiconductors","authors":"Nawal Korti-Baghdadli, A. Merad, T. Benouaz","doi":"10.7726/AJMST.2013.1008","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1008","url":null,"abstract":"The energy gap of the semiconductor changes dramatically with its size. Consequently the determination of the correlation between the exciton Bohr parameter (aB), which is a size parameter, and the energy gap (Eg) is a main property for understanding the behaviour of the nanostructure properties. In this work, we propose the adjustment of Adashi’s model of exciton Bohr parameter with energy band gap to III-V family of semiconductors and propose new numerical models linking the exciton Bohr parameter (aB) to the optical properties such as the refractive index (n) and the dielectric constant (e). We found that our predictions will be more accurate for this family of semiconductors. Our objective is to propose some models which corresponding to bulk semiconductors and giving predictions to semiconductor nanostructures.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78564395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Growth and Characterization of Electrospun LaMnO3 Nanofibers by Electrospinning Technique 静电纺LaMnO3纳米纤维的生长与表征
Pub Date : 2013-01-01 DOI: 10.7726/AJMST.2013.1003
Y. Maung, Zin Min Myat, T. Win, K. Soe
The polycrystalline perovskite structure of LaMnO3 nanofibers was obtained by calcination of the PVA/[LaCl3+MnCl2+(NH4)2CO3] composite at 600°C with electrospinning technique. The decomposition and crystalline behavior of sample were examined by Thermogravimetric and Simultaneous Differential Thermal Analysis (TG-DTA). The crystal structure and phase formation were characterized by X-ray Diffraction (XRD). Scanning Electron Microscopy (SEM) was performed and the diameters of the LaMnO3 nanofibers were calculated to be 42 nm and 55 nm with different spinning intervals at 600°C. SEM analysis was also carried out to examine the fiber diameters and morphological properties.
采用静电纺丝技术将PVA/[LaCl3+MnCl2+(NH4)2CO3]复合材料在600℃下煅烧,得到了LaMnO3纳米纤维的多晶钙钛矿结构。采用热重法和同步差热分析(TG-DTA)对样品的分解和结晶行为进行了研究。用x射线衍射(XRD)对晶体结构和相形成进行了表征。通过扫描电镜(SEM)计算了不同纺丝间隔下LaMnO3纳米纤维在600℃下的直径分别为42 nm和55 nm。对纤维的直径和形态进行了扫描电镜分析。
{"title":"Growth and Characterization of Electrospun LaMnO3 Nanofibers by Electrospinning Technique","authors":"Y. Maung, Zin Min Myat, T. Win, K. Soe","doi":"10.7726/AJMST.2013.1003","DOIUrl":"https://doi.org/10.7726/AJMST.2013.1003","url":null,"abstract":"The polycrystalline perovskite structure of LaMnO3 nanofibers was obtained by calcination of the PVA/[LaCl3+MnCl2+(NH4)2CO3] composite at 600°C with electrospinning technique. The decomposition and crystalline behavior of sample were examined by Thermogravimetric and Simultaneous Differential Thermal Analysis (TG-DTA). The crystal structure and phase formation were characterized by X-ray Diffraction (XRD). Scanning Electron Microscopy (SEM) was performed and the diameters of the LaMnO3 nanofibers were calculated to be 42 nm and 55 nm with different spinning intervals at 600°C. SEM analysis was also carried out to examine the fiber diameters and morphological properties.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83157544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Comparative Studies of The Effect of Particle Size on the Microstructural Characteristics of Bi 2 O 3 and Sb 2 O 3 Additives on Sintered Zno Ceramics 粒度对bi2o3和sb2o3烧结Zno陶瓷显微组织特性影响的比较研究
Pub Date : 2012-12-01 DOI: 10.5923/J.MATERIALS.20120205.04
S. C. Udensi
Two different powder samples of ZnO with minuscule additives, of Bi2O3 and Sb2O3 were prepared through ball milling, in solutions containing deionized water and polyvinyl alcohol (PVA ) using zirconia balls. The powder samples were sieved to obtain particle size ranges of ≤ 38μm (Z, ZB, ZBS) and ≤ 63μm (Z 1, ZB1, ZBS1). The sample pellets were sintered at 800℃/ 60mins and 1100℃/600mins and their microstructures examined using SEM and X-ray for densification and coarsening kinetics. Grain growths were observed for samples ZB and ZB1 at both temperatures due to the format ion of bismuth-rich liquid phase, whereas for ZBS and ZBS1 grains growths were hindered because of the enclosure of spinel phase which pinned grain boundary motion. SEM micrographs show high densities for particle size range of ≤ 38μm at both temperatures, while for particle size range of ≤ 63μm, densificat ion was highest at 1100℃/ 600mins.The decisive parameters which controlled densification were found to be temperature, sintering time and particle geometry. In the cases where all three parameters were utilized (Z, ZB, ZBS at 1100℃/600mins), denser materials were obtained. Also equal masses of representative samples of ZB and ZB1 were seen to be electrically co mparable fro m the nonlinear p lot.
在含去离子水和聚乙烯醇(PVA)的氧化锆球溶液中,采用球磨法制备了两种添加微量Bi2O3和Sb2O3的ZnO粉末样品。粉末样品的粒度范围为≤38μm (Z、ZB、ZBS)和≤63μm (Z 1、ZB1、ZBS1)。分别在800℃/ 60min和1100℃/600min进行烧结,用扫描电镜(SEM)和x射线(X-ray)对其显微组织进行致密化和粗化动力学分析。由于富铋液相的形成,ZB和ZB1在两种温度下均能观察到晶粒的生长,而ZBS和ZBS1由于尖晶石相的包裹而抑制了晶界运动,晶粒的生长受到阻碍。SEM显微图显示,两种温度下,粒径≤38μm的合金密度均较高,粒径≤63μm的合金密度在1100℃/ 600min时最高。发现温度、烧结时间和颗粒几何形状是控制致密化的决定性参数。在同时使用三个参数(1100℃/600min下的Z、ZB、ZBS)的情况下,可以得到密度更大的材料。ZB和ZB1等质量的代表性样品也可以从非线性p批次中看到电可比较。
{"title":"Comparative Studies of The Effect of Particle Size on the Microstructural Characteristics of Bi 2 O 3 and Sb 2 O 3 Additives on Sintered Zno Ceramics","authors":"S. C. Udensi","doi":"10.5923/J.MATERIALS.20120205.04","DOIUrl":"https://doi.org/10.5923/J.MATERIALS.20120205.04","url":null,"abstract":"Two different powder samples of ZnO with minuscule additives, of Bi2O3 and Sb2O3 were prepared through ball milling, in solutions containing deionized water and polyvinyl alcohol (PVA ) using zirconia balls. The powder samples were sieved to obtain particle size ranges of ≤ 38μm (Z, ZB, ZBS) and ≤ 63μm (Z 1, ZB1, ZBS1). The sample pellets were sintered at 800℃/ 60mins and 1100℃/600mins and their microstructures examined using SEM and X-ray for densification and coarsening kinetics. Grain growths were observed for samples ZB and ZB1 at both temperatures due to the format ion of bismuth-rich liquid phase, whereas for ZBS and ZBS1 grains growths were hindered because of the enclosure of spinel phase which pinned grain boundary motion. SEM micrographs show high densities for particle size range of ≤ 38μm at both temperatures, while for particle size range of ≤ 63μm, densificat ion was highest at 1100℃/ 600mins.The decisive parameters which controlled densification were found to be temperature, sintering time and particle geometry. In the cases where all three parameters were utilized (Z, ZB, ZBS at 1100℃/600mins), denser materials were obtained. Also equal masses of representative samples of ZB and ZB1 were seen to be electrically co mparable fro m the nonlinear p lot.","PeriodicalId":7420,"journal":{"name":"American Journal of Materials Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2012-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85469778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
American Journal of Materials Science
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1