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Hybrid Orbital Formation and Multicenter Bonding of Hydrogen Atoms and Molecules in Ti 3 C 2 ${rm Ti}_{3}{rm C}_{2}$ MXenes Ti3C2${rm Ti}_{3}{rm C}_{2}$二茂钛中氢原子和分子的混合轨道形成与多中心结合
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-22 DOI: 10.1002/andp.202400011
Norbert H. Nickel

The formation and stability of solids and molecules is not possible without chemical bonds, which are divided into covalent, ionic, metallic, and van der Waals bonds. A special type of intermolecular bond is hydrogen bonding, which plays a crucial role for chemical, biological, and physical processes. However, hydrogen shows a far more complex behavior when it is present in solids. In this paper, it is shown that the chemical bonding of hydrogen atoms and molecules extends far beyond the simple picture of conventional, ionic, covalent, and multicenter bonds. The interaction of H with its host material is particularly important for hydrogen storage in metallic materials such as Ti3C2${rm Ti}_{3}{rm C}_{2}$ MXenes. Hydrogen atoms and H2${rm H}_2$ molecules form multicenter bonds in Ti3C2${rm Ti}_{3}{rm C}_{2}$. On the surface and between two Ti3C2${rm Ti}_{3}{rm C}_{2}$ sheets this is limited to the formation of H–Ti bonds. However, H and H2${rm H}_2$ on interstitial sites form multicenter bonds not only with nearest neighbor Ti atoms but also with carbon atoms. Interestingly, the H–C bonds are characterized by the formation of s–p hybrid orbitals. For

固体和分子的形成与稳定离不开化学键,化学键分为共价键、离子键、金属键和范德华键。氢键是分子间键的一种特殊类型,在化学、生物和物理过程中起着至关重要的作用。然而,当氢存在于固体中时,其行为要复杂得多。本文表明,氢原子和分子的化学键远远超出了传统的离子键、共价键和多中心键的简单描述。氢与其宿主材料的相互作用对于金属材料(如二氧化二烯)中的氢储存尤为重要。氢原子和分子在......中形成多中心键。在表面和两个薄片之间,这仅限于形成 H-Ti 键。然而,氢原子和间隙位点上的氢原子不仅会与近邻的钛原子形成多中心键,还会与碳原子形成多中心键。有趣的是,H-C 键的特点是形成 s-p 混合轨道。对于分子来说,多中心键的形成伴随着键长的增加,表面和间隙部位的键长分别为 2.07 Å 和 1.85 Å。另一方面,放置在两个片层之间会导致解离。对所有 H 和复合物的振动特征模态都进行了计算。它们的频率在 890 到 1610 之间,这表明键的强度非常高。
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引用次数: 0
Temporal Bistability in the Dissipative Dicke-Bose-Hubbard System 耗散型 Dicke-Bose-Hubbard 系统中的时间双稳态性
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-22 DOI: 10.1002/andp.202300505
Tianyi Wu, Sayak Ray, Johann Kroha

A driven-dissipative system is considered, consisting of an atomic Bose-Einstein condensates loaded into a 2D Hubbard lattice and coupled to a single mode of an optical cavity. Due to the interplay between strong, repulsive atomic interaction and the atom-cavity coupling, the system exhibits several phases of atoms and photons including the atomic superfluid (SF) and supersolid (SS). The dynamical behavior of the system, where dissipation is included by means of Lindblad master equation formalism. Due to the discontinuous nature of the Dicke transition for strong atomic repulsion, extended co-existence region of different phases are found. The resulting switching dynamics are investigated, particularly between the coexisting SF and SS phases, which eventually becomes damped by the dissipation.

研究考虑了一个驱动-耗散系统,该系统由装入二维哈伯德晶格并与光腔单模耦合的原子玻色-爱因斯坦凝聚态组成。由于强排斥性原子相互作用和原子-腔耦合之间的相互作用,该系统呈现出原子和光子的多个阶段,包括原子超流体(SF)和超固体(SS)。该系统的动力学行为通过林德布拉德主方程形式化计算出来。由于强原子斥力的 Dicke 转变具有不连续性,因此发现了不同阶段的扩展共存区域。对由此产生的切换动力学进行了研究,特别是共存的 SF 相和 SS 相之间的切换,这种切换最终会受到耗散的阻尼。
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引用次数: 0
Preparation of Distant Quantum Entanglement and One-way Quantum Steering in Hybrid Cavity-Magnonics-and-Cavity-Optomechanical Systems 制备混合腔体-磁体-腔体-光机械系统中的远距离量子纠缠和单向量子转向
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-22 DOI: 10.1002/andp.202300484
Qin-Min Wan, Yue-Han Lin, Ya-Qin Lin, Long-Jiang Cong, Rong-Can Yang, Hong-Yu Liu

A hybrid system that combines cavity magnonics and cavity optomechanics is proposed to facilitate the generation of long-distance entanglement and enable one-way steering between magnons and phonons. This configuration involves two directly coupled cavities, with one interacting with magnons and the other coupling with a mechanical oscillator (i.e., phonons). By driving the microwave cavity with a weak squeezed vacuum field generated by a flux-driven Josephson parametric amplifier, entanglement and one-way steering can be further enhanced. Moreover, the results demonstrate that magnon–phonon entanglement and one-way quantum steering exhibit robustness against temperature variations, which has significant implications for quantum information processing and storage.

为了促进长距离纠缠的产生,并实现磁子和声子之间的单向转向,我们提出了一种结合空腔磁学和空腔光学机械学的混合系统。这种配置涉及两个直接耦合的空腔,其中一个与磁子相互作用,另一个与机械振荡器(即声子)耦合。通过用通量驱动的约瑟夫森参量放大器产生的弱挤压真空场驱动微波腔,可以进一步增强纠缠和单向转向。此外,研究结果表明,磁子-声子纠缠和单向量子转向对温度变化具有稳健性,这对量子信息处理和存储具有重要意义。
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引用次数: 0
Magnetic Properties of A Cavity-Embedded Square Lattice of Quantum Dots or Antidots 嵌入腔体的方形量子点或反点阵的磁性能
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-15 DOI: 10.1002/andp.202300274
Vram Mughnetsyan, Vidar Gudmundsson, Nzar Rauf Abdullah, Chi-Shung Tang, Valeriu Moldoveanu, Andrei Manolescu

Quantum electrodynamical density functional theory is applied to obtain the electronic density, spin polarization, as well as orbital and spin magnetizations of square periodic arrays of quantum dots or antidots subjected to the influence of a far-infrared cavity photon field. A gradient-based exchange-correlation functional adapted to a 2D electron gas in a transverse homogeneous magnetic field is used in the theoretical framework and calculations. The obtained results predict a non-trivial effect of the cavity field on the electron distribution in the unit cell of the superlattice, as well as on the orbital and spin magnetizations. The number of electrons per unit cell of the superlattice is shown to play a crucial role in the modification of the magnetization via the electron–photon coupling. The calculations show that cavity photons strengthen the diamagnetic effect in the quantum dot structure, while they weaken the paramagnetic effect in the antidot structure. As the number of electrons per unit cell of the lattice increases, the electron–photon interaction reduces the exchange forces that will otherwise promote strong spin splitting for both the dot and the antidot arrays.

本研究应用量子电动力学密度泛函理论,获得了受远红外空腔光子场影响的方形周期性量子点或反点阵列的电子密度、自旋极化以及轨道和自旋磁化。理论框架和计算中使用了基于梯度的交换相关函数,该函数适用于横向均匀磁场中的二维电子气体。计算结果预测,空穴场对超晶格单元格中的电子分布以及轨道磁化和自旋磁化有非同一般的影响。结果表明,超晶格单位晶胞中的电子数量在通过电子-光子耦合改变磁化方面起着至关重要的作用。计算表明,空穴光子增强了量子点结构中的二磁效应,而削弱了反点阵结构中的顺磁效应。随着晶格每个单元的电子数增加,电子-光子相互作用减少了交换力,否则交换力将促进点阵和反点阵的强自旋分裂。
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引用次数: 0
(Ann. Phys. 2/2024) (Ann. Phys. 2/2024)
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-14 DOI: 10.1002/andp.202470003

Neutron Star Mergers

When two neutron stars revolve around each other, they emit gravitational waves which drives them – initially very subtly but in the end very violently – towards a collision. In such a collision, neutron star matter gets ejected into space where it forms heavy elements via the “rapid-neutron capture process”. The freshly synthesized, initially radioactive nuclei power electromagnetic transients called “kilonovae” that are observable in a merger's aftermath. In article 2200306, Stephan Rosswog and Oleg Korobkin discuss today's state-of-the-art of this active research field.

中子星合并当两颗中子星绕着对方旋转时,它们会发出引力波,引力波会驱动它们--最初是非常微妙的,但最终会非常剧烈地--发生碰撞。在这种碰撞中,中子星物质被抛射到太空中,通过 "快速中子俘获过程 "形成重元素。这些新合成的、最初具有放射性的原子核会产生被称为 "千新星 "的电磁瞬变,这种瞬变可以在天体合并后观测到。在第 2200306 号文章中,斯蒂芬-罗斯沃格(Stephan Rosswog)和奥列格-科罗布金(Oleg Korobkin)讨论了这一活跃研究领域的最新进展。
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引用次数: 0
Masthead: Ann. Phys. 2/2024 刊头Ann.2/2024
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-14 DOI: 10.1002/andp.202470004
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引用次数: 0
Conservation of a Spectral Asymmetry Invariant in Optical Fiber Four-Wave Mixing 光纤四波混频中光谱不对称不变量的守恒性
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-13 DOI: 10.1002/andp.202300489
Anastasiia Sheveleva, Pierre Colman, John M. Dudley, Christophe Finot

The conservation of spectral asymmetry is a fundamental feature of the ideal four-wave mixing process as it exists in a medium combining quadratic chromatic dispersion and third-order nonlinearity. The robustness of this invariant in an experimental configuration where the excitation conditions of an optical fiber are sequentially updated, mimicking infinite propagation is tested in this paper. This theoretical and experimental study reveals the high sensitivity of the asymmetry to very slight deviations from the ideal case, and the idealized system behaves as an intermediate case between the ideal case of noncascaded four-wave mixing and propagation in a system governed by the nonlinear Schrödinger equation is shown.

光谱不对称性的保持是理想四波混合过程的一个基本特征,因为它存在于结合了二次色散和三阶非线性的介质中。本文测试了这一不变性在模拟无限传播的实验配置中的稳健性,在这种实验配置中,光纤的激发条件被顺序更新。这项理论和实验研究揭示了非对称性对理想情况下极微小偏差的高度敏感性,理想化的系统表现为非级联四波混合理想情况与非线性薛定谔方程支配的系统传播之间的中间情况。
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引用次数: 0
Anomaly Non-Renormalization, Lattice QFT, and Universality of Transport Coefficients 反常非正则化、晶格 QFT 和输运系数的普遍性
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-09 DOI: 10.1002/andp.202300346
Vieri Mastropietro

Recently new methods have been introduced to investigate the non-renormalization properties of the anomalies at a non perturbative level and in presence of a lattice. The issue is relevant in a number of problems ranging from the anomaly-free construction of chiral lattice gauge theory with large cut-off to the universality properties observed in transport coefficients in condensed matter systems. A review of main results and future perspectives is presented.

最近,人们引入了新的方法来研究在非微扰水平和存在晶格的情况下反常现象的非反常化特性。这个问题与许多问题相关,从大截距手性晶格规理论的无反常构造到凝聚态系统中观测到的输运系数的普遍性。本文回顾了主要成果和未来展望。
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引用次数: 0
How to Rapidly Evaluate Uranium Adsorption Capacity Using Only a Portable Geiger Counter? 如何仅使用便携式盖革计数器快速评估铀吸附能力?
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-06 DOI: 10.1002/andp.202300425
Jingtao Bi, Siyang Xing, Chengqian Li, Mengmeng Sun, Hongqing Wu, Yingying Zhao

The development of the nuclear industry has stimulated research in uranium extraction from seawater (UES) by adsorption. However, in practical applications, it's hard to equip various ion concentration measurement instruments for real-time characterizing uranium adsorption capacity. Given the radioactive property of uranium, if only a Geiger counter is possessed, how it can be utilized to rapidly evaluate uranium adsorption in the adsorbent? This study proposes the Geiger-Uranium-Distance model, which establishes correlations among Geiger counter readings, uranium adsorption capacity, and distance, thereby offering a viable approach. While maintaining a constant radius for the adsorbent stack point, during the laboratory phase, the average molecular mass (MA) and the kGg(z) values of the original adsorbent are determined. In practical applications, the surrounding radiation background GE (µSv h−1) is detected. Subsequently, the Geiger counter is vertically positioned above the stacked point of adsorbent after uranium adsorption. Utilizing the measured radiation intensity value G (µSv h−1), and employing the equation G=kGg(z)Qe1+MAQe+GE$G = {k}_G g( z )frac{{{Q}_e}}{{1 + {M}_A{Q}_e}} + {G}_E$, the uranium adsorption capacity Qe can be obtained.

核工业的发展推动了吸附法从海水中提取铀(UES)的研究。然而,在实际应用中,很难配备各种离子浓度测量仪器来实时表征铀的吸附能力。鉴于铀的放射性特性,如果仅有一台盖革计数器,如何利用它来快速评估铀在吸附剂中的吸附情况呢?本研究提出了盖革-铀-距离模型,该模型建立了盖革计数器读数、铀吸附能力和距离之间的相关性,从而提供了一种可行的方法。在实验室阶段,在保持吸附剂堆积点半径不变的情况下,确定原始吸附剂的平均分子质量 (MA) 和 kGg(z) 值。在实际应用中,要检测周围的辐射背景 GE(µSv h-1)。随后,将盖革计数器垂直放置在铀吸附后吸附剂堆积点的上方。利用测得的辐射强度值 G (µSv h-1),并利用公式 G=kGg(z)Qe1+MAQe+GE$G = {k}_G g( z )frac{{Q}_e}}{{1 + {M}_A{Q}_e}}+ {G}_E$,即可求得铀吸附容量 Qe。
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引用次数: 0
Photon Generation Scheme of 32-Fold Millimeter-Wave Signal Based on Mach-Zehnder Modulator 基于马赫-泽恩德调制器的 32 倍毫米波信号光子生成方案
IF 2.4 4区 物理与天体物理 Q2 Physics and Astronomy Pub Date : 2024-02-02 DOI: 10.1002/andp.202300360
Shali Wang, Dongfei Wang, Lei Ren, Hu Zhang, Zihao Wu, Wusong Li, Fenghui Zhang, Xiangqing Wang

This paper proposes a 32-tupling frequency millimeter-wave (MMW) filter-free system based on four Mach-Zehnder Modulators (MZM) connected in parallel and cascaded with a simple radio-fiber (RoF) link structure. The four MZMs are all at the maximum transmission point (MATP), and the radio frequency (RF) driving voltage phase difference between MZMs is π /2. The center carrier is suppressed by using an optical attenuator (OATT) and an optical phase shifter (OPS). Two parallel MZMs can generate ±8th order and ±12th order optical sidebands, and the ±4th order optical sidebands can be suppressed by adjusting the modulation index m of the MZM, using cascaded two dual-parallel MZMS(DPMZM) and the phase difference of the RF signal source is π/4 to generate ±16th order optical sidebands. The theoretical analysis and simulation experiments are performed for the scheme proposed in this paper. The results show that the simulated and theoretical values of the optical sideband suppression ratio (OSSR) for ±16th order optical sideband signals are 60.02 and 59.96 dB, respectively, and the simulated and theoretical values of the RF sideband suppression ratio (RFSSR) for the 32-tupling MMW signal are 56.34 and 53.94 dB, respectively.

本文提出了一种 32 倍频毫米波(MMW)无滤波器系统,该系统基于四个并联和级联的马赫-泽恩德调制器(MZM),采用简单的无线电光纤(RoF)链路结构。四个 MZM 均位于最大传输点 (MATP),MZM 之间的射频 (RF) 驱动电压相位差为 π /2。通过使用光衰减器(OATT)和光移相器(OPS)抑制中心载波。两个并联的 MZM 可以产生±8阶和±12阶光边带,通过调整 MZM 的调制指数 m 可以抑制±4阶光边带,使用级联的两个双并联 MZMS(DPMZM),射频信号源的相位差为 π/4,可以产生±16阶光边带。本文提出的方案进行了理论分析和仿真实验。结果表明,±16 阶光边带信号的光边带抑制比(OSSR)的模拟值和理论值分别为 60.02 和 59.96 dB,32 倍频 MMW 信号的射频边带抑制比(RFSSR)的模拟值和理论值分别为 56.34 和 53.94 dB。
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引用次数: 0
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