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Nonadiabatic and Anharmonic Effects in High-Pressure H3S and D3S Superconductors 高压H3S和D3S超导体中的非绝热和非调和效应
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-25 DOI: 10.1002/andp.202500553
Shashi B. Mishra, Elena R. Margine
<p>Superconductivity in compressed <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>3</mn> </msub> <mi>S</mi> </mrow> <annotation>${rm H}_3{rm S}$</annotation> </semantics></math> arises from the interplay between high-frequency phonons and a pronounced van Hove singularity near the Fermi level. Using first-principles calculations, we investigate the superconducting properties of <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>3</mn> </msub> <mi>S</mi> </mrow> <annotation>${rm H}_3{rm S}$</annotation> </semantics></math> and <span></span><math> <semantics> <mrow> <msub> <mi>D</mi> <mn>3</mn> </msub> <mi>S</mi> </mrow> <annotation>${rm D}_3{rm S}$</annotation> </semantics></math> at 160 and 200 GPa, explicitly incorporating anharmonic lattice dynamics and first-order vertex corrections to electron-phonon (e-ph) interactions, thereby going beyond the Migdal approximation underlying conventional Migdal-Eliashberg theory. We find that both anharmonicity and nonadiabatic vertex corrections suppress the effective e-ph coupling and reduce the superconducting critical temperature (<span></span><math> <semantics> <msub> <mi>T</mi> <mi>c</mi> </msub> <annotation>$T_{rm c}$</annotation> </semantics></math>). Calculations performed within the energy-dependent full-bandwidth Eliashberg formalism, including both anharmonic and vertex effects, yield <span></span><math> <semantics> <msub> <mi>T</mi> <mi>c</mi> </msub> <annotation>$T_{rm c}$</annotation> </semantics></math> values in close agreement with experimental measurements for <span></span><math> <semantics> <mrow> <msub> <mi>D</mi> <mn>3</mn> </msub> <mi>S</mi> </mrow> <annotation>${rm D}_3{rm S}$</annotation> </semantics></math> at both pressures and for <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>3</mn> </msub>
压缩h3s ${rm H}_3{rm S}$中的超导性是由费米能级附近的高频声子和明显的范霍夫奇点之间的相互作用引起的。利用第一性原理计算,我们研究了h3s ${rm H}_3{rm S}$和d3s ${rm D}_3{rm S}$在160和明确地结合了非调和晶格动力学和电子-声子(e-ph)相互作用的一阶顶点修正,从而超越了传统Migdal- eliashberg理论基础上的Migdal近似。我们发现非调和性和非绝热顶点修正都抑制了有效的e-ph耦合,降低了超导临界温度(tc $T_{rm c}$)。在能量依赖的全带宽Eliashberg形式下进行的计算,包括非调和效应和顶点效应,在两种压力下,产率T c $T_{rm c}$的值与实验测量值非常吻合,D ${rm D}_3{rm S}$H 3 S ${rm H}_3{rm S}$ 200gpa。
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引用次数: 0
Wilhelm Veltmann's Contribution to “Optical Relativity” Wilhelm Veltmann对“光学相对论”的贡献
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-24 DOI: 10.1002/andp.70120
Christian Bracco

In 1873, German mathematician and theoretical physicist Wilhelm Veltmann (1832–1902), who taught in secondary schools for most of his career, published in Annalen der Physik an article that caught the attention of influential scientists such as Hendrik Antoon Lorentz or Alfred Potier at the École Polytechnique in France. Veltmann was the first to find a theoretical explanation for the impossibility of detecting the Earth's motion in the ether using optical devices involving reflection, refraction, interference, diffraction, etc. We briefly review his contribution, which was instrumental in the birth of “optical relativity” in the 19th century.

1873年,大部分时间在中学教书的德国数学家和理论物理学家威廉·维特曼(1832-1902)在《物理学年鉴》上发表了一篇文章,引起了法国École理工学院的亨德里克·安东·洛伦兹和阿尔弗雷德·波蒂埃等有影响力的科学家的注意。Veltmann是第一个用反射、折射、干涉、衍射等光学设备对不可能探测到地球在以太中的运动进行理论解释的人。我们简要回顾一下他的贡献,这对19世纪“光学相对论”的诞生起了重要作用。
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引用次数: 0
High-Pressure Synthesis of Samarium Hydrides 高压合成钐氢化物
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-24 DOI: 10.1002/andp.202500545
Liang Ma, Pengfei Shan, Jingkai Bi, Wenfei Xu, Sheng Jiang, Lili Zhang, Pengtao Yang, Bosen Wang, Jianping Sun, Haizhong Guo, Jinguang Cheng

We report an experimental study on the high-pressure syntheses and characterizations of the samarium (Sm) hydrides system, for which the theoretical predictions have long struggled to accurately describe the crystal structures and superconducting properties. By laser heating Sm and ammonia borane (BH3NH3) compressed in diamond anvil cells (DACs), we successfully synthesized a series of Sm hydrides, including P63/mmc SmH9, Im-3m SmH6, I4/mmm SmH4, Pm-3n SmH3, P6/mmm SmH2, and Fm-3m SmH2-x. Electrical transport measurements performed in four independent experimental runs revealed metallic behavior without any signature of superconductivity, while some samples exhibited anomalies suggestive of magnetic or electronic transitions. These findings establish Sm hydrides as a model platform for probing the interplay between strong electronic correlations, magnetism, and superconductivity in high-pressure hydrides, highlighting the complex role of 4f electrons in governing their physical properties.

本文报道了一项高压合成和表征钐(Sm)氢化物体系的实验研究,长期以来,理论预测难以准确描述钐(Sm)氢化物体系的晶体结构和超导性能。通过激光加热Sm和金刚石砧细胞(DACs)中压缩的氨硼烷(BH3NH3),成功合成了一系列Sm氢化物,包括P63/mmc SmH9、Im-3m SmH6、I4/mmm SmH4、Pm-3n SmH3、P6/mmm SmH2和Fm-3m SmH2-x。在四个独立的实验运行中进行的电输运测量显示,金属行为没有任何超导特征,而一些样品表现出异常,暗示磁性或电子跃迁。这些发现奠定了Sm氢化物作为探索高压氢化物中强电子相关性、磁性和超导性之间相互作用的模型平台,突出了4f电子在控制其物理性质方面的复杂作用。
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引用次数: 0
Randomized Hypergraph States and Their Entanglement Properties 随机超图态及其纠缠特性
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-24 DOI: 10.1002/andp.202500622
Vinícius Salem, Alison A. Silva, Fabiano M. Andrade

We study the entanglement properties of randomized mixed hypergraph states, extending the concept of randomized mixed graph states to encompass hypergraph-based quantum states. In our model, imperfect generalized multi-qubit gates are applied probabilistically, simulating experimentally realistic noisy gate operations where gate fidelity decreases with increasing hyperedge order. We analyze bipartite and genuine multipartite entanglement of these mixed multi-qubit states. Numerical results for various hypergraph configurations with up to four qubits reveal rich, sometimes nonmonotonic entanglement behavior stemming from the interplay between hyperedge structure and gate imperfections. We derive analytical expressions for entanglement witnesses based on randomization overlap for new hypergraph families. Our findings contribute to understanding entanglement resilience under gate imperfections, providing insight into the experimental implementation of hypergraph states in noisy quantum devices.

我们研究了随机混合超图态的纠缠特性,将随机混合图态的概念扩展到包含基于超图的量子态。在我们的模型中,不完美广义多量子比特门被概率地应用,模拟实验上真实的噪声门操作,其中门的保真度随着超边缘阶数的增加而降低。我们分析了这些混合多量子位态的二部纠缠和真多部纠缠。对于多达四个量子比特的各种超图构型的数值结果显示,由于超边缘结构和栅极缺陷之间的相互作用,产生了丰富的、有时是非单调的纠缠行为。我们导出了基于随机重叠的新超图族纠缠见证的解析表达式。我们的发现有助于理解门缺陷下的纠缠弹性,为噪声量子器件中超图态的实验实现提供见解。
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引用次数: 0
Development of Boron-Doped Diamond Electrodes in Diamond Anvil Cell and Application for Exploration of Superconducting Hydrides 金刚石砧槽中掺硼金刚石电极的研制及其在超导氢化物研究中的应用
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1002/andp.202500557
Ryo Matsumoto, Satoshi Nakano, Tetsuo Irifune, Yoshihiko Takano

One of the grand challenges in physics is the exploration of room-temperature superconductivity and the promising candidate is hydrides under high-pressure. In this review, we introduce a custom-designed diamond anvil cell equipped with boron-doped diamond electrodes that enables both the synthesis and in situ evaluation of superconductivity under extreme conditions without complex experimental configurations. The metallic boron-doped diamond epitaxial film is selectively grown on the diamond anvil surface by microwave-assisted plasma chemical vapor deposition, combined with lithographic patterning techniques. We describe the fabrication process of the boron-doped diamond electrodes and demonstrate their application to the synthesis and transport measurements of superconducting hydrides. This approach provides a powerful and reusable platform for exploring new superconductors at ultrahigh pressures.

物理学的重大挑战之一是探索室温超导性,而高压下的氢化物是最有希望的候选者。在这篇综述中,我们介绍了一种定制设计的金刚石砧池,配备了掺杂硼的金刚石电极,可以在极端条件下合成和原位评估超导性,而无需复杂的实验配置。采用微波辅助等离子体化学气相沉积技术,结合光刻图像化技术,在金刚石砧表面选择性地生长金属硼掺杂金刚石外延膜。我们描述了掺硼金刚石电极的制备过程,并展示了它们在超导氢化物的合成和输运测量中的应用。这种方法为在超高压下探索新的超导体提供了一个强大的、可重复使用的平台。
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引用次数: 0
Engineering Absorption in CdSe/CdS Nanostructures Through Controlled Strain and Dimensionality 控制应变和尺寸的CdSe/CdS纳米结构的工程吸收
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-22 DOI: 10.1002/andp.202500589
Ayoub Ed-Dahmouny, Reda Arraoui, Nabil Zeiri, Mohammed Jaouane, Abdelghani Fakkahi, Hamed D. Jahromi, Noureddine Sfina, Fahad Aljuaid, Ahmed Sali

This study theoretically investigates the optical absorption spectrum of CdSe/CdS core–shell quantum dots (CSQDs) under the combined influence of quantum confinement, elastic strain, and an on-center donor impurity. Utilizing the effective mass approximation and continuum elasticity theory, we model the system's energy eigenvalues and absorption coefficients. For unstrained CSQDs, our findings demonstrate that quantum confinement strongly dictates the electronic energy levels and absorption peak positions, exhibiting a blueshift with decreasing core radius and a redshift with increasing shell thickness. Crucially, the presence of elastic strain, originating from the lattice mismatch between the core and shell materials, significantly modifies the confinement potential. This strain leads to a progressive delocalization of electron wavefunctions into the shell material, particularly for higher excited states, effectively attenuating the confinement potential. This wavefunction redistribution directly impacts the energy level spacing and causes concomitant redshifts in the absorption spectra with increasing core size. Our results provide fundamental insights into how strain and dimensionality can be precisely engineered to tune the optoelectronic properties of CdSe/CdS nanostructures, offering a pathway for designing advanced optoelectronic devices.

本研究从理论上研究了CdSe/CdS核壳量子点(CSQDs)在量子约束、弹性应变和中心外给体杂质共同影响下的光吸收光谱。利用有效质量近似和连续介质弹性理论,建立了系统能量特征值和吸收系数的模型。对于非应变的CSQDs,我们的研究结果表明,量子约束强烈地决定了电子能级和吸收峰的位置,表现出蓝移随着核半径的减小而减小,红移随着壳层厚度的增加而增加。至关重要的是,由于核和壳材料之间的晶格不匹配而产生的弹性应变的存在,显著地改变了约束势。这种应变导致电子波函数逐渐离域到壳层材料中,特别是对于高激发态,有效地衰减了约束势。这种波函数重分布直接影响能级间距,并导致吸收光谱随芯尺寸的增加而伴随红移。我们的研究结果为如何精确地设计应变和尺寸来调整CdSe/CdS纳米结构的光电特性提供了基本的见解,为设计先进的光电器件提供了途径。
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引用次数: 0
Infrared Quantum Electrodynamics and the Rayleigh-Jeans Physics 红外量子电动力学和瑞利-金斯物理学
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-16 DOI: 10.1002/andp.202500481
Jorge Gamboa, Natalia Tapia-Arellano

Infrared quantum electrodynamics (IR–QED) acquires a natural geometric interpretation once soft photons are described as adiabatically transported electron–photon clouds. Within this framework, the relevant infrared structure is encoded in a functional Berry phase associated with the space of gauge connections, and the corresponding Berry corrections modify the Rayleigh–Jeans spectrum. The infrared scaling symmetry of the Rayleigh–Jeans law leads to a simple renormalization–group equation whose solution determines the frequency dependence of an effective factor Feff(ω)$F_{rm eff}(omega)$ controlling the strength of the electron–photon cloud dressing. As a result, the energy density of the cosmic microwave background (CMB) receives a Berry-induced correction that scales as a power law and produces a frequency-dependent temperature excess in the radio domain. Although the exponent γ$gamma$ governing this scaling behavior is not fixed internally by the present formulation of IR–QED and must instead be determined phenomenologically, the existence and structure of the excess are genuine predictions of the theory. Remarkably, the resulting expression is extremely simple and naturally aligns with the deviations suggested by the ARCADE 2 data. Taken together, these results indicate that Berry phases in IR–QED may lead to observable consequences in the low-frequency tail of the CMB spectrum.

一旦将软光子描述为绝热传输的电子-光子云,红外量子电动力学(IR-QED)就获得了自然的几何解释。在这个框架中,相关红外结构被编码在与测量连接空间相关的功能Berry相位中,相应的Berry修正修改了瑞利-琼斯光谱。瑞利-金斯定律的红外尺度对称性导致了一个简单的重整化群方程,其解决定了控制电子-光子强度的有效因子F (ω) $F_{rm eff}(omega)$的频率依赖性云妆。结果,宇宙微波背景(CMB)的能量密度接受了贝里诱导的修正,该修正按幂律缩放,并在无线电域中产生频率相关的温度过剩。虽然控制这种标度行为的指数γ $gamma$不是由IR-QED的当前公式内部固定的,而是必须从现象学上确定,但过剩的存在和结构是理论的真正预测。值得注意的是,结果表达式非常简单,并且自然地与ARCADE 2数据所显示的偏差保持一致。综上所述,这些结果表明IR-QED中的贝里相位可能导致CMB频谱低频尾部的可观察结果。
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引用次数: 0
Skyrmion Footprint in the Thermodynamics of the Josephson Superconducting Diode Josephson超导二极管热力学中的Skyrmion足迹
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-15 DOI: 10.1002/andp.202500488
Andreas Sinner, Xi-Guang Wang, Levan Chotorlishvili

We study the thermodynamics of the recently proposed superconducting Josephson junction diode, in particular its specific heat capacity. Its low temperature behavior is determined by the interplay of two intrinsic energy scales of the microscopic Hamiltonian, associated with the superconducting gap and tunneling amplitude of conventional electrons through the junction. If the latter is large enough to overcome the former, the specific heat decays linearly with temperature, reflecting the presence of a current through the diode. In the opposite case, the specific heat decays exponentially and the diode becomes non-conducting. In the intermediate regime, where both scales are equally large, the specific heat exhibits a non-trivial power-law behavior in terms of the temperature. It is demonstrated, that switching on and off of the device is possible by changing the phase of the superconducting condensate only, which is accessible via an external magnetic field. Having magnetic textures hosting magnetic defects, such as skyrmions, antiskyrmions or domain walls as sources of such magnetic field leaves behind unique defect specific footprints in the specific heat.

我们研究了最近提出的超导约瑟夫森结二极管的热力学,特别是它的比热容。它的低温行为是由微观哈密顿量的两个本征能量尺度的相互作用决定的,与超导间隙和通过结的常规电子的隧穿振幅有关。如果后者足够大,可以克服前者,则比热随温度线性衰减,反映通过二极管的电流的存在。在相反的情况下,比热呈指数衰减,二极管变得不导电。在中间状态下,当两个尺度都相等时,比热表现出与温度有关的非平凡的幂律行为。实验证明,仅通过改变超导冷凝物的相位就可以打开和关闭该装置,而超导冷凝物可以通过外部磁场进入。具有磁性纹理承载磁性缺陷,如skyrmions,反skyrmions或域壁作为这种磁场的来源,在特定的热量下留下独特的缺陷特定足迹。
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引用次数: 0
Charging a quantum battery from the Bloch Sphere 从布洛赫球给量子电池充电
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-15 DOI: 10.1002/andp.202500638
Charles Andrew Downing, Muhammad Shoufie Ukhtary

We reconsider the quantum energetics and quantum thermodynamics of the charging process of a simple, two-component quantum battery model made up of a charger qubit and a single–cell battery qubit. We allow for the initial quantum state of the charger to lie anywhere on the surface of the Bloch sphere, and find the generalized analytical expressions describing the stored energy, ergotropy, and capacity of the battery, all of which depend upon the initial Bloch sphere polar angle in a manner evocative of the quantum area theorem. The origin of the ergotropy produced, as well as the genesis of the battery capacity, can be readily traced back to the quantum coherences and population inversions generated (and the balance between these two mechanisms is contingent upon the starting Bloch polar angle). Importantly, the ergotropic charging power and its associated optimal charging time display notable deviations from standard results, which disregard thermodynamic considerations. Our theoretical groundwork may be useful for guiding forthcoming experiments in quantum energy science based upon coupled two-level systems.

我们重新考虑了由充电器量子比特和单电池量子比特组成的简单双组分量子电池模型充电过程的量子能量学和量子热力学。我们允许充电器的初始量子态位于布洛赫球表面的任何地方,并找到描述电池存储能量,自恋性和容量的广义解析表达式,所有这些都以量子面积定理的方式依赖于初始布洛赫球极角。产生的自向性的起源,以及电池容量的起源,可以很容易地追溯到产生的量子相干和种群反转(这两种机制之间的平衡取决于开始的布洛赫极角)。重要的是,自适应充电功率及其相关的最佳充电时间显示出与标准结果的显著偏差,这忽略了热力学因素。我们的理论基础可能有助于指导未来基于耦合两能级系统的量子能量科学实验。
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引用次数: 0
Architectured Graphene/Iron Microsphere Meta-Composites for Effective Microwave Dissipation 结构石墨烯/铁微球复合材料的有效微波耗散
IF 2.5 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY Pub Date : 2026-01-14 DOI: 10.1002/andp.202500495
Ruiling Xie, Hongyang Li, Shentao Zeng, Hong Li, Ran Wang, Cui Luo, Ying Liu

Spherical Fe/graphene composite microwave-absorbing materials are synthesized with liquid-phase atomization and redox composite ball-milling process. The effects of graphene content on the microstructure, electromagnetic parameters, and wave absorption properties are investigated. Results demonstrate that Fe particles maintain a nearly spherical morphology with an average diameter of approximately 2 µm, while graphene is uniformly dispersed in a sheet-like form. The crystallographic structures of both Fe and graphene are preserved after the composite formation. As the graphene content increases, both the real and imaginary components of the dielectric constant of the composite gradually increase. The dielectric loss mechanisms transitioned from polarization relaxation dominance at low graphene content to conductivity loss dominance at higher concentrations. In terms of magnetic losses, magnetic resonance primarily governs the low-frequency range, while eddy current losses dominate at medium to high frequencies. The sample with 25% graphene content exhibits the strongest electromagnetic wave attenuation capability, while the 10% sample demonstrates optimal impedance matching characteristics. When the graphene content is 15%, and the matching thickness is 1.7 mm, the material achieves a minimum reflection loss of −19.87 dB, with an effective absorption bandwidth of 4.4 GHz at a thickness of 1.2 mm.

采用液相雾化和氧化还原复合球磨工艺合成了球形铁/石墨烯复合吸波材料。研究了石墨烯含量对复合材料微观结构、电磁参数和吸波性能的影响。结果表明,铁颗粒保持近球形形态,平均直径约为2µm,而石墨烯均匀分散在片状结构中。复合材料形成后,铁和石墨烯的晶体结构都得以保留。随着石墨烯含量的增加,复合材料介电常数的实分量和虚分量都逐渐增大。介质损耗机制由低石墨烯含量时的极化弛豫主导转变为高石墨烯含量时的电导率损失主导。在磁损耗方面,磁共振主要控制低频范围,而涡流损耗主要在中高频。石墨烯含量为25%的样品表现出最强的电磁波衰减能力,而石墨烯含量为10%的样品表现出最佳的阻抗匹配特性。当石墨烯含量为15%,匹配厚度为1.7 mm时,材料的反射损耗最小为- 19.87 dB,有效吸收带宽为4.4 GHz,厚度为1.2 mm。
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引用次数: 0
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