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Studying substituent number effects on vibrational energy transfer by time−resolved CARS spectroscopy 用时间分辨 CARS 光谱法研究取代基数对振动能量转移的影响
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-08 DOI: 10.1140/epjd/s10053-024-00830-w
Xiaosong Liu, Qingxiao Zou, Hui Li, Weilong Liu, Feng Hu, Yanqiang Yang

Vibrational energy transfer was a key property of chemical reactions that remains deeply understood. In this work, the detail information of vibrational energy transfer in aniline, N,N-dimethylaniline (DMA) and N,N-diethylaniline (DEA) were studied by femtosecond time-resolved coherent anti-Stokes Raman scattering (CARS) spectroscopy, respectively. Low frequency modes of aniline, DMA and DEA were collectively excited, the beats arising from vibrational couplings among these modes were described. With analysis of vibrational coupling, energy transfer flow from one mode to another was visualized. An investigation into the molecular structure and vibrational couplings can be found that vibrational energy transfer is related to vibrational mode symmetry. In addition, substituent groups play an important role in vibrational coupling and energy transfer of aniline, DMA and DEA. A decrease of the number of substituent vibrational modes involved in coupling and energy transfer efficiency with the increase of the amount of relative molecular mass ratio was found out.

Graphical abstract

振动能量转移是化学反应的一个关键特性,但人们对这一特性的理解仍然很深。本研究利用飞秒时间分辨相干反斯托克斯拉曼散射(CARS)光谱分别研究了苯胺、N,N-二甲基苯胺(DMA)和N,N-二乙基苯胺(DEA)中振动能量传递的详细信息。对苯胺、DMA 和 DEA 的低频模式进行了集体激发,并描述了这些模式之间振动耦合产生的节拍。通过分析振动耦合,可以直观地看到能量从一个模式传递到另一个模式。通过对分子结构和振动耦合的研究可以发现,振动能量的传递与振动模式的对称性有关。此外,取代基团在苯胺、DMA 和 DEA 的振动耦合和能量传递中起着重要作用。研究发现,随着相对分子质量比的增加,参与耦合和能量传递效率的取代基振动模式数量减少。
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引用次数: 0
Direct spectroscopy of Rubidium using a narrow-line transition at 420 nm 利用波长 420 纳米的窄线转变直接测定铷原子的光谱
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-04 DOI: 10.1140/epjd/s10053-024-00831-9
Rajnandan Choudhury Das, Samir Khan, Thilagaraj Ravi, Kanhaiya Pandey

The 5S(rightarrow )6P transition in rubidium (Rb) at 420 nm offers the advantage of narrow linewidth and diverse applications in quantum technologies. However, the direct spectroscopy at this transition is challenging due to its weak transition strength. In this paper, we have discussed the saturated absorption spectroscopy (SAS) of Rb using the narrow-line transition at 420 nm. We have studied the effect of the temperature of the Rb cell, control beam power, and beam size on the SAS dip heights and their linewidths. Additionally, our study offers a comprehensive examination, encompassing all eight error signals of Rb for the 5 S(rightarrow )6P transition at 420 nm and 421 nm. These findings contribute valuable insights to the field of laser frequency stabilization of Rb at blue transition and can be useful in quantum technologies based on this transition.

Direct spectroscopy of Rubidium at blue transition.

摘要 铷(Rb)在 420 纳米波长处的 5S(rightarrow)6P 转变具有线宽窄的优势,在量子技术中的应用多种多样。然而,由于该转变的转变强度较弱,在该转变处直接进行光谱分析具有挑战性。本文讨论了利用 420 纳米窄线跃迁对铷进行饱和吸收光谱分析(SAS)的问题。我们研究了铷原子池的温度、控制光束功率和光束大小对饱和吸收光谱倾角高度及其线宽的影响。此外,我们的研究还提供了全面的检查,包括 420 纳米和 421 纳米波长处 5 S(rightarrow)6P 转变的所有八个掺铒误差信号。这些发现为铷在蓝色转变时的激光稳频领域提供了宝贵的见解,并可用于基于这一转变的量子技术。
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引用次数: 0
A continuous beam monochromator for matter waves 物质波连续光束单色仪
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-04 DOI: 10.1140/epjd/s10053-024-00829-3
Johannes Fiedler, Bodil Holst

Atom and, of late, molecule interferometers find application in both the crucible of fundamental research and industrial pursuits. A prevalent methodology in the construction of atom interferometers involves the utilisation of gratings fashioned from laser beams. While this approach imparts commendable precision, it is hampered by its incapacity to attain exceedingly short wavelengths and its dependence on intricate laser systems for operational efficacy. All applications require the control of matter waves, particularly the particle’s velocity. In this manuscript, we propose a continuous beam monochromator scheme reaching enormously high velocity purification with speed ratios in the order of (10^3) based on atom-surface diffraction. Beyond these high purifications, the proposed scheme simplifies the application by reducing the degree of freedom to a single angle, selecting the wanted particle’s velocity.

摘要 原子干涉仪以及最近的分子干涉仪在基础研究和工业领域都得到了应用。制造原子干涉仪的一种普遍方法是利用激光束制成的光栅。虽然这种方法的精确度值得称赞,但由于无法达到极短的波长,而且需要依赖复杂的激光系统才能有效运行,因此这种方法受到了阻碍。所有应用都需要控制物质波,特别是粒子的速度。在本手稿中,我们提出了一种基于原子表面衍射的连续光束单色仪方案,可以达到极高的速度净化,速度比达到 (10^3)的数量级。除了这些高纯度之外,所提出的方案还通过将自由度降低到单一角度来选择所需的粒子速度,从而简化了应用。
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引用次数: 0
Orthogonal operators: extension to hyperfine structure and equivalent p- and f-electrons 正交算子:扩展到超精细结构以及等效 p 电子和 f 电子
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-03 DOI: 10.1140/epjd/s10053-024-00828-4
Peter Uylings, Ton Raassen

Orthogonal operators are a next step in the semi-empirical description of complex spectra. Orthogonality yields optimal independence and thus least correlation between the operators. The increased stability of the fitting process is used to include higher-order many-body as well as fully relativistic effects. The calculated eigenvalues are frequently an order of magnitude more accurate with respect to a conventional semi-empirical approach. The resulting eigenvectors may not only be put to use to calculate transition probabilities and g-factors, but also to calculate hyperfine structure A and B constants. We illustrate our first steps in this field with two examples of first spectra of the iron group elements. The results are compared to current experimental hyperfine structure A-values while strong and weak points of the method are discussed. In particular to be able to deal with lanthanides and actinides, the orthogonal operator method is completed with the definition of operators for equivalent p- and f-electrons.

摘要 正交算子是复杂光谱半经验描述的下一步。正交性产生了最佳的独立性,从而使算子之间的相关性最小。拟合过程稳定性的提高可用于包含高阶多体效应和完全相对论效应。与传统的半经验方法相比,计算出的特征值通常要精确一个数量级。由此得到的特征向量不仅可以用来计算转变概率和 g 因子,还可以用来计算超细结构 A 常量和 B 常量。我们以两个铁族元素的第一光谱为例,说明我们在这一领域迈出的第一步。我们将结果与当前的实验超正弦结构 A 值进行了比较,同时讨论了该方法的强项和弱项。特别是为了能够处理镧系元素和锕系元素,通过定义等效 p 电子和 f 电子的算子完成了正交算子方法。 图形摘要
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引用次数: 0
Evaluation of uncertainties in atomic data on spectral lines and transition probabilities 评估光谱线和转变概率原子数据的不确定性
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-03 DOI: 10.1140/epjd/s10053-024-00820-y
Alexander Kramida

The present article discusses some recent advances in methods of critical evaluation of experimental data on wavelengths of spectral lines and theoretical data on transition probabilities and oscillator strengths for atoms and atomic ions. In particular, recently developed new statistical approaches to estimation of uncertainties of weighted means of multiple measurements are described, and a numerical toolbox implementing these new approaches is presented. There are also some new developments in estimation of uncertainties of theoretical transition probabilities. A short review of literature implementing these new procedures is provided, including a description of the methodology.

摘要 本文讨论了对原子和原子离子光谱线波长的实验数据以及跃迁概率和振荡器强度的理论数据进行批判性评估的方法方面的一些最新进展。其中特别介绍了最近开发的估算多次测量加权平均值不确定性的新统计方法,并介绍了实现这些新方法的数值工具箱。在估算理论转变概率的不确定性方面也有一些新进展。还对实施这些新程序的文献进行了简短回顾,包括对方法的描述。
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引用次数: 0
Many-body theory calculations of positron binding to hydrogen cyanide 正电子与氰化氢结合的多体理论计算
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-03 DOI: 10.1140/epjd/s10053-024-00810-0
Jaroslav Hofierka, Brian Cunningham, Dermot G. Green

Positron bound state properties in hydrogen cyanide are studied via many-body theory calculations that account for strong positron-electron correlations including positron-induced polarization, screening of the electron–positron Coulomb interaction, virtual-positronium formation and positron–hole repulsion. Specifically, the Dyson equation is solved using a Gaussian basis, with the positron self-energy in the field of the molecule calculated using the Bethe–Salpeter equations for the two-particle and particle–hole propagators. The present results suggest near cancellation of screening corrections to the bare polarization, and the non-negligible role of the positron–hole interaction. There are no existing measurements to compare to for HCN. Previous configuration interaction (CI) and fixed-node diffusion Monte Carlo (FN-DMC) calculations give positron binding energies in the range 35–44 meV, most of which used a single even-tempered basis centred near the nitrogen atom. Using a similar single-centre positron basis we calculate a positron binding energy of 41 meV, in good agreement. However, we find that including additional basis centres gives an improved description of the positron wave function near the nuclei, and results in a converged binding energy in the range 63–73 meV (depending on geometry and approximation to the positron–molecule correlation potential used).

摘要 通过多体理论计算研究了氰化氢中的正电子束缚态特性,这些计算考虑了强正电子-电子相关性,包括正电子诱导的极化、电子-正电子库仑相互作用的屏蔽、虚正电子的形成和正电子-空穴排斥。具体来说,戴森方程是利用高斯基础求解的,分子场中的正电子自能则是利用双粒子和粒子-空穴传播者的贝特-萨尔佩特方程计算的。目前的结果表明,裸极化的筛选修正几乎被取消,正电子-空穴相互作用的作用不可忽略。目前还没有关于 HCN 的测量结果可供比较。之前的构型相互作用(CI)和固定节点扩散蒙特卡洛(FN-DMC)计算得出的正电子结合能在 35-44 meV 之间,其中大部分都使用了以氮原子附近为中心的单偶次基。使用类似的单中心正电子基础,我们计算出的正电子结合能为 41 meV,两者非常吻合。然而,我们发现,加入额外的基中心可以改进对原子核附近正电子波函数的描述,并使结合能趋近于 63-73 meV(取决于几何形状和所使用的正电子-分子关联势近似值)。 图表摘要
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引用次数: 0
Effect of Zr4+ concentration on optical properties and defect structure of Zr:Ho:LiNbO3 crystals Zr4+ 浓度对 Zr:Ho:LiNbO3 晶体光学特性和缺陷结构的影响
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-04-02 DOI: 10.1140/epjd/s10053-024-00819-5
Li Dai, Shuo Shi, Zhipeng Huang, Xianbiao Li

Zr:Ho:LiNbO3 crystals with different concentrations of Zr4+ were prepared by Czochralski method. The internal structure changes and the occupancy of doped ions were analyzed by X-ray diffraction (XRD). The effective segregation coefficient was analyzed by inductively coupled plasma atomic emission spectrometer (ICP-AES), and the optical homogeneity was analyzed by birefringence gradient method. The experimental results show that doping does not change the inherent structure of the crystal, the threshold concentration of Zr4+ is 1 mol%, and the occupation of Zr4+ changes before and after the threshold concentration. The effective separation coefficient of Zr4+ and Ho3+ decreases with the increase of ZrO2 concentration. The optical homogeneity of the crystal will increase with the increase of ZrO2 concentration, and the optical homogeneity of the crystal is strongest when the concentration of ZrO2 reaches the maximum (4 mol%).

Graphical abstract

In this study, a series of Zr:Ho:LiNbO3 crystals of different Zr ions doped concentrations were grown using the Czochralski method. The defect structure of different Zr ions concentrations crystals is analyzed using X-ray diffraction mode. The effects of Zr ions concentrations changes on the concentration of doping elements and the segregation coefficient were investigated using ICP. The optical uniformity of Zr:Ho:LiNbO3 crystals with different concentrations of Zr4+ has been analyzed by birefringence gradient method.

采用 Czochralski 法制备了不同 Zr4+ 浓度的 Zr:Ho:LiNbO3 晶体。通过 X 射线衍射 (XRD) 分析了晶体内部结构的变化和掺杂离子的占有率。电感耦合等离子体原子发射光谱仪(ICP-AES)分析了有效偏析系数,双折射梯度法分析了光学均匀性。实验结果表明,掺杂并不改变晶体的固有结构,Zr4+的阈值浓度为1 mol%,在阈值浓度前后,Zr4+的占有率会发生变化。Zr4+ 和 Ho3+ 的有效分离系数随 ZrO2 浓度的增加而降低。晶体的光学均匀性会随着 ZrO2 浓度的增加而增加,当 ZrO2 浓度达到最大值(4 mol%)时,晶体的光学均匀性最强。图文摘要本研究采用 Czochralski 法生长了一系列不同 Zr 离子掺杂浓度的 Zr:Ho:LiNbO3 晶体。利用 X 射线衍射模式分析了不同 Zr 离子浓度晶体的缺陷结构。使用 ICP 研究了掺杂浓度变化对掺杂元素浓度和偏析系数的影响。利用双折射梯度法分析了不同浓度 Zr4+ 的 Zr:Ho:LiNbO3 晶体的光学均匀性。
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引用次数: 0
Fluorescence molecular tomographic image reconstruction based on the wavelet-Schur decomposition 基于小波-舒尔分解的荧光分子断层图像重建
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-03-28 DOI: 10.1140/epjd/s10053-024-00826-6
Wei Zou

In image reconstruction for fluorescence molecular tomography (FMT), solving matrix equations of large scale can result in high computational costs. In this article, a method based on the wavelet-Schur decomposition is developed. In this method, the reconstruction problem for FMT is solved via the Schur decomposition in the wavelet domain. The proposed method can sufficiently explore the features of wavelet and Schur decomposition. The performance of convergence for reconstruction can be improved based on the proposed method. The results confirm that our method can improve the computational efficiency of reconstruction and achieve the high accuracy of reconstruction.

Graphical abstract

在荧光分子断层成像(FMT)的图像重建中,求解大规模的矩阵方程会导致高昂的计算成本。本文开发了一种基于小波-舒尔分解的方法。在这种方法中,FMT 的重建问题通过小波域中的 Schur 分解来解决。所提出的方法能充分挖掘小波分解和舒尔分解的特点。基于所提出的方法,重构的收敛性能可以得到改善。结果证实,我们的方法可以提高重建的计算效率,实现高精度的重建。
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引用次数: 0
Enhancement of mirror–mirror entanglement with intracavity squeezed light and squeezed-vacuum injection 利用腔内挤压光和挤压真空注入增强镜像-镜像纠缠
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-03-26 DOI: 10.1140/epjd/s10053-024-00825-7
Noura Chabar, M’bark Amghar, Mohamed Amazioug, Mostafa Nassik

In this manuscript, we investigate the enhancement of the transfer of quantum correlations from squeezed light to movable mirrors within an optomechanical system. This enhancement was achieved via the injection of squeezed light in the cavities and via intracavity squeezed light. We quantify the entanglement between mechanical oscillators via logarithmic negativity. We demonstrate that entanglement is influenced by various factors, including the gain of the parametric amplifier, the squeezing parameter characterizing the squeezed light, the rate of the phonon tunneling process, the coupling strength of the photon hopping process and the bath temperature of the mechanical oscillators. We have shown that entanglement can be improved by a convenient choice of coupling strength in the case of the photon hopping process, as well as for specified values of the gain of the parametric amplifier.

摘要 在这篇手稿中,我们研究了如何在光学机械系统中增强从挤压光到可移动反射镜的量子相关性传递。这种增强是通过向腔内注入挤压光和腔内挤压光实现的。我们通过对数负性来量化机械振荡器之间的纠缠。我们证明,纠缠受多种因素的影响,包括参量放大器的增益、表征挤压光的挤压参数、声子隧道过程的速率、光子跳跃过程的耦合强度以及机械振荡器的浴温。我们已经证明,在光子跳变过程中,通过方便地选择耦合强度,以及参数放大器增益的特定值,可以改善纠缠。
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引用次数: 0
Polarization of recoil photon in nonlinear Compton process 非线性康普顿过程中反冲光子的偏振
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2024-03-25 DOI: 10.1140/epjd/s10053-024-00827-5
A. I. Titov

The polarization of recoil photon ((gamma ')) in the nonlinear Compton process (e + vec L rightarrow vec {gamma }' +e') in the interaction of a relativistic electron with a linearly polarized laser beam ((vec L)) is studied within the Furry picture in the lowest order, tree-level S matrix element. In particular, we consider the asymmetry of differential cross sections (mathcal{A}) for two independent axes describing the Compton process equal to the intrinsic spin variable ({xi }^f_3) that determines the polarization properties of (gamma '). The sign and absolute value of the asymmetry determine the direction and degree of (gamma ') polarization. We have analyzed the process in a wide range of laser intensity that covers existing and future experiments. Our results provide additional knowledge for studying nonlinear multi-photon effects in quantum electrodynamics and can be used in planning experiments at envisaged laser facilities.

特别是,我们考虑了描述康普顿过程的两个独立轴的微分截面 (mathcal{A}) 的不对称性,它等于决定 (gamma ') 偏振特性的本征自旋变量 ({xi }^f_3) 。不对称的符号和绝对值决定了 (gamma ') 极化的方向和程度。我们分析了激光强度范围广泛的过程,涵盖了现有和未来的实验。我们的结果为研究量子电动力学中的非线性多光子效应提供了额外的知识,并可用于规划设想中的激光设施的实验。 图表摘要
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引用次数: 0
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The European Physical Journal D
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