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Roadmap on carbon molecular nanostructures in space 空间碳分子纳米结构路线图
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-08-04 DOI: 10.1140/epjd/s10053-025-00984-1
Klavs Hansen, D. A. García-Hernández, E. E. B. Campbell, Dogan Erbahar, Alicja Domaracka, Cornelia Jäger, C. Ewels, Polona Umek, S. Kwok, E. Peeters, J. Cami, Greg C. Sloan, P. Ehrenfreund, H. Linnartz, A. Manchado, Nick L. J. Cox, J. Bernard-Salas, E. K. Campbell, A. Monreal-Ibero, B. H. Foing, J. Smoker, M. Elyajouri, A. Ebenbichler, J. Th. van Loon, J. Bouwman, A. Farhang, F. Salama, C. Joblin, G. Mulas, U. Jacovella, M. A. Gómez-Muñoz, R. Barzaga, T. Huertas-Roldán, Hugh Mohan, Michał Bartkowski, Silvia Giordani, Gao-Lei Hou, J. J. Díaz-Luis, J. Alcolea, D. Tafoya, V. Bujarrabal, N. Došlić, T. Došlić, E. Catalano, M. Yesiltas, P. Ferrari, S. Brünken, G. Berden, J. M. Bakker, J. Oomens, B. Redlich, A. Pitanti, B. Bertoni, L. Vicarelli, P. Lamberti, M. Cojocari, G. Fedorov, Yu. Svirko, P. Kuzhir, M. Hochlaf, M. Mogren Al Mogren, Alexey Potapov, Eftal Gezer, H. Zettergren, H. T. Schmidt, Mark H. Stockett, Eleanor K. Ashworth, James N. Bull, M. Fárník, T. Wakabayashi, L. Ganner, M. Kappe, E. Gruber, C. Pardanaud, J. Dezalay, J. A. Noble, K. Tőkési, Z. Li, X. H. Zhou, J. M. Gong, R. G. Zeng, Z. J. Ding, Clayton S.-C. Yang, Feng Jin, Sudhir Trivedi, Uwe Hommerich, Laszlo Nemes, Alan C. Samuels, G. Shmavonyan, L. Misakyan, A. Shmavonyan, I. Sciriha, S. Suriyaprasanth, Dhanoj Gupta, D. A. Kalchevski, D. Trifonov, S. Kolev, T. Milenov, Miguel A. Caro, SeyedAbdolreza Sadjadi, Quentin Andrew Parker, A. Lombardi, Martin McCoustra, F. Koch, I. Schubert, C. Trautmann, M. E. Toimil-Molares, B. Kerkeni, D. Talbi, C. P. Hsu, G. Ouerfelli, H. H. Chuang, Ko-Ju Chuang, Yu-Jung Chen, E. Villaver, M. Manteiga

In this roadmap article, we consider the main challenges and recent breakthroughs in understanding the role of carbon molecular nanostructures in space and propose future avenues of research. The focus lies on small carbon-containing molecules up to fullerenes, extending to even larger, more complex organic species. The roadmap contains forty contributions from scientists with leading expertise in observational astronomy, laboratory astrophysics/chemistry, astrobiology, theoretical chemistry, synthetic chemistry, molecular reaction dynamics, material science, spectroscopy, graph theory, and data science. The concerted interdisciplinary combination of the state-of-the-art of these astronomical, laboratory, and theoretical studies opens up new ways to advance the fundamental understanding of the physics and chemistry of cosmic carbon molecular nanostructures and touches on their wider relevance and impact in nanotechnology and catalysis.

A collection of carbon atoms on the road to a fullerene

在这篇路线图文章中,我们考虑了理解碳分子纳米结构在空间中的作用的主要挑战和最近的突破,并提出了未来的研究途径。研究的重点是小到富勒烯的含碳分子,然后扩展到更大、更复杂的有机物种。该路线图包含40位科学家的贡献,他们在观测天文学、实验室天体物理学/化学、天体生物学、理论化学、合成化学、分子反应动力学、材料科学、光谱学、图论和数据科学方面具有领先的专业知识。这些最先进的天文学、实验室和理论研究的协调跨学科结合,为推进对宇宙碳分子纳米结构的物理和化学的基本理解开辟了新的途径,并触及了它们在纳米技术和催化方面更广泛的相关性和影响。在通往富勒烯的路上的碳原子集合
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引用次数: 0
Theoretical spectroscopic analysis of (hbox {W}^{27+})-(hbox {W}^{29+}) ions using collisional-radiative modeling and relativistic atomic structure calculations 利用碰撞辐射模型和相对论原子结构计算对(hbox {W}^{27+}) - (hbox {W}^{29+})离子进行理论光谱分析
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-08-04 DOI: 10.1140/epjd/s10053-025-01042-6
Yanlan Xu, Xiaobin Ding, Cunqiang Wu, Denghong Zhang, Ling Zhang, Fengling Zhang, Chenzhong Dong

The transition wavelengths and transition rates of (hbox {W}^{27+}), (hbox {W}^{28+}) and (hbox {W}^{29+}) ions in the 45-65 Å range have been calculated using the flexible atomic code (FAC) package based on the Dirac–Fock–Slater (DFS) method with central potential. By considering a reasonable rate equation, the charge state distributions of (hbox {W}^{27+})-(hbox {W}^{29+}) ions at different electron temperatures were investigated, and the importance of the dielectronic recombination process in the charge state equilibrium was found. In addition, the emission spectra of (hbox {W}^{27+})-(hbox {W}^{29+}) ions in the 45-65 Å in the EAST Tokamak plasma were simulated using a collisional-radiative model. The synthetic spectra show good agreement with the observed in the experiment. Finally, for the diagnostic needs of plasma, some transition pairs that can be used as diagnostic lines are proposed based on the intensity ratio of the transition pair with respect to the electron temperature and density.

采用基于中心电位Dirac-Fock-Slater (DFS)方法的柔性原子码(FAC)包计算了45 ~ 65 Å范围内(hbox {W}^{27+})、(hbox {W}^{28+})和(hbox {W}^{29+})离子的跃迁波长和跃迁速率。考虑合理的速率方程,研究了(hbox {W}^{27+}) - (hbox {W}^{29+})离子在不同电子温度下的电荷态分布,发现介电子复合过程在电荷态平衡中的重要性。此外,利用碰撞辐射模型模拟了EAST托卡马克等离子体45-65 Å中(hbox {W}^{27+}) - (hbox {W}^{29+})离子的发射光谱。合成光谱与实验结果吻合较好。最后,针对等离子体的诊断需要,根据跃迁对的强度与电子温度和密度的比值,提出了一些可以作为诊断线的跃迁对。
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引用次数: 0
A generalized formulation of two-particle interference 双粒子干涉的一个广义公式
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-08-04 DOI: 10.1140/epjd/s10053-025-01043-5
Kamran Nazir, Tabish Qureshi

Two-photon interference is an interesting quantum phenomenon that is usually captured in two distinct types of experiments, namely the Hanbury Brown–Twiss (HBT) experiment and the Hong–Ou–Mandel (HOM) experiment. While the HBT experiment was carried out much earlier in 1956, with classical light, the demonstration of the HOM effect came much later in 1987. Unlike the former, the latter has frequently been argued to be a purely quantum effect. A generalized formulation of two-particle interference is presented here. The HOM and the quantum HBT effects emerge as special cases in the general analysis. A realizable two-particle interference experiment, which is intermediate between the two effects, is proposed and analyzed. Thus two-particle interference is shown to be a single phenomenon with various possible implementations, including the HBT and HOM setups.

In the generalized view of two-particle interference, independent particles from sources A and B are split into n common channels by the path splitter, and then arrive at detectors (D_1) to (D_n).

双光子干涉是一种有趣的量子现象,通常在两种不同类型的实验中被捕获,即Hanbury Brown-Twiss (HBT)实验和Hong-Ou-Mandel (HOM)实验。虽然HBT实验早在1956年就在经典光下进行了,但HOM效应的演示在1987年晚得多。与前者不同,后者经常被认为是纯粹的量子效应。本文给出了双粒子干涉的一个广义公式。HOM和量子HBT效应在一般分析中是作为特殊情况出现的。提出并分析了介于这两种效应之间的一种可实现的双粒子干涉实验。因此,双粒子干涉被证明是一种单一的现象,具有各种可能的实现,包括HBT和HOM设置。在双粒子干涉的广义观点中,来自源A和源B的独立粒子被分路器分割成n个公共通道,然后到达探测器(D_1)到(D_n)。
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引用次数: 0
Elimination of spurious oscillations on photoemission spectra 光发射光谱上杂散振荡的消除
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-08-03 DOI: 10.1140/epjd/s10053-025-01036-4
Martín Barlari, Diego G. Arbó, María Silvia Gravielle, Darío M. Mitnik

We present a method for accurately computing transition probabilities in one-dimensional photoionization problems. Our approach involves solving the time-dependent Schrödinger equation and projecting its solution onto scattering states that satisfy the correct incoming or outgoing boundary conditions. Conventionally, the photoelectron emission spectrum is obtained by projecting the time-evolved wave function onto the stationary continuum eigenstates of the unperturbed, time-independent Hamiltonian. However, when the spatial potential is symmetric, both the initial bound state and the final continuum states exhibit well-defined parity. The propagated wave function retains structural features of the initial bound state, including its parity. As a result, changes in the parity of the continuum states can introduce substantial variations in the projections, leading to spurious oscillations in the computed electron emission spectrum. Our method circumvents this issue by employing scattering states without defined parity. Furthermore, it enables the calculation of directional emission, making it possible to study emission asymmetries. To illustrate the capabilities of our scattering projection method, we analyze the partial differential photoionization probabilities of Al(111) metallic surfaces under short laser pulses at grazing incidence.

Photoelectron spectrum of an aluminum surface. The conventional projection method (thin brown solid line) produces a highly oscillatory spectrum. Smoothing via the standard convolution method (window operator, thick green solid line) results in over-smoothing, eliminating genuine physical oscillations that our method correctly preserves (thick red line).

我们提出了一种精确计算一维光电离问题中跃迁概率的方法。我们的方法包括求解与时间相关的Schrödinger方程,并将其解投影到满足正确的入射或出射边界条件的散射状态上。传统上,光电子发射谱是通过将随时间变化的波函数投射到平稳连续统的无摄动、与时间无关的哈密顿量的特征态来获得的。然而,当空间势是对称的时,初始束缚态和最终连续态都表现出明确的宇称。传播波函数保留了初始束缚态的结构特征,包括其宇称。因此,连续态宇称的变化会引起投影的实质性变化,从而导致计算出的电子发射谱出现伪振荡。我们的方法通过使用没有定义宇称的散射态来规避这个问题。此外,它可以计算定向发射,使研究发射不对称成为可能。为了说明我们的散射投影方法的能力,我们分析了短激光脉冲在掠射入射下Al(111)金属表面的偏微分光离概率。铝表面的光电子能谱。传统的投影方法(细棕色实线)产生高度振荡的频谱。通过标准卷积方法(窗口算子,粗绿色实线)进行平滑会导致过度平滑,消除了我们的方法正确保留的真正的物理振荡(粗红线)。
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引用次数: 0
Electron impact processes for TiClx and CFx (x = 1 − 4) TiClx和CFx (x = 1−4)的电子冲击过程
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-08-02 DOI: 10.1140/epjd/s10053-025-01041-7
Rakesh Bhavsar, Yogesh Thakar, Neha Barad, Minaxi Vinodkumar, Chetan Limbachiya

In the present work, we studied electron-assisted molecular processes for plasma feed gases, TiClx and CFx (x = 1 − 4). These radicals and their parent molecules are of great interest due to their importance for developing plasma reactors and other industrial applications. It is imminent to study charge transport for these molecules to model various phenomena involving ionization. We have calculated total ionization ((Q_{{{text{ion}}}})), elastic ((Q_{{{text{el}}}})), and total ((Q_{{{text{tot}}}})) cross sections using the quantum spherical complex optical potential (SCOP) formalism aided with the complex scattering potential–ionization contribution (CSP-ic) method. The present results are the first report for TiClx (x = 1 − 3) radicals in this work.

Graphical Abstract

Partial and total ionization

在本研究中,我们研究了等离子体原料气TiClx和CFx (x = 1−4)的电子辅助分子过程。由于这些自由基及其母分子在等离子体反应器和其他工业应用中的重要性,它们引起了人们的极大兴趣。研究这些分子的电荷输运以模拟各种电离现象已迫在眉睫。我们已经计算了总电离((Q_{{{text{ion}}}})),弹性((Q_{{{text{el}}}}))和总((Q_{{{text{tot}}}}))截面使用量子球面复光势(SCOP)形式辅助复散射势-电离贡献(CSP-ic)方法。本研究结果是首次报道TiClx (x = 1−3)自由基。图解:部分和全部电离
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引用次数: 0
Arbitrary amplitude dust ion acoustic soliton in dusty plasmas with regularized kappa distributed electrons 具有正则卡帕分布电子的尘埃等离子体中的任意振幅尘埃离子声孤子
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-07-28 DOI: 10.1140/epjd/s10053-025-01014-w
Na-Na Wei, Yong Liu

Arbitrary amplitude dust ion acoustic solitons (DIASs) in plasma consisting of positive ions, regularized kappa distributed electrons and negatively charged dust grains have been investigated by the Sagdeev pseudopotential method. It is found that negative DIASs exist only in a certain range of spectral index (kappa ) and cutoff parameter (alpha ), which increases with the electron concentration. Correspondingly, the region of (kappa ) and (alpha ) for the coexistence of negative and positive DIASs shrinks. In addition, the velocity of soliton decreases with increasing (alpha ) and electron concentration (sigma ), regardless of soliton polarity. On the other hand, the width of positive DIASs decreases with the increase of (kappa ), whereas the one negative solitons take an opposite way. Moreover, the width of DIASs varies non-monotonous with respect to the cutoff parameter. Based on the parameters within Saturn’s magnetosphere, the strength of the electric field with DIAS can explain the observations made within Saturn’s magnetosphere. The present investigation may be useful in the understanding of the properties of localized nonlinear electrostatic structure in space dusty plasma with nonthermal electrons.

用Sagdeev赝势方法研究了由正离子、正规化kappa分布电子和带负电荷的尘埃颗粒组成的等离子体中的任意振幅尘埃离子声孤子。发现负dias仅在一定的谱指数(kappa )和截止参数(alpha )范围内存在,且随电子浓度的增大而增大。相应的,负、正DIASs共存的(kappa )和(alpha )区域缩小。此外,与孤子极性无关,孤子的速度随(alpha )和电子浓度(sigma )的增加而减小。另一方面,正孤子宽度随(kappa )的增大而减小,而负孤子宽度则相反。此外,dias的宽度相对于截止参数呈非单调变化。基于土星磁层内的参数,DIAS的电场强度可以解释土星磁层内的观测结果。本文的研究有助于理解含非热电子的空间尘埃等离子体中局域非线性静电结构的性质。
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引用次数: 0
Ion transport properties of ({mathbf{C}mathbf{O}}^{+}) ions in helium gas at low temperatures: a comparative study of two computational methods 低温下氦气中({mathbf{C}mathbf{O}}^{+})离子的输运性质:两种计算方法的比较研究
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-07-27 DOI: 10.1140/epjd/s10053-025-01037-3
Imane Ghodbane, Lamia Aissaoui

To understand ion transport properties, such as ion mobility, using the classical approach of diatomic ions in atomic gas at low temperatures, we employed two methods to calculate the mobility of ({text{CO}}^{+}) ions in helium gas. Both methods are performed using the ab initio potential energy surfaces provided by Gharibi et al. We used the modified version of Monchick–Mason approximation MMA2 to calculate the effective transport cross sections and effective potentials. The results obtained are compared with the available experimental data.

Graphical abstract

Comparison of effective cross-section MMA2Q and effective potential MMA2V non-zero-field mobilities K_0 of ({text{CO}}^{+}) ions in He gas with experimental data, at T=300 K as a function of E/N. The solid line is obtained from the effective cross-section MMA2Q, the dashed line is from the effective potential MMA2V, and the solide circle with error bars corresponds to experimental data. The horizontal line indicate the polarization limit (K_{(pol)}=16.35;{rm{cm}}^2 V^(-1) s^(-1).)

为了理解低温下原子气体中双原子离子的传输特性(如离子迁移率),我们采用两种方法计算了({text{CO}}^{+})离子在氦气中的迁移率。这两种方法都是使用Gharibi等人提供的从头算势能面来执行的。我们使用改进版的Monchick-Mason近似MMA2计算了有效输运截面和有效势。所得结果与现有实验数据进行了比较。图摘要He气中({text{CO}}^{+})离子在T=300 K时有效横截面MMA2Q和有效势MMA2V非零场迁移率K_0与实验数据的比较实线为有效截面MMA2Q,虚线为有效电位MMA2V,带误差条的实圆为实验数据。水平线表示极化极限 (K_{(pol)}=16.35;{rm{cm}}^2 V^(-1) s^(-1).)
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引用次数: 0
Bipartite entropic uncertainty and entanglement dynamics in triangular qubit spin networks under irregular magnetic fields with intrinsic decoherence 具有本征退相干的不规则磁场下三角形量子自旋网络的二部熵不确定性和纠缠动力学
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-07-25 DOI: 10.1140/epjd/s10053-025-01038-2
H. Allhibi, A. N. Khedr, F. Aljuaydi, A.-B. A. Mohamed

Motivated by the prospect of triangular spin cells for quantum information processing, we propose a model featuring spin–orbit interactions on the rungs and magnetic field effects along the legs. Quantum memory can enhance measurement precision for two incompatible observables in the physical system. In this work, we have examined the dynamics of entropic uncertainty and pairwise entanglement for a system of three-spin ( -1/2 ) particles interacting with a quantum memory in the presence of intrinsic decoherence and a non-uniform magnetic field. We employ logarithmic negativity to measure entanglement and study its evolution in a non-uniform magnetic field and decoherence. In addition, we examine and evaluate the operation of the entropic uncertainty relation for non-commuting observables in the three-spin system, analyzing its behavior under identical circumstances. According to the study, entropic uncertainty increases and entanglement decays due to intrinsic decoherence, whereas non-uniform magnetic fields produce complex entanglement patterns. Notably, entanglement and entropic uncertainty can display synchronized oscillatory behavior in specific situations, indicating possible approaches to alleviate decoherence in quantum memories. The fundamental characteristics and constraints of quantum memories are better understood thanks to this work, which also highlights how crucial it is to consider realistic environmental effects when creating quantum technologies.

考虑到三角自旋细胞用于量子信息处理的前景,我们提出了一种基于阶梯上的自旋轨道相互作用和沿腿的磁场效应的模型。量子存储器可以提高物理系统中两个不相容观测量的测量精度。在这项工作中,我们研究了在本征退相干和非均匀磁场存在下与量子存储器相互作用的三自旋( -1/2 )粒子系统的熵不确定性和成对纠缠动力学。我们采用对数负性来测量纠缠,并研究其在非均匀磁场和退相干中的演变。此外,我们考察和评价了三自旋系统中非交换观测值的熵不确定性关系的运作,分析了其在相同情况下的行为。根据研究,由于本征退相干,熵不确定性增加,纠缠衰减,而非均匀磁场产生复杂的纠缠模式。值得注意的是,纠缠和熵不确定性在特定情况下可以显示同步振荡行为,这表明了减轻量子存储器退相干的可能方法。由于这项工作,量子存储器的基本特征和限制得到了更好的理解,这也突出了在创造量子技术时考虑现实环境影响的重要性。
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引用次数: 0
Performance of silicon photomultipliers from room temperature to below 200 mK 室温至200 mK以下硅光电倍增管的性能
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-07-25 DOI: 10.1140/epjd/s10053-025-01034-6
Otto Hanski, Tom Kiilerich, Sampsa Ahopelto, Aleksei Semakin, Janne Ahokas, Viacheslav Dvornichenko, Sergey Vasiliev

We present experimental results of characterization of Silicon photomultipliers (SiPM) in a temperature range from 90 mK to 40 K and compare them to room-temperature results. Two SiPMs, one from ONSEMI and one from Hamamatsu Photonics, were tested. Operating voltage ranges, dark count rates, afterpulsing effects and photon detection efficiencies (PDE) were determined with illumination by 275- and 470-nm light fed into the cryostat via an optical fiber. A cryogenic shutter provided a true dark condition, where thermal radiation from room temperature is shielded and the thermal excitations in the chips are frozen. A second tunneling breakdown was observed at this condition, which substantially limits the operating voltage range for the temperatures 20–30 K. Below (sim )5 K, both SiPMs recover to an operating overvoltage range of 3–5 V. We found the chips function through the entire tested temperature range and are capable of withstanding thermal cycling with no major performance degradation.

本文介绍了硅光电倍增管(SiPM)在90 mK至40 K温度范围内的表征实验结果,并将其与室温结果进行了比较。测试了两个sipm,一个来自ONSEMI,一个来自Hamamatsu Photonics。工作电压范围、暗计数率、后脉冲效应和光子探测效率(PDE)在275 nm和470 nm光照射下通过光纤输入低温恒温器。低温百叶窗提供了一个真正的黑暗条件,在这里,来自室温的热辐射被屏蔽,芯片中的热激发被冻结。在此条件下观察到第二次隧道击穿,这实质上限制了温度为20-30 K的工作电压范围。在(sim ) 5 K以下,两个sipm恢复到3-5 V的工作过电压范围。我们发现芯片在整个测试温度范围内都能正常工作,并且能够承受热循环而不会出现重大性能下降。
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引用次数: 0
Topological rainbow trapping in gradient photonic structure for terahertz band 太赫兹波段梯度光子结构中的拓扑彩虹捕获
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-07-25 DOI: 10.1140/epjd/s10053-025-01033-7
Wenwen Wang, Yun Shen, Huichang Li, Xiaohua Deng

The integration of topological principles with rainbow trapping techniques presents a transformative approach in photonic device design, particularly in developing photonic topological rainbow based on quantum Hall effect. In this paper, we propose a quantum spin Hall photonic crystal with gradient radius of circles to achieve topological rainbow trapping, demonstrating trapping effect within topological edge states through fine-tuning. Theoretical and numerical analyses show that the topological rainbow is capable of capturing photonic states across a range of frequencies. Moreover, by modulating the group velocity of the edge states, we can effectively direct the path of light propagation, enabling selective light trapping within specific regions. The strategy outlined in this study offers a universal approach to topological rainbow trapping, which is anticipated to significantly advance the research and development in the domain of topological photonic devices.

Graphical abstract

将拓扑原理与彩虹捕获技术相结合,为光子器件的设计,特别是基于量子霍尔效应的光子拓扑彩虹的开发提供了一种革命性的方法。本文提出了一种具有梯度圆半径的量子自旋霍尔光子晶体来实现拓扑彩虹捕获,并通过微调在拓扑边缘态内展示了捕获效应。理论和数值分析表明,拓扑彩虹能够在一定频率范围内捕获光子态。此外,通过调制边缘状态的群速度,我们可以有效地指导光的传播路径,在特定区域内实现选择性的光捕获。本研究概述的策略为拓扑彩虹捕获提供了一种通用的方法,有望显著推进拓扑光子器件领域的研究和发展。图形抽象
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引用次数: 0
期刊
The European Physical Journal D
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