Pub Date : 2025-06-30DOI: 10.1140/epjd/s10053-025-01023-9
Debasish Parida, Jiakuan Chen, Lara Schorr, Vy T. T. Nguyen, Muhammad Saqib, Andreas Bayer, Fabio Zappa, Stephan Denifl
In the present study we investigated electron attachment to the nucleoside thymidine (Td) and the nucleobase guanine (G) using a laser desorption source to transfer the compounds into the gas phase. Previous studies with Td indicated that the compound is thermally labile and may degrade upon thermal heating in standard molecular beam source. The present negative ion mass spectra for laser-desorbed Td and resistively heated Td share the same most three abundant fragment anions. Among those is the dehydrogenated parent anion (Td-H)− which is strongly enhanced for laser-desorbed Td. We also find a considerable change of the fragmentation pattern for less abundant peaks in the mass spectra as well as changed characteristic in the total and mass selected anion efficiency curves of fragment anions. Electron attachment to G proceeds predominantly at electron energies below 3 eV. We ascribe this property to formation of a dipole-bound anion acting as a precursor state for efficient formation of the dehydrogenated anion (G-H)−. The present results complement previous electron attachment studies with other nucleobases showing that the dehydrogenated parent anion is the most abundant fragment anion for G as well.
{"title":"Electron interaction with laser-desorbed thymidine and guanine in the gas phase","authors":"Debasish Parida, Jiakuan Chen, Lara Schorr, Vy T. T. Nguyen, Muhammad Saqib, Andreas Bayer, Fabio Zappa, Stephan Denifl","doi":"10.1140/epjd/s10053-025-01023-9","DOIUrl":"10.1140/epjd/s10053-025-01023-9","url":null,"abstract":"<p>In the present study we investigated electron attachment to the nucleoside thymidine (Td) and the nucleobase guanine (G) using a laser desorption source to transfer the compounds into the gas phase. Previous studies with Td indicated that the compound is thermally labile and may degrade upon thermal heating in standard molecular beam source. The present negative ion mass spectra for laser-desorbed Td and resistively heated Td share the same most three abundant fragment anions. Among those is the dehydrogenated parent anion (Td-H)<sup>−</sup> which is strongly enhanced for laser-desorbed Td. We also find a considerable change of the fragmentation pattern for less abundant peaks in the mass spectra as well as changed characteristic in the total and mass selected anion efficiency curves of fragment anions. Electron attachment to G proceeds predominantly at electron energies below 3 eV. We ascribe this property to formation of a dipole-bound anion acting as a precursor state for efficient formation of the dehydrogenated anion (G-H)<sup>−</sup>. The present results complement previous electron attachment studies with other nucleobases showing that the dehydrogenated parent anion is the most abundant fragment anion for G as well.</p>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12208974/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144556129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-06-30DOI: 10.1140/epjd/s10053-025-01020-y
W. Sakhraoui, I. Kada, A. Mansouri, C. Dal Cappello
We report new investigations for the five differential cross section (FDCS) of the double ionization of methane by fast electron impact. The present study is performed within the first and second Born approximation. The target initial state is described by a single-center wave function of Moccia, while we represent the final state by using the approximate 3C model with the usual Gamow factor then with the Ward and Macek factor as a corrected version. The different mechanisms have been identified for specific kinematic conditions.
{"title":"Second Born approximation for the double ionization of methane by electron impact: a study of the different mechanisms","authors":"W. Sakhraoui, I. Kada, A. Mansouri, C. Dal Cappello","doi":"10.1140/epjd/s10053-025-01020-y","DOIUrl":"10.1140/epjd/s10053-025-01020-y","url":null,"abstract":"<div><p>We report new investigations for the five differential cross section (FDCS) of the double ionization of methane by fast electron impact. The present study is performed within the first and second Born approximation. The target initial state is described by a single-center wave function of Moccia, while we represent the final state by using the approximate 3C model with the usual Gamow factor then with the Ward and Macek factor as a corrected version. The different mechanisms have been identified for specific kinematic conditions.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145145260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-06-28DOI: 10.1140/epjd/s10053-025-01028-4
M. Hoshino, J. Kim, M. Matsukuma
We report on the absolute excitation cross sections of the lowest-lying optically allowed transitions in difluoromethane (CH2F2) molecules at intermediate impact energies between 100 and 400 eV and for scattering angles of 1.5° to 15°. The energy loss ranges from 8.5 to 11 eV, which has been assigned as the optically allowed 3s ← 2b2 and 3p ← 2b2 overlapping with the dipole-forbidden 11A2 ← X1A1 excitations. The absolute scale of the corresponding cross sections is obtained by normalizing the angular distributions of inelastically scattered electrons to the absolute excitation differential cross section (DCS) of He as the reference. The excitation integral cross sections (ICSs) for these excitations obtained by the generalized oscillator strength analysis are in reasonable agreement with the corresponding BE-scaled ICSs derived recently at an impact energy of 1500 eV within the experimental uncertainties. The absolute measurement suggested that the BE-scaling law is experimentally confirmed to be quite useful for CH2F2 molecules even at intermediate electron energies.
{"title":"Quantitative measurement of the excitation cross section for the lowest-lying optically allowed transitions in difluoromethane molecules by electron impact: verification of the BE-scaled cross section in the intermediate-energy region","authors":"M. Hoshino, J. Kim, M. Matsukuma","doi":"10.1140/epjd/s10053-025-01028-4","DOIUrl":"10.1140/epjd/s10053-025-01028-4","url":null,"abstract":"<div><p>We report on the absolute excitation cross sections of the lowest-lying optically allowed transitions in difluoromethane (CH<sub>2</sub>F<sub>2</sub>) molecules at intermediate impact energies between 100 and 400 eV and for scattering angles of 1.5° to 15°. The energy loss ranges from 8.5 to 11 eV, which has been assigned as the optically allowed 3<i>s</i> ← 2b<sub>2</sub> and 3<i>p</i> ← 2b<sub>2</sub> overlapping with the dipole-forbidden 1<sup>1</sup>A<sub>2</sub> ← X<sup>1</sup>A<sub>1</sub> excitations. The absolute scale of the corresponding cross sections is obtained by normalizing the angular distributions of inelastically scattered electrons to the absolute excitation differential cross section (DCS) of He as the reference. The excitation integral cross sections (ICSs) for these excitations obtained by the generalized oscillator strength analysis are in reasonable agreement with the corresponding BE-scaled ICSs derived recently at an impact energy of 1500 eV within the experimental uncertainties. The absolute measurement suggested that the BE-scaling law is experimentally confirmed to be quite useful for CH<sub>2</sub>F<sub>2</sub> molecules even at intermediate electron energies.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145145564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-06-28DOI: 10.1140/epjd/s10053-025-01025-7
Pranaya Pratik Das, Biplab Ganguli
Out-of-Time-Order Correlator (OTOC) and Loschmidt Echo (LE) are commonly regarded as diagnostic tools for chaos, although they may yield misleading results, as we observe. Previous studies have concluded that OTOC shows exponential growth in the neighbourhood of a local maximum. If this statement holds true, the exponential growth should break off once the local maximum is no longer present within the system. By applying a small symmetry-breaking perturbation, we notice that the behaviour of the OTOCs remains remarkably resilient even in the absence of a maximum. Besides this, we also notice that with the increase in perturbation strength, the broken symmetric region expands, causing a broader range of eigenstates to engage in the exponential growth of OTOCs. Therefore, the critical factor lies not in the presence of a local maximum, but in the dynamic nature of the density of states in the broken symmetry regions. Our examination, spanning diverse one- dimensional potential landscapes, reveals the universality of this phenomenon. We also use other chaos diagnostic tool, LE. Interestingly, it also gives a false signal of chaos.
{"title":"Out-of-Time-Order Correlation in perturbed quantum wells","authors":"Pranaya Pratik Das, Biplab Ganguli","doi":"10.1140/epjd/s10053-025-01025-7","DOIUrl":"10.1140/epjd/s10053-025-01025-7","url":null,"abstract":"<p><i>Out-of-Time-Order Correlator</i> (OTOC) and <i>Loschmidt Echo</i> (LE) are commonly regarded as diagnostic tools for chaos, although they may yield misleading results, as we observe. Previous studies have concluded that OTOC shows exponential growth in the neighbourhood of a local maximum. If this statement holds true, the exponential growth should break off once the local maximum is no longer present within the system. By applying a small symmetry-breaking perturbation, we notice that the behaviour of the OTOCs remains remarkably resilient even in the absence of a maximum. Besides this, we also notice that with the increase in perturbation strength, the broken symmetric region expands, causing a broader range of eigenstates to engage in the exponential growth of OTOCs. Therefore, the critical factor lies not in the presence of a local maximum, but in the dynamic nature of the density of states in the broken symmetry regions. Our examination, spanning diverse one- dimensional potential landscapes, reveals the universality of this phenomenon. We also use other chaos diagnostic tool, LE. Interestingly, it also gives a false signal of chaos.\u0000</p>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145145563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this study, we present experimentally determined transition probabilities of 86 singly ionized cerium emission lines. We used a widely employed spectroscopic technique, laser-induced breakdown spectroscopy (LIBS), to measure the transition probabilities considering the great demand for experimentally determined atomic data. In astrophysics, cerium is a significant element of interest, especially when examining kilonova emissions that are observed following the merging of two neutron stars. The experimental data are compared with previously reported data.
{"title":"Experimental transition probabilities of singly ionized cerium using laser-induced breakdown spectroscopy (LIBS)","authors":"Supriya Kodangil, Masaomi Tanaka, Daiji Kato, Gediminas Gaigalas, Hajime Tanuma, Nobuyuki Nakamura","doi":"10.1140/epjd/s10053-025-01027-5","DOIUrl":"10.1140/epjd/s10053-025-01027-5","url":null,"abstract":"<div><p>In this study, we present experimentally determined transition probabilities of 86 singly ionized cerium emission lines. We used a widely employed spectroscopic technique, laser-induced breakdown spectroscopy (LIBS), to measure the transition probabilities considering the great demand for experimentally determined atomic data. In astrophysics, cerium is a significant element of interest, especially when examining kilonova emissions that are observed following the merging of two neutron stars. The experimental data are compared with previously reported data.\u0000</p></div>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2025-06-24DOI: 10.1140/epjd/s10053-025-01019-5
Suleyman Yilmaz
In this study, it is aimed to draw attention to the environmental problem and air pollution, which are the most important components of sustainable development for the new century. An appropriate model has been developed to determine the light scattering of axisymmetric particles in the suspension, which is the source of airborne pollution, with numerical calculations. In this axisymmetric model developed for aerosol composition, the distribution of light intensity has been calculated using optical parameters. Thus, light scattering has been obtained for different absorbance and dielectric parameters of inhomogeneous particles. The correlation between the absorbance of the sample and the pollution defining the molecular density has been characterized with the data obtained from the change of scattering intensity according to the azimuth angle in the sample geometry. In the axisymmetric model designed for numerical calculations, standard scattering intensity data have been obtained for future calculations for different absorbed and non-absorbed environments according to the calculated light intensities.
{"title":"Investigation of air pollution in India in terms of climate change and ecological environment problem with optical methods","authors":"Suleyman Yilmaz","doi":"10.1140/epjd/s10053-025-01019-5","DOIUrl":"10.1140/epjd/s10053-025-01019-5","url":null,"abstract":"<p>In this study, it is aimed to draw attention to the environmental problem and air pollution, which are the most important components of sustainable development for the new century. An appropriate model has been developed to determine the light scattering of axisymmetric particles in the suspension, which is the source of airborne pollution, with numerical calculations. In this axisymmetric model developed for aerosol composition, the distribution of light intensity has been calculated using optical parameters. Thus, light scattering has been obtained for different absorbance and dielectric parameters of inhomogeneous particles. The correlation between the absorbance of the sample and the pollution defining the molecular density has been characterized with the data obtained from the change of scattering intensity according to the azimuth angle in the sample geometry. In the axisymmetric model designed for numerical calculations, standard scattering intensity data have been obtained for future calculations for different absorbed and non-absorbed environments according to the calculated light intensities.</p>","PeriodicalId":789,"journal":{"name":"The European Physical Journal D","volume":"79 6","pages":""},"PeriodicalIF":1.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Traditional ghost image (GI) relies on the intensity fluctuation correlation between the reference beam and the object beam. In this paper, a novel analysis for characteristic recognition ghost imaging (CRGI) is proposed based on characteristic classification of the light field, which indicates that GI can be considered as the superposition of ghost images with different characteristic information. The analytical results show that the reconstructed images of GI by processing the reference light are identical to that by processing the object light, which make it possible to utilize the prefabricated reference light to recognize the target characteristic in the imaging process. Moreover, the distinction between targets can be clearly identified by CRGI when the difference of characteristic information is quite slight, while it is difficult to be distinguished in traditional GI. Our results not only provide a new method for real-time characteristic recognition, but also promote the development of GI technology in fields such as medical imaging and security systems.