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Electron interaction with laser-desorbed thymidine and guanine in the gas phase 激光解吸胸苷和鸟嘌呤在气相中的电子相互作用。
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-30 DOI: 10.1140/epjd/s10053-025-01023-9
Debasish Parida, Jiakuan Chen, Lara Schorr, Vy T. T. Nguyen, Muhammad Saqib, Andreas Bayer, Fabio Zappa, Stephan Denifl

In the present study we investigated electron attachment to the nucleoside thymidine (Td) and the nucleobase guanine (G) using a laser desorption source to transfer the compounds into the gas phase. Previous studies with Td indicated that the compound is thermally labile and may degrade upon thermal heating in standard molecular beam source. The present negative ion mass spectra for laser-desorbed Td and resistively heated Td share the same most three abundant fragment anions. Among those is the dehydrogenated parent anion (Td-H) which is strongly enhanced for laser-desorbed Td. We also find a considerable change of the fragmentation pattern for less abundant peaks in the mass spectra as well as changed characteristic in the total and mass selected anion efficiency curves of fragment anions. Electron attachment to G proceeds predominantly at electron energies below 3 eV. We ascribe this property to formation of a dipole-bound anion acting as a precursor state for efficient formation of the dehydrogenated anion (G-H). The present results complement previous electron attachment studies with other nucleobases showing that the dehydrogenated parent anion is the most abundant fragment anion for G as well.

摘要:本研究利用激光解吸源研究了核苷胸苷(Td)和核碱基鸟嘌呤(G)的电子附着,将化合物转移到气相。以往对Td的研究表明,该化合物具有热不稳定性,在标准分子束源中加热后会降解。激光解吸Td和电阻加热Td的负离子质谱具有相同的三个最丰富的片段阴离子。其中包括脱氢的母阴离子(Td- h),它在激光解吸的Td中被强烈增强。我们还发现质谱中较少丰度峰的碎片化模式发生了很大的变化,碎片阴离子的总阴离子效率曲线和质量选择阴离子效率曲线的特征也发生了变化。电子对G的附着主要发生在电子能量低于3ev的地方。我们将这种性质归因于偶极结合阴离子的形成,作为有效形成脱氢阴离子(G-H)-的前体态。本研究结果与其他核碱基的电子附着研究相补充,表明脱氢的母阴离子也是G最丰富的片段阴离子。图片摘要:补充资料:在线版本包含补充资料,下载地址:10.1140/epjd/s10053-025-01023-9。
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引用次数: 0
Second Born approximation for the double ionization of methane by electron impact: a study of the different mechanisms 甲烷电子撞击双电离的第二伯恩近似:不同机制的研究
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-30 DOI: 10.1140/epjd/s10053-025-01020-y
W. Sakhraoui, I. Kada, A. Mansouri, C. Dal Cappello

We report new investigations for the five differential cross section (FDCS) of the double ionization of methane by fast electron impact. The present study is performed within the first and second Born approximation. The target initial state is described by a single-center wave function of Moccia, while we represent the final state by using the approximate 3C model with the usual Gamow factor then with the Ward and Macek factor as a corrected version. The different mechanisms have been identified for specific kinematic conditions.

Graphical abstract

我们报道了甲烷快速电子撞击双电离的五微分截面(FDCS)的新研究。本研究是在第一和第二伯恩近似范围内进行的。目标初始状态用Moccia的单中心波函数来描述,最终状态用近似3C模型表示,该模型采用常用的Gamow因子,然后用Ward和Macek因子作为修正版本。在特定的运动条件下,已经确定了不同的机构。图形抽象
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引用次数: 0
Quantitative measurement of the excitation cross section for the lowest-lying optically allowed transitions in difluoromethane molecules by electron impact: verification of the BE-scaled cross section in the intermediate-energy region 通过电子冲击对二氟甲烷分子中最低光学允许跃迁的激发截面进行定量测量:在中能区be标度截面的验证
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-28 DOI: 10.1140/epjd/s10053-025-01028-4
M. Hoshino, J. Kim, M. Matsukuma

We report on the absolute excitation cross sections of the lowest-lying optically allowed transitions in difluoromethane (CH2F2) molecules at intermediate impact energies between 100 and 400 eV and for scattering angles of 1.5° to 15°. The energy loss ranges from 8.5 to 11 eV, which has been assigned as the optically allowed 3s ← 2b2 and 3p ← 2b2 overlapping with the dipole-forbidden 11A2 ← X1A1 excitations. The absolute scale of the corresponding cross sections is obtained by normalizing the angular distributions of inelastically scattered electrons to the absolute excitation differential cross section (DCS) of He as the reference. The excitation integral cross sections (ICSs) for these excitations obtained by the generalized oscillator strength analysis are in reasonable agreement with the corresponding BE-scaled ICSs derived recently at an impact energy of 1500 eV within the experimental uncertainties. The absolute measurement suggested that the BE-scaling law is experimentally confirmed to be quite useful for CH2F2 molecules even at intermediate electron energies.

Graphical abstract

我们报道了二氟甲烷(CH2F2)分子在100和400 eV之间的中间冲击能量和1.5°到15°的散射角下的最低光学允许跃迁的绝对激发截面。能量损失范围在8.5 ~ 11ev之间,这是由于光学允许的3s←2b2和3p←2b2与偶极禁止的11A2←X1A1激发重叠。以He的绝对激发微分截面(DCS)为参考,将非弹性散射电子的角分布归一化,得到相应截面的绝对尺度。在实验不确定度范围内,用广义振子强度分析得到的激振积分截面(ics)与最近得到的冲击能为1500 eV的be尺度激振积分截面(ics)基本一致。绝对测量结果表明,be标度定律在实验上被证实是非常有用的,即使在中间电子能量的CH2F2分子。图形抽象
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引用次数: 0
Out-of-Time-Order Correlation in perturbed quantum wells 摄动量子阱中的非时序相关
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-28 DOI: 10.1140/epjd/s10053-025-01025-7
Pranaya Pratik Das, Biplab Ganguli

Out-of-Time-Order Correlator (OTOC) and Loschmidt Echo (LE) are commonly regarded as diagnostic tools for chaos, although they may yield misleading results, as we observe. Previous studies have concluded that OTOC shows exponential growth in the neighbourhood of a local maximum. If this statement holds true, the exponential growth should break off once the local maximum is no longer present within the system. By applying a small symmetry-breaking perturbation, we notice that the behaviour of the OTOCs remains remarkably resilient even in the absence of a maximum. Besides this, we also notice that with the increase in perturbation strength, the broken symmetric region expands, causing a broader range of eigenstates to engage in the exponential growth of OTOCs. Therefore, the critical factor lies not in the presence of a local maximum, but in the dynamic nature of the density of states in the broken symmetry regions. Our examination, spanning diverse one- dimensional potential landscapes, reveals the universality of this phenomenon. We also use other chaos diagnostic tool, LE. Interestingly, it also gives a false signal of chaos.

非时序相关器(OTOC)和洛施密特回声(LE)通常被认为是混沌的诊断工具,尽管它们可能产生误导性的结果,正如我们所观察到的。以前的研究已经得出结论,OTOC在局部极大值附近呈指数增长。如果这种说法成立,一旦系统内不再存在局部最大值,指数增长就会中断。通过施加一个小的对称破缺扰动,我们注意到即使在没有最大值的情况下,OTOCs的行为仍然具有显著的弹性。除此之外,我们还注意到,随着扰动强度的增加,破缺对称区域扩大,导致更广泛的本征态参与OTOCs的指数增长。因此,关键因素不在于局部最大值的存在,而在于破缺对称区域中状态密度的动态性质。我们的研究跨越了不同的一维潜在景观,揭示了这种现象的普遍性。我们还使用了另一种混沌诊断工具LE。有趣的是,它也给出了混乱的错误信号。
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引用次数: 0
Experimental transition probabilities of singly ionized cerium using laser-induced breakdown spectroscopy (LIBS) 利用激光诱导击穿光谱(LIBS)研究单电离铈的跃迁概率
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-25 DOI: 10.1140/epjd/s10053-025-01027-5
Supriya Kodangil, Masaomi Tanaka, Daiji Kato, Gediminas Gaigalas, Hajime Tanuma, Nobuyuki Nakamura

In this study, we present experimentally determined transition probabilities of 86 singly ionized cerium emission lines. We used a widely employed spectroscopic technique, laser-induced breakdown spectroscopy (LIBS), to measure the transition probabilities considering the great demand for experimentally determined atomic data. In astrophysics, cerium is a significant element of interest, especially when examining kilonova emissions that are observed following the merging of two neutron stars. The experimental data are compared with previously reported data.

在本研究中,我们通过实验确定了86条单电离铈发射谱线的跃迁概率。考虑到对实验确定的原子数据的巨大需求,我们使用了广泛使用的光谱技术,激光诱导击穿光谱(LIBS)来测量跃迁概率。在天体物理学中,铈是一个重要的感兴趣的元素,特别是在检查两颗中子星合并后观察到的千新星发射时。实验数据与以往报道的数据进行了比较。
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引用次数: 0
Investigation of air pollution in India in terms of climate change and ecological environment problem with optical methods 用光学方法从气候变化和生态环境问题的角度研究印度的空气污染
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-24 DOI: 10.1140/epjd/s10053-025-01019-5
Suleyman Yilmaz

In this study, it is aimed to draw attention to the environmental problem and air pollution, which are the most important components of sustainable development for the new century. An appropriate model has been developed to determine the light scattering of axisymmetric particles in the suspension, which is the source of airborne pollution, with numerical calculations. In this axisymmetric model developed for aerosol composition, the distribution of light intensity has been calculated using optical parameters. Thus, light scattering has been obtained for different absorbance and dielectric parameters of inhomogeneous particles. The correlation between the absorbance of the sample and the pollution defining the molecular density has been characterized with the data obtained from the change of scattering intensity according to the azimuth angle in the sample geometry. In the axisymmetric model designed for numerical calculations, standard scattering intensity data have been obtained for future calculations for different absorbed and non-absorbed environments according to the calculated light intensities.

在这项研究中,旨在引起人们对环境问题和空气污染的关注,这是新世纪可持续发展的最重要组成部分。本文建立了轴对称粒子在空气污染源悬浮液中的光散射模型,并进行了数值计算。在这个为气溶胶成分建立的轴对称模型中,光强的分布已经用光学参数计算出来。从而得到了不同吸光度和介电参数对非均匀粒子光散射的影响。利用样品几何中散射强度随方位角变化的数据,表征了样品的吸光度与定义分子密度的污染之间的相关性。在设计用于数值计算的轴对称模型中,根据计算得到的光强,得到了不同吸收和非吸收环境下的标准散射强度数据,便于以后的计算。
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引用次数: 0
Characteristic recognition ghost imaging with pseudo-thermal light 伪热光特征识别鬼影成像
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-24 DOI: 10.1140/epjd/s10053-025-00978-z
Xuanpengfan Zou, Yanfeng Bai, Wei Tan, Xianwei Huang, Qin Fu, Liyu Zhou, Xiquan Fu

Traditional ghost image (GI) relies on the intensity fluctuation correlation between the reference beam and the object beam. In this paper, a novel analysis for characteristic recognition ghost imaging (CRGI) is proposed based on characteristic classification of the light field, which indicates that GI can be considered as the superposition of ghost images with different characteristic information. The analytical results show that the reconstructed images of GI by processing the reference light are identical to that by processing the object light, which make it possible to utilize the prefabricated reference light to recognize the target characteristic in the imaging process. Moreover, the distinction between targets can be clearly identified by CRGI when the difference of characteristic information is quite slight, while it is difficult to be distinguished in traditional GI. Our results not only provide a new method for real-time characteristic recognition, but also promote the development of GI technology in fields such as medical imaging and security systems.

Graphical abstract

This diagram depicts the process of achieving target characteristic recognition by pre-processing the reference light

传统的鬼像依赖于参考光束和目标光束之间的强度波动相关性。本文提出了一种基于光场特征分类的特征识别鬼像分析方法,认为鬼像可以看作是具有不同特征信息的鬼像的叠加。分析结果表明,参考光处理后的GI图像与物体光处理后的GI图像完全一致,这使得利用预制参考光在成像过程中识别目标特征成为可能。此外,在特征信息差异很小的情况下,CRGI可以清晰地识别目标之间的区别,而传统GI难以区分。我们的研究结果不仅为实时特征识别提供了一种新的方法,而且还促进了GI技术在医学成像和安全系统等领域的发展。图形摘要本图描述了通过对参考光进行预处理来实现目标特征识别的过程
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引用次数: 0
Spectral line identification for highly charged heavy ions in soft X-ray and EUV regions based on Z-dependence measurements 基于z依赖性测量的软x射线和EUV区高电荷重离子谱线识别
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-23 DOI: 10.1140/epjd/s10053-025-01026-6
Chihiro Suzuki, Fumihiro Koike, Naoki Tamura, Tetsutarou Oishi, Nobuyuki Nakamura, Izumi Murakami

This study focuses on new identifications of discrete spectral lines of heavy ions with one or two outermost 4s/4p subshell electrons in soft X-ray and extreme ultraviolet regions. The study is basically based on the spectroscopic data systematically taken in the last decades in high-temperature plasmas produced in the Large Helical Device using multiple grazing incidence spectrometers. In addition, we have newly taken spectroscopic data using the Tokyo electron beam ion trap (EBIT) for some of the missing elements in the past EBIT experiments. Consequently, we could identify a number of discrete lines experimentally for the first time in this study based on the detailed atomic number (Z)-dependences of the wavelengths of major resonance lines. Some transitions of Ga- and Ge-like ions show irregular Z-dependences in which the transition wavelength suddenly shifts to another curve at around a specific Z due to the effect of strong configuration interaction.

本研究的重点是在软x射线和极紫外区对具有一个或两个最外层4s/4p亚壳电子的重离子的离散谱线进行新的鉴定。本研究基本上是基于近几十年来在大型螺旋装置中使用多个掠入射光谱仪系统采集的高温等离子体光谱数据。此外,我们利用东京电子束离子阱(EBIT)对过去EBIT实验中缺失的一些元素进行了新的光谱数据采集。因此,在本研究中,我们可以基于主要共振线波长的详细原子序数(Z)依赖性,首次在实验上识别出一些离散谱线。类Ga离子和类ge离子的一些跃迁表现出不规则的Z依赖性,由于强组态相互作用的影响,跃迁波长在特定Z附近突然转变为另一条曲线。
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引用次数: 0
Projectile charge effects in ionization of water molecule by positron and electron impact 正电子与电子碰撞使水分子电离时的抛射电荷效应
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-21 DOI: 10.1140/epjd/s10053-025-01017-7
I. Khiat, S. Houamer, I. Kada, S. Mekhalfa, A. Tamin, C. Dal Cappello

We present a theoretical investigation to study the ionization reaction of the water molecule in its ground state by positron and electron impact, from low to intermediate impact energies. The triple differential cross section (TDCS) is calculated using the M3CWZ model, where each particle in the continuum is represented by a Coulomb wave with a variable charge Z(r), and the post collision interaction (PCI) is included and exactly treated. Numerical results are compared with available data and other theories in a wide range of kinematics. It is found that M3CWZ results reproduce quite well the data at intermediate and low impact energies for electron impact process. For positron impact, our results are in good agreement with theoretical predictions and show interesting trends that should be confirmed by future experiments.

Graphical abstract

本文从理论上研究了水分子在基态下受正电子和电子冲击的电离反应,从低到中冲击能量。采用M3CWZ模型计算了三微分截面(TDCS),其中连续介质中的每个粒子都用具有可变电荷Z(r)的库仑波表示,并包括碰撞后相互作用(PCI)并进行了精确处理。数值结果与现有数据和其他理论在广泛的运动学范围内进行了比较。发现M3CWZ结果较好地再现了电子冲击过程中低冲击能的数据。对于正电子撞击,我们的结果与理论预测非常一致,并显示出有趣的趋势,应该在未来的实验中得到证实。图形抽象
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引用次数: 0
Photodetachment in a soft confinement potential 软约束电位下的光脱离
IF 1.5 4区 物理与天体物理 Q3 OPTICS Pub Date : 2025-06-20 DOI: 10.1140/epjd/s10053-025-01021-x
De-hua Wang, Shu-fang Zhang, Gang Zhao

Soft confinement potential provides a more realistic model for physical systems, such as many-body interactions, atomic clusters, and ion trap, making it a hot topic of current research. In this study, the photodetachment dynamics of the H ion in a soft confinement potential ((z/d)N) is investigated using closed orbit theory (COT). The photodetachment cross section (PCS) of this system is shown to be highly sensitive to the stiffness (N) and confinement width (d) of the potential. When N is odd, the photodetachment dynamics resembles that in a uniform electric field, resulting in a relatively simple oscillatory structure in the PCS. For even N, the force acting on the detached electron becomes a restoring force, leading to periodic oscillation of the detached electron. This makes the oscillatory structure in the PCS more complex. Additionally, the oscillating amplitude of the PCS decreases as N increases, and for very large N, the PCS approximates that of a system near a hard wall (for odd N) or in a quantum well with two hard walls (for even N). This study highlights that by varying the parameters of a soft confinement potential, researchers can precisely regulate the photodetachment of negative ions in various external field environment. These findings offer valuable insights into how soft confinement potentials affect negative ions, advancing both fundamental research and practical applications, such as photodetachment microscopy, ion manipulation, and ion trap.

Graphical abstract

软约束势为多体相互作用、原子团簇和离子阱等物理系统提供了更为现实的模型,是当前研究的热点。本文利用闭轨道理论(COT)研究了软约束势((z/d)N)下氢离子的光脱离动力学。该系统的光分离截面(PCS)对电势的刚度(N)和约束宽度(d)高度敏感。当N为奇数时,光分离动力学类似于均匀电场中的光分离动力学,导致PCS中的振荡结构相对简单。对于偶数N,作用在分离电子上的力变成了恢复力,导致分离电子的周期性振荡。这使得PCS中的振荡结构更加复杂。此外,PCS的振荡幅度随着N的增加而减小,并且对于非常大的N, PCS近似于靠近硬壁(对于奇数N)或具有两个硬壁的量子阱(对于偶数N)的系统。本研究强调,通过改变软约束电位的参数,研究人员可以精确地调节负离子在不同外场环境下的光分离。这些发现为软约束电位如何影响负离子提供了有价值的见解,推动了基础研究和实际应用,如光分离显微镜、离子操作和离子阱。图形抽象
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引用次数: 0
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The European Physical Journal D
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