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Investigation into Operation of a Semitower Boiler of a 158-MW Power Unit and Prospects for Application of Such Boilers in Russia 俄罗斯某158mw机组半塔锅炉运行情况调查及应用前景展望
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-03-10 DOI: 10.1134/S0040601524700708
V. M. Supranov, B. R. Sosa, B. Kh. F. Sosa, K. A. Pleshanov

Steam boilers of various arrangements (or profiles) exist in the world. The most widely used ones include, for example, semitower boilers (or L-paso boilers). In Russia, there is not sufficient experience in designing such boilers, especially in their practical application. The paper analyzes advantages and disadvantages of semitower boilers. As with tower boilers, their main advantage is a small footprint. However, compared to tower boilers, the L-paso boilers have a lower height. According to the performed analysis, the semitower configuration is best suited to boilers fired with gaseous or liquid fuel. In Russia, due to its climatic conditions, semitower boilers can be used for replacements of obsolete (type E) natural circulation gas-and-fuel oil-fired boilers with a steam output of 210–420 t/h. As an example, the paper presents a brief description of the L‑paso (type Ep) natural circulation reheat boiler manufactured by the well-known Babcock–Wilcox Co. This boiler, which is a part of a 158-MW power unit, has been successfully fired with sulfur fuel oil for many years. A customized numerical model of the boiler was developed in the Boiler Designer software package. Multivariant calculations of the boiler were performed on the basis of this model. An analysis of the predictions has confirmed that the boiler can operate in a wide range of loads while maintaining the design steam conditions. The furnace heat release rate qF, the furnace cross-section heat release rate qV, and the flue gas temperature at the furnace outlet (vartheta _{{text{f}}}^{{''}}) have been demonstrated to considerably exceed the values allowed by the applicable Russian regulations for similar boilers. This fact is explained. The gas velocities in the boiler gas ducts are noticeably higher, and the gas and air velocities in the air heater are approximately the same as in the Russian-made boilers. The steam enthalpy increments Δh and the mass velocity ρw in the superheater stages basically correspond to the concepts of Russian specialists.

世界上存在着各种布置(或型材)的蒸汽锅炉。最广泛使用的包括,例如,半塔锅炉(或L-paso锅炉)。在俄罗斯,这种锅炉的设计经验,特别是在实际应用方面,还不够丰富。本文分析了半塔式锅炉的优缺点。与塔式锅炉一样,它们的主要优点是占地面积小。然而,与塔式锅炉相比,L-paso锅炉的高度较低。根据所进行的分析,半塔结构最适合使用气体或液体燃料的锅炉。在俄罗斯,由于其气候条件,半塔锅炉可用于替代过时的(E型)蒸汽输出210-420 t/h的燃气燃油自然循环锅炉。本文以著名的巴布科克-威尔科克斯公司生产的L - paso (Ep型)自然循环再热锅炉为例,简要介绍了该锅炉作为158mw发电机组的一部分,已成功使用含硫燃料油多年。在锅炉设计软件中建立了定制的锅炉数值模型。在此模型的基础上对锅炉进行了多变量计算。通过对预测结果的分析,证实了锅炉在保持设计蒸汽工况的情况下,可以在较宽的负荷范围内运行。炉膛放热率qF、炉膛横截面放热率qV和炉膛出口烟道气温度(vartheta _{{text{f}}}^{{''}})已被证明大大超过适用于类似锅炉的俄罗斯法规所允许的值。这一事实得到了解释。锅炉燃气管道中的燃气速度明显较高,空气加热器中的燃气和空气速度与俄制锅炉中的燃气和空气速度大致相同。过热器阶段的蒸汽焓增量Δh和质量速度ρw基本符合俄罗斯专家的概念。
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引用次数: 0
Modeling of R-142b Saturated Vapor Condensation in a Horizontal Tube Using the VOF Method in the Wall Conjugate Statement 用壁共轭态VOF法模拟水平管内R-142b饱和蒸汽凝结
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-03-10 DOI: 10.1134/S0040601524700745
G. G. Yan’kov, K. B. Minko, O. O. Mil’man, V. I. Artemov

Due to the advanced capabilities of modern computational fluid dynamics (CFD) codes and developed models and algorithms, numerical simulation has become an efficient tool for studying two-phase flows, analyzing the entire totality of the processes occurring in them, and obtaining the data on flow local characteristics, which are difficult to measure directly. Active efforts taken for incorporating new models into various CFD codes should be accompanied by their cross-verification, the results of which can serve as a basis for selecting the most accurate, efficient, and universal models and algorithms. In this article, the results obtained from the solution of the problem about the condensation of R-142b refrigerant saturated vapor in a horizontal tube in the wall conjugate statement using two CFD codes, ANES and ANSYS Fluent, are analyzed. The copper tube’s inner diameter is 28 mm, its length is 2.75 m, wall thickness is 2 mm, and the total mass flux is 47 kg/(m2 s). The studies are of relevance for heat recovery installations based on the organic Rankine cycle. The calculations were carried out using the modified Lee model that we suggested previously, and which has been implemented in the ANES CFD code developed at the Department of Engineering Thermophysics, NRU MPEI. The cross verification of the VOF algorithms implemented in the ANES and ANSYS Fluent codes has shown that the results of modeling the saturated vapor condensation in a horizontal tube obtained using the above-mentioned codes are in good agreement with each other and are close to the empirical dependences recommended in the literature sources (M. Shah) for calculating the condensation in a horizontal channel. Data on the distribution of local heat-transfer characteristics over the tube’s inner wall are presented, which demonstrate that the heat-transfer coefficient features an essential nonuniformity over both the tube length and perimeter.

由于现代计算流体力学(CFD)代码的先进功能以及已开发的模型和算法,数值模拟已成为研究两相流、分析其中发生的整个过程以及获得难以直接测量的流动局部特征数据的有效工具。在将新模型纳入各种CFD代码时,应积极进行交叉验证,交叉验证的结果可作为选择最准确、最高效、最通用的模型和算法的基础。本文利用ANES和ANSYS Fluent两种CFD软件对水平管内R-142b制冷剂饱和蒸汽在壁面共轭状态下的冷凝问题进行了分析。铜管的内径为28 mm,长度为2.75 m,壁厚为2mm,总质量通量为47 kg/(m2 s),研究结果与基于有机朗肯循环的热回收装置相关。计算是使用我们之前提出的修改后的Lee模型进行的,该模型已在NRU MPEI工程热物理系开发的ANES CFD代码中实现。在ANES和ANSYS Fluent代码中实现的VOF算法的交叉验证表明,使用上述代码对水平管道中饱和蒸汽凝结进行建模的结果彼此吻合良好,并且接近文献来源(M. Shah)中推荐的计算水平通道中凝结的经验依赖关系。给出了管内局部传热特性分布的数据,表明传热系数在管内长度和周长上都具有本质的不均匀性。
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引用次数: 0
Influence of Discharge Collecting Chambers on the Efficiency of a Turbogenerator Air Ventilator 集流室对汽轮发电机组通风机效率的影响
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-03-10 DOI: 10.1134/S0040601524700721
V. G. Gribin, O. M. Mitrokhova, P. M. Nesterov, S. N. Mitrokhov

This paper presents the results of computational-theoretical and experimental studies of a model of discharge collecting channels of a typical centrifugal fan in an air-cooled turbogenerator. An experimental test bench was created and a measurement system was developed to determine losses with different configurations of cooling air discharge channels. It was found that the original design of the turbogenerator fan’s discharge collecting chamber has low aerodynamic efficiency due to high internal losses, which reduce the technical and economic performance of the turbogenerator. One cost-effective way to increase fan performance by reducing losses is through aerodynamic optimization of the collecting chamber contours. Analysis of computational-theoretical and experimental research results of the typical fan collecting chamber design showed that the system of guide ribs has the main influence on loss levels and aerodynamic efficiency, since these ribs simultaneously provide structural rigidity and reliability while forming the flow path geometry. An optimized flow path for the collecting chamber was developed and tested without requiring changes to the overall fan housing dimensions. The improvement in aerodynamic characteristics is associated with modifying the guide rib system design through flow channel reprofiling. The optimization of the fan collecting chamber design increased useful power output by reducing aerodynamic losses in the turbogenerator’s air-cooling system. The design optimization, which ensures smooth increase in flow area with reduced positive pressure gradients in diffuser sections of the flow path, led to a relative efficiency increase of 24% while simultaneously reducing the metal consumption of the air-cooled turbogenerator centrifugal fan collecting chamber structure.

本文介绍了风冷汽轮发电机组典型离心风机集流通道模型的计算、理论和实验研究结果。建立了实验试验台,开发了一套测量系统,以确定不同配置的冷却空气排出通道的损失。研究发现,原有的汽轮发电机风机集流室设计由于内部损失大,气动效率低,降低了汽轮发电机的技术经济性能。通过减少损失来提高风扇性能的一种经济有效的方法是通过收集室轮廓的空气动力学优化。对典型风机集流室设计的计算理论和实验研究结果分析表明,导肋系统对损失水平和气动效率有主要影响,因为导肋在形成流道几何形状的同时提供了结构刚度和可靠性。在不改变整体风扇外壳尺寸的情况下,开发并测试了收集室的优化流道。气动特性的改善与通过流道改型改进导肋系统设计有关。风机收集室的优化设计通过减少汽轮发电机风冷系统的空气动力学损失来增加有效功率输出。通过优化设计,通过减小流道扩压段的正压梯度,保证了过流面积的平稳增加,使得相对效率提高了24%,同时降低了风冷汽轮发电机离心风机集风室结构的金属消耗。
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引用次数: 0
Nucleate Boling Heat Transfer of Dielectric Liquid HFE-7100 in Horizontal Layers at Various Pressures 不同压力下介电液体HFE-7100水平层成核沸腾传热研究
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-03-10 DOI: 10.1134/S004060152470068X
A. E. Brester, D. A. Shvetsov, V. I. Zhukov, A. N. Pavlenko

Experimental data are presented on nucleate boiling heat transfer of dielectric liquid HFE-7100 in horizontal layers. The liquid layer height was varied in a wide range while changing the pressure in the working chamber. The experiments were performed on a flat surface of a 120-mm outer diameter stainless-steel plate in an experimental heat-transfer vacuum setup whose working chamber was a thermal syphon. The experimental data were compared with the Yagov and Gogonin correlations which had been obtained for pool boiling. The Gogonin correlation has been demonstrated to properly generalize the experimental data in all ranges of reduced pressures and liquid layer heights. This correlation explicitly describes the influence of such parameters as the heating surface roughness and the ratio of the thermophysical properties of the liquid and the heat-transfer wall, which have a pronounced effect on the heat-transfer coefficient during boiling of dielectric liquids. Besides, this correlation is convenient since it can be used with parameters that can be monitored during the experiment. A generalization is presented of experimental data by the Pioro empirical correlation recommended for generalizing data on nucleate boiling in thin liquid layers. It has been demonstrated that the Pioro correlation with carefully selected coefficients and power exponents can generalize with an acceptable accuracy the experimental data obtained under given conditions on a heat-transfer wall exposed to a working fluid. To quantitatively assess the agreement between the computational correlations and experimental data on nucleate boiling of dielectric liquid HFE-7100 in horizontal layers, the mean error and rms deviation were used.

介绍了介电液体HFE-7100在水平层内的成核沸腾传热实验数据。随着工作腔内压力的变化,液层高度变化幅度较大。实验在外径为120mm的不锈钢板的平面上进行,实验换热真空装置的工作腔为热虹吸。实验数据与池沸腾的Yagov关联和Gogonin关联进行了比较。Gogonin相关已被证明可以很好地推广在所有减压和液层高度范围内的实验数据。这种相关性明确地描述了受热面粗糙度和液体与传热壁的热物性之比等参数对介质液体沸腾过程传热系数的影响。此外,这种相关性很方便,因为它可以与实验过程中可以监测的参数一起使用。用Pioro经验相关法对实验数据进行了推广,该方法被推荐用于推广薄液体层中核沸腾的数据。结果表明,采用精心选择的系数和幂指数的Pioro相关可以以可接受的精度概括在给定条件下暴露于工作流体的传热壁上得到的实验数据。为了定量评价介电液体HFE-7100水平层成核沸腾的计算相关性与实验数据的一致性,采用了平均误差和均方根偏差。
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引用次数: 0
Advanced Exergy Analysis and Performance Ranking of Components of a Combined Cycle Power Plant 联合循环电厂各部件的高级火用分析与性能排序
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S0040601524700642
Uchenna G. Azubuike, Howard O. Njoku, Mkpamdi N. Eke, Onyemaechi V. Ekechukwu

As conventional exergy analyses do not reveal the exergy destruction rates in a thermal system component caused by inefficiencies of interconnected components, actual potentials for improving the component performances cannot be provided by such analyses. This study analyses a combined-cycle gas turbine power plant using advanced exergy analysis methodologies, which address the shortcomings of conventional exergy analysis by evaluating the exergy destruction rates that are endogenous and exogenous, avoidable and unavoidable. Avoidable exergy destruction rates in the entire plant were found to be 31% of the total exergy destruction rates, indicating a significant potential for improving the plant. Exergy destruction rates for most of the plant components were largely endogenous (95.2%), signifying that contributions of cross-component interactions were limited. Avoidable endogenous exergy destruction rates account for 28.4% of the overall exergy destruction rates in the plant, while avoidable exogenous exergy destruction rates account for 2.1%. A component-level ranking of the plant components ranked the pumps in the plant as first for improvement whereas the highest priority was allocated to the combustion chambers (CC) by a plant-level ranking. A parametric study of the influence of CC operating conditions on the plant’s performance showed that CC operating temperatures more significantly affected plant exergy destruction rates than the CC operating pressures.

由于传统的火用分析并没有揭示由互连组件效率低下引起的热系统组件的火用破坏率,因此这种分析无法提供改善组件性能的实际潜力。本研究采用先进的火用分析方法对某联合循环燃气轮机电厂进行分析,通过评估内生和外生、可避免和不可避免的火用破坏率,解决了传统火用分析的不足。在整个工厂中,可避免的火用破坏率被发现是总火用破坏率的31%,这表明工厂有很大的改进潜力。大多数植物组分的能破坏率主要是内源的(95.2%),表明组分间相互作用的贡献有限。可避免的内源能破坏率占植株总能破坏率的28.4%,可避免的外源能破坏率占2.1%。工厂组件的组件级排名将工厂中的泵排在首位,而工厂级排名将最高优先级分配给燃烧室(CC)。一项关于CC工况对电厂性能影响的参数化研究表明,CC工况温度比CC工况压力对电厂火用破坏率的影响更为显著。
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引用次数: 0
Assessing the Economic Efficiency of Using Wind Turbines Jointly with Boiler Houses for Heat Supply in Remote and Isolated Regions of the Westernmost Part of Russia’s Arctic Zone 评估在俄罗斯北极地区最西端偏远和孤立地区联合使用风力涡轮机和锅炉房供热的经济效益
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S0040601524700678
A. V. Bezhan

The article addresses matters concerned with decreasing the prime cost of thermal energy in the remote and isolated regions of Russia’s Arctic zone (AZ) that have a high wind energy potential by using wind turbines (WTs) jointly with boiler houses operating on expensive imported fossil fuel for heat-supply purposes. The use of wind turbines will make it possible to decrease the participation of boiler houses in the supply of heat to consumers, save fossil fuel, and, thereby, help decrease the prime cost of thermal energy. A procedure for calculating the levelized cost of thermal energy is developed and described in detail. The procedure is adapted to analyzing the efficiency of alternative options of using WTs jointly with boiler houses for heat-supply purposes, among which the alternative ensuring the minimal levelized cost of thermal energy is regarded as the most efficient one. By using the obtained technique, the economic efficiency of applying WTs jointly with boiler houses in the heat-supply systems of remote and isolated regions is evaluated taking the westernmost part of Russia’s Arctic zone as an example. It has been determined that, in such regions, in which the final annual average cost of fossil fuel is more than 1.5 times higher than the fuel cost in the cities and industrial centers of the AZ westernmost part as a consequence of a high transport component, the WTs are most efficient when used jointly with boiler houses operating on diesel fuel. For boiler houses operating on fuel oil and coal, the effect from using WTs is not so high. It is also shown that the cheaper the fuel, the less efficient or even inefficient at all the use of WTs becomes in comparison with the heat-supply option from a boiler house without connecting a WT. For the regions considered, the joint production of thermal energy by WTs and boiler houses operating on diesel fuel, fuel oil, and coal makes it possible to decrease its levelized cost by 7‒55, 5‒20, and 2‒7%, respectively.

本文讨论了在俄罗斯北极地区(AZ)偏远和孤立的地区,通过使用风力涡轮机(WTs)和锅炉房(以昂贵的进口化石燃料为供热目的)来降低热能主要成本的问题,这些地区具有很高的风能潜力。使用风力涡轮机将有可能减少锅炉房向消费者提供热量的参与,节省化石燃料,从而有助于降低热能的主要成本。提出了一种计算热能平准化成本的方法,并对其进行了详细描述。该程序适用于分析WTs与锅炉房联合供热的备选方案的效率,其中以保证热能均一化成本最小的方案效率最高。利用所获得的技术,以俄罗斯北极地区最西端为例,对WTs与锅炉房联合应用于偏远偏远地区供热系统的经济效益进行了评价。已经确定,在这些地区,由于高运输成分,化石燃料的最终年平均成本比AZ最西部的城市和工业中心的燃料成本高出1.5倍以上,当WTs与使用柴油燃料的锅炉房联合使用时,WTs的效率最高。对于燃料油和煤的锅炉房,使用WTs的效果并不高。研究还表明,与不连接WT的锅炉房供热选项相比,燃料越便宜,WTs的使用效率就越低,甚至效率就越低。对于所考虑的地区,由WTs和使用柴油、燃料油和煤炭的锅炉房联合生产热能,可以将其平均成本分别降低7-55、5-20和2-7%。
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引用次数: 0
Performance Improvement of Power Plant at Aberrant Steam Temperature Condition through E3 Analysis 基于E3分析的电厂异常汽温工况性能改进
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S0040601524700538
Goutam Khankari, D. V. Rajan, Sujit Karmakar

Energy efficient and environment friendly power generation is the primary goal for any power generating industries. This paper proposes a thermodynamic approach based on E3 (energy, exergy and environment) analysis for performance improvement of power plant during low main steam and high reheater (RH) temperature conditions through a suitable operation technique. Thermodynamic modeling of a 500 MW Subcritical (SubC) coal based thermal power plant is carried in “Cycle-Tempo” at different conditions. Partial withdrawl of final feed water heater (high pressure heater—HPH-6) from service without RH spray condition during low main steam (MS) temperature and high RH steam temperature condition will help to increase the MS temperature by about 0.85–1.00°C and thereby, the net plant energy and exergy efficiency will be improved by about 0.09 and 0.08% point, respectively. Partial withdrawl of HPH-6 with RH spray condition will deteriorate the plant energetic and exergetic plant performance and this will guide the operation engineer for which extend withdrawl of HPH-6 can be done for getting higher plant performance. The net energy efficiency of turbogenerator (TG) cycle decreases with partial withdrawl of HPH-6 due to decrease in the feed water temperature by about 7°C and more relative energy rejection of the cycle. The net exergy efficiency of TG cycle increases due to less relative exergy destruction rate causing from improvement in steam quality. However, the use of RH spray increases the irreversiblities in the plant and the spray does not expand in high pressure turbine (HPT) which in turn decrease the exergy efficiency. The boiler energy efficiency increases due to decrease in fluegas exit loss as the fluegas exit temperature drops from about 140 to 133°C due to partial withdrawl of HPH-6. The exergy efficiency of boiler also decreases due to increase in exergy destruction in final super heater (FSH), reheater and economizer. For a 500 MW SubC coal power plant, hourly about 930 kg of coal and about 1183 kg of CO2 emission can be saved and reduced through this operation technique namely, partial withdrawl of HPH-6 without RH spray condition for controlling low MS temperature. Hence, the proposed analysis will help to take proper operational technique for mitigating coal crisis and safeguarding the environment as well.

节能环保发电是所有发电行业的首要目标。本文提出了一种基于能量、火用和环境(E3)分析的热力方法,通过适当的运行技术来改善电厂在低主汽、高再热(RH)温度条件下的性能。对某500mw亚临界(SubC)煤基火电厂在不同工况下进行了“循环- tempo”热力学建模。在低主蒸汽温度和高RH蒸汽温度工况下,部分退出无RH喷雾工况的最终给水加热器(高压加热器- hph -6)将有助于使主蒸汽温度提高约0.85-1.00℃,从而使电厂净能量和火用效率分别提高约0.09和0.08%。在RH喷雾条件下,部分抽提HPH-6会使装置的高能化和火用性能下降,这将指导运行工程师通过扩大抽提HPH-6来获得更高的装置性能。汽轮发电机(TG)循环的净能量效率随着HPH-6的部分退出而降低,这是由于给水温度降低了约7℃,循环的相对能量损失增加了。由于蒸汽质量的改善,减少了相对火用破坏率,热重循环的净火用效率得到提高。然而,RH喷雾的使用增加了装置的不可逆性,并且喷雾在高压涡轮(HPT)中不膨胀,从而降低了火用效率。由于HPH-6的部分退出,烟气出口温度从140℃左右下降到133℃,烟气出口损失减少,锅炉能效提高。由于末端过热器、再热器和省煤器的火用破坏增加,锅炉的火用效率也有所下降。500mw SubC燃煤电厂采用无RH喷淋条件下部分抽出HPH-6控制低MS温度的运行技术,每小时可节约煤炭约930 kg,减少CO2排放约1183 kg。因此,所提出的分析将有助于采取适当的操作技术,以缓解煤炭危机和保护环境。
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引用次数: 0
Environmental Consequences of Using Ammonia-Ethanolamine Water Chemistry in the Secondary Circuit of VVER-1200 Nuclear Power Plants 在VVER-1200核电站二回路中使用氨-乙醇胺水化学的环境后果
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S004060152470054X
V. G. Kritsky, A. V. Gavrilov, N. A. Prokhorov, E. A. Motkova, N. A. Pelageecheva, M. S. Shvaleva, A. V. Karpov

The ammonia-ethanolamine water chemistry used at NPPs with VVER-1200 ensures low rates of corrosion, mass transfer, and growth of corrosion product deposits. The content of corrosion products in the feedwater of the steam generator is less than 1 μg/dm3. This significantly increases the period between flushing the steam generator to remove deposits. However, ethanolamine and ammonia are absorbed by the cation exchange resin in the ion-exchange filters of the secondary circuit purification systems, which leads to the need to regenerate the cation exchange resin and continuously dose reagents to maintain the required pH value in the feedwater. Waste solutions from regeneration containing ethanolamine and large amounts of ammonia must be treated to ensure that the concentrations of these substances do not exceed maximum permissible values when discharged into the environment. To remove ethanolamine and ammonia from regeneration solutions, special installations are created, the operation of which is based on various principles. A pilot plant for cleaning regeneration solutions was manufactured and installed at the Belarusian NPP with VVER-1200. An analysis of the pilot plant’s operation showed that it successfully fulfills its function of protecting the aquatic environment but, at the same time, it is forced to release a significant amount of ammonia into the surrounding air. Removing ammonia is energy-consuming, environmentally unsafe, and requires the additional use of chemical reagents. In this regard, the water-chemical regime of the secondary circuit without ammonia is very promising. Possible options could be either switching from ammonia to dimethylamine or using ethanolamine as the only corrective reagent with the replacement of some of the structural materials of the secondary circuit with steels with a high chromium content, which have higher corrosion resistance compared to those currently used. Both options will simplify the wastewater treatment technology and reduce the environmental impact while maintaining the low corrosion rates achieved by using the ammonia–ethanolamine water chemistry.

使用VVER-1200的核电站使用的氨-乙醇胺水化学可确保低腐蚀率、传质率和腐蚀产物沉积物的生长。蒸汽发生器给水中腐蚀产物含量小于1 μg/dm3。这大大增加了冲洗蒸汽发生器以清除沉积物之间的时间。然而,在二级回路净化系统的离子交换过滤器中,乙醇胺和氨被阳离子交换树脂吸收,这导致需要再生阳离子交换树脂并不断添加试剂以维持给水中所需的pH值。必须对含有乙醇胺和大量氨的再生废液进行处理,以确保这些物质的浓度在排放到环境中时不超过最大允许值。为了从再生溶液中去除乙醇胺和氨,建立了特殊的装置,其操作基于各种原理。白俄罗斯核电站用VVER-1200制造和安装了一个清洁再生溶液的试验工厂。对中试工厂运行的分析表明,它成功地履行了保护水生环境的功能,但与此同时,它被迫向周围空气中释放了大量的氨。去除氨是耗能的,不环保的,并且需要额外使用化学试剂。在这方面,无氨二次回路的水化学状况是很有前途的。可能的选择是将氨改为二甲胺或使用乙醇胺作为唯一的校正试剂,并将二次回路的一些结构材料替换为高铬含量的钢,与目前使用的钢相比,高铬含量的钢具有更高的耐腐蚀性。这两种选择都将简化废水处理技术,减少对环境的影响,同时保持氨-乙醇胺水化学的低腐蚀速率。
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引用次数: 0
Ammonia as a Fuel for Gas-Turbine Units with Thermochemical Recuperation of Exhaust Gas Heat 氨作为废气热化学回收燃气轮机机组的燃料
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S0040601524700691
D. I. Pashchenko

The prospects are examined for application of ammonia-fired gas turbine units (GTUs) with thermochemical recuperation of the exhaust gas heat. Examples of operating ammonia-fired gas turbine units are given, and the main operating restrictions for the use of existing gas turbine units are specified. A thermodynamic analysis of a simple gas turbine unit with thermochemical heat recuperation (TCR) was performed in a wide range of operating conditions: the gas temperature at the turbine inlet varied from 700 to 1300°C and the compressor pressure ratio from 5 to 20. It has been established that the thermochemical heat recuperation can increase the GTU efficiency by as much as 9%. The effectiveness of TCR application has been demonstrated to depend on such operating parameters as pressure and temperature. At a temperature above 500°C, the enthalpy of the ammonia decomposition reaction reaches a value close to the maximum of approximately 3.0 MJ/kg NH3. Thermochemical recuperation leads to the decomposition of ammonia with production of a hydrogen-rich gas (up to 75% (by volume)), which is burned in the combustion chamber, thereby changing the combustion process characteristics. The flame propagation velocity in a gas mixture consisting of hydrogen, nitrogen, and ammonia in different proportions was calculated on the basis of the GRI-Mech 3.0 list of elementary reactions in the Chemkin-Pro module. It has been found that the products of complete thermochemical decomposition of ammonia have a flame propagation velocity that is approximately two times higher than that for methane and more than ten times higher than that for ammonia. Thus, the implementation of the thermochemical heat recuperation in ammonia-fired gas turbine units is expected to increase the energy efficiency and improve the combustion process stability.

展望了烟气热化学回收氨燃气轮机的应用前景。给出了运行氨燃气轮机机组的实例,并说明了使用现有燃气轮机机组的主要运行限制。对具有热化学热回收(TCR)功能的简单燃气轮机机组在多种工况下进行了热力学分析:涡轮入口气体温度从700°C变化到1300°C,压缩机压力比从5到20。热化学热回收可使GTU效率提高9%。TCR应用的有效性已被证明取决于诸如压力和温度等操作参数。在温度高于500℃时,氨分解反应的焓值接近最大值,约为3.0 MJ/kg NH3。热化学回收导致氨分解,产生富氢气体(高达75%(体积)),在燃烧室中燃烧,从而改变燃烧过程特性。根据Chemkin-Pro模块中的GRI-Mech 3.0基本反应表,计算了不同比例的氢、氮、氨混合气体中火焰的传播速度。研究发现,氨完全热化学分解产物的火焰传播速度约为甲烷的两倍,比氨的火焰传播速度高十倍以上。因此,在氨燃气轮机机组中实施热化学热回收有望提高能源效率,改善燃烧过程的稳定性。
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引用次数: 0
Development of a Theoretical Model for Predicting Performance of a Gas Ejector in Different Boundary Conditions and Working Fluids 不同边界条件和工质下气体喷射器性能预测理论模型的建立
IF 0.9 Q4 ENERGY & FUELS Pub Date : 2025-02-21 DOI: 10.1134/S0040601524700526
Saeed Akbarnejad,  Masoud Ziabasharhagh

Ejectors are devices designed to suck fluid, steam or gas (primary fluid) from a closed space using a powerful jet of steam (secondary fluid), usually operated under specified boundary conditions using specific working fluids. If ejectors are to be used under new boundary conditions, predicting their performance requires either numerical or experimental studies. This paper presents a simple theoretical model capable of accurately predicting the performance of an ejector, given its geometry and boundary conditions, under different operating conditions. The model can predict the entrainment ratio, critical back pressure, and break-up back pressure using a given simple performance curve. The accuracy of the model is validated using computational fluid dynamics (CFD) simulations. Two ejectors with different geometries, dimensions, and boundary conditions are studied using ANSYS Fluent 19.2, and the results are compared with those from two other studies. The model successfully predicts the performance of all four ejectors across a wide range of operating conditions. Finally, the model is extended to any working fluid and temperature and validated numerically using air as the working fluid instead of water vapor. The results show that the model has an entrainment ratio error of less than 2%. It’s worth noting that this model’s applicability is contingent upon simultaneous changes to both the primary and suction streams by the same factor. Under these conditions, the model aligns closely with CFD-simulations.

喷射器是一种利用强大的蒸汽射流(二次流体)从封闭空间吸入流体、蒸汽或气体(一次流体)的装置,通常在特定的边界条件下使用特定的工作流体。如果要在新的边界条件下使用喷射器,预测其性能需要进行数值或实验研究。本文提出了一个简单的理论模型,在给定喷射器的几何形状和边界条件下,可以准确地预测喷射器在不同工作条件下的性能。该模型可以使用给定的简单性能曲线来预测夹带比、临界背压和破裂背压。通过计算流体力学(CFD)仿真验证了该模型的准确性。利用ANSYS Fluent 19.2软件对两种不同几何形状、尺寸和边界条件的喷射器进行了研究,并与其他两种研究结果进行了比较。该模型成功地预测了所有四种喷射器在各种操作条件下的性能。最后,将该模型推广到任何工作流体和温度下,并以空气代替水蒸气作为工作流体进行了数值验证。结果表明,该模型的夹带比误差小于2%。值得注意的是,该模型的适用性取决于同一因素同时改变主流和吸力流。在这些条件下,模型与cfd模拟非常接近。
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引用次数: 0
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Thermal Engineering
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