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On How to Determine Surface Roughness Power Spectra 如何确定表面粗糙度功率谱
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-27 DOI: 10.1007/s11249-024-01933-6
N. Rodriguez, L. Gontard, C. Ma, R. Xu, B. N. J. Persson

Analytical contact mechanics theories depend on surface roughness through the surface roughness power spectrum. In the present study, we evaluated the usability of various experimental methods for studying surface roughness. Our findings indicated that height data obtained from optical methods often lack accuracy and should not be utilized for calculating surface roughness power spectra. Conversely, engineering stylus instruments and atomic force microscopy (AFM) typically yield reliable results that are consistent across the overlapping roughness length scale region. For surfaces with isotropic roughness, the two-dimensional (2D) power spectrum can be derived from the one-dimensional (1D) power spectrum using several approaches, which we explored in this paper.

Graphical Abstract

解析接触力学理论通过表面粗糙度功率谱依赖于表面粗糙度。在本研究中,我们评估了研究表面粗糙度的各种实验方法的可用性。我们的研究结果表明,光学方法获得的高度数据往往缺乏精度,不应用于计算表面粗糙度功率谱。相反,工程触笔仪器和原子力显微镜(AFM)通常会产生可靠的结果,这些结果在重叠的粗糙度长度尺度区域内是一致的。对于具有各向同性粗糙度的表面,二维(2D)功率谱可以使用几种方法从一维(1D)功率谱中导出,我们在本文中探索了这些方法。图形抽象
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引用次数: 0
Theoretical Calculation and Experimental Verification of Wear Prediction During the Tightening Process of Bolted Joint 螺栓连接拧紧过程磨损预测的理论计算与实验验证
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-21 DOI: 10.1007/s11249-024-01947-0
Wentao Zhang, Liansheng Li, Jin Gao, Jianhua Liu, Hao Gong, Qinghua Wang

Thread seizure is a common failure mode for bolted joints during the process of tightening, significantly influencing their reliability and detachability. Research results have demonstrated that the accumulation and blocking of wear debris are the main reasons for thread seizure. This study proposed a theoretical model to predict the wear volume on thread surface in the tightening process for the first time. First, many sub-regions on the thread surface were divided. The real contact force and area on each region were calculated considering the nonuniform axial load distribution in a bolted joint. Second, for each sub-region, the micro morphology was characterized by fractal function. Based on the fractal contact theory, the contact model of single asperity was built, and the contact force and area of single asperity were calculated in the stages of elastic, elastoplastic, and plastic deformations. Subsequently, the contact force and contact area of each sub-region were obtained by integral on single asperity. The former was compared with the contact force of sub-region calculated by nonuniform axial load distribution to determine the termination condition of iteration. The latter was brought into the wear prediction model based on Archard wear theory. According to the theoretical model of predicting the wear volume on thread surface, the effects of axial load distribution coefficient, preload, fractal parameters, friction coefficient, and thread pitch on the wear volume of thread surface were analyzed and discussed. Finally, experiments were conducted to validate the reliability of the proposed theoretical prediction model for wear volume.

螺纹卡扣是螺栓连接在紧固过程中常见的失效形式,严重影响螺栓连接的可靠性和可拆卸性。研究结果表明,磨损碎屑的堆积和堵塞是导致螺纹卡住的主要原因。本文首次提出了一种预测螺纹拧紧过程中螺纹表面磨损量的理论模型。首先,在螺纹表面划分了许多子区域。在考虑非均匀轴向载荷分布的情况下,计算了螺栓连接中各区域的实际接触力和面积。其次,用分形函数对各子区域的微观形貌进行表征。基于分形接触理论,建立了单个粗糙体的接触模型,计算了单个粗糙体在弹性、弹塑性和塑性变形阶段的接触力和接触面积。然后,对单个粗糙体进行积分,得到各子区域的接触力和接触面积。将前者与非均匀轴向载荷分布计算的子区域接触力进行比较,确定迭代的终止条件。将后者引入到基于Archard磨损理论的磨损预测模型中。根据螺纹表面磨损量预测的理论模型,分析和讨论了轴向载荷分布系数、预紧力、分形参数、摩擦系数和螺纹节距对螺纹表面磨损量的影响。最后,通过实验验证了所提出的磨损量理论预测模型的可靠性。
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引用次数: 0
Design, Synthesis and Tribological Properties of Fatty Acid Diethanolamide Borate Esters with Different Carbon Chain Lengths 不同碳链长度脂肪酸二乙醇酰胺硼酸酯的设计、合成及其摩擦学性能
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-19 DOI: 10.1007/s11249-024-01951-4
Xi Yang, Guangbin Yang, Shengmao Zhang, Yujuan Zhang, Shuguang Fan, Zhengquan Jiang, Laigui Yu, Pingyu Zhang

With the increasing attention to environmental issues and the improvement of environmental regulations, traditional lubricant additives are facing huge challenges, while biodegradable green lubricant additives are facing new opportunities. Organic borate esters, as lubricating additives, have core competitiveness over traditional lubricating additives containing S, P, and Cl. Borate esters not only overcome the poor corrosion resistance of traditional additives, but also have excellent load-bearing capacity and extreme pressure performance. In addition, introducing fatty acid diethanolamide containing active groups such as hydroxyl and amide bonds into borate esters enhances the adsorption capacity. In this article, three borate esters with different carbon chain length were prepared, namely stearic acid diethanolamide borate ester with a chain length of 18, tetradecanoic acid diethanolamide borate ester with a chain length of 14, and octanoic acid diethanolamide borate ester with a chain length of 8. The as-prepared borate ester, especially C18ONB, exhibits excellent tribological properties as lubricant additives in poly (a-olefin) (PAO6), significantly improving the friction reducing and antiwear properties of the base oil. This is due to the weak polarity of C18ONB with long carbon chains, which exhibits good solubility in PAO6 with weaker polarity and forms thick multilayer viscoelastic adsorption film on the friction surface. In addition, the adsorption film undergoes tribochemical reactions during the rubbing process, generating a tribofilm containing excellent lubricants such as B2O3 and BN, which further plays a good role in reducing friction and antiwear.

随着人们对环境问题的日益关注和环保法规的不断完善,传统的润滑油添加剂面临着巨大的挑战,而可生物降解的绿色润滑油添加剂则面临着新的机遇。有机硼酸酯作为润滑添加剂,与传统含硫、磷、氯的润滑添加剂相比,具有核心竞争力。硼酸酯不仅克服了传统添加剂的耐腐蚀性差,而且具有优异的承载能力和极压性能。此外,将含有羟基和酰胺键等活性基团的脂肪酸二乙醇酰胺引入硼酸酯中,可以提高其吸附能力。本文制备了三种碳链长度不同的硼酸酯,即链长为18的硬脂酸二乙醇酰胺硼酸酯、链长为14的十四烷酸二乙醇酰胺硼酸酯和链长为8的辛酸二乙醇酰胺硼酸酯。制备的硼酸酯,特别是C18ONB,在聚a-烯烃(PAO6)中作为润滑剂添加剂表现出优异的摩擦学性能,显著提高了基础油的减摩和抗磨性能。这是由于长碳链的C18ONB极性较弱,在极性较弱的PAO6中表现出良好的溶解性,在摩擦表面形成较厚的多层粘弹性吸附膜。此外,吸附膜在摩擦过程中发生摩擦化学反应,生成含有B2O3和BN等优良润滑剂的摩擦膜,进一步起到良好的减少摩擦和抗磨作用。
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引用次数: 0
Effect of Surface Texturing on Friction and Lubrication of Ti6Al4V Biomaterials for Joint Implants 表面织构对关节植入Ti6Al4V生物材料摩擦润滑的影响
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-19 DOI: 10.1007/s11249-024-01950-5
Matúš Ranuša, Lukáš Odehnal, Ondřej Kučera, David Nečas, Martin Hartl, Ivan Křupka, Martin Vrbka

The number of endoprosthetic implants for both large and small joints is increasing at a steady rate, thereby creating a growing demand for durable products that closely replicate the functionality of human joints. Notwithstanding the aforementioned advancements, challenges pertaining to implant fixation and tribological surfaces persist. The advent of progressive technologies, such as three-dimensional printing, offers a promising avenue for addressing these challenges in implant design and surface engineering. The Ti6Al4V and CoCrMo alloys, renowned for their biocompatibility and osseointegration properties, represent promising printable materials, although they are susceptible to wear on articulating surfaces. In order to mitigate the effects of abrasion, it is essential to implement surface treatments to facilitate the formation of a robust lubricating film. This research investigates the potential of texturing and electrochemical polishing to enhance protein aggregation in the contact area. The study employs a reciprocating simulator and colorimetric interferometry to observe the contact area and measure the coefficient of friction (CoF) of modified surfaces. The findings demonstrate that textured surfaces and the combination of electrochemical polishing result in an increase in the thickness of the protein lubrication film, which may potentially reduce wear. These outcomes suggest the potential for the utilization of Ti6Al4V alloy implants with fewer elements manufactured by additive technology.

用于大关节和小关节的人工关节内植入物的数量正在稳步增长,因此人们对能够紧密复制人体关节功能的耐用产品的需求也在不断增长。尽管取得了上述进步,但与植入物固定和摩擦表面相关的挑战依然存在。三维打印等先进技术的出现,为解决植入物设计和表面工程中的这些难题提供了一个前景广阔的途径。Ti6Al4V 和 CoCrMo 合金因其生物相容性和骨结合特性而闻名,是很有前途的可打印材料,但它们在铰接表面容易磨损。为了减轻磨损的影响,必须进行表面处理,以促进形成坚固的润滑膜。本研究调查了纹理和电化学抛光在增强接触区域蛋白质聚集方面的潜力。研究采用了往复式模拟器和比色干涉仪来观察接触区域,并测量改性表面的摩擦系数 (CoF)。研究结果表明,纹理表面和电化学抛光相结合可增加蛋白质润滑膜的厚度,从而有可能减少磨损。这些结果表明,通过添加剂技术制造的元素较少的 Ti6Al4V 合金植入体具有利用潜力。
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引用次数: 0
Study on Adhesive Friction Process Considering Electrostatic Interaction 考虑静电相互作用的粘合剂摩擦过程研究
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-17 DOI: 10.1007/s11249-024-01948-z
Hongsheng Lu, Pengzhe Zhu, Rao Li, Jiacheng Rong, Ying Yin

Adhesive friction considering electrostatic interaction is an important problem in practical engineering. However, the friction mechanism considering electrostatic interaction and adhesion of elastoplastic materials on the contact interfaces remains poorly understood. A sliding friction model considering the van der Waals attraction, repulsive and electrostatic interactions is established in this work. The effect of charge density on the normal force, friction force, contact area and stress distribution is thoroughly investigated. And the repeated sliding friction process is also quantitatively analyzed. It is shown that adhesion enhances with the increase of surface charge density. Moreover, the contribution of electrostatic interaction to adhesion in the contact process is always greater than that to friction in the sliding friction process under the conditions studied. In the initial stage of friction, the friction will gradually increase and the normal force will gradually decrease. It is also found that a higher charge density results in a lower normal force in the friction process. Furthermore, the increase of charge density leads to a bigger contact diameter and the increased asymmetry of stress field, resulting in the increase of friction force, equivalent plastic strain and friction coefficient. In addition, both normal force and friction force arrive at a steady state after several repeated friction circles for elastoplastic materials, which is due to the fact that the contact diameter tends to be constant because of the accumulation of plastic deformation. This work reveals the contribution of electrostatic interaction to friction during adhesive sliding process and provides some insights into the adhesive friction problem considering electrostatic interaction.

考虑静电相互作用的粘着摩擦是实际工程中的一个重要问题。然而,考虑静电相互作用和弹塑性材料在接触界面上的粘附作用的摩擦机制仍然知之甚少。建立了考虑范德华引力、斥力和静电相互作用的滑动摩擦模型。研究了电荷密度对法向力、摩擦力、接触面积和应力分布的影响。并对重复滑动摩擦过程进行了定量分析。结果表明,随着表面电荷密度的增加,附着力增强。此外,在所研究的条件下,静电相互作用对接触过程中粘附的贡献始终大于滑动摩擦过程中摩擦的贡献。在摩擦初始阶段,摩擦力会逐渐增大,法向力会逐渐减小。研究还发现,电荷密度越高,摩擦过程中的法向力越小。电荷密度增大,接触直径增大,应力场不对称性增大,摩擦力增大,等效塑性应变增大,摩擦系数增大。此外,对于弹塑性材料,法向力和摩擦力经过多次重复摩擦循环后都达到稳态,这是由于接触直径由于塑性变形的积累而趋于恒定。这项工作揭示了静电相互作用对胶粘剂滑动过程中摩擦的贡献,并为考虑静电相互作用的胶粘剂摩擦问题提供了一些见解。
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引用次数: 0
Investigation on the Effect of Ionic Liquids on the Dispersion and Lubrication Performance of Nano-silver-Based Lubricating Oils 离子液体对纳米银基润滑油的分散和润滑性能的影响研究
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-14 DOI: 10.1007/s11249-024-01935-4
Chengjie Jin, Long Sun, Kexin Cao, Peng Chen, Songquan Wang, Ningning Hu

Aiming at the phenomenon that nanosilver lubricants are prone to agglomeration and sedimentation, the influence of different anions and cations in ionic liquids on the adsorption capacity of nanosilver particles is studied, and three ionic liquids with different structures are selected to improve the agglomeration of nanosilver particles in lubricants and to improve the anti-wear performance of lubricants; the dispersive performance of different ionic liquids is studied using quantum chemical simulation methods to study the adsorption and dispersion mechanism of nanosilver. The tribological properties of the three different ionic liquids in combination with the nanosilver lubricant were investigated using a multifunctional friction and wear tester and a field emission scanning electron microscope. The results show that hexyltributylphosphine hexafluorophosphate ([P4446][PF6]) can stabilise the dispersion of nanosilver lubricant and solve the problem of agglomeration and sedimentation due to its strong adsorption cation, which is attributed to its high adsorption and the synergistic effect of friction chemistry, and its anionic intermixing is good, and the ionic liquids have excellent anti-friction and wear reduction properties. It is shown that the design and utilisation of functional ionic liquids with the compound effect of nanosilver particles can effectively improve the dispersion of nanosilver as a lubricant additive.

Graphic Abstract

针对纳米银润滑剂易团聚和沉降的现象,研究了离子液体中不同阴阳离子对纳米银颗粒吸附能力的影响,选择了三种不同结构的离子液体,以改善纳米银颗粒在润滑剂中的团聚,提高润滑剂的抗磨性能;利用量子化学模拟方法研究了不同离子液体的分散性能,研究了纳米银的吸附和分散机理。使用多功能摩擦磨损测试仪和场发射扫描电子显微镜研究了三种不同离子液体与纳米银润滑剂结合的摩擦学特性。结果表明,六氟磷酸基三丁基膦([P4446][PF6])因其吸附阳离子性强,可稳定纳米银润滑剂的分散,解决团聚和沉积问题,这得益于其高吸附性和摩擦化学的协同效应,且其阴离子互混性好,离子液体具有优异的抗摩擦和减磨性能。研究表明,设计和利用具有纳米银颗粒复合效应的功能性离子液体,可有效提高纳米银作为润滑油添加剂的分散性。 图文摘要
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引用次数: 0
First-Principles Study of Superlubricity of Two-Dimensional Graphene/ WS2 Heterostructures 二维石墨烯/ WS2异质结构超润滑性第一性原理研究
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-07 DOI: 10.1007/s11249-024-01949-y
Dongwei Liang, Cheng Zhang, Chengyu Shen, Guangteng Cao, Ningbo Liao, Miao Zhang

Layered two-dimensional nanomaterials such as graphene and WS2, possess superlubricity properties and thus offer a promising solution to mitigate friction and wear in micro-electromechanical systems. In this study, the atomic friction properties of graphene/graphene, WS2/WS2, and graphene/WS2 bilayer heterostructure systems were examined through density functional theory simulations. Results indicated that the friction strength of the graphene/WS2 bilayer heterostructure system was lower than that of the graphene/graphene and WS2/WS2 systems. Specifically, the graphene/WS2 bilayer heterostructure system demonstrated ultra-low friction coefficients ranging from 0.0006 to 0.0096, resulting in friction strengths in the range of 10^−3 nN. Furthermore, the heightened electrostatic repulsion and smooth potential energy fluctuation helped reduce friction, validating the superlubricity performance of the graphene/WS2 heterostructure system.

层状二维纳米材料,如石墨烯和WS2,具有超润滑性能,因此为减轻微机电系统中的摩擦和磨损提供了一个有前途的解决方案。本研究通过密度泛函理论模拟研究了石墨烯/石墨烯、WS2/WS2和石墨烯/WS2双层异质结构体系的原子摩擦性能。结果表明,石墨烯/WS2双层异质结构体系的摩擦强度低于石墨烯/石墨烯和WS2/WS2体系。具体而言,石墨烯/WS2双层异质结构体系的摩擦系数在0.0006至0.0096之间,摩擦强度在10^−3 nN之间。此外,增强的静电斥力和平滑的势能波动有助于减少摩擦,验证了石墨烯/WS2异质结构体系的超润滑性能。
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引用次数: 0
Prediction of Wear in Start–Stop Systems Using Continuum Damage Mechanics 基于连续损伤力学的启停系统磨损预测
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-12-02 DOI: 10.1007/s11249-024-01943-4
Soroosh Salehi, Sahar Ghatrehsamani, Saleh Akbarzadeh, M. M. Khonsari

A vehicle start–stop system automatically shuts down and restarts the internal combustion engine to reduce the time the engine spends idling, thereby reducing fuel consumption and emissions. For the start–stop system to work, the engine must be at a certain temperature and conditions. If the engine is too hot, the system may not activate. This study explores the tribological characteristics of the start–stop system by applying principles of Continuum Damage Mechanics (CDM) to predict both the lifespan and wear volume subsequent to the start–stop cycles. A series of pin-on-disk tests were conducted to evaluate the efficacy of the modeling and predictions. The results from these tests were compared to the CDM predictions, demonstrating satisfactory accuracy. Additionally, a Finite Element Method (FEM) analysis was employed to model temperature variations during the start–stop cycles. Findings indicate that an increase in consecutive start–stop cycles impedes the system’s ability to sufficiently cool, thereby increasing wear. Conversely, extending the duration of the stop phase reduces wear and enhances the system’s lifespan.

车辆启停系统自动关闭并重新启动内燃机,以减少发动机的空转时间,从而减少燃料消耗和排放。为了使启停系统工作,发动机必须处于一定的温度和条件下。如果发动机过热,系统可能无法启动。本研究通过应用连续损伤力学(CDM)原理来预测启停循环后的使用寿命和磨损量,探讨了启停系统的摩擦学特性。进行了一系列针盘试验,以评估建模和预测的有效性。这些测试的结果与CDM预测结果进行了比较,显示出令人满意的准确性。此外,采用有限元法(FEM)模拟了启停循环过程中的温度变化。研究结果表明,连续启停周期的增加阻碍了系统充分冷却的能力,从而增加了磨损。相反,延长停止阶段的持续时间可以减少磨损,提高系统的使用寿命。
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引用次数: 0
Study on Tribological Properties of Gear Material PA66 Reinforced by Glass Fibers 玻璃纤维增强 PA66 齿轮材料的摩擦学特性研究
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-27 DOI: 10.1007/s11249-024-01941-6
Xinmin Li, Zhengjie Qiu, Wing San Tony Hung, Ulf Olofsson, Löwer Manuel, Chaoqun Duan

Polyamide 66 (PA66) is one of the commonly used polymer gear materials. This paper focuses on the tribological properties of glass fiber reinforced PA66 composites in self-mated contact using a pin-on-disc tribometer. The effects of glass fiber content, PV (the product of the contact pressure and sliding speed), and lubrication on the tribological properties of the specimens are also investigated. The results show that the glass fiber reinforced PA66 exhibit higher coefficients of friction and specific wear rates than PA66 under dry sliding conditions. This is probably due to the peeled glass fibers during the sliding process acting as abrasive particles which have an aggressive effect on the surface. Under grease lubricated conditions, PA66 + 33% GF has the lowest coefficient of friction and specific wear rate due to its higher strength. Under dry sliding conditions, all specimens show the highest friction coefficient and specific wear rate at 30 MPa·m/s with the change of PV value. Under grease lubricated conditions, all specimens show the highest friction coefficient and specific wear rate at 4 MPa·m/s with the change of PV value. The addition of grease improves friction and wear of PA66 composites under most of the experimental conditions. However, the specific wear rates of PA66 and PA66 + 13% GF under grease lubrication are higher than those under dry sliding conditions at low PV values. This may be due to the fact that greases can reduce the surface mechanical strength of PA66 and PA66 + 13% GF.

Graphical abstract

聚酰胺 66(PA66)是常用的聚合物齿轮材料之一。本文使用针盘摩擦磨损试验机重点研究了玻璃纤维增强 PA66 复合材料在自啮合接触中的摩擦学特性。同时还研究了玻璃纤维含量、PV(接触压力与滑动速度的乘积)和润滑对试样摩擦学特性的影响。结果表明,在干滑动条件下,玻璃纤维增强 PA66 比 PA66 表现出更高的摩擦系数和特定磨损率。这可能是由于在滑动过程中剥离的玻璃纤维充当了研磨颗粒,对表面产生了侵蚀作用。在油脂润滑条件下,PA66 + 33% GF 的摩擦系数和比磨损率最低,这是因为其强度较高。在干滑动条件下,随着 PV 值的变化,所有试样在 30 MPa-m/s 时的摩擦系数和比磨损率都最高。在油脂润滑条件下,随着 PV 值的变化,所有试样在 4 MPa-m/s 时的摩擦系数和特定磨损率都最大。在大多数实验条件下,添加润滑脂可改善 PA66 复合材料的摩擦和磨损。然而,在低 PV 值条件下,PA66 和 PA66 + 13% GF 在润滑脂润滑下的特定磨损率高于干滑动条件下的磨损率。这可能是由于润滑脂会降低 PA66 和 PA66 + 13% GF 的表面机械强度。
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引用次数: 0
Effect of Humidity on the Wear Behavior of Graphene Under Current Carrying Conditions 湿度对载流条件下石墨烯磨损行为的影响
IF 2.9 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-26 DOI: 10.1007/s11249-024-01946-1
Qian Tang, Yuehua Huang, Deen Sun, Qunyang Li

Wear problem has become an important issue limiting the functionality and lifetime of sliding electrical contact components. Adding conductive solid lubricants is a potential means of improving the tribological performance of these devices. Graphene, a two-dimensional material with excellent electrical conductivity and lubrication property, has been proposed to be a promising candidate for such applications. However, the tribological performance graphene has been demonstrated to be very susceptible to humidity even under non-current-carrying conditions. In this work, we study the effect of humidity on the wear behavior of graphene in the sliding electrical contact interfaces. The tribological behaviors of graphene under 10%, 30%, 60%, and 90% relative humidity conditions and 1 A current are investigated. The results show that the humidity can effectively slow down the wear of graphene in the sliding electrical contact interface by two key mechanisms. Firstly, as revealed by the infrared temperature measurements, higher humidity can significantly reduce the Joule heating. Secondly, X-ray photoelectron spectroscopy shows that with the existence of the electric current, at high humidity water molecules can passivate the graphene carbon dangling bonds more readily thereby reducing oxidation and slowing down the wear process. At low humidity, Joule heating not only caused graphene to oxidize but also accelerated the evaporation of water molecules, which was not conducive to its passivation, resulting in severe wear of the graphene.

磨损问题已成为限制滑动电接触元件功能和使用寿命的一个重要问题。添加导电固体润滑剂是改善这些设备摩擦学性能的潜在方法。石墨烯是一种二维材料,具有优异的导电性和润滑性,被认为是此类应用的理想候选材料。然而,石墨烯的摩擦学性能已被证明非常容易受到湿度的影响,即使在非载流条件下也是如此。在这项工作中,我们研究了湿度对石墨烯在滑动电接触界面中磨损行为的影响。研究了石墨烯在 10%、30%、60% 和 90% 的相对湿度和 1 A 电流条件下的摩擦学行为。结果表明,湿度可以通过两种关键机制有效减缓石墨烯在滑动电接触界面中的磨损。首先,红外温度测量结果表明,较高的湿度可以显著降低焦耳热。其次,X 射线光电子能谱显示,在电流存在的情况下,高湿度下水分子更容易钝化石墨烯碳悬键,从而减少氧化,减缓磨损过程。而在低湿度条件下,焦耳加热不仅会导致石墨烯氧化,还会加速水分子的蒸发,不利于石墨烯的钝化,从而导致石墨烯严重磨损。
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引用次数: 0
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