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Defining Scuffing Phases via Friction Evolution and Surface Analysis Through Experiments Using Castor Oil Biolubricant 用蓖麻油生物润滑剂通过摩擦演化和表面分析来确定磨损阶段
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-26 DOI: 10.1007/s11249-025-02073-1
R. H. S. Souza, G. Lasch, A. A. Rodrigues, G. S. Gehlen, L. Y. Barros, J. C. Poletto, P. Stradolini, C. L. Petzhold, N. F. Ferreira, P. D. Neis

Scuffing is a severe wear mode that occurs under boundary lubrication. This wear mode remains challenging to predict, and no objective criteria have been established in the literature to characterize the evolution of the phenomenon across the distinct phases of frictional behavior. This study proposes a quantitative method to characterize the three typical scuffing phases (stable, incipient, and severe) based on friction force evolution. Block-on-ring tests were conducted using SAE 52100 steel and two biolubricants: pure castor oil (CO) and aminolyzed castor oil (ACO). A mathematical approach was developed by analyzing the variation of friction force (delta friction) across discretized time intervals. Real-time imaging enabled direct correlation between friction behavior and surface damage. SEM/EDS analyses revealed that the material accumulated during severe scuffing consisted of oxidized oil and steel particles. The dynamic of formation and destruction of these accumulated material explains the observed friction instabilities. The proposed method successfully identified all scuffing phases across tests and was validated by consistent morphological and chemical evidence. ACO significantly increased the time to reach severe scuffing compared to CO, with results confirmed by Weibull statistical analysis. The approach presented herein provides a robust and replicable framework for scuffing characterization and supports the application of chemically modified biolubricants as sustainable alternatives with enhanced tribological performance.

磨损是在边界润滑下发生的一种严重磨损模式。这种磨损模式的预测仍然具有挑战性,并且在文献中没有建立客观的标准来描述这种现象在摩擦行为的不同阶段的演变。本研究提出了一种基于摩擦力演化的定量方法来表征三个典型磨损阶段(稳定阶段、初期阶段和严重阶段)。采用SAE 52100钢和两种生物润滑剂(纯蓖麻油(CO)和氨基水解蓖麻油(ACO))进行了环块试验。通过分析摩擦力(δ摩擦力)在离散时间间隔上的变化,提出了一种数学方法。实时成像可以将摩擦行为与表面损伤直接联系起来。SEM/EDS分析表明,在严重磨损过程中积累的物质由氧化油和钢颗粒组成。这些累积物质的形成和破坏的动力学解释了观察到的摩擦不稳定性。该方法成功地识别了所有磨损阶段,并通过一致的形态和化学证据进行了验证。与CO相比,ACO显著增加了达到严重磨损的时间,Weibull统计分析证实了这一结果。本文提出的方法为磨损表征提供了一个可靠且可复制的框架,并支持化学改性生物润滑剂作为具有增强摩擦学性能的可持续替代品的应用。
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引用次数: 0
Research on Fractal Modeling of Hard-Coated Rough Surface Contact Considering the Mechanism of Elastic–Plastic Deformation 考虑弹塑性变形机理的硬质涂层粗糙表面接触分形建模研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-25 DOI: 10.1007/s11249-025-02071-3
Yizhang Lian, Xueliang Zhang, Nanshan Wang, Yonghui Chen, Shanjun Liao

This study develops an elastoplastic fractal contact model for rough hard-coated surfaces along, with a corresponding contact stiffness model based, on a coated asperity contact model and a statistical rough surface contact model. To establish the contact stiffness model for the coated surface asperities, seven fundamental postulates were developed. Numerical simulations were conducted to systematically analyze the influence of the ratio between the coating thickness and the asperity radius, the material properties of the coating and the substrate, and the substrate surface roughness on the contact behavior and stiffness of the coated surfaces. The results demonstrate that under a given load, hard-coated rough surfaces exhibit a smaller real contact area but higher stiffness compared to uncoated surfaces. Thicker and stiffer coatings further reduce the contact area while increasing stiffness. Smoother substrate surfaces lead to a larger contact area and higher stiffness in the coated systems. These findings align with the existing statistical contact models for hard-coated rough surfaces, and the predicted contact area closely matches the prior simulation results. To validate the model, experimental tests were conducted on the TiN-coated specimens. The theoretically predicted contact stiffness showed strong agreement with the experimental measurements, confirming the accuracy and applicability of the proposed fractal-based stiffness model.

本研究建立了粗糙硬涂层表面的弹塑性分形接触模型,并在此基础上建立了相应的接触刚度模型。为了建立涂层表面凹凸不平的接触刚度模型,提出了7个基本假设。通过数值模拟,系统分析了涂层厚度与粗糙度半径之比、涂层与基体的材料性能、基体表面粗糙度对涂层表面接触行为和刚度的影响。结果表明,在给定载荷下,硬涂层粗糙表面的实际接触面积比未涂层表面小,但刚度更高。更厚和更硬的涂层进一步减少了接触面积,同时增加了刚度。更光滑的基材表面导致涂层系统中更大的接触面积和更高的刚度。这些发现与现有硬涂层粗糙表面的统计接触模型一致,预测的接触面积与先前的模拟结果非常吻合。为了验证模型的有效性,对镀锡试样进行了实验测试。理论预测的接触刚度与实验测量结果吻合较好,验证了分形刚度模型的准确性和适用性。
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引用次数: 0
Sliding Friction of Hard Sliders on Rubber: Theory and Experiment 硬滑块在橡胶上的滑动摩擦:理论与实验
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-17 DOI: 10.1007/s11249-025-02064-2
R. Xu, B. N. J. Persson

We present a study of sliding friction for rigid triangular steel sliders on soft rubber substrates under both lubricated and dry conditions. For rubber surfaces lubricated with a thin film of silicone oil, the measured sliding friction at room temperature agrees well with theoretical predictions obtained from a viscoelastic model originally developed for rolling friction. On the lubricated surface, the sliding friction is primarily due to bulk viscoelastic energy dissipation in the rubber. The model, which includes strain-dependent softening of the rubber modulus, accurately predicts the experimental friction curves. At lower temperatures ((T = -20^circ textrm{C}) and (-40^circ textrm{C})), the measured friction exceeds the theoretical prediction. We attribute this increase to penetration of the lubricant film by surface asperities, leading to a larger adhesive contribution. For dry surfaces, the adhesive contribution becomes dominant. By subtracting the viscoelastic component inferred from the lubricated case, we estimate the interfacial frictional shear stress. This shear stress increases approximately linearly with the logarithm of the sliding speed, consistent with stress-augmented thermal activation mechanisms.

我们提出了在润滑和干燥条件下软橡胶基板上的刚性三角形钢滑块滑动摩擦的研究。对于用硅油薄膜润滑的橡胶表面,在室温下测量的滑动摩擦与最初为滚动摩擦开发的粘弹性模型的理论预测吻合得很好。在润滑表面,滑动摩擦主要是由于橡胶中的大块粘弹性能量耗散。该模型考虑了橡胶模量随应变的软化,能够准确地预测实验摩擦曲线。在较低的温度下((T = -20^circ textrm{C})和(-40^circ textrm{C})),测量的摩擦超过理论预测。我们将这种增加归因于表面凸起对润滑膜的渗透,从而导致更大的粘合剂贡献。对于干燥的表面,粘合剂的贡献成为主导。通过减去从润滑情况推断的粘弹性分量,我们估计了界面摩擦剪应力。剪切应力随滑动速度的对数近似线性增加,与应力增强热激活机制一致。
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引用次数: 0
Achieving Ultra-Low Friction in Ti-6Al-4 V Alloy: Hydration Lubrication Mechanisms of HEC-Glycerol Composite 在ti - 6al - 4v合金中实现超低摩擦:hec -甘油复合材料的水化润滑机制
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-17 DOI: 10.1007/s11249-025-02068-y
Dezun Sheng, Hongliang Yu, Xiao Zhang, Xin Zhou

Reducing alloy friction to achieve ultra-low friction is a valuable approach to save energy and reduce pollution from oil use, which is a major challenge for researchers. This study introduces a successful method to achieve ultra-low friction in Ti-6Al-4 V using a hydrated lubricant composed of hydroxyethyl cellulose (HEC). And the effects of speed and concentration on lubricating were investigated. It was found that excessive sliding speeds may lead to lubricant detachment and consequent friction increase, indicating that the adsorption ability of HEC needs to be enhanced in future studies. In addition, when the concentration exceeds 5 wt%, wear loss tends to stabilize across tests with different concentrations, while the friction force increases with rising concentrations. Based on these findings, microscopic studies were conducted to investigate the mechanism of friction reduction. Notably, distinct topographic features resembling ‘valleys’ and ‘plateaus’ were identified on the wear scars in a nanoscale scope. The movement of the surfaces induces the hydrated HEC lubricant to flow from the lower valleys to the higher plateaus, suggesting elastohydrodynamic lubrication mechanisms to form robust films. The valleys serve as lubricant reservoirs, while the plateau tops support the lubricant films to prevent contacts between Ti-6Al-4 V and Si3N4. The schematic illustrations depict the microscopic mechanisms for achieving of ultra-low friction on Ti-6Al-4 V alloy.

降低合金摩擦以实现超低摩擦是一种有价值的节能和减少石油污染的方法,也是研究人员面临的主要挑战。本研究介绍了一种利用由羟乙基纤维素(HEC)组成的水合润滑剂在ti - 6al - 4v中实现超低摩擦的成功方法。考察了转速和浓度对润滑性能的影响。研究发现,过大的滑动速度可能导致润滑油脱离,从而导致摩擦增加,这表明HEC的吸附能力需要在未来的研究中得到加强。此外,当浓度超过5wt %时,不同浓度下的磨损量趋于稳定,而摩擦力随浓度的增加而增加。基于这些发现,进行了微观研究,以探讨摩擦减少的机制。值得注意的是,在纳米尺度范围内,在磨损痕上发现了类似“山谷”和“高原”的独特地形特征。表面的运动诱导水合HEC润滑剂从较低的山谷流向较高的高原,表明弹性流体动力润滑机制形成坚固的膜。山谷作为润滑剂储层,而高原顶部支撑润滑膜,防止ti - 6al - 4v和Si3N4接触。原理图描述了ti - 6al - 4v合金实现超低摩擦的微观机理。
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引用次数: 0
Laser-Induced Fluorescence (LIF) Method-Based Research on the Influence of Textured Water-Lubricated UHMWPE Bearing Tribological Performance 基于激光诱导荧光(LIF)方法的织构水润滑超高分子量聚乙烯轴承摩擦学性能影响研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-12 DOI: 10.1007/s11249-025-02070-4
Haixian Song, Haideng Mu, Dequan Zhu, Quan Zheng, Fuming Kuang

The surface texturing of water-lubricated ultra-high molecular weight polyethylene (UHMWPE) bearing has the advantages of enhancing the hydrodynamic effect, capturing wear debris, reducing secondary friction, and storing water, and is one of the research hotspots in tribology. However, the influence of the surface texture of water-lubricated UHMWPE bearing on the friction performance of bearing is still unclear. Based on the laser induced fluorescence (LIF) method, this study developed an in situ-visualization observation system for water film on the friction interface of non-metallic bearing with the help of transparent glass friction pair. The typical textures with different area ratios, aspect ratios and distribution angles were used as the research objects. The water film thickness, friction coefficient and surface morphology of the friction interface of UHMWPE bearing with different textures under low-speed and heavy-load conditions were analyzed. The results show that elongated textures with a reasonable area ratio and length-to-width ratio, arranged along the direction of friction, are more likely to form hydrodynamic effects and create strong support points at the friction interface. Additionally, the divergent and convergent spaces formed at the inlet and outlet of the textured units cause the lubrication pressure at the inlet to be lower than that at the outlet, resulting in severer wear at the inlet compared to the outlet. The overall trends and the mechanism discussed in this research may be considered as a guideline for the design and optimization of surface texture of water-lubricated UHMWPE bearing.

水润滑超高分子量聚乙烯(UHMWPE)轴承的表面织构具有增强流体动力效应、捕获磨损碎屑、减少二次摩擦、储水等优点,是摩擦学领域的研究热点之一。然而,水润滑UHMWPE轴承表面织构对轴承摩擦性能的影响尚不清楚。基于激光诱导荧光(LIF)方法,研制了一种基于透明玻璃摩擦副的非金属轴承摩擦界面水膜的现场可视化观测系统。以不同面积比、纵横比和分布角度的典型纹理为研究对象。分析了低速和重载条件下不同质地超高分子量聚乙烯轴承摩擦界面的水膜厚度、摩擦系数和表面形貌。结果表明:沿摩擦方向排列具有合理面积比和长宽比的细长织构更容易形成水动力效应,并在摩擦界面处形成强支撑点;此外,在织构单元的进出口处形成发散和收敛的空间,导致进口处的润滑压力低于出口处的润滑压力,导致进口处的磨损比出口处严重。本文研究的总体趋势和机理可为水润滑超高分子量聚乙烯轴承表面织构的设计和优化提供指导。
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引用次数: 0
Effects of High-Temperature Annealing on the Frictional Properties of Graphene 高温退火对石墨烯摩擦性能的影响
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-11 DOI: 10.1007/s11249-025-02065-1
Wenjie He, Yu Zhang, Qiang He, Wen Wang

Due to the high surface-to-volume ratio, micro/nano-electromechanical systems (MEMS/NEMS) undergo severe wear during the relative sliding. Graphene, possessing excellent mechanical, physical, and chemical properties, can achieve an ultralow friction and wear state, making it highly promising for significantly minimizing friction and wear in MEMS/NEMS. However, graphene films used in MEMS/NEMS are typically subjected to thermal annealing pretreatment during the fabrication process. To maintain optimal performance, it is particularly necessary to investigate the evolution of graphene tribological properties after high-temperature annealing. In this article, by performing nanoscale atomic force microscopy (AFM) measurements on mechanically exfoliated graphene, we reveal that the friction force on graphene decreases slightly upon annealing to approximately 200 °C, then gradually increases before rising rapidly once the annealing temperature exceeds 500 °C. Raman spectroscopy identifies that the changes in friction result from the annealing-induced compressive stress accumulation and defects creation. Our results provide deep insights for the application of graphene in sliding MEMS/NEMS.

Graphical Abstract

由于高表面体积比,微/纳米机电系统(MEMS/NEMS)在相对滑动过程中会遭受严重的磨损。石墨烯具有优异的机械、物理和化学性能,可以实现超低摩擦和磨损状态,在MEMS/NEMS中具有极大的应用前景。然而,用于MEMS/NEMS的石墨烯薄膜通常在制造过程中进行热退火预处理。为了保持最佳性能,研究石墨烯高温退火后摩擦学性能的演变尤为必要。在本文中,通过对机械剥离的石墨烯进行纳米尺度原子力显微镜(AFM)测量,我们发现石墨烯上的摩擦力在退火至约200℃时略有下降,然后逐渐增加,一旦退火温度超过500℃时迅速上升。拉曼光谱分析表明,摩擦的变化是由退火引起的压应力积累和缺陷产生引起的。我们的研究结果为石墨烯在滑动MEMS/NEMS中的应用提供了深刻的见解。图形抽象
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引用次数: 0
Friction Reduction Behavior of Polyacrylic Acid Solutions Driven by Molecular Structure and Adsorption Stability 分子结构和吸附稳定性驱动聚丙烯酸溶液的减摩行为
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-08 DOI: 10.1007/s11249-025-02066-0
Cheng Zheng, Jimin Xu, Haiyang Gu, Lin Sun, Juchen Zhang, Kun Liu, Tomoko Hirayama

In the context of low-viscosity aqueous lubrication, this study systematically investigates the lubrication mechanisms of polyacrylic acid (PAA) solutions. It combines experimental techniques with molecular dynamics simulations to elucidate the effects of concentration-dependent molecular structures and temperature-dependent adsorption stability. Results show that with increasing PAA concentration, the friction coefficient first decreases and then increases, with optimal lubrication observed at 0.2%. Higher concentrations lead to increased PAA adsorption, elevated acidity, and molecular aggregation, resulting in surface corrosion and intensified wear. At high temperatures, while adsorption energy remains stable, enhanced chain flexibility and entanglement raise viscosity, reduce film fluidity, and accelerate wear. These findings provide valuable insights for optimizing water-based lubrication systems using PAA additives.

Graphical Abstract

在低粘度水润滑的背景下,本研究系统地研究了聚丙烯酸(PAA)溶液的润滑机理。它将实验技术与分子动力学模拟相结合,阐明了浓度依赖的分子结构和温度依赖的吸附稳定性的影响。结果表明:随着PAA浓度的增加,摩擦系数先减小后增大,在0.2%时润滑效果最佳;较高的浓度会导致PAA吸附增加、酸度升高和分子聚集,从而导致表面腐蚀和磨损加剧。在高温下,在吸附能保持稳定的同时,增强的链柔韧性和缠结会提高粘度,降低膜的流动性,加速磨损。这些发现为优化使用PAA添加剂的水基润滑系统提供了有价值的见解。图形抽象
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引用次数: 0
Enhanced Tribological Modelling of Violin Rosin 小提琴松香的增强摩擦学建模
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-03 DOI: 10.1007/s11249-025-02062-4
Jim Woodhouse, Paul Galluzzo

Accurate simulation of the motion of a bowed violin string requires a reliable tribological model for rosin, with which the bow-hairs are coated. None of the models proposed in the past have given entirely satisfactory results. An enhanced model is proposed here, which combines influences from the contact temperature and the sliding speed. Transient vibration predictions using this model are compared with earlier experimental measurements in the “Guettler diagram”, demonstrating better agreement than with earlier models.

要精确模拟小提琴琴弦的弯曲运动,就需要一个可靠的松香摩擦学模型,因为弓毛是涂在松香上的。过去提出的模型都没有给出完全令人满意的结果。本文提出了一种结合接触温度和滑动速度影响的增强模型。在“Guettler图”中,将使用该模型的瞬态振动预测与早期的实验测量结果进行了比较,显示出比早期模型更好的一致性。
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引用次数: 0
On the Dependence of Static Friction Coefficient on Normal Load 论静摩擦系数对法向载荷的依赖关系
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-03 DOI: 10.1007/s11249-025-02061-5
Michele Ciavarella

In recent interesting experiments, Peng et al. ((2015) PRL, 134, 176202) have shown that the static friction coefficient in a spherical contact drops of a factor close to 2 over 3 decades of increase of normal load, converging to a dynamic friction coefficient. The difference is larger than what commonly attributed in dry metals. They have interpreted this with a numerical boundary integral contact calculations involving many asperities using two input parameters (a static and a dynamic friction coefficient from AFM experiments at nanoscale). However, we show that similar drop with normal load is also expected from the theory of "Griffith" or "JKR" friction (Ciavarella (2015) J Mech Phys Solids 84: 313–324) which has the advantage of being a simple analytical theory and also of being closely connected with friction laws used commonly today in geophysics. Further, it also uses two input parameters, and requires no numerical solution of the rough contact problem for the sphere.

在最近有趣的实验中,Peng等人((2015)PRL, 134, 176202)表明,在30年的法向载荷增加中,球面接触的静摩擦系数下降了近2个因子,收敛为动摩擦系数。这种差异比通常认为是干金属的差异要大。他们用两个输入参数(纳米尺度AFM实验的静态和动态摩擦系数)对涉及许多凹凸不平的数值边界积分接触计算进行了解释。然而,我们表明,从“Griffith”或“JKR”摩擦理论(Ciavarella (2015) J Mech Phys Solids 84: 313-324)中也可以预期正常载荷下的类似下降,该理论具有简单分析理论的优势,并且与当今地球物理学中常用的摩擦定律密切相关。此外,它还使用了两个输入参数,并且不需要对球体的粗糙接触问题进行数值求解。
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引用次数: 0
Robustness and Sensitivity of the Λ*-Ratio in Microelastohydrodynamic Lubrication 微弹流润滑中({{varLambda }}^{{*}}) -比的鲁棒性和灵敏度
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-09-03 DOI: 10.1007/s11249-025-02060-6
Jonny Hansen, Deepak K. Prajapati, Marcus Björling, Roland Larsson

This study builds upon the work published by Hansen et al. (Tribol Lett 69:1–17, 2021), which introduced a revised film parameter, ({Lambda }^{*}={({h}_{text{m}}+h}_{text{c}}{f}_{text{q}})/Spk), for evaluating rough surface contacts in the microelastohydrodynamic (micro-EHL) and mixed lubrication (ML) regimes. The parameter incorporates a micro-EHL correction term (({f}_{text{q}})) that accounts for different roughness lays (or pattern), the reduced peak height parameter ((Spk)) for more relevant roughness representation, and an updated criterion for the EHL-to-ML transition (({Lambda }^{*}=1)). These advancements address the limitations of the traditional (Lambda)-ratio by offering improved sensitivity to running-in wear, resilience to measurement artefacts, and more realistic predictions of lubrication quality. In the present study, we investigate how measurement and calculation methods influence the robustness and sensitivity of the ({Lambda }^{*})-ratio. Key considerations include the impact of spatial resolution from surface roughness measurements, the sensitivity of asperity summit radius calculation methods, and the use of amplitude reduction theory (ART) as an alternative approach to compute ({Lambda }^{*}) and benchmark its performance. Within the given scope, the results show that spatial biases can be mitigated with appropriate filter sizes and that ({Lambda }^{*}) consistently predicts the EHL–ML transition more accurately than the traditional Λ-ratio, regardless of the asperity radius method used. Furthermore, we found that while ART can be used to compute ({Lambda }^{*}), the original approach using the ({f}_{text{q}})-term offers both overall improved accuracy and simplicity. By critically assessing key uncertainties with ({Lambda }^{*}), this study strengthens the parameter's robustness and enhances its applicability as a reliable tool for analysing and designing tribological systems.

这项研究建立在Hansen等人(Tribol Lett 69:1 - 17,2021)发表的研究成果的基础上,该研究引入了一个修订的膜参数({Lambda }^{*}={({h}_{text{m}}+h}_{text{c}}{f}_{text{q}})/Spk),用于评估微弹性流体动力学(micro-EHL)和混合润滑(ML)体系中的粗糙表面接触。该参数包含一个micro-EHL校正项(({f}_{text{q}})),用于解释不同的粗糙度层(或模式),减少的峰高参数((Spk))用于更相关的粗糙度表示,以及ehl到ml转换的更新标准(({Lambda }^{*}=1))。这些进步解决了传统(Lambda) -比率的局限性,提高了对磨合磨损的灵敏度,对测量工件的弹性,以及对润滑质量的更现实的预测。在本研究中,我们探讨测量和计算方法如何影响({Lambda }^{*}) -比率的稳健性和灵敏度。关键考虑因素包括表面粗糙度测量对空间分辨率的影响,粗糙顶点半径计算方法的敏感性,以及使用减幅理论(ART)作为计算({Lambda }^{*})和基准性能的替代方法。在给定的范围内,结果表明,适当的过滤器大小可以减轻空间偏差,并且无论使用何种粗糙半径方法,({Lambda }^{*})都比传统的Λ-ratio更准确地预测EHL-ML过渡。此外,我们发现虽然ART可用于计算({Lambda }^{*}),但使用({f}_{text{q}}) -term的原始方法提供了总体上提高的准确性和简单性。通过使用({Lambda }^{*})对关键不确定性进行批判性评估,本研究增强了参数的鲁棒性,并增强了其作为分析和设计摩擦学系统的可靠工具的适用性。
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引用次数: 0
期刊
Tribology Letters
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