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Research on the Differences Between the Stick-Slide and Roll-Slide Friction Behaviors of Third-Body Colloidal Particles 第三体胶体颗粒粘滑与滚滑摩擦行为差异研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-16 DOI: 10.1007/s11249-025-02086-w
Chunsheng Luo, Keke Xu, Zhanyun Deng, Honglin Gou, Chen Xiao, Steven E. Franklin, Linmao Qian, Lei Chen

The tribo-dynamic behaviors of third-body colloidal particles (CPs) at the soft–hard contact interface significantly impact the substrate surface performance. To explore the differences of the stick-slide and roll-slide tribo-dynamic behaviors of CPs, the tribological behaviors of fixed and free CPs on hydrophilic silicon substrates were investigated using the colloid probe and nano-manipulation technology in atomic force microscopy, respectively. In contrast to the velocity-enhanced static friction commonly observed in fixed CPs, the static friction of free CPs exhibits a logarithmic decrease with increasing velocity. This phenomenon can be attributed to the transition from a “sliding-dominated” to a “rolling-dominated” driving state of the CPs as velocity increases. The findings enhance the understanding of tribo-dynamic behaviors of CPs at the nanoscale and provide a foundation for the deliberate design and optimization of CP-based applications in chemical mechanical polishing (CMP) and post-CMP cleaning technologies.

第三体胶体颗粒(CPs)在软硬接触界面处的摩擦动力学行为对衬底表面性能有显著影响。为了探究CPs的粘滑和滚滑摩擦动力学行为的差异,分别利用胶体探针和原子力显微镜纳米操作技术研究了固定和游离CPs在亲水性硅衬底上的摩擦动力学行为。与固定cp中通常观察到的速度增强静摩擦相反,自由cp的静摩擦随着速度的增加而呈对数递减。这种现象可以归因于随着速度的增加,CPs的驱动状态从“滑动主导”转变为“滚动主导”。该研究结果增强了对纳米级CPs摩擦动力学行为的理解,并为有意设计和优化基于cp的化学机械抛光(CMP)和后CMP清洁技术的应用提供了基础。
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引用次数: 0
Mechanical and Tribological Performance of Magnetron-Sputtered MoS2–ZrN Composite Coatings: A Combined Experimental and Modeling Study 磁控溅射MoS2-ZrN复合涂层的力学和摩擦学性能:实验和模型相结合的研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-07 DOI: 10.1007/s11249-025-02090-0
P. O. Bukovskiy, Ahraf Gulzar, A. A. Yakovenko, I. G. Goryacheva, Shahid Saleem, M. F. Wani, Rakesh Sehgal

In this paper, MoS2–ZrN composite coatings with a Chromium interlayer were fabricated using magnetron sputtering technique. The structure and properties of the MoS2–ZrN composite coatings with different ZrN contents were systematically investigated. It was observed that both hardness and elastic modulus improved with increasing ZrN content, reaching peak values of 6.60 GPa and 109.95 GPa, respectively, at 30% ZrN. Tribological performance was assessed using steel balls with varying surface roughness, where the lowest coefficient of friction of 0.09 was recorded when the coating was paired with a smoother counterface. Abrasive wear was identified as the dominant wear mechanism. Additionally, a contact mechanics model was developed to describe the interaction between a rough spherical indenter and the coating surface. This model enabled analysis of how surface roughness and coating mechanical properties jointly affect macroscopic contact parameters, such as real and nominal pressure distributions and contact radius. A good qualitative agreement was found between the experimental results and theoretical predictions, confirming the model's validity.

Graphical Abstract

本文采用磁控溅射技术制备了含铬中间层的MoS2-ZrN复合镀层。系统地研究了不同ZrN含量的MoS2-ZrN复合镀层的结构和性能。随着ZrN含量的增加,合金的硬度和弹性模量均有所提高,在ZrN含量为30%时,硬度和弹性模量分别达到6.60 GPa和109.95 GPa的峰值。使用不同表面粗糙度的钢球来评估摩擦学性能,当涂层与更光滑的表面配对时,摩擦系数最低,为0.09。磨粒磨损是主要的磨损机制。此外,建立了一个接触力学模型来描述粗糙球形压头与涂层表面之间的相互作用。该模型能够分析表面粗糙度和涂层力学性能如何共同影响宏观接触参数,如实际压力分布和公称压力分布以及接触半径。实验结果与理论预测有很好的定性一致性,证实了模型的有效性。图形抽象
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引用次数: 0
A Thermodynamic Insight into the Speed Dependence of Brass Sliding Wear Process 黄铜滑动磨损过程速度依赖性的热力学分析
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-04 DOI: 10.1007/s11249-025-02084-y
Kai Chen, Shuaishuai Zeng, Xiang Li, Dongdong Zhou, Xianfa Li, Yi Liu

This study examined the impact of sliding speed on the wear process of brass by integrating thermodynamic principles with molecular dynamics simulation. The simulation findings indicate that as the sliding speed increases, the strain rate of the workpiece rises while the tensile stress decreases and the compressive stress increases. Consequently, the tangential force remains constant regardless of sliding speed, whereas the normal force increases with higher speeds. Additionally, the temperature of the workpiece rises with increasing sliding speed, leading to a more significant thermal softening effect. Due to the interplay between strain rate hardening and thermal softening, the wear of the workpiece initially decreases and then increases as the sliding speed continues to rise. The specific wear rate, specific wear amount, and degradation coefficient all decrease with increasing sliding speed, suggesting that cutting becomes more challenging at higher speeds. Therefore, careful consideration is necessary when selecting the cutting speed to achieve efficient machining. This study serves as a valuable reference for the machining of metal materials.

采用热力学原理与分子动力学模拟相结合的方法,研究了滑动速度对黄铜磨损过程的影响。仿真结果表明,随着滑动速度的增加,工件的应变速率增大,拉应力减小,压应力增大。因此,无论滑动速度如何,切向力保持不变,而法向力随着速度的增加而增加。此外,随着滑动速度的增加,工件温度升高,导致更显著的热软化效应。由于应变速率硬化和热软化的相互作用,随着滑动速度的继续增加,工件的磨损先减小后增大。比磨损率、比磨损量和退化系数都随着滑动速度的增加而降低,这表明在更高的速度下切削变得更具挑战性。因此,在选择切削速度时必须仔细考虑,以实现高效的加工。该研究为金属材料的加工提供了有价值的参考。
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引用次数: 0
Research on the Effects of Roughness, Load, and Speed on Rubber-Ice Friction 粗糙度、载荷和速度对橡胶-冰摩擦影响的研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-03 DOI: 10.1007/s11249-025-02088-8
Manjiang Niu, XiaoQian Hou, Wenzhen Yang, Aiqin Wu, Yu Zhang, Hongzhen Wang

Three different reinforcing fillers were selected for winter tire tread rubber. After improving the testing method using the LAT100 testing machine, tests were conducted on the effect of rubber surface roughness on ice grip and wet grip performance, as well as research on the effect of load and speed on the rubber-ice friction coefficient at different temperatures. The results showed that with the increase of the macroscopic roughness of the rubber surface, the frictional force between the rubber and the ice surface decreased, the frictional force between the rubber and the wet road surface increased; With the increase of load and speed, the friction coefficient of rubber on the ice surface decreases, and the change is more obvious on the – 15 ℃ ice surface compared to the – 5 ℃ ice surface, and the friction coefficient on the – 15 ℃ dry ice surface is greater than that on the – 5 ℃ wet ice surface; In order to better predict the results of the real vehicle test, in the LAT ice friction test, the load was selected from 75 to 100N, the speed was selected from 0.6 km/h, and the run-in conditions specifically for winter tread rubber were determined. This provided theoretical support for improving the accuracy of indoor predictions of real vehicle ice grip test results and enriched the research on the rubber-ice friction mechanism.

选择了三种不同的增强填料用于冬季轮胎胎面胶。在改进了试验方法后,利用LAT100试验机进行了橡胶表面粗糙度对冰握性和湿握性的影响试验,并研究了不同温度下载荷和速度对橡胶-冰摩擦系数的影响。结果表明:随着橡胶表面宏观粗糙度的增大,橡胶与冰面之间的摩擦力减小,橡胶与湿路面之间的摩擦力增大;随着载荷和速度的增加,橡胶在冰面上的摩擦系数减小,且- 15℃冰面比- 5℃冰面变化更明显,- 15℃干冰表面的摩擦系数大于- 5℃湿冰表面;为了更好地预测实车试验结果,在LAT冰摩擦试验中,载荷选取75 ~ 100N,速度选取0.6 km/h,并确定了专用于冬季胎面橡胶的磨合条件。这为提高室内实车冰抓力试验结果预测精度提供了理论支持,丰富了橡胶-冰摩擦机理的研究。
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引用次数: 0
In-situ Investigation of Stick–Slip Behavior of an Elastic String: Insights into Fiber-Based Friction 弹性管柱粘滑特性的原位研究:纤维基摩擦的新见解
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-03 DOI: 10.1007/s11249-025-02087-9
Zitong Huang, Qingrui Song, Kun Liu, Jiaxin Ye

Using a custom-built microtribometer, the stick–slip behavior of a single elastic string in Hertz contact with a cylindrical glass lens was observed in situ, collecting dynamic contact area and friction force data during the adhesion phase. The results indicate that stick–slip occurs periodically due to repeated contact and elastic deformation. The friction pair was modeled for both translational and rotational movement, quantifying energy changes during the adhesion phase. It was inferred that slip occurs due to instability when the contact area reaches its maximum, which is possibly determined by a combination of factors including surface roughness, rubber deformation, and cylindrical rotation. These findings provide new insight into the macroscopic frictional properties of fiber-structured surfaces.

利用特制的微摩擦计,原位观察了单弹性弦与圆柱形玻璃透镜赫兹接触时的粘滑行为,收集了粘着阶段的动态接触面积和摩擦力数据。结果表明,由于反复接触和弹性变形,粘滑是周期性发生的。对摩擦副进行了平移和旋转运动建模,量化了粘附阶段的能量变化。由此推断,当接触面积达到最大时,由于不稳定而发生滑移,这可能是由表面粗糙度、橡胶变形和圆柱旋转等因素共同决定的。这些发现为纤维结构表面的宏观摩擦特性提供了新的见解。
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引用次数: 0
New Insight into the Correlation Between Lubricant Glass Transition and friction Plateau in Highly Loaded Contacts 高负荷接触中润滑油玻璃化转变与摩擦平台关系的新认识
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-03 DOI: 10.1007/s11249-025-02077-x
Marjolaine Gonon, David Philippon, Jérémie Margueritat, Lionel Lafarge, Philippe Vergne, Laetitia Martinie

It was shown in a previous paper that friction in highly loaded non-conforming contacts correlated with the formation of a glassy state of the lubricant, for the only lubricant studied (benzyl benzoate). The aim of the present paper is to extend this conclusion to other types of fluid: a model fluid from the literature (glycerol) and a well-known lubricant (squalane). The characterization of these fluids in the bulk by Brillouin spectroscopy shows a similar evolution of their behavior with pressure and makes it possible to identify their glass transition pressure. Furthermore, comparison of this characterization with friction data for squalane validates the correlation previously established for benzyl benzoate. In a second part, the structural relaxation time of benzyl benzoate is derived from Brillouin spectra to probe the influence of hydrostatic pressure on fluid dynamics. This parameter, superimposed on the previous friction measurements, shows that the dynamics of the molecules is highly reduced at high pressures, which explains the macroscopically solid-like behavior of the lubricant. This result suggests that the relaxation time is an essential parameter for the correct modeling of highly loaded lubricated contacts.

在之前的一篇论文中表明,对于唯一研究的润滑剂(苯甲酸苄酯),高负载非一致性接触中的摩擦与润滑剂玻璃态的形成相关。本文的目的是将这一结论扩展到其他类型的流体:文献中的模型流体(甘油)和众所周知的润滑剂(角鲨烷)。用布里渊光谱对这些流体进行了表征,显示出它们的行为随压力的相似演变,并使确定它们的玻璃化转变压力成为可能。此外,将这种表征与角鲨烷的摩擦数据进行比较,验证了先前建立的苯甲酸苄酯的相关性。第二部分,利用布里渊谱推导了苯甲酸苄酯的结构弛豫时间,探讨静水压力对流体动力学的影响。该参数与之前的摩擦测量结果相叠加,表明分子的动力学在高压下大大降低,这解释了润滑剂在宏观上的固体样行为。这一结果表明,松弛时间是高负荷润滑接触正确建模的重要参数。
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引用次数: 0
An Incremental Model for Interfacial Stiffness Unifying Sublinear and Linear Scaling Regimes 统一亚线性和线性标度的界面刚度增量模型
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-03 DOI: 10.1007/s11249-025-02091-z
Xuan-Ming Liang, Gang-Feng Wang

Accurately predicting the interfacial gap and stiffness between rough solids is essential for understanding contact behavior in tribological, sealing, and thermal systems. This work proposes a novel model that accurately captures the evolution of mean interfacial gap and stiffness from initial finite contacts to accumulated statistical response. The obtained load-gap relationship is validated against boundary element simulations of elastic rough contact, showing excellent agreement across a wide range of normal loads. Unlike conventional models, the proposed approach captures finite-size effects at light loads, yielding a sublinear power-law scaling of stiffness with load, and transitions seamlessly to the linear regime at higher loads. The model provides a simple, parameter-free tool for quantitative analysis of rough surface contacts.

准确预测粗糙固体之间的界面间隙和刚度对于理解摩擦学、密封和热系统中的接触行为至关重要。这项工作提出了一种新的模型,可以准确地捕捉平均界面间隙和刚度从初始有限接触到累积统计响应的演变。通过弹性粗糙接触的边界元模拟验证了所得的载荷-间隙关系,在大范围的法向载荷范围内显示出良好的一致性。与传统模型不同,所提出的方法在轻载荷下捕获有限尺寸效应,产生随载荷的次线性幂律缩放刚度,并在高载荷下无缝过渡到线性状态。该模型为粗糙表面接触的定量分析提供了一个简单、无参数的工具。
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引用次数: 0
Dynamics of a Rayleigh-Step Bearing: Generic Stribeck Curve and Rate-State Models 瑞利-步进轴承动力学:通用Stribeck曲线和速率-状态模型
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-11-03 DOI: 10.1007/s11249-025-02082-0
Farid Al-Bender

The Stribeck curve forms the backbone of our understanding of frictional behavior. It has traditionally been associated with lubricated journal bearings and later on with EHL lubricated rough contacts. Still later, this behavior appeared to manifest itself also in dry rough contacts. While in this latter case, the Stribeck behavior has been simulated theoretically, in the lubricated case, the models have been confined to a few restricted cases. Here, I show that the Stribeck behavior emanates directly from the most basic/generic type of hydrodynamic bearing; namely the Rayleigh-step bearing, without resort to the EHL/mixed-lubrication assumption. This bearing type can be taken in the macro sense, as a self-standing bearing; or in the micro sense, as an elemental roughness feature, which can be aggregated to understand rough lubricated sliding contacts. Furthermore, this simple model of a step bearing allows us to establish the dynamic behavior of the Stribeck curve; in particular, the friction lag phenomenon and the rate-state law. Main results show that the normalized CoF is a universal function of the normalized Sommerfeld number, reduced by the aspect ratio of the bearing, and that the dynamic Stribeck effect cannot be decomposed into time-dependent Stribect effect combined with time-independent (instantaneous) viscous effect.

斯特里贝克曲线是我们理解摩擦行为的基础。传统上,它与润滑轴颈轴承有关,后来与EHL润滑粗糙接触有关。再后来,这种行为似乎也在干燥的粗糙接触中表现出来。在后一种情况下,理论上模拟了Stribeck行为,而在润滑情况下,模型仅限于少数受限情况。在这里,我表明斯特里贝克行为直接来自最基本/通用类型的流体动力轴承;即瑞利步进轴承,无需采用EHL/混合润滑假设。这种轴承类型在宏观意义上可以理解为自立轴承;或者在微观上,作为一种基本的粗糙度特征,可以将其聚集起来以理解粗糙润滑滑动接触。此外,这个简单的阶跃轴承模型允许我们建立Stribeck曲线的动态特性;特别是摩擦滞后现象和速率-状态定律。主要结果表明,归一化CoF是归一化索默菲尔德数的通用函数,该函数被轴承的长径比减小,动态Stribeck效应不能分解为时变的Stribeck效应与时变的(瞬时)粘性效应相结合。
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引用次数: 0
Improved Process for Laser-Assisted, In Situ, Multi-Stage Wear Measurement of Simultaneously Wearing Counterparts 改进的激光辅助、原位、多阶段同步磨损测量工艺
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-10-31 DOI: 10.1007/s11249-025-02089-7
Paul Christian Sager, Birgit Schaedel, Roland Kral, Rainer Adelung

Accurate in situ wear measurements of polymer-polymer wear combinations using techniques like ball-on-prism tribometers pose a significant challenge. Simultaneous wear of both counterparts complicates obtaining continuous wear data without interrupting experiments to perform slow, intermediate measurements. Building on Harden et al. (Tribol Lett 71(3):1–14, 2023), this work develops an accurate, low-noise measurement approach to enable reliable in situ measurements. The method employs a laser line scanner and a precision linear axis for accurate positioning within the test stand, complemented by an algorithm for debris detection and data smoothing to minimize noise from wear residue. This approach achieves up to a 98% reduction in peak-to-peak noise levels, enabling high-resolution measurements and supporting parallel experiments with various polymer-polymer wear combinations. Unlike existing non-in situ methods, this technique offers efficient and accurate in situ wear measurements, advancing tribological research and polymer material testing.

使用球-棱镜摩擦计等技术对聚合物-聚合物磨损组合进行精确的原位磨损测量是一个重大挑战。两种对应的同时磨损使获得连续磨损数据变得复杂,而不中断实验以执行缓慢的中间测量。在哈登等人(Tribol Lett 71(3):1 - 14,2023)的基础上,这项工作开发了一种准确、低噪声的测量方法,以实现可靠的原位测量。该方法采用激光线扫描仪和精密线轴在试验台内进行精确定位,辅以碎片检测和数据平滑算法,以最大限度地减少磨损残留物带来的噪音。该方法可将峰值噪声水平降低98%,实现高分辨率测量,并支持各种聚合物磨损组合的并行实验。与现有的非原位方法不同,该技术提供了高效、准确的原位磨损测量,促进了摩擦学研究和聚合物材料测试。
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引用次数: 0
Influence of the Gas Atmosphere on the In-Situ Formation of Low-Friction Molybdenum and Tungsten Diselenides 气体气氛对原位形成低摩擦钼钨二硒化物的影响
IF 3.3 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2025-10-22 DOI: 10.1007/s11249-025-02081-1
Daniel Pölzlberger, Carsten Gachot, Philipp G. Grützmacher, Sabine Schwarz, Helmut Riedl, Zhen Yan, Xudong Sui

This study investigates the influence of the gas atmosphere on friction and wear characteristics of transition metal dichalcogenides synthesized via an in-operando method. MoSe2 and WSe2 layers are formed through tribochemical reactions between molybdenum or tungsten coatings and nanosized selenium powder. Their tribological behavior is evaluated under nitrogen and ambient air conditions using a ball-on-disc tribometer within a custom-built inert gas chamber. The results indicate that both MoSe2 and WSe2 layers exhibit consistently low friction coefficients (below 0.1) across different atmospheric conditions, with slightly lower friction coefficient observed in air compared to nitrogen. However, the durability of the transition metal dichalcogenide layers is significantly extended under nitrogen, particularly for MoSe2, which demonstrates superior durability compared to WSe2 in nitrogen. This disparity becomes less pronounced under ambient air conditions. The enhanced wear resistance of MoSe2 in nitrogen may be attributed to easier in-operando formation, as confirmed by transmission electron microscopy analysis, which reveals a thicker and more well-defined layered tribofilm. These findings suggest that in-operando synthesized MoSe2 and WSe2 layers serve as effective solid lubricants, offering promising potential for a broader range of solid lubrication applications.

Graphical Abstract

本文研究了气体气氛对操作法合成的过渡金属二硫化物摩擦磨损特性的影响。MoSe2和WSe2是由钼或钨涂层与纳米硒粉之间的摩擦化学反应形成的。在氮气和环境空气条件下,使用特制的惰性气体室内的球盘式摩擦计评估其摩擦学行为。结果表明,MoSe2和WSe2层在不同大气条件下均表现出较低的摩擦系数(小于0.1),其中空气中的摩擦系数略低于氮气。然而,在氮气条件下,过渡金属二硫化物层的耐久性显著延长,特别是MoSe2,与WSe2相比,在氮气条件下表现出更高的耐久性。在环境空气条件下,这种差异变得不那么明显。MoSe2在氮气中的耐磨性增强可能是由于更容易形成在操作中,正如透射电镜分析所证实的那样,它显示出更厚、更明确的层状摩擦膜。这些发现表明,在操作中合成的MoSe2和WSe2层可以作为有效的固体润滑剂,为更广泛的固体润滑应用提供了广阔的前景。图形抽象
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引用次数: 0
期刊
Tribology Letters
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