Dissimilar metal welding between 9Cr18MoV and 3Cr13 offers promising practical applications in the tool manufacturing industry. However, limited previous studies have investigated the effects of post-weld quenching and tempering heat treatment on the performances of dissimilar welded joints of martensitic stainless steels, specifically between 3Cr13 and 9Cr18MoV. This study examined the evolution of microstructure, mechanical properties, and corrosion resistance of the dissimilar welded joints of 3Cr13 and 9Cr18MoV after post-weld quenching and tempering. It was found that the microstructures of the weld metal (WM) were changed, with the disappearance of columnar and dendritic grain morphologies following the generation of tempered martensite after the post-weld heat treatment (PWHT). The grain size in the WM decreased from 67.1 μm to 9.2 μm. After the PWHT, the corrosion resistance of the WM was enhanced based on the results of electrochemical corrosion tests. Additionally, the welded joint exhibited a significant increase in hardness and ultimate tensile strength, with an approximate 18% rise in tensile strength noted. However, the impact toughness of the WM dropped from 7 ± 2.2 J/cm2 to 0.87 ± 0.2 J/cm2, representing the lowest value among all samples tested.
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