首页 > 最新文献

Welding in the World最新文献

英文 中文
Effect of different regions on fatigue crack growth behavior of 6005-T6 aluminum alloy metal inert gas (MIG) butt welded joint: experimental and numerical study 不同区域对 6005-T6 铝合金金属惰性气体 (MIG) 对焊接头疲劳裂纹生长行为的影响:实验和数值研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-23 DOI: 10.1007/s40194-024-01788-4
Chao Wang, Bing Yang, Tao Zhu, Shuwei Zhou, Shoune Xiao, Guangwu Yang

This paper presents an experimental and numerical investigation of the fatigue crack growth behavior in different regions of metal inert gas (MIG) butt welded joints of 6005-T6 aluminum alloy. A series of experiments were carried out, including the compact tensile specimen crack growth rate, microstructure, and failure fracture analysis, which reveals the crack growth mechanism in different weld regions. A fracture mechanics numerical model considering geometric features and material inhomogeneity was developed, and the crack growth life results were obtained in agreement with the test. The results show that the microstructure and inhomogeneous material properties significantly affect their crack growth behavior and life distribution. The life distribution of different weld regions was quantified based on the Weibull distribution parameters to guide crack growth life assessment.

本文对 6005-T6 铝合金金属惰性气体(MIG)对焊接头不同区域的疲劳裂纹生长行为进行了实验和数值研究。通过一系列实验,包括紧凑拉伸试样裂纹生长率、微观结构和破坏断裂分析,揭示了不同焊接区域的裂纹生长机理。建立了考虑几何特征和材料不均匀性的断裂力学数值模型,并得出了与试验一致的裂纹生长寿命结果。结果表明,微观结构和材料非均质性对其裂纹生长行为和寿命分布有显著影响。根据 Weibull 分布参数对不同焊接区域的寿命分布进行了量化,以指导裂纹生长寿命评估。
{"title":"Effect of different regions on fatigue crack growth behavior of 6005-T6 aluminum alloy metal inert gas (MIG) butt welded joint: experimental and numerical study","authors":"Chao Wang,&nbsp;Bing Yang,&nbsp;Tao Zhu,&nbsp;Shuwei Zhou,&nbsp;Shoune Xiao,&nbsp;Guangwu Yang","doi":"10.1007/s40194-024-01788-4","DOIUrl":"10.1007/s40194-024-01788-4","url":null,"abstract":"<div><p>This paper presents an experimental and numerical investigation of the fatigue crack growth behavior in different regions of metal inert gas (MIG) butt welded joints of 6005-T6 aluminum alloy. A series of experiments were carried out, including the compact tensile specimen crack growth rate, microstructure, and failure fracture analysis, which reveals the crack growth mechanism in different weld regions. A fracture mechanics numerical model considering geometric features and material inhomogeneity was developed, and the crack growth life results were obtained in agreement with the test. The results show that the microstructure and inhomogeneous material properties significantly affect their crack growth behavior and life distribution. The life distribution of different weld regions was quantified based on the Weibull distribution parameters to guide crack growth life assessment.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141107713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparison of fatigue crack growth design curves on GMAW and EBW joints of high strength steels 高强度钢 GMAW 和 EBW 接头疲劳裂纹增长设计曲线的比较
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-18 DOI: 10.1007/s40194-024-01787-5
R. P. S. Sisodia, M. Gáspár, J. Lukács

There is a growing demand in the industrial sector for the use of high-strength structural steels (HSSSs), which can achieve a significant weight reduction in structures. These structural steels are usually produced by quenching and tempering (Q + T) or thermomechanical treatment (TM), and their applications in welded structures pose several challenges for the users. In industrial practice, gas metal arc welding (GMAW) is basically the most commonly used fusion welding process, which has a relatively high heat input. However, at HSSSs, there is a need for low heat input but, at the same time, productive welding processes. High-energy density welding processes, e.g., electron beam welding (EBW), offer a unique opportunity to weld these steels. The widespread use of HSSSs is also hampered by the fact that the benefits of high strength can be exploited primarily under static loading. At the same time, different welded structures made of HSSSs are often subjected to cyclic loading, and possible weld defects and material discontinuities are major risks in this case. During our experiments, GMAW and autogenous EBW processes were applied to make welded joints from S960 Q + T and TM structural steels. The fatigue resistance of the welded joints was characterized by fatigue crack growth (FCG) tests, considering the increased crack sensitivity of HSSSs. A statistical approach was followed both in the design of the experiments and in the evaluation of their results. Based on the test results fatigue crack propagation design curves were determined for the investigated GMAW and EBW welded joints. The design curves were compared with each other, with design curves of lower strength material (S690QL) and with the recommended fatigue crack growth laws of BS 7910.

工业领域对使用高强度结构钢(HSSS)的需求日益增长,因为高强度结构钢可以显著减轻结构重量。这些结构钢通常是通过淬火和回火(Q + T)或热机械处理(TM)生产出来的,它们在焊接结构中的应用给用户带来了一些挑战。在工业实践中,气体金属弧焊(GMAW)基本上是最常用的熔焊工艺,其输入热量相对较高。然而,在高速钢系统中,需要输入热量低但同时产量高的焊接工艺。高能量密度焊接工艺,如电子束焊接(EBW),为焊接这些钢材提供了独特的机会。高强度钢的优点主要是在静态载荷下才能发挥出来,这也阻碍了高强度钢的广泛应用。同时,由 HSSS 焊接而成的不同结构通常要承受循环载荷,在这种情况下,可能出现的焊接缺陷和材料不连续性是主要风险。在实验过程中,我们采用了 GMAW 和自生 EBW 工艺来制造 S960 Q + T 和 TM 结构钢的焊接接头。考虑到高速钢的裂纹敏感性较高,我们通过疲劳裂纹增长(FCG)测试对焊接接头的耐疲劳性进行了鉴定。实验设计和结果评估都采用了统计方法。根据测试结果,确定了所研究的 GMAW 和 EBW 焊接接头的疲劳裂纹扩展设计曲线。将这些设计曲线与较低强度材料(S690QL)的设计曲线以及 BS 7910 推荐的疲劳裂纹增长规律进行了比较。
{"title":"Comparison of fatigue crack growth design curves on GMAW and EBW joints of high strength steels","authors":"R. P. S. Sisodia,&nbsp;M. Gáspár,&nbsp;J. Lukács","doi":"10.1007/s40194-024-01787-5","DOIUrl":"10.1007/s40194-024-01787-5","url":null,"abstract":"<div><p>There is a growing demand in the industrial sector for the use of high-strength structural steels (HSSSs), which can achieve a significant weight reduction in structures. These structural steels are usually produced by quenching and tempering (Q + T) or thermomechanical treatment (TM), and their applications in welded structures pose several challenges for the users. In industrial practice, gas metal arc welding (GMAW) is basically the most commonly used fusion welding process, which has a relatively high heat input. However, at HSSSs, there is a need for low heat input but, at the same time, productive welding processes. High-energy density welding processes, e.g., electron beam welding (EBW), offer a unique opportunity to weld these steels. The widespread use of HSSSs is also hampered by the fact that the benefits of high strength can be exploited primarily under static loading. At the same time, different welded structures made of HSSSs are often subjected to cyclic loading, and possible weld defects and material discontinuities are major risks in this case. During our experiments, GMAW and autogenous EBW processes were applied to make welded joints from S960 Q + T and TM structural steels. The fatigue resistance of the welded joints was characterized by fatigue crack growth (FCG) tests, considering the increased crack sensitivity of HSSSs. A statistical approach was followed both in the design of the experiments and in the evaluation of their results. Based on the test results fatigue crack propagation design curves were determined for the investigated GMAW and EBW welded joints. The design curves were compared with each other, with design curves of lower strength material (S690QL) and with the recommended fatigue crack growth laws of BS 7910.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01787-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141063776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced mechanical properties of TZM joint brazed at high temperature using Mo-Ni filler metal with Boron addition 使用添加硼的钼-镍填充金属在高温下钎焊 TZM 接头可提高机械性能
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-15 DOI: 10.1007/s40194-024-01783-9
Quanbin Lu, Junlan Huang, Zongye Ding, Dengwen Hu, Gaoming Lu, Weimin Long

Controlling the growth of brittle intermetallic compounds (IMCs) and interfacial structure is crucial to obtaining desirable mechanical properties of the high-temperature brazing joints of titanium-zirconium-molybdenum (TZM) alloy. The effect of B addition on the mechanical properties of the joints and the microstructures in the brazing seam was investigated. The results show that the addition of 1%B enhances significantly the wettability of Mo-45Ni filler metal. The strength of the brazed joint with Mo-45Ni-1B filler metal is 30% higher than that of the joint with Mo-45Ni filler metal. The microstructure of the brazed joint with Mo-45Ni filler metal consisted of TZM/NiMo/eutectic (Mo + NiMo) + NiMo /NiMo/TZM. B addition led to the formation of Mo2B intermetallic compounds at the interface between NiMo layer and TZM alloy during heating and the precipitation of faceted Mo2B IMCs in the brazing seam during solidification, promoting the brittle-to-ductile fracture transition. This study provides a deep insight into the HT brazing of TZM alloy.

控制脆性金属间化合物(IMC)的生长和界面结构是获得钛锆钼(TZM)合金高温钎焊接头理想机械性能的关键。研究了硼添加量对接头机械性能和钎缝微观结构的影响。结果表明,添加 1%B 能显著提高 Mo-45Ni 填充金属的润湿性。使用 Mo-45Ni-1B 填充金属的钎焊接头强度比使用 Mo-45Ni 填充金属的接头强度高 30%。使用 Mo-45Ni 填充金属的钎焊接头的微观结构由 TZM/NiMo/共晶(Mo + NiMo)+ NiMo /NiMo/TZM 组成。在加热过程中,B 的加入导致在 NiMo 层和 TZM 合金的界面上形成 Mo2B 金属间化合物,并在凝固过程中在钎缝中析出刻面 Mo2B IMC,从而促进了从脆性到韧性的断裂转变。这项研究为 TZM 合金的高温钎焊提供了深入的见解。
{"title":"Enhanced mechanical properties of TZM joint brazed at high temperature using Mo-Ni filler metal with Boron addition","authors":"Quanbin Lu,&nbsp;Junlan Huang,&nbsp;Zongye Ding,&nbsp;Dengwen Hu,&nbsp;Gaoming Lu,&nbsp;Weimin Long","doi":"10.1007/s40194-024-01783-9","DOIUrl":"10.1007/s40194-024-01783-9","url":null,"abstract":"<div><p>Controlling the growth of brittle intermetallic compounds (IMCs) and interfacial structure is crucial to obtaining desirable mechanical properties of the high-temperature brazing joints of titanium-zirconium-molybdenum (TZM) alloy. The effect of B addition on the mechanical properties of the joints and the microstructures in the brazing seam was investigated. The results show that the addition of 1%B enhances significantly the wettability of Mo-45Ni filler metal. The strength of the brazed joint with Mo-45Ni-1B filler metal is 30% higher than that of the joint with Mo-45Ni filler metal. The microstructure of the brazed joint with Mo-45Ni filler metal consisted of TZM/NiMo/eutectic (Mo + NiMo) + NiMo /NiMo/TZM. B addition led to the formation of Mo<sub>2</sub>B intermetallic compounds at the interface between NiMo layer and TZM alloy during heating and the precipitation of faceted Mo<sub>2</sub>B IMCs in the brazing seam during solidification, promoting the brittle-to-ductile fracture transition. This study provides a deep insight into the HT brazing of TZM alloy.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140973805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Monte Carlo simulation of grain growth in heat-affected zone during welding process of cast steel joint and optimization of welding process 铸钢接头焊接过程中热影响区晶粒生长的蒙特卡罗模拟及焊接工艺优化
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-10 DOI: 10.1007/s40194-024-01782-w
Haihan Jiao, Hui Jin

The final microstructure and mechanical properties of a welded joint are determined by the evolution and crystallization process of grain structure during welding. This study aims to improve the mechanical properties of the weak weld root zone in a G20Mn5 cast steel—Q345 low-alloy steel circular butt weld. The microstructure changes of the weld during the welding process were investigated using metallographic testing combined with Monte Carlo simulation, and suggestions for optimizing the welding process were provided. Firstly, the microstructural assessment of welded cast steel joints was conducted using metallographic and hardness tests. It was clarified that the heat-affected zone at the weld root on the Q345 steel side was the weak zone. Additionally, the relationship between grain size and mechanical properties of the joints was established. A Monte Carlo model was then used to simulate the dynamic recrystallization process and determine the final distribution of grain structure in the heat-affected zone. Finally, the calibrated model was utilized to analyze the impact of different welding processes on grain structure and mechanical properties. The findings indicate that employing a three-pass welding process, incorporating a V-shaped groove on the cast steel side, and dispersing the welding start and stop positions can effectively inhibit grain growth in the heat-affected zone, which provides valuable insights for optimizing the welding process of cast steel welded joints.

焊接接头的最终微观结构和机械性能取决于焊接过程中晶粒结构的演变和结晶过程。本研究旨在改善 G20Mn5 铸钢-Q345 低合金钢圆形对接焊缝中弱焊缝根部区域的机械性能。通过金相测试结合蒙特卡罗模拟研究了焊接过程中焊缝的微观结构变化,并提出了优化焊接工艺的建议。首先,使用金相和硬度测试对焊接铸钢接头进行了微观结构评估。结果表明,Q345 钢一侧焊缝根部的热影响区是薄弱区。此外,还确定了晶粒大小与接头机械性能之间的关系。然后使用蒙特卡罗模型模拟动态再结晶过程,并确定热影响区晶粒结构的最终分布。最后,利用校准模型分析不同焊接工艺对晶粒结构和机械性能的影响。研究结果表明,采用三道焊接工艺、在铸钢侧加入 V 形槽以及分散焊接开始和停止位置可有效抑制热影响区的晶粒长大,这为优化铸钢焊接接头的焊接工艺提供了有价值的启示。
{"title":"Monte Carlo simulation of grain growth in heat-affected zone during welding process of cast steel joint and optimization of welding process","authors":"Haihan Jiao,&nbsp;Hui Jin","doi":"10.1007/s40194-024-01782-w","DOIUrl":"10.1007/s40194-024-01782-w","url":null,"abstract":"<div><p>The final microstructure and mechanical properties of a welded joint are determined by the evolution and crystallization process of grain structure during welding. This study aims to improve the mechanical properties of the weak weld root zone in a G20Mn5 cast steel—Q345 low-alloy steel circular butt weld. The microstructure changes of the weld during the welding process were investigated using metallographic testing combined with Monte Carlo simulation, and suggestions for optimizing the welding process were provided. Firstly, the microstructural assessment of welded cast steel joints was conducted using metallographic and hardness tests. It was clarified that the heat-affected zone at the weld root on the Q345 steel side was the weak zone. Additionally, the relationship between grain size and mechanical properties of the joints was established. A Monte Carlo model was then used to simulate the dynamic recrystallization process and determine the final distribution of grain structure in the heat-affected zone. Finally, the calibrated model was utilized to analyze the impact of different welding processes on grain structure and mechanical properties. The findings indicate that employing a three-pass welding process, incorporating a V-shaped groove on the cast steel side, and dispersing the welding start and stop positions can effectively inhibit grain growth in the heat-affected zone, which provides valuable insights for optimizing the welding process of cast steel welded joints.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140935928","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on microstructure and mechanical properties of continuous drive friction-welded joints of bainitic rail steel 贝氏体钢轨连续驱动摩擦焊接接头的微观结构和机械性能研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-05-01 DOI: 10.1007/s40194-024-01780-y
Jiaqi Xie, Han Zhang, Chang’an Li, Zhiming Zhu

The U20Mn bainitic rail steel rods with a diameter of 15mm were joined by continuous drive friction welding (CDFW) below the A1 temperature. The microstructure characteristics of the welded joints without post weld heat treatment (PWHT) were investigated by metallographic observation, scanning electron microscope investigation, and electron backscattered diffraction analysis. Their mechanical properties were evaluated through hardness, tensile, and impact tests. The results show that the welded joints are well-formed without metallurgical defects. They manifest a dense martensitic-bainitic composite phase structure with good mechanical properties attributed to fine-grain and second-phase strengthening effects. The maximum impact energy is 29.2J, with peak hardness increasing to about 124% compared to the base material (BM). Tensile strength reaches 1267±15.1 MPa (102% of BM), and elongation reaches 13.8±0.2% (97% of BM), realizing quasi-equal strength and toughness matching with the BM. These findings provide a basis for the realization of friction welding for bainitic steel rails and the future development of novel rail welding techniques and equipment.

直径为 15 毫米的 U20Mn 贝氏体钢轨钢棒采用低于 A1 温度的连续驱动摩擦焊(CDFW)进行焊接。通过金相观察、扫描电子显微镜检查和电子反向散射衍射分析,研究了未进行焊后热处理(PWHT)的焊接接头的微观结构特征。通过硬度、拉伸和冲击试验对其机械性能进行了评估。结果表明,焊接接头成形良好,无冶金缺陷。它们表现出致密的马氏体-贝氏体复合相结构,具有良好的机械性能,这归功于细晶粒和第二相强化效应。与基体材料(BM)相比,最大冲击能量为 29.2J,峰值硬度提高了约 124%。拉伸强度达到 1267±15.1 MPa(BM 的 102%),伸长率达到 13.8±0.2%(BM 的 97%),实现了与 BM 的准等强度和韧性匹配。这些发现为实现贝氏体钢轨的摩擦焊接以及未来新型钢轨焊接技术和设备的开发提供了依据。
{"title":"Study on microstructure and mechanical properties of continuous drive friction-welded joints of bainitic rail steel","authors":"Jiaqi Xie,&nbsp;Han Zhang,&nbsp;Chang’an Li,&nbsp;Zhiming Zhu","doi":"10.1007/s40194-024-01780-y","DOIUrl":"10.1007/s40194-024-01780-y","url":null,"abstract":"<div><p>The U20Mn bainitic rail steel rods with a diameter of 15mm were joined by continuous drive friction welding (CDFW) below the A<sub>1</sub> temperature. The microstructure characteristics of the welded joints without post weld heat treatment (PWHT) were investigated by metallographic observation, scanning electron microscope investigation, and electron backscattered diffraction analysis. Their mechanical properties were evaluated through hardness, tensile, and impact tests. The results show that the welded joints are well-formed without metallurgical defects. They manifest a dense martensitic-bainitic composite phase structure with good mechanical properties attributed to fine-grain and second-phase strengthening effects. The maximum impact energy is 29.2J, with peak hardness increasing to about 124% compared to the base material (BM). Tensile strength reaches 1267±15.1 MPa (102% of BM), and elongation reaches 13.8±0.2% (97% of BM), realizing quasi-equal strength and toughness matching with the BM. These findings provide a basis for the realization of friction welding for bainitic steel rails and the future development of novel rail welding techniques and equipment.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140829781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Spatial stabilization of arc discharges in pulsed gas tungsten arc welding 脉冲气体钨极氩弧焊中电弧放电的空间稳定性
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-30 DOI: 10.1007/s40194-024-01781-x
Stepan Skripko, Anton Gordynets, Alexey Kiselev, Mikhail Slobodyan

The aim of this study was to investigate the influence of the discharge parameters on the initial spatial instability of arcs after their initiation by the non-contact method in single-pulse electrode-negative gas tungsten arc welding. The investigated parameters were the Ppeak peak arc pressures, the T durations for achieving the peak arc pressure, and the Pfinal arc pressures at the end of current pulses. It was found that increasing the current amplitudes from 50 to 200 A enhanced mean both the Ppeak values (from 0.25 to 4.00 kPa) and the Pfinal levels (from 0.16 to 1.72 kPa). Enhancing the electrode diameters from 1.0 to 2.4 mm increased these experimental output parameters from 1.85 to 1.99 kPa and from 0.57 to 1.23 kPa, respectively, while they were decreased from 2.32 to 1.47 kPa and from 1.19 to 0.62 kPa after changing the sharpening angle of their tips from 30° to 90°. The period of the spatial instability of arc discharges was shortened from 14.4 to 5.8 ms by increasing the current amplitudes from 50 to 200 A. However, enhancing the electrode diameters from 1.0 to 2.4 mm increased its duration from 9.2 to 12.0 ms. It was also prolonged from 6.2 to 16.8 ms after changing the sharpening angle of the electrode tips from 30° up to 90°. The shortest duration of the arc stabilization period of 5 ms was observed when using the WL15 non-consumable electrode, while it was the longest (35 ms) for the WP one.

本研究旨在探讨在单脉冲负极气体钨极氩弧焊中采用非接触式方法引弧后,放电参数对电弧初始空间不稳定性的影响。研究的参数包括 Ppeak 峰值弧压、达到峰值弧压的 T 持续时间以及电流脉冲结束时的 Pfinal 弧压。研究发现,将电流振幅从 50 A 提高到 200 A,可提高峰值(从 0.25 kPa 提高到 4.00 kPa)和峰值(从 0.16 kPa 提高到 1.72 kPa)的平均值。电极直径从 1.0 mm 增加到 2.4 mm 后,这些实验输出参数分别从 1.85 kPa 增加到 1.99 kPa 和从 0.57 kPa 增加到 1.23 kPa,而电极尖端锐角从 30° 变为 90° 后,这些参数分别从 2.32 kPa 降低到 1.47 kPa 和从 1.19 kPa 降低到 0.62 kPa。将电流振幅从 50 A 增加到 200 A 后,电弧放电的空间不稳定性周期从 14.4 ms 缩短到 5.8 ms。将电极尖端的锐角从 30° 改为 90° 后,电弧持续时间也从 6.2 毫秒延长到 16.8 毫秒。使用 WL15 非消耗性电极时,电弧稳定期最短为 5 毫秒,而使用 WP 电极时则最长(35 毫秒)。
{"title":"Spatial stabilization of arc discharges in pulsed gas tungsten arc welding","authors":"Stepan Skripko,&nbsp;Anton Gordynets,&nbsp;Alexey Kiselev,&nbsp;Mikhail Slobodyan","doi":"10.1007/s40194-024-01781-x","DOIUrl":"10.1007/s40194-024-01781-x","url":null,"abstract":"<div><p>The aim of this study was to investigate the influence of the discharge parameters on the initial spatial instability of arcs after their initiation by the non-contact method in single-pulse electrode-negative gas tungsten arc welding. The investigated parameters were the <i>P</i><sub>peak</sub> peak arc pressures, the <i>T</i> durations for achieving the peak arc pressure, and the <i>P</i><sub>final</sub> arc pressures at the end of current pulses. It was found that increasing the current amplitudes from 50 to 200 A enhanced mean both the <i>P</i><sub>peak</sub> values (from 0.25 to 4.00 kPa) and the <i>P</i><sub>final</sub> levels (from 0.16 to 1.72 kPa). Enhancing the electrode diameters from 1.0 to 2.4 mm increased these experimental output parameters from 1.85 to 1.99 kPa and from 0.57 to 1.23 kPa, respectively, while they were decreased from 2.32 to 1.47 kPa and from 1.19 to 0.62 kPa after changing the sharpening angle of their tips from 30° to 90°. The period of the spatial instability of arc discharges was shortened from 14.4 to 5.8 ms by increasing the current amplitudes from 50 to 200 A. However, enhancing the electrode diameters from 1.0 to 2.4 mm increased its duration from 9.2 to 12.0 ms. It was also prolonged from 6.2 to 16.8 ms after changing the sharpening angle of the electrode tips from 30° up to 90°. The shortest duration of the arc stabilization period of 5 ms was observed when using the WL15 non-consumable electrode, while it was the longest (35 ms) for the WP one.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140829531","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dissimilar transient liquid phase bonding of Ti-6Al-4V alloy to Inconel 625 superalloy: effect of bonding temperature on microstructural evolutions and mechanical properties Ti-6Al-4V 合金与 Inconel 625 超级合金的异种瞬态液相键合:键合温度对微观结构演变和机械性能的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-30 DOI: 10.1007/s40194-024-01777-7
Behnam Zorriatolhosseini, Seyyed Ehsan Mirsalehi, Faezeh Shamsi

The present study investigated the effect of bonding temperature on the dissimilar transient liquid phase (TLP)–bonded IN-625/Ti-6Al-4V dissimilar joints using a thin foil of pure copper as the interlayer. The samples were bonded in a vacuum chamber at 900, 930, and 960 °C for 60 min. The results indicated the occurrence of different intermetallic compounds such as Ti2Cu, TiCu2, TiCu, NiTi, and Ni3Ti at different bonding temperatures, and it was concluded that in all the samples, isothermal solidification was accomplished. Maximum shear strength of 278 MPa was achieved at 930 °C. At lower bonding temperatures, the presence of porosities and cracks decreases the shear strength. At higher temperatures, a high-volume percentage of intermetallic compounds embrittled the specimen and reduced its shear strength. The results of scanning electron microscopy of the fracture surfaces revealed the formation of extensive cleavage fracture and river-like patterns in all samples, indicating a brittle failure mode.

本研究探讨了粘接温度对以纯铜薄箔为中间层的瞬态液相(TLP)粘接 IN-625/Ti-6Al-4V 异种接头的影响。样品在真空室中分别于 900、930 和 960 °C 下粘合 60 分钟。结果表明,在不同的粘合温度下出现了不同的金属间化合物,如 Ti2Cu、TiCu2、TiCu、NiTi 和 Ni3Ti,并得出结论:所有样品都实现了等温凝固。在 930 ℃ 时,达到了 278 兆帕的最大剪切强度。在较低的结合温度下,气孔和裂缝的存在会降低剪切强度。在较高温度下,高体积百分比的金属间化合物使试样脆化,降低了其剪切强度。对断裂表面进行扫描电子显微镜观察的结果表明,所有试样都形成了广泛的劈裂断口和河流状图案,这表明试样属于脆性破坏模式。
{"title":"Dissimilar transient liquid phase bonding of Ti-6Al-4V alloy to Inconel 625 superalloy: effect of bonding temperature on microstructural evolutions and mechanical properties","authors":"Behnam Zorriatolhosseini,&nbsp;Seyyed Ehsan Mirsalehi,&nbsp;Faezeh Shamsi","doi":"10.1007/s40194-024-01777-7","DOIUrl":"10.1007/s40194-024-01777-7","url":null,"abstract":"<div><p>The present study investigated the effect of bonding temperature on the dissimilar transient liquid phase (TLP)–bonded IN-625/Ti-6Al-4V dissimilar joints using a thin foil of pure copper as the interlayer. The samples were bonded in a vacuum chamber at 900, 930, and 960 °C for 60 min. The results indicated the occurrence of different intermetallic compounds such as Ti<sub>2</sub>Cu, TiCu<sub>2</sub>, TiCu, NiTi, and Ni<sub>3</sub>Ti at different bonding temperatures, and it was concluded that in all the samples, isothermal solidification was accomplished. Maximum shear strength of 278 MPa was achieved at 930 °C. At lower bonding temperatures, the presence of porosities and cracks decreases the shear strength. At higher temperatures, a high-volume percentage of intermetallic compounds embrittled the specimen and reduced its shear strength. The results of scanning electron microscopy of the fracture surfaces revealed the formation of extensive cleavage fracture and river-like patterns in all samples, indicating a brittle failure mode.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140829535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Micro-macro modeling of tensile behavior of a friction stir welded hybrid joint of AlSi10Mg parts produced by powder bed fusion and casting 粉末床熔融和铸造生产的 AlSi10Mg 零件摩擦搅拌焊接混合接头拉伸行为的微观-宏观建模
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-29 DOI: 10.1007/s40194-024-01775-9
Aravindh Nammalvar Raja Rajan, Marcel Krochmal, Thomas Wegener, Alexander Hartmaier, Thomas Niendorf, Ghazal Moeini

Additive manufacturing (AM) has gained considerable interest due to its ability to produce lightweight parts with hierarchical microstructures. However, the current constraints on the build chamber size in powder-bed fusion type AM processes limit its industrial application. A hybrid welded joint, consisting of an AM-processed and a conventionally manufactured part, can be employed to produce larger components. Due to the varying processing conditions, these hybrid welded joints contain a wide range of microstructural heterogeneities, which influences the mechanical properties of the joint. Using a numerical model to predict the mechanical behavior of welded joints by considering the microstructural variations is essential for the safe and reliable implementation of hybrid welded joints. This study aims to predict the local tensile behavior of each region of a hybrid friction-stir welded joint of AlSi10Mg produced by laser-based powder bed fusion and casting using a microstructure-sensitive model as well as the global tensile behavior by considering the properties of each region using a joint macroscopic model. The results from this modeling approach agree well with the experimental results. Therefore, this method can predict the mechanical behavior of hybrid welded joints and can establish the structure–property relationship in each weld region.

快速成型制造(AM)能够生产出具有分层微结构的轻质部件,因此受到了广泛关注。然而,目前粉末床熔融式快速成型工艺对成型室尺寸的限制限制了其工业应用。混合焊接接头由一个 AM 加工部件和一个传统制造部件组成,可用于生产较大的部件。由于加工条件的不同,这些混合焊点包含多种微观结构异质性,从而影响了焊点的机械性能。考虑到微观结构的变化,使用数值模型预测焊接接头的机械性能对于安全可靠地实施混合焊接接头至关重要。本研究旨在使用微观结构敏感模型预测基于激光的粉末床熔铸技术生产的 AlSi10Mg 混合摩擦搅拌焊接接头每个区域的局部拉伸行为,并使用接头宏观模型考虑每个区域的特性,预测整体拉伸行为。这种建模方法得出的结果与实验结果非常吻合。因此,这种方法可以预测混合焊接接头的力学行为,并能建立每个焊接区域的结构-性能关系。
{"title":"Micro-macro modeling of tensile behavior of a friction stir welded hybrid joint of AlSi10Mg parts produced by powder bed fusion and casting","authors":"Aravindh Nammalvar Raja Rajan,&nbsp;Marcel Krochmal,&nbsp;Thomas Wegener,&nbsp;Alexander Hartmaier,&nbsp;Thomas Niendorf,&nbsp;Ghazal Moeini","doi":"10.1007/s40194-024-01775-9","DOIUrl":"10.1007/s40194-024-01775-9","url":null,"abstract":"<div><p>Additive manufacturing (AM) has gained considerable interest due to its ability to produce lightweight parts with hierarchical microstructures. However, the current constraints on the build chamber size in powder-bed fusion type AM processes limit its industrial application. A hybrid welded joint, consisting of an AM-processed and a conventionally manufactured part, can be employed to produce larger components. Due to the varying processing conditions, these hybrid welded joints contain a wide range of microstructural heterogeneities, which influences the mechanical properties of the joint. Using a numerical model to predict the mechanical behavior of welded joints by considering the microstructural variations is essential for the safe and reliable implementation of hybrid welded joints. This study aims to predict the local tensile behavior of each region of a hybrid friction-stir welded joint of AlSi10Mg produced by laser-based powder bed fusion and casting using a microstructure-sensitive model as well as the global tensile behavior by considering the properties of each region using a joint macroscopic model. The results from this modeling approach agree well with the experimental results. Therefore, this method can predict the mechanical behavior of hybrid welded joints and can establish the structure–property relationship in each weld region.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01775-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modification of electro gas weld metal microstructure reflecting mechanical property specifications in cruise vessel shipbuilding 邮轮造船中反映机械性能规范的气体保护焊缝金属微观结构改性
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-29 DOI: 10.1007/s40194-024-01779-5
Richard Banaschik, Oliver Brätz, Andreas Gericke, Knuth-Michael Henkel

To identify the microstructural factors effecting the electro gas welding (EGW) weld metal properties, this study investigated the influence of different prototype welding consumables and shielding gases on the microstructural composition and mechanical-technological properties. The aim was to adjust the weld metal properties as a trade-off between strength, ductility, and impact toughness to fulfill typical weld metal material specifications in cruise vessel shipbuilding under consideration of the manufacturing conditions at European shipyards. The microstructure is analyzed by quantitative metallography of the ferritic matrix, martensite-retained austenite (M/A) constituents, and non-metallic inclusions (NMI). The influence of the Ni content, the deoxidation concept by variation of Si and Ti contents, and different shielding gas activity by variation of the Ar proportions is discussed. The interaction of ferritic matrix with high acicular ferrite content of about 70 ± 10%, the existence of larger grain boundary ferrite formations, and the M/A morphology plus distribution are considered as the determining factors for the material properties.

为了确定影响气体保护焊(EGW)焊缝金属特性的微观结构因素,本研究调查了不同原型焊材和保护气体对微观结构组成和机械技术特性的影响。目的是根据欧洲造船厂的生产条件,在强度、延展性和冲击韧性之间进行权衡,调整焊缝金属性能,以满足游轮造船业典型的焊缝金属材料规格要求。通过对铁素体基体、马氏体-残余奥氏体(M/A)成分和非金属夹杂物(NMI)的定量金相分析,对微观结构进行了分析。讨论了镍含量的影响、Si 和 Ti 含量变化带来的脱氧概念以及 Ar 比例变化带来的不同屏蔽气体活性。铁素体基体与高针状铁素体含量(约 70 ± 10%)的相互作用、较大晶界铁素体的形成以及 M/A 形态和分布被认为是材料性能的决定因素。
{"title":"Modification of electro gas weld metal microstructure reflecting mechanical property specifications in cruise vessel shipbuilding","authors":"Richard Banaschik,&nbsp;Oliver Brätz,&nbsp;Andreas Gericke,&nbsp;Knuth-Michael Henkel","doi":"10.1007/s40194-024-01779-5","DOIUrl":"10.1007/s40194-024-01779-5","url":null,"abstract":"<div><p>To identify the microstructural factors effecting the electro gas welding (EGW) weld metal properties, this study investigated the influence of different prototype welding consumables and shielding gases on the microstructural composition and mechanical-technological properties. The aim was to adjust the weld metal properties as a trade-off between strength, ductility, and impact toughness to fulfill typical weld metal material specifications in cruise vessel shipbuilding under consideration of the manufacturing conditions at European shipyards. The microstructure is analyzed by quantitative metallography of the ferritic matrix, martensite-retained austenite (M/A) constituents, and non-metallic inclusions (NMI). The influence of the Ni content, the deoxidation concept by variation of Si and Ti contents, and different shielding gas activity by variation of the Ar proportions is discussed. The interaction of ferritic matrix with high acicular ferrite content of about 70 ± 10%, the existence of larger grain boundary ferrite formations, and the M/A morphology plus distribution are considered as the determining factors for the material properties.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01779-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140830089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of the effects of beam oscillations in electron beam–welded S1100M TMCP steel 电子束焊接 S1100M TMCP 钢中束流振荡影响的研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-26 DOI: 10.1007/s40194-024-01765-x
Raghawendra P. S. Sisodia, Marcell Gáspár, Sumit Ghosh, Erika Hodúlová

The development of thermomechanically controlled processed (TMCP) high-strength steel (HSS) has significantly contributed to designing and developing the intricate structural components. It has broader applications in the cranes and lifting process industry (base frame, crane jibs, and crane columns), trailers, agricultural and forestry machinery, earth-moving equipment, etc. However, the development of new-grade steels with higher tensile strength led to higher requirements for welded joints, and the associated weldability issues have inspired detailed studies on electron beam welding (EBW) with different beam oscillations. Beam oscillation application with EBW processes improves the welding efficiency, weld quality, weld geometry, keyhole, etc., affecting the welded joints mechanical and microstructural properties. Thus, the present study investigates the impact and comparison of various beam oscillations on the microstructural and mechanical properties of EB-welded S1100M steel. The influence of welding parameters on the microstructure of welded joints was analyzed using a scanning electron microscope (SEM) and electron backscattered diffraction (EBSD). The analysis focused on evaluation of grain sizes, morphologies, distributions, and crystallographic orientations of different phase constituents in fusion zone (FZ) and heat-affected zone (HAZ). The mechanical properties were analyzed using hardness, tensile, and Charpy V-notch impact tests. The texture in the FZ is typically random, while the HAZ typically exhibits a strong rolling texture. In general, the cooling rate in EBW is very fast, possibly resulting in a fine-grained structure and reduced formation of coarse second-phase particles in the weld zone. The elliptical beam oscillation showed the highest hardness in HAZ 450 HV10. Elliptical beam oscillation slightly improves the welded joint’s tensile strength, and the impact test showed mixed fracture behavior.

热机械控制加工(TMCP)高强度钢(HSS)的发展极大地促进了复杂结构部件的设计和开发。它在起重机和起重加工业(底架、起重机副臂和起重机立柱)、拖车、农业和林业机械、推土设备等领域有着广泛的应用。然而,抗拉强度更高的新型钢材的开发对焊接接头提出了更高的要求,相关的可焊性问题激发了对不同光束振荡的电子束焊接(EBW)的详细研究。在 EBW 过程中应用电子束振荡可提高焊接效率、焊接质量、焊接几何形状、键孔等,从而影响焊接接头的机械和微观结构特性。因此,本研究调查和比较了各种光束振荡对 EB 焊接 S1100M 钢的微观结构和机械性能的影响。研究使用扫描电子显微镜(SEM)和电子反向散射衍射(EBSD)分析了焊接参数对焊接接头微观结构的影响。分析的重点是评估熔合区(FZ)和热影响区(HAZ)中不同相成分的晶粒大小、形态、分布和结晶取向。使用硬度、拉伸和夏比 V 型缺口冲击试验分析了机械性能。熔合区的纹理通常是随机的,而热影响区通常表现出强烈的轧制纹理。一般来说,EBW 的冷却速度非常快,这可能导致了细粒结构,减少了焊接区粗大第二相颗粒的形成。在 HAZ 450 HV10 中,椭圆形光束振荡的硬度最高。椭圆梁振荡略微提高了焊接接头的抗拉强度,冲击试验显示了混合断裂行为。
{"title":"Investigation of the effects of beam oscillations in electron beam–welded S1100M TMCP steel","authors":"Raghawendra P. S. Sisodia,&nbsp;Marcell Gáspár,&nbsp;Sumit Ghosh,&nbsp;Erika Hodúlová","doi":"10.1007/s40194-024-01765-x","DOIUrl":"10.1007/s40194-024-01765-x","url":null,"abstract":"<div><p>The development of thermomechanically controlled processed (TMCP) high-strength steel (HSS) has significantly contributed to designing and developing the intricate structural components. It has broader applications in the cranes and lifting process industry (base frame, crane jibs, and crane columns), trailers, agricultural and forestry machinery, earth-moving equipment, etc. However, the development of new-grade steels with higher tensile strength led to higher requirements for welded joints, and the associated weldability issues have inspired detailed studies on electron beam welding (EBW) with different beam oscillations. Beam oscillation application with EBW processes improves the welding efficiency, weld quality, weld geometry, keyhole, etc., affecting the welded joints mechanical and microstructural properties. Thus, the present study investigates the impact and comparison of various beam oscillations on the microstructural and mechanical properties of EB-welded S1100M steel. The influence of welding parameters on the microstructure of welded joints was analyzed using a scanning electron microscope (SEM) and electron backscattered diffraction (EBSD). The analysis focused on evaluation of grain sizes, morphologies, distributions, and crystallographic orientations of different phase constituents in fusion zone (FZ) and heat-affected zone (HAZ). The mechanical properties were analyzed using hardness, tensile, and Charpy V-notch impact tests. The texture in the FZ is typically random, while the HAZ typically exhibits a strong rolling texture. In general, the cooling rate in EBW is very fast, possibly resulting in a fine-grained structure and reduced formation of coarse second-phase particles in the weld zone. The elliptical beam oscillation showed the highest hardness in HAZ 450 HV10. Elliptical beam oscillation slightly improves the welded joint’s tensile strength, and the impact test showed mixed fracture behavior.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":null,"pages":null},"PeriodicalIF":2.4,"publicationDate":"2024-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01765-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140810569","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Welding in the World
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1