首页 > 最新文献

Welding in the World最新文献

英文 中文
Shunt current-assisted one-step resistance element welding of vibration-damping aluminum to ultra-high-strength hot-press-formed steel 减振铝与超高强度热压成形钢的分流电流辅助一步电阻元件焊接
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-14 DOI: 10.1007/s40194-025-02065-8
EunBeen Gong, Sunusi Marwana Manladan, Nellikode Savyasachi, Siva Prasad Murugan, Ki-Man Bae, Jong-Jin Baek, Changwook Ji, Yeong-Do Park

To satisfy recent demands for reducing NVH (noise, vibration, harshness), vehicle weight, and improving collision safety, the development of reliable processes for dissimilar joining of lightweight vibration-damping aluminum to ultra-high strength steels is required. The resistance element welding (REW) process to join the dissimilar material involves a two-step process of pre-drilling a hole in the aluminum to insert the element and then welding to join the element to steel. Consequently, this increases cycle time and makes it challenging to ensure joint quality due to potential robot teaching errors. To overcome these limitations, an innovative one-step REW process was proposed to shorten the two-step REW process into a single process. However, the thermoplastic resin layer at the interface of the vibration-damping aluminum limits current conduction, posing challenges for REW. The current study introduces stainless-steel clips to bypass the thermoplastic resin layer between the vibration-damping aluminum, which limits the current conduction during the one-step REW process. The adjacent REW joint ensures further bypass of the current and acts as an initial weld point (shunt weld) for continuous one-step REW. Optimization of the welding variables was carried out to achieve excellent joint performance in terms of joint formation. Subsequently, the quality evaluation of the joint was done based on the evaluation of microstructure and mechanical properties. This process significantly enhances productivity with one-step REW instead of the traditional two-step welding. It surpasses the difficulty of welding the vibration-damping aluminum to HPF (hot press forming) steel.

为了满足最近对降低NVH(噪音、振动、粗糙度)、车辆重量和提高碰撞安全性的要求,需要开发可靠的轻质减振铝与超高强度钢的不同连接工艺。连接异种材料的电阻元件焊接(REW)工艺包括两个步骤,首先在铝上预钻一个孔以插入元件,然后焊接将元件连接到钢上。因此,这增加了周期时间,并且由于潜在的机器人教学错误而使确保关节质量变得具有挑战性。为了克服这些限制,提出了一种创新的一步REW工艺,将两步REW工艺缩短为单一工艺。然而,减振铝界面的热塑性树脂层限制了电流的传导,给REW带来了挑战。目前的研究引入了不锈钢夹来绕过减振铝之间的热塑性树脂层,这限制了一步REW过程中的电流传导。相邻的REW接头确保了电流的进一步旁路,并作为连续一步REW的初始焊接点(分流焊接)。对焊接变量进行了优化,在接头成形方面实现了优异的接头性能。随后,通过对接头的微观组织和力学性能进行评价,对接头进行质量评价。该工艺显著提高了一步REW的生产率,而不是传统的两步焊接。它超越了减振铝与热压成形钢焊接的难度。
{"title":"Shunt current-assisted one-step resistance element welding of vibration-damping aluminum to ultra-high-strength hot-press-formed steel","authors":"EunBeen Gong,&nbsp;Sunusi Marwana Manladan,&nbsp;Nellikode Savyasachi,&nbsp;Siva Prasad Murugan,&nbsp;Ki-Man Bae,&nbsp;Jong-Jin Baek,&nbsp;Changwook Ji,&nbsp;Yeong-Do Park","doi":"10.1007/s40194-025-02065-8","DOIUrl":"10.1007/s40194-025-02065-8","url":null,"abstract":"<div><p>To satisfy recent demands for reducing NVH (noise, vibration, harshness), vehicle weight, and improving collision safety, the development of reliable processes for dissimilar joining of lightweight vibration-damping aluminum to ultra-high strength steels is required. The resistance element welding (REW) process to join the dissimilar material involves a two-step process of pre-drilling a hole in the aluminum to insert the element and then welding to join the element to steel. Consequently, this increases cycle time and makes it challenging to ensure joint quality due to potential robot teaching errors. To overcome these limitations, an innovative one-step REW process was proposed to shorten the two-step REW process into a single process. However, the thermoplastic resin layer at the interface of the vibration-damping aluminum limits current conduction, posing challenges for REW. The current study introduces stainless-steel clips to bypass the thermoplastic resin layer between the vibration-damping aluminum, which limits the current conduction during the one-step REW process. The adjacent REW joint ensures further bypass of the current and acts as an initial weld point (shunt weld) for continuous one-step REW. Optimization of the welding variables was carried out to achieve excellent joint performance in terms of joint formation. Subsequently, the quality evaluation of the joint was done based on the evaluation of microstructure and mechanical properties. This process significantly enhances productivity with one-step REW instead of the traditional two-step welding. It surpasses the difficulty of welding the vibration-damping aluminum to HPF (hot press forming) steel.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 7","pages":"2159 - 2170"},"PeriodicalIF":2.5,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145165332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid ultrasonic arc welding of nickel-based alloys: improved cavitation and grain refinement 镍基合金复合超声弧焊:改善空化和晶粒细化
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-14 DOI: 10.1007/s40194-025-02070-x
Yunhao Xia, Bolun Dong, Yangyang Fan, Qihao Chen, Xiaoyu Cai, Sanbao Lin

Hybrid ultrasonic welding experiments on Inconel 625 alloy were carried out to address the challenges of refining microstructure. The welding process phenomena and resulting microstructures were systematically analyzed. Four distinct welding methods—conventional tungsten inert gas (C-TIG), ultrasonic-frequency pulsed TIG (UFP-TIG), ultrasonic vibration-assisted TIG (UV-TIG), and hybrid ultrasonic TIG (HU-TIG)—were compared in terms of grain morphology, grain size distribution, and overall refinement. In the weld zone adjacent to the fusion line, hybrid ultrasonic treatment demonstrated a superior effect on grain morphology adjustment. The results show that HU-TIG effectively suppresses columnar growth and increases the proportion of equiaxed grains, yielding a finer microstructure than the other methods. The synergy of ultrasonic-frequency pulsing and mechanical ultrasonic vibration enhances cavitation activity in the molten pool, promoting dendrite fragmentation and homogenizing elemental distribution. Moreover, ultrasonic-frequency pulsed arcs alter the physical properties of the molten pool, enabling the melt to respond more effectively to ultrasonic cavitation.

针对Inconel 625合金微观组织的细化问题,进行了复合超声焊接试验。系统地分析了焊接过程中的现象和产生的显微组织。对传统钨惰性气体(C-TIG)、超声频率脉冲TIG (UFP-TIG)、超声振动辅助TIG (UV-TIG)和混合超声TIG (HU-TIG)四种不同的焊接方法进行了晶粒形貌、晶粒尺寸分布和整体细化的比较。在靠近熔合线的焊接区,复合超声处理对晶粒形貌的调整效果较好。结果表明,HU-TIG有效地抑制了柱状晶粒的生长,增加了等轴晶的比例,获得了比其他方法更精细的组织。超声频率脉冲和机械超声振动的协同作用增强了熔池中的空化活性,促进了枝晶破碎和元素均匀分布。此外,超声频率脉冲电弧改变了熔池的物理性质,使熔体更有效地响应超声空化。
{"title":"Hybrid ultrasonic arc welding of nickel-based alloys: improved cavitation and grain refinement","authors":"Yunhao Xia,&nbsp;Bolun Dong,&nbsp;Yangyang Fan,&nbsp;Qihao Chen,&nbsp;Xiaoyu Cai,&nbsp;Sanbao Lin","doi":"10.1007/s40194-025-02070-x","DOIUrl":"10.1007/s40194-025-02070-x","url":null,"abstract":"<div><p>Hybrid ultrasonic welding experiments on Inconel 625 alloy were carried out to address the challenges of refining microstructure. The welding process phenomena and resulting microstructures were systematically analyzed. Four distinct welding methods—conventional tungsten inert gas (C-TIG), ultrasonic-frequency pulsed TIG (UFP-TIG), ultrasonic vibration-assisted TIG (UV-TIG), and hybrid ultrasonic TIG (HU-TIG)—were compared in terms of grain morphology, grain size distribution, and overall refinement. In the weld zone adjacent to the fusion line, hybrid ultrasonic treatment demonstrated a superior effect on grain morphology adjustment. The results show that HU-TIG effectively suppresses columnar growth and increases the proportion of equiaxed grains, yielding a finer microstructure than the other methods. The synergy of ultrasonic-frequency pulsing and mechanical ultrasonic vibration enhances cavitation activity in the molten pool, promoting dendrite fragmentation and homogenizing elemental distribution. Moreover, ultrasonic-frequency pulsed arcs alter the physical properties of the molten pool, enabling the melt to respond more effectively to ultrasonic cavitation.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 10","pages":"3115 - 3127"},"PeriodicalIF":2.5,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145062149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of process parameters on microstructure and mechanical properties of ER 4043 Al-5Si alloys fabricated by wire arc additive manufacturing 工艺参数对电弧增材制造ER 4043 Al-5Si合金组织和力学性能的影响
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-14 DOI: 10.1007/s40194-025-02067-6
Yongxing Li, Dongyu Liu, Yansong Huang, Zeyu Yang, Xin Shang

In this study, thin-walled parts of ER 4043 Al-5Si alloys were deposited using the cold metal transfer (CMT)-wire arc additive manufacturing (WAAM) process. The effects of variation of process parameters of wire feed speed (WFS), interlayer time interval (ITI), and travel speed (TS) on the microstructure and mechanical properties of thin-walled parts were investigated. The results showed that the microstructures of the thin-walled parts were composed of the α-Al phase and Al-Si eutectic phase. The samples deposited by WAAM consisted mainly of a large number of columnar grains and a few equiaxial grains. As WFS increased, heat input increased and reduced the temperature gradient; the average grain size of thin-walled parts increased significantly from 90 μm to 135 μm. The maximum texture intensity of the thin-walled parts is also increased. The ultimate tensile strength (UTS) of the samples decreased from 134 to 101 MPa. As ITI increased, the average grain size of thin-walled parts decreased from 122 to 85 μm due to higher subcooling and temperature gradient. This resulted in an increase in UTS from 104 to 130 MPa. Although the increased TS enhances the solidification rate, the average grain size of the thin-walled parts only decreases from 145 to 129 μm. The UTS of thin-walled parts was increased from 123 to 146 MPa. The tensile fractures of the samples were plastic fractures; therefore, the samples maintained high elongation (EL). In addition, the anisotropy in the mechanical properties results from differences in grain size, directional growth and inhomogeneous grain structure, eutectic microstructure, and texture.

本研究采用冷金属转移(CMT)-电弧增材制造(WAAM)工艺沉积ER 4043 Al-5Si合金薄壁件。研究了送丝速度(WFS)、层间时间间隔(ITI)和行程速度(TS)等工艺参数的变化对薄壁件显微组织和力学性能的影响。结果表明:薄壁件的显微组织由α-Al相和Al-Si共晶相组成;WAAM沉积的样品主要由大量柱状晶粒和少量等轴晶粒组成。随着WFS的增加,热输入增加,温度梯度减小;薄壁件的平均晶粒尺寸由90 μm显著增大到135 μm。薄壁件的最大织构强度也有所提高。试样的极限抗拉强度(UTS)由134 MPa降至101 MPa。随着ti的增大,由于过冷度增大和温度梯度增大,薄壁件的平均晶粒尺寸从122 μm减小到85 μm。这使得UTS从104兆帕增加到130兆帕。TS的增加虽然提高了凝固速度,但薄壁件的平均晶粒尺寸仅从145 μm减小到129 μm。薄壁件的UTS由123 MPa提高到146 MPa。试样的拉伸断裂为塑性断裂;因此,样品保持了较高的延伸率。此外,力学性能的各向异性是由晶粒尺寸、定向生长和不均匀晶粒组织、共晶组织和织构的差异造成的。
{"title":"Influence of process parameters on microstructure and mechanical properties of ER 4043 Al-5Si alloys fabricated by wire arc additive manufacturing","authors":"Yongxing Li,&nbsp;Dongyu Liu,&nbsp;Yansong Huang,&nbsp;Zeyu Yang,&nbsp;Xin Shang","doi":"10.1007/s40194-025-02067-6","DOIUrl":"10.1007/s40194-025-02067-6","url":null,"abstract":"<div><p>In this study, thin-walled parts of ER 4043 Al-5Si alloys were deposited using the cold metal transfer (CMT)-wire arc additive manufacturing (WAAM) process. The effects of variation of process parameters of wire feed speed (WFS), interlayer time interval (ITI), and travel speed (TS) on the microstructure and mechanical properties of thin-walled parts were investigated. The results showed that the microstructures of the thin-walled parts were composed of the α-Al phase and Al-Si eutectic phase. The samples deposited by WAAM consisted mainly of a large number of columnar grains and a few equiaxial grains. As WFS increased, heat input increased and reduced the temperature gradient; the average grain size of thin-walled parts increased significantly from 90 μm to 135 μm. The maximum texture intensity of the thin-walled parts is also increased. The ultimate tensile strength (UTS) of the samples decreased from 134 to 101 MPa. As ITI increased, the average grain size of thin-walled parts decreased from 122 to 85 μm due to higher subcooling and temperature gradient. This resulted in an increase in UTS from 104 to 130 MPa. Although the increased TS enhances the solidification rate, the average grain size of the thin-walled parts only decreases from 145 to 129 μm. The UTS of thin-walled parts was increased from 123 to 146 MPa. The tensile fractures of the samples were plastic fractures; therefore, the samples maintained high elongation (EL). In addition, the anisotropy in the mechanical properties results from differences in grain size, directional growth and inhomogeneous grain structure, eutectic microstructure, and texture.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 11","pages":"3285 - 3303"},"PeriodicalIF":2.5,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145230491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deep learning for predicting welding distortions in T-joints 基于深度学习的t型接头焊接变形预测
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-13 DOI: 10.1007/s40194-025-02056-9
Mahdi Karimi, Narges Mokhtari, Jasmin Jelovica

Stiffened panels are common structural units in marine vessels, civil and aerospace structures. Production via welding can lead to excessive distortion of their plates, which negatively affects structural integrity and dimensional accuracy. Conventional practical approaches for distortion control are costly, making simulation models attractive tools to mitigate distortions. Prediction of welding distortions using finite element (FE) simulations is computationally intensive, especially when used repeatedly in design and optimization. Effective surrogate models in the form of deep learning could alleviate this issue, but the selection and construction of deep neural networks for this purpose are presently unclear. This study focuses on predicting welding-induced distortions in a T-joint. Two neural networks—a multilayer perceptron (MLP) and a convolutional neural network (CNN)—are employed to predict distortions. Two case studies are conducted for each model, exploring variations in geometry and welding sequences. The database is generated from FE simulations of the gas metal arc welding (GMAW) process. The effects of welding order and direction on distortions are studied, concluding that an appropriate selection of welding sequence and direction can reduce distortion by up to 40%. This data is then used to train the neural networks. The MLP and CNN models are designed and trained to predict distortion fields by tuning their architecture and other hyperparameters. Results demonstrate that both models are effective; however, the CNN achieves higher accuracy for complex distortion patterns, highlighting its suitability for more intricate scenarios. 

加筋板是船舶、民用和航空航天结构中常见的结构单元。通过焊接生产会导致板材过度变形,从而对结构完整性和尺寸精度产生负面影响。传统的实际畸变控制方法是昂贵的,使仿真模型有吸引力的工具,以减轻畸变。利用有限元模拟预测焊接变形需要大量的计算量,尤其是在设计和优化中反复使用时。深度学习形式的有效代理模型可以缓解这一问题,但目前尚不清楚为此目的选择和构建深度神经网络。本研究的重点是预测焊接引起的t形接头变形。两个神经网络——一个多层感知器(MLP)和一个卷积神经网络(CNN)——被用来预测扭曲。每个模型进行了两个案例研究,探索几何形状和焊接顺序的变化。该数据库是通过对气体金属弧焊(GMAW)过程的有限元模拟生成的。研究了焊接顺序和方向对变形的影响,结果表明,合理选择焊接顺序和方向可使变形率降低40%。这些数据随后被用来训练神经网络。MLP和CNN模型被设计和训练为通过调整它们的结构和其他超参数来预测失真场。结果表明,两种模型都是有效的;然而,CNN在复杂的失真模式上达到了更高的精度,突出了它对更复杂场景的适用性。
{"title":"Deep learning for predicting welding distortions in T-joints","authors":"Mahdi Karimi,&nbsp;Narges Mokhtari,&nbsp;Jasmin Jelovica","doi":"10.1007/s40194-025-02056-9","DOIUrl":"10.1007/s40194-025-02056-9","url":null,"abstract":"<div><p>Stiffened panels are common structural units in marine vessels, civil and aerospace structures. Production via welding can lead to excessive distortion of their plates, which negatively affects structural integrity and dimensional accuracy. Conventional practical approaches for distortion control are costly, making simulation models attractive tools to mitigate distortions. Prediction of welding distortions using finite element (FE) simulations is computationally intensive, especially when used repeatedly in design and optimization. Effective surrogate models in the form of deep learning could alleviate this issue, but the selection and construction of deep neural networks for this purpose are presently unclear. This study focuses on predicting welding-induced distortions in a T-joint. Two neural networks—a multilayer perceptron (MLP) and a convolutional neural network (CNN)—are employed to predict distortions. Two case studies are conducted for each model, exploring variations in geometry and welding sequences. The database is generated from FE simulations of the gas metal arc welding (GMAW) process. The effects of welding order and direction on distortions are studied, concluding that an appropriate selection of welding sequence and direction can reduce distortion by up to 40%. This data is then used to train the neural networks. The MLP and CNN models are designed and trained to predict distortion fields by tuning their architecture and other hyperparameters. Results demonstrate that both models are effective; however, the CNN achieves higher accuracy for complex distortion patterns, highlighting its suitability for more intricate scenarios. </p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 8","pages":"2483 - 2507"},"PeriodicalIF":2.5,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145165280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Oscillation-driven grain structure control and its mechanisms in Ti64 wire arc additive manufacturing Ti64电弧增材制造中振荡驱动晶粒结构控制及其机理
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-12 DOI: 10.1007/s40194-025-02064-9
Guo Xian, Muralimohan Cheepu, Namhyun Kang

Controlling prior-β grain morphology is crucial for achieving specific isotropic properties in Wire Arc Additive Manufacturing (WAAM). Arc oscillation has been proven effective in refining grain size during aluminum welding, primarily due to the dendrite fragmentation mechanism. However, its impact on the grain structure of Ti-6Al-4 V remains underexplored. In this study, various arc oscillation amplitudes were applied to assess grain morphology evolution. In the stringer method (without oscillation), 100% equiaxed grains were observed in both the transverse and longitudinal directions due to lower heat input. As oscillation amplitude increased, the grain structure gradually transformed from equiaxed to columnar. At an amplitude of 6 mm, 80% columnar grains were obtained. To understand these findings, numerical simulations were conducted to quantitatively analyze the thermal history. SYSWELD calculations showed that a larger oscillation amplitude (6 mm) significantly influenced the weld pool shape (height and width), amplifying the temperature gradient (G) to nearly twice that of the specimen without oscillation during solidification. Furthermore, the dendrite fragmentation mechanism suggests that although thermal fluctuations caused by oscillation were observed in the molten region, they gradually dissipated after one or two remelting cycles. Controlling the frequency of these thermal fluctuations and the weld geometry presents a potential approach to modifying prior-β in Ti-6Al-4 V using arc oscillation.

在电弧增材制造(WAAM)中,控制预先的-β晶粒形态对于实现特定的各向同性性能至关重要。在铝焊接过程中,电弧振荡对细化晶粒是有效的,这主要是由于枝晶断裂机制造成的。然而,其对ti - 6al - 4v晶粒结构的影响尚不清楚。在本研究中,采用不同的电弧振荡幅度来评估晶粒形貌演变。在无振荡的弦法中,由于较低的热输入,在横向和纵向上均观察到100%等轴晶粒。随着振荡振幅的增大,晶粒结构逐渐由等轴向柱状转变。在振幅为6 mm时,得到80%的柱状晶粒。为了理解这些发现,进行了数值模拟来定量分析热历史。SYSWELD计算表明,较大的振荡幅度(6 mm)显著影响熔池形状(高度和宽度),使凝固过程中的温度梯度(G)放大到几乎是无振荡试样的两倍。此外,枝晶破碎机制表明,虽然在熔融区观察到振荡引起的热波动,但在一到两次重熔循环后,它们逐渐消散。控制这些热波动的频率和焊缝的几何形状是利用电弧振荡来改变ti - 6al - 4v中先验-β的一种潜在方法。
{"title":"Oscillation-driven grain structure control and its mechanisms in Ti64 wire arc additive manufacturing","authors":"Guo Xian,&nbsp;Muralimohan Cheepu,&nbsp;Namhyun Kang","doi":"10.1007/s40194-025-02064-9","DOIUrl":"10.1007/s40194-025-02064-9","url":null,"abstract":"<div><p>Controlling prior-β grain morphology is crucial for achieving specific isotropic properties in Wire Arc Additive Manufacturing (WAAM). Arc oscillation has been proven effective in refining grain size during aluminum welding, primarily due to the dendrite fragmentation mechanism. However, its impact on the grain structure of Ti-6Al-4 V remains underexplored. In this study, various arc oscillation amplitudes were applied to assess grain morphology evolution. In the stringer method (without oscillation), 100% equiaxed grains were observed in both the transverse and longitudinal directions due to lower heat input. As oscillation amplitude increased, the grain structure gradually transformed from equiaxed to columnar. At an amplitude of 6 mm, 80% columnar grains were obtained. To understand these findings, numerical simulations were conducted to quantitatively analyze the thermal history. SYSWELD calculations showed that a larger oscillation amplitude (6 mm) significantly influenced the weld pool shape (height and width), amplifying the temperature gradient (G) to nearly twice that of the specimen without oscillation during solidification. Furthermore, the dendrite fragmentation mechanism suggests that although thermal fluctuations caused by oscillation were observed in the molten region, they gradually dissipated after one or two remelting cycles. Controlling the frequency of these thermal fluctuations and the weld geometry presents a potential approach to modifying prior-β in Ti-6Al-4 V using arc oscillation.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 12","pages":"3675 - 3692"},"PeriodicalIF":2.5,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145456790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-resolution thermal imaging for melt pool dynamics studies in TIG welding process 高分辨率热成像用于TIG焊接过程熔池动力学研究
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-10 DOI: 10.1007/s40194-025-02055-w
Vinicius Lemes Jorge, Issam Bendaoud, Fabien Soulié, Cyril Bordreuil

Challenges in terms of reliability still surround thermal measurement methods in welding processes. However, the temperature distribution within the weld pool can provide important resources for understanding behaviors and explaining phenomena. This work aims to study the effect of gravity on the temperature distribution within the weld pool under different welding positions using an in-house developed equipment. First, a combination of optical settings and a calibration procedure were established. Experiments were carried out with the same welding parameters under flat, horizontal, vertical upward, and vertical downward positions. The thermal field from the backside of fully penetrated thin plates was accessed using the TIG process. The device allowed a well-delimited and detailed weld pool thermal field assessment. Dimensionless numbers were quantified, and Marangoni shear stress was plotted on the weld pool surface. Along the transversal weld pool direction, a symmetrical heat distribution was stated in the flat position, while an asymmetrical one was observed in the others. The Marangoni effect played a crucial role in all the experiments, emerging as the dominant driving force in 1G and 2G positions. It governed the fluid flow within the weld pool by influencing temperature gradients over time, which, in turn, altered the direction and magnitude of shear stress on the free surface. Notably, in the 2G position, the observed asymmetry in the weld pool features may be attributed to the combined effects of buoyancy and Marangoni forces acting together. Finally, through the developed equipment, it was possible to evaluate the impacts of gravity on the heat distribution within the weld pool and demonstrate its contribution to dynamics studies.

焊接过程中的热测量方法仍然面临着可靠性方面的挑战。然而,焊池内的温度分布可以为理解行为和解释现象提供重要的资源。本工作旨在利用自行研制的设备,研究重力对不同焊接位置下熔池内温度分布的影响。首先,建立了光学设置和校准程序的组合。在相同的焊接参数下进行了平、水平、垂直向上和垂直向下的焊接试验。采用TIG法获得了完全穿透薄板背面的热场。该设备可以对焊接池进行详细的热场评估。对无因次数进行量化,绘制熔池表面的Marangoni剪应力图。沿横向熔池方向,平坦部位的热分布呈对称分布,其余部位的热分布呈不对称分布。马兰戈尼效应在所有实验中都发挥了至关重要的作用,成为1G和2G位置的主要驱动力。它通过影响温度梯度随时间的变化来控制焊池内的流体流动,而温度梯度又改变了自由表面上剪切应力的方向和大小。值得注意的是,在2G位置,观察到的焊缝池特征的不对称可能归因于浮力和Marangoni力共同作用的综合影响。最后,通过开发的设备,可以评估重力对焊接池内热分布的影响,并证明其对动力学研究的贡献。
{"title":"High-resolution thermal imaging for melt pool dynamics studies in TIG welding process","authors":"Vinicius Lemes Jorge,&nbsp;Issam Bendaoud,&nbsp;Fabien Soulié,&nbsp;Cyril Bordreuil","doi":"10.1007/s40194-025-02055-w","DOIUrl":"10.1007/s40194-025-02055-w","url":null,"abstract":"<div><p>Challenges in terms of reliability still surround thermal measurement methods in welding processes. However, the temperature distribution within the weld pool can provide important resources for understanding behaviors and explaining phenomena. This work aims to study the effect of gravity on the temperature distribution within the weld pool under different welding positions using an in-house developed equipment. First, a combination of optical settings and a calibration procedure were established. Experiments were carried out with the same welding parameters under flat, horizontal, vertical upward, and vertical downward positions. The thermal field from the backside of fully penetrated thin plates was accessed using the TIG process. The device allowed a well-delimited and detailed weld pool thermal field assessment. Dimensionless numbers were quantified, and Marangoni shear stress was plotted on the weld pool surface. Along the transversal weld pool direction, a symmetrical heat distribution was stated in the flat position, while an asymmetrical one was observed in the others. The Marangoni effect played a crucial role in all the experiments, emerging as the dominant driving force in 1G and 2G positions. It governed the fluid flow within the weld pool by influencing temperature gradients over time, which, in turn, altered the direction and magnitude of shear stress on the free surface. Notably, in the 2G position, the observed asymmetry in the weld pool features may be attributed to the combined effects of buoyancy and Marangoni forces acting together. Finally, through the developed equipment, it was possible to evaluate the impacts of gravity on the heat distribution within the weld pool and demonstrate its contribution to dynamics studies.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 9","pages":"2789 - 2804"},"PeriodicalIF":2.5,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145164826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure, abrasive resistance and impact property of Fe-xCr-C-Nb-Mo-V-W hardfacing alloys after heat treatment at 900 °C 900℃热处理后Fe-xCr-C-Nb-Mo-V-W堆焊合金的组织、耐磨性和冲击性能
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-09 DOI: 10.1007/s40194-025-02061-y
Erhu Li, Li Cui, Wei Shao, Yi Xu, Jinman Yu, Dingyong He

High carbon ferrochrome hardfacing alloys are widely used to protect machinery equipment exposed to a combination of abrasion and impact. Strengthening high-chromium iron-based alloys with alloying elements is an important strategy for developing its wear resistance and impact property. In this study, novel complex Fe-xCr-C-Nb-Mo-V-W hardfacing alloys with varying Cr contents of 14, 18 and 23 wt. % were prepared using open arc welding. The effects of the Cr content and the heat treatment on the microstructure, abrasive resistance and impact property of the hardfacing alloys were evaluated. With the rise in Cr content, the area fraction of M7C3 hard phase improves from 56 to 62%, while the grain size of M7C3 is refined from 26.5 μm to 22.0 μm. Results show that increasing Cr content increases the abrasive resistance but declines the impact property of the hardfacing alloys. Heat treatment at 900 °C decreases the area fraction of M7C3 phase and induces the grains coarse, resulting in the descent of the abrasive resistance and ascent of the impact property of the hardfacing alloys. Abrasive test results highlight that the importance of area fraction and grain size of M7C3 phase for abrasive resistance. However, the martensite/ austenite matrix with toughness plays the predominant role in the impact resistance by absorbing and dispersing the impact energy.

高碳铬铁堆焊合金广泛用于保护暴露在磨损和冲击下的机械设备。用合金元素强化高铬铁基合金是提高其耐磨性和冲击性能的重要策略。采用开弧焊法制备了Cr含量分别为14、18和23 wt. %的Fe-xCr-C-Nb-Mo-V-W复合堆焊合金。研究了Cr含量和热处理对堆焊合金组织、耐磨性和冲击性能的影响。随着Cr含量的增加,M7C3硬质相的面积分数从56%提高到62%,晶粒尺寸从26.5 μm细化到22.0 μm。结果表明,Cr含量的增加提高了堆焊合金的耐磨性,但降低了其冲击性能。900℃热处理使堆焊合金的M7C3相的面积分数降低,晶粒变粗,导致堆焊合金的耐磨性下降,冲击性能上升。磨料试验结果表明,M7C3相的面积分数和晶粒尺寸对磨料耐磨性有重要影响。而具有韧性的马氏体/奥氏体基体吸收和分散冲击能量,在抗冲击性能中起主导作用。
{"title":"Microstructure, abrasive resistance and impact property of Fe-xCr-C-Nb-Mo-V-W hardfacing alloys after heat treatment at 900 °C","authors":"Erhu Li,&nbsp;Li Cui,&nbsp;Wei Shao,&nbsp;Yi Xu,&nbsp;Jinman Yu,&nbsp;Dingyong He","doi":"10.1007/s40194-025-02061-y","DOIUrl":"10.1007/s40194-025-02061-y","url":null,"abstract":"<div><p>High carbon ferrochrome hardfacing alloys are widely used to protect machinery equipment exposed to a combination of abrasion and impact. Strengthening high-chromium iron-based alloys with alloying elements is an important strategy for developing its wear resistance and impact property. In this study, novel complex Fe-<i>x</i>Cr-C-Nb-Mo-V-W hardfacing alloys with varying Cr contents of 14, 18 and 23 wt. % were prepared using open arc welding. The effects of the Cr content and the heat treatment on the microstructure, abrasive resistance and impact property of the hardfacing alloys were evaluated. With the rise in Cr content, the area fraction of M<sub>7</sub>C<sub>3</sub> hard phase improves from 56 to 62%, while the grain size of M<sub>7</sub>C<sub>3</sub> is refined from 26.5 μm to 22.0 μm. Results show that increasing Cr content increases the abrasive resistance but declines the impact property of the hardfacing alloys. Heat treatment at 900 °C decreases the area fraction of M<sub>7</sub>C<sub>3</sub> phase and induces the grains coarse, resulting in the descent of the abrasive resistance and ascent of the impact property of the hardfacing alloys. Abrasive test results highlight that the importance of area fraction and grain size of M<sub>7</sub>C<sub>3</sub> phase for abrasive resistance. However, the martensite/ austenite matrix with toughness plays the predominant role in the impact resistance by absorbing and dispersing the impact energy.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 11","pages":"3255 - 3266"},"PeriodicalIF":2.5,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-025-02061-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145230284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combined heating rate and restraint condition effect on stress relief cracking during PWHT of thick-walled Cr–Mo-V steel SAW joints 复合升温速率和约束条件对厚壁Cr-Mo-V钢SAW接头PWHT过程中应力释放开裂的影响
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-08 DOI: 10.1007/s40194-025-02062-x
Michael Rhode, Denis Czeskleba, Hannah Fleißner-Rieger, Jonathan Nietzke, Thomas Kannengiesser

Creep-resistant steels such as 13CrMoV9-10 are utilized in the manufacture of thick-walled pressure vessels and are typically joined by submerged arc welding (SAW). However, these materials are susceptible to stress relief cracking (SRC) if the required post weld heat treatment (PWHT) is not applied correctly. Existing PWHT guidelines, encompassing heating rate and dwell (or holding) time at a given temperature, are derived from a synthesis of empirical knowledge and typically free-shrinkage weld experiments to assess the susceptibility to SRC. Therefore, this study discusses the combined effect of the PWHT heating rate under free-shrinkage compared to restrained shrinkage. Welding experiments were conducted (using plates with a thickness of 25 mm) for both shrinkage conditions for a variety of heating rates and maximum temperatures. In-situ acoustic emission analysis was used to locate propagating SRCs during PWHT. Hardness measurements, mechanical property characterization (Charpy impact strength), and microstructure correlation were used to evaluate the SRC susceptibility. The results suggested that the influence of heating rate could not be directly related to SRC formation and that the initial weld microstructure prior to PWHT was more relevant in terms of very high hardness in the coarse grain heat affected zone, especially that of the last beads in the top layer of the welding sequence. This was seen in the form of random, unexpected SRC occurrence in only one specimen at a heating rate commonly used in welding practice (approximately 100 K/h). In this context, the additional effect of an external shrinkage restraint on SRC must be considered in the form of increasing mechanical loads during welding, which are typically not within the scope of welding practice. To mitigate the probability of SRC during PWHT, it is imperative to reduce the welding heat input and to restrict the structural shrinkage restraint of the weld joint.

13CrMoV9-10等抗蠕变钢用于制造厚壁压力容器,通常通过埋弧焊(SAW)连接。然而,如果没有正确应用所需的焊后热处理(PWHT),这些材料很容易发生应力缓解开裂(SRC)。现有的PWHT指南,包括在给定温度下的加热速率和停留(或保持)时间,是从经验知识和典型的自由收缩焊接实验的综合得出的,以评估对SRC的敏感性。因此,本研究讨论了自由收缩和约束收缩条件下PWHT加热速率的综合影响。在不同加热速率和最高温度下的收缩条件下进行了焊接实验(使用厚度为25 mm的板)。采用原位声发射分析对PWHT过程中传播的SRCs进行定位。硬度测量、力学性能表征(Charpy冲击强度)和微观结构相关性用于评估SRC敏感性。结果表明,加热速率的影响与SRC的形成没有直接关系,而PWHT之前的初始焊缝组织与粗晶热影响区硬度很高有关,尤其是焊接顺序顶层的最后一层珠的硬度很高。在焊接实践中常用的加热速率(约100 K/h)下,只有一个试样出现了随机的、意外的SRC。在这种情况下,外部收缩约束对SRC的额外影响必须以焊接过程中增加机械载荷的形式考虑,这通常不在焊接实践的范围内。为了降低PWHT过程中发生SRC的可能性,必须减少焊接热输入和限制焊缝的结构收缩约束。
{"title":"Combined heating rate and restraint condition effect on stress relief cracking during PWHT of thick-walled Cr–Mo-V steel SAW joints","authors":"Michael Rhode,&nbsp;Denis Czeskleba,&nbsp;Hannah Fleißner-Rieger,&nbsp;Jonathan Nietzke,&nbsp;Thomas Kannengiesser","doi":"10.1007/s40194-025-02062-x","DOIUrl":"10.1007/s40194-025-02062-x","url":null,"abstract":"<div><p>Creep-resistant steels such as 13CrMoV9-10 are utilized in the manufacture of thick-walled pressure vessels and are typically joined by submerged arc welding (SAW). However, these materials are susceptible to stress relief cracking (SRC) if the required post weld heat treatment (PWHT) is not applied correctly. Existing PWHT guidelines, encompassing heating rate and dwell (or holding) time at a given temperature, are derived from a synthesis of empirical knowledge and typically free-shrinkage weld experiments to assess the susceptibility to SRC. Therefore, this study discusses the combined effect of the PWHT heating rate under free-shrinkage compared to restrained shrinkage. Welding experiments were conducted (using plates with a thickness of 25 mm) for both shrinkage conditions for a variety of heating rates and maximum temperatures. In-situ acoustic emission analysis was used to locate propagating SRCs during PWHT. Hardness measurements, mechanical property characterization (Charpy impact strength), and microstructure correlation were used to evaluate the SRC susceptibility. The results suggested that the influence of heating rate could not be directly related to SRC formation and that the initial weld microstructure prior to PWHT was more relevant in terms of very high hardness in the coarse grain heat affected zone, especially that of the last beads in the top layer of the welding sequence. This was seen in the form of random, unexpected SRC occurrence in only one specimen at a heating rate commonly used in welding practice (approximately 100 K/h). In this context, the additional effect of an external shrinkage restraint on SRC must be considered in the form of increasing mechanical loads during welding, which are typically not within the scope of welding practice. To mitigate the probability of SRC during PWHT, it is imperative to reduce the welding heat input and to restrict the structural shrinkage restraint of the weld joint.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 10","pages":"3097 - 3113"},"PeriodicalIF":2.5,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-025-02062-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145062258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-06
{"title":"","authors":"","doi":"","DOIUrl":"","url":null,"abstract":"","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 10","pages":"3223 - 3241"},"PeriodicalIF":2.5,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145062260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the welding strategy and welding technology for medium-thick plates based on three-line structured light vision 基于三线结构光视觉的中厚板焊接策略及焊接工艺研究
IF 2.5 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2025-05-06 DOI: 10.1007/s40194-025-02052-z
Junjie He, Liyang Cui, Tianqi Wang, Lei Wang

Weld reconstruction technology based on visual sensors is a crucial component of intelligent robotic welding systems. In thick-wall workpieces with big groove multi-layer automatic welding, precise measurement of the workpiece and weld seams directly affects subsequent weld path planning and posture planning of the welding torch. To address this issue, this study employs a three-line structured light measurement system for weld profile detection. A sub-plane fitting algorithm is proposed for 3D reconstruction of weld grooves, accompanied by a rapid workpiece coordinate system establishment method using three-line structured light to ensure accurate boundary segmentation. However, direct welding based on reconstructed feature points cannot guarantee high-quality results. Therefore, we investigated the effects of key process parameters, such as welding position, direction of welding, and torch inclination angle on weld bead geometry. A second-order general rotational composite design was implemented to develop regression models correlating welding parameters with weld bead characteristics. Finally, integrated process planning combining reconstruction data with optimized welding parameters was implemented for torch trajectory and orientation planning. Experimental results demonstrate that this methodology effectively satisfies quality control requirements for automated welding of thick-walled structural components.

基于视觉传感器的焊缝重构技术是智能机器人焊接系统的重要组成部分。在厚壁大坡口多层自动焊接中,工件和焊缝的精确测量直接影响到后续焊接路径规划和焊枪姿态规划。为了解决这一问题,本研究采用三线结构光测量系统进行焊缝轮廓检测。提出了一种用于焊缝坡口三维重建的子平面拟合算法,并结合三线结构光快速建立工件坐标系的方法,保证了边界的精确分割。然而,基于重构特征点的直接焊接无法保证高质量的焊接结果。因此,我们研究了焊接位置、焊接方向和焊枪倾角等关键工艺参数对焊缝几何形状的影响。采用二阶一般旋转复合材料设计,建立了焊接参数与焊缝特性之间的回归模型。最后,将重建数据与优化后的焊接参数相结合,对焊枪轨迹和方向进行综合工艺规划。实验结果表明,该方法能有效地满足厚壁结构件自动化焊接的质量控制要求。
{"title":"Research on the welding strategy and welding technology for medium-thick plates based on three-line structured light vision","authors":"Junjie He,&nbsp;Liyang Cui,&nbsp;Tianqi Wang,&nbsp;Lei Wang","doi":"10.1007/s40194-025-02052-z","DOIUrl":"10.1007/s40194-025-02052-z","url":null,"abstract":"<div><p>Weld reconstruction technology based on visual sensors is a crucial component of intelligent robotic welding systems. In thick-wall workpieces with big groove multi-layer automatic welding, precise measurement of the workpiece and weld seams directly affects subsequent weld path planning and posture planning of the welding torch. To address this issue, this study employs a three-line structured light measurement system for weld profile detection. A sub-plane fitting algorithm is proposed for 3D reconstruction of weld grooves, accompanied by a rapid workpiece coordinate system establishment method using three-line structured light to ensure accurate boundary segmentation. However, direct welding based on reconstructed feature points cannot guarantee high-quality results. Therefore, we investigated the effects of key process parameters, such as welding position, direction of welding, and torch inclination angle on weld bead geometry. A second-order general rotational composite design was implemented to develop regression models correlating welding parameters with weld bead characteristics. Finally, integrated process planning combining reconstruction data with optimized welding parameters was implemented for torch trajectory and orientation planning. Experimental results demonstrate that this methodology effectively satisfies quality control requirements for automated welding of thick-walled structural components.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"69 10","pages":"3223 - 3241"},"PeriodicalIF":2.5,"publicationDate":"2025-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Welding in the World
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1