首页 > 最新文献

Welding in the World最新文献

英文 中文
Investigation on residual stress, microstructure, and properties of the electron beam welded Haynes 230-based thin-walled piece 电子束焊接海恩斯 230 型薄壁件的残余应力、微观结构和性能研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-07 DOI: 10.1007/s40194-024-01832-3
Jian Xu, Yang Guo, Hailong Cheng, Guijun Mao, Shaolin Zhao, Xin Wu

Haynes 230 material is an important high-temperature alloy used in many significant applications. Electron beam welding (EBW) process is necessary for Haynes 230 to realize some complex structures. In this study, by combining three-dimensional finite element simulation with different experimental methods, the thermal behavior, residual stress, microstructure, and mechanical properties of Haynes 230 thin-walled weldment made by EBW were comprehensively investigated. The EBW process would induce an uneven temperature distribution in the weldment, which then results in a large amount of tensile residual stress. Sufficient amount of precipitates was generated to provide enough enhancement for the strength. The quality of the weldment was good to provide comparable strength to the base metal. This study could offer important information for the application of EBW welded Haynes 230 material, especially in the thin-walled workpieces that are used in hot-end components of combustion gas turbines.

Haynes 230 材料是一种重要的高温合金,被广泛应用于许多重要领域。电子束焊接(EBW)工艺是实现某些复杂结构所必需的。本研究结合三维有限元模拟和不同的实验方法,全面研究了 EBW 工艺制成的 Haynes 230 薄壁焊件的热行为、残余应力、微观结构和力学性能。EBW 工艺会导致焊件温度分布不均,进而产生大量拉伸残余应力。产生的足够数量的析出物足以提高强度。焊接件的质量良好,可提供与母材相当的强度。这项研究为 EBW 焊接 Haynes 230 材料的应用提供了重要信息,尤其是在燃烧式燃气轮机热端部件中使用的薄壁工件方面。
{"title":"Investigation on residual stress, microstructure, and properties of the electron beam welded Haynes 230-based thin-walled piece","authors":"Jian Xu,&nbsp;Yang Guo,&nbsp;Hailong Cheng,&nbsp;Guijun Mao,&nbsp;Shaolin Zhao,&nbsp;Xin Wu","doi":"10.1007/s40194-024-01832-3","DOIUrl":"10.1007/s40194-024-01832-3","url":null,"abstract":"<div><p>Haynes 230 material is an important high-temperature alloy used in many significant applications. Electron beam welding (EBW) process is necessary for Haynes 230 to realize some complex structures. In this study, by combining three-dimensional finite element simulation with different experimental methods, the thermal behavior, residual stress, microstructure, and mechanical properties of Haynes 230 thin-walled weldment made by EBW were comprehensively investigated. The EBW process would induce an uneven temperature distribution in the weldment, which then results in a large amount of tensile residual stress. Sufficient amount of precipitates was generated to provide enough enhancement for the strength. The quality of the weldment was good to provide comparable strength to the base metal. This study could offer important information for the application of EBW welded Haynes 230 material, especially in the thin-walled workpieces that are used in hot-end components of combustion gas turbines.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3129 - 3140"},"PeriodicalIF":2.4,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190705","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural analysis of aluminium-titanium-stainless steel three-layer composites produced by explosive welding 爆炸焊接生产的铝钛不锈钢三层复合材料的结构分析
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-05 DOI: 10.1007/s40194-024-01830-5
I. Galvão, G. H. S. F. L. Carvalho, J. Pimenta, T. Abreu, C. Leitão, R. M. Leal, R. Mendes

The present work aimed to study the morphological, microstructural, and mechanical properties of Al sheet-Ti sheet-SS sheet composites produced by explosion welding. Trimetallic composites with sound structure and very good mechanical behaviour were obtained. The mechanical performance of the produced composites makes them very appropriate for applications requiring increased lightness, corrosion resistance, and mechanical properties at high and low temperature. Regarding the weldability of the material trio, the type of the explosive mixture was found to have a strong influence on the results. Better conditions were achieved by using a mixture with a lower detonation velocity, as high detonation velocities are not appropriate for welding low melting temperature flyers, like aluminium alloys. Although IMC-rich zones were formed at the Al-Ti and Ti-SS interfaces of the composites, these regions were encompassed/accommodated by ductile interfacial waves, which allowed to overcome the brittleness of the IMC regions and to achieve composites with an improved performance. An encompassing literature-based study also allowed to infer that, regardless of the material couples being joined by EXW, the matrix of the intermediate regions formed at the weld interface is always richer in the main element of the welded couple with lower melting temperature.

本工作旨在研究通过爆炸焊接生产的铝片-钛片-SS 片复合材料的形态、微观结构和机械性能。结果表明,三金属复合材料具有良好的结构和机械性能。所生产的复合材料的机械性能使其非常适合于要求提高轻质、耐腐蚀性和高低温机械性能的应用。关于三组材料的可焊性,发现爆炸混合物的类型对结果有很大影响。使用爆速较低的混合物可获得较好的焊接条件,因为高爆速不适合焊接铝合金等低熔点飞散物。虽然在复合材料的 Al-Ti 和 Ti-SS 界面形成了富含 IMC 的区域,但这些区域被韧性界面波所覆盖/容纳,从而克服了 IMC 区域的脆性,使复合材料的性能得到改善。基于文献的全面研究还推断出,无论采用 EXW 焊接的是哪种材料组合,在焊接界面形成的中间区域基体总是富含熔化温度较低的焊接组合的主要元素。
{"title":"Structural analysis of aluminium-titanium-stainless steel three-layer composites produced by explosive welding","authors":"I. Galvão,&nbsp;G. H. S. F. L. Carvalho,&nbsp;J. Pimenta,&nbsp;T. Abreu,&nbsp;C. Leitão,&nbsp;R. M. Leal,&nbsp;R. Mendes","doi":"10.1007/s40194-024-01830-5","DOIUrl":"10.1007/s40194-024-01830-5","url":null,"abstract":"<div><p>The present work aimed to study the morphological, microstructural, and mechanical properties of Al sheet-Ti sheet-SS sheet composites produced by explosion welding. Trimetallic composites with sound structure and very good mechanical behaviour were obtained. The mechanical performance of the produced composites makes them very appropriate for applications requiring increased lightness, corrosion resistance, and mechanical properties at high and low temperature. Regarding the weldability of the material trio, the type of the explosive mixture was found to have a strong influence on the results. Better conditions were achieved by using a mixture with a lower detonation velocity, as high detonation velocities are not appropriate for welding low melting temperature flyers, like aluminium alloys. Although IMC-rich zones were formed at the Al-Ti and Ti-SS interfaces of the composites, these regions were encompassed/accommodated by ductile interfacial waves, which allowed to overcome the brittleness of the IMC regions and to achieve composites with an improved performance. An encompassing literature-based study also allowed to infer that, regardless of the material couples being joined by EXW, the matrix of the intermediate regions formed at the weld interface is always richer in the main element of the welded couple with lower melting temperature.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 11","pages":"2911 - 2925"},"PeriodicalIF":2.4,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190785","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Required fatigue strength (RFS) – a simple concept for determining an equivalent stress range indicating the necessary minimum joint quality in contrast to the actual modified equivalent strength (MES) method 所需疲劳强度 (RFS) - 一个简单的概念,用于确定等效应力范围,表明必要的最低接头质量,与实际的修正等效强度 (MES) 方法形成对比
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-28 DOI: 10.1007/s40194-024-01820-7
J. Baumgartner, M. Breitenberger, C. M. Sonsino

 This paper treats different fatigue (FAT)-scenarios for determining damage-equivalent stress ranges according to two methods for transforming a stress or load spectrum into a damage-equivalent constant amplitude loading, i.e., the Modified Equivalent Stress (MES) and the Required Fatigue Strength (RFS) concepts. The MES method is suggested by the IIW-recommendations for fatigue design and the RFS method is applied especially in the design of vehicle safety components. The resulting MES- and RFS-ranges are similar, but not equal. The MES-method delivers a damage-equivalent stress range that depends on the selected FAT-value, i.e., the position of the Woehler-curve is decisive. In contrast, the RFS-method results in a damage-equivalent fictitious Woehler-line that indicates the lowest necessary strength quality for a given stress spectrum. The allocation of the modified equivalent stress range to the appertaining bi-linear Woehler-curve does not result in the fatigue life caused by the spectrum. Only in the case of a linear Woehler-curve, the fatigue life is directly obtained. In the case of the RFS-application, the fatigue life is by definition equal to the spectrum length. For durability tests, the modified equivalent stress range (at ({L}_{S}) cycles) and the associated FAT-Woehler-curve should not be used. However, the Woehler-curve derived by the RFS-method allows experimental durability proofs for any amplitude-cycle combination along it. Furthermore, the required lowest necessary strength also enables the selection of the most cost-effective manufacturing technique and quality. The RFS-Woehler-curve also results in a FAT-value with a defined probability of failure depending on the required safety factor.

本文根据将应力或载荷谱转化为损害当量恒定振幅载荷的两种方法,即修正当量应力(MES)和所需疲劳强度(RFS)概念,讨论了用于确定损害当量应力范围的不同疲劳(FAT)情景。MES 方法是 IIW 建议的疲劳设计方法,而 RFS 方法则特别适用于车辆安全部件的设计。由此得出的 MES 和 RFS 范围相似,但并不等同。MES 方法提供的损伤当量应力范围取决于所选的 FAT 值,即 Woehler 曲线的位置起决定性作用。相比之下,RFS 方法得出的损害当量虚构 Woehler 线表示给定应力谱的最低必要强度质量。将修改后的等效应力范围分配到相应的双线性 Woehler 曲线上并不会导致应力谱引起的疲劳寿命。只有在线性 Woehler 曲线的情况下,才能直接获得疲劳寿命。在 RFS 应用中,疲劳寿命根据定义等于频谱长度。对于耐久性试验,不应使用修正的等效应力范围(在 ({L}_{S}) 周期)和相关的 FAT-Woehler 曲线。然而,通过 RFS 方法得出的 Woehler 曲线可以对其沿线的任何振幅-周期组合进行耐久性实验证明。此外,所需的最低必要强度还有助于选择最具成本效益的制造技术和质量。根据所需的安全系数,RFS-Woehler-曲线还可得出具有确定失效概率的 FAT 值。
{"title":"Required fatigue strength (RFS) – a simple concept for determining an equivalent stress range indicating the necessary minimum joint quality in contrast to the actual modified equivalent strength (MES) method","authors":"J. Baumgartner,&nbsp;M. Breitenberger,&nbsp;C. M. Sonsino","doi":"10.1007/s40194-024-01820-7","DOIUrl":"10.1007/s40194-024-01820-7","url":null,"abstract":"<div><p> This paper treats different fatigue (FAT)-scenarios for determining damage-equivalent stress ranges according to two methods for transforming a stress or load spectrum into a damage-equivalent constant amplitude loading, i.e., the Modified Equivalent Stress (MES) and the Required Fatigue Strength (RFS) concepts. The MES method is suggested by the IIW-recommendations for fatigue design and the RFS method is applied especially in the design of vehicle safety components. The resulting MES- and RFS-ranges are similar, but not equal. The MES-method delivers a damage-equivalent stress range that depends on the selected FAT-value, i.e., the position of the Woehler-curve is decisive. In contrast, the RFS-method results in a damage-equivalent fictitious Woehler-line that indicates the lowest necessary strength quality for a given stress spectrum. The allocation of the modified equivalent stress range to the appertaining bi-linear Woehler-curve does not result in the fatigue life caused by the spectrum. Only in the case of a linear Woehler-curve, the fatigue life is directly obtained. In the case of the RFS-application, the fatigue life is by definition equal to the spectrum length. For durability tests, the modified equivalent stress range (at <span>({L}_{S})</span> cycles) and the associated FAT-Woehler-curve should not be used. However, the Woehler-curve derived by the RFS-method allows experimental durability proofs for any amplitude-cycle combination along it. Furthermore, the required lowest necessary strength also enables the selection of the most cost-effective manufacturing technique and quality. The RFS-Woehler-curve also results in a FAT-value with a defined probability of failure depending on the required safety factor.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3177 - 3194"},"PeriodicalIF":2.4,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01820-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190702","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and mechanical properties of C/C composites/Ni superalloy dissimilar brazed joint for high-temperature applications 用于高温应用的碳/碳复合材料/镍超合金异种钎焊接头的微观结构和机械性能
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-27 DOI: 10.1007/s40194-024-01826-1
Yuanxun Shen, Yunyue Li, Lanbing Sheng, Yiming Liang, Chuanyong Hao, Chun She

In this paper, the brazing of high-reliability C/C composite-metal joints for high-temperature application was studied. The surface of C/C composites was modified by the Cr metallization process and then brazed to Ni-based superalloy by AgPd braze. Alumina block was used as interlayer, and a zig-zag interfacial structure was constructed at the composites/braze interface. The results show that, after the metallization process, a strong adhesion reaction layer consisting of Cr carbides was coated on the C/C surface which in turn obviously improved the wettability of braze. The molted braze filled completely into the laser-machined holes in the C/C substrate and well-bonded interfaces and a homogeneous Ag(Pd) solution microstructure were obtained in the joint. The strength of the joint with C/C metalized at 1100 ℃ is higher than that of the joint with 1300 ℃. The joints exhibit very high bending strength of up to 82 MPa and shear strength of up to 54 MPa, respectively. The braze spikes increase the connection area and provide a strong pinning effect.

本文研究了用于高温应用的高可靠性 C/C 复合金属接头的钎焊。通过铬金属化工艺对 C/C 复合材料的表面进行改性,然后通过 AgPd 钎焊将其钎焊到镍基超合金上。采用氧化铝块作为中间层,在复合材料/钎焊界面上构建了 "之 "字形界面结构。结果表明,经过金属化处理后,C/C 表面镀上了一层由碳化铬组成的强粘附反应层,从而明显改善了钎料的润湿性。熔融钎料完全填充到 C/C 基材上的激光加工孔中,在接合处获得了良好的结合界面和均匀的 Ag(Pd) 溶液微观结构。温度为 1100 ℃ 的 C/C 金属化接头的强度高于温度为 1300 ℃ 的接头。接头的抗弯强度和抗剪强度分别高达 82 兆帕和 54 兆帕。钎钉增加了连接面积,并提供了强大的销钉效应。
{"title":"Microstructure and mechanical properties of C/C composites/Ni superalloy dissimilar brazed joint for high-temperature applications","authors":"Yuanxun Shen,&nbsp;Yunyue Li,&nbsp;Lanbing Sheng,&nbsp;Yiming Liang,&nbsp;Chuanyong Hao,&nbsp;Chun She","doi":"10.1007/s40194-024-01826-1","DOIUrl":"10.1007/s40194-024-01826-1","url":null,"abstract":"<div><p>In this paper, the brazing of high-reliability C/C composite-metal joints for high-temperature application was studied. The surface of C/C composites was modified by the Cr metallization process and then brazed to Ni-based superalloy by AgPd braze. Alumina block was used as interlayer, and a zig-zag interfacial structure was constructed at the composites/braze interface. The results show that, after the metallization process, a strong adhesion reaction layer consisting of Cr carbides was coated on the C/C surface which in turn obviously improved the wettability of braze. The molted braze filled completely into the laser-machined holes in the C/C substrate and well-bonded interfaces and a homogeneous Ag(Pd) solution microstructure were obtained in the joint. The strength of the joint with C/C metalized at 1100 ℃ is higher than that of the joint with 1300 ℃. The joints exhibit very high bending strength of up to 82 MPa and shear strength of up to 54 MPa, respectively. The braze spikes increase the connection area and provide a strong pinning effect.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3071 - 3078"},"PeriodicalIF":2.4,"publicationDate":"2024-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of holding time on interfacial evolution and mechanical strength of wide-gap brazed K417G superalloy joints 保温时间对宽间隙钎焊 K417G 超合金接头界面演变和机械强度的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-26 DOI: 10.1007/s40194-024-01828-z
Xinyu Ren, Hao Wang, Wenwen Li, Qi Dong, Bo Chen, Wei Mao

K417G superalloy is widely applied in gas turbine components such as blades, vanes, and nozzles. In this study, wide-gap brazing of K417G superalloy is investigated using BNi-5 filler alloy. The brazing experiment is conducted at 1150 °C for different holding times with the fixed gap of 0.2 mm. For the joints brazed for 15 min, the brazing seam mainly consists of γ/γ’ phase, Ni2Si and TiC phase. The average tensile strength tested at 950 °C is 401 MPa. As the holding time increased, the excessive element diffusion phenomenon is observed. Hence, Ni2Si intermetallic phases gradually become embedded in the additive alloy particles. The interfacial evolution and fracture behavior are discussed.

K417G 超合金广泛应用于燃气轮机部件,如叶片、叶片和喷嘴。本研究使用 BNi-5 填充合金研究了 K417G 超耐热合金的宽间隙钎焊。钎焊实验在 1150 °C、固定间隙为 0.2 mm 的不同保温时间下进行。对于钎焊 15 分钟的接头,钎缝主要由 γ/γ'相、Ni2Si 和 TiC 相组成。在 950 °C 下测试的平均拉伸强度为 401 MPa。随着保温时间的延长,观察到元素过度扩散现象。因此,Ni2Si 金属间相逐渐嵌入添加剂合金颗粒中。本文讨论了界面演变和断裂行为。
{"title":"Effect of holding time on interfacial evolution and mechanical strength of wide-gap brazed K417G superalloy joints","authors":"Xinyu Ren,&nbsp;Hao Wang,&nbsp;Wenwen Li,&nbsp;Qi Dong,&nbsp;Bo Chen,&nbsp;Wei Mao","doi":"10.1007/s40194-024-01828-z","DOIUrl":"10.1007/s40194-024-01828-z","url":null,"abstract":"<div><p>K417G superalloy is widely applied in gas turbine components such as blades, vanes, and nozzles. In this study, wide-gap brazing of K417G superalloy is investigated using BNi-5 filler alloy. The brazing experiment is conducted at 1150 °C for different holding times with the fixed gap of 0.2 mm. For the joints brazed for 15 min, the brazing seam mainly consists of γ/γ’ phase, Ni<sub>2</sub>Si and TiC phase. The average tensile strength tested at 950 °C is 401 MPa. As the holding time increased, the excessive element diffusion phenomenon is observed. Hence, Ni<sub>2</sub>Si intermetallic phases gradually become embedded in the additive alloy particles. The interfacial evolution and fracture behavior are discussed.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3079 - 3084"},"PeriodicalIF":2.4,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical and electrochemical behaviour of electron beam welded commercially pure aluminium using oscillating beam 使用摆动电子束焊接商用纯铝的机械和电化学特性
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-20 DOI: 10.1007/s40194-024-01823-4
Aakash Rathore, Jeetendra Kumar Singh, Gour Gopal Roy, Indranil Manna, Jyotsna Dutta Majumdar

The present study evaluates the effect of beam oscillation on the mechanical and electrochemical properties of electron beam welded commercially pure aluminium. The circular beam oscillation diameters of 1 mm and 2 mm have been used while keeping all the other welding parameters constant. The churning effect of beam oscillation led to the formation of a broader fusion zone compared to static beam joint. The fusion zone of a static beam weld consists of equiaxed and columnar structures, while the fusion zone of an oscillated beam weld mainly consists of equiaxed structures. The joints produced using beam oscillation have less porosity (0.01%) than static beam joint (0.02%). Also, the pores were more evenly distributed in the oscillated beam joints. The application of circular beam oscillation of diameters 1 mm and 2 mm increased the microhardness (56 VHN and 58 VHN) as compared to the static beam joint (52 VHN) and base metal (45 VHN). The tensile strength of aluminium (102 MPa) decreased slightly after electron beam welding (99 to 91 MPa). Beam oscillation reduced the tensile strength further (91 MPa and 93 MPa) as compared to the static beam joint (99 MPa), whereas the percentage elongation increased (9 to 17%) due to beam oscillation. Beam oscillation has reduced the corrosion rate from 0.02 mm/year (base metal) to 0.001 mm/year (oscillated beam weld). The mechanism of variation in mechanical and electrochemical properties of electron beam welded aluminium with the application of beam oscillation has been established.

本研究评估了电子束振荡对电子束焊接商业纯铝的机械和电化学性能的影响。在保持所有其他焊接参数不变的情况下,使用了直径分别为 1 毫米和 2 毫米的圆形光束振荡。与静态电子束焊接相比,电子束振荡的搅动效应导致形成了更宽的熔合区。静态横梁焊缝的熔合区由等轴和柱状结构组成,而摆动横梁焊缝的熔合区主要由等轴结构组成。与静态横梁焊缝(0.02%)相比,横梁摆动焊缝的气孔率(0.01%)更低。此外,气孔在振荡型钢焊缝中分布更均匀。与静态横梁连接(52 VHN)和基体金属(45 VHN)相比,直径为 1 毫米和 2 毫米的圆形横梁振荡提高了显微硬度(56 VHN 和 58 VHN)。电子束焊接后,铝的抗拉强度(102 兆帕)略有下降(从 99 兆帕降至 91 兆帕)。与静态横梁连接(99 兆帕)相比,横梁摆动进一步降低了抗拉强度(91 兆帕和 93 兆帕),但由于横梁摆动,伸长百分比增加了(9% 至 17%)。横梁摆动使腐蚀速率从 0.02 毫米/年(母材)降低到 0.001 毫米/年(横梁摆动焊缝)。电子束振荡应用于电子束焊接铝的机械和电化学特性的变化机理已经确定。
{"title":"Mechanical and electrochemical behaviour of electron beam welded commercially pure aluminium using oscillating beam","authors":"Aakash Rathore,&nbsp;Jeetendra Kumar Singh,&nbsp;Gour Gopal Roy,&nbsp;Indranil Manna,&nbsp;Jyotsna Dutta Majumdar","doi":"10.1007/s40194-024-01823-4","DOIUrl":"10.1007/s40194-024-01823-4","url":null,"abstract":"<div><p>The present study evaluates the effect of beam oscillation on the mechanical and electrochemical properties of electron beam welded commercially pure aluminium. The circular beam oscillation diameters of 1 mm and 2 mm have been used while keeping all the other welding parameters constant. The churning effect of beam oscillation led to the formation of a broader fusion zone compared to static beam joint. The fusion zone of a static beam weld consists of equiaxed and columnar structures, while the fusion zone of an oscillated beam weld mainly consists of equiaxed structures. The joints produced using beam oscillation have less porosity (0.01%) than static beam joint (0.02%). Also, the pores were more evenly distributed in the oscillated beam joints. The application of circular beam oscillation of diameters 1 mm and 2 mm increased the microhardness (56 VHN and 58 VHN) as compared to the static beam joint (52 VHN) and base metal (45 VHN). The tensile strength of aluminium (102 MPa) decreased slightly after electron beam welding (99 to 91 MPa). Beam oscillation reduced the tensile strength further (91 MPa and 93 MPa) as compared to the static beam joint (99 MPa), whereas the percentage elongation increased (9 to 17%) due to beam oscillation. Beam oscillation has reduced the corrosion rate from 0.02 mm/year (base metal) to 0.001 mm/year (oscillated beam weld). The mechanism of variation in mechanical and electrochemical properties of electron beam welded aluminium with the application of beam oscillation has been established.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 10","pages":"2779 - 2792"},"PeriodicalIF":2.4,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of microalloying on precipitation behavior and notch impact toughness of welded high-strength structural steels 微合金化对焊接高强度结构钢析出行为和缺口冲击韧性的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-20 DOI: 10.1007/s40194-024-01827-0
Nina Schroeder, Michael Rhode, Thomas Kannengiesser

Microalloying elements such as Nb and Ti are essential to increase the strength of quenched and tempered high-strength low alloy (HSLA) structural steels with nominal yield strength ≥ 690 MPa and their welded joints. Standards such as EN 10025–6 only specify limits or ranges for chemical composition, which leads to variations in specific compositions between steel manufacturers. These standards do not address the mechanical properties of the material, and even small variations in alloy content can significantly affect these properties. This makes it difficult to predict the weldability and integrity of welded joints, with potential problems such as softening or excessive hardening of the heat-affected zone (HAZ). To understand these metallurgical effects, previous studies have investigated different microalloying routes with varying Ti and Nb contents using test alloys. The high-strength quenched and tempered fine-grained structural steel S690QL is the basic grade regarding chemical composition and heat treatment. To evaluate weldability, three-layer welds were made using high-performance MAG welding. HAZ formation was investigated, and critical microstructural areas were identified, focusing on phase transformations during cooling and metallurgical precipitation behavior. Isothermal thermodynamic calculations for different precipitations were also carried out. Mechanical properties, especially Charpy notch impact toughness, were evaluated to understand the influence of different microalloys on the microstructure of the HAZ and mechanical properties.

Nb 和 Ti 等微合金元素对于提高名义屈服强度≥ 690 兆帕的淬火和回火高强度低合金 (HSLA) 结构钢及其焊接接头的强度至关重要。EN 10025-6 等标准只规定了化学成分的限制或范围,这导致不同钢材制造商的具体成分存在差异。这些标准并不涉及材料的机械性能,即使是合金含量的微小变化也会对这些性能产生重大影响。这就很难预测焊接接头的可焊性和完整性,可能会出现热影响区(HAZ)软化或过度硬化等问题。为了了解这些冶金效应,以前的研究使用测试合金调查了不同钛和铌含量的微合金化途径。高强度淬火和回火细晶粒结构钢 S690QL 是化学成分和热处理方面的基本钢种。为了评估可焊性,使用高性能 MAG 焊接进行了三层焊接。对热影响区的形成进行了研究,并确定了关键的微观结构区域,重点关注冷却过程中的相变和冶金析出行为。此外,还对不同析出物进行了等温热力学计算。对机械性能,尤其是夏比缺口冲击韧性进行了评估,以了解不同微合金对热影响区微观结构和机械性能的影响。
{"title":"Influence of microalloying on precipitation behavior and notch impact toughness of welded high-strength structural steels","authors":"Nina Schroeder,&nbsp;Michael Rhode,&nbsp;Thomas Kannengiesser","doi":"10.1007/s40194-024-01827-0","DOIUrl":"10.1007/s40194-024-01827-0","url":null,"abstract":"<div><p>Microalloying elements such as Nb and Ti are essential to increase the strength of quenched and tempered high-strength low alloy (HSLA) structural steels with nominal yield strength ≥ 690 MPa and their welded joints. Standards such as EN 10025–6 only specify limits or ranges for chemical composition, which leads to variations in specific compositions between steel manufacturers. These standards do not address the mechanical properties of the material, and even small variations in alloy content can significantly affect these properties. This makes it difficult to predict the weldability and integrity of welded joints, with potential problems such as softening or excessive hardening of the heat-affected zone (HAZ). To understand these metallurgical effects, previous studies have investigated different microalloying routes with varying Ti and Nb contents using test alloys. The high-strength quenched and tempered fine-grained structural steel S690QL is the basic grade regarding chemical composition and heat treatment. To evaluate weldability, three-layer welds were made using high-performance MAG welding. HAZ formation was investigated, and critical microstructural areas were identified, focusing on phase transformations during cooling and metallurgical precipitation behavior. Isothermal thermodynamic calculations for different precipitations were also carried out. Mechanical properties, especially Charpy notch impact toughness, were evaluated to understand the influence of different microalloys on the microstructure of the HAZ and mechanical properties.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 10","pages":"2647 - 2659"},"PeriodicalIF":2.4,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01827-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The variation law and mechanism of titanium alloy MIG welding process under the synergistic effect of coaxial dual channel gas path 同轴双通道气路协同作用下钛合金 MIG 焊接工艺的变化规律与机理
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-17 DOI: 10.1007/s40194-024-01825-2
Chuanchuan Jia, Guorui Sun, Boqiao Ren, Jiuqing Liu, Chao Chen

MIG welding still had a lot of potential in the titanium alloy industry with many advantages. How to achieve stable process and forming was still a hard nut to crack for titanium alloy MIG welding. The conventional MIG welding torch had a small coverage of shielding gas which causes an obvious insufficient capability of isolating air. Therefore, this study introduced the fluid field composite MIG process, proposed a novel strategy of titanium alloy MIG welding process under the synergistic effect of coaxial dual channel gas path, and had explored the impact of the synergistic effect of internal gas flow(Q) and external gas flow(q) on the welding process from three aspects: droplet transfer characteristics and weld surface morphology, weld cross-section. The results showed that the form of “one large droplet + several small droplets” was always maintained during transition process. Q mainly impacted on the variation law of the droplet transition; however, the length of transition period was mainly affected by q. In addition, the arc length was reduced meanwhile the geometric parameters of welds’ cross-section had more regular changes after adding q. The surface morphology was the worst when Q acted solely; however, it was straight and uniform after adding q. When q = 40L/min and Q = 15L/min, the coverage and protective effect of shielding gas was excellent, no turbulence was generated, and no pores generated in the cross-section of the weld. It was easier to obtain a more stable forming of titanium alloy MIG welding when Q and q worked together.

MIG 焊接在钛合金工业中仍有很大的潜力,具有很多优势。如何实现稳定的工艺和成形仍然是钛合金 MIG 焊接的难点。传统的 MIG 焊枪保护气体覆盖面小,隔绝空气的能力明显不足。因此,本研究引入了流场复合 MIG 工艺,提出了同轴双通道气路协同作用下钛合金 MIG 焊接工艺的新策略,并从熔滴传递特性和焊缝表面形貌、焊缝截面三个方面探讨了内部气体流量(Q)和外部气体流量(q)协同作用对焊接过程的影响。结果表明,在过渡过程中始终保持着 "一个大液滴+多个小液滴 "的形式。当 q = 40L/min 和 Q = 15L/min 时,保护气体的覆盖和保护效果很好,没有产生湍流,焊缝横截面也没有产生气孔。当 Q 和 q 共同作用时,钛合金 MIG 焊接更容易获得稳定的成形。
{"title":"The variation law and mechanism of titanium alloy MIG welding process under the synergistic effect of coaxial dual channel gas path","authors":"Chuanchuan Jia,&nbsp;Guorui Sun,&nbsp;Boqiao Ren,&nbsp;Jiuqing Liu,&nbsp;Chao Chen","doi":"10.1007/s40194-024-01825-2","DOIUrl":"10.1007/s40194-024-01825-2","url":null,"abstract":"<div><p>MIG welding still had a lot of potential in the titanium alloy industry with many advantages. How to achieve stable process and forming was still a hard nut to crack for titanium alloy MIG welding. The conventional MIG welding torch had a small coverage of shielding gas which causes an obvious insufficient capability of isolating air. Therefore, this study introduced the fluid field composite MIG process, proposed a novel strategy of titanium alloy MIG welding process under the synergistic effect of coaxial dual channel gas path, and had explored the impact of the synergistic effect of internal gas flow(<i>Q</i>) and external gas flow(<i>q</i>) on the welding process from three aspects: droplet transfer characteristics and weld surface morphology, weld cross-section. The results showed that the form of “one large droplet + several small droplets” was always maintained during transition process. <i>Q</i> mainly impacted on the variation law of the droplet transition; however, the length of transition period was mainly affected by <i>q</i>. In addition, the arc length was reduced meanwhile the geometric parameters of welds’ cross-section had more regular changes after adding <i>q</i>. The surface morphology was the worst when <i>Q</i> acted solely; however, it was straight and uniform after adding <i>q</i>. When <i>q</i> = 40L/min and <i>Q</i> = 15L/min, the coverage and protective effect of shielding gas was excellent, no turbulence was generated, and no pores generated in the cross-section of the weld. It was easier to obtain a more stable forming of titanium alloy MIG welding when <i>Q</i> and <i>q</i> worked together.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3051 - 3070"},"PeriodicalIF":2.4,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on welding parameters and interface of aluminum/steel composite pipe using underwater explosive welding 水下爆炸焊接铝钢复合管的焊接参数和界面研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-17 DOI: 10.1007/s40194-024-01822-5
Moujin Lin, Jiangliang Li, Junqi Zhou, Dingjun Xiao, Jiamou Wu, Bing Xue

Welding parameters play a crucial role in determining the quality of welds. In this study, we investigated the motion characteristics of aluminum pipes under underwater explosion loads using theoretical calculations and experimental measurements to obtain welding parameters. We conducted contrasting experiments with varied welding parameters to examine their effect on the aluminum/steel composite pipe interface. Subsequently, we thoroughly analyzed the microstructures and mechanical properties of the joints. The velocity histories predicted by theoretical calculations closely matched our experimental findings, validating the use of these calculations for predicting welding parameters in underwater explosive welding processes. Notably, our observations revealed that at an impact velocity of 510 m/s and a dynamic collision angle of 10.4°, no visible melted layer was detected at the welding interface. However, at lower impact velocities (340 m/s) and smaller dynamic collision angles (6.9°), some interfaces exhibited melted layers, contrary to theoretical predictions of kinetic energy loss. This discrepancy underscores the significant influence of collision angle on the formation of interfacial microstructures, a factor often overlooked in similar studies. Furthermore, the melted layer identified at the welding interface was identified as an intermetallic compound, which resulted in a 10.75% reduction in the bonding strength of the aluminum/steel interface. These findings contribute valuable insights for optimizing the design of underwater explosive welding processes for metal pipes, offering a practical tool for industry applications.

焊接参数对焊接质量起着至关重要的作用。在本研究中,我们利用理论计算和实验测量来获得焊接参数,从而研究了铝管在水下爆炸载荷下的运动特性。我们用不同的焊接参数进行了对比实验,以研究它们对铝/钢复合管界面的影响。随后,我们对接头的微观结构和机械性能进行了深入分析。理论计算所预测的速度历程与我们的实验结果非常吻合,从而验证了这些计算可用于预测水下爆炸焊接工艺中的焊接参数。值得注意的是,我们的观察结果表明,在冲击速度为 510 米/秒、动态碰撞角为 10.4°时,焊接界面上没有检测到可见的熔化层。然而,在较低的冲击速度(340 米/秒)和较小的动态碰撞角(6.9°)下,一些界面出现了熔化层,这与动能损失的理论预测相反。这一差异凸显了碰撞角对界面微结构形成的重要影响,而这一因素在类似研究中经常被忽视。此外,在焊接界面发现的熔化层被确定为金属间化合物,这导致铝/钢界面的结合强度降低了 10.75%。这些发现为优化金属管道水下爆炸焊接工艺的设计提供了宝贵的见解,为工业应用提供了实用的工具。
{"title":"Study on welding parameters and interface of aluminum/steel composite pipe using underwater explosive welding","authors":"Moujin Lin,&nbsp;Jiangliang Li,&nbsp;Junqi Zhou,&nbsp;Dingjun Xiao,&nbsp;Jiamou Wu,&nbsp;Bing Xue","doi":"10.1007/s40194-024-01822-5","DOIUrl":"10.1007/s40194-024-01822-5","url":null,"abstract":"<div><p>Welding parameters play a crucial role in determining the quality of welds. In this study, we investigated the motion characteristics of aluminum pipes under underwater explosion loads using theoretical calculations and experimental measurements to obtain welding parameters. We conducted contrasting experiments with varied welding parameters to examine their effect on the aluminum/steel composite pipe interface. Subsequently, we thoroughly analyzed the microstructures and mechanical properties of the joints. The velocity histories predicted by theoretical calculations closely matched our experimental findings, validating the use of these calculations for predicting welding parameters in underwater explosive welding processes. Notably, our observations revealed that at an impact velocity of 510 m/s and a dynamic collision angle of 10.4°, no visible melted layer was detected at the welding interface. However, at lower impact velocities (340 m/s) and smaller dynamic collision angles (6.9°), some interfaces exhibited melted layers, contrary to theoretical predictions of kinetic energy loss. This discrepancy underscores the significant influence of collision angle on the formation of interfacial microstructures, a factor often overlooked in similar studies. Furthermore, the melted layer identified at the welding interface was identified as an intermetallic compound, which resulted in a 10.75% reduction in the bonding strength of the aluminum/steel interface. These findings contribute valuable insights for optimizing the design of underwater explosive welding processes for metal pipes, offering a practical tool for industry applications.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 11","pages":"3019 - 3032"},"PeriodicalIF":2.4,"publicationDate":"2024-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142190708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of temperature profile and chemical composition of the flux on void formation in solder joints: in-depth analysis 温度曲线和助焊剂化学成分对焊点空洞形成的影响:深入分析
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-08-15 DOI: 10.1007/s40194-024-01824-3
Martin Kozak, Petr Vesely, Dominik Pilnaj, Jonas Uricar, Karel Dusek

Due to electronics miniaturization, the size of voids is becoming comparable to that of solder joints, thereby increasing the risk of reduced reliability. This work presents a novel method of achieving void reduction through preliminary characterization of the flux and, consequently, the proper flux selection and adjustment of the temperature profile during soldering. To validate this approach, five SAC305 solder pastes differing in flux composition were subjected to testing. The flux components were characterized by a gas chromatograph combined with a mass spectrometer (GC–MS) and thermogravimetric analysis (TGA). Subsequently, four temperature profiles differing in the heating rate were employed for reflow soldering of the test boards with components while maintaining the same peak temperature for all profiles. The results of the X-ray computed tomography (XCT) analysis indicated that as the temperature gradient decreased, the number of voids decreased by up to 36%. The decrease in the number of flux residues detected by TGA present at the peak process temperature was also accompanied by a decrease in the void area within the solder joint. Moreover, a comparison between the GC–MS and XCT results revealed that certain flux compounds, such as butylated hydroxytoluene, were found to have a greater impact on void formation than others. The proposed method combining flux characterization by GC–MS and TGA and adjustment of temperature gradient during the soldering process can be an efficient way to reduce voids in solder joints. Additionally, it appears that a lower temperature gradient is generally associated with a lower incidence of voids.

由于电子产品的微型化,空隙的大小正变得与焊点相当,从而增加了可靠性降低的风险。这项研究提出了一种新方法,通过对助焊剂进行初步表征,从而在焊接过程中正确选择助焊剂和调整温度曲线来减少空隙。为了验证这种方法,对五种助焊剂成分不同的 SAC305 焊膏进行了测试。通过气相色谱仪结合质谱仪(GC-MS)和热重分析(TGA)对助焊剂成分进行了表征。随后,在保持所有温度曲线的峰值温度相同的情况下,采用了四种加热速率不同的温度曲线对带有元件的测试电路板进行回流焊接。X 射线计算机断层扫描(XCT)分析结果表明,随着温度梯度的降低,空隙数量最多减少了 36%。TGA 在峰值工艺温度下检测到的助焊剂残留物数量减少的同时,焊点内的空隙面积也在减少。此外,通过比较 GC-MS 和 XCT 的结果发现,某些助焊剂化合物(如丁基羟基甲苯)对空隙形成的影响比其他化合物更大。所建议的方法结合了 GC-MS 和 TGA 对助焊剂的表征以及焊接过程中温度梯度的调整,可以有效减少焊点中的空洞。此外,较低的温度梯度似乎通常与较低的空洞发生率相关。
{"title":"Effect of temperature profile and chemical composition of the flux on void formation in solder joints: in-depth analysis","authors":"Martin Kozak,&nbsp;Petr Vesely,&nbsp;Dominik Pilnaj,&nbsp;Jonas Uricar,&nbsp;Karel Dusek","doi":"10.1007/s40194-024-01824-3","DOIUrl":"10.1007/s40194-024-01824-3","url":null,"abstract":"<div><p>Due to electronics miniaturization, the size of voids is becoming comparable to that of solder joints, thereby increasing the risk of reduced reliability. This work presents a novel method of achieving void reduction through preliminary characterization of the flux and, consequently, the proper flux selection and adjustment of the temperature profile during soldering. To validate this approach, five SAC305 solder pastes differing in flux composition were subjected to testing. The flux components were characterized by a gas chromatograph combined with a mass spectrometer (GC–MS) and thermogravimetric analysis (TGA). Subsequently, four temperature profiles differing in the heating rate were employed for reflow soldering of the test boards with components while maintaining the same peak temperature for all profiles. The results of the X-ray computed tomography (XCT) analysis indicated that as the temperature gradient decreased, the number of voids decreased by up to 36%. The decrease in the number of flux residues detected by TGA present at the peak process temperature was also accompanied by a decrease in the void area within the solder joint. Moreover, a comparison between the GC–MS and XCT results revealed that certain flux compounds, such as butylated hydroxytoluene, were found to have a greater impact on void formation than others. The proposed method combining flux characterization by GC–MS and TGA and adjustment of temperature gradient during the soldering process can be an efficient way to reduce voids in solder joints. Additionally, it appears that a lower temperature gradient is generally associated with a lower incidence of voids.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3195 - 3204"},"PeriodicalIF":2.4,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Welding in the World
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1