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WO3 Modification by Synthesis of Nanocomposites 纳米复合材料对WO3的改性
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.01.031
Nilofar Asim , M.F. Syuhami , Marzieh Badiei , M. Ambar Yarmo

This study presents the preparation of tungsten trioxide (WO3) nanoparticles by acidic precipitation using sodium tungstate as a precursor. Composite synthesis was selected among various modification methods to investigate catalytic activity improvement. WO3:polyaniline (PANI) nanocomposites with different weight ratios were prepared. The synthesized nanocomposites were characterized by field emission scanning electron microscopy, X-ray diffraction, thermogravimetric analysis–differential thermal analysis, and Fourier transform infrared spectroscopy. Results revealed the successful preparation of WO3: PANI nanocomposites. These nanocomposites exhibit higher thermal stability compared with PANI, indicating a satisfactory interaction between WO3 and PANI. The synthesized nanocomposites are being evaluated for their catalytic activity.

以钨酸钠为前驱体,采用酸沉淀法制备了三氧化钨纳米颗粒。在不同的改性方法中选择复合合成法来考察催化活性的改善情况。制备了不同重量比的聚苯胺(PANI)纳米复合材料。采用场发射扫描电镜、x射线衍射、热重分析-差热分析和傅里叶变换红外光谱对合成的纳米复合材料进行了表征。结果表明,成功制备了WO3: PANI纳米复合材料。与聚苯胺相比,这些纳米复合材料表现出更高的热稳定性,表明WO3与聚苯胺之间具有良好的相互作用。对合成的纳米复合材料的催化活性进行了评价。
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引用次数: 17
Utilization of Vetiveria Zizaniodes (L.) Nash Leaves in Ganoderma Lucidum Cultivated 香根草的利用栽培的灵芝纳什叶
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.01.078
R. Sornprasert , S. Aroonsrimorakot

The aim of this reserch were investigate the substitution of sawdust with Vetiveria zizaniodes (L.)Nash, Sri Langka cultivar on the media in mycelia growth of Ganoderma lucidum in plastic bag. The suitable three media from eleven formulas with different weight ratio of sawdust and V. zizaniodes leaves at 100:0, 0:100 and 20:80 are selected in this research and gave the biological efficiency with 42.72, 00.00 and 40.71% respectively. This results show the opportunity for substitution of sawdust with V. zizaniodes leaves which can reduce the production cost of G. lucidum. Nutrition analysis of fruiting body of mushroom are cultivated on different type of the substrates, particularly sawdust 100:0 in plastic bag, found more protein than cultivated in sawdust 20:80 with 10.29 and 8.45 mg/100 g dry weight in G. lucidum respectively. In amount of essential amino acid and non-essential amino acid of G. lucidum cultivated sawdust 100:0 gave more amino acid than 20:80.

研究了香根草对木屑的替代作用。纳什、斯里兰卡栽培品种在培养基上菌丝体在塑料袋中生长灵芝。本研究从11个配方中选择了3种适宜的培养基,分别为锯末与紫荆叶质量比为100:0、0:100和20:80,生物效率分别为42.72、00.00和40.71%。研究结果表明,利用木屑代替木屑,可以降低木屑的生产成本。对不同基质上培养的香菇子实体进行营养分析,其中以100:0袋装木屑为主要材料,其蛋白质含量高于20:80袋装木屑,干重分别为10.29 mg/100 g和8.45 mg/100 g。栽培木屑中必需氨基酸和非必需氨基酸的比例为100:0,氨基酸含量高于20:80。
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引用次数: 3
Use of Multi-diffusion Model to Study the Release of Urea from Urea Fertilizer Coated with Polyurethane-like Coating (PULC) 用多扩散模型研究聚氨酯类涂层(PULC)尿素肥料中尿素的释放☆
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.03.017
Thanh H. Trinh, KuZilati KuShaari, Abdul Basit, Babar Azeem, Anis Shuib

Controlled release fertilizer (CRF) play an important role in nutrient loss prevention and plant's uptake efficiency. This study uses a multi-diffusion model to simulate urea release from urea fertilizers coated with polyurethane-like coating (PULC). In this model, finite element method (FEM) and 2D geometry are applied for three sizes of urea granule using COMSOL Multiphysics software. Modeling results are in agreement with the experimental data for the “constant release” stage. Standard error of estimate (SEE) ranges from 0.00417 to 0.02084 in these simulations. Besides, relationship of coating thickness with release time and percent of urea released at the end of “constant release” stage has also been established.

控释肥在防止养分流失和提高植物吸收效率方面起着重要作用。本研究采用多扩散模型模拟尿素肥料在包覆聚氨酯类涂层(PULC)后的尿素释放。该模型采用COMSOL Multiphysics软件对三种粒径的尿素颗粒进行有限元分析和二维几何分析。模拟结果与“恒释放”阶段的实验数据吻合较好。在这些模拟中,估计的标准误差(SEE)在0.00417 ~ 0.02084之间。此外,还建立了涂层厚度与释放时间和“恒释放”阶段末尿素释放率的关系。
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引用次数: 16
Release and Transport of Toxic, Mobile Organic Compounds (Formaldehyde and Phenols) on an Arctic Glacier 北极冰川上有毒、可移动的有机化合物(甲醛和酚类)的释放和运输
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.10.006
Krystyna Kozioł , Marek Ruman , Katarzyna Kozak , Żaneta Polkowska

As a result of current deglaciation, the chemical cycles of many compounds, including toxic formaldehyde and phenols, are changing. However, the processes by which these chemicals are released have yet to be studied in situ. Here, we quantify fluxes of HCHO and phenols in a glacial catchment within one summer season, obtaining a net release from the glacier of 0.106 · 106 g formaldehyde and 0.255 · 106 g phenols, which can be interpreted as a combined result of summer deposition and glacier ice melt. Formaldehyde flux was shown to increase by 164% on a 250 m stretch of the stream flowing through an icing (an exposed former glacier bed area), whilst phenols have shown a smaller increase of 48%. Hence, the importance of glacial forefields in chemical cycle of toxic compounds is pronounced and requires further attention.

由于目前的冰川消融,包括有毒的甲醛和酚类在内的许多化合物的化学循环正在发生变化。然而,这些化学物质释放的过程尚未在现场进行研究。在这里,我们量化了一个夏季冰川集水区中HCHO和酚的通量,得到了冰川净释放0.106·106 g甲醛和0.255·106 g酚,这可以解释为夏季沉积和冰川冰融化的综合结果。在流经冰层(暴露的前冰川床区)的250米长的河流中,甲醛通量增加了164%,而苯酚的增幅较小,仅为48%。因此,冰川前田在有毒化合物化学循环中的重要性是明显的,需要进一步注意。
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引用次数: 4
Influence of Substituents on Reactivity and Reaction Mechanism of SN Reaction of Some Organophosphorus Compounds; Relied on Linear Free Energy Relationship 取代基对某些有机磷化合物SN反应活性及反应机理的影响依赖于线性自由能关系
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.01.008
Bilkis Jahan Lumbiny , Zhang Hui , M. Azizul Islam

The tetracoordinated organophosphorous compound (4 - Chlorophenyl 4 - methyl phenyl Chlorophosphate, 1) were synthesized, characterized and nucleophilic substitution reaction (pyridinolysis) were investigated in acetonitrile at 5.0oC by varying substituents in nucleophiles. The reactivity is expressed in terms of second-order rate constant, k2 and measured conductometrically. Physical organic chemistry tools mainly Hammett (ρ), Brönsted (β) Linear Free Energy Relationship (LFER) coefficients being determined in quest for the mechanistic information by comparing pyridinolysis of structurally similar organophosphorous compounds reported earlier. Nice linear correlation being found for Hammett (logk2 vs σx) and Brönsted (logk2 vs pKa(x)) plots. In the light of the reported results the LFER obtained for 1 with negative value of the ρX, −5.78 and large positive value for βX, 1.17 can be interpreted as SN2 process, with greater extent of bond formation in TS of 1.

合成了四配位有机磷化合物(4 -氯苯基4 -甲基苯基氯磷酸,1),对其进行了表征,并在5.0℃的乙腈中通过亲核试剂中不同取代基进行了亲核取代反应(吡啶分解)。反应性用二阶速率常数k2表示,并用电导法测量。物理有机化学工具主要是Hammett (ρ), Brönsted (β)线性自由能关系(LFER)系数的测定,通过比较前人报道的结构相似的有机磷化合物吡啶分解的机理信息。在Hammett (logk2 vs σx)和Brönsted (logk2 vs pKa(x))图中发现了很好的线性相关性。从已有的结果来看,1的ρX为负值,−5.78,βX为较大的正值,1.17的LFER可以解释为SN2过程,在1的TS中形成键的程度更大。
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引用次数: 0
Asymmetric Price Transmission in the Livestock Industry of Thailand 泰国畜牧业的不对称价格传导
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.03.016
Jorge Fidel Barahona , Bernardo Trejos , Jai Wei Lee , Wanvilai Chulaphan , Chalermpon Jatuporn

This study aimed to investigate the farm-retail price transmission for the livestock industry in Thailand employing monthly data from 2002 to 2012. Using the Engle-Granger two step approach, the study confirmed that farmgate prices were cointegrated with retail prices in the poultry and swine industry. Consequently, an asymmetric error correction model (AECM) was used to test for asymmetric price transmission between farmgate and retail prices of chicken and pork. Results show that the pork industry, which is focused on supplying domestic consumption and has heavy export restrictions, is characterized by positive asymmetric price transmission whereas the poultry industry, which is highly export-oriented, is characterized by symmetric price transmission. This suggests that the export-oriented nature of the poultry market has linked Thailand's domestic market with the international market. This has led to an increase in market competition, allowing for increases and decreases of farmgate prices to be equally transmitted to retail prices of chicken.

本研究旨在利用2002年至2012年的月度数据调查泰国畜牧业的农场零售价格传导。使用恩格尔-格兰杰两步方法,研究证实了家禽和养猪业的农场价格与零售价格是协整的。因此,采用非对称误差修正模型(AECM)检验鸡肉和猪肉的农场价格与零售价格之间的不对称价格传导。结果表明,以供给国内消费为主、出口限制较多的猪肉产业具有正不对称价格传导特征,而高度出口导向的家禽业具有对称价格传导特征。这表明,家禽市场的出口导向性质将泰国国内市场与国际市场联系起来。这导致了市场竞争的增加,允许农场价格的上涨和下跌平均地传递到鸡肉的零售价格。
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引用次数: 17
Analysis of Polymorphism of Callipyge Gene in Lori Sheep by PCR-RFLP Method PCR-RFLP法分析洛瑞羊Callipyge基因多态性
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.03.002
Shahram Nanekarani, Majid Goodarzi, Morteza Mahdavi

The callipyge locus has been localized in the telomeric region on ovine chromosome 18, within a cluster of imprinted genes. In this study were collected blood samples from 124 Lori sheep. Genomic DNA was extracted from blood sample. Gel monitoring and spectrophotometer methods were used to determination quality and quantity of DNA. FaqI enzyme was used for restricting of PCR products. Digested products were separated by electrophoresis on 2% agarose gel and visualized after staining with ethidium bromide on UV transillumination. The PCR product (426 bp) was digested by restriction endonucleases FaqI. The FaqI digestion of the PCR products produced digestion fragments of 395, 278, 117 and 31 bp. Data analysis was done using PopGen32 software. There was no difference between digestion patterns and all sampled animals displayed AA genotype. As such, three 278, 117 and 31 bp amplified fragments from enzyme digestion were observed for all animals, indicating that the total population of sheep was monomorphic for CLPG gene.

callipyge基因座定位于羊18号染色体的端粒区,在一组印迹基因中。本研究采集了124只洛里羊的血液样本。从血样中提取基因组DNA。采用凝胶监测和分光光度计法测定DNA的质量和数量。采用FaqI酶对PCR产物进行限制性反应。消化产物经2%琼脂糖凝胶电泳分离,溴化乙啶紫外透照染色。PCR产物(426 bp)用限制性内切酶FaqI酶切。PCR产物经FaqI酶切得到395、278、117和31 bp的酶切片段。数据分析采用PopGen32软件。消化模式之间没有差异,所有取样动物均为AA基因型。结果表明,在所有动物中均有278、117和31 bp的酶切扩增片段,表明CLPG基因在绵羊群体中为单态。
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引用次数: 5
Ecological Engineering, Industrial Ecology and Eco-Industrial Networking Aspects of Ship Recycling Sector in India 印度船舶回收行业的生态工程、工业生态和生态工业网络
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.10.035
Anand M. Hiremath, Sachin Kumar Pandey, Dinesh Kumar, Shyam R. Asolekar

India is the world's leading ship recycling country which works on the principle of waste to wealth. In this paper an attempt has been made to articluate the Ecological Engineering, Industrial Ecology and Eco-Industrial Networking aspects which are embedded in beaching method of ship recycling in Alang, India. There is a need to promote such activities for sustainalbe growth, but, it is equally true that, if ship recycling is conducted haphazardly with very little scientific and technical knowledge, it will expose workers to hazardous conduitions as well as would leave disproportionately large environmental footprint behind. In this context, Gujarat Maritime Board (GMB), Government of Gujarat, India has initiated many projects to defend human and environmental health. In India, already impressive positive changes can be seen as the GMB has set training and welfare institute and its efforts resulted in decrease of fatal accidents from 2.0 per 1000 workers to 0.13 per 1000 workers i.e. 93.5% decrease in the fatal accidents from the year 2003 to 2011 in the ship recycling yards. Present status of ship recycling in India is substantial. The overall trend of the industry is towards following more and more Health Safety & Environment (HSE) norms and has commitments with them. Zero accidents and near zero pollution to the surrounding environment should be the ultimate goal of beaching method of recycling in India to handle pile of end-of-life ships in environmentally sound manner - which are expected to reach ship recycling yards in near future.

印度是世界领先的船舶回收国,其工作原则是废物转化为财富。在本文中,本文试图阐明生态工程,工业生态学和生态工业网络方面嵌入在印度Alang船舶回收的搁浅方法中。有必要促进此类活动以实现可持续增长,但是,同样正确的是,如果船舶回收是在缺乏科学和技术知识的情况下随意进行的,它将使工人暴露在危险的条件下,并将留下不成比例的巨大环境足迹。在这方面,印度古吉拉特邦政府古吉拉特邦海事局(GMB)发起了许多项目,以捍卫人类和环境健康。在印度,可以看到令人印象深刻的积极变化,GMB设立了培训和福利机构,其努力使致命事故从每1000名工人2.0减少到每1000名工人0.13,即从2003年到2011年,船舶回收场的致命事故减少了93.5%。印度目前的船舶回收状况相当可观。行业的整体趋势是越来越多地遵循健康安全& &;环境(HSE)规范并对其作出承诺。零事故和对周围环境的接近零污染应该是印度搁浅回收方法的最终目标,以环保的方式处理一堆报废船舶-预计在不久的将来将到达船舶回收场。
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引用次数: 10
Impact of Farm Design on Plant-pollinator Interaction in Brinjal (Solanum Melongena) 农场设计对茄子(Solanum Melongena)植物-传粉者相互作用的影响
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.03.014
Munmun Mukherjee

Pollinators are crucial in agricultural crop production as a large variety of crops including horticultural and vegetable crops depend essentially on insect pollination. Unfortunately over the past decades, the pollinator population in the agricultural system has declined across the globe due to over use of synthetic chemical pesticides. Disruption of ecosystem service provided by pollinators due to pollinator decline in chemical intensive cropping systems has assumed a global dimension. This paper addresses how farming practices and designs affect the diversity of pollinators. In this study the relationship between pollinator density and brinjal (Solanum melongena, Fam. Solanacae) productivity was evaluated in a chemical intensive vegetable cropping system in North 24 Parganas, West Bengal, India (hot sub-humid to humid eco-region; Lat 22°22’ 26, N Lon 88°21’ 26 E). By comparing pollinator density and fruit set between ecological farm and chemical intensive farm, it was investigated whether pesticide application affects pollinator visitation and in such a scenario what was the impact on brinjal production. Visitation rate of pollinators (butterflies and bees) was significantly higher in ecological farm as compared to the conventional farm (Mann Whitney U test, p < 0.001).

传粉媒介在农作物生产中至关重要,因为包括园艺和蔬菜作物在内的各种作物基本上都依赖昆虫授粉。不幸的是,在过去的几十年里,由于过度使用合成化学农药,全球农业系统中的传粉昆虫数量有所下降。在化学集约化种植系统中,传粉者减少导致传粉者提供的生态系统服务中断,这已成为全球性问题。本文讨论了农业实践和设计如何影响传粉媒介的多样性。本文研究了传粉媒介密度与茄子(茄)的关系。在印度西孟加拉邦北部24 Parganas(炎热的半湿润到湿润的生态区)进行了化学集约化蔬菜种植体系中茄属植物(Solanacae)的生产力评价;纬度22°22′26,北纬88°21′26 E)。通过比较生态农场和化学集约型农场的传粉媒介密度和坐果量,研究了农药施用是否影响传粉媒介访视,以及在这种情况下对茄子产量的影响。生态农场的传粉者(蝴蝶和蜜蜂)访花率显著高于传统农场(Mann Whitney U检验,p <0.001)。
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引用次数: 1
An Efficient and Reliable Structural Health Monitoring System for Buildings after Earthquake 一种高效可靠的地震后建筑物结构健康监测系统
Pub Date : 2014-01-01 DOI: 10.1016/j.apcbee.2014.01.055
M. Roghaei, A. Zabihollah

Occupation of buildings of high importance like hospitals and shelters after earthquake is a risky yet vital task for rescue workers. This paper presents a structural health monitoring system to ensure the safety and reliability of the buildings after earth quack. It is understood that ground motion and lateral displacement due to earthquack may cause deformation and thus excessive strain and stress at the main structural elements. Therefore, the building may suddenly goes to failure, requiring a reliable yet efficient health monitoring system. An array of piezoelectric sensors is mounted at desired location to measure the deformation and stress at critical points. The voltage generated by piezoelectric sensors is sent to computer via a data acquisition system. Measuring and monitoring the trend of changing sensors voltages indicate the probability of existing damages and the rate of propagation. The performance-based seismic is reported based on the nonlinear static analysis (pushover) under the influence of the lateral loading and structural behaviour through the Sap2000® software and FEMA356. The proposed model is verified for a three-story steel structure building. The effects of the lateral displacement caused by earthquake forces on strain and sensors voltage are investigated for each main element in each floor. Increasing the strain and displacements at selected elements increases the voltage generated at piezoelectric sensors. Continuous monitoring and analysis of generated signals helps the building manager to apply warning alarm or call for evacuation of the building.

地震后占领医院和避难所等重要建筑对救援人员来说是一项危险但又至关重要的任务。本文提出了一种结构健康监测系统,以保证建筑物在地震后的安全可靠。据了解,由于地震引起的地面运动和横向位移可能导致变形,从而在主要结构元件上产生过大的应变和应力。因此,建筑物可能会突然发生故障,这就需要一个可靠而高效的健康监测系统。在需要的位置安装一组压电传感器来测量关键点的变形和应力。压电传感器产生的电压通过数据采集系统发送给计算机。通过测量和监测传感器电压的变化趋势,可以了解现有损伤的发生概率和损伤的传播速度。通过Sap2000®软件和FEMA356,基于侧向载荷和结构行为影响下的非线性静力分析(推覆),报告了基于性能的地震。并对一个三层钢结构建筑进行了验证。研究了地震力引起的侧向位移对各层主单元应变和传感器电压的影响。增加所选元件的应变和位移会增加压电传感器产生的电压。对所产生的信号进行持续的监测和分析,有助于建筑物管理者应用警告警报或呼叫建筑物疏散。
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引用次数: 13
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APCBEE Procedia
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