Anti-corrosion Methods and Materials最新文献

Purpose

This paper aims to contribute to the performance improvement and the broader application of hot-dip galvanized coating.

Design/methodology/approach

First, the ability to provide barrier protection, galvanic protection, and corrosion product protection provided by hot-dip galvanized coating is introduced. Then, according to the varying Fe content, the growth process of each sublayer within the hot-dip galvanized coating, as well as their respective microstructures and physical properties, is presented. Finally, the electrochemical corrosion behaviors of the different sublayers are analyzed.

Findings

The hot-dip galvanized coating is composed of η-Zn sublayer, ζ-FeZn13 sublayer, δ-FeZn10 sublayer, and Γ-Fe3Zn10 sublayer. Among these sublayers, with the increase in Fe content, the corrosion potential moves in a noble direction.

Research limitations/implications

There is a lack of research on the corrosion behavior of each sublayer of hot-dip galvanized coating in different electrolytes.

Practical implications

It provides theoretical guidance for the microstructure control and performance improvement of hot-dip galvanized coatings.

Originality/value

The formation mechanism, coating properties, and corrosion behavior of different sublayers in hot-dip galvanized coating are expounded, which offers novel insights and directions for future research.

Purpose

This study aims to develop eco-friendly corrosion inhibitors for aluminum in acidic media by evaluating the corrosion inhibition properties of corn leaf extract (CLE) using response surface methodology (RSM) and experiments.

Design/methodology/approach

The RSM was combined with experiments to evaluate the corrosion inhibition properties of CLE on aluminum in acid media.

Findings

The effectiveness of the inhibition increased with increasing inhibitor concentration and time but decreased with increasing temperature. The corrosion inhibition mechanism revealed the corrosion process is spontaneous exothermic physical adsorption. Thermodynamic parameters revealed an activation energy between 32.1 and 24.7 kJ/mol, energy of adsorption between −14.53 and −65.07 and Gibbs free energy of −10.12 kJ/mol which indicated the CLE exothermically spontaneously physisorbed. A model was generated to estimate the effect of the process parameters (inhibitor concentration, reaction time and temperature) using the RSM. Optimization of the process factors was also carried out using the RSM. The percentage inhibition efficiency obtained experimentally (85.61%) was closely comparable to 84.89% obtained by the theoretical technique (RSM). The SEM observations of the inhibited and uninhibited Al samples demonstrated that CLE is an effective corrosion inhibitor for aluminum in acid media.

Originality/value

Results herein provide novel information on the possible application of CLEs as effective eco-friendly corrosion inhibitors.

Purpose

The purpose of this study is to compare the prediction models for half-cell potential (HCP) of RCC slabs cathodically protected using pure magnesium anodes and subjected to chloride ingress.The models for HCP using 1,134 data set values based on experimentation are developed and compared using ANFIS, artificial neural network (ANN) and integrated ANN-GA algorithms.

Design/methodology/approach

In this study, RCC slabs, 1000 mm × 1000 mm × 100 mm were cast. Five slabs were cast with 3.5% NaCl by weight of cement, and five more were cast without NaCl. The distance of the point under consideration from the anode in the x- and y-axes, temperature, relative humidity and age of the slab in days were the input parameters, while the HCP values with reference to the Standard Calomel Electrode were the output. Experimental values consisting of 80 HCP values per slab per day were collected for 270 days and were averaged for both cases to generate the prediction model.

Findings

In this study, the premise and consequent parameters are trained, validated and tested using ANFIS, ANN and by using ANN as fitness function of GA. The MAPE, RMSE and MAE of the ANFIS model were 24.57, 1702.601 and 871.762, respectively. Amongst the ANN algorithms, Levenberg−Marquardt (LM) algorithm outperforms the other methods, with an overall R-value of 0.983. GA with ANN as the objective function proves to be the best means for the development of prediction model.

Originality/value

Based on the original experimental values, the performance of ANFIS, ANN and GA with ANN as objective function provides excellent results.

Purpose

The purpose of this paper was to prepare a ternary hierarchical rough particle to accelerate the anti-corrosive design for coastal concrete infrastructures.

Design/methodology/approach

A kind of micro-nano hydrophobic ternary microparticles was fabricated from SiO₂/halloysite nanotubes (HNTs) and recycled concrete powders (RCPs), which was then mixed with sodium silicate and silane to form an inorganic slurry. The slurry was further sprayed on the concrete surface to construct a superhydrophobic coating (SHC). Transmission electron microscopy and energy-dispersive X-ray spectroscopy mappings demonstrate that the nano-sized SiO₂ has been grafted on the sub-micron HNTs and then further adhered to the surface of micro-sized RCP, forming a kind of superhydrophobic particles (SiO₂/HNTs@RCP) featured of abundant micro-nano hierarchical structures.

Findings

The SHC surface presents excellent superhydrophobicity with the water contact angle >156°. Electrochemical tests indicate that the corrosion rate of mild steel rebar in coated concrete reduces three-order magnitudes relative to the uncoated one in 3.5% NaCl solution. Water uptake and chloride ion (Cl^-) diffusion tests show that the SHC exhibits high H₂O and Cl^- ions barrier properties thanks to the pore-sealing and water-repellence properties of SiO₂/HNTs@RCP particles. Furthermore, the SHC possesses considerable mechanical durability and outstanding self-cleaning ability.

Originality/value

SHC inhibits water uptake, Cl^- diffusion and rebar corrosion of concrete, which will promote the sustainable application of concrete waste in anti-corrosive concrete projects.

Purpose

This study aims to investigate the individual electrochemical transients arising from local anodic events on stainless steel, to uncover the potential mechanisms producing different types of transients and to derive appropriate parameters indicative of the corrosion severity of such transient events.

Design/methodology/approach

An equivalent circuit model was used for the transient analysis, which was performed using a local current allocation rule based on the relative instant cathodic resistance of the coupled electrodes, as well as the kinetic parameters derived from the electrochemical polarization measurement.

Findings

The shape and size of the electrochemical current transients arising from SS 316 L were influenced by the film stability, local anodic dissolution kinetics and the symmetry of the cathodic kinetics between the coupled electrodes, where the ultralong transient might correspond to the propagation of film damage with a slow anodic dissolution rate. The dynamic cathodic resistance during the final stage of transient current growth can serve as a characteristic parameter that reflects the loss of passive film protection.

Originality/value

Estimation of the local anodic current trace opens a new way for individual electrochemical transient analysis associated with the charges involved, local current densities and changes in film resistance throughout localized corrosion processes.

Purpose

This study aims to study the formation mechanism of micro-arc oxidation (MAO) coating on AZ31 magnesium alloy and how the annealing process affects its corrosion resistance.

Design/methodology/approach

This study involved immersion experiments, electrochemical experiments and slow strain rate tensile experiments, along with scanning electron microscopy, optical microscopy observation and X-ray diffraction analysis.

Findings

The findings suggest that annealing treatment can refine the grain size of AZ31 magnesium alloy to an average of 6.9 µm at 300°C. The change in grain size leads to a change in conductivity, which affects the performance of MAO coatings. The MAO coating obtained by annealing the substrate at 300°C has smaller pores and porosity, resulting in better adhesion and wear resistance.

Originality/value

The coating acts as a barrier to prevent corrosive substances from entering the substrate. However, the smaller pores and porosity reduce the channels for the corrosive solution to pass through the coating. When the coating cracks or falls off, the corrosive medium and substrate come into direct contact. Smaller and uniform grains have better corrosion resistance.

Purpose

This study aims to investigate the corrosion behavior of cold-rolled Fe₃₅Ni₂₀C_r12Mn_(28-x)Al_x high-entropy alloys (HEAs) using the potentiodynamic polarization technique in 1 M H₂SO₄ acid. Additionally, the influence of molybdenum (Mo) additions as inhibitors and the effect of variations in cold rolling reduction ratios and Al content on corrosion behavior are examined.

Design/methodology/approach

Two cold rolling reduction ratios, namely, 50% (R50) and 90% (R90), were examined for the cold-rolled Fe₃₅Ni₂₀Cr₁₂Mn₂₈Al₅ (Al₅) and Fe₃₅Ni₂₀Cr₁₂Mn₂₃Al₁₀ (Al₁₀) HEAs. Mo inhibitor additions were introduced at varying concentrations of 0.3, 0.6 and 0.9 Wt.%. The potentiodynamic polarization technique was used to evaluate the corrosion rates (CRs) under different experimental conditions.

Findings

The results indicate that the addition of 0.3 Wt.% Mo in 1 M H₂SO₄ yielded the lowest CR for both R50 and R90, irrespective of the Al content in the HEAs. However, the highest CR was observed at 0.6 Wt.% Mo addition. Furthermore, increasing the concentration of Al resulted in a corresponding rise in the CR. Comparatively, the CR decreased significantly when the cold rolling reduction ratio increased from R50 to R90.

Originality/value

This research provides valuable insights into the intricate relationship between Mo inhibitors, cold rolling reduction ratio, Al content and the resulting corrosion behavior of Fe₃₅Ni₂₀Cr₁₂Mn_(28-x)Al_x HEAs. The comprehensive analysis of corroded HEAs, including surface morphology, compositions and elemental distribution mapping, contributes to the understanding of the corrosion mechanisms and offers potential strategies for enhancing the corrosion behavior of HEAs.

Purpose

The purpose of this paper is to investigate the effect of NaCl solution with different concentrations on impact-sliding fretting corrosion behavior of Inconel 690TT steam generator heat transfer tubes.

Design/methodology/approach

The optical 3D profiler was used to measure the wear profile and calculated the wear volume. Corrosion behavior was studied using open circuit potential monitoring and potentiodynamic polarization testing. The morphologies and elemental distributions of wear scars were analyzed using scanning electron microscopy and energy-dispersive spectroscopy. The synergism of wear and corrosion was analyzed according to the ASTM G119 standard.

Findings

The corrosion tendency reflected by OCP and the corrosion current calculated by Tafel both increased with the increase of NaCl concentration. The total volume loss of the material increased with concentration, and it was known from the synergism that the volume loss caused by corrosion-enhanced wear accounted for the largest proportion, while the wear-enhanced corrosion also made a greater contribution to volume loss than tangential fretting corrosion. Through the analysis of the material morphologies and synergism of wear and corrosion, the damage mechanism was elucidated.

Originality/value

The research findings can provide reference for impact-sliding fretting corrosion behavior of Inconel 690TT heat transfer tubes in NaCl solution with different concentrations.

Purpose

Polyaniline (PANI) has garnered attention for its potential applications in anticorrosion fields because of its unique properties. Satisfactory outcomes have been achieved when using PANI as a functional filler in organic coatings. More recently, research has extensively explored PANI-based organic coatings with self-healing properties. The purpose of this paper is to provide a summary of the active agents, methods and mechanisms involved in the self-healing of organic coatings.

Design/methodology/approach

This study uses specific doped acids and metal corrosion inhibitors as active and self-healing agents to modify PANI using the methods of oxidation polymerization, template synthesis, nanosheet carrier and nanocontainer loading methods. The anticorrosion performance of the coatings is evaluated using EIS, LEIS and salt spray tests.

Findings

Specific doped acids and metal corrosion inhibitors are used as active agents to modify PANI and confer self-healing properties to the coatings. The coatings’ active protection mechanism encompasses PANI’s own passivation ability, the adsorption of active agents and the creation of insoluble compounds or complexes.

Originality/value

This paper summarizes the active agents used to modify PANI, the procedures used for modification and the self-healing mechanism of the composite coatings. It also proposes future directions for developing PANI organic coatings with self-healing capabilities. The summaries and proposals presented may facilitate large-scale production of the PANI organic coatings, which exhibit outstanding anticorrosion competence and self-healing properties.

Purpose

This paper aims to characterize the surface film formed on Alloys 800 and 690 in chloride and thiosulfate-containing solution at 300°C.

Design/methodology/approach

Alloy 800 and 690 were immersed in chloride and thiosulfate-containing solution at 300°C up to five days, and then the surface film was analyzed by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM) and energy dispersive X-ray spectrometers (EDX).

Findings

Through static immersion experiments in a high-temperature and high-pressure water environment, the alloy samples covered by surface film after five days of immersion were obtained. The morphology of the surface film was characterized at both horizontal and cross-sectional scales using SEM and focused ion beam-TEM techniques. It was observed that due to the influence of the quartz lining, the surface film primarily exhibited a bilayered structure. The first layer contained a significant amount of SiO₂, with a higher content of metal hydroxides compared to metal oxides. The second layer was predominantly composed of Fe, Ni and Cr, with a higher content of metal oxides compared to metal hydroxides.

Originality/value

The results showed that the materials of the lining of the autoclave could significantly influence the film composition of the tested material, which should be paid attention when analyzing the corrosion mechanism at high temperature.