Pub Date : 2023-09-15DOI: 10.1108/acmm-05-2023-2809
Yang Liu, Qian Zhang, Jialing Wang, Yawei Shao, Zhengyi Xu, Yanqiu Wang, Junyi Wang
Purpose The purpose of this paper is to enhance the compatibility of titanium dioxide in epoxy resins and thus the corrosion resistance of the coatings. Design/methodology/approach In this work, TiO 2 was modified by the mechanochemistry method where mechanical energy was combined with thermal energy to complete the modification. The stability of modified TiO 2 in epoxy was analyzed by sedimentation experiment. The modified TiO 2 -epoxy coating was prepared, and the corrosion resistance of the coating was analyzed by open circuit potential, electrochemical impedance spectroscopy and neutral salt spray test. Findings High-temperature mechanical modification can improve the compatibility of TiO 2 in epoxy resin. At the same time, the modified TiO 2 -epoxy coating showed better corrosion resistance. Compared to the unmodified TiO 2 -epoxy coating, the coating improved the dry adhesion force by 61.7% and the adhesion drop by 33.3%. After 2,300 h of immersion in 3.5 Wt.% NaCl solution, the coating resistance of the modified TiO 2 coating was enhanced by nearly two orders of magnitude compared to the unmodified coating. Originality/value The authors have grafted epoxy molecules onto TiO 2 surfaces using a high-temperature mechanical force modification method. The compatibility of TiO 2 with epoxy resin is enhanced, resulting in improved adhesion of the coating to the substrate and corrosion resistance of the coating.
{"title":"Effect of high-temperature mechanochemistry method modified TiO<sub>2</sub> on the dispersibility and corrosion resistance of TiO<sub>2</sub>-epoxy coatings","authors":"Yang Liu, Qian Zhang, Jialing Wang, Yawei Shao, Zhengyi Xu, Yanqiu Wang, Junyi Wang","doi":"10.1108/acmm-05-2023-2809","DOIUrl":"https://doi.org/10.1108/acmm-05-2023-2809","url":null,"abstract":"Purpose The purpose of this paper is to enhance the compatibility of titanium dioxide in epoxy resins and thus the corrosion resistance of the coatings. Design/methodology/approach In this work, TiO 2 was modified by the mechanochemistry method where mechanical energy was combined with thermal energy to complete the modification. The stability of modified TiO 2 in epoxy was analyzed by sedimentation experiment. The modified TiO 2 -epoxy coating was prepared, and the corrosion resistance of the coating was analyzed by open circuit potential, electrochemical impedance spectroscopy and neutral salt spray test. Findings High-temperature mechanical modification can improve the compatibility of TiO 2 in epoxy resin. At the same time, the modified TiO 2 -epoxy coating showed better corrosion resistance. Compared to the unmodified TiO 2 -epoxy coating, the coating improved the dry adhesion force by 61.7% and the adhesion drop by 33.3%. After 2,300 h of immersion in 3.5 Wt.% NaCl solution, the coating resistance of the modified TiO 2 coating was enhanced by nearly two orders of magnitude compared to the unmodified coating. Originality/value The authors have grafted epoxy molecules onto TiO 2 surfaces using a high-temperature mechanical force modification method. The compatibility of TiO 2 with epoxy resin is enhanced, resulting in improved adhesion of the coating to the substrate and corrosion resistance of the coating.","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":"83 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135353920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-11DOI: 10.1108/acmm-07-2023-2861
Yang Liu, Jialing Wang, Huayang Cai, Yawei Shao, Zhengyi Xu, Yanqiu Wang, Junyi Wang
Purpose Epoxy zinc-rich coatings are widely used in harsh environments because of the long-lasting cathodic protection of steel surfaces. The purpose of this paper is to use flake zinc powder instead of the commonly used spherical zinc powder to reduce the zinc powder content. Design/methodology/approach In this paper, the authors have prepared an anticorrosive zinc-rich coating using a flake zinc powder instead of the conventional spherical zinc powder. The optimal dispersion of scaly zinc powder in zinc-rich coatings has been explored by looking at the surface and cross-sectional morphology and studying the cathodic protection time of the coating. Findings The final epoxy zinc-rich coating with 35 Wt.% flake zinc powder content was prepared using sand-milling dispersions. It has a similar cathodic protection time and salt spray resistance as the 60 Wt.% spherical zinc-rich coating, with a higher low-frequency impedance modulus value. Originality/value This study uses flake zinc powder instead of the traditional spherical zinc powder. This reduces the amount of zinc powder in the coating and improves the corrosion resistance of the coating.
{"title":"Studies of zinc content reduction using flake zinc powder in epoxy zinc-rich coatings","authors":"Yang Liu, Jialing Wang, Huayang Cai, Yawei Shao, Zhengyi Xu, Yanqiu Wang, Junyi Wang","doi":"10.1108/acmm-07-2023-2861","DOIUrl":"https://doi.org/10.1108/acmm-07-2023-2861","url":null,"abstract":"Purpose Epoxy zinc-rich coatings are widely used in harsh environments because of the long-lasting cathodic protection of steel surfaces. The purpose of this paper is to use flake zinc powder instead of the commonly used spherical zinc powder to reduce the zinc powder content. Design/methodology/approach In this paper, the authors have prepared an anticorrosive zinc-rich coating using a flake zinc powder instead of the conventional spherical zinc powder. The optimal dispersion of scaly zinc powder in zinc-rich coatings has been explored by looking at the surface and cross-sectional morphology and studying the cathodic protection time of the coating. Findings The final epoxy zinc-rich coating with 35 Wt.% flake zinc powder content was prepared using sand-milling dispersions. It has a similar cathodic protection time and salt spray resistance as the 60 Wt.% spherical zinc-rich coating, with a higher low-frequency impedance modulus value. Originality/value This study uses flake zinc powder instead of the traditional spherical zinc powder. This reduces the amount of zinc powder in the coating and improves the corrosion resistance of the coating.","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":"68 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135937979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-06DOI: 10.1108/acmm-07-2023-2858
Donghui Hu, Shenyou Song, Zongxing Zhang, Linfeng Wang
Purpose This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements. Design/methodology/approach The “two-step” hot-dip coating process for cable steel wires was developed, which involved first hot-dip galvanizing and then hot-dip galvanizing of aluminum magnesium alloy. The corrosion rate, polarization curve and impedance of Zn–6Al–1Mg and Zn–10Al–3Mg alloy-coated steel wires were compared through acetate spray test and electrochemical test, and the corrosion mechanism of Zn–Al–Mg alloy-coated steel wires was revealed. Findings The corrosion resistance of Zn–10Al–3Mg alloy-coated steel wires had the best corrosion resistance, which was more than seven times that of pure zinc-coated steel wires. The corrosion current of Zn–10Al–3Mg alloy-coated steel wires was lower than that of Zn–6Al–1Mg alloy-coated steel wires, whereas the capacitive arc and impedance value of the former were higher than that of the latter, making it clear that the corrosion resistance of Zn–10Al–3Mg was better than that of Zn–6Al–1Mg alloy coating. Moreover, the Zn–Al–Mg alloy-coated steel wires for bridge cables had the function of coating “self-repairing.” Originality/value Controlling the temperature and time of the hot dip galvanizing stage can reduce the thickness of transition layer and solve the problem of easy cracking of the transition layer in the Zn–Al–Mg alloy coating due to the Sandelin effect.
{"title":"Experimental study on corrosion resistance of Zn–Al–Mg alloy coating of high-strength steel wires for bridge cables","authors":"Donghui Hu, Shenyou Song, Zongxing Zhang, Linfeng Wang","doi":"10.1108/acmm-07-2023-2858","DOIUrl":"https://doi.org/10.1108/acmm-07-2023-2858","url":null,"abstract":"\u0000Purpose\u0000This paper aims to figure out the conundrum that the corrosion resistance longevity of steel wires for bridge cables was arduous to meet the requirements.\u0000\u0000\u0000Design/methodology/approach\u0000The “two-step” hot-dip coating process for cable steel wires was developed, which involved first hot-dip galvanizing and then hot-dip galvanizing of aluminum magnesium alloy. The corrosion rate, polarization curve and impedance of Zn–6Al–1Mg and Zn–10Al–3Mg alloy-coated steel wires were compared through acetate spray test and electrochemical test, and the corrosion mechanism of Zn–Al–Mg alloy-coated steel wires was revealed.\u0000\u0000\u0000Findings\u0000The corrosion resistance of Zn–10Al–3Mg alloy-coated steel wires had the best corrosion resistance, which was more than seven times that of pure zinc-coated steel wires. The corrosion current of Zn–10Al–3Mg alloy-coated steel wires was lower than that of Zn–6Al–1Mg alloy-coated steel wires, whereas the capacitive arc and impedance value of the former were higher than that of the latter, making it clear that the corrosion resistance of Zn–10Al–3Mg was better than that of Zn–6Al–1Mg alloy coating. Moreover, the Zn–Al–Mg alloy-coated steel wires for bridge cables had the function of coating “self-repairing.”\u0000\u0000\u0000Originality/value\u0000Controlling the temperature and time of the hot dip galvanizing stage can reduce the thickness of transition layer and solve the problem of easy cracking of the transition layer in the Zn–Al–Mg alloy coating due to the Sandelin effect.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48117935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-30DOI: 10.1108/acmm-05-2023-2812
Dalei Zhang, Xinwei Zhang, Enze Wei, Xiaohui Dou, Zonghao He
Purpose This study aims to improve the corrosion resistance of TA2-welded joints by superhydrophobic surface modification using micro-arc oxidation technology and low surface energy substance modification. Design/methodology/approach The microstructure and chemical state of the superhydrophobic film layer were analyzed using scanning electron microscopy, energy dispersive X-ray spectroscopy, three-dimensional morphology, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared absorption spectroscopy. The influence of the superhydrophobic film layer on the corrosion resistance of TA2-welded joints was investigated using classical electrochemical testing methods. Findings The characterization results showed that the super hydrophobic TiO2 ceramic membrane was successfully constructed on the surface of the TA2-welded joint, and the construction of the super hydrophobic film greatly improved the corrosion resistance of the TA2-welded joint. Originality/value The superhydrophobic TiO2 ceramic membrane has excellent corrosion resistance. The micro nanostructure in the superhydrophobic film can intercept air to form an air layer to prevent the corrosion medium from contacting the surface, thus, improving the corrosion resistance of the sample.
{"title":"Construction of superhydrophobic film on the titanium alloy welded joint and its corrosion resistance study","authors":"Dalei Zhang, Xinwei Zhang, Enze Wei, Xiaohui Dou, Zonghao He","doi":"10.1108/acmm-05-2023-2812","DOIUrl":"https://doi.org/10.1108/acmm-05-2023-2812","url":null,"abstract":"\u0000Purpose\u0000This study aims to improve the corrosion resistance of TA2-welded joints by superhydrophobic surface modification using micro-arc oxidation technology and low surface energy substance modification.\u0000\u0000\u0000Design/methodology/approach\u0000The microstructure and chemical state of the superhydrophobic film layer were analyzed using scanning electron microscopy, energy dispersive X-ray spectroscopy, three-dimensional morphology, X-ray diffraction, X-ray photoelectron spectroscopy and Fourier transform infrared absorption spectroscopy. The influence of the superhydrophobic film layer on the corrosion resistance of TA2-welded joints was investigated using classical electrochemical testing methods.\u0000\u0000\u0000Findings\u0000The characterization results showed that the super hydrophobic TiO2 ceramic membrane was successfully constructed on the surface of the TA2-welded joint, and the construction of the super hydrophobic film greatly improved the corrosion resistance of the TA2-welded joint.\u0000\u0000\u0000Originality/value\u0000The superhydrophobic TiO2 ceramic membrane has excellent corrosion resistance. The micro nanostructure in the superhydrophobic film can intercept air to form an air layer to prevent the corrosion medium from contacting the surface, thus, improving the corrosion resistance of the sample.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42537915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-29DOI: 10.1108/acmm-04-2023-2782
Yingshuang Liu, Ran Liu, Dalei Zhang, Shaohua Xing, Xiaohui Dou, Xinwei Zhang, Zonghao He
Purpose The corrosion behaviour of titanium alloy surface when fluid with different flow rates flows through welded joints with different residual heights was explored. Design/methodology/approach The experiment uses a combination of array electrodes and simulation. Findings It is found that when the weld reinforcement exists, the corrosion tendency of both ends of the weld metal is greater than that of other parts of the welded joint due to the influence of high turbulence kinetic energy and shear stress. The presence of weld reinforcement heights makes the fluid behind it fluctuate greatly. The passivation films of both the base metal (BM) at the rear and the heat-affected zone (HAZ) are more prone to corrosion than those of the front BM and HAZ, and the passivation film is rougher. Originality/value The combination of test and simulation was used to explore the influence of electrochemical and hydrodynamic factors on the corrosion behaviour of titanium alloy-welded joints when welding residual height existed.
{"title":"Investigation on corrosion tendency behaviour of TA2 titanium alloy welded joints under flow scouring conditions using the array electrode method","authors":"Yingshuang Liu, Ran Liu, Dalei Zhang, Shaohua Xing, Xiaohui Dou, Xinwei Zhang, Zonghao He","doi":"10.1108/acmm-04-2023-2782","DOIUrl":"https://doi.org/10.1108/acmm-04-2023-2782","url":null,"abstract":"\u0000Purpose\u0000The corrosion behaviour of titanium alloy surface when fluid with different flow rates flows through welded joints with different residual heights was explored.\u0000\u0000\u0000Design/methodology/approach\u0000The experiment uses a combination of array electrodes and simulation.\u0000\u0000\u0000Findings\u0000It is found that when the weld reinforcement exists, the corrosion tendency of both ends of the weld metal is greater than that of other parts of the welded joint due to the influence of high turbulence kinetic energy and shear stress. The presence of weld reinforcement heights makes the fluid behind it fluctuate greatly. The passivation films of both the base metal (BM) at the rear and the heat-affected zone (HAZ) are more prone to corrosion than those of the front BM and HAZ, and the passivation film is rougher.\u0000\u0000\u0000Originality/value\u0000The combination of test and simulation was used to explore the influence of electrochemical and hydrodynamic factors on the corrosion behaviour of titanium alloy-welded joints when welding residual height existed.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47664406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-25DOI: 10.1108/acmm-06-2023-2819
Xin Zhou, Wenbin Zhou, Yang Zheng Zhang, Meng-Ran Li, Haijing Sun, Jie Sun
Purpose This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass. Design/methodology/approach The authors performed weight loss experiments, electrochemical experiments including the polarization curve and electrochemical impedance spectrum, corrosion morphology observation using scanning electron microscope (SEM) and atomic force microscope (AFM) and surface composition analysis via X-ray photoelectron spectroscopy (XPS) to analyze the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass by using quantum chemical calculation (Gaussian 09), molecular dynamics simulation (M-S) and Langmuir adsorption isotherm. Findings According to the results, imidazole-pyridine and its derivatives were found to be modest or moderately mixed corrosion inhibitors; moreover, they were spontaneously adsorbed on the metal surface in a single-layer, mixed adsorption mode. Originality/value The corrosion inhibition properties of pyrazolo-[1,2-a]pyridine and its derivatives on brass in sulfuric acid solution were analyzed through weight loss and electrochemical experiments. Moreover, SEM and AFM were simultaneously used to observe the corrosion appearance. Furthermore, XPS was used to analyze the surface. Then, Gaussian 09 and M-S were combined along with the Langmuir adsorption isotherm to investigate the corrosion inhibition mechanism of imidazole-[1,2-a]pyridine and its derivatives.
{"title":"Experimental and computational study of imidazole-pyridine and its derivatives as corrosion inhibitors on brass in sulfuric acid solution","authors":"Xin Zhou, Wenbin Zhou, Yang Zheng Zhang, Meng-Ran Li, Haijing Sun, Jie Sun","doi":"10.1108/acmm-06-2023-2819","DOIUrl":"https://doi.org/10.1108/acmm-06-2023-2819","url":null,"abstract":"Purpose This paper aims to study the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass. Design/methodology/approach The authors performed weight loss experiments, electrochemical experiments including the polarization curve and electrochemical impedance spectrum, corrosion morphology observation using scanning electron microscope (SEM) and atomic force microscope (AFM) and surface composition analysis via X-ray photoelectron spectroscopy (XPS) to analyze the corrosion inhibition behavior of imidazopyridine and its three derivatives on brass by using quantum chemical calculation (Gaussian 09), molecular dynamics simulation (M-S) and Langmuir adsorption isotherm. Findings According to the results, imidazole-pyridine and its derivatives were found to be modest or moderately mixed corrosion inhibitors; moreover, they were spontaneously adsorbed on the metal surface in a single-layer, mixed adsorption mode. Originality/value The corrosion inhibition properties of pyrazolo-[1,2-a]pyridine and its derivatives on brass in sulfuric acid solution were analyzed through weight loss and electrochemical experiments. Moreover, SEM and AFM were simultaneously used to observe the corrosion appearance. Furthermore, XPS was used to analyze the surface. Then, Gaussian 09 and M-S were combined along with the Langmuir adsorption isotherm to investigate the corrosion inhibition mechanism of imidazole-[1,2-a]pyridine and its derivatives.","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":"189 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135237020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-24DOI: 10.1108/acmm-05-2023-2806
Hai-Xiao Sun, Jia Cui, He Wang, Shuai Yang, Souavang Xaikoua, Y. Tan, Xin Zhou, Baojie Wang, Jie Sun
Purpose The purpose of this paper is to study the effect of temperature on Zn–Ni alloys in ChCl–Urea. Design/methodology/approach Based on cyclic voltammetry experiments, the deposition behavior and kinetics of the Zn–Ni alloy are studied. The nucleation process of the Zn–Ni alloy is studied in detail via chronoamperometry experiments. The effects of the deposition temperature on the microstructure, Ni content and phase composition of Zn–Ni alloy coatings are investigated via scanning electron microscopy and X-ray diffraction (XRD) combined with classical thermodynamics. Findings The results show that with increasing temperature, the reduction peak shifts toward a more positive electric potential, which is beneficial for the co-electric deposition process, and the diffusion coefficient is estimated. With increasing temperature, the nucleation process of the Zn–Ni alloy becomes a three-dimensional instantaneous nucleation, the typical kinetic parameters are determined using the standard 3D growth proliferation control model and the Gibbs free energy is estimated. The Zn–Ni alloy coatings are prepared via normal co-deposition. With increasing temperature, the degree of crystallinity increases, the coating gradually becomes uniform and compact and the XRD peak intensity increases. Originality/value The nucleation process of the Zn–Ni alloy at different temperatures is analyzed. The diffusion coefficient D and Gibbs free energy are calculated. The contribution of the three processes at different temperatures is analyzed. The effect of temperature on the morphology of the Zn–Ni alloy coatings is studied.
{"title":"Effect of temperature on electronucleation and growth mechanism of Zn–Ni alloy in deep eutectic solvent","authors":"Hai-Xiao Sun, Jia Cui, He Wang, Shuai Yang, Souavang Xaikoua, Y. Tan, Xin Zhou, Baojie Wang, Jie Sun","doi":"10.1108/acmm-05-2023-2806","DOIUrl":"https://doi.org/10.1108/acmm-05-2023-2806","url":null,"abstract":"\u0000Purpose\u0000The purpose of this paper is to study the effect of temperature on Zn–Ni alloys in ChCl–Urea.\u0000\u0000\u0000Design/methodology/approach\u0000Based on cyclic voltammetry experiments, the deposition behavior and kinetics of the Zn–Ni alloy are studied. The nucleation process of the Zn–Ni alloy is studied in detail via chronoamperometry experiments. The effects of the deposition temperature on the microstructure, Ni content and phase composition of Zn–Ni alloy coatings are investigated via scanning electron microscopy and X-ray diffraction (XRD) combined with classical thermodynamics.\u0000\u0000\u0000Findings\u0000The results show that with increasing temperature, the reduction peak shifts toward a more positive electric potential, which is beneficial for the co-electric deposition process, and the diffusion coefficient is estimated. With increasing temperature, the nucleation process of the Zn–Ni alloy becomes a three-dimensional instantaneous nucleation, the typical kinetic parameters are determined using the standard 3D growth proliferation control model and the Gibbs free energy is estimated. The Zn–Ni alloy coatings are prepared via normal co-deposition. With increasing temperature, the degree of crystallinity increases, the coating gradually becomes uniform and compact and the XRD peak intensity increases.\u0000\u0000\u0000Originality/value\u0000The nucleation process of the Zn–Ni alloy at different temperatures is analyzed. The diffusion coefficient D and Gibbs free energy are calculated. The contribution of the three processes at different temperatures is analyzed. The effect of temperature on the morphology of the Zn–Ni alloy coatings is studied.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43783533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Purpose This study aims to evaluate the protection performance of zinc as sacrificial anode for ABS A steel in the presence of H2S under different temperatures, pH and salinities. Design/methodology/approach In this paper, weight loss measurements and electrochemical measurements are used to evaluate the corrosion degree of zinc and ABS A steel. Findings Under the conditions involved in this work, it is shown that zinc is a nice sacrificial anode with the reason of its stable potential and excellent anode current efficiency according to the relevant standard. And it is also found that the hydrogen evolution does not occur on ABS A steel specimens. The potential difference between cathode and anode is suitable; thus, it can be concluded that each steel is well protected. Originality/value To the best of the authors’ knowledge, no other study has analyzed the protection mechanism and effect of zinc as sacrificial anode in H2S-containing environments under high temperature at present.
{"title":"The evaluation on the protection performance of high temperature sacrificial anode for ABS A steels in H2S-containing environment","authors":"Yongtao Zhao, Weili Li, X. Xuan, Jianbang Gao, Jue Wang, L. Dong, Dawei Zang, Mingjian Wang, X. Zhong","doi":"10.1108/acmm-06-2023-2837","DOIUrl":"https://doi.org/10.1108/acmm-06-2023-2837","url":null,"abstract":"\u0000Purpose\u0000This study aims to evaluate the protection performance of zinc as sacrificial anode for ABS A steel in the presence of H2S under different temperatures, pH and salinities.\u0000\u0000\u0000Design/methodology/approach\u0000In this paper, weight loss measurements and electrochemical measurements are used to evaluate the corrosion degree of zinc and ABS A steel.\u0000\u0000\u0000Findings\u0000Under the conditions involved in this work, it is shown that zinc is a nice sacrificial anode with the reason of its stable potential and excellent anode current efficiency according to the relevant standard. And it is also found that the hydrogen evolution does not occur on ABS A steel specimens. The potential difference between cathode and anode is suitable; thus, it can be concluded that each steel is well protected.\u0000\u0000\u0000Originality/value\u0000To the best of the authors’ knowledge, no other study has analyzed the protection mechanism and effect of zinc as sacrificial anode in H2S-containing environments under high temperature at present.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45793390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Purpose The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice. Design/methodology/approach First, the opening size of the wedge-shaped crevice was designed to 0.1, 0.3 and 0.5 mm by controlling the thickness of silicon rubber and the double-side adhesive tape. Then, one side of the glass sheet was stuck on the silicon strip and keep the electrodes of Rows 1 and 2 outside the crevice as a reference, and the opposite side was stuck to the wire beam electrode by silica gel. Findings The current density with a maximum value of 5.7 × 10−6 A/cm2 was observed at the crevice opening of 0.5 mm, while the lowest value of 9.2 × 10−7 A/cm2 was found at the crevice opening of 0.1 mm. In addition, the corrosion resistance at the inside of the crevice is higher than that at the outside and the middle of the crevice. It means that the internal width of the wedge-shaped crevice tends toward 0, which hinders the migration of ions in the corrosive medium. The generation of corrosive products further reduce the crevice size to cause the inhibition of corrosion at the inside of the crevice as well. Originality/value The multilayer and multipath LAM component is prepared to show the complex microstructure, which made the corrosion behavior and mechanism at wedge-shaped crevice nondeterminacy.
{"title":"Crevice corrosion behavior and mechanism of laser additive manufacturing nickel-based alloy under wedge-shaped crevice by using wire beam electrode","authors":"Yu-chen Xi, Qinying Wang, Yafei Wu, Xingshou Zhang, Lijin Dong, Shulin Bai, Yezhou Yang","doi":"10.1108/acmm-06-2023-2833","DOIUrl":"https://doi.org/10.1108/acmm-06-2023-2833","url":null,"abstract":"\u0000Purpose\u0000The purpose of this study is to investigate the crevice corrosion behavior and mechanism of laser additive manufacturing (LAM) nickel-based alloy under wedge-shaped crevice.\u0000\u0000\u0000Design/methodology/approach\u0000First, the opening size of the wedge-shaped crevice was designed to 0.1, 0.3 and 0.5 mm by controlling the thickness of silicon rubber and the double-side adhesive tape. Then, one side of the glass sheet was stuck on the silicon strip and keep the electrodes of Rows 1 and 2 outside the crevice as a reference, and the opposite side was stuck to the wire beam electrode by silica gel.\u0000\u0000\u0000Findings\u0000The current density with a maximum value of 5.7 × 10−6 A/cm2 was observed at the crevice opening of 0.5 mm, while the lowest value of 9.2 × 10−7 A/cm2 was found at the crevice opening of 0.1 mm. In addition, the corrosion resistance at the inside of the crevice is higher than that at the outside and the middle of the crevice. It means that the internal width of the wedge-shaped crevice tends toward 0, which hinders the migration of ions in the corrosive medium. The generation of corrosive products further reduce the crevice size to cause the inhibition of corrosion at the inside of the crevice as well.\u0000\u0000\u0000Originality/value\u0000The multilayer and multipath LAM component is prepared to show the complex microstructure, which made the corrosion behavior and mechanism at wedge-shaped crevice nondeterminacy.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44869560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-11DOI: 10.1108/acmm-06-2023-2845
Yu-chen Xi, Qinying Wang, Xiaofang Luo, Xingshou Zhang, Tingyao Liu, Hua Zheng, Lijin Dong, Jie Wang, J. Zhang
Purpose The purpose of this paper is to investigate the effect Ti on stress corrosion cracking (SCC) and flow accelerated stress corrosion cracking (FA-SCC) behavior and mechanisms of Monel K500 alloy. Design/methodology/approach Monel K500 alloy with different Ti contents was designed. A metallurgical microscope (XJP-3C) and scanning electron microscopy (EV0 MA15 Zeiss) with an energy dispersive spectroscopy were used to analyze the microstructure of the Monel K500 alloy. In situ electrochemical tests were carried out in static and flowing seawater to study FA-SCC behavior. Findings The number of TiCN particles in the alloy increased as the increase of Ti content. The static corrosion and SCC of Monel K500 alloy are reduced as the content of Ti increases. Generally, the SCC of alloys was caused by the synergistic effect of the anodic dissolution at exposed metal matrix and the pit corrosion of metal matrix adjacent to TiCN particles, which was further accelerated by flowing. Originality/value The corrosion behavior and mechanism of Monel K500 alloy with different Ti contents in a complex flowing seawater environment are still unclear, which remain systematic study to insure the safe service of the alloy.
{"title":"Effect of Ti on stress corrosion cracking behavior and mechanism of Monel K500 alloy in flowing seawater","authors":"Yu-chen Xi, Qinying Wang, Xiaofang Luo, Xingshou Zhang, Tingyao Liu, Hua Zheng, Lijin Dong, Jie Wang, J. Zhang","doi":"10.1108/acmm-06-2023-2845","DOIUrl":"https://doi.org/10.1108/acmm-06-2023-2845","url":null,"abstract":"\u0000Purpose\u0000The purpose of this paper is to investigate the effect Ti on stress corrosion cracking (SCC) and flow accelerated stress corrosion cracking (FA-SCC) behavior and mechanisms of Monel K500 alloy.\u0000\u0000\u0000Design/methodology/approach\u0000Monel K500 alloy with different Ti contents was designed. A metallurgical microscope (XJP-3C) and scanning electron microscopy (EV0 MA15 Zeiss) with an energy dispersive spectroscopy were used to analyze the microstructure of the Monel K500 alloy. In situ electrochemical tests were carried out in static and flowing seawater to study FA-SCC behavior.\u0000\u0000\u0000Findings\u0000The number of TiCN particles in the alloy increased as the increase of Ti content. The static corrosion and SCC of Monel K500 alloy are reduced as the content of Ti increases. Generally, the SCC of alloys was caused by the synergistic effect of the anodic dissolution at exposed metal matrix and the pit corrosion of metal matrix adjacent to TiCN particles, which was further accelerated by flowing.\u0000\u0000\u0000Originality/value\u0000The corrosion behavior and mechanism of Monel K500 alloy with different Ti contents in a complex flowing seawater environment are still unclear, which remain systematic study to insure the safe service of the alloy.\u0000","PeriodicalId":8217,"journal":{"name":"Anti-corrosion Methods and Materials","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42519977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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