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Zinc oxide nanoparticles as photo-catalytic and anti-bacterial pigment for alkyd resin based coating 氧化锌纳米粒子光催化抗菌颜料在醇酸树脂基涂料中的应用
Q3 Materials Science Pub Date : 2022-11-01 DOI: 10.5604/01.3001.0016.2445
A. Kavitha Sri, M. Sivaraj, S. Rajkumar, A. Ruby Shelin, L. Sajitha, K. Jeyasubramanian, R. Jeen Robert, G. S. Hikku
Recently, there has been an upsurge among people around the world in maintaining a sustainable and hygienic environment. This is due to the over-exploitation of recourses causing environmental pollution and spreading bacterial infections. In this regard, scientists are motivated to develop smart coatings where environmental pollutants and bacterial cells are degraded when in contact with their surfaces.In our previous report, ZnO nanoparticles (NPs) were prepared using the precipitation technique, showing good photocatalytic and antibacterial activity [1]. In this context, the present study details the use of ZnO NPs as pigment for the fabrication of alkyd resin-based self-cleaning coating. The coating was developed by mixing ZnO NPs and alkyd resin along with the additives using the ball milling technique. The developed coating was characterized using field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, atomic force microscopy, and water contact angle measurements.To elucidate the self-cleaning and hygienic behaviour of the ZnO/alkyd resin coating, the dried coating was exposed to crystal violet (CV) solution as a model dye pollutant and bacterial strains to assess its photocatalytic and antibacterial activity. The droplets of CV solution placed over the coating almost degraded after 360 min of exposure to sunlight owing to the presence of ZnO NPs in the coating. Further, the coating exhibits reasonable antibacterial activity against E. coli and P. aeruginosa whereas it displays low antibacterial activity against S. aureus.Even though, the self-cleaning coating shows promising results, tuning the activity of the photo-catalytic pigment can improve the pollutant degradation efficiency and elevate bactericidal activity.ZnO NPs-impregnated alkyd resin coating for self-cleaning applications is novel.
最近,世界各地的人们都掀起了一股维护可持续卫生环境的热潮。这是由于过度开发资源造成环境污染并传播细菌感染。在这方面,科学家们有动力开发智能涂层,使环境污染物和细菌细胞在与表面接触时降解。在我们之前的报告中,使用沉淀技术制备了ZnO纳米颗粒,显示出良好的光催化和抗菌活性[1]。在这种背景下,本研究详细介绍了ZnO纳米粒子作为颜料用于制备醇酸树脂基自清洁涂料。采用球磨技术,将ZnO纳米粒子和醇酸树脂以及添加剂混合制成涂层。使用场发射扫描电子显微镜、能量色散X射线光谱、原子力显微镜和水接触角测量对所开发的涂层进行了表征。为了阐明ZnO/醇酸树脂涂层的自清洁和卫生行为,将干燥的涂层暴露于作为模型染料污染物的结晶紫(CV)溶液和细菌菌株中,以评估其光催化和抗菌活性。由于涂层中存在ZnO NP,放置在涂层上的CV溶液液滴在暴露于阳光下360分钟后几乎降解。此外,该涂层对大肠杆菌和铜绿假单胞菌表现出合理的抗菌活性,而对金黄色葡萄球菌表现出较低的抗菌活性。尽管自清洁涂料显示出了良好的效果,但调节光催化颜料的活性可以提高污染物的降解效率并提高杀菌活性。用于自清洁应用的ZnO纳米粒子浸渍醇酸树脂涂料是一种新型涂料。
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引用次数: 0
Assessment of gold with titanium alloy weldability in conditions of a dental technique laboratory 牙科技术实验室条件下金与钛合金可焊性的评定
Q3 Materials Science Pub Date : 2022-11-01 DOI: 10.5604/01.3001.0016.2451
G. Jania, J. Żmudzki, S. Topolska
In dental practice, there is necessary to weld gold with titanium under the conditions of a dental technique laboratory, which is difficult. The aim was to assess the weldability of pure gold with the titanium alloy Ti6Al4V using a prosthetic laser welding machine.Gold wire in a diameter of 0.4 mm made with the use of a jewellery drawbar (GOLDPORT, Szczecin, Poland) was welded to a titanium alloy Ti6Al4V substrate of dental implant abutment screw (MegaGen). Dental laser welding parameters (Bego Laser Star T plus) were 230 V; 6.5 ms; 2.5 Hz; laser spot 0.3 mm, and argon blow. Samples were included in resin, ground (500-4000 SiC), polished (Al2O3 suspension) and etched (Kroll solution) per 20 s before observation under a light microscope.There were well-welded and poorly joined zones. The discontinuities and voids there were not visible or sparse next to the initial weld point. Dendritic structure at well-welded remelting zones and two-phase microstructure of titanium and Ti3Au phase were found. The heat-affected zone was about of 20 microns.Light microscopy was used, and precise phase identification required further investigations. Weld strength assessment requires further micro-hardness and load-bearing ability tests. Weldability concerns the model system with pure gold.In the case of elements with dimensions below 0.4 mm, the use of a laser with a smaller spot should be considered for better control of the remelting zone and mechanical positioning of the elements in order to stabilize and avoid discontinuities and voids.Prosthetic laser welding with a laser spot about of 0.3 mm allows to obtain well-welded parts of 0.3 mm in diameter under stable stitching conditions and higher than 0.4 mm in dimensions.
在牙科实践中,有必要在牙科技术实验室的条件下将金与钛焊接,这是困难的。目的是利用假肢激光焊接机评估纯金与钛合金Ti6Al4V的可焊性。使用珠宝拉杆(GOLDPORT, Szczecin, Poland)制作直径为0.4 mm的金丝,焊接到种植牙基牙螺钉(MegaGen)的钛合金Ti6Al4V基板上。牙科激光焊接参数(Bego laser Star T plus)为230 V;6.5女士;2.5赫兹;激光光斑0.3 mm,氩气吹制。样品每20 s放入树脂中,研磨(500-4000 SiC),抛光(Al2O3悬浮液)和蚀刻(Kroll溶液),然后在光学显微镜下观察。有焊接良好和连接不良的区域。在初始焊点附近,不可见或稀疏的不连续和空洞。在焊接良好的重熔区发现了枝晶组织和钛与Ti3Au相的两相组织。热影响区约为20微米。使用光学显微镜,精确的相识别需要进一步的研究。焊接强度评估需要进一步的显微硬度和承载能力测试。可焊性与纯金的模型系统有关。对于尺寸小于0.4 mm的元件,应考虑使用光斑较小的激光,以便更好地控制重熔区域和元件的机械定位,以稳定和避免不连续和空洞。激光光斑约为0.3 mm的假肢激光焊接可以在稳定的拼接条件下获得直径0.3 mm且尺寸大于0.4 mm的焊接良好的零件。
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引用次数: 0
The formation of Si-aluminide coating formed by plasma spraying and subsequent diffusion annealing on Ti-Al-7Nb intermetallic alloy 对Ti-Al-7Nb金属间合金进行等离子喷涂和扩散退火后形成的si -铝化物涂层进行了研究
Q3 Materials Science Pub Date : 2022-10-01 DOI: 10.5604/01.3001.0016.1775
M. Góral, P. C. Monteiro, P. Sosnowy, M. Woźniak, T. Kubaszek, B. Kościelniak
In the article, the kinetic growth phenomena of aluminide coating formed by plasma spraying pure Al-Si powder and subsequent diffusion annealing on TiAl intermetallic alloy in inert atmosphere were investigated.The Al-Si powder was thermal sprayed (APS) on TiAl7Nb intermetallic alloy and annealed in Ar atmosphere during 5, 15, 30, 60, 240 and 480 min. The kinetic growth of the coating was observed using the scanning electron microscopy method (SEM), and chemical composition was analysed using the EDS method.The Kirkendall Effects pores formation, as well as titanium silicides on the grain boundary of TiAl3, was found.The oxidation resistance of the developed coating might be analysed in further work.The developed coating might be used for the production of protective aluminide coatings on TiAl intermetallic alloys.The description of aluminide coating formation in a new technological process.
本文研究了TiAl金属间合金在惰性气氛中等离子喷涂纯Al-Si粉末并随后进行扩散退火形成的铝化物涂层的动力学生长现象。将Al-Si粉末热喷涂(APS)在TiAl7Nb金属间合金上,并在Ar气氛中退火5、15、30、60、240和480分钟。使用扫描电子显微镜方法(SEM)观察涂层的动力学生长,并使用EDS方法分析化学成分。发现了Kirkendall效应孔隙的形成,以及TiAl3晶界上的硅化钛。开发的涂层的抗氧化性可在进一步的工作中进行分析。所开发的涂层可用于在TiAl金属间合金上制备保护性铝化物涂层。介绍了一种新工艺中铝化物涂层的形成。
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引用次数: 0
Enhanced algorithm for energy optimization and improvised synchronization in knee exoskeleton system 膝关节外骨骼系统能量优化与临时同步的改进算法
Q3 Materials Science Pub Date : 2022-10-01 DOI: 10.5604/01.3001.0016.1778
J. Arunamithra, R. Saravanan, S. Venkatesh Babu
The purpose of the study is to develop an augmented algorithm with optimised energy and improvised synchronisation to assist the knee exoskeleton design. This enhanced algorithm is used to estimate the accurate left and right movement signals from the brain and accordingly moves the lower-limb exoskeleton with the help of motors.An optimised deep learning algorithm is developed to differentiate the right and left leg movements from the acquired brain signals. The obtained test signals are then compared with the signals obtained from the conventional algorithm to find the accuracy of the algorithm.The obtained average accuracy rate of about 63% illustrates the improvised differentiation in identifying the right and left leg movement.The future work involves the comparative study of the proposed algorithm with other classification technologies to extract more reliable results. A comparative analysis of the replaceable and rechargeable battery will be done in the future study to exhibit the effectiveness of the proposed model.This study involves the extended study of five frequency regions namely alpha, beta, gamma, delta and theta, to handle the real-time EEG signal processing exoskeleton, model.
本研究的目的是开发一种具有优化能量和临时同步的增强算法,以辅助膝关节外骨骼设计。这种增强算法用于估计来自大脑的准确的左右运动信号,并在马达的帮助下相应地移动下肢外骨骼。开发了一种优化的深度学习算法,从获得的大脑信号中区分右腿和左腿的运动。然后将得到的测试信号与常规算法得到的信号进行比较,以确定算法的精度。获得的平均准确率约为63%,说明了在识别右腿和左腿运动方面的临时区分。未来的工作包括将该算法与其他分类技术进行比较研究,以提取更可靠的结果。在未来的研究中,将对可更换电池和可充电电池进行比较分析,以证明所提出模型的有效性。本研究涉及对alpha、beta、gamma、delta和theta五个频率区域的扩展研究,以处理外骨骼实时脑电信号处理模型。
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引用次数: 0
Effectiveness of hybrid Al2O3-TiO2 nano cutting fluids application in CNC turning process 混合Al2O3-TiO2纳米切削液在数控车削加工中的应用效果
Q3 Materials Science Pub Date : 2022-10-01 DOI: 10.5604/01.3001.0016.1777
A. Arifuddin, A. Redhwan, A. M. Syafiq, S. Z. Zainal Ariffin, A. Aminullah, W. Azmi
The purpose of this study is to evaluate the effectiveness of hybrid Al2O3-TiO2 nano-cutting fluid in the turning process application under the selected significant machining parameters consisting of nano concentration, depth of cut and feed rate.The preparation of aqueous hybrid Al2O3-TiO2 water-based nano-cutting fluids and their application as the cutting fluid in turning operations are undertaken. The Al2O3-TiO2 hybrid nano-cutting fluids were prepared through a one-step method; by dispersing nanoparticles of Al2O3 (average diameter 30 nm) and TiO2 (average diameter 30-50 nm) in CNC coolant based at four different volume concentrations (1%, 2%, 3%, 4%). The effectiveness of turning cutting performance, namely cutting temperature (°C), average surface roughness (Ra), and tool wear (%), were assessed via air-assisted nano cutting fluids impinged through MQL setup in turning of Aluminium Alloy AA7075. The response surface method (RSM) was employed in the design of the experiment (DOE).The lowest cutting temperature, surface roughness, and tool wear of 25.8°C, 0.494 µm, and 0.0107%, are obtained, respectively, when the combinations of hybrid nano cutting fluid concentration of 4%, feed rate value of 0.1 mm/rev, and 0.3 mm depth of cut is used.The result in this paper is based on the experimental study of Al2O3-TiO2 hybrid nano-cutting fluid using CNC turning operation. The process focuses on the finishing process by using a finishing insert. Further work using roughing process may be suggested to observe the better performance of this cutting process using nano-cutting fluid towards reducing the wear rate.The use of Al2O3-TiO2 hybrid nano-cutting fluid coupled with MQL in the CNC turning process is considered a new method. Machining soft and delicate materials such as Aluminium should consider using this combination technique since it lowers the cutting temperature and removes the chips, reducing the adhesive wear.The hybrid nano-cutting fluid can replace the conventional cutting fluid and will perform better if combined with the MQL cooling technique; this new method should be considered by major industry players that require a high-precision finished product such as the product that involves aircraft and aerospace applications.
本研究的目的是在选定的由纳米浓度、切削深度和进给速率组成的重要加工参数下,评估混合Al2O3-TiO2纳米切削液在车削工艺应用中的有效性。研究了水性杂化Al2O3-TiO2水性纳米切削液的制备及其在车削加工中的应用。采用一步法制备了Al2O3-TiO2杂化纳米切削液;通过将Al2O3(平均直径30nm)和TiO2(平均直径30-50nm)的纳米颗粒以四种不同的体积浓度(1%、2%、3%、4%)分散在CNC冷却剂中。在AA7075铝合金车削过程中,通过MQL装置冲击的空气辅助纳米切削液评估了车削切削性能的有效性,即切削温度(°C)、平均表面粗糙度(Ra)和刀具磨损(%)。实验设计采用响应面法(RSM)。当混合纳米切削液浓度为4%、进给速度值为0.1mm/rev和切削深度为0.3mm时,获得的最低切削温度、表面粗糙度和刀具磨损分别为25.8°C、0.494µm和0.0107%。本文的研究结果是基于对Al2O3-TiO2杂化纳米切削液的数控车削实验研究。该过程侧重于使用精加工镶片的精加工过程。可以建议使用粗加工工艺进行进一步的工作,以观察使用纳米切削液的这种切削工艺在降低磨损率方面的更好性能。将Al2O3-TiO2杂化纳米切削液与MQL结合用于数控车削工艺被认为是一种新的方法。加工柔软细腻的材料(如铝)应考虑使用这种组合技术,因为它可以降低切割温度并去除碎屑,减少粘合剂磨损。混合纳米切削液可以取代传统的切削液,如果与MQL冷却技术相结合,性能会更好;这种新方法应该被需要高精度成品的主要行业参与者考虑,比如涉及飞机和航空航天应用的产品。
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引用次数: 0
Evaluation of the gas recycling duration on the hydrocarbon recovery from gas condensate fields 凝析气田油气开采中气循环周期的评价
Q3 Materials Science Pub Date : 2022-10-01 DOI: 10.5604/01.3001.0016.1776
S. Matkivskyi, O. Burachok, L. Matiishyn
Optimization of formation pressure maintenance technologies in the development of gas condensate fields with a high initial content of condensate in the reservoir gas using numerical modelling.A study on the efficiency of dry gas injection for pressure maintenance in gas condensate fields was performed with the help of numerical 3D models. Key technological indicators of the reservoir development were calculated for the dry gas injection period of 12, 24, 36, 48, and 60 months. The results are presented as plots for the parameters in a study.Based on the results of the studies, it was found that the introduction of dry gas injection technology ensures that reservoir pressure is maintained at the highest level compared to the development of gas condensate reservoirs on primary depletion. Due to this, further condensate drop-out in the reservoir is slowed down, and the production of partly already condensed hydrocarbons is ensured by their evaporation into the dry gas injected from the surface. The simulation results indicate that increase in the injection duration period leads to an increase of the cumulative condensate production and hence the final hydrocarbon recovery factor.The heterogeneity of oil and gas deposits, both in terms of area and thickness, significantly affects the efficiency of the developed hydrocarbon enhancement technologies. In order to minimize the negative impact of heterogeneity, it is necessary to conduct additional studies on the conditions of specific reservoirs or fields.The reservoir pressure maintenance technology implementation according to various technological schemes, as well as using various types of injection agents, will significantly intensify the development of depleted gas condensate fields with a high condensate yield.Statistical analysis of the simulation results identified the optimum value of the dry gas injection period into the gas condensate reservoir, which is 34.3 months for the conditions of a given reservoir in the study.
基于数值模拟的高凝析气初始含量凝析气田开发中地层压力维持技术优化利用三维数值模型对凝析气田干注保压效率进行了研究。计算了干气注入周期为12、24、36、48、60个月的储层开发关键技术指标。结果以图的形式表示研究中的参数。研究结果表明,相对于凝析气藏一次衰竭开发,干注气技术的引入确保了储层压力保持在最高水平。因此,油藏中的凝析液进一步下降的速度会减慢,并且已经部分冷凝的碳氢化合物的生产通过将其蒸发到从地面注入的干气中来保证。模拟结果表明,注入时间的增加导致累积凝析油产量的增加,从而提高最终的油气采收率。油气沉积面积和厚度的非均质性对已开发的油气强化技术的效果有显著影响。为了尽量减少非均质性的负面影响,有必要对特定油藏或油田的条件进行额外的研究。根据各种技术方案实施储层保压技术,使用各种类型的注入剂,将大大加强高凝析油枯竭凝析气田的开发。通过对模拟结果的统计分析,确定了在给定储层条件下凝析气藏干气注入周期的最佳值为34.3个月。
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引用次数: 0
Prediction of flexural strength of FRC pavements by soft computing techniques 基于软计算技术的frp路面抗弯强度预测
Q3 Materials Science Pub Date : 2022-09-01 DOI: 10.5604/01.3001.0016.1393
A. Kimteta, M. S. Thakur, P. Sihag, A. Upadhya, N. Sharma
The mechanical characteristics of concrete used in rigid pavements can be improved by using fibre-reinforced concrete. The purpose of the study was to predict the flexural strength of the fibre-reinforced concrete for ten input variables i.e., cement, fine aggregate, coarse aggregate, water, superplasticizer/high range water reducer, glass fibre, polypropylene fibre, steel fibres, length and diameter of fibre and further to perform the sensitivity analysis to determine the most sensitive input variable which affects the flexural strength of the said fibre-reinforced concrete.The data used in the study was acquired from the published literature to create the soft computing modes. Four soft computing techniques i.e., Artificial neural networks (ANN), Random forests (RF), Random trees RT), and M5P, were applied to predict the flexural strength of fibre-reinforced concrete for rigid pavement using ten significant input variables as stated in the ‘purpose’. The most performing algorithm was determined after evaluating the applied models on the threshold of five statistical indices, i.e., the coefficient of correlation, mean absolute error, root mean square error, relative absolute error, and root relative squared error. The sensitivity analysis for most sensitive input variable was performed with out-performing model, i.e., ANN.The testing stage findings show that the Artificial neural networks model outperformed other applicable models, having the highest coefficient of correlation (0.9408), the lowest mean absolute error (0.8292), and the lowest root mean squared error (1.1285). Furthermore, the sensitivity analysis was performed using the artificial neural networks model. The results demonstrate that polypropylene fibre-reinforced concrete significantly influences the prediction of the flexural strength of fibre-reinforced concrete.Large datasets may enhance machine learning technique performance.The article's novelty is that the most suitable model amongst the four applied techniques has been identified, which gives far better accuracy in predicting flexural strength.
使用纤维混凝土可以改善刚性路面中使用的混凝土的力学特性。本研究的目的是预测水泥、细骨料、粗骨料、水、高效减水剂/高效减水剂、玻璃纤维、聚丙烯纤维、钢纤维、,并进一步进行灵敏度分析以确定影响所述纤维增强混凝土的抗弯强度的最敏感的输入变量。研究中使用的数据是从已发表的文献中获得的,以创建软计算模式。四种软计算技术,即人工神经网络(ANN)、随机森林(RF)、随机树RT和M5P,应用“目的”中所述的十个重要输入变量来预测刚性路面纤维混凝土的抗弯强度。在根据五个统计指标的阈值(即相关系数、平均绝对误差、均方根误差、相对绝对误差和相对均方根误差)评估应用模型后,确定了性能最好的算法。对最敏感的输入变量的灵敏度分析是用表现不佳的模型,即ANN进行的。测试阶段的结果表明,人工神经网络模型优于其他适用的模型,具有最高的相关系数(0.9408)、最低的平均绝对误差(0.8292)和最低的均方根误差(1.1285)。此外,使用人工神经网络模型进行灵敏度分析。结果表明,聚丙烯纤维混凝土对纤维混凝土抗弯强度的预测有显著影响。大型数据集可以提高机器学习技术的性能。这篇文章的新颖之处在于,在四种应用技术中,已经确定了最合适的模型,这在预测弯曲强度方面提供了更好的准确性。
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引用次数: 0
Methods of hydrodynamic calculation oil pipeline sequential transportation of small batches of various oil 小批量各种油品管道顺序输送的流体力学计算方法
Q3 Materials Science Pub Date : 2022-09-01 DOI: 10.5604/01.3001.0016.1394
M. Serediuk
To improve the technologies of different oil types of sequential pumping through the pipeline by establishing the laws of changing the throughput and energy efficiency of the oil pipeline operator in the process of pumping and displacing oil batches. The identified regularities would contribute to more effective management of the mixture realisation process at the end of the oil pipeline and reliable forecasting of the results of the different oil types of mixture formation.Carrying out theoretical studies and applying mathematical modelling methods in order to establish the regularities of hy-drodynamic processes during the injection into the oil pipeline and the displacement of oil different grades from it.The regularities of changes in oil pipeline capacity and specific electricity costs for transportation as a function of the coordinates of different oil types of batches contacts and the time of sequential pumping cycle implementation they have been established.The next stage of the research is to establish the influence of the hydrodynamic processes features on the intensity of the oil different grades mixture formation in the process of their successive pumping in the oil pipeline.A method and software have been developed that make it possible to predict the throughput and energy efficiency of oil pipeline operation for each moment of the sequential pumping cycle of small batches of different grade oil. The application of the method for the conditions of an operating oil pipeline proved that during the cycle of four types of sequential oil pumping, the change in throughput exceeds 20%, and the change in energy consumption exceeds 10%.The originality of the method consists in taking into account the regularities of the hydrodynamic process of the movement of several batches of oil of different grades in the pipeline, the features of the profile of the pipeline route and the physical properties of the liquid that fills the cavity of the pumps.
通过建立输油管道操作员在泵送和置换石油批次过程中的吞吐量和能效变化规律,改进不同石油类型的管道顺序泵送技术。确定的规律将有助于更有效地管理输油管道末端的混合物实现过程,并可靠地预测不同石油类型的混合物形成的结果。进行理论研究并应用数学建模方法,以建立输油管道注入和不同等级石油排出过程中的流体动力学过程的规律。输油管道容量和运输用电成本的变化规律是不同石油类型坐标的函数批量接触的时间以及它们已经建立的顺序泵送循环实施的时间。下一阶段的研究是确定不同等级的油在输油管道中连续泵送过程中的流体动力学过程特征对其形成强度的影响。已经开发了一种方法和软件,可以预测小批量不同等级石油的顺序泵送循环的每个时刻的输油管道操作的吞吐量和能源效率。该方法在输油管道运行工况下的应用证明,在四种顺序抽油方式的循环过程中,产量变化超过20%,能耗变化超过10%。该方法的独创性在于考虑了不同等级的几批油在管道中运动的流体动力学过程的规律、管道路线的剖面特征以及填充泵腔的液体的物理特性。
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引用次数: 0
Effect of fibre laser welding parameters on the microstructure and weld geometry of commercially pure titanium 光纤激光焊接参数对工业纯钛显微组织和焊缝几何形状的影响
Q3 Materials Science Pub Date : 2022-09-01 DOI: 10.5604/01.3001.0016.1395
M. Abdulridha, A. Jilabi
The primary purpose of the study was the metallurgical characterization of laser welds. The weldability of commercial production of pure titanium and titanium alloy (CP-Ti) has also been examined.In this research, the laser fibre method was used to weld sheets of pure titanium, and then microscopy and scanning electron microscopy were used to study the changes in the microstructure, the depth of weld penetration and the width of the weld area with changing welding parameters.The results proved that increasing the laser power significantly increases the depth of weld penetration and weld width. When the heat input is increased, the shape of the weld pool changes from a V shape to an hourglass shape. It was also observed that the depth of the crater formed increases with the increase in the laser power due to the increase in the melting and evaporation of the weld metal. Increasing the welding speed also has a negative impact on the weld geometry because it reduces the heat input and absorption of laser energy by the weld metal and thus reduces the melting of the metal. The microstructure of the fusion zone consists of acicular α. Fine grains formed in the weld centre at low heat input; the granules became columnar-like. Since commercially pure titanium contains a small amount of beta-phase stabilizers, the cooling rate is extremely high for martensite to occur.In the future, it is recommended to study the effect of changing welding parameters on the mechanical properties of pure titanium because of its great importance in industrial and medical applications.Studying the effect of changing laser power and welding speed on the metallurgical properties of pure titanium, and consequently its effect on the mechanical properties of welds.
本研究的主要目的是对激光焊接的冶金特性进行研究。还对纯钛和钛合金(CP-Ti)商业生产的可焊性进行了检验。本研究采用激光纤维法对纯钛板材进行焊接,然后利用显微镜和扫描电子显微镜研究了焊接参数变化对组织、焊透深度和焊区宽度的影响。结果表明,提高激光功率可显著增加焊缝熔深和焊缝宽度。当热输入增加时,熔池的形状从V形变为沙漏形。还观察到,由于焊接金属的熔化和蒸发的增加,形成的凹坑的深度随着激光功率的增加而增加。增加焊接速度也会对焊接几何形状产生负面影响,因为它减少了焊接金属的热输入和激光能量的吸收,从而减少了金属的熔化。熔合区的微观结构由针状α组成。在低热输入时,焊缝中心形成细小晶粒;颗粒呈柱状。由于商业纯钛含有少量的β相稳定剂,因此冷却速率对于马氏体的发生是非常高的。由于纯钛在工业和医疗应用中具有重要意义,建议今后研究改变焊接参数对纯钛力学性能的影响。研究了改变激光功率和焊接速度对纯钛冶金性能的影响,以及对焊缝力学性能的影响。
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引用次数: 2
Stability analysis of hybrid Al2O3-TiO2 nano-cutting fluids Al2O3-TiO2纳米复合切削液的稳定性分析
Q3 Materials Science Pub Date : 2022-09-01 DOI: 10.5604/01.3001.0016.1392
A. Arifuddin, A. Redhwan, A. M. Syafiq, S. Z. Zainal Ariffin, A. Aminullah, W. Azmi
This paper is to study the stability of the current combination of hybrid nano-cutting fluids due to the recent progress in the analysis of nano-cutting fluids, such as the assessment methods for the stability of nano-cutting fluids, have revealed that instability is a common problem associated with nano cutting fluids.Five samples of 0.001 vol% that are suitable to be tested at UV-Vis machine, Al2O3–TiO2 hybrid nano-cutting fluid was prepared using a one-step process with the help of a magnetic stirrer to stir for 30 minutes with different sonication time to determine the best or optimum sonication time for this hybrid nano-cutting fluid. Stability of nano-cutting fluids was analyses using UV–Vis spectrophotometer (0.001%, 0.0001%, 0.00001%), visual sedimentation (1%, 2%, 3%, 4%), TEM photograph capturing techniques (2%) and zeta potential analysis (0.001%, 0.00001%), that used different volume concentration that is suitable for each type of stability analysis.The stability analysis reveals that the best sonication time is 90 minutes, and the UV-vis spectrophotometer shows the stability of all samples is above 80% during a month compared to the initial value. Further, visual sedimentation shows good stability with minimum sedimentation and colour separation only. The zeta potential value also shows great stability with a value of 37.6 mV. It is found that the hybrid nano-cutting fluid is stable for more than a month when the nano is suspended in the base fluid of conventional coolant.The result in this paper is based on the experimental study of Al2O3-TiO2/CNC coolant base hybrid nano-cutting fluid for a month. However, to further validate the results presented in this paper, it is recommended to prolong the stability assessment time for six months for longer shelf life.The finding of this experimental study can be useful for high-precision product machining using similar CNC coolants, especially for aircraft and airspace applications for machining parts.No thorough stability assessment using all four types of stability analysis is done on Al2O3-TiO2/CNC Coolant base hybrid nano cutting fluid.
由于近年来对纳米切削液的分析进展,如纳米切削液稳定性的评价方法,揭示了纳米切削液的不稳定性是纳米切削液的一个普遍问题,因此本文将研究当前混合纳米切削液组合的稳定性。在磁力搅拌器的帮助下,采用一步法制备了5个体积为0.001 %的适合紫外可见机测试的Al2O3-TiO2杂化纳米切削液,在不同的超声时间下搅拌30分钟,以确定该杂化纳米切削液的最佳或最佳超声时间。采用紫外-可见分光光度计(0.001%、0.0001%、0.00001%)、目视沉降(1%、2%、3%、4%)、透射电镜(2%)和ζ电位(0.001%、0.00001%)分析纳米切削液的稳定性,采用不同的体积浓度进行不同类型的稳定性分析。稳定性分析表明,最佳超声时间为90分钟,紫外-可见分光光度计显示,与初始值相比,所有样品在一个月内的稳定性均在80%以上。此外,视觉沉降表现出良好的稳定性,只有最小的沉降和颜色分离。zeta电位值也表现出很强的稳定性,为37.6 mV。研究发现,当纳米悬浮在常规冷却液的基液中时,混合纳米切削液的稳定性超过一个月。本文的研究结果是在对Al2O3-TiO2/CNC冷却剂基复合纳米切削液进行为期一个月的实验研究的基础上得出的。然而,为了进一步验证本文的结果,建议将稳定性评估时间延长6个月,以延长保质期。这项实验研究的发现可以为使用类似CNC冷却剂的高精度产品加工,特别是飞机和空域应用的加工零件提供帮助。对Al2O3-TiO2/CNC冷却剂基混合纳米切削液进行了四种类型的稳定性分析,但没有进行全面的稳定性评估。
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引用次数: 0
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Archives of materials science and engineering
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