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Performance of an integrated household greywater treatment system for water optimization and reuse 优化和回用水综合家庭中水处理系统的性能
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-30 DOI: 10.1007/s13201-024-02303-2
Khalid Hassan, Abdulaziz Alzahrani, Nahaa M. Alotaibi, Mohamed Helmy

This study evaluated the efficiency of an on-site household greywater treatment system for indirect human reuse and for domestic lawn irrigation. This helps in the reduction in the disparity between water demand and supply that is facing the rapidly increasing global populace. Natural household greywater was settled and then conventionally filtered by using two types of non-woven geotextile media; thermally bonded and needle punched. A third woven cotton textile media was also experimented and all the non-woven geotextile media were tested in single and double layers and combined with the woven cotton textile layer. The different filter media configurations were tested for a period of one year operation (six runs) with two filtration rates of 15.00 and 25.00 m3/m2/day for each run. For all runs, the final treated effluent was disinfected using calcium hypochlorite prior to reuse. The double layer needle punched non-woven geotextile media together with the woven cotton textile media gave the best removal efficiencies; 96.34 ± 1.85% for turbidity 81.87 ± 6.43% for BOD5, 97.49 ± 1.68% for TSS, 75.35 ± 3.99% for CODt, 99.59% for E.coli. The soluble CODs removal efficiencies were negligible (below 3%) in the first four runs with non-woven geotextile media and increased to 28.05 ± 4.29% when the woven cotton textile media was added. In general, the system was found to save about 63% of the daily water consumption reflecting a net 22.50% reduction in the daily water billing costs for the whole household.

这项研究评估了现场家庭灰水处理系统用于人类间接回用和家庭草坪灌溉的效率。这有助于减少迅速增长的全球人口所面临的水资源供需矛盾。天然家庭灰水经过沉淀后,使用两种类型的无纺土工织物介质(热粘合和针刺)进行传统过滤。此外,还试验了第三种有纺棉织物介质,并对所有无纺土工织物介质进行了单层和双层测试,以及与有纺棉织物层的组合测试。对不同的过滤介质配置进行了为期一年的运行测试(六次运行),每次运行的过滤率分别为 15.00 和 25.00 立方米/平方米/天。在所有运行中,最终处理过的污水在回用前都使用次氯酸钙进行了消毒。双层针刺无纺土工织物滤料和有纺棉织物滤料的去除率最高:浊度 96.34 ± 1.85%,BOD5 81.87 ± 6.43%,TSS 97.49 ± 1.68%,CODt 75.35 ± 3.99%,大肠杆菌 99.59%。在使用无纺土工织物介质的前四次运行中,可溶性 CODs 去除率可忽略不计(低于 3%),而在加入有纺棉织物介质后,可溶性 CODs 去除率增至 28.05 ± 4.29%。总体而言,该系统节省了约 63% 的日常用水量,反映出整个家庭的日常水费成本净减少了 22.50%。
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引用次数: 0
Classification of risk levels for snow damage estimation considering socioeconomic factors in South Korea 考虑韩国社会经济因素的雪灾估算风险等级划分
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-25 DOI: 10.1007/s13201-024-02297-x
Hyeongjoo Lee, Donghyun Kim, Gunhui Chung

In South Korea, the snowy season spans from October to April, and the annual average snowfall varies significantly depending on specific regions, latitudes, and elevations, ranging from 0 to 260 cm. The average annual snowfall in South Korea is 25.1 cm. Despite of the relatively shallow snowfall depth, over the past decade, South Korea has experienced approximately 120 million dollars in damages attributed to snow-related incidents. In this study, the DPSIR (Driver-Pressure-State-Impact-Response) framework was employed to consider the meteorological and socioeconomic factors to calculate the snow damage vulnerability. A total of 17 indicators were taken into account to comprehend meteorological conditions, socioeconomic factors, and historical damage records from 1994 to 2020. However, due to the limited availability of meteorological observatories and changes in greenhouse design standards, accurately estimating the snow damage amount poses challenges. Therefore, based on the vulnerability, the risk levels were classified into four categories and estimated snow damage generated by the categorized models was compared with those of the model constructed using the entire dataset. The categorized models offer improved estimation results, as the meteorological and socioeconomic characteristics within each category differ and should be addressed separately in modeling. Among the categorized models, the Green zone exhibited the best results, primarily because it did not include outlier snow damage incidents. The developed model in this study could be utilized to mitigate the impact of heavy snowfall and prioritize snow removal regions.

韩国的雪季从 10 月持续到次年 4 月,年平均降雪量因地区、纬度和海拔高度的不同而有很大差异,从 0 厘米到 260 厘米不等。韩国的年平均降雪量为 25.1 厘米。尽管降雪深度相对较浅,但在过去十年中,韩国因降雪相关事故造成的损失约为 1.2 亿美元。本研究采用 DPSIR(动因-压力-状态-影响-反应)框架,考虑气象和社会经济因素来计算雪灾脆弱性。共考虑了 17 项指标,包括气象条件、社会经济因素以及 1994 年至 2020 年的历史雪灾记录。然而,由于气象观测站的有限性和温室设计标准的变化,准确估算雪灾损失量面临挑战。因此,根据脆弱性将风险等级分为四类,并将分类模型生成的雪灾损失估计与使用整个数据集构建的模型进行比较。分类模型提供了更好的估算结果,因为每个类别中的气象和社会经济特征各不相同,在建模时应分别处理。在分类模型中,绿色区域的结果最好,主要是因为它不包括异常雪灾事件。本研究开发的模型可用于减轻强降雪的影响,并确定除雪区域的优先次序。
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引用次数: 0
Tectonic activation and the risk of Ilisu Dam collapse to Iraq through modelling and simulation using HEC-RAS 通过使用 HEC-RAS 进行建模和模拟,了解构造活动和伊利苏大坝溃坝对伊拉克造成的风险
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-24 DOI: 10.1007/s13201-024-02299-9
Ahmad Al-Gurairy, Mohamed S. Al-Jubory, Nadhir Al-Ansari, Salih Muhammad Awadh, Ali H. Al-Zubaidi, Muhammad T. Al-Sadun, Riyadh M. Al-Ghurairy

Floods caused by dam failures can cause huge losses of life and property, especially in estuarine areas and valleys. In spite of all the capabilities and great improvements reached by man in the construction of dams and their structures, they will remain helpless before the powerful forces of nature, especially those related to tectonic activation, and the occurrence of earthquakes of different intensities.

The region extending from the Ilisu Dam in Turkey to the Mosul Dam in Iraq was chosen as an area for this study, and the HEC-RAS application was used to simulate the collapse of the Ilisu Dam due to a major earthquake, to know the magnitude of the risks and losses that could result from this. The Ilisu Dam was built very close to a highly tectonically active fault system, particularly the East Anatolian Fault (EAF), which is one of the largest tectonically active faults in the world with a length of 500 km. This region has witnessed past and present earthquakes of high magnitude (M > 7), especially in the EAF, so the construction of the Ilisu Dam near the EAF fault system is of great concern, as it was built in a basin with very complex seismic activity and geology.

Using the HEC-RAS simulation application, the study found that the flood resulting from the collapse of the Ilisu Dam would reach the edges of the Mosul Dam Lake in just 13 h. With a flow of more than 100,000 m3/s, more than 10 billion m3 of water will flow into the Mosul Dam Lake within four days of the disaster. This will lead to the collapse of the Mosul Dam and direct the flood wave of the collapse of these dams towards Baghdad through Mosul, Tikrit, and Samarra. This could pose risks to all Iraqi cities located within the Iraqi sedimentary plain (Mesopotamia), from south of the Mosul Dam up to Basra, in a scenario similar to Noah’s Flood.

大坝垮塌引发的洪水会造成巨大的生命和财产损失,尤其是在河口地区和山谷。本研究选择了从土耳其的伊利苏大坝到伊拉克的摩苏尔大坝的区域作为研究区域,并使用 HEC-RAS 应用程序模拟了伊利苏大坝因大地震而垮塌的情况,以了解由此可能造成的风险和损失的严重程度。伊利苏大坝建在一个构造非常活跃的断层系统附近,特别是东安纳托利亚断层(EAF),它是世界上最大的构造活跃断层之一,长达 500 公里。该地区过去和现在都发生过震级很高(M > 7)的地震,尤其是在东安纳托利亚断层,因此在东安纳托利亚断层系统附近修建伊利苏大坝非常令人担忧,因为该大坝建在一个地震活动和地质情况非常复杂的盆地中。研究利用 HEC-RAS 模拟应用程序发现,伊利苏大坝溃坝导致的洪水将在短短 13 小时内到达摩苏尔大坝湖的边缘,流量超过 100,000 立方米/秒,灾难发生后四天内将有超过 100 亿立方米的水流入摩苏尔大坝湖。这将导致摩苏尔大坝坍塌,并将这些大坝坍塌的洪水波经摩苏尔、提克里特和萨迈拉冲向巴格达。这可能会给位于伊拉克沉积平原(美索不达米亚)的所有伊拉克城市带来风险,从摩苏尔大坝以南一直到巴士拉,情况类似于诺亚洪水。
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引用次数: 0
Spatial distribution and composition of benthic macro-invertebrate in upper Awash River, below and upper Ginchi town, West Shoa Zone, Ethiopia 埃塞俄比亚西肖亚区阿瓦什河上游 Ginchi 镇下方和上游底栖大型无脊椎动物的空间分布和组成
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-18 DOI: 10.1007/s13201-024-02302-3
Ayana Chimdo

The composition and distribution of macro-invertebrates of benthic species can be influenced by water quality. The primary objective of this study was to understand the spatial distribution and composition of macro-invertebrates of benthic nature in the upper Awash River below and above Ginchi Town. The study was carried out for a period of three months from February 2020 to April 2020, and macro-invertebrates samples were collected from three stations using Surber sampler with 500 (upmu)m/mesh size and 25 cm × 25 cm (0.0625 m2) of sampling area coverage. The present study showed that, in the study area, there was a low density of macro-invertebrates and species richness in general with a comparative difference between the pool riffle habitats in density and family richness. And the total abundance of benthic macro-invertebrates showed a positive correlation with NO3-N, dissolved oxygen, and total phosphorus, while a negative correlation with all the other physicochemical parameters measured during the study period. Spatial and monthly variations in the diversity and richness of benthic macro-invertebrates were attributed to the effects of human action and changes in environmental factors. So, the water shade management system should be applied to control pollution factors that can affect the macro-benthic fauna community.

底栖大型无脊椎动物的组成和分布会受到水质的影响。本研究的主要目的是了解阿瓦什河上游金奇镇以下和以上地区的大型底栖无脊椎动物的空间分布和组成。研究从 2020 年 2 月至 2020 年 4 月进行,为期 3 个月,使用 Surber 采样器从 3 个站点采集大型无脊椎动物样本,采样器规格为 500 (upmu)m /目,采样区域覆盖率为 25 cm × 25 cm (0.0625 m2)。本研究表明,在研究区域内,大型无脊椎动物的密度和物种丰富度总体较低,池堑生境之间在密度和科属丰富度方面存在比较差异。底栖大型无脊椎动物的总丰度与 NO3-N、溶解氧和总磷呈正相关,而与研究期间测量的所有其他理化参数呈负相关。底栖大型无脊椎动物多样性和丰富度的空间和月度变化归因于人类活动和环境因素变化的影响。因此,应采用水荫管理系统来控制可能影响大型底栖动物群落的污染因素。
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引用次数: 0
Multi-objective simulation–optimization for water resources management and uses in multi-dam systems in low-water regions 低水位地区多坝系统水资源管理和利用的多目标模拟优化
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-17 DOI: 10.1007/s13201-024-02296-y
Moslem Najafi, Mohsen Najarchi, Seyed Mohammad Mirhosseini

One of the challenging issues in surface water resources management is the optimal operation of multi-dam systems. In addition to the applicability in determining the optimal pattern of operation of existing dams, this approach can be implemented in specifying the optimal capacity of under design dams. In this research, the simulation–optimization technique is used along with the reservoir zoning method in order to specify the optimal role curve of each of the dams in a multi-dam system (i.e., the Marun and Jarreh dams) in monthly intervals. The objective of this study is to develop a multi-objective algorithm on the basis of the zoning of reservoirs for the optimal operation of multi-dam systems. In this technique, instead of increasing the reliability of supplying demands in the whole period regardless the dry months, some of the inflow of rainy periods is stored in dam reservoirs to be consumed in dry months in order to mitigate the severity of deficiency. To examine the efficiency of the proposed model, the results obtained from the system operation in the current conditions are compared under two scenarios including optimal and reference. In the reference scenario, during 30-years, in some dry and low-water years, especially in the last six years of planning, the percentage of the demand supply is zero or less than five percent in several consecutive months. After optimizing the system, the minimum supply percentage in critical and dry months reaches 30 to 60 percent. Also, in the optimization scenario, the percentage of downstream ecological demands is improved. This research indicates that using the solution of this research leads to the better management of reservoirs in multi-dam systems and reduces the severity of deficiency in supplying various uses in low-water months.

地表水资源管理的挑战之一是多坝系统的优化运行。这种方法除了适用于确定现有大坝的最佳运行模式外,还可用于确定设计中大坝的最佳库容。在本研究中,模拟优化技术与水库分区方法一起使用,以确定多坝系统(即马伦大坝和贾雷大坝)中每个大坝每月的最佳作用曲线。本研究的目的是在水库分区的基础上开发一种多目标算法,以优化多坝系统的运行。在这一技术中,不考虑旱季,而是将雨季的部分流入量储存在大坝水库中,在旱季消耗,以减轻缺水的严重程度,从而提高整个时期的需求供应可靠性。为了考察所提模型的效率,我们对当前条件下的系统运行结果进行了比较,包括最佳和参考两种方案。在参考方案中,30 年间,在一些枯水和少水年份,尤其是规划的最后六年,连续几个月的供需百分比为零或小于 5%。系统优化后,关键月份和枯水月份的最低供应比例达到 30%至 60%。同时,在优化方案中,下游生态需求的比例也有所提高。这项研究表明,使用本研究的解决方案可以更好地管理多坝系统中的水库,并降低枯水期各种用途供水不足的严重程度。
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引用次数: 0
Geospatial analysis and AHP for flood risk mapping in Quetta, Pakistan: a tool for disaster management and mitigation 绘制巴基斯坦奎达洪水风险图的地理空间分析和 AHP:灾害管理和减灾工具
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-15 DOI: 10.1007/s13201-024-02293-1
Niamat Ullah, Aqil Tariq, Said Qasim, Sanaullah Panezai, Md. Galal Uddin, M. Abdullah-Al-Wadud, Sajid Ullah

The 2022 flood events in Quetta, Pakistan, caused severe damage to the economy, properties, and lives. Therefore, flood risk mapping to identify flood-prone areas is essential for planners and decision-makers to take critical protective measures to control the effects of flooding. This study focuses on mapping flood-prone regions in the Quetta district of Pakistan using an analytical hierarchy process (AHP) and a geographic information system (GIS). The factors influencing flood used in the present study were topographic witness index (TWI), elevation, slope, land use, land cover, precipitation, stream distance, drainage density, and soil type. Weights and ranks were allocated separately to all factors through AHP and were interpreted in a GIS environment. The produced flood hazard model of the study area depicted four zones. These zones ranged from low (19.49%), moderate (43.34%), high (28.30%), to very high (8.87%). The model was further validated through previous flood events in the study area. Around 90% of flood hazard events in the past took place mainly in the produced model's very high and high zones, which is why the current model is reliable. Finally, integrating geospatial approaches with AHP in flood hazard mapping is a quick, reliable, and affordable method that may be utilized in the area.

2022 年巴基斯坦奎达发生的洪灾给经济、财产和生命造成了严重破坏。因此,绘制洪水风险图以确定洪水易发地区,对于规划者和决策者采取关键保护措施以控制洪水影响至关重要。本研究的重点是利用层次分析法(AHP)和地理信息系统(GIS)绘制巴基斯坦奎达地区的洪水易发区地图。本研究采用的洪水影响因素包括地形见证指数 (TWI)、海拔、坡度、土地利用、土地覆盖、降水、溪流距离、排水密度和土壤类型。通过 AHP 分别为所有因素分配权重和等级,并在 GIS 环境中进行解释。研究区域的洪水危害模型分为四个区域。这些区域从低度(19.49%)、中度(43.34%)、高度(28.30%)到极高度(8.87%)不等。该模型通过研究区域以往的洪水事件得到了进一步验证。过去约 90% 的洪水灾害事件主要发生在所生成模型的极高区和高区,这也是当前模型可靠的原因。最后,将地理空间方法与 AHP 结合用于洪水灾害绘图是一种快速、可靠且经济实惠的方法,可用于该地区。
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引用次数: 0
Reservoir-based flood forecasting and warning: deep learning versus machine learning 基于水库的洪水预报和预警:深度学习与机器学习
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-15 DOI: 10.1007/s13201-024-02298-w
Sooyeon Yi, Jaeeung Yi

In response to increasing flood risks driven by the climate crisis, urban areas require advanced forecasting and informed decision-making to support sustainable development. This study seeks to improve the reliability of reservoir-based flood forecasting and ensure adequate lead time for effective response measures. The main objectives are to predict hourly downstream flood discharge at a reference point, compare discharge predictions from a single reservoir with a four-hour lead time against those from three reservoirs with a seven-hour lead time, and evaluate the accuracy of data-driven approaches. The study takes place in the Han River Basin, located in Seoul, South Korea. Approaches include two non-deep learning (NDL) (random forest (RF), support vector regression (SVR)) and two deep learning (DL) (long short-term memory (LSTM), gated recurrent unit (GRU)). Scenario 1 incorporates data from three reservoirs, while Scenario 2 focuses solely on Paldang reservoir. Results show that RF performed 4.03% (in R2) better than SVR, while GRU performed 4.69% (in R2) better than LSTM in Scenario 1. In Scenario 2, none of the models showed any outstanding performance. Based on these findings, we propose a two-step reservoir-based approach: Initial predictions should utilize models for three upstream reservoirs with long lead time, while closer to the event, the model should focus on a single reservoir with more accurate prediction. This work stands as a significant contribution, making accurate and well-timed predictions for the local administrations to issue flood warnings and execute evacuations to mitigate flood damage and casualties in urban areas.

为应对气候危机导致的日益增加的洪水风险,城市地区需要先进的预报和明智的决策,以支持可持续发展。本研究旨在提高基于水库的洪水预报的可靠性,确保有足够的准备时间采取有效的应对措施。主要目标是预测参考点的每小时下游泄洪量,比较一座水库在 4 小时准备时间内的泄洪预测与三座水库在 7 小时准备时间内的泄洪预测,并评估数据驱动方法的准确性。研究地点位于韩国首尔的汉江流域。方法包括两种非深度学习 (NDL)(随机森林 (RF)、支持向量回归 (SVR))和两种深度学习 (DL)(长短期记忆 (LSTM)、门控递归单元 (GRU))。方案 1 结合了三个水库的数据,而方案 2 则只关注帕尔当水库。结果表明,在情景 1 中,RF 的性能(R2)比 SVR 高 4.03%,而 GRU 的性能(R2)比 LSTM 高 4.69%。在情景 2 中,没有一个模型表现出突出的性能。基于这些发现,我们提出了一种基于水库的两步法:最初的预测应利用三个上游水库的模型,提前期较长,而在临近事件发生时,模型应专注于单个水库,预测更准确。这项工作是一项重大贡献,为地方政府发布洪水预警和实施疏散提供了准确及时的预测,从而减轻了洪水对城市地区造成的破坏和人员伤亡。
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引用次数: 0
Development of a water resources utilization model and optimization of the patterns of rice genotypes with system dynamics approach 利用系统动力学方法开发水资源利用模型和优化水稻基因型模式
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-14 DOI: 10.1007/s13201-024-02295-z
Meysam Motahari, Abbas Sotoodehnia, Bijan Nazari, Mohamadreza Yazdani

The system dynamics approach was conducted to optimize genotype patterns in various climatic and water availability scenarios, to address the water productivity improvement of the Sefidrood irrigation network. The studied cropping pattern scenarios were SD1 (the continuation of current trends), SD2 (the reduction in the cultivated area), SD3 (replacing modified crops on an annual basis), and SD4 (increasing the annual cultivated area of Hashemi type rice). Moreover, the impacts of irrigation efficiency improvements and water resources management strategies on the physical and economic water productivity indices were studied. The results indicated that the SD3 scenario has the most positive impact on water productivity with 0.45 kg/m3 increases. However, a questionnaire survey revealed that this scenario that belongs to the increase in the modified genotype area cannot be recommended due to cooking quality and low prices. The Hashemi genotype was the favorite rice among farmers and experts. Also, analyzing the irrigation efficiency improvement scenario showed that this strategy has a limited impact on the physical and economic water productivity. Increasing the capacity of local rainwater storage pools, Ab-bandans, and increasing the drainage water reuse had the highest water productivity in the condition of river water reduction and uncertain water availability.

采用系统动力学方法优化了各种气候和水供应情况下的基因型模式,以提高 Sefidrood 灌溉网的水生产力。所研究的种植模式情景包括 SD1(保持当前趋势)、SD2(减少种植面积)、SD3(每年替换改良作物)和 SD4(增加哈希米型水稻的年种植面积)。此外,还研究了提高灌溉效率和水资源管理策略对物理和经济水资源生产力指数的影响。结果表明,SD3 方案对水生产率的影响最为积极,增加了 0.45 千克/立方米。然而,问卷调查显示,由于烹饪质量和价格较低,这种属于增加改良基因型面积的方案不值得推荐。哈希米基因型是农民和专家最喜欢的稻米。此外,对提高灌溉效率方案的分析表明,该战略对物理和经济水生产力的影响有限。在河水减少和可用水量不确定的情况下,增加当地雨水储存池(Ab-bandans)的容量和提高排水回用率的用水生产率最高。
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引用次数: 0
Assessment of biocidal efficacy of zinc oxide-zeolite nanocomposites as a novel water disinfectant against commercial disinfectants used in water purification 评估氧化锌-沸石纳米复合材料作为新型水消毒剂对用于水净化的商用消毒剂的杀菌效果
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-10 DOI: 10.1007/s13201-024-02266-4
Manar Bahaa El Din Mohamed, Fatma I. Abo El Ela, Rehab Mahmoud, Ahmed A. Farghali, Sarah I. Othman, Ahmed A. Allam, Sahar Abdel Aziz Abdel Aleem

Water microbial contamination is a serious issue that poses a risk to both animal and human health. One hundred and twenty water were samples collected from main water source and drinkers from a poultry farm. Different bacterial pathogens were isolated from water sources. Escherichia (E.) coli, Pseudomonas (P.) aureoginosa, (Salmonella) Salmonella (s). Typhimurim, Aeromonas (A.) hydrophila at different percentages. Variable degree of bacterial resistance to some commercial disinfectants commonly used to disinfect water system (iodine, terminator and H2O2). Nanoparticles were used to control bacteria in water. About the safety investigation for the prepared nanomaterials, the work results demonstrated that zinc oxide (ZnO) nanoparticles (NPs) exhibit the highest safety profile among the manufactured materials. The median fatal dose (LD50) for ZnO NPs was determined to be 3709 mg/kg body weight. In comparison, the LD50 values for zeolites and nanocomposites were 3251 mg/kg and 2658 mg/kg, respectively. Therapeutic dosages were estimated based on the LD50. Zeolite NPs, ZnO NPs and ZnO/zeolite NPs showing promising results in control of those bacteria. It was concluded that the escalating resistance of bacteria to disinfectants have led to a need to find alternative such as nanoparticles that proved promising results in control of pathogens, particularly it showed a safe effect on laboratory animals.

水微生物污染是一个严重问题,对动物和人类健康都构成威胁。我们从一个家禽养殖场的主要水源和饮水器中采集了 120 个水样。从水源中分离出了不同的细菌病原体。大肠杆菌(E. coli)、金黄色假单胞菌(P. aureoginosa)、沙门氏菌(Salmonella)。Typhimurim、嗜水气单胞菌(A. hydrophila)的不同比例。细菌对一些常用于水系统消毒的商用消毒剂(碘、终结者和 H2O2)的耐药性程度各不相同。利用纳米粒子控制水中的细菌。关于所制备纳米材料的安全性调查,研究结果表明,氧化锌(ZnO)纳米粒子(NPs)是所制备材料中安全性最高的。经测定,氧化锌纳米粒子的中位致死剂量(LD50)为每千克体重 3709 毫克。相比之下,沸石和纳米复合材料的半数致死剂量分别为 3251 毫克/千克和 2658 毫克/千克。治疗剂量是根据半数致死剂量估算的。沸石氮氧化物、氧化锌氮氧化物和氧化锌/沸石氮氧化物在控制这些细菌方面显示出良好的效果。结论是,由于细菌对消毒剂的抗药性不断增强,因此需要寻找替代品,如纳米粒子,这种粒子在控制病原体方面具有良好效果,尤其是对实验动物具有安全作用。
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引用次数: 0
Clays-based geopolymers: a sustainable application as adsorbent of cytostatic drugs for water purification 粘土基土工聚合物:作为细胞抑制药物吸附剂在水净化中的可持续应用
IF 5.7 3区 环境科学与生态学 Q1 WATER RESOURCES Pub Date : 2024-10-10 DOI: 10.1007/s13201-024-02273-5
Assia Ben Amor, Marina Arenas, Julia Martín, Abdelkader Ouakouak, Juan Luis Santos, Irene Aparicio, Esteban Alonso, Noureddine Hamdi

The administration of cytostatic drugs in chemotherapy is steadily increasing, triggering thus a risk to the environment. Identifying powerful ways to effectively remove these hazardous pollutants from hospital and effluent wastewater before they discharge into the aquatic environment remains a critical and challenging task. Adsorption is among the most effective ways to treat contaminated water due to the wide availability and selectivity of the adsorbents besides the simplicity and the low start-up costs of the technique. In this work, a geopolymer, elaborated from an illito-kaolinitic clay (Douiret region of Tunisia) and industrial waste (silica fume and phosphogypsum), has been tested as promising decontamination of the cytostatic drugs paclitaxel (PCX) and irinotecan (IRI) from water samples. The foamed geopolymer was characterized using X-ray diffraction, Fourier transform infrared, scanning electron microscopy and thermogravimetric analysis before and after adsorption. Adsorption batch assays were performed using different concentrations of PCX and IRI, contact times and environmental conditions. The geopolymer had an excellent removal efficiency (almost 100% for PCX and 89% for IRI) using 20 mg of adsorbent and 2.5 mg/L of each drug concentration. The characterization results showed that cytostatic drugs were adsorbed to the geopolymer through physical interactions, pore filling, electrostatic attraction and hydrogen bonding. The specific surface area and pore volume of the geopolymer were 82.23 m2/g and 0.19 cm3/g, respectively. In addition to its cost-effective properties, the geopolymer demonstrated excellent efficiency in contaminated natural samples (including influent, effluent wastewater and surface water) denoting a great application for water purification.

化疗中细胞抑制药物的用量正在稳步增加,从而引发了对环境的风险。在这些有害污染物排入水生环境之前,找到有效去除医院废水和污水中这些有害污染物的有力方法,仍然是一项关键而又具有挑战性的任务。吸附是处理受污染水体的最有效方法之一,这是因为吸附剂的广泛可用性和选择性,以及该技术的简单性和低启动成本。在这项工作中,对一种由伊利托-高岭土(突尼斯 Douiret 地区)和工业废料(硅灰和磷石膏)制成的土工聚合物进行了测试,结果表明这种土工聚合物有望净化水样中的细胞抑制药物紫杉醇(PCX)和伊立替康(IRI)。在吸附前后,使用 X 射线衍射、傅立叶变换红外线、扫描电子显微镜和热重分析对发泡土工聚合物进行了表征。利用不同浓度的 PCX 和 IRI、接触时间和环境条件进行了吸附批量试验。在使用 20 毫克吸附剂和每种药物浓度为 2.5 毫克/升的情况下,土工聚合物具有极佳的去除率(对 PCX 的去除率接近 100%,对 IRI 的去除率为 89%)。表征结果表明,细胞抑制药物是通过物理相互作用、孔隙填充、静电吸引和氢键作用吸附到土工聚合物上的。土工聚合物的比表面积和孔体积分别为 82.23 平方米/克和 0.19 立方厘米/克。除了具有成本效益的特性外,该土工聚合物在污染的天然样品(包括进水、出水废水和地表水)中也表现出卓越的效率,在水净化方面有很大的应用前景。
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引用次数: 0
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Applied Water Science
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