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Photocatalytic Degradation of Pollutants by Using Highly Surface Pd Doped on ZnO/CdS Nanocomposite: As a Model of Water Treatment 高表面Pd掺杂ZnO/CdS纳米复合材料光催化降解污染物:水处理模型
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230068
Mithal N. Mohwes, Khawla K. Jassm, Ayad F. Alkaim
In the last few decades, more attention has been focussed on water treatment. In this study, an advanced catalyst Pd-doped ZnO-CdS nanocomposite was prepared using the photo deposition method. The structure and morphology of the obtained material were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), examining optical properties using UV-visible spectroscopy. Results of absorption show broader bands with moderated energy band gaps and improved photocatalytic properties. The photocatalytic applications show that the increase in amount of pd/ZnO-CdS nanocomposites up to 0.4 g/L increase the number of active site, but beyond 0.4 g/L there is little increase in % degradation. Therefore, the best catalyst at 0.4 g/L was used to remove BG dye. Photo catalytic activity increase was observed for Pd/ZnO-CdS nanocomposites which is about 86.6%. Photocatalytic degradation efficiency (PDE%) increases as the dye concentration decreases from 86.66% to 26.9 %. It was observed that the photo-catalytic degradation of BG dye was 86.6%–95.8% for the first four cycles. This indicates the good stability of ZnO-CdS/Pd nano-composites and could be potentially applied in the practical batch degradation.
在过去的几十年里,越来越多的注意力集中在水处理上。本研究采用光沉积法制备了一种先进的催化剂掺杂ZnO-CdS纳米复合材料。采用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、x射线衍射仪(XRD)对所得材料的结构和形貌进行了研究,并利用紫外可见光谱对所得材料的光学性能进行了检测。吸收结果显示出更宽的能带,带隙缓和,光催化性能得到改善。光催化应用表明,pd/ZnO-CdS纳米复合材料用量增加到0.4 g/L时,活性位点数量增加,但超过0.4 g/L时,降解率几乎没有增加。因此,采用0.4 g/L的催化剂去除BG染料效果最佳。Pd/ZnO-CdS纳米复合材料的光催化活性提高了86.6%。光催化降解效率(PDE%)随染料浓度从86.66%降低到26.9%而增加。结果表明,前4次循环对BG染料的光催化降解率为86.6% ~ 95.8%。这表明ZnO-CdS/Pd纳米复合材料具有良好的稳定性,具有应用于实际批量降解的潜力。
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引用次数: 0
Decarbonising of the Indian Cement Industry Through Alternative Fuels – Challenge of Transfer Chute Jamming 印度水泥工业用替代燃料脱碳——转移溜槽堵塞的挑战
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230067
Kapil Kukreja, Manoj Kumar Soni, Bibekananda Mohapatra, M.V. Ramachandra Rao
The Indian cement industry in COP27 highlighted its commitment to achieving net zero CO2 emission by 2070 made during COP26. The industry is moving towards decarbonisation and has identified various levers to achieve the goal. Fossil fuel replacement by Alternative Fuels (AFs) has been identified as one of the levers. Refused Derived Fuel (RDF), surplus biomass, industrial waste, and other societal wastes, etc., have emerged as potential AFs; however, their use comes with technical challenges like transfer chute jamming due to the wide range of variations in their properties. Jammed transfer chute leads to the breakdown of the entire transportation system and further fluctuation in AFs feeding to the kiln/calciner. Fluctuation in the feed rate of the AFs disturbs the fuel mix ratio (mix ratio of fossil fuel and AFs) and ultimately negatively impacts the process, operation, and quality of the produced cement. Transfer chute design is often overlooked, leading to build-up, blockage, and wear in chutes. Designing of transfer chute is more challenging when handling solid alternative fuels in cement plants, as the properties of these fuels have a wide range of variation where moisture may be as high up to 40%, bulk density may vary from 0.1 to 0.75 tonnes/m3, and particle size ranges from 1 to 100 mm, etc. This study covers a survey to establish which types of AFs, and their characteristics contribute to the chute jamming problem. The outcome of this study shall help the Indian cement industry to consider the appropriate inputs for transfer chute design and selection of the correct alternative fuels and their mix to avoid chute jamming.
印度水泥行业在COP27上强调了其在COP26期间做出的到2070年实现二氧化碳净零排放的承诺。该行业正朝着脱碳的方向发展,并已确定了实现这一目标的各种杠杆。替代燃料(AFs)替代化石燃料已被确定为杠杆之一。废弃衍生燃料(RDF)、剩余生物质、工业废物和其他社会废物等已成为潜在的AFs;然而,由于其性能的广泛变化,它们的使用带来了技术挑战,如转移滑槽干扰。堵塞的输送槽会导致整个输送系统的崩溃,并进一步影响输送到窑/煅烧炉的AFs的波动。AFs进料速率的波动会扰乱燃料混合比(化石燃料与AFs的混合比),最终对生产水泥的工艺、操作和质量产生负面影响。转移斜槽的设计经常被忽视,导致斜槽的堆积、堵塞和磨损。在水泥厂处理固体替代燃料时,设计转移槽更具挑战性,因为这些燃料的特性变化范围很大,水分可能高达40%,堆积密度可能在0.1至0.75吨/立方米之间变化,颗粒大小范围从1到100毫米不等,等等。本研究涵盖了一项调查,以确定哪些类型的AFs及其特性导致了溜槽干扰问题。这项研究的结果将有助于印度水泥行业考虑适当的转移溜槽设计和选择正确的替代燃料及其混合物,以避免溜槽堵塞。
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引用次数: 0
Lead and Cadmium (Pb, Cd) Levels Determination in the Blood of the Gasoline Station Workers 加油站工作人员血液中铅、镉(Pb、Cd)含量测定
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230066
Aamal Muhsen Kadhum, Ali S. Moalif, Noor Muhsen Jawad
The inhalation of hazardous fumes from lead containing gasoline in the workplace has become a major public health concern. These gases include extremely dangerous poisons that can induce aberrant changes in the functioning of a variety of essential organs. The current study aimed to estimate the concentration of blood lead level (BLLs) and blood cadmium level in male working gasoline station and compared with healthy people. An atomic absorption spectrophotometer (AAS) was used to measure cadmium and lead levels in the blood. The findings of this investigation revealed that there was significant increase in age (P-value = 0.002), mean age of worker station (32.0 ± 11.99) while in the control group (22.85 ± 2.18), the result of blood lead level shown (1.92 ±1.54) in gasoline station while in the control group (1.63 ±0.04) no significant differences was observed (P-value = 0.238). The main of blood cadmium level was 0.005 ±0.0069 in the gasoline station while in the control group (0.069 ±0.011) no significant differences were observed (P- value = 0.5), the smokers (n = 13) has (P > 0.426) mean BLL (21.60 ± 12.88 μg/dL), while non-smoking workers (n = 8) the BLL mean was 15.52 ± 6.80 μg/dL. The results also show that there is a correlation between age and blood lead level while no correlation was observed in blood cadmium level.
在工作场所吸入含铅汽油产生的有害烟雾已成为一个主要的公共卫生问题。这些气体包括极其危险的毒物,可以引起各种重要器官功能的异常变化。本研究旨在评估男性加油站工作人员血铅和血镉浓度,并与健康人进行比较。采用原子吸收分光光度计(AAS)测定血中镉和铅的含量。调查结果显示,年龄有显著增加(p值= 0.002),加油站平均年龄(32.0±11.99)高于对照组(22.85±2.18),加油站血铅水平(1.92±1.54)高于对照组(1.63±0.04),差异无统计学意义(p值= 0.238)。加油站人群血镉水平为0.005±0.0069,对照组为0.069±0.011,差异无统计学意义(P值= 0.5),吸烟人群(n = 13)有(P >0.426),平均BLL(21.60±12.88 μg/dL),而非吸烟工人(n = 8)的平均值为15.52±6.80 μg/dL。结果还表明,年龄与血铅水平存在相关性,而与血镉水平无相关性。
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引用次数: 0
Characterisation of Waste and Assessment of Surface Methane Emissions by Static Chamber Technique at a Major Dumping Site in Central India 印度中部一个主要倾倒场的废物特征和静态室技术对地表甲烷排放的评估
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230060
Tanmay Srivastava, Smita Dutta, M. Suresh Kumar
Given the vast amount and higher organic content of waste generated by developing nations such as India, as well as the challenges related to waste management and global warming, controlling methane emissions from such municipal solid waste (MSW) dumpsites becomes a major concern. As a result, studying the characteristics of solid waste dumped and the subsequent emissions of methane (CH4) from a site lacking proper disposal and gas emission management facilities, as is common in developing countries, becomes more important for suggesting appropriate corrective measures. In this study, MSW samples were collected from the Bhandewadi dumping site, a prominent site in Nagpur city and subjected to proximate, ultimate, and biochemical analysis. The results showed that the waste had high moisture content due to the tropical climate of the region which, together with the greater carbon content and organic matter (OM), may be responsible for increased overall greenhouse gas emissions. Biochemical study, on the other hand, revealed lower lignin content when compared with cellulose and hemicellulose, which are key contributors to CH4 emissions. The actual on site measurements using static chamber technique at fresh dumping sites showed that the methane (CH4) flux was between 1 and 14.3 mg m-2 sec-2 and 0.9 to 7.11 g m-3 day-2 at old dumping areas. The study contributes to a better understanding of the amount and unpredictability of methane produced by solid waste in an unmanaged dumping site.
考虑到印度等发展中国家产生的废物数量巨大,有机含量较高,以及与废物管理和全球变暖有关的挑战,控制这些城市固体废物(MSW)垃圾场的甲烷排放成为一个主要问题。因此,研究从缺乏适当处置和气体排放管理设施的场地倾倒的固体废物的特征以及随后的甲烷(CH4)排放(这种情况在发展中国家很常见),对于提出适当的纠正措施变得更加重要。在这项研究中,从那格浦尔市一个重要的垃圾场bhanddewadi垃圾场收集了生活垃圾样本,并对其进行了近似值、最终值和生化分析。结果表明,由于该地区的热带气候,废物具有较高的水分含量,加上较高的碳含量和有机质(OM),可能是温室气体总排放量增加的原因。另一方面,生物化学研究表明,与纤维素和半纤维素相比,木质素含量较低,而纤维素和半纤维素是CH4排放的主要贡献者。在新排土场采用静室技术进行的现场实测表明,甲烷(CH4)通量在1 ~ 14.3 mg m-2秒-2之间,在旧排土场为0.9 ~ 7.11 g m-3天-2之间。这项研究有助于更好地了解在一个无人管理的垃圾场中,固体废物产生的甲烷的数量和不可预测性。
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引用次数: 0
Crowbar Protection Scheme for Fault Ride Through in a Doubly-fed Induction Generator 双馈感应发电机故障穿越的撬棍保护方案
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230063
Sarthak Seth, Kusum Tharani, Sandeep Banerjee, Chaitanya Chhabra, Anshika Verma, Mridul Bhatia
This study focusses on using a crowbar protection scheme to overcome the symmetrical voltage dips in a doubly fed induction generator (DFIG). The crowbar protection scheme is integrated into the wind energy conversion system of the DFIG. The implementation of this scheme provides automated fault ride-through during sudden transients which may otherwise lead to over current faults. The increased use of renewable sources for electricity generation leads to a reduction in pollution which directly benefits the environment. Sustained usage of renewable resources will be beneficial for the environment.
本研究的重点是利用撬棍保护方案来克服双馈感应发电机(DFIG)的对称电压降。将撬棍保护方案集成到DFIG的风能转换系统中。该方案的实现在突然瞬变期间提供自动故障穿越,否则可能导致过电流故障。增加使用可再生能源发电导致污染的减少,这直接有利于环境。持续使用可再生资源对环境有益。
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引用次数: 0
Experimental Study and Process Optimisation for Fabrication of Circular Sheet Made from Waste PP/HDPE via Extrusion and Hydraulic Press 废PP/HDPE挤压-液压机制圆片的实验研究及工艺优化
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230065
Ritu Chaudhary, Sushant Upadhyaya, Vikas Kumar Sangal
Plastic waste is a well-known hazard to the ecosystem due to which many countries are exploring ways to mitigate this polymer from the environment. Various plastic wastes are generated after end use in the form of plastic bottles, plastic bags, bottle caps, straw, plastic cups, etc. These are generally made up of HDPE, LPDE, PP, PET, PS, etc. Therefore, this study focusses to utilise this wastage to make some value-added products. In this context, waste plastic bottles and containers made up of polypropylene and high-density polyethylene were targeted and shredded into small pieces ranging from 1.4 to 2 mm and mixed with additives in the extruder and hydraulic press to make circular sheets that can be used for electrical purposes. During the study, the effect of various process parameters on fabricated circular sheet properties such as tensile strength, melt flow index (MFI), and thermal conductivity were investigated. The developed non-linear theoretical models were found to be in good agreement with the experimental data. The gradient descent method is applied in BBD for estimating the optimum condition for fabricating a circular sheet. Under optimum conditions, the tensile strength and thermal conductivity were found to be 1535 MPa and 0.0312 W/mK, respectively, for the HDPE circular sheet using extrusion. The tensile strength, MFI, and thermal conductivity were determined using a Universal testing machine, melt flow tester (ASTM D1238), and Thermal constant analyser based on ASTM D1350.
众所周知,塑料垃圾对生态系统是一种危害,因此许多国家正在探索如何从环境中减少这种聚合物。最终使用后会产生各种塑料废物,包括塑料瓶、塑料袋、瓶盖、吸管、塑料杯等。这些通常由HDPE, lde, PP, PET, PS等组成。因此,本研究的重点是利用这种浪费来制造一些增值产品。在这种情况下,由聚丙烯和高密度聚乙烯制成的废弃塑料瓶和容器成为目标,并被粉碎成1.4至2毫米的小块,并在挤出机和液压机中与添加剂混合,制成可用于电气目的的圆形薄片。在研究过程中,考察了不同工艺参数对圆形板材抗拉强度、熔体流动指数(MFI)和导热系数等性能的影响。所建立的非线性理论模型与实验数据吻合较好。将梯度下降法应用于BBD中,估计了圆片加工的最佳条件。在最佳挤压条件下,HDPE圆形板材的拉伸强度和导热系数分别为1535 MPa和0.0312 W/mK。使用万能试验机、熔体流动测试仪(ASTM D1238)和基于ASTM D1350的热常数分析仪测定拉伸强度、MFI和导热系数。
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引用次数: 0
Interaction, Adhesion and Aggregation of Microplastic/Nanoplastic Particles: Effects of Plastic Polymer Type 微塑料/纳米塑料粒子的相互作用、粘附和聚集:塑料聚合物类型的影响
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230061
Azizul Hakim, Ferdouse Zaman Tanu, Sabrina Sharmeen Alam
Microplastics (MP; <5 mm) and nanoplastics (NP; <1000 nm) are now ubiquitous in nature as they have been released into inland water, lakes, rivers, and marine water through direct discharge, runoff from upland watersheds, and other terrestrial environments. To understand the aggregation of MP and NP in the last decade, surveys and analytical efforts were undertaken. The MP and NP particles in the soil and water environments interact with other natural and engineered nanoparticles, which in turn form aggregates. These plastic particles could form homoaggregates and/or heteroaggregates depending on pH, ionic type, ionic valence, salt concentration, shape and size of the plastic particles, and the polymer type of MP. Differences in MP aggregation due to differences in plastic polymer type are not yet well documented. This review is conducted to investigate the effect of polymer type on the aggregation of MP and NP particles in the presence of various aggregation conditions.
塑料微粒(议员;<5毫米)和纳米塑料(NP;现在在自然界中无处不在,因为它们已经通过直接排放、高地流域径流和其他陆地环境释放到内陆水域、湖泊、河流和海水中。为了了解过去十年中MP和NP的聚集情况,进行了调查和分析工作。土壤和水环境中的MP和NP颗粒与其他天然和工程纳米颗粒相互作用,进而形成聚集体。根据pH、离子类型、离子价、盐浓度、塑料颗粒的形状和大小以及MP的聚合物类型,这些塑料颗粒可以形成同质聚集体和/或异质聚集体。由于塑料聚合物类型的不同,MP聚集的差异尚未得到很好的证明。本文研究了不同聚合条件下聚合物类型对MP和NP粒子聚集的影响。
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引用次数: 0
The Transmission Effectiveness of the Dissolved Nutrients (N, P, Si) Through a South Mediterranean Estuary (Seybouse, Algeria) Under Large Anthropogenic Forcing 在大人为强迫下,溶解营养物(N, P, Si)通过南地中海河口(阿尔及利亚seyouse)的传输有效性
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230059
Omar Ramzi Ziouch, Tarek Daifallah, Houda Chenaker, Zoubir Moujari, Naouel Dali, Rabeh Zebsa
The Seybouse Estuary (SE) is the downstream of the second great river in Algeria draining one of the main country’s watersheds (6471 km2, 1.5 million inhabitants). This study highlights the effect of the estuarine part on the distribution and the flux of dissolved nitrogen (N), phosphorus (P) and silicon (Si) through the SE. Surface water sampling was taken and analysed in the dry (September 2016) and wet (April 2017) seasons. Physical parameters and water discharge data were jointly recorded in parallel to sampling dates. Very low flows varying between 0.3 and 4.7 m3 s-1 were recorded at the outlet in dry and wet seasons, respectively. The SE outlet waters were 2.6 and 10 folds higher than upstream in dissolved inorganic nitrogen (DIN) and phosphates (PO4) levels, respectively. However, the silicates (SiO4) levels decreased by about 1/2 in the outlet waters. In terms of flux, the SE delivered to the coast 84 t·yr-1, 9 t·yr-1 and 56 t·yr-1 of DIN, PO4 and SiO4, respectively. The high DIN:PO4 = 137 and low SiO4:DIN = 0.52 molar ratios classify SE as one of the strong anthropised estuaries. The estuarine part amply modifies cycles and budgets of riverine nutrients introduced to the coast.
塞舌尔河口(sehouse Estuary, SE)是阿尔及利亚第二大河流的下游,是阿尔及利亚主要的流域之一(6471平方公里,150万居民)。本研究重点研究了河口部分对SE中溶解态氮(N)、磷(P)和硅(Si)的分布和通量的影响。在干季(2016年9月)和湿季(2017年4月)采集地表水样本并进行分析。物理参数和水排放数据与采样日期并行记录。在干季和湿季,出口分别记录到0.3 ~ 4.7 m3 s-1的极低流量。东南方向出水溶解无机氮(DIN)和磷酸盐(PO4)含量分别比上游高2.6倍和10倍。而出水口的硅酸盐(SiO4)含量下降了约1/2。从通量来看,东南向海岸输送的DIN、PO4和SiO4分别为84 t·年-1、9 t·年-1和56 t·年-1。高的DIN:PO4 = 137和低的SiO4:DIN = 0.52的摩尔比使SE成为强烈人类活动的河口之一。河口部分充分地改变了流向海岸的河流养分的循环和平衡。
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引用次数: 0
Seasonal Variations in Chemical Composition and Source Apportionment of Fine Particulate Matter (PM1) in an Urban Site of Jaipur City, Rajasthan 拉贾斯坦邦斋浦尔市区细颗粒物(PM1)化学成分和来源的季节变化
Q3 Environmental Science Pub Date : 2023-10-09 DOI: 10.3233/ajw230064
Shivani Sharma, Charu Jhamaria, Suresh Tiwari, Namrata Singh, Harsha Parwani, Nidhi Rajoria, Tanisha Ameriya, Akanksha Gupta
The present study was conducted with an aim to investigate the seasonal variation in mass concentration of fine particulate matter (PM1), their chemical composition, (water and soluble and non-soluble ions and other elements) and gaseous pollutants (SO2, NO2, CO and O3) at an urban site of Jaipur city in India. During summers, pollutants showed a reduction of 18.97%, 41.95%, 32.32% and 20.56% for PM1, NO2, SO2 and CO, respectively. In contrast, O3 showed an increase of 27%. The substantial reduction was also observed in the levels of secondary aerosols SO4 2- (71.15%), NO3-(21.86%), Cl- (65.63%) and K+ (8.16%). The elemental components Al, B, Be, Ca, Cu, Fe, Mn, Ni, and Pb showed a reduction in the range of 15.13 % (Al) to 71% (Cu). On the contrary, an increment was found in the levels of Ag (21.95%), Cd (62.5%), Cr (89.74%), Mg (10.43%) and Na (25.32%). Four factors were extracted by principal component analysis (PCA). In addition to the local sources, three stationary sources have been identified as contributing to the pollution load located in the WNW, NE and ENE direction of the site. It can be concluded that pollutant concentration and chemical composition of any area not only depend on the local emission, but nearby stationary sources and meteorology are significant contributors.
本研究旨在调查印度斋浦尔市区细颗粒物(PM1)质量浓度、化学成分(水、可溶性和非可溶性离子及其他元素)和气态污染物(SO2、NO2、CO和O3)的季节变化。夏季PM1、NO2、SO2和CO分别减少18.97%、41.95%、32.32%和20.56%。相比之下,O3增长了27%。次生气溶胶SO4 2-(71.15%)、NO3-(21.86%)、Cl-(65.63%)和K+(8.16%)的含量也显著降低。元素成分Al、B、Be、Ca、Cu、Fe、Mn、Ni、Pb减少幅度为15.13% (Al) ~ 71% (Cu)。相反,Ag(21.95%)、Cd(62.5%)、Cr(89.74%)、Mg(10.43%)和Na(25.32%)的含量增加。采用主成分分析(PCA)提取4个影响因子。除本地污染源外,已确定三个固定污染源对污染负荷有贡献,分别位于工地的西北、东北和东北方向。可以得出结论,任何地区的污染物浓度和化学成分不仅取决于当地的排放,而且附近的固定源和气象是重要的贡献者。
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引用次数: 0
Hydrogeochemical Evaluation of Groundwater for Drinking and Irrigation Purposes in Avudaiyarkoil Block, Pudukkottai District, Tamil Nadu, India 印度泰米尔纳德邦Pudukkottai地区Avudaiyarkoil区块饮用和灌溉用地下水水文地球化学评价
IF 0.5 Q3 Environmental Science Pub Date : 2023-07-21 DOI: 10.3233/ajw230053
T. Kongeswaran, K. Sivakumar, A. Muruganantham, K. Prabakaran, V. Perumal, V. Agastheeswaran, S. Bangaru Priyanga, R. Muthuramalingam
The purpose of this study is to evaluate the quality of groundwater for drinking and irrigation in the Avudaiyarkoil block of the Pudukottai district, which is a drought-prone region. Samples were collected from 20 wells on January 2021 and analysed for the water quality parameters, such as pH, EC, TDS, Ca2+, Mg2+, Na+, K+, Cl-, HCO3, SO4, NO3 and F-. The analysis revealed that SO4 is the dominant ion followed by Cl-, HCO3-, Na+, Ca2+, Mg2+, K+, NO3- and F- with respect to the mean value 292>234>208.4>125>100>24.75>18>16.15>0.2. The analytical results were compared with WHO and BIS guideline values to know the groundwater potability and TH, TA, SAR, Na%, RSC, PI, MgC and KI were calculated using the analytical results to identify the suitability of groundwater for irrigation purposes.
本研究的目的是评价普度科泰地区Avudaiyarkoil区块的饮用和灌溉地下水质量,该区块是一个干旱易发地区。于2021年1月采集了20口井的样品,分析了水质参数,如pH、EC、TDS、Ca2+、Mg2+、Na+、K+、Cl-、HCO3、SO4、NO3和F-。分析结果表明,SO4为主要离子,其次为Cl-、HCO3-、Na+、Ca2+、Mg2+、K+、NO3-和F-,平均值为292>234>208.4>125>100>24.75>18>16.15>0.2。将分析结果与WHO和BIS指南值进行比较,了解地下水的可饮用性,并根据分析结果计算TH、TA、SAR、Na%、RSC、PI、MgC和KI,以确定地下水的灌溉适宜性。
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引用次数: 0
期刊
Asian Journal of Water, Environment and Pollution
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