Pub Date : 2024-07-12DOI: 10.15376/biores.19.3.5764-5792
Azuan Abdul Latif, Harun Shuhaida, Mohd Shaiful Sajab, M. Markom
Laboratory and pilot scale pretreatment processes were assessed for empty fruit bunch (EFB) at different morphologies using anhydrous ammonia pretreatment (AAP). The AAP was used to deconstruct the complex structure of EFB through physical and chemical reaction to promote efficient conversion of the carbohydrates to monomeric sugars. Different morphologies of EFB samples used were unpressed EFB (UE), pressed EFB (PE), pressed and shredded EFB (PES), and lastly pressed, shredded and ground EFB (PESG). The APP process was optimized using a 1.0 L laboratory scale reactor and further scaled up to a 22 L pressure vessel (AAPB). AAP-PESG contained 76.2%, and AAP-PES contained 75.5% of structural carbohydrates, showing no significant difference. AAP-UE showed the lowest glucan conversion of 28%. The optimal laboratory conditions adopted were 135 °C, 30 min, moist to dry EFB loading of 2:1, and ammonia to dry EFB loading of 1:1. Glucan conversion of AAP-PES were 87%, 80%, and 62% at 1%, 3%, and 6% glucan loadings, respectively. The AAP-PES detected acetamide concentration at 7.3 mg/g, while AAPB-PES was only at 4.4 mg/g. Chemical composition, Fourier transform infrared spectroscopy, Brunauer Emmett Teller surface area, and scanning electron microscopy supported the assessment of AAP and AAPB processes.
{"title":"Lab to pilot scale assessment on the pretreatment of empty fruit bunch using anhydrous ammonia","authors":"Azuan Abdul Latif, Harun Shuhaida, Mohd Shaiful Sajab, M. Markom","doi":"10.15376/biores.19.3.5764-5792","DOIUrl":"https://doi.org/10.15376/biores.19.3.5764-5792","url":null,"abstract":"Laboratory and pilot scale pretreatment processes were assessed for empty fruit bunch (EFB) at different morphologies using anhydrous ammonia pretreatment (AAP). The AAP was used to deconstruct the complex structure of EFB through physical and chemical reaction to promote efficient conversion of the carbohydrates to monomeric sugars. Different morphologies of EFB samples used were unpressed EFB (UE), pressed EFB (PE), pressed and shredded EFB (PES), and lastly pressed, shredded and ground EFB (PESG). The APP process was optimized using a 1.0 L laboratory scale reactor and further scaled up to a 22 L pressure vessel (AAPB). AAP-PESG contained 76.2%, and AAP-PES contained 75.5% of structural carbohydrates, showing no significant difference. AAP-UE showed the lowest glucan conversion of 28%. The optimal laboratory conditions adopted were 135 °C, 30 min, moist to dry EFB loading of 2:1, and ammonia to dry EFB loading of 1:1. Glucan conversion of AAP-PES were 87%, 80%, and 62% at 1%, 3%, and 6% glucan loadings, respectively. The AAP-PES detected acetamide concentration at 7.3 mg/g, while AAPB-PES was only at 4.4 mg/g. Chemical composition, Fourier transform infrared spectroscopy, Brunauer Emmett Teller surface area, and scanning electron microscopy supported the assessment of AAP and AAPB processes.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141834190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-11DOI: 10.15376/biores.19.3.hubbe
M. Hubbe, Björn Sjöstrand, Magnus Lestelius, Helena Håkansson, A. Swerin, Gunnar Henriksson
Factors affecting the swelling of cellulosic fibers are considered in this review. Emphasis is placed on aqueous systems and papermaking fibers, but the review also considers cellulose solvent systems, nanocellulose research, and the behavior of cellulosic hydrogels. The topic of swelling of cellulosic fibers ranges from effects of humid air, continuing through water immersion, and extends to hydrogels and the dissolution of cellulose, as well as some of its derivatives. The degree of swelling of cellulose fibers can be understood as involving a balance between forces of expansion (especially osmotic pressure) vs. various restraining forces, some of which involve the detailed structure of layers within the fibril structure of the fibers. The review also considers hornification and its effects related to swelling. The expansive forces are highly dependent on ionizable groups, pH, and the ionic strength of solution. The restraining forces depend on the nature of lignin, cellulose, and their detailed structural arrangements.
{"title":"Swelling of cellulosic fibers in aqueous systems: A Review of chemical and mechanistic factors","authors":"M. Hubbe, Björn Sjöstrand, Magnus Lestelius, Helena Håkansson, A. Swerin, Gunnar Henriksson","doi":"10.15376/biores.19.3.hubbe","DOIUrl":"https://doi.org/10.15376/biores.19.3.hubbe","url":null,"abstract":"Factors affecting the swelling of cellulosic fibers are considered in this review. Emphasis is placed on aqueous systems and papermaking fibers, but the review also considers cellulose solvent systems, nanocellulose research, and the behavior of cellulosic hydrogels. The topic of swelling of cellulosic fibers ranges from effects of humid air, continuing through water immersion, and extends to hydrogels and the dissolution of cellulose, as well as some of its derivatives. The degree of swelling of cellulose fibers can be understood as involving a balance between forces of expansion (especially osmotic pressure) vs. various restraining forces, some of which involve the detailed structure of layers within the fibril structure of the fibers. The review also considers hornification and its effects related to swelling. The expansive forces are highly dependent on ionizable groups, pH, and the ionic strength of solution. The restraining forces depend on the nature of lignin, cellulose, and their detailed structural arrangements.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141834613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-10DOI: 10.15376/biores.19.3.5741-5751
L. Khademibami, Fatemeh Rezaei, R. Shmulsky, Seyed Abolghasem Fatemi
The effect of sticker thickness on final moisture content (MC) of southern pine lumber was investigated in this work. Three kiln charges of lumber were dried to examine the impact of sticker thickness. Sticker thicknesses were 0.75-, 1.00-, and 1.25-in. The moisture contents at different locations within the kiln pack (edge vs middle / course position) were noted. Three course positions were top 5, middle, and bottom 5 courses. Two within-pack locations were considered: outer 25% and middle 50%. Drying time decreased as sticker thickness increased from 0.75 in. to 1.00 in. Statistically significant interactions were noted for sticker thickness and course position (<0.0001) as well as location and course position (P= 0.0378); 1.25 in. thick stickers exhibited higher MC in comparison to 0.75 in. and 1.0 in. for top to bottom positions. Additionally, 1.0 in. thick stickers developed lower MC at the top and bottom. Lower MC was observed in outer relative to inner location regardless of course position. Lower MCs were observed at the top courses for both inner and outer location. The 1.25 in. thick stickers did not produce acceptably dry lumber given the production time constraint. The results suggested that 1.0 in. sticker thickness was most favorable.
这项工作研究了贴纸厚度对南方松木材最终含水率（MC）的影响。为了研究贴纸厚度的影响，对木材进行了三次窑炉干燥。贴纸厚度分别为 0.75 英寸、1.00 英寸和 1.25 英寸，并记录了窑包内不同位置（边缘与中间/窑道位置）的含水率。三个道次位置分别为顶部 5 道次、中部 5 道次和底部 5 道次。包装内有两个位置：外侧 25%和中间 50%。干燥时间随着贴纸厚度从 0.75 英寸增加到 1.00 英寸而缩短。在贴纸厚度和包装位置（<0.0001）以及包装位置和包装位置（P= 0.0378）之间存在明显的统计学交互作用；1.25 英寸厚的贴纸与 0.75 英寸和 1.0 英寸的贴纸相比，在从上到下的位置上显示出更高的 MC 值。此外，1.0 英寸厚的贴纸在顶部和底部的 MC 值较低。无论路线位置如何，外侧位置的 MC 值均低于内侧位置。内侧和外侧顶部的 MC 都较低。在生产时间有限的情况下，1.25 英寸厚的贴纸无法生产出可接受的干燥木材。结果表明，1.0 英寸的贴纸厚度最合适。
{"title":"Field test of sticker thickness in kiln drying of southern pine","authors":"L. Khademibami, Fatemeh Rezaei, R. Shmulsky, Seyed Abolghasem Fatemi","doi":"10.15376/biores.19.3.5741-5751","DOIUrl":"https://doi.org/10.15376/biores.19.3.5741-5751","url":null,"abstract":"The effect of sticker thickness on final moisture content (MC) of southern pine lumber was investigated in this work. Three kiln charges of lumber were dried to examine the impact of sticker thickness. Sticker thicknesses were 0.75-, 1.00-, and 1.25-in. The moisture contents at different locations within the kiln pack (edge vs middle / course position) were noted. Three course positions were top 5, middle, and bottom 5 courses. Two within-pack locations were considered: outer 25% and middle 50%. Drying time decreased as sticker thickness increased from 0.75 in. to 1.00 in. Statistically significant interactions were noted for sticker thickness and course position (<0.0001) as well as location and course position (P= 0.0378); 1.25 in. thick stickers exhibited higher MC in comparison to 0.75 in. and 1.0 in. for top to bottom positions. Additionally, 1.0 in. thick stickers developed lower MC at the top and bottom. Lower MC was observed in outer relative to inner location regardless of course position. Lower MCs were observed at the top courses for both inner and outer location. The 1.25 in. thick stickers did not produce acceptably dry lumber given the production time constraint. The results suggested that 1.0 in. sticker thickness was most favorable.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141835602","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-10DOI: 10.15376/biores.19.3.5731-5740
Alexey Zhukov, I. Stepina, M. Sodomon, Sofia Bazhenova
Composite materials based on modified stems of Heracleum sosnowskyi (Sosnowsky’s hogweed) and polyurethane binder are used for thermal insulation of building structures. The purpose of this study was to create a mathematical model for the optimization of composite compositions and the prediction of their properties. Numerical methods of mathematical statistics were used and nomogram plots were obtained. It was possible to select optimal compositions for the given characteristics of composites based on modified stems of H. sosnowskyi and polyurethane binder and predict the thermophysical properties of composites by knowing their composition. To produce thermal insulation boards with a thermal conductivity coefficient of 0.05 W/(m°C) it was necessary to use particles of H. sosnowskyi with a size of approximately 5 mm. The ratio of plant raw material and polyurethane binder was approximately 3:1 by weight. The bending strength of the thermal insulation boards was 1.56 MPa, and the compressive strength was 0.27 MPa.
{"title":"Preliminary optimization of composite compositions based on modified Sosnowsky’s Heracleum","authors":"Alexey Zhukov, I. Stepina, M. Sodomon, Sofia Bazhenova","doi":"10.15376/biores.19.3.5731-5740","DOIUrl":"https://doi.org/10.15376/biores.19.3.5731-5740","url":null,"abstract":"Composite materials based on modified stems of Heracleum sosnowskyi (Sosnowsky’s hogweed) and polyurethane binder are used for thermal insulation of building structures. The purpose of this study was to create a mathematical model for the optimization of composite compositions and the prediction of their properties. Numerical methods of mathematical statistics were used and nomogram plots were obtained. It was possible to select optimal compositions for the given characteristics of composites based on modified stems of H. sosnowskyi and polyurethane binder and predict the thermophysical properties of composites by knowing their composition. To produce thermal insulation boards with a thermal conductivity coefficient of 0.05 W/(m°C) it was necessary to use particles of H. sosnowskyi with a size of approximately 5 mm. The ratio of plant raw material and polyurethane binder was approximately 3:1 by weight. The bending strength of the thermal insulation boards was 1.56 MPa, and the compressive strength was 0.27 MPa.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141835587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-10DOI: 10.15376/biores.19.3.5752-5763
Ayşe Muslu, Osman Üçüncü, Cemalettin Baltacı
The compound 5-(hydroxymethyl)furfural (HMF) has emerged as a versatile intermediate with the ability to undergo conversion into both fuel and a variety of platform chemicals. Lignocellulosic biomass, such as hazelnut shells and tea processing residues, was employed in this study for HMF production through two distinct methods. In the first method, cellulose from biomass was converted to sugars using a 4% acid solution, followed by catalytic conversion with NaCl/CrCl3.6H2O. After a 1-h reaction at 131 °C in a high-pressure system, HMF was obtained from tea processing waste and hazelnut shells with yields of 8.6% (82.3 mg/g) and 6.7% (66.7 mg/g), respectively. The second method involved LiCl/NaCl-doped N,N-dimethylacetamide (DMA) as an ionic solvent system for HMF production. After a 2-h reaction at 131 °C in the DMA-NaCl/[EMIM]Cl ionic solvent system, HMF was obtained from tea processing waste and hazelnut shell celluloses with yields of 5.7% (57.5 mg/g) and 3.1% (31.3 mg/g), respectively. This study contributes to the economic conversion of various food wastes into valuable chemicals, highlighting the potential of lignocellulosic biomass in sustainable chemical production.
{"title":"Production of 5-hydroxymethylfurfural from non-edible lignocellulosic food wastes","authors":"Ayşe Muslu, Osman Üçüncü, Cemalettin Baltacı","doi":"10.15376/biores.19.3.5752-5763","DOIUrl":"https://doi.org/10.15376/biores.19.3.5752-5763","url":null,"abstract":"The compound 5-(hydroxymethyl)furfural (HMF) has emerged as a versatile intermediate with the ability to undergo conversion into both fuel and a variety of platform chemicals. Lignocellulosic biomass, such as hazelnut shells and tea processing residues, was employed in this study for HMF production through two distinct methods. In the first method, cellulose from biomass was converted to sugars using a 4% acid solution, followed by catalytic conversion with NaCl/CrCl3.6H2O. After a 1-h reaction at 131 °C in a high-pressure system, HMF was obtained from tea processing waste and hazelnut shells with yields of 8.6% (82.3 mg/g) and 6.7% (66.7 mg/g), respectively. The second method involved LiCl/NaCl-doped N,N-dimethylacetamide (DMA) as an ionic solvent system for HMF production. After a 2-h reaction at 131 °C in the DMA-NaCl/[EMIM]Cl ionic solvent system, HMF was obtained from tea processing waste and hazelnut shell celluloses with yields of 5.7% (57.5 mg/g) and 3.1% (31.3 mg/g), respectively. This study contributes to the economic conversion of various food wastes into valuable chemicals, highlighting the potential of lignocellulosic biomass in sustainable chemical production.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141835629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Effects of different concentrations of biogas slurry (BS) were evaluated relative to vegetable cultivation. Five concentration levels of BS were used as organic fertilizer to grow Chinese cabbages (CA) by drip irrigation to study the effect of BS on the yield and quality. Each level was replicated three times and BS was used seven times. Results showed that the average plant height, fresh weight, dry weight, and soluble sugars and protein contents of Chinese cabbage under the T1 (BS 25%) treatment were optimal. Among them, dry weight per plant (3.53g), soluble sugar content (0.41%), and soluble protein content (0.0039%) were 1.74 times, 1.41 times, and 1.14 times more than under the CK treatment, respectively. In addition, the application of biogas slurry improved the physical and chemical properties of soil. Soil total nitrogen (TN) and available phosphorus (AP) content increased after the use of biogas slurry, and the soil total nitrogen and available phosphorus content increased with the increase in the concentration of the applied biogas slurry. The available potassium (AK) content of soil fluctuated with the concentration of biogas slurry. In addition, biogas slurry can properly improve soil pH. In conclusion, BS 25% was the best for the growth of CA and its quality, which provided scientific basis for biogas slurry as fertilizer.
评估了不同浓度的沼气浆（BS）对蔬菜种植的影响。将五种浓度的沼渣作为有机肥，通过滴灌种植大白菜（CA），研究沼渣对产量和质量的影响。每个浓度水平重复三次，使用 BS 七次。结果表明，在 T1（BS 25%）处理下，大白菜的平均株高、鲜重、干重、可溶性糖和蛋白质含量均达到最佳水平。其中，单株干重（3.53 克）、可溶性糖含量（0.41%）和可溶性蛋白质含量（0.0039%）分别是 CK 处理的 1.74 倍、1.41 倍和 1.14 倍。此外，施用沼液还改善了土壤的理化性质。施用沼液后，土壤全氮（TN）和可利用磷（AP）含量增加，土壤全氮和可利用磷含量随施用沼液浓度的增加而增加。土壤中的可利用钾（AK）含量随沼气浆浓度的增加而波动。此外，沼液还能适当改善土壤 pH 值。总之，BS 25% 的沼液对 CA 的生长及其质量最为有利，这为沼液作为肥料提供了科学依据。
{"title":"Effect of drip irrigation with biogas slurry on the yield and quality of Chinese cabbage","authors":"Dongxue Yin, Dongdong Chen, Jiajun Qin, Wei Liu, Yingxian Wang, Weijuan Lan, Naining Zhong, Peiqu Ma","doi":"10.15376/biores.19.3.5717-5730","DOIUrl":"https://doi.org/10.15376/biores.19.3.5717-5730","url":null,"abstract":"Effects of different concentrations of biogas slurry (BS) were evaluated relative to vegetable cultivation. Five concentration levels of BS were used as organic fertilizer to grow Chinese cabbages (CA) by drip irrigation to study the effect of BS on the yield and quality. Each level was replicated three times and BS was used seven times. Results showed that the average plant height, fresh weight, dry weight, and soluble sugars and protein contents of Chinese cabbage under the T1 (BS 25%) treatment were optimal. Among them, dry weight per plant (3.53g), soluble sugar content (0.41%), and soluble protein content (0.0039%) were 1.74 times, 1.41 times, and 1.14 times more than under the CK treatment, respectively. In addition, the application of biogas slurry improved the physical and chemical properties of soil. Soil total nitrogen (TN) and available phosphorus (AP) content increased after the use of biogas slurry, and the soil total nitrogen and available phosphorus content increased with the increase in the concentration of the applied biogas slurry. The available potassium (AK) content of soil fluctuated with the concentration of biogas slurry. In addition, biogas slurry can properly improve soil pH. In conclusion, BS 25% was the best for the growth of CA and its quality, which provided scientific basis for biogas slurry as fertilizer.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141835578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-05DOI: 10.15376/biores.19.3.5685-5698
Mingda Zhu, Xuejiao Qiu, Jingyun Hao, Jian-dong Hu, Zhanying Liu
The excellent physical and chemical properties of deep eutectic solvents, especially the ability of some of them to dissolve biomass, make them broadly applicable in biomass pretreatment. In this study, oat straw was pretreated with deep eutectic solvents composed of choline chloride and an acid (formic, lactic, or oxalic acid). The highest reducing sugar yield was obtained for the formic acid/choline chloride mixture. Using a pretreatment temperature of 110 °C, a reaction time of 2 h, and a solid-liquid ratio of 1:20, the reducing sugar yield obtained by cellulase hydrolysis was 23.5%, the degradation rate of cellulose reached 76.9%, and hemicellulose was completely degraded. The pretreated oat straw was then analyzed by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. The changes in its crystallinity and lignin content compared to the untreated specimen were determined. A preliminary mechanism for the pretreatment of oat straw with formic acid/choline chloride was revealed. The study could provide an opportunity to expand the application in biochemicals or biological feed processes.
深共晶溶剂具有优异的物理和化学性质，尤其是其中一些溶剂溶解生物质的能力，因此可广泛应用于生物质预处理。在这项研究中，燕麦秸秆用氯化胆碱和一种酸（甲酸、乳酸或草酸）组成的深共晶溶剂进行预处理。甲酸/氯化胆碱混合物的还原糖产量最高。预处理温度为 110 °C，反应时间为 2 小时，固液比为 1:20，纤维素酶水解得到的还原糖产量为 23.5%，纤维素降解率达到 76.9%，半纤维素完全降解。然后对预处理后的燕麦秸秆进行了扫描电子显微镜、傅立叶变换红外光谱和 X 射线衍射分析。与未处理的样品相比，测定了其结晶度和木质素含量的变化。初步揭示了甲酸/氯化胆碱预处理燕麦秸秆的机理。这项研究可为扩大其在生物化学或生物饲料工艺中的应用提供机会。
{"title":"Unlocking the potential of oat straw: Efficient pretreatment methods for enhanced glucose production","authors":"Mingda Zhu, Xuejiao Qiu, Jingyun Hao, Jian-dong Hu, Zhanying Liu","doi":"10.15376/biores.19.3.5685-5698","DOIUrl":"https://doi.org/10.15376/biores.19.3.5685-5698","url":null,"abstract":"The excellent physical and chemical properties of deep eutectic solvents, especially the ability of some of them to dissolve biomass, make them broadly applicable in biomass pretreatment. In this study, oat straw was pretreated with deep eutectic solvents composed of choline chloride and an acid (formic, lactic, or oxalic acid). The highest reducing sugar yield was obtained for the formic acid/choline chloride mixture. Using a pretreatment temperature of 110 °C, a reaction time of 2 h, and a solid-liquid ratio of 1:20, the reducing sugar yield obtained by cellulase hydrolysis was 23.5%, the degradation rate of cellulose reached 76.9%, and hemicellulose was completely degraded. The pretreated oat straw was then analyzed by scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. The changes in its crystallinity and lignin content compared to the untreated specimen were determined. A preliminary mechanism for the pretreatment of oat straw with formic acid/choline chloride was revealed. The study could provide an opportunity to expand the application in biochemicals or biological feed processes.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141837128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-05DOI: 10.15376/biores.19.3.5699-5716
Ainul Hafiza Abd Hair, Kushairi Mohd Salleh, Nyak Syazwani Nyak Mazlan, Mohamad Khalid Khairunnisa-Atiqah, Noorain Purhanudin, Anin Sofya Mohd Akhiri, Sarani Zakaria, R. Awang
Surface modification via plasma treatment is useful in improving textile-based wound dressing functionality. This study was conducted to optimise the nitrogen plasma exposure time and its effect on the cotton surface (CS) properties at a constant nitrogen flow rate of 20 sccm for 5 to 30 min. The optimisation was done by analysing the alteration in morphology, functional group composition, crystallinity phase, electrokinetic potential, and colour of CS as subjected to nitrogen plasma. CS experienced an etching effect due to the presence of microcracks on its surface, with its electrokinetic potential becoming less negative, ranging from -5.51 to –8.05 mV. Then, the nitrogen functional group was detected on CS ranging from 2.9% to 4.5%, with its whiteness index reduced to 8.67% compared to the pristine cotton. As a result, 20 min was selected as the optimum exposure time for surface treatment. An exposure time of 30 min showed an early sign of degradation, which reduced its crystallinity index by 11.1%. Apparently, the CS is activated as exposed to the nitrogen plasma and experiences slight changes in its molecular structure without affecting its bulk properties.
{"title":"Optimisation of nitrogen plasma exposure time for surface modification of cotton fibre","authors":"Ainul Hafiza Abd Hair, Kushairi Mohd Salleh, Nyak Syazwani Nyak Mazlan, Mohamad Khalid Khairunnisa-Atiqah, Noorain Purhanudin, Anin Sofya Mohd Akhiri, Sarani Zakaria, R. Awang","doi":"10.15376/biores.19.3.5699-5716","DOIUrl":"https://doi.org/10.15376/biores.19.3.5699-5716","url":null,"abstract":"Surface modification via plasma treatment is useful in improving textile-based wound dressing functionality. This study was conducted to optimise the nitrogen plasma exposure time and its effect on the cotton surface (CS) properties at a constant nitrogen flow rate of 20 sccm for 5 to 30 min. The optimisation was done by analysing the alteration in morphology, functional group composition, crystallinity phase, electrokinetic potential, and colour of CS as subjected to nitrogen plasma. CS experienced an etching effect due to the presence of microcracks on its surface, with its electrokinetic potential becoming less negative, ranging from -5.51 to –8.05 mV. Then, the nitrogen functional group was detected on CS ranging from 2.9% to 4.5%, with its whiteness index reduced to 8.67% compared to the pristine cotton. As a result, 20 min was selected as the optimum exposure time for surface treatment. An exposure time of 30 min showed an early sign of degradation, which reduced its crystallinity index by 11.1%. Apparently, the CS is activated as exposed to the nitrogen plasma and experiences slight changes in its molecular structure without affecting its bulk properties.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141837365","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-03DOI: 10.15376/biores.19.3.5672-5684
Marek Nociar, Tomáš Pipíška, Pavel Kral, Samo Grbec, Milan Šernek
Due to climate changes, it is necessary to consider the use of other wood species to replace currently used woods. This work deals with the determination of the shear strength of bonded veneers (eight European wood species: spruce, larch, pine, beech, oak, poplar, birch, and alder) with Silekol® 311 melamine-urea-formaldehyde adhesive (MUF) with a variable coverage on the surface of the samples: 10, 15, 20, 25, 30, 50, 75, and 100%. The Automated Bonding Evaluation System (ABES) was used to evaluate and compare adhesive bond strengths. The larch, beech, and oak samples exhibited greater single-lap shear strength than the control samples from spruce. There was no statistically significant difference in shear strength regarding the adhesive coverage from 100% to 20% on the surface of the samples, for almost all wood species. The results of the project provide basic information about the bonding strengths with different coverage in the adhesive layer, comparing non-commonly used wood species in wood-based composites such as oriented strand board and particleboard.
{"title":"Effect of the percentage of MUF adhesive coverage on shear strength when bonding different wood species","authors":"Marek Nociar, Tomáš Pipíška, Pavel Kral, Samo Grbec, Milan Šernek","doi":"10.15376/biores.19.3.5672-5684","DOIUrl":"https://doi.org/10.15376/biores.19.3.5672-5684","url":null,"abstract":"Due to climate changes, it is necessary to consider the use of other wood species to replace currently used woods. This work deals with the determination of the shear strength of bonded veneers (eight European wood species: spruce, larch, pine, beech, oak, poplar, birch, and alder) with Silekol® 311 melamine-urea-formaldehyde adhesive (MUF) with a variable coverage on the surface of the samples: 10, 15, 20, 25, 30, 50, 75, and 100%. The Automated Bonding Evaluation System (ABES) was used to evaluate and compare adhesive bond strengths. The larch, beech, and oak samples exhibited greater single-lap shear strength than the control samples from spruce. There was no statistically significant difference in shear strength regarding the adhesive coverage from 100% to 20% on the surface of the samples, for almost all wood species. The results of the project provide basic information about the bonding strengths with different coverage in the adhesive layer, comparing non-commonly used wood species in wood-based composites such as oriented strand board and particleboard.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141837915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-07-02DOI: 10.15376/biores.19.3.5654-5671
T. S. Rejiniemon, Hussain Rejula Raishy, Rajamani Bhamadevi, M. Binobead, Reem M. Aljowaie, Rathi Muthaiyan Ahalliya
Lactic acid is used in various industrial processes, including the production of emulsifiers, polymers, cosmetics, and pharmaceuticals. Fermentation of renewable biomass from natural sources has several advantages over costly chemical methods. Thermal and acidic pretreatments were used to improve the availability of sugars in the medium. Bacillus coagulans was isolated from the banana pseudostem; it was cultured with cattle manure-banana pseudostem for the improved production of lactic acid. Lactic acid production was high in the culture medium containing a 1:1 ratio of cow manure and banana pseudostem after 72 h of fermentation. After 24 h, lactic acid production was 19.4 ± 1.2 g/kg substrate, and it increased after 48 h (20.5 ± 0.1 g/kg substrate), and 72 h (26.3 ± 0.1 g/kg substrate). Lactic acid synthesized by B. coagulans was purified and used for the synthesis of polylactic acid. Polylactic acid was used for the fabrication of composite materials with cellulose and silver nanoparticles. The scanning electron microscopy image showed a smooth surface with uniform particle sizes. The fabricated nanoparticles showed antibacterial activity against food spoilage bacteria. The film was used to pack goat meat and chicken meat. The fabricated film reduced the bacterial load in the stored meat and improved food quality.
{"title":"Banana pseudo-stem and cattle manure for lactic acid production and the application of polylactic acid-cellulose silver nanoparticle-based nanocomposite films in food storage","authors":"T. S. Rejiniemon, Hussain Rejula Raishy, Rajamani Bhamadevi, M. Binobead, Reem M. Aljowaie, Rathi Muthaiyan Ahalliya","doi":"10.15376/biores.19.3.5654-5671","DOIUrl":"https://doi.org/10.15376/biores.19.3.5654-5671","url":null,"abstract":"Lactic acid is used in various industrial processes, including the production of emulsifiers, polymers, cosmetics, and pharmaceuticals. Fermentation of renewable biomass from natural sources has several advantages over costly chemical methods. Thermal and acidic pretreatments were used to improve the availability of sugars in the medium. Bacillus coagulans was isolated from the banana pseudostem; it was cultured with cattle manure-banana pseudostem for the improved production of lactic acid. Lactic acid production was high in the culture medium containing a 1:1 ratio of cow manure and banana pseudostem after 72 h of fermentation. After 24 h, lactic acid production was 19.4 ± 1.2 g/kg substrate, and it increased after 48 h (20.5 ± 0.1 g/kg substrate), and 72 h (26.3 ± 0.1 g/kg substrate). Lactic acid synthesized by B. coagulans was purified and used for the synthesis of polylactic acid. Polylactic acid was used for the fabrication of composite materials with cellulose and silver nanoparticles. The scanning electron microscopy image showed a smooth surface with uniform particle sizes. The fabricated nanoparticles showed antibacterial activity against food spoilage bacteria. The film was used to pack goat meat and chicken meat. The fabricated film reduced the bacterial load in the stored meat and improved food quality.","PeriodicalId":9172,"journal":{"name":"Bioresources","volume":null,"pages":null},"PeriodicalIF":1.3,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141685293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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