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Reduction of fines in recycled paper white water via cellulase enzymes 通过纤维素酶减少再生纸白水中的细小颗粒
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-12-01 DOI: 10.15376/biores.19.1.635-655
Đorđe Jevtović, Predrag Živković, Ana Milivojević, Dejan I. Bezbradica, Luc Van Der Auwera
Due to the high wastepaper recyclability and water-loop system closure, packaging paper mills struggle with increased fines, causing runnability issues. Cellulase enzymes are a preferred treatment choice for the improvement of the pulp refining in stock preparation area but are not widely used or easy to introduce in the production process. Different cellulase enzymes were tested, and those with the highest activity were introduced to the white-water (WW) samples with the aim to reduce fines content as potentially new enzyme applications on the paper machine. The first portion of the study involved the development of an experiment model to find and confirm the optimal enzyme process parameters (40 °C, pH 5.7, reaction time 3 h, and 0.18% v/v enzyme addition) for laboratory made white-water. The second portion of the study included turbidity, colloidal charge, flow cytometry (FCM), and chemical oxygen demand (COD) analysis on industrial and laboratory made white-water samples at optimized process parameters. Obtained results corresponded to reduced fines content in white-water samples, which justified commercial usage of cellulase enzymes on recycled paper machine short loop and potentially increased machine runnability without negative influence on wastewater treatment plant.
由于废纸的高可回收性和水循环系统的封闭性,包装纸厂与增加的罚款作斗争,造成可操作性问题。纤维素酶是浆料制备领域改善纸浆精炼的首选处理方法,但在生产过程中应用并不广泛,也不容易引入。测试了不同的纤维素酶,并将活性最高的酶引入白水(WW)样品中,目的是降低细粒含量,作为潜在的新酶在造纸机上的应用。研究的第一部分包括建立实验模型,以寻找和确定实验室制白水的最佳酶工艺参数(40°C, pH 5.7,反应时间3 h,酶添加量0.18% v/v)。研究的第二部分包括在优化的工艺参数下对工业和实验室制备的白水样品进行浊度、胶体电荷、流式细胞术(FCM)和化学需氧量(COD)分析。所获得的结果与白水样品中细粒含量的降低相对应,这证明了纤维素酶在再生纸机短回路上的商业使用是合理的,并且可能提高机器的运行性能,而不会对废水处理厂产生负面影响。
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引用次数: 0
The impact of drying conditions on the surface color changes of pine wood 干燥条件对松木表面颜色变化的影响
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-12-01 DOI: 10.15376/biores.19.1.656-669
A. Suchta, J. Barański, Tatiana Vilkovská, I. Klement, Peter Vilkovský
The article presents the impact of drying process and selected parameters on the color changes on the surface of pine wood (Pinus sylvestris L.). Three predetermined process conditions (modes), mild, normal, and intensive, were investigated. The experiments were conducted using a semi-industrial scale dryer designed at the Gdańsk University of Technology with a loading capacity of 0.55 m3. The drying process was applied to pine wood grown in the northern part of Pomeranian region in Poland. The specimens were selected taking into consideration the radial angle of the growth rings. During each drying mode, 25 pieces of wood with dimensions (thickness, width, length) of 0.03 m, 0.2 m, and 1.5 m, respectively, were dried. The total color change (ΔE) after drying process and color saturation (h*) before and after drying processes of the wood surface was determined using the normalized CIELAB methods. The obtained results indicated that the color change of the pine wood surface increased simultaneously with the intensification of the drying process. However, the normalized wood quality after drying under intensive drying process conditions remained within the standard limits. The application of intensive drying process conditions remarkably changes the surface color of the obtained material, while remarkably reducing the drying process duration.
本文研究了干燥工艺和干燥参数对松材表面颜色变化的影响。三种预定的工艺条件(模式),温和,正常,和密集,进行了研究。实验采用Gdańsk理工大学设计的半工业规模干燥机进行,装载能力为0.55 m3。干燥过程适用于生长在波兰波美拉尼亚地区北部的松木。试样的选择考虑了生长环的径向角。在每种干燥模式下,分别对尺寸(厚度、宽度、长度)为0.03 m、0.2 m和1.5 m的25块木材进行干燥。采用归一化CIELAB方法测定木材表面干燥后的总颜色变化(ΔE)和干燥前后的颜色饱和度(h*)。结果表明,随着干燥过程的加剧,松材表面的颜色变化也随之增加。然而,在密集干燥工艺条件下,干燥后的标准化木材质量仍在标准范围内。强化干燥工艺条件的应用显著改变了所得物料的表面颜色,同时显著缩短了干燥过程的持续时间。
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引用次数: 0
Possibilities of using organic wastes as a growing medium in soilless culture for cut flower rose 在玫瑰切花无土栽培中使用有机废物作为生长介质的可能性
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-30 DOI: 10.15376/biores.19.1.582-594
B. Altun
The possibilities of using organic wastes, such as hazelnut shells (HS), walnut shells (WS), hazelnut skins (HzS), and spent mushroom compost (SMC), as growth medium in cut flower rose cultivation in soilless substrate culture were investigated. The parameters, such as the date of cutting the flower (day), flower stem length (cm), flower stem diameter (mm), flower length (cm), flower diameter (cm), flower color, color of the top and bottom of the leaf, and yield (piece), were examined. In addition, samples taken from the growth medium at the beginning and ending stages of the experiment were analyzed. The first flowers were cut from the HzS +P medium 38 days after planting. The highest yield value (20.6 flower/plant) was obtained from SMC medium. The longest flowers (63.89 ± 0.947 cm) and the thickest stem flowers (5.86 ± 0.136 mm) were cut from the control medium. It was determined that the media also affected the flower and leaf colors. According to the results obtained, SMC and HzS+perlite mediums can be recommended as an alternative to cocopeat in the production of cut roses in soilless substrate culture.
研究了使用榛子壳(HS)、核桃壳(WS)、榛子皮(HzS)和废蘑菇堆肥(SMC)等有机废弃物作为无土基质栽培切花玫瑰的生长介质的可能性。考察了切花日期(天)、花茎长度(厘米)、花茎直径(毫米)、花朵长度(厘米)、花朵直径(厘米)、花朵颜色、叶片上下颜色和产量(朵)等参数。此外,还分析了实验开始和结束阶段从生长培养基中提取的样本。种植 38 天后,从 HzS +P 培养基上切下第一朵花朵。SMC 培养基的产量最高(20.6 朵花/株)。从对照培养基上切下的花最长(63.89 ± 0.947 厘米),茎花最粗(5.86 ± 0.136 毫米)。结果表明,培养基也会影响花朵和叶片的颜色。根据所获得的结果,在无土基质培养切花玫瑰的过程中,建议使用 SMC 和 HzS+ 珍珠岩培养基替代椰糠培养基。
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引用次数: 0
Central composite design for optimization of kenaf-reinforced epoxy composite bonding performance 用于优化 kenaf 增强环氧树脂复合材料粘接性能的中心复合设计
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-30 DOI: 10.15376/biores.19.1.605-619
M. Ibrahim, Noremylia Mohd Bakhori, Ariff Farhan Mohd Nor, Roslina Mohammad, Sa’ardin Abd Aziz, Mohd Yusof Md Daud, H. Kuan, M. Mahardika, M. Z. Hassan
Kenaf fiber is gaining prominence because of its ability as a natural-based reinforced material in advanced composites. However, kenaf contains a hygroscopic natural waxy substance that covers the fiber layer, providing a low surface tension and preventing strong bonding with the polymer matrix. The goal of this study is to optimize the blending parameters of kenaf fiber-reinforced epoxy composites by alkali treatment concentration, length, and fiber-matrix loading using central composite design. The maximum tensile strength was obtained at 6.03 wt% of NaOH concentration, fiber loading of 26.02 wt%, and fiber length at 7.39 mm, which showed a strong correlation between experimental and predicted values. The analysis of variance function model indicated that fiber length, sodium hydroxide concentration, and fiber loading all play important roles in mechanical properties of composites. Based on the fracture surface observations, kenaf fiber composite strength was closely related to bonding at fiber-matrix interfaces. The most common failure modes in the samples were voids, matrix fracture, fiber breakage, weak bonding, and fiber pull-out.
槿麻纤维作为先进复合材料中的天然增强材料,其地位日益突出。然而,槿麻含有一种吸湿性天然蜡质,覆盖在纤维层上,表面张力低,无法与聚合物基体牢固粘合。本研究的目的是利用中心复合设计,通过碱处理浓度、长度和纤维-基体负载,优化剑麻纤维增强环氧树脂复合材料的混合参数。在 NaOH 浓度为 6.03 wt%、纤维负载量为 26.02 wt%、纤维长度为 7.39 mm 时,拉伸强度最大,实验值与预测值之间具有很强的相关性。方差函数分析模型表明,纤维长度、氢氧化钠浓度和纤维负载量对复合材料的力学性能都有重要影响。根据断裂面观察,槿麻纤维复合材料的强度与纤维-基体界面的粘结密切相关。样品中最常见的破坏模式是空洞、基体断裂、纤维断裂、弱粘合和纤维拉出。
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引用次数: 0
Evaluation of rice husk composite boards prepared using different adhesives and processing methods 对使用不同粘合剂和加工方法制备的稻壳复合板进行评估
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-30 DOI: 10.15376/biores.19.1.595-604
Suman Pradhan, Edward D. Entsminger, Mostafa Mohammadabadi, Daniel Seale, K. Ragon
Rice husks, a byproduct of rice milling, were used to develop composite boards. Different processing methods, grinding, and treating with sodium hydroxide (NaOH), were adopted to improve the bonding and mechanical performance. NaOH solution was prepared at 5% (wt/v) concentration. The effect of different adhesives, phenol formaldehyde (PF), and polymeric diphenylmethane diisocyanate (pMDI), was evaluated. Rice husks mixed with resin were hot pressed to the target density of 768 kg/m3 and thickness of 12.7 mm. Specimens cut from these flat panels were submitted to bending, internal bond, water absorption, and thickness swelling tests. Results revealed that chemical treatment with NaOH significantly improved fiber-to-fiber bonding of rice husks. Internal bond strength of specimens made from chemically treated rice husks increased at least 1000% compared to others. Considering the mechanical properties and water uptake, rice husk boards fabricated with unprocessed rice husks and pMDI showed a better performance.
稻壳是碾米的副产品,被用来开发复合板。为改善粘合和机械性能,采用了不同的加工方法,包括研磨和氢氧化钠(NaOH)处理。氢氧化钠溶液的浓度为 5%(wt/v)。评估了不同粘合剂、苯酚甲醛(PF)和聚合二苯基甲烷二异氰酸酯(pMDI)的效果。混合了树脂的稻壳经热压后,目标密度为 768 公斤/立方米,厚度为 12.7 毫米。从这些平板上切下的试样被送去进行弯曲、内部粘合、吸水和厚度膨胀测试。结果表明,用 NaOH 进行化学处理可明显改善稻壳纤维间的粘结。用经过化学处理的稻壳制成的试样的内部粘合强度比其他试样至少提高了 1000%。考虑到机械性能和吸水性,用未加工稻壳和 pMDI 制作的稻壳板性能更好。
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引用次数: 0
Microwave-assisted extraction of β-Sitosterol: A by-product from Agave angustifolia Haw bagasse 微波辅助提取β-谷甾醇:龙舌兰蔗渣的副产品
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-29 DOI: 10.15376/biores.19.1.568-581
Herminia López-Salazar, B. Camacho-Díaz, M. L. A. Ocampo, R. Campos-Mendiola, R. Martínez-Velarde, Argelia López-Bonilla, A. Jiménez–Aparicio
β-sitosterol (BSS) and β-sitosterol glucoside (BSSG) were extracted from Agave angustifolia Haw bagasse using microwave-assisted extraction (MAE). The quantification and characterization of BSS and BSSG were performed through high-performance thin-layer chromatography (HPTLC), Fourier-transform infrared spectroscopy (FT-IR), high-performance liquid chromatography coupled with mass spectrometry (HPLC-MS), and gas chromatography-mass spectrometry (GC-MS). With an extraction time of 9 seconds using MAE, a higher amount of BSS (103.6 mg of β-sitosterol per gram of dry weight of extract) was obtained compared to BSSG (61.6 mg of β-sitosterol glucoside per gram of dry weight of extract). MAE emerges as a promising method for the efficient recovery of β-sitosterol (BSS) and β-sitosterol glucoside (BSSG) from A. angustifolia bagasse. This enriches scientific knowledge regarding phytochemical extraction and holds great potential for various industries, such as pharmaceuticals and nutraceuticals. Additionally, by valorizing the by-products of the agave industry, this research contributes to the sustainable utilization of resources, aligning with the principles of green and circular economy practices.
采用微波辅助萃取法(MAE)从龙舌兰鹰嘴豆渣中提取了β-谷甾醇(BSS)和β-谷甾醇葡萄糖苷(BSSG)。通过高效薄层色谱(HPTLC)、傅立叶变换红外光谱(FT-IR)、高效液相色谱-质谱联用(HPLC-MS)和气相色谱-质谱联用(GC-MS)对 BSS 和 BSSG 进行了定量和表征。与 BSSG(每克提取物干重含 61.6 毫克 β-谷甾醇葡萄糖苷)相比,使用 MAE 萃取 9 秒钟,可获得更多的 BSS(每克提取物干重含 103.6 毫克 β-谷甾醇)。MAE 是一种从 A. angustifolia 甘蔗渣中高效回收 β-谷甾醇(BSS)和 β-谷甾醇葡萄糖苷(BSSG)的有效方法。这丰富了有关植物化学提取的科学知识,并为制药和营养保健品等各种行业带来了巨大潜力。此外,通过龙舌兰产业副产品的价值评估,这项研究有助于资源的可持续利用,符合绿色和循环经济实践的原则。
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引用次数: 0
Comprehensive treatment and disposal of logistics waste in China: Prospects of biomass resource conversion 中国物流废弃物的综合处理和处置:生物质资源转化的前景
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-28 DOI: 10.15376/biores.19.1.ma
Hongzhi Ma, Pin Lv, Chen Wang, Jun Zhou
The exponential growth of China’s economy, coupled with the surge in online commerce, has led to a significant expansion of the logistics industry. In 2022, China’s express delivery industry generated approximately 9 million tons of waste paper and 1.8 million tons of plastic. This study analyzed the current composition and utilization of logistics waste in China, with suggestions for recycling. Logistics waste can be defined as the packaging waste generated in the logistics industry. Corrugated paper and plastic waste were chosen as the objects for utilization. Due to its high cellulose content, corrugated paper can be utilized along with other paper waste for biomass resourcing. Biodegradable plastics can also be converted into biomass resources through the action of specific microorganisms. These polymers can be enzymatically depolymerized by certain bacteria and fungi, yielding valuable organic products. In general, logistics wastes all have potential for biomass resource recovery. By adopting appropriate recovery and conversion technologies, these waste streams can be transformed into high-value bio-based products, such as biofuels, biochemicals, and biopolymers, thus contributing to the development of a circular and sustainable economy.
中国经济的指数级增长,加上在线商务的激增,导致物流业大幅扩张。2022 年,中国快递业产生了约 900 万吨废纸和 180 万吨塑料。本研究分析了中国物流废弃物的构成和利用现状,并提出了回收利用的建议。物流废弃物可定义为物流业产生的包装废弃物。研究选择了瓦楞纸和塑料废弃物作为利用对象。瓦楞纸纤维素含量高,可与其他废纸一起作为生物质资源加以利用。生物降解塑料也可以通过特定微生物的作用转化为生物质资源。某些细菌和真菌可以对这些聚合物进行酶解聚,从而产生有价值的有机产品。总的来说,物流废物都具有生物质资源回收的潜力。通过采用适当的回收和转化技术,这些废物流可以转化为高价值的生物基产品,如生物燃料、生物化学品和生物聚合物,从而促进循环和可持续经济的发展。
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引用次数: 0
Agricultural products supply chain risk assessment model construction and application in IOT environment 物联网环境下农产品供应链风险评估模型构建与应用
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-28 DOI: 10.15376/biores.19.1.552-567
Yiming Lu
This paper constructs the operation model of agricultural products supply chain under an IoT (Internet of Things) environment, based on which the HHM (Hodrick-Prescott Filter) model is used to identify the risk. The ISM (Internal Supply Management) model was used to analyze risk factors. A risk index system was constructed, which was divided into three primary indexes and 18 secondary indexes. The backpropagation (BP) neural network approach was used to establish the risk assessment model. The sample data from 2017 to 2020 was employed as the test sample to test the network assessment model. There was a very small error in the risk level assessment and training results. The results showed that the risk level assessment model was highly operable and can have practical value for effective assessment of the risk level.
本文构建了物联网(IoT)环境下农产品供应链的运行模型,并在此基础上利用 HHM(Hodrick-Prescott Filter)模型识别风险。采用 ISM(内部供应管理)模型分析风险因素。构建了一个风险指标体系,分为三个一级指标和 18 个二级指标。采用反向传播(BP)神经网络方法建立风险评估模型。采用 2017 年至 2020 年的样本数据作为测试样本,对网络评估模型进行测试。风险等级评估和训练结果误差很小。结果表明,该风险等级评估模型可操作性强,对有效评估风险等级具有实用价值。
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引用次数: 0
Convolutional neural network performance and the factors affecting performance for classification of seven Quercus species using sclereid characteristics in the bark 利用树皮中的硬毛特征对 7 种柞树进行分类的卷积神经网络性能及其影响因素
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-27 DOI: 10.15376/biores.19.1.510-524
Jong Ho Kim, B. Purusatama, Alvin Muhammad Savero, Denni Prasetia, J. Jang, Se Young Park, Seung Hwan Lee, Nam Hun Kim
Based on the sclereids in the bark of oak species, a convolutional neural network (CNN) was employed to validate species classification performance and its influencing factors. Three optimizers including stochastic gradient descent (SGD), adaptive moment estimation (Adam), root mean square propagation (RMSProp), and dataset augmentation were adopted. The accuracy and loss stabilized at approximately 15 to 20 and 70 to 80 epochs for the augmented and non-augmented condition, respectively. In the last five epochs, the RMSProp-augmented condition achieved the highest accuracy of 89.8%, whereas the Adam-augmented condition achieved the lowest accuracy of 73.8%. Regarding the loss, SGD-non-augmented condition was the lowest at 0.498, whereas Adam-augmented condition was the highest at 2.740. The highest accuracy was influenced by RMSProp at 0.194. Dataset augmentation had a significant influence on accuracy at 0.456. Homogeneous subsets among the validation conditions indicated that the accuracy and loss were classified into the same subset using an augmented dataset during the training, regardless of the optimizer. Only Adam and RMSProp with non-augmented datasets were categorized into the same subset during the test. Hence, species classification using CNN and sclereid characteristics in the bark was feasible, and RMSProp with augmented datasets showed optimal performance for species classification.
基于栎类树皮中的硬壳蛋白,采用卷积神经网络(CNN)验证了物种分类性能及其影响因素。采用了三种优化器,包括随机梯度下降(SGD)、自适应矩估计(Adam)、均方根传播(RMSProp)和数据集增强。在扩增和非扩增条件下,准确率和损失分别在大约 15 至 20 个和 70 至 80 个历时后趋于稳定。在最后五个 epochs 中,RMSProp 增强条件的准确率最高,达到 89.8%,而 Adam 增强条件的准确率最低,为 73.8%。在损失方面,SGD-non-augmented 条件的损失最低,为 0.498,而 Adam-augmented 条件的损失最高,为 2.740。受 RMSProp 影响的准确率最高,为 0.194。数据集增强对准确率的影响很大,为 0.456。验证条件中的同质子集表明,无论使用哪种优化器,准确率和损失都被归类到了训练期间使用的增强数据集的同一个子集中。只有使用非增强数据集的 Adam 和 RMSProp 在测试中被归入同一子集。因此,利用树皮中的 CNN 和 sclereid 特征进行物种分类是可行的,使用增强数据集的 RMSProp 在物种分类方面表现出最佳性能。
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引用次数: 0
Polyhydroxyalkanoate production from food packaging waste paper 利用食品包装废纸生产聚羟基烷酸酯
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-27 DOI: 10.15376/biores.19.1.539-551
Wei-Lin Tu, Yu-Chuan Hsiung, Chen-Hsien Liang, Jung-Mei Huang, Chung-Mao Ou, Gia-Luen Guo
This study evaluated the production of marine biodegradable plastics, specifically polyhydroxyalkanoates (PHAs), using waste paper from food containers as a novel material source. The results showed that adding dilute sulfuric acid as a pretreatment may have a negative impact on enzyme hydrolysis efficiency. Without pretreatment, the highest glucose concentration was observed in the 50-min heating group. In the experimental group with 1% dilute sulfuric acid as a pretreatment, the highest average glucose concentration was observed in the 25-min treatment group. In flask scale experiments, the C/N ratio was controlled at 10, 20, and 30. The results showed that when the C/N ratio was 10, the PHA/CDM ratios were 16.3 and 23.6 at 48 and 72 h, respectively. After 96 h of cultivation using hydrolysis liquid from the waste paper container as the sole carbon source in a 5-L scale experiment, the PHA/CDM ratio was 28.7 and the PHA concentration was 0.95 g/L. The potential bacterial strain in this study was confirmed to be a Bacillus genus bacterium after strain identification. The signal peaks indicated that the PHA obtained from the Bacillus sp. production process was PHB.
本研究评估了利用食品容器废纸作为新型材料来源生产海洋生物降解塑料(特别是聚羟基烷酸酯(PHA))的情况。结果表明,添加稀硫酸作为预处理可能会对酶水解效率产生负面影响。在没有预处理的情况下,50 分钟加热组的葡萄糖浓度最高。在添加 1%稀硫酸作为预处理的实验组中,25 分钟处理组的平均葡萄糖浓度最高。在烧瓶规模实验中,C/N 比分别控制在 10、20 和 30。结果表明,当 C/N 比为 10 时,48 小时和 72 小时的 PHA/CDM 比率分别为 16.3 和 23.6。在 5 升规模的实验中,以废纸容器中的水解液为唯一碳源进行培养 96 小时后,PHA/CDM 比率为 28.7,PHA 浓度为 0.95 g/L。经菌株鉴定,本研究中的潜在细菌菌株被确认为芽孢杆菌属细菌。信号峰表明,从芽孢杆菌生产过程中获得的 PHA 为 PHB。
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引用次数: 0
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