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Recommended practice for measurement and evaluation of oxygen evolution reaction electrocatalysis 测量和评估氧进化反应电催化的推荐做法
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-09-17 DOI: 10.1002/eom2.12486
Hongmin An, Wonchul Park, Heejong Shin, Dong Young Chung

The Oxygen evolution reaction (OER) is a pivotal technology driving next-generation sustainable energy conversion and storage devices. Establishing a robust analytical methodology is paramount to fostering innovation in this field. This review offers a comprehensive discussion on measurement and interpretation, advocating for standardized protocols and best practices to mitigate the myriad factors that complicate analysis. The initial focus is directed toward substrate electrodes and gas bubbles, both significant contributors to reduced reliability and reproducibility. Subsequently, the review focuses on intrinsic activity assessment, identification of electrochemical active sites, and the disentanglement of competing process contributions. These careful methodologies ensure the systematic delivery of insights crucial for assessing OER performance. In conclusion, the review highlights the critical role played by precise measurement techniques and unbiased activity comparison methodologies in propelling advancements in OER catalyst development.

氧进化反应(OER)是推动下一代可持续能源转换和储存设备的关键技术。建立健全的分析方法对于促进该领域的创新至关重要。本综述对测量和解释进行了全面讨论,提倡采用标准化协议和最佳实践,以减少导致分析复杂化的各种因素。最初的重点是基底电极和气泡,它们都是降低可靠性和可重复性的重要因素。随后,评述将重点放在内在活性评估、电化学活性位点的识别以及竞争过程贡献的分离上。这些细致的方法可确保系统性地提供对评估开放式辐射计性能至关重要的见解。总之,综述强调了精确测量技术和无偏见的活性比较方法在推动 OER 催化剂开发方面所发挥的关键作用。
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引用次数: 0
Lanthanides in the water electrolysis 电解水中的镧系元素
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-09-12 DOI: 10.1002/eom2.12484
Ashish Gaur, Jatin Sharma, Enkhtuvshin Enkhbayar, Min Su Cho, Jeong Ho Ryu, HyukSu Han

The most feasible technique for producing green hydrogen is water electrolysis. In recent years, there has been significant study conducted on the use of transition metal compounds as electrocatalysts for both anodes and cathodes. Peoples have attempted several strategies to improve the electrocatalytic activity of their original structure. One such technique involves introducing rare earth metals or creating heterostructures with compounds based on rare earth metals. The incorporation of rare earth metals significantly enhances the activity by many folds, while their compounds offer structural stability and the ability to manipulate the electronic properties of the original system. These factors have led to a recent boom in investigations on rare earth metal-based electrocatalysts. There is currently a pressing demand for a review article that can provide a comprehensive overview of the scientific advancements and elucidate the mechanistic aspects of the impact of lanthanide doping. This review begins by explaining the electronic structure of the lanthanides. We next examine the mechanistic aspects, followed by recent advancements in lanthanide doping and heterostructure formation for water electrolysis applications. It is expected that this particular effort will benefit a broad audience and stimulate more research in this area of interest.

生产绿色氢气最可行的技术是水电解法。近年来,人们对使用过渡金属化合物作为阳极和阴极的电催化剂进行了大量研究。人们尝试了多种策略来提高其原始结构的电催化活性。其中一种方法是引入稀土金属或与稀土金属化合物形成异质结构。稀土金属的加入使活性显著提高了许多倍,而其化合物则提供了结构稳定性和操纵原始系统电子特性的能力。这些因素导致了最近对稀土金属电催化剂的研究热潮。目前,人们迫切希望能有一篇综述性文章,对科学进展进行全面概述,并阐明镧系元素掺杂的机理影响。本综述首先解释镧系元素的电子结构。接下来,我们将探讨机理方面的问题,然后介绍镧系元素掺杂和异质结构形成在水电解应用中的最新进展。我们希望这一特别的研究工作能使广大读者受益,并激励人们在这一感兴趣的领域开展更多的研究。
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引用次数: 0
Double transition metal MXenes for enhanced electrochemical applications: Challenges and opportunities 用于增强电化学应用的双过渡金属 MXenes:挑战与机遇
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-09-09 DOI: 10.1002/eom2.12485
Faiza Bibi, Abdul Hanan, Irfan Ali Soomro, Arshid Numan, Mohammad Khalid

Double transition metal (DTM) MXenes are a recently discovered class of two-dimensional composite nanomaterials with excellent potential in energy storage applications. Since their emergence in 2015, DTM MXenes have expanded their composition boundary beyond traditional single-metal carbide and nitride MXenes. DTM MXenes offer tunable structures and properties through variations in the constituent transition metals and positioning within the layered lattice. These MXenes can exist in two primary forms: ordered DTMs and solid solutions. The compositional versatility of DTM MXenes offers opportunities to enhance their performance in electrochemical energy storage applications. However, the quality, stability, and surface chemistry of DTM MXenes are influenced by several factors, including the etching process, etchant type, and synthesis route. Currently, limited literature is available on experimentally synthesized DTM MXenes, with most studies focusing on carbide-based MXenes. Most of the articles have dedicated their efforts only to generalized synthesis strategies. Although extensive theoretical studies have explored the suitability of etchants, synthesis parameters, and methods for producing high-quality MXene with selective terminal functional groups, their stability issues have not been thoroughly examined. This review addresses various types of DTM MXenes, their synthesis techniques, and the impact of these methods on their physicochemical properties and electrochemical performance. Additionally, it provides a critical analysis of the causes of instability in MXenes, particularly DTMs, from synthesis to application. The challenges associated with these materials are discussed, along with opportunities and prospects for enhancing synthesis, structural tuning, surface modification, and applications in electrochemical energy storage.

双过渡金属(DTM)MXenes 是最近发现的一类二维复合纳米材料,在储能应用方面具有卓越的潜力。自 2015 年出现以来,DTM MXenes 已将其组成边界扩展到传统的单金属碳化物和氮化物 MXenes 之外。DTM MXenes 通过改变组成过渡金属和层状晶格内的位置,提供了可调的结构和性能。这些 MXenes 可以两种主要形式存在:有序 DTM 和固溶体。DTM MXenes 的组成多样性为提高其在电化学储能应用中的性能提供了机会。然而,DTM MXenes 的质量、稳定性和表面化学性质受到多种因素的影响,包括蚀刻工艺、蚀刻剂类型和合成路线。目前,有关实验合成 DTM MXenes 的文献有限,大多数研究都集中在碳化物基 MXenes 上。大多数文章只致力于研究通用的合成策略。虽然大量理论研究探讨了蚀刻剂的适用性、合成参数以及生产具有选择性末端官能团的高质量 MXene 的方法,但对其稳定性问题还没有进行深入研究。本综述探讨了各种类型的 DTM MX 烯、其合成技术以及这些方法对其物理化学特性和电化学性能的影响。此外,它还对 MXenes(尤其是 DTM)从合成到应用过程中的不稳定性原因进行了批判性分析。报告还讨论了与这些材料相关的挑战,以及加强合成、结构调整、表面改性和电化学储能应用的机遇和前景。
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引用次数: 0
Addressing electrode passivation in lithium–sulfur batteries by site-selective morphology-controlled Li2S formation 通过位点选择性形貌控制 Li2S 的形成解决锂硫电池中的电极钝化问题
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-22 DOI: 10.1002/eom2.12483
Ilju Kim, Jinkwan Jung, Sejin Kim, Hannah Cho, Hyunwon Chu, Wonhee Jo, Dongjae Shin, Hyeokjin Kwon, Hee-Tak Kim

The sulfur utilization efficiency of lithium–sulfur batteries is often limited by the uncontrolled electrodeposition of the insulating Li2S and the resulting electrode passivation. Herein, purposeful electrode and electrolyte design is used to realize site-selective three-dimensional (3D) Li2S electrodeposition and thus mitigate the above problem. Site-selective Li2S nucleation is induced at the tips of CoP nanoneedles grown on a carbon cloth electrode, and the 3D growth of Li2S at these tips without the passivation of the inner part is achieved using a LiBr-containing high-donor-number electrolyte. The controlled Li2S morphology is rationalized by considering the tip effect, the energy of Li2S binding on the electrode surface, and the solubility of Li2S in the electrolyte. Owing to the suppressed electrode passivation, CoP nanoneedle–decorated carbon cloth electrode and LiBr-containing electrolyte deliver a capacity of >1400 mAh gs−1 at a current density of 0.33 A gs−1. Thus, this work paves the way for the active control of Li2S morphology for high-performance lithium–sulfur batteries.

锂硫电池的硫利用效率通常受制于绝缘的 Li2S 不受控制的电沉积以及由此导致的电极钝化。在此,利用有目的的电极和电解质设计实现了位点选择性三维(3D)Li2S 电沉积,从而缓解了上述问题。在碳布电极上生长的 CoP 纳米针尖上诱导了定点选择性 Li2S 成核,并使用含 LiBr 的高钝化数电解质在这些针尖上实现了 Li2S 的三维生长,而无需对内部进行钝化。通过考虑尖端效应、Li2S 与电极表面结合的能量以及 Li2S 在电解质中的溶解度,实现了对 Li2S 形态的合理控制。由于抑制了电极钝化,CoP 纳米针状装饰碳布电极和含 LiBr 的电解液在 0.33 A gs-1 的电流密度下可产生 1400 mAh gs-1 的容量。因此,这项工作为主动控制 Li2S 形态以实现高性能锂硫电池铺平了道路。
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引用次数: 0
Unveiled mechanism of prolonged stability of Zn anode coated with two-dimensional nanomaterial protective layers toward high-performance aqueous Zn ion batteries 揭示涂有二维纳米材料保护层的锌阳极对高性能水性锌离子电池的长期稳定性机理
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-08-14 DOI: 10.1002/eom2.12482
Yunhee Ahn, Jueun Baek, Seulgi Kim, Ingyu Choi, Jungjoon Yoo, Segi Byun, Dongju Lee

Rechargeable aqueous zinc (Zn) ion batteries (AZIBs) are gaining popularity in large-scale energy storage due to their low cost, high safety, and environmental friendliness; however, dendrite growth and side reactions in Zn metal anodes limit their practical applications. Additionally, the difficulty of developing successful passivation of Zn anodes, combined with large-area coating of protective layers, remains a major limitation to the commercialization of AZIBs. Here, we introduce two-dimensional (2D) nanomaterials including MoS2, h-BN, and Ti3C2Tx MXene as protective layers for Zn anodes, created on a Zn surface using a scalable, large-area spray-coating process. Examinations of electrochemical performance-related material characterizations revealed that a specific type of 2D material with an optimal thickness prevents vertical growth of Zn dendrites, as well as side reactions including hydrogen evolution and corrosion, resulting in stable device operation with minimal overpotential and extended life, even under harsh measurement conditions. The highly stable MoS2@Zn anode allowed the MoS2@Zn//MnO2 full cell to achieve significantly more stable capacity retention, compared with the bare Zn//MnO2 cell. Our versatile and scalable solution-based coating technique for easily forming large-area 2D protective layers on Zn anodes offers new insights concerning improvements to AZIB reliability and performance.

可充电锌(Zn)离子水电池(AZIBs)因其低成本、高安全性和环保性而在大规模储能领域越来越受欢迎;然而,锌金属阳极中的枝晶生长和副反应限制了其实际应用。此外,开发成功钝化锌阳极的难度以及大面积涂覆保护层仍然是 AZIBs 商业化的主要限制因素。在这里,我们介绍了二维(2D)纳米材料,包括 MoS2、h-BN 和 Ti3C2Tx MXene,作为锌阳极的保护层,采用可扩展的大面积喷涂工艺在锌表面形成。对电化学性能相关材料特性的研究表明,具有最佳厚度的特定类型二维材料可以防止锌枝晶的垂直生长,以及包括氢演化和腐蚀在内的副反应,从而使器件即使在苛刻的测量条件下也能以最小的过电位稳定运行,并延长使用寿命。与裸锌//MnO2 电池相比,高度稳定的 MoS2@Zn 阳极使 MoS2@Zn//MnO2 全电池实现了更稳定的容量保持。我们基于溶液的多功能、可扩展涂层技术可在锌阳极上轻松形成大面积二维保护层,这为提高 AZIB 的可靠性和性能提供了新的视角。
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引用次数: 0
Li1.3Al0.3Ti1.7P3O12 activated PVDF solid electrolyte for advanced lithium–oxygen batteries 用于先进锂-氧电池的 Li1.3Al0.3Ti1.7P3O12 活性 PVDF 固体电解质
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-07-31 DOI: 10.1002/eom2.12481
Caizheng Ou, Hao Zhang, Dan Ma, Hailiang Mu, Xiangqun Zhuge, Yurong Ren, Maryam Bayati, Ben Bin Xu, Xiaoteng Liu, Xiaoqin Zou, Kun Luo

Lithium-ion composite solid electrolyte membranes embedded with Li1.3Al0.3Ti1.7P3O12 and poly(vinylidene fluoride) are prepared using a facile casting method. Furthermore, we added LiI as an active agent for decomposing the anode product. The synergy resulted in a high conductivity of 7.4 mS·cm−1 and lithium-ion mobility of 0.59 and a reduction of the overpotential to 0.86 V for lithium–oxygen batteries (LOBs). The membrane has enhanced Young's modulus of 6.6 GPa that effectively blocked the lithium dendrite growth during the battery operation and puncturing to the membrane led to a significant LOB cycle life of 542 cycles. Meanwhile, Li|Li symmetrical battery overpotential maintained at 42 mV after 470 h of operation.

我们采用简便的浇铸法制备了嵌入 Li1.3Al0.3Ti1.7P3O12 和聚(偏氟乙烯)的锂离子复合固体电解质膜。此外,我们还添加了 LiI 作为分解阳极产物的活性剂。通过协同作用,锂氧电池(LOB)的电导率达到 7.4 mS-cm-1,锂离子迁移率达到 0.59,过电位降低到 0.86 V。膜的杨氏模量提高到 6.6 GPa,可有效阻止电池运行过程中锂枝晶的生长,穿刺膜可使锂氧电池的循环寿命达到 542 次。同时,锂锂对称电池的过电位在运行 470 小时后保持在 42 mV。
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引用次数: 0
Conjugated cobalt-based metal complex nanosheet for fabricating high-performance supercapacitor electrode 用于制造高性能超级电容器电极的共轭钴基金属复合物纳米片
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-07-16 DOI: 10.1002/eom2.12480
Qian Liu, Zengqi Guo, Zhiwei Xu, Cong Wang, Wai-Yeung Wong

In order to cope with the increasingly serious problem of energy shortage, supercapacitors have been developed as a clean and renewable energy source, and the supercapacitors with excellent energy density and long cycle life are imperative. Here, by employing a facile liquid–liquid (L-L) interfacial method at room temperature (RT), a set of two-dimensional (2D) metal complex nanosheets N1-N3 have been synthesized by the facile coordination between Co2+ ion and 2,3,6,7,10,11-hexaiminotriphenylene (HITP). Given the layered superstructure with well-ordered nanopores, the N1-N3 electrodes displayed excellent capacities of 4751.9, 5770.9 and 6075.2 F g−1 at 1 A g−1, and a good cyclic stability with 92.1% capacity retention after 1000 cycles for the N3 electrode. The asymmetric supercapacitor device with N3 as the positive electrode delivers a maximum energy density of 238.2 Wh kg−1 at a power density of 1610.1 W kg−1 and an excellent cycling stability with a capacitance retention of 109.1% after 5000 cycles. This is the best electroactive bottom-up metal complex nanosheet reported so far for use in supercapacitor, which greatly expands the applicability of this 2D nanomaterial in energy device applications.

为了应对日益严重的能源短缺问题,超级电容器作为一种清洁的可再生能源被开发出来,具有优异能量密度和长循环寿命的超级电容器势在必行。本文采用液-液(L-L)界面法,在室温(RT)下通过Co2+离子与2,3,6,7,10,11-六亚氨基三亚苯(HITP)的简单配位合成了一组二维(2D)金属复合物纳米片N1-N3。由于 N1-N3 电极具有层状上层结构和有序的纳米孔,因此在 1 A g-1 的条件下,N1-N3 电极的容量分别为 4751.9、5770.9 和 6075.2 F g-1,并且具有良好的循环稳定性,N3 电极在 1000 次循环后的容量保持率为 92.1%。以 N3 为正极的非对称超级电容器装置在功率密度为 1610.1 W kg-1 时的最大能量密度为 238.2 Wh kg-1,循环稳定性极佳,5000 次循环后电容保持率为 109.1%。这是迄今为止报道的用于超级电容器的最佳电活性自下而上金属复合物纳米片,极大地扩展了这种二维纳米材料在能源设备应用中的适用性。
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引用次数: 0
Amorphous carbon intercalated MoS2 nanosheets embedded on reduced graphene oxide for excellent high-rate and ultralong cycling sodium storage 嵌入在还原氧化石墨烯上的非晶碳插层 MoS2 纳米片可实现出色的高倍率和超长循环钠存储
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-07-08 DOI: 10.1002/eom2.12479
Jun Xu, Junbao Jiang, Shoufu Cao, Suwan Li, Yuanming Ma, Junwei Chen, Yan Zhang, Xiaoqing Lu

MoS2 as a typical layered transition metal dichalcogenide (LTMD) has attracted considerable attention to work as sodium host materials for sodium-ion batteries (SIBs). However, it suffers from low semiconducting behavior and high Na+ diffusion barriers. Herein, intercalation of N-doped amorphous carbon (NAC) into each interlayer of the tiny MoS2 nanosheets embedded on rGO conductive network is achieved, resulting in formation of rGO@MoS2/NAC hierarchy with interoverlapped MoS2/NAC superlattices for high-performance SIBs. Attributed to intercalation of NAC, the resulting MoS2/NAC superlattices with wide MoS2 interlayer of 1.02 nm facilitates rapid Na+ insertion/extraction and accelerates reaction kinetics. Theoretical calculations uncover that the MoS2/NAC superlattices are beneficial for enhanced electron transport, decreased Na+ diffusion barrier and improved Na+ adsorption energy. The rGO@MoS2/NAC anode presents significantly improved high-rate capabilities of 228, 207, and 166 mAh g−1 at 20, 30, and 50 A g−1, respectively, compared with two control samples of pristine MoS2 and MoS2/NAC counterparts. Excellent long-term cyclability over 10 000 cycles with extremely low capacity decay is demonstrated at high current densities of 20 and 50 A g−1. Sodium-ion full cells based on the rGO@MoS2/NAC anode are also demonstrated, yielding decent cycling stability of 200 cycles at 5C. Our work provides a novel interlayer strategy to regulate electron/Na+ transport for fast-charging SIBs.

MoS2 作为一种典型的层状过渡金属二钴化物(LTMD),在钠离子电池(SIB)中作为钠宿主材料的应用引起了广泛关注。然而,它的半导体性能较低,Na+扩散障碍较高。在本文中,将掺杂 N 的无定形碳 (NAC) 插层到嵌入在 rGO 导电网络上的微小 MoS2 纳米片的每个层间,从而形成了具有 MoS2/NAC 超晶格交叠的 rGO@MoS2/NAC 层次结构,用于制造高性能 SIB。由于 NAC 的插层作用,所形成的 MoS2/NAC 超晶格具有 1.02 nm 宽的 MoS2 夹层,有利于 Na+ 的快速插入/萃取,并加快了反应动力学。理论计算发现,MoS2/NAC 超晶格有利于增强电子传输、降低 Na+ 扩散阻力和提高 Na+ 吸附能。与两个对照样品(原始 MoS2 和 MoS2/NAC 对应样品)相比,rGO@MoS2/NAC 阳极在 20、30 和 50 A g-1 电流条件下的高速率能力分别达到 228、207 和 166 mAh g-1。在 20 A g-1 和 50 A g-1 的高电流密度下,该电池具有超过 10,000 次循环的出色长期循环能力,且容量衰减极低。此外,还展示了基于 rGO@MoS2/NAC 阳极的钠离子全电池,在 5C 温度下可稳定循环 200 次。我们的工作提供了一种新颖的层间策略,可调节快速充电 SIB 的电子/Na+ 传输。
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引用次数: 0
Energy-saving hydrogen production by heteroatom modulations coupling urea electrooxidation 通过杂原子调制耦合尿素电氧化实现节能制氢
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-06-30 DOI: 10.1002/eom2.12477
Shun Lu, Xingqun Zheng, Haoqi Wang, Chuan Wang, Esther Akinlabi, Ben Bin Xu, Xiaohui Yang, Qingsong Hua, Hong Liu

Developing efficient electrocatalysts with low-cost for the urea oxidation reaction (UOR) is a significant challenge in energy-saving H2 production owing to its lower thermodynamic potential. Heteroatom incorporation strategy has been proven to boost electrocatalytic activity by altering electronic structures and revealing more active sites on catalysts. Herein, nickel hydroxide nanosheets with various vanadium incorporation (Vx-Ni(OH)2) were developed through a facile hydrothermal approach. By optimizing the incorporated vanadium contents, V6-Ni(OH)2 catalyst exhibited easily accessible active sites and enhanced charge transfer with structural advantages, then assembled as the working electrode for urea-assisted H2 production. Consequently, V6-Ni(OH)2 catalyst demonstrated superior UOR activity compared with other incorporated samples with an overpotential of 1.33 V and a Tafel slope of 28.3 mV dec−1. Theoretical calculations revealed that the improved UOR activity was attributed to the potential determining step of V-Ni(OH)2, which exhibited lower energy in comparison with the pristine Ni(OH)2 and increased electronic states density near the Fermi level. Both experimental and theoretical calculations confirmed vanadium incorporation on Ni(OH)2 could modify the electronic structure of Ni(III) species, improving electrical conductivity, and optimizing the adsorption energy for key reaction intermediates. Furthermore, the crucial contribution of vanadium incorporation with optimized electronic structures to the high UOR activity of Ni(OH)2 is demonstrated.

由于尿素氧化反应(UOR)的热力学潜力较低,因此开发低成本的高效尿素氧化反应电催化剂是节能型 H2 生产中的一项重大挑战。事实证明,杂原子掺入策略可通过改变电子结构和在催化剂上发现更多活性位点来提高电催化活性。在此,通过一种简便的水热法开发出了不同钒掺杂量的氢氧化镍纳米片(Vx-Ni(OH)2)。通过优化掺入的钒含量,V6-Ni(OH)2 催化剂表现出易于获得的活性位点和增强的电荷转移,并具有结构上的优势,然后组装成工作电极用于脲辅助生产 H2。因此,与其他掺杂样品相比,V6-Ni(OH)2 催化剂表现出更高的尿素活性,过电位为 1.33 V,塔菲尔斜率为 28.3 mV dec-1。理论计算显示,UOR 活性的提高归因于 V-Ni(OH)2 的电位决定步骤,与原始 Ni(OH)2 相比,V-Ni(OH)2 的能量更低,费米级附近的电子态密度更高。实验和理论计算都证实,在 Ni(OH)2 上掺入钒可以改变 Ni(III)物种的电子结构,提高导电性,优化关键反应中间产物的吸附能。此外,还证明了掺入钒并优化电子结构对 Ni(OH)2 的高 UOR 活性的重要贡献。
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引用次数: 0
Electrically active/inert dual-function architecture enabled by screen printing grid-like SiO2 on Cu foil for ultra-long life lithium metal anodes 通过在铜箔上丝网印刷网格状二氧化硅,实现超长寿命锂金属阳极的电活性/惰性双功能结构
IF 10.7 Q1 CHEMISTRY, PHYSICAL Pub Date : 2024-06-30 DOI: 10.1002/eom2.12478
Dongdong Li, Yue He, Bin Chen, Qingyi Liu, Jun Xu, Shengchen Yang, Wen-Yong Lai

Three-dimensional (3D) current collectors (CCs) have emerged as an effective strategy to inhibit dendrites and ensure the safety of lithium (Li) metal anodes. However, existing 3D CCs are generally too heavy (typically tens of mg cm−2) or too thick (tens to hundreds of micrometers), making large-scale production and further application challenging. Additionally, the use of single-component 3D CCs, whether electrically active or inert, only exhibits limited effects on stabilizing Li anodes. Here, we present a scalable screen-printing technique for the synthesis of ultralight (~0.4 mg cm−2) and ultrathin (~0.54 μm) SiO2 grids on Cu foil to regulate both the vertical electric field and Li-ion concentration by forming an electrically active/inert dual-function architecture. This technology breaks the limitations of traditional 3D CCs in material/fabrication costs, weight, thickness and especially, scalability for large-scale fabrication. By using this dual-function architecture, our Cu@SiO2-grid CCs (~8.31 mg cm−2), which are even lighter than the original Cu-foil CCs (~8.85 mg cm−2), realize an ultra-smooth anode surface without Li dendrites, and thus leads to an ultra-long cyclic life of over 1500 h at 1 mA cm−2. The assembled Li metal batteries demonstrate excellent capacity retention of ~80% over 400 cycles at 1 C and ~ 76% over 250 cycles at 5 C, which highlight the promising 3D CCs for practical applications.

三维(3D)电流收集器(CC)已成为抑制枝晶和确保锂(Li)金属阳极安全的有效策略。然而,现有的三维集电体通常太重(通常为几十毫克厘米-2)或太厚(几十到几百微米),使得大规模生产和进一步应用面临挑战。此外,使用单组分三维 CC,无论是电活性还是惰性,对稳定锂阳极的效果都很有限。在这里,我们提出了一种可扩展的丝网印刷技术,在铜箔上合成超轻(约 0.4 mg cm-2)、超薄(约 0.54 μm)的二氧化硅网格,通过形成电活性/惰性双功能结构来调节垂直电场和锂离子浓度。这项技术打破了传统 3D CC 在材料/制造成本、重量、厚度,特别是大规模制造的可扩展性方面的限制。通过使用这种双功能结构,我们的 Cu@SiO2 网格 CCs(约 8.31 mg cm-2)比原来的 Cu 箔 CCs(约 8.85 mg cm-2)更轻,实现了没有锂枝晶的超光滑阳极表面,从而在 1 mA cm-2 电流条件下实现了超过 1500 小时的超长循环寿命。组装后的金属锂电池在 1 摄氏度条件下循环 400 次以上可保持约 80% 的容量,在 5 摄氏度条件下循环 250 次以上可保持约 76% 的容量,显示出三维 CC 在实际应用中的广阔前景。
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