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A new spin on electrochemistry in the undergraduate lab 本科实验室对电化学的新解读
Pub Date : 2021-11-22 DOI: 10.1515/cti-2021-0013
Holly M. Fruehwald, Olena V. Zenkina, E. Easton
Abstract The growing interest in electrochemistry over recent years has sparked an increase in the popularity of various electrochemical techniques, including more advanced methods, that have previously been overlooked in academia and industry. This makes comprehensive hands-on experience in electrochemistry a highly demanded addition to chemistry graduates. However, many students do not receive sufficient training in the theory and experimental design to confidently use and apply various electrochemical techniques throughout their undergraduate, and sometimes even in graduate studies. Here we summarize the theory and practical applications for both rotating disk electrode (RDE) and rotating ring disk electrode (RRDE) techniques. The different modes of operation of rotating ring disk voltammetry, methodologies of data analysis and interpretation as well as the scope of the information that can be extracted from the RDE/RRDE are discussed. Proposed modifications of the laboratory curriculum will allow students to examine and learn valuable information about the reactions on the surface of the electrode/liquid interface. This information will allow chemists to confidently use RDE and RRDE techniques for a wide range of research and development targets. Furthermore, incorporating these techniques into existing chemistry laboratories will help chemistry educators to enrich the undergraduate chemistry curriculum and improve students’ learning outcomes.
近年来,人们对电化学的兴趣日益浓厚,导致各种电化学技术(包括更先进的方法)越来越受欢迎,这些技术以前在学术界和工业界被忽视。这使得全面的实践经验,在电化学高度要求除了化学毕业生。然而,许多学生在整个本科阶段,甚至在研究生阶段,都没有接受足够的理论和实验设计方面的培训,无法自信地使用和应用各种电化学技术。本文综述了旋转圆盘电极(RDE)技术和旋转环圆盘电极(RRDE)技术的理论和实际应用。讨论了旋转环盘伏安法的不同操作模式、数据分析和解释的方法以及可从RDE/RRDE中提取的信息范围。实验课程的建议修改将允许学生检查和学习有关电极/液体界面表面上的反应的有价值的信息。这些信息将使化学家能够自信地将RDE和RRDE技术用于广泛的研究和开发目标。此外,将这些技术纳入现有的化学实验室将有助于化学教育者丰富本科化学课程,提高学生的学习成果。
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引用次数: 4
Learning Green Chemistry and its principles from Nature’s process and development of green procedures mimicking nature 从大自然的过程中学习绿色化学及其原理,发展模仿自然的绿色程序
Pub Date : 2021-11-11 DOI: 10.1515/cti-2021-0023
B. Ranu, Laksmikanta Adak, Tubai Ghosh
Abstract We have highlighted an example of a natural process like photosynthesis to introduce the subject of Green Chemistry. Photosynthesis can be an ideal example to illustrate a green process explaining all the features such as selection of raw materials, solvent, catalyst, energy, etc. for an environment-friendly reaction. From the same reaction, all the principles of Green Chemistry can be derived in a simpler way without the need of memorizing these in a set language. In this article, a few examples of green procedures for the synthesis of useful molecules have been illustrated in light of the knowledge of photosynthesis. The visible-light mediated reactions, organic reactions in water, and solvent-free organic reactions are discussed here for a practical illustration of Green synthesis.
摘要我们着重介绍了光合作用等自然过程的一个例子,介绍了绿色化学这门学科。光合作用可以作为一个理想的例子来说明绿色过程,解释环境友好反应的所有特征,如原料、溶剂、催化剂、能量等的选择。从同样的反应中,绿色化学的所有原理都可以用一种更简单的方式推导出来,而不需要用一种固定的语言记住这些原理。在这篇文章中,根据光合作用的知识,举例说明了合成有用分子的绿色程序。本文讨论了可见光介导的反应、水中的有机反应和无溶剂有机反应,以实际说明绿色合成。
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引用次数: 3
Simple experiments with immobilized enzymes as a contribution to green and sustainable chemistry education in the high school laboratory 用固定化酶进行简单实验,为高中实验室的绿色和可持续化学教育做出贡献
Pub Date : 2021-10-20 DOI: 10.1515/cti-2021-0019
Michael Linkwitz, I. Eilks
Abstract Green chemistry became an eminent trend in chemical research and industry since the 1990s, and thus green chemistry is also increasingly suggested to become an issue in chemistry education. One of the principles of green chemistry is to use effective catalysis in general, and enzymatic catalysis under mild conditions in particular. This article presents a set of experiments under catalysis by immobilized lipase that were developed and tested in an action research project for developing a green organic chemistry curriculum for the senior secondary schooling level in Germany.
摘要:自20世纪90年代以来,绿色化学成为化学研究和工业的一个突出趋势,因此绿色化学也越来越被提出成为化学教育中的一个问题。绿色化学的原则之一是一般使用有效的催化剂,特别是在温和条件下的酶催化。本文介绍了在固定化脂肪酶催化下的一组实验,这些实验是在德国高中阶段开发绿色有机化学课程的行动研究项目中开发和测试的。
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引用次数: 2
Measuring the mass of an electron: an undergraduate laboratory experiment with high resolution mass spectrometry 测量电子质量:高分辨率质谱的本科生实验室实验
Pub Date : 2021-10-20 DOI: 10.1515/cti-2021-0016
M. Bouza, B. Gilbert-López, J. García-Reyes, Pilar Gema Rodríguez Ortega
Abstract High-resolution mass spectrometry (HRMS) has become increasingly affordable and user-friendly. Its potential spans a wide range of applications and experiments including the measurement of accurate masses, supporting the elucidation of elemental compositions and the identification of unknown compounds. To illustrate the main features of mass spectrometry, and particularly, of HRMS, we have designed and implemented a 3-h laboratory experiment using direct infusion electrospray HRMS analysis of non-steroidal anti-inflammatory drugs (e.g., ibuprofen or naproxen) solutions, acquiring full-scan spectra in both positive and negative ionization modes. The experimental accurate mass measurements (m/z values) of selected characteristic fragment ions -so called twin ions, with common elemental composition in both ionization modes but with different charge, allow the indirect measurement of the mass of an electron with relative errors below 5% with respect to the accepted IUPAC value (0.00055 Da). The experiment demonstrates how powerful and useful HRMS can be for research challenges often encountered during undergraduate or graduate research projects as well as for addressing undergraduate level general chemistry problems that provide the opportunity to discuss aspects related to the Nature of Science in an analytical chemistry context (such as measurement precision and accuracy).
高分辨率质谱(HRMS)已经变得越来越便宜和用户友好。它的潜力涵盖了广泛的应用和实验,包括精确质量的测量,支持元素组成的阐明和未知化合物的鉴定。为了说明质谱,特别是HRMS的主要特点,我们设计并实施了一个3小时的实验室实验,使用直接输注电喷雾HRMS分析非甾体抗炎药(如布洛芬或萘普生)溶液,获得正负电离模式下的全扫描光谱。所选择的特征碎片离子-即所谓的双离子,在两种电离模式下具有相同的元素组成,但具有不同的电荷,其实验精确的质量测量(m/z值)允许间接测量电子的质量,相对于公认的IUPAC值(0.00055 Da)的相对误差低于5%。实验证明了HRMS在解决本科或研究生研究项目中经常遇到的研究挑战以及解决本科水平的一般化学问题时是多么强大和有用,这些问题提供了在分析化学背景下讨论与科学本质相关的方面(如测量精度和准确性)的机会。
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引用次数: 1
Understanding Le Châtelier’s principle fundamentals: five key questions 理解Le Châtelier的基本原理:五个关键问题
Pub Date : 2021-10-15 DOI: 10.1515/cti-2020-0030
M. Peris
Abstract The well-known Le Châtelier’s principle is almost always mentioned when dealing with chemical equilibrium. Nevertheless, although a must in most general chemistry courses starting from the secondary level, when students face questions about it, some major misconceptions are often highlighted; to avoid this, a somewhat challenging problem is now presented. It can be deemed a very useful tool for a full understanding of this principle and chemical equilibrium as a whole. A generic chemical reaction at equilibrium is subject to different types of perturbation, and the student is required – in each case – to identify the new position of equilibrium among a number of proposals. The correct answers are finally provided along with the corresponding explanations.
在处理化学平衡时,人们几乎总是提到著名的勒夏·特立埃原理。然而,尽管从中学开始,在大多数普通化学课程中都是必须的,但当学生面对有关它的问题时,一些主要的误解往往会被突出;为了避免这种情况,现在提出了一个有点挑战性的问题。它可以被认为是一个非常有用的工具,以充分理解这一原理和化学平衡作为一个整体。处于平衡状态的一般化学反应会受到不同类型的扰动,在每种情况下,学生都需要在许多建议中确定新的平衡位置。最后给出了正确答案以及相应的解释。
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引用次数: 1
New approach for assigning mean oxidation number of carbons to organonitrogen and organosulfur compounds 计算有机氮和有机硫化合物碳平均氧化数的新方法
Pub Date : 2021-10-07 DOI: 10.1515/cti-2021-0015
Pong Kau Yuen, C. M. Lau
Abstract Organonitrogen and organosulfur compounds are abundant in the natural environment. To understand the biological redox pathways properly, it is important for learners to be able to count the oxidation number of organic carbons. However, the process of counting is not always easy. In addition, organonitrogen and organosulfur molecules are seldom studied. To compensate these problems, this paper explores the bond-dividing method, which can effectively determine the mean oxidation number of carbons of organonitrogen and organosulfur molecules. This method uses the cleavage of carbon-sulfur and carbon-nitrogen bonds to obtain the organic and inorganic fragments. The mean oxidation numbers of carbon atoms, nitrogen atoms, and sulfur atoms can be calculated by the molecular formulas of their fragments. Furthermore, when comparing organosulfur or organonitrogen molecules in a redox conversion, the changes of the mean oxidation numbers of carbon atoms, nitrogen atoms, and sulfur atoms can be used as indicators to identify the redox positions and determine the number of transferred electrons.
有机氮和有机硫化合物在自然环境中含量丰富。为了正确理解生物氧化还原途径,学习者能够计算有机碳的氧化数是很重要的。然而,计数的过程并不总是那么容易。此外,对有机氮和有机硫分子的研究很少。为了弥补这些问题,本文探索了能有效测定有机氮和有机硫分子平均碳氧化数的分键方法。该方法利用碳硫键和碳氮键的裂解得到有机和无机碎片。碳原子、氮原子和硫原子的平均氧化数可由其碎片的分子式计算得到。此外,在比较氧化还原转化过程中的有机硫或有机氮分子时,碳原子、氮原子和硫原子的平均氧化数的变化可以作为识别氧化还原位置和确定转移电子数的指标。
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引用次数: 7
Illustrating catalysis with a handmade molecular model set: catalytic oxidation of carbon monoxide over a platinum surface 说明催化与手工分子模型集:催化氧化一氧化碳在铂表面
Pub Date : 2021-08-02 DOI: 10.1515/cti-2021-0010
R. Horikoshi, Syota Nakajima, S. Hosokawa, Y. Kobayashi, H. Kageyama
Abstract Catalytic converters (automotive catalysts) and the chemical reactions they catalyze appear in general and introductory chemistry textbooks. Although the detailed mechanisms of the chemical reactions that occur in catalytic converters have been clearly revealed via recent developments in surface and computational chemistry research, the description and illustration of the catalysis are still ambiguous in textbooks. In this paper, we describe an extracurricular lecture whereby a handmade teaching aid was employed to illustrate the basic principle of the catalytic oxidation of carbon monoxide over platinum surface, which is an essential reaction occurring in catalytic converters. The teaching aid, constructed combining easily available materials, can illustrate the positions and motions of the molecules on the platinum surface during catalytic oxidation. The lecture was favorably received by non-chemistry majors and high school students. Despite the difficulty of the topic, the audience displayed a relatively high level of understanding.
催化转化器(汽车催化剂)及其催化的化学反应出现在一般和入门化学教科书中。虽然催化转化器中发生的化学反应的详细机制已经通过最近的表面化学和计算化学研究的发展清楚地揭示出来,但在教科书中对催化的描述和说明仍然是模糊的。在本文中,我们描述了一个课外讲座,其中使用手工教具来说明一氧化碳在铂表面催化氧化的基本原理,这是催化转化器中发生的重要反应。该教具结合了容易获得的材料,可以说明催化氧化过程中分子在铂表面的位置和运动。讲座受到非化学专业学生和高中生的好评。尽管这个话题很困难,但观众的理解程度还是比较高的。
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引用次数: 2
Educational reconstruction of size-depended-properties in nanotechnology for teaching in tertiary education 高等教育教学中纳米技术尺寸依赖特性的教育重建
Pub Date : 2021-07-13 DOI: 10.1515/cti-2021-0011
Ioannis Metaxas, Emily Michailidi, D. Stavrou, Ioannis V. Pavlidis
Abstract There is an overarching theme in Science Education to integrate in the school and university curriculum interdisciplinary state-of-art innovations. The field of Nanotechnology is such an example, because it combines the aforementioned interdisciplinarity and novelty with a well-documented educational value. Herein, a novel teaching approach concerning size-dependent properties at the nanoscale for chemistry and physics undergraduate students is proposed. The analysis of the scientific content and its following reconstruction for teaching purposes is based on the theoretical framework of the Model of Educational Reconstruction (MER). This analysis yielded two fundamental concepts and a series of activities that can be the main core of teaching Nanotechnology at a university level.
摘要在科学教育中,有一个首要主题是将跨学科的创新融入学校和大学的课程中。纳米技术领域就是这样一个例子,因为它将上述跨学科性和新颖性与有据可查的教育价值相结合。在此,提出了一种针对化学和物理本科生的纳米尺度尺寸相关特性的新教学方法。以教育重建模式为理论框架,对科学内容及其后续教学重建进行分析。这一分析得出了两个基本概念和一系列活动,这些概念和活动可以成为大学纳米技术教学的主要核心。
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引用次数: 2
Homemade bismuth plating by galvanic displacement from bismuth subsalicylate tablets: a chemistry experiment for distance learning 国产亚水杨酸铋片电镀铋的远程化学实验
Pub Date : 2021-06-30 DOI: 10.1515/cti-2021-0002
Jose Luis Aguilar-Charfen, Ines Castro-Sayago, Jimena Turnbull-Agraz, J. G. Ibanez
Abstract This paper presents a student-designed one-pot electroless deposition of Bi extracted from a Pepto Bismol® tablet by galvanic displacement of the Zn coating of a galvanized iron nail. This experiment relies on a readily accessible and reasonably safe method and materials and it has been used during the present COVID pandemic as a hands-on activity with higher education students (i.e., Junior and Senior Chemical Engineering students). Its simplicity should allow its use with High School students as well. The entire procedure can be completed in 30–45 min.
摘要本文介绍了一名学生设计的通过镀锌铁钉锌涂层的电流置换从Pepto Bismol®片剂中提取的铋的一锅化学沉积。该实验依赖于一种易于获得且合理安全的方法和材料,在当前的新冠肺炎疫情期间,它已被用作高等教育学生(即初级和高级化学工程学生)的动手活动。它的简单性应该允许高中生使用。整个过程可以在30–45分钟内完成。
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引用次数: 9
Using electrostatic potential maps as visual representations to promote better understanding of chemical bonding 使用静电势图作为视觉表示,以促进更好地理解化学键
Pub Date : 2021-06-10 DOI: 10.1515/cti-2021-0012
Georgios Tsaparlis, Giannoula Pantazi, E. Pappa, B. Byers
Abstract Static visual representations (VRs) of chemical structures are necessary for an understanding of chemical bonding, a topic which continues to lead to learning difficulties and misconceptions for many students. The efficacy and problems associated with the use of VRs of chemical structures and chemical bonding in the form of electrostatic potential maps resulting from accurate quantum mechanical calculations are the subject of this study, which involved a sample of first year, second semester students, studying the elective course “Science Education” (N = 31). Students distinguished between nonpolar and polar covalent bonding, however, they encountered difficulties with concepts related to ionic bonding. Most students did not employ multistructural thinking (in the sense of the SOLO taxonomy), when providing explanations about the variation of bond polarity. Persistence of a covalent-ionic bond dichotomy was apparent, while for some, ions can be involved in both ionic and covalent bonding. Many students preferred to use their established high school knowledge. On a positive note, many students were clearly affected by the information provided by the colored VRs. Finally, the minimal experience of our students with these VRs leads us to believe that a more systematic and extensive coverage would be likely to produce improved outcomes.
化学结构的静态视觉表示(vr)对于理解化学键是必要的,这一主题一直导致许多学生的学习困难和误解。通过精确的量子力学计算,以静电势图的形式使用化学结构和化学键的vr的功效和问题是本研究的主题,该研究涉及一年级,第二学期的学生样本,学习选修课程“科学教育”(N = 31)。学生区分了非极性共价键和极性共价键,然而,他们在离子键相关的概念上遇到了困难。在解释键极性的变化时,大多数学生没有使用多结构思维(在SOLO分类法的意义上)。共价键和离子键的二分法是显而易见的,而对一些离子来说,离子和共价键都可以参与。许多学生更喜欢运用他们已经掌握的高中知识。积极的一面是,许多学生明显受到了有色vr提供的信息的影响。最后,我们的学生对这些虚拟现实的最少体验使我们相信,更系统和更广泛的覆盖可能会产生更好的结果。
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引用次数: 4
期刊
Chemistry Teacher International : best practices in chemistry education
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