首页 > 最新文献

Journal of hazardous materials letters最新文献

英文 中文
Unwanted loss of volatile organic compounds (VOCs) during in situ chemical oxidation sample preservation: Mechanisms and solutions 原位化学氧化样品保存过程中挥发性有机化合物 (VOC) 的意外损失:机理与解决方案
Q2 Environmental Science Pub Date : 2024-02-01 DOI: 10.1016/j.hazl.2024.100102
Tae-Kyoung Kim , Donghyun Lee , Griffin Walsh , Changha Lee , David L. Sedlak

To assess the performance of hazardous waste sites remediation technologies like in situ chemical oxidation (ISCO) with persulfate (S2O82) researchers must periodically measure concentrations of target contaminants. Due to the presence of relatively high concentrations of the residual oxidant expected in many samples, the standard analytical method requires the addition of a relatively high concentration of ascorbic acid to prevent the oxidation process from continuing after sample collection. We discovered that addition of ascorbic acid quencher results in a radical chain reaction that transforms two common halogenated solvents (i.e., tetrachloroethene and hexachloroethane). To avoid the artifact associated with the radical chain reaction, a small quantity of n-hexane can be added to aqueous samples to extract target compounds and protect them from the radical chain reaction initiated by addition of the quencher. We recommend the use of this alternative sample preservation method whenever high concentrations of residual S2O82 are expected to be present in water samples that are contaminated with halogenated solvents.

为了评估危险废物场地修复技术(如使用过硫酸盐(S2O82-)的原位化学氧化(ISCO))的性能,研究人员必须定期测量目标污染物的浓度。由于许多样本中会存在相对高浓度的残留氧化剂,因此标准分析方法需要添加相对高浓度的抗坏血酸,以防止样本采集后氧化过程继续进行。我们发现,添加抗坏血酸淬灭剂会导致自由基链式反应,从而转化两种常见的卤代溶剂(即四氯乙烯和六氯乙烷)。为了避免与自由基链式反应相关的假象,可在水样中加入少量正己烷,以提取目标化合物,并保护它们免受因加入淬灭剂而引发的自由基链式反应的影响。如果预计受卤化溶剂污染的水样中会存在高浓度的残留 S2O82-,我们建议使用这种替代样品保存方法。
{"title":"Unwanted loss of volatile organic compounds (VOCs) during in situ chemical oxidation sample preservation: Mechanisms and solutions","authors":"Tae-Kyoung Kim ,&nbsp;Donghyun Lee ,&nbsp;Griffin Walsh ,&nbsp;Changha Lee ,&nbsp;David L. Sedlak","doi":"10.1016/j.hazl.2024.100102","DOIUrl":"10.1016/j.hazl.2024.100102","url":null,"abstract":"<div><p>To assess the performance of hazardous waste sites remediation technologies like in situ chemical oxidation (ISCO) with persulfate (S<sub>2</sub>O<sub>8</sub><sup>2<em>−</em></sup>) researchers must periodically measure concentrations of target contaminants. Due to the presence of relatively high concentrations of the residual oxidant expected in many samples, the standard analytical method requires the addition of a relatively high concentration of ascorbic acid to prevent the oxidation process from continuing after sample collection. We discovered that addition of ascorbic acid quencher results in a radical chain reaction that transforms two common halogenated solvents (i.e., tetrachloroethene and hexachloroethane). To avoid the artifact associated with the radical chain reaction, a small quantity of n-hexane can be added to aqueous samples to extract target compounds and protect them from the radical chain reaction initiated by addition of the quencher. We recommend the use of this alternative sample preservation method whenever high concentrations of residual S<sub>2</sub>O<sub>8</sub><sup>2<em>−</em></sup> are expected to be present in water samples that are contaminated with halogenated solvents.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911024000017/pdfft?md5=3338963548d57841b251e61872405d09&pid=1-s2.0-S2666911024000017-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139686243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low-temperature oxidation pathways are critical to thermal incineration of PFAS-laden materials 低温氧化途径对热焚烧含有全氟辛烷磺酸的材料至关重要
Q2 Environmental Science Pub Date : 2023-12-30 DOI: 10.1016/j.hazl.2023.100100
Rodger E. Cornell , Michael P. Burke

With growing desire to destroy per- and poly-fluoroalkyl substances (PFAS) now known to be detrimental to human health, a sound understanding of fluorocarbon combustion chemistry is important to efficient thermal destruction within incinerators. While most fluorocarbon combustion models and the sets of reactions contained within them were originally developed for the high temperatures encountered in flame suppression applications, they have often been used to assess PFAS destruction in incinerators, which emphasize a lower range of temperatures. We present results that demonstrate that low-temperature fluorocarbon oxidation pathways—not yet known to play a role in fluorocarbon combustion—impact key incinerator performance metrics, including: PFAS surrogate mole fractions, products of incomplete destruction, and waste destruction efficiencies. The results further point to the utility of NO as a potential additive. The present results show the influence of these pathways for CF3O2, for which some data are available, but analogous pathways would also occur for other fluoroalkylperoxy radicals, for which little is known. The results demonstrate the need for future work to identify and characterize low-temperature pathways more generally, consider such pathways in kinetic model development, and experimentally probe intermediate temperature conditions to better understand, design, and control thermal destruction technologies for improved PFAS management.

众所周知,全氟烷基和多氟烷基物质(PFAS)对人类健康有害,随着人们销毁这种物质的愿望日益强烈,正确理解碳氟化合物的燃烧化学性质对于在焚烧炉内进行高效热销毁非常重要。虽然大多数碳氟化合物燃烧模型及其中包含的成套反应最初是针对火焰抑制应用中遇到的高温而开发的,但它们经常被用于评估焚化炉中的 PFAS 销毁情况,因为焚化炉强调的是较低的温度范围。我们展示的结果表明,低温碳氟化合物氧化途径--目前还不知道它在碳氟化合物燃烧中的作用--会影响焚化炉的关键性能指标,其中包括PFAS 代用品摩尔分数、不完全销毁产物和废物销毁效率。研究结果进一步表明,氮氧化物是一种潜在的添加剂。本研究结果表明了这些途径对 CF3O2 的影响,目前已有一些相关数据,但对其他氟烷基过氧自由基也会产生类似的途径,而对这些自由基的了解还很少。这些结果表明,今后需要更广泛地确定和描述低温途径,在动力学模型开发中考虑这些途径,并通过实验探测中间温度条件,以更好地理解、设计和控制热破坏技术,从而改善全氟辛烷磺酸的管理。
{"title":"Low-temperature oxidation pathways are critical to thermal incineration of PFAS-laden materials","authors":"Rodger E. Cornell ,&nbsp;Michael P. Burke","doi":"10.1016/j.hazl.2023.100100","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100100","url":null,"abstract":"<div><p>With growing desire to destroy per- and poly-fluoroalkyl substances (PFAS) now known to be detrimental to human health, a sound understanding of fluorocarbon combustion chemistry is important to efficient thermal destruction within incinerators. While most fluorocarbon combustion models and the sets of reactions contained within them were originally developed for the high temperatures encountered in flame suppression applications, they have often been used to assess PFAS destruction in incinerators, which emphasize a lower range of temperatures. We present results that demonstrate that low-temperature fluorocarbon oxidation pathways—not yet known to play a role in fluorocarbon combustion—impact key incinerator performance metrics, including: PFAS surrogate mole fractions, products of incomplete destruction, and waste destruction efficiencies. The results further point to the utility of NO as a potential additive. The present results show the influence of these pathways for CF<sub>3</sub>O<sub>2</sub>, for which some data are available, but analogous pathways would also occur for other fluoroalkylperoxy radicals, for which little is known. The results demonstrate the need for future work to identify and characterize low-temperature pathways more generally, consider such pathways in kinetic model development, and experimentally probe intermediate temperature conditions to better understand, design, and control thermal destruction technologies for improved PFAS management.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000266/pdfft?md5=f8240c784c93e5ee1fd3cd1855b92519&pid=1-s2.0-S2666911023000266-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139100677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Uranium and arsenic bioremediation potential of plastic associated multi-metal tolerant Bacillus sp. EIKU23 与塑料相关的耐多金属芽孢杆菌 EIKU23 的铀和砷生物修复潜力
Q2 Environmental Science Pub Date : 2023-12-29 DOI: 10.1016/j.hazl.2023.100101
Atif Aziz Chowdhury , Nilendu Basak , Ekramul Islam

Plastic waste accumulation is a significant environmental concern as it promotes microbial growth and acts as a carrier for heavy metals. This study focuses on a Bacillus sp. strain isolated from the surface of a used plastic bottle, tolerant to various potential toxic elements (PTEs) such as chromium, nickel, cobalt, copper, zinc, arsenite [As(III)], but sensitive to uranium (U) and arsenate [As(V)] toxicity. The strain demonstrates growth under different abiotic stress conditions, with the optimal pH range of 5.0–8.0 and a temperature of 30 °C. It shows remarkable removal capabilities, removing > 23.3% of U, > 38% of As(III)), and > 22.6% of As(V) from an initial dose of 100 mg L−1 in an aqueous solution. The biosorption capacity for U, As(III), and As(V) is 3.12, 3.1, and 1.8 mg g−1 of biomass, respectively. Kinetic modelling suggests that the biosorption of U and As(V) follows a pseudo-second-order mechanism, while As(III) biosorption follows a pseudo-first-order mechanism. Moreover, the strain has the ability to precipitate > 38.1% and ∼67% of U using bacterially released phosphate from inorganic and organic sources, respectively. These findings highlight the strain's potential for bioremediation of PTE-contaminated environments, providing valuable insights for optimizing metal removal and immobilization processes in future research.

塑料垃圾会促进微生物的生长,并成为重金属的载体,因此塑料垃圾的积累是一个重大的环境问题。该菌株能耐受各种潜在有毒元素(PTEs),如铬、镍、钴、铜、锌、亚砷酸[As(III)],但对铀(U)和砷酸盐[As(V)]毒性敏感。该菌株可在不同的非生物胁迫条件下生长,最佳 pH 值范围为 5.0-8.0,温度为 30 °C。它显示出了卓越的去除能力,在初始剂量为 100 mg L-1 的水溶液中,它能去除 23.3% 的铀,38% 的 As(III),以及 22.6% 的 As(V)。生物质对铀、砷(III)和砷(V)的生物吸附容量分别为 3.12、3.1 和 1.8 mg g-1。动力学模型表明,U 和 As(V) 的生物吸附遵循伪二阶机制,而 As(III) 的生物吸附遵循伪一阶机制。此外,该菌株还能利用细菌从无机和有机来源释放的磷酸盐分别沉淀出 38.1% 和 67% 的铀。这些发现凸显了该菌株对受 PTE 污染的环境进行生物修复的潜力,为未来研究中优化金属去除和固定过程提供了宝贵的见解。
{"title":"Uranium and arsenic bioremediation potential of plastic associated multi-metal tolerant Bacillus sp. EIKU23","authors":"Atif Aziz Chowdhury ,&nbsp;Nilendu Basak ,&nbsp;Ekramul Islam","doi":"10.1016/j.hazl.2023.100101","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100101","url":null,"abstract":"<div><p>Plastic waste accumulation is a significant environmental concern as it promotes microbial growth and acts as a carrier for heavy metals. This study focuses on a <em>Bacillus</em> sp. strain isolated from the surface of a used plastic bottle, tolerant to various potential toxic elements (PTEs) such as chromium, nickel, cobalt, copper, zinc, arsenite [As(III)], but sensitive to uranium (U) and arsenate [As(V)] toxicity. The strain demonstrates growth under different abiotic stress conditions, with the optimal pH range of 5.0–8.0 and a temperature of 30 °C. It shows remarkable removal capabilities, removing &gt; 23.3% of U, &gt; 38% of As(III)), and &gt; 22.6% of As(V) from an initial dose of 100 mg L<sup>−1</sup> in an aqueous solution. The biosorption capacity for U, As(III), and As(V) is 3.12, 3.1, and 1.8 mg g<sup>−1</sup> of biomass, respectively. Kinetic modelling suggests that the biosorption of U and As(V) follows a pseudo-second-order mechanism, while As(III) biosorption follows a pseudo-first-order mechanism. Moreover, the strain has the ability to precipitate &gt; 38.1% and ∼67% of U using bacterially released phosphate from inorganic and organic sources, respectively. These findings highlight the strain's potential for bioremediation of PTE-contaminated environments, providing valuable insights for optimizing metal removal and immobilization processes in future research.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000278/pdfft?md5=00aa0ff43d77569d99ac4894ac3b04a7&pid=1-s2.0-S2666911023000278-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139100678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A brief study on heavy metal resistance genes from 10 genomes of Georgenia sp. and In vitro confirmation on Georgenia sp. SUBG003 关于 Georgenia sp. 10 个基因组中重金属抗性基因的简要研究和 Georgenia sp. SUBG003 的体外确认
Q2 Environmental Science Pub Date : 2023-12-15 DOI: 10.1016/j.hazl.2023.100097
Tejas Oza , Pooja Patel , Vrinda S. Thaker

Heavy metal pollution is consistently a critical issue in many parts of the world, affecting living systems remarkably. Many microorganisms possess such toxic metals utilizing capacities that can be explored for remediation. The present study demonstrates a comparative analysis of Mercury (Hg), Lead (Pb), Cobalt (Co), Zinc (Zn), and Magnesium (Mg) resistance genes in genomes of 11 different Georgenia sps. and confirmation of this gene pool in Georgenia sp. SUBG003 by growth on HgCl2, CdCl2, CoCl2, and ZnCl2 with varying concentrations and periods of up to 144hrs in a liquid medium and on a solid medium. Over a period HgCl2 initial concentrations 0.01 mM, 0.03 mM, and 0.05 mM showed controlled growth, at interim concentrations of 0.07 mM, 0.09 mM were found to be an interim effect while 0.11 mM, 0.13 mM and 0.15 mM higher concentrations showed increased growth. While CdCl2, CoCl2, and ZnCl2 showed growth inhibition upon increasing concentration from 0.01 mM to 0.5 mM. The concentrations tested are in a higher range than the polluted sources observed and the probable role in remediation is discussed.

重金属污染一直是世界许多地方的一个严重问题,对生物系统造成了极大的影响。许多微生物都具有利用有毒金属的能力,可用于补救。本研究对 11 种不同的 Georgenia sps 基因组中的汞(Hg)、铅(Pb)、钴(Co)、锌(Zn)和镁(Mg)抗性基因进行了比较分析,并通过在 HgCl2、CdCl2、CoCl2 和 ZnCl2(浓度不同,时间长达 144 小时)的液体培养基和固体培养基上的生长,确认了 Georgenia sp.在一段时间内,氯化汞初始浓度为 0.01 毫摩尔、0.03 毫摩尔和 0.05 毫摩尔时,生长受到控制;在中间浓度为 0.07 毫摩尔和 0.09 毫摩尔时,生长受到临时影响;而在 0.11 毫摩尔、0.13 毫摩尔和 0.15 毫摩尔的较高浓度下,生长有所增加。而 CdCl2、CoCl2 和 ZnCl2 在浓度从 0.01 mM 增加到 0.5 mM 时,生长受到抑制。所测试的浓度范围高于所观察到的污染源,并讨论了其在补救中可能发挥的作用。
{"title":"A brief study on heavy metal resistance genes from 10 genomes of Georgenia sp. and In vitro confirmation on Georgenia sp. SUBG003","authors":"Tejas Oza ,&nbsp;Pooja Patel ,&nbsp;Vrinda S. Thaker","doi":"10.1016/j.hazl.2023.100097","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100097","url":null,"abstract":"<div><p>Heavy metal pollution is consistently a critical issue in many parts of the world, affecting living systems remarkably. Many microorganisms possess such toxic metals utilizing capacities that can be explored for remediation. The present study demonstrates a comparative analysis of Mercury (Hg), Lead (Pb), Cobalt (Co), Zinc (Zn), and Magnesium (Mg) resistance genes in genomes of 11 different <em>Georgenia sps.</em> and confirmation of this gene pool in <em>Georgenia sp</em>. <em>SUBG003</em> by growth on HgCl<sub>2,</sub> CdCl<sub>2,</sub> CoCl<sub>2,</sub> and ZnCl<sub>2</sub> with varying concentrations and periods of up to 144hrs in a liquid medium and on a solid medium. Over a period HgCl<sub>2</sub> initial concentrations 0.01 mM, 0.03 mM, and 0.05 mM showed controlled growth, at interim concentrations of 0.07 mM, 0.09 mM were found to be an interim effect while 0.11 mM, 0.13 mM and 0.15 mM higher concentrations showed increased growth. While CdCl<sub>2,</sub> CoCl<sub>2,</sub> and ZnCl<sub>2</sub> showed growth inhibition upon increasing concentration from 0.01 mM to 0.5 mM. The concentrations tested are in a higher range than the polluted sources observed and the probable role in remediation is discussed.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000230/pdfft?md5=aaba4d3e16e515fbbe1925431a24cbf1&pid=1-s2.0-S2666911023000230-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138839553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Organochlorine pesticides remediation techniques: Technological perspective and opportunities 有机氯农药补救技术:技术视角与机遇
Q2 Environmental Science Pub Date : 2023-12-15 DOI: 10.1016/j.hazl.2023.100098
Afonso Henrique da Silva Júnior , Carlos Rafael Silva de Oliveira , Tarcisio Wolff Leal , António Benjamim Mapossa , Juliane Fiates , Antônio Augusto Ulson de Souza , Selene Maria de Arruda Guelli Ulson de Souza , Adriano da Silva

Organochlorine pesticides have been widely used in agriculture to control agricultural pests. Although effective in controlling pests, organochlorine pesticides present numerous hazards to ecosystems and human health due to their persistence in the environment, bioaccumulation, and toxicity. Scientific studies have shown that organochlorines may be associated with endocrine and neurological problems. Several strategies have been developed to apply treatment techniques to remove pesticides from various ecosystems, both aquatic and terrestrial. Physicochemical and biological methods have revealed other potentialities for remediation of aqueous environments contaminated with organochlorine pesticides. In addition, combined processes using different approaches have been highlighted as efficient alternatives to mitigate the impacts of agrochemicals on the environment, e.g., physical technique followed by a biological process. However, there are still numerous gaps that need to be explored and elucidated. Therefore, this review addressed the impacts of organochlorine pesticides on ecosystems and some treatment techniques used to remove agrochemicals from water. Furthermore, new findings, technological perspectives, and opportunities on this subject were presented and discussed.

有机氯杀虫剂被广泛用于农业,以控制农业害虫。有机氯杀虫剂虽然能有效控制害虫,但由于其在环境中的持久性、生物累积性和毒性,对生态系统和人类健康造成了诸多危害。科学研究表明,有机氯可能与内分泌和神经问题有关。目前已开发出多种策略,应用处理技术来清除水生和陆生生态系统中的农药。物理化学和生物方法揭示了修复受有机氯农药污染的水环境的其他潜力。此外,使用不同方法的组合工艺已被强调为减轻农用化学品对环境影响的有效替代方法,例如,先使用物理技术,再使用生物工艺。然而,仍有许多空白需要探索和阐明。因此,本综述探讨了有机氯农药对生态系统的影响以及用于去除水中农用化学品的一些处理技术。此外,还介绍和讨论了这一主题的新发现、技术前景和机遇。
{"title":"Organochlorine pesticides remediation techniques: Technological perspective and opportunities","authors":"Afonso Henrique da Silva Júnior ,&nbsp;Carlos Rafael Silva de Oliveira ,&nbsp;Tarcisio Wolff Leal ,&nbsp;António Benjamim Mapossa ,&nbsp;Juliane Fiates ,&nbsp;Antônio Augusto Ulson de Souza ,&nbsp;Selene Maria de Arruda Guelli Ulson de Souza ,&nbsp;Adriano da Silva","doi":"10.1016/j.hazl.2023.100098","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100098","url":null,"abstract":"<div><p>Organochlorine pesticides have been widely used in agriculture to control agricultural pests. Although effective in controlling pests, organochlorine pesticides present numerous hazards to ecosystems and human health due to their persistence in the environment, bioaccumulation, and toxicity. Scientific studies have shown that organochlorines may be associated with endocrine and neurological problems. Several strategies have been developed to apply treatment techniques to remove pesticides from various ecosystems, both aquatic and terrestrial. Physicochemical and biological methods have revealed other potentialities for remediation of aqueous environments contaminated with organochlorine pesticides. In addition, combined processes using different approaches have been highlighted as efficient alternatives to mitigate the impacts of agrochemicals on the environment, e.g., physical technique followed by a biological process. However, there are still numerous gaps that need to be explored and elucidated. Therefore, this review addressed the impacts of organochlorine pesticides on ecosystems and some treatment techniques used to remove agrochemicals from water. Furthermore, new findings, technological perspectives, and opportunities on this subject were presented and discussed.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000242/pdfft?md5=8af23a0ec38ba4a9457d4bfc3140910d&pid=1-s2.0-S2666911023000242-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138769789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A vape condensate collection method for degradant identification and toxicity screening 用于降解剂鉴定和毒性筛选的蒸汽冷凝物收集方法
Q2 Environmental Science Pub Date : 2023-12-15 DOI: 10.1016/j.hazl.2023.100099
Yanira Baldovinos, Precious Obiako, Clancy Collom, Christie M. Sayes

Since 2007, the market for e-cigarettes has resulted in increasing demand for newer technologies and flavorings contributing to the complexity of these products. As a result, methodologies for e-cigarette aerosol capturing and testing have become a necessity in understanding the toxicities surrounding e-cigarette products. This study tests an alternative aerosol capture method followed by toxicity testing of the sample collected on a lung in vitro model.

自 2007 年以来,电子烟市场对新技术和新香料的需求不断增加,导致这些产品变得更加复杂。因此,电子烟气溶胶捕获和测试方法已成为了解电子烟产品毒性的必要条件。本研究测试了一种替代气溶胶捕获方法,然后在肺部体外模型上对收集的样本进行了毒性测试。
{"title":"A vape condensate collection method for degradant identification and toxicity screening","authors":"Yanira Baldovinos,&nbsp;Precious Obiako,&nbsp;Clancy Collom,&nbsp;Christie M. Sayes","doi":"10.1016/j.hazl.2023.100099","DOIUrl":"10.1016/j.hazl.2023.100099","url":null,"abstract":"<div><p>Since 2007, the market for e-cigarettes has resulted in increasing demand for newer technologies and flavorings contributing to the complexity of these products. As a result, methodologies for e-cigarette aerosol capturing and testing have become a necessity in understanding the toxicities surrounding e-cigarette products. This study tests an alternative aerosol capture method followed by toxicity testing of the sample collected on a lung in vitro model.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000254/pdfft?md5=5f216618283c668952cd8167ecc21f45&pid=1-s2.0-S2666911023000254-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139018828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recycling of paper, cardboard and its PFAS in Norway 挪威纸张、纸板及其全氟辛烷磺酸的回收利用
Q2 Environmental Science Pub Date : 2023-12-14 DOI: 10.1016/j.hazl.2023.100096
Håkon A. Langberg , Hans Peter H. Arp , Gabriela Castro , Alexandros G. Asimakopoulos , Heidi Knutsen

Per- and polyfluoroalkyl substances (PFAS) have been used in paper products since the 1960s. PFAS emissions during the life cycle of these products have been substantial sources of these substances to the environment. Here, a total of 37 PFAS were analysed in 13 paper products sampled in 2021, for which some were made of virgin paper and others recycled paper, including food contact materials (FCM), packaging, and a notebook. In addition, different fractions of the recycling process of corrugated paper and board were sampled at a Norwegian cardboard recycling plant and analysed for the same PFAS, to get an overview of PFAS in the recycling stream of these materials in Norway. PFAS were found in recycled paper and board, indicating PFAS can be a non-intentionally added substance (NIAS) in recycled paper products. Sum of targeted PFAS detected in paper products (including products made of virgin and recycled materials) ranged between 0.4 and 971 µg kg−1, dominated by SAmPAP diester and 6:2 FTS (0–62% and 0–98%, respectively). The sum of targeted PFAS in returned corrugated paper and board in Norway is at least 32 kg per year (6 mg per capita per year). Recycling is important to ensure sustainability. As part of the broad PFAS restriction in Europe, PFAS are to be restricted in paper and board materials. Thus, lower levels of PFAS entering the recycling stream are expected in the future. Monitoring is necessary to assess reductions of PFAS in the paper waste stream due to PFAS regulations in Europe.

自 20 世纪 60 年代起,全氟烷基和多氟烷基物质 (PFAS) 就被用于纸制品中。这些产品在生命周期中排放的 PFAS 是环境中这些物质的主要来源。在此,我们对 2021 年采样的 13 种纸制品中的 37 种 PFAS 进行了分析,其中一些是原生纸,另一些是回收纸,包括食品接触材料 (FCM)、包装和笔记本。此外,还在挪威一家纸板回收厂对瓦楞纸和纸板回收过程中的不同部分进行了采样,并分析了相同的 PFAS,以了解挪威这些材料回收流中 PFAS 的总体情况。在回收的纸张和纸板中发现了 PFAS,这表明 PFAS 可能是回收纸制品中的一种非有意添加物质 (NIAS)。在纸制品(包括由原生材料和回收材料制成的产品)中检测到的目标 PFAS 总量介于 0.4 至 971 µg kg-1 之间,主要是 SAmPAP 二酯和 6:2 FTS(分别为 0-62% 和 0-98%)。挪威每年退回的瓦楞纸和纸板中的目标 PFAS 总量至少为 32 千克(每年人均 6 毫克)。回收利用对于确保可持续性非常重要。作为欧洲广泛限制 PFAS 的一部分,纸张和纸板材料中的 PFAS 将受到限制。因此,预计未来进入回收流的 PFAS 含量将会降低。有必要进行监测,以评估由于欧洲的 PFAS 法规,废纸流中 PFAS 的减少情况。
{"title":"Recycling of paper, cardboard and its PFAS in Norway","authors":"Håkon A. Langberg ,&nbsp;Hans Peter H. Arp ,&nbsp;Gabriela Castro ,&nbsp;Alexandros G. Asimakopoulos ,&nbsp;Heidi Knutsen","doi":"10.1016/j.hazl.2023.100096","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100096","url":null,"abstract":"<div><p>Per- and polyfluoroalkyl substances (PFAS) have been used in paper products since the 1960s. PFAS emissions during the life cycle of these products have been substantial sources of these substances to the environment. Here, a total of 37 PFAS were analysed in 13 paper products sampled in 2021, for which some were made of virgin paper and others recycled paper, including food contact materials (FCM), packaging, and a notebook. In addition, different fractions of the recycling process of corrugated paper and board were sampled at a Norwegian cardboard recycling plant and analysed for the same PFAS, to get an overview of PFAS in the recycling stream of these materials in Norway. PFAS were found in recycled paper and board, indicating PFAS can be a non-intentionally added substance (NIAS) in recycled paper products. Sum of targeted PFAS detected in paper products (including products made of virgin and recycled materials) ranged between 0.4 and 971 µg kg<sup>−1</sup>, dominated by SAmPAP diester and 6:2 FTS (0–62% and 0–98%, respectively). The sum of targeted PFAS in returned corrugated paper and board in Norway is at least 32 kg per year (6 mg per capita per year). Recycling is important to ensure sustainability. As part of the broad PFAS restriction in Europe, PFAS are to be restricted in paper and board materials. Thus, lower levels of PFAS entering the recycling stream are expected in the future. Monitoring is necessary to assess reductions of PFAS in the paper waste stream due to PFAS regulations in Europe.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000229/pdfft?md5=d86c1c260f87f7247fc717283dec3fda&pid=1-s2.0-S2666911023000229-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138839552","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyquaternium polymers cause inflammatory response and alterations of the lipidome in Danio rerio larvae 聚季铵盐聚合物会导致丹利欧幼虫出现炎症反应和脂质体改变
Q2 Environmental Science Pub Date : 2023-12-07 DOI: 10.1016/j.hazl.2023.100095
Anna Magdalene Brun Hansen , Rikke Poulsen , Louise von Gersdorff Jørgensen , Martin Hansen

Polyquaternium polymers are widely used in various applications, such as personal care products and wastewater treatment plants, and eventually end up in the aquatic environment. While polymers have been perceived of low toxicological concern due to their size, several studies have pointed towards water-soluble cationic polymers being toxic towards aquatic organisms – and that the toxicity largely is determined by the polymer charge density. The present study investigated the polyquaternium toxicological mechanism of action throughout lipidomic analysis and changes in immune-gene expression (qPCR) of zebrafish larvae exposed continuously to two water-soluble polymers; a high charge density polyquaternium-6 and a low charge density polyquaternium-10, for 5 and 12 days upon fertilization. The results showed that the investigated polyquaterniums cause both inflammatory responses and significant alterations of the zebrafish larvae lipidome. Depending on polyquaternium polymer and larvae development stage, the gene expression showed an inflammatory response (e.g. significant up-regulation of il8, il1β and tnfα) in the exposed zebrafish. Alterations of the lipidome were additionally observed, with severe depletion of lipids (e.g. lyso-glycerophosphocholines and ceramides) in the 12 days old larvae exposed to high charge density polymer. The findings furthermore support a hypothetical mechanism of action to be non-specific and lethality potentially to be narcosis-like driven.

聚季铵盐聚合物被广泛应用于个人护理产品和污水处理厂等各种应用中,并最终进入水生环境。虽然聚合物由于其大小而被认为是低毒理学问题,但一些研究指出水溶性阳离子聚合物对水生生物是有毒的-并且毒性在很大程度上取决于聚合物的电荷密度。本研究通过脂质组学分析和连续暴露于两种水溶性聚合物的斑马鱼幼鱼免疫基因表达(qPCR)的变化,研究了聚季铵盐的毒理学作用机制;高电荷密度的聚季铵盐-6和低电荷密度的聚季铵盐-10,受精后5天和12天。结果表明,所研究的聚季铵盐引起斑马鱼幼鱼脂质组的炎症反应和显著改变。根据聚季铵盐聚合物和幼虫发育阶段的不同,暴露的斑马鱼表现出炎症反应(如il - 8、il - 1β和tnf - α显著上调)。脂质组的改变也被观察到,在暴露于高电荷密度聚合物的12天大的幼虫中,脂质(如溶甘油磷胆碱和神经酰胺)严重耗损。这些发现进一步支持了一种假设的作用机制,即非特异性和致死率可能是由麻醉样驱动的。
{"title":"Polyquaternium polymers cause inflammatory response and alterations of the lipidome in Danio rerio larvae","authors":"Anna Magdalene Brun Hansen ,&nbsp;Rikke Poulsen ,&nbsp;Louise von Gersdorff Jørgensen ,&nbsp;Martin Hansen","doi":"10.1016/j.hazl.2023.100095","DOIUrl":"10.1016/j.hazl.2023.100095","url":null,"abstract":"<div><p>Polyquaternium polymers are widely used in various applications, such as personal care products and wastewater treatment plants, and eventually end up in the aquatic environment. While polymers have been perceived of low toxicological concern due to their size, several studies have pointed towards water-soluble cationic polymers being toxic towards aquatic organisms – and that the toxicity largely is determined by the polymer charge density. The present study investigated the polyquaternium toxicological mechanism of action throughout lipidomic analysis and changes in immune-gene expression (qPCR) of zebrafish larvae exposed continuously to two water-soluble polymers; a high charge density polyquaternium-6 and a low charge density polyquaternium-10, for 5 and 12 days upon fertilization. The results showed that the investigated polyquaterniums cause both inflammatory responses and significant alterations of the zebrafish larvae lipidome. Depending on polyquaternium polymer and larvae development stage, the gene expression showed an inflammatory response (e.g. significant up-regulation of <em>il8</em>, <em>il1β</em> and <em>tnfα</em>) in the exposed zebrafish. Alterations of the lipidome were additionally observed, with severe depletion of lipids (e.g. lyso-glycerophosphocholines and ceramides) in the 12 days old larvae exposed to high charge density polymer. The findings furthermore support a hypothetical mechanism of action to be non-specific and lethality potentially to be narcosis-like driven.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000217/pdfft?md5=9d3433fbad769174ad36916e21de8aff&pid=1-s2.0-S2666911023000217-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138619618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook 高效降解有机染料废水的铜- BTC金属-有机框架材料的研究进展:合成、机理及展望
Q2 Environmental Science Pub Date : 2023-11-23 DOI: 10.1016/j.hazl.2023.100094
Saptarshi Roy, Jnyanashree Darabdhara, Md. Ahmaruzzaman

Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented.

水传播的新兴污染物是现代社会面临的重大挑战。由于纺织和其他工业过度使用染料和颜料,大量这些有毒和难降解物质广泛散布到水生资源中,除了对生态系统造成潜在破坏外,还可能对所有生命形式造成严重的健康问题。废水中这些有害且不可生物降解的有机污染物的处理已成为环境修复研究人员关注的焦点。值得注意的是,据报道,金属有机框架(MOFs)及其复合材料是解决这些挑战的有前途的材料。这篇综述通过整合Cu-BTC MOF的各种有益属性,提供了一个简明的概述,使其成为一种用途广泛的材料,应用于各个领域,重点是反应性,金属离子的作用及其最近在解决废水中有毒纺织染料废物的消除方面的潜力。此外,它还记录了控制Cu - BTC降解机制和优越电子传输特性的潜在机制途径,此外还详细描述了阻碍其在工业平台上适用性的现有限制。此外,还提出了一组未来的研究展望,作为探索Cu - BTC mof潜力的路线图。
{"title":"Recent advances of Copper- BTC metal-organic frameworks for efficient degradation of organic dye-polluted wastewater: Synthesis, mechanistic insights and future outlook","authors":"Saptarshi Roy,&nbsp;Jnyanashree Darabdhara,&nbsp;Md. Ahmaruzzaman","doi":"10.1016/j.hazl.2023.100094","DOIUrl":"https://doi.org/10.1016/j.hazl.2023.100094","url":null,"abstract":"<div><p>Water borne emerging pollutants represents a significant challenge confronting the modern society. As a result of excessive use of dyes and pigments by the textile and other industries, substantial amount of these toxic and recalcitrant substances are widely dispersed into the aquatic sources that may raise serious health issues to all life forms besides causing potential disruption to the ecosystem. Treatments of these hazardous and non-biodegradable organic contaminants in wastewater effluents have become a focal point for researchers dedicated to environmental remediation. Notably, Metal organic frameworks (MOFs) and their composites have been reported to be promising materials for tackling such challenges. This review is dedicated to provide a concise overview by consolidating the diverse beneficial attributes of Cu-BTC MOF rendering it as a versatile material with applications spanning diverse domains, focusing on the reactivity, the role of the metal ion and its recent potential for addressing the elimination of toxic textile dye wastes from the wastewater effluent. Furthermore, it also documents the underlying mechanistic pathway governing the degradation mechanism and the superior electron transport property of Cu ̶ BTC, besides painting in detail the existing limitations that hinder their applicability at an industrial platform. Moreover, a set of future research outlooks serving as a roadmap for exploring the potentiality of Cu ̶ BTC MOFs have also been presented.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000205/pdfft?md5=03140f376cdb280fc9234d3f37f5b7eb&pid=1-s2.0-S2666911023000205-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138501249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding arsenic toxicity: Implications for environmental exposure and human health 了解砷毒性:对环境暴露和人类健康的影响
Q2 Environmental Science Pub Date : 2023-11-04 DOI: 10.1016/j.hazl.2023.100090
Ravidarshdeep kaur , Atul Garkal , Lopmudra Sarode , Priyanka Bangar , Tejal Mehta , Dhirendra Pratap Singh , Rakesh Rawal

Arsenic is a trace element and a metalloid which is prominently known as an environmental hazard. At present, rising health apprehensions are linked to emanating from a wide array of industrial, chemical, residential, agricultural, and technological sources, leading to extensive pollution of water, soil, and air ecosystems including flora, fauna and humans. It poses significant harm to biological organisms upon acute and chronic exposure. In this review, we delve into the reported experimental data that elaborates on arsenic as a toxicant, with particular emphasis on its occurrence, metabolism and diverse molecular mechanisms involved. It also includes the major molecular mechanisms leading to systemic toxicity with special emphasis on shedding light on the intricate ways it disrupts the nervous system.

砷是一种微量元素和类金属,是众所周知的环境危害。目前,越来越多的健康担忧与一系列广泛的工业、化学、住宅、农业和技术来源有关,导致包括动植物和人类在内的水、土壤和空气生态系统受到广泛污染。急性和慢性暴露对生物机体造成重大危害。在这篇综述中,我们深入研究了报道的实验数据,详细阐述了砷作为一种毒物,特别强调了它的发生、代谢和不同的分子机制。它还包括导致全身毒性的主要分子机制,特别强调揭示它破坏神经系统的复杂方式。
{"title":"Understanding arsenic toxicity: Implications for environmental exposure and human health","authors":"Ravidarshdeep kaur ,&nbsp;Atul Garkal ,&nbsp;Lopmudra Sarode ,&nbsp;Priyanka Bangar ,&nbsp;Tejal Mehta ,&nbsp;Dhirendra Pratap Singh ,&nbsp;Rakesh Rawal","doi":"10.1016/j.hazl.2023.100090","DOIUrl":"10.1016/j.hazl.2023.100090","url":null,"abstract":"<div><p>Arsenic is a trace element and a metalloid which is prominently known as an environmental hazard. At present, rising health apprehensions are linked to emanating from a wide array of industrial, chemical, residential, agricultural, and technological sources, leading to extensive pollution of water, soil, and air ecosystems including flora, fauna and humans. It poses significant harm to biological organisms upon acute and chronic exposure. In this review, we delve into the reported experimental data that elaborates on arsenic as a toxicant, with particular emphasis on its occurrence, metabolism and diverse molecular mechanisms involved. It also includes the major molecular mechanisms leading to systemic toxicity with special emphasis on shedding light on the intricate ways it disrupts the nervous system.</p></div>","PeriodicalId":93463,"journal":{"name":"Journal of hazardous materials letters","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666911023000163/pdfft?md5=834a86ea1d64b7090a225e5b2f8fa1f7&pid=1-s2.0-S2666911023000163-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135455184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Journal of hazardous materials letters
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1