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Removing heavy metal ions from wastewater by Chlorella sorokiniana coupled to manganese-doped magnetic ferrite nanoparticles 小球藻偶联锰掺杂磁性铁氧体纳米颗粒去除废水中的重金属离子
Q2 Environmental Science Pub Date : 2023-08-17 DOI: 10.1016/j.hazl.2023.100082
Louie A. Lapeñas , Janire Peña-Bahamonde , Lúrima Uane Soares Faria , Mark Daniel G. de Luna , Debora F. Rodrigues

In this study, we investigated the benefit of combining Chlorella sorokiniana with manganese-containing ferrite nanoparticles (NPs) for heavy metal removal and cell harvesting. Our results demonstrate that the combination of non-toxic nanoparticles significantly enhances the heavy metal removal capacity of C. sorokiniana without affecting its growth. The microalgae combined with NPs was able to sequester Cr6+, Co2+, and Ni2+ from aqueous solutions and could remove these metals at a higher adsorption capacity and within a relatively short time than their individual counterparts, indicating a synergistic effect between the algal cells and the nanomaterials, where bioadsorption and chemisorption were the main players. Both biosorption and chemisorption capacities were found to be the highest for single-metal systems and decreased when coexisting ions were present in the solution. The adsorption of the heavy metals evaluated was better described by the pseudo-second order model than the pseudo-first order model, indicating that chemisorption dominated over physisorption. These characteristics suggest that the combination of biosorbents with nanosorbents is a promising approach for the treatment of water contaminated with heavy metals making this process more efficient, economical, sustainable, and clean.

在这项研究中,我们研究了小球藻与含锰铁氧体纳米颗粒(NPs)结合对重金属去除和细胞收获的益处。结果表明,无毒纳米颗粒的组合显著提高了sorokiniana的重金属去除能力,而不影响其生长。结合NPs的微藻对Cr6+、Co2+和Ni2+具有较强的吸附能力,并且在相对较短的时间内对这些金属具有较强的吸附能力,表明微藻细胞与纳米材料之间存在协同作用,其中生物吸附和化学吸附是主要的作用机制。发现单金属体系的生物吸附和化学吸附能力最高,当溶液中存在共存离子时,生物吸附和化学吸附能力下降。拟二级吸附模型比拟一级吸附模型能更好地描述吸附过程,表明化学吸附作用大于物理吸附作用。这些特征表明,生物吸附剂与纳米吸附剂的结合是处理重金属污染水的一种很有前途的方法,使处理过程更加高效、经济、可持续和清洁。
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引用次数: 0
Insight into the highly-selective separation of Fe(III) with cinnamon-like blended fiber 类肉桂混合纤维对Fe(III)的高选择性分离研究
Q2 Environmental Science Pub Date : 2023-08-16 DOI: 10.1016/j.hazl.2023.100083
Xi Zhang , Weiguo Zhang , Yao Feng , Zhengbin Li , Fuqiang Liu , Aimin Li

The separation and recovery of Fe(III) in heavy metal mixtures is a great challenge due to its strong ion exchange property. In this study, we developed a novel cinnamon-like blended fiber (PAN/PEG) using electrostatic spinning and dissolution post-treatment, which exhibited highly selective separation properties and satisfactory adsorption capacity for Fe(III). Owing to the preferential coordination of Fe(III) with both cyanide and hydroxyl groups, PAN/PEG possessed such excellent adsorption capacity as 1.12 mmol/g. Notably, the infinite selective separation coefficient between Fe(III) and other heavy metal ions (HMIs) achieved even from the octa-mixed metal systems. Furthermore, PAN/PEG demonstrated good anti-interference ability against coexisting inorganic salts. In addition, PAN/PEG was highly effective in removing lower concentration Fe(III) from complex PTA wastewater with super-high selectivity, which enabled the subsequent purification of Co(II) and Mn(II). Overall, PAN/PEG could be prepared and recovered facilely, and had great potential in the exclusive separation of Fe(III).

铁(III)具有较强的离子交换特性,是重金属混合物中分离和回收的一大挑战。本研究采用静电纺丝和溶解后处理的方法制备了一种新型的肉桂类共混纤维(PAN/PEG),该纤维具有高度的选择性分离性能和对Fe(III)的良好吸附能力。由于Fe(III)与氰化物和羟基的优先配位,PAN/PEG具有1.12 mmol/g的优异吸附量。值得注意的是,即使在八元混合金属体系中,Fe(III)和其他重金属离子(hmi)之间也实现了无限的选择性分离系数。此外,PAN/PEG对共存无机盐表现出良好的抗干扰能力。此外,PAN/PEG对复杂PTA废水中低浓度Fe(III)具有超高选择性去除效果,从而实现Co(II)和Mn(II)的后续净化。综上所述,PAN/PEG制备方便,回收方便,在Fe(III)的纯分离方面具有很大的潜力。
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引用次数: 0
Mesoporous tubular g-C3N4 as an efficient metal-free photocatalyst with peroxymonosulfate to degrade carbamazepine 介孔管状g-C3N4与过氧单硫酸盐降解卡马西平的高效无金属光催化剂
Q2 Environmental Science Pub Date : 2023-07-29 DOI: 10.1016/j.hazl.2023.100081
Yanchun Huang , Lingxiao Yang , Weifang Huang , Jun Li , Chao Liu , Bo Lai , Naiwen Li

In advanced oxidation processes with metal-containing catalysts, metal dissolution usually leads to reduced efficiency and biotoxicity. Therefore, it is very important to find efficient non-metallic materials. In this work, a metal-free mesoporous tubular g-C3N4 was fabricated using melamine and urea mixed according to the mass ratios of 1:12 (TPCN12) by a facile one-step thermal polymerization method. Mesoporous tubular TPCN12 was proved to be successfully synthesized by scanning electron microscope (SEM) and X-ray diffraction (XRD). Then the degradation of carbamazepine (CBZ) by activating peroxymonosulfate (PMS) of TPCN12 under visible light was investigated. It was found that degradation rate constant of CBZ in TPCN12/Vis/PMS system (0.0939 min−1) exhibited great superiority over that in TPCN12/Vis system (0.0149 min−1) and in TPCN12/PMS system, which indicated TPCN12, Vis and PMS had a synergistic effect. The dominant role of the electron transfer and the primary contribution of the holes (h+) and •O2 reactive species were revealed in TPCN12/Vis/ PMS system. Furthermore, the system showed sufficient advantages over a wide pH range and high resistance to inorganic anions. In general, the TPCN12/Vis/PMS system was capable of high stability and recyclability. This metal-free mesoporous tubular catalyst was proposed to achieve efficient and green elimination of pharmaceutical organic pollutants.

在含金属催化剂的高级氧化过程中,金属溶解通常会导致效率降低和生物毒性。因此,寻找高效的非金属材料是非常重要的。本研究以三聚氰胺和尿素按1:12的质量比(TPCN12)为原料,采用简单的一步热聚合法制备了无金属介孔管状g-C3N4。通过扫描电子显微镜(SEM)和x射线衍射仪(XRD)证实了介孔管状TPCN12的成功合成。研究了TPCN12活化过氧单硫酸盐(PMS)在可见光下对卡马西平(CBZ)的降解作用。结果表明,CBZ在TPCN12/Vis/PMS体系中的降解速率常数(0.0939 min−1)明显优于TPCN12/Vis体系和TPCN12/PMS体系中的降解速率常数(0.0149 min−1),表明TPCN12、Vis和PMS具有协同效应。在TPCN12/Vis/ PMS体系中,电子转移起主导作用,空穴(h+)和•O2−反应物质起主要作用。此外,该体系在较宽的pH范围和对无机阴离子的高抗性方面表现出足够的优势。总体而言,TPCN12/Vis/PMS体系具有较高的稳定性和可回收性。该无金属介孔管状催化剂是为实现高效、绿色去除医药类有机污染物而提出的。
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引用次数: 1
Burning questions: Current practices and critical gaps in evaluating removal of per- and polyfluoroalkyl substances (PFAS) during pyrolysis treatments of biosolids 亟待解决的问题:评估生物固体热解处理过程中全氟烷基和多氟烷基物质(PFAS)去除的当前做法和关键差距
Q2 Environmental Science Pub Date : 2023-06-27 DOI: 10.1016/j.hazl.2023.100079
Joshua S. Wallace , Dulan Edirisinghe , Saba Seyedi , Haley Noteboom , Micah Blate , Derya Dursun Balci , Mohammad Abu-Orf , Robert Sharp , Jeanette Brown , Diana S. Aga

Concerns surrounding potential health and environmental impacts of per- and polyfluoroalkyl substances (PFAS) are growing at tremendous rates because adverse health impacts are expected with trace-level exposures. Extreme measures are required to mitigate potential PFAS contamination and minimize exposures. Extensive PFAS use results in the release of diverse PFAS species from domestic, industrial, and municipal effluents to wastewater, which partition to biosolids throughout secondary treatment. Biosolids generated during municipal wastewater treatment are a major environmental source of PFAS due to prevailing disposal practices as fertilizers. Pyrolysis is emerging as a viable, scalable technology for PFAS removal from biosolids while retaining nutrients and generating renewable, raw materials for energy generation. Despite early successes of pyrolysis in PFAS removal, significant unknowns remain about PFAS and transformation product fates in pyrolysis products and emissions. Applicable PFAS sampling methods, analytical workflows, and removal assessments are currently limited to a subset of high-interest analytes and matrices. Further, analysis of exhaust gases, particulate matter, fly ashes, and other pyrolysis end-products remain largely unreported or limited due to cost and sampling limitations. This paper identifies critical knowledge gaps on the pyrolysis of biosolids that must be addressed to assess the effectiveness of PFAS removal during pyrolysis treatment.

对全氟烷基和多氟烷基物质(PFAS)潜在健康和环境影响的关注正在以惊人的速度增长,因为预计微量接触会对健康产生不利影响。需要采取极端措施来减轻潜在的PFAS污染并尽量减少暴露。PFAS的广泛使用导致各种PFAS从家庭、工业和城市污水中释放到废水中,在二级处理过程中分解成生物固体。在城市污水处理过程中产生的生物固体是PFAS的主要环境来源,因为普遍的处理做法是作为肥料。热解是一种可行的、可扩展的技术,可用于从生物固体中去除PFAS,同时保留营养物质并产生可再生的能源原料。尽管热解在去除PFAS方面取得了早期的成功,但对于热解产物和排放中的PFAS及其转化产物的命运仍然存在重大的未知因素。适用的PFAS取样方法、分析工作流程和去除评估目前仅限于高兴趣分析物和矩阵的子集。此外,由于成本和采样限制,废气、颗粒物、飞灰和其他热解最终产物的分析在很大程度上没有报道或受到限制。本文确定了生物固体热解的关键知识空白,必须解决这些空白,以评估热解处理过程中PFAS去除的有效性。
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引用次数: 0
Analysis of ultraviolet and thermal degradations of four common microplastics and evidence of nanoparticle release 四种常见微塑料的紫外线和热降解分析及纳米颗粒释放的证据
Q2 Environmental Science Pub Date : 2023-04-17 DOI: 10.1016/j.hazl.2023.100078
Laura M. Hernandez , Joel Grant , Parvin Shakeri Fard , Jeffrey M. Farner , Nathalie Tufenkji

Many environmental factors affect the breakdown of plastics in aquatic environments, including exposure to ultraviolet (UV) irradiation and elevated environmental temperatures. More studies are needed to understand how these stressors contribute to plastic degradation, resulting in the release of smaller plastic particles. We studied the impact of environmentally relevant UV and temperature (37 °C) weathering of four high-production volume plastics (polystyrene, polypropylene, low-density polyethylene, and high-density polyethylene) suspended in water. Particle release was detected, characterized by scanning electron microscopy (SEM), and nanoparticles were quantified by nanoparticle tracking analysis (NTA). Weathering resulted in the release of micro- and nanoparticles that exhibited a plastic signature corresponding to the parent microplastic. Nanoparticle release is broadly correlated with an increase in the carbonyl index of the parent microplastic. Aged microplastics were characterized for physical and chemical changes. The impact of weathering on microplastic surface hardness and polymer oxidation depended on material type and environmental factors. Few to no particles were observed in controls, including controls that contained microplastics at 4 °C in dark conditions, highlighting the importance of weathering stimuli in particle release. These results show that plastic degradation needs to consider both the parent microplastic and the smaller particles that are formed.

许多环境因素影响塑料在水生环境中的分解,包括暴露于紫外线(UV)照射和环境温度升高。需要更多的研究来了解这些压力源如何导致塑料降解,从而释放出更小的塑料颗粒。我们研究了悬浮在水中的四种大批量塑料(聚苯乙烯、聚丙烯、低密度聚乙烯和高密度聚乙烯)的环境相关紫外线和温度(37°C)风化的影响。采用扫描电镜(SEM)检测颗粒释放,纳米颗粒跟踪分析(NTA)定量。风化作用导致微颗粒和纳米颗粒的释放,这些微颗粒表现出与母体微塑料相对应的塑性特征。纳米颗粒释放与母体微塑料羰基指数的增加广泛相关。老化微塑料的物理和化学变化进行了表征。风化对微塑料表面硬度和聚合物氧化的影响取决于材料类型和环境因素。在对照组中,包括在4°C的黑暗条件下含有微塑料的对照组,几乎没有观察到颗粒,这突出了风化刺激在颗粒释放中的重要性。这些结果表明,塑料降解既需要考虑母体微塑料,也需要考虑形成的较小颗粒。
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引用次数: 0
Revising the EPA dilution-attenuation soil screening model for PFAS 修正EPA对PFAS的稀释衰减筛分模型
Q2 Environmental Science Pub Date : 2023-03-20 DOI: 10.1016/j.hazl.2023.100077
Mark L. Brusseau , Bo Guo

Per and polyfluoroalkyl substances (PFAS) have been shown to be ubiquitous in the environment, and one issue of critical concern is the leaching of PFAS from soil to groundwater. The risk posed by contaminants present in soil is often assessed in terms of the anticipated impact to groundwater through the determination of soil screening levels (SSLs). The U.S. Environmental Protection Agency (EPA) established a soil screening model for determining SSLs. However, the model does not consider the unique retention properties of PFAS and, consequently, the SSLs established with the model may not represent the actual levels that are protective of groundwater quality. The objective of this work is to revise the standard EPA SSL model to reflect the unique properties and associated retention behavior of PFAS. Specifically, the distribution parameter used to convert soil porewater concentrations to soil concentrations is revised to account for adsorption at the air-water interface. Example calculations conducted for PFOS and PFOA illustrate the contrasting SSLs obtained with the revised and standard models. A comparison of distribution parameters calculated for a series of PFAS of different chain length shows that the significance of air-water interfacial adsorption can vary greatly as a function of the specific PFAS. Therefore, the difference between SSLs calculated with the revised versus standard models will vary as a function of the specific PFAS, with greater differences typically observed for longer-chain PFAS. It is anticipated that this revised model will be useful for developing improved SSLs that can be used to enhance site investigations and management for PFAS-impacted sites.

Synopsis

The widely used EPA SSL model is revised for PFAS applications to account for adsorption at the air-water interface.

已证明全氟磺酸和多氟烷基物质(PFAS)在环境中无处不在,其中一个严重关切的问题是PFAS从土壤向地下水的浸出。土壤中存在的污染物所构成的风险通常通过确定土壤筛选水平(SSLs)来评估对地下水的预期影响。美国环境保护署(EPA)建立了一种土壤筛选模型来确定土壤中SSLs。然而,该模型没有考虑到PFAS独特的保留特性,因此,用该模型建立的SSLs可能不能代表保护地下水质量的实际水平。这项工作的目的是修订标准EPA SSL模型,以反映PFAS的独特性质和相关的保留行为。具体来说,用于将土壤孔隙水浓度转换为土壤浓度的分布参数进行了修正,以考虑空气-水界面的吸附。对全氟辛烷磺酸和全氟辛烷磺酸进行的算例计算说明了修正模型和标准模型所得到的SSLs的对比。对不同链长PFAS的分布参数进行了比较,结果表明,不同类型的PFAS对空气-水界面吸附的影响差异很大。因此,修正模型与标准模型计算的SSLs之间的差异将随着特定PFAS的函数而变化,对于长链PFAS通常观察到更大的差异。预期这个修订后的模型将有助于发展更完善的安全证书,以加强受pfas影响地点的现场调查和管理。广泛使用的EPA SSL模型针对PFAS应用进行了修订,以考虑空气-水界面的吸附。
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引用次数: 2
Exploring the untapped potentials of oily sludge ash blended with fly ash for geopolymer binder via waste valorisation approach 通过废物增值方法探索含油污泥灰与粉煤灰混合作为地聚合物粘合剂的未开发潜力
Q2 Environmental Science Pub Date : 2023-03-20 DOI: 10.1016/j.hazl.2023.100076
Vicky Kumar , Shamsul Rahman Mohamed Kutty , Siti Nooriza Abd Razak , Nasir Shafiq , Abiola Adebanjo , Lavania Baloo , Ahmed-Aberkan Azougagh , Rilind Iseni

Globally, large quantities of oily sludge are produced in petroleum refineries as wastes from petroleum refining processes. Petroleum refinery oily sludge (PROS) is a major by-product of the processes and a major contributor to pollution in the oil and gas industry. In this study, Response Surface Methodology (RSM) was used for optimising and modelling experimental work. Thermally treated PROS replaced fly ash (FA) at 5–20 % in geopolymer mortar mixes at a fixed combination of sodium silicate (Na2SiO3) and sodium hydroxide (NaOH). The visual observations and effects of PROS on the density and compressive strength of PROS geopolymer mortar (PGM) were studied. PGM with 10 % replacement of PROS had the maximum compressive strength of 38.17 MPa after 28 days. P-values obtained from the quadratic models developed for the synergistic effect of FA-PROS on density and compressive strength were less than 0.005. Optimisation of the synergistic effect of FA-PROS binder produced an optimal combination of both materials for maximum compressive strength and density of 2200 kg/m3 with desirability factor of 0.981. This investigation shows that replacing PROS with FA in geopolymer mortar can result in a new supply chain for greener binder materials in geopolymer mortar.

在全球范围内,石油炼制过程中产生了大量的含油污泥。石油炼制含油污泥是石油炼制过程的主要副产品,也是石油和天然气工业污染的主要来源。在本研究中,响应面法(RSM)被用于优化和建模实验工作。在水玻璃(Na2SiO3)和氢氧化钠(NaOH)的固定组合下,经热处理的PROS取代了5 - 20%的粉煤灰(FA)。研究了PROS对PROS地聚合物砂浆(PGM)密度和抗压强度的影响。添加10% pro的PGM 28d后的最大抗压强度为38.17 MPa。FA-PROS对密度和抗压强度协同效应的二次模型p值均小于0.005。对FA-PROS粘结剂的协同效应进行优化,使两种材料的最大抗压强度和密度达到2200 kg/m3,理想系数为0.981。这项调查表明,用FA取代地聚合物砂浆中的PROS可以为更环保的地聚合物砂浆粘结材料提供新的供应链。
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引用次数: 1
Exploring the Untapped Potentials of Oily Sludge Ash Blended With Fly Ash for Geopolymer Binder Via Waste Valorization Approach 利用废弃Valorization方法探索含油污泥灰与粉煤灰混合用作地质聚合物粘结剂的潜力
Q2 Environmental Science Pub Date : 2023-03-01 DOI: 10.1016/j.hazl.2023.100076
Vicky Kumar, S. Kutty, S. N. A. Razak, N. Shafiq, A. Adebanjo, L. Baloo, Ahmed Azougagh, Rilind Iseni
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引用次数: 4
Seeing beyond the smoke: Selecting waterpipe wastewater chemicals for risk assessments 超越烟雾:选择水管废水化学品进行风险评估
Q2 Environmental Science Pub Date : 2023-01-02 DOI: 10.1016/j.hazl.2022.100074
Yasmin Termeh-Zonoozi , P. Dilip Venugopal , Vyomesh Patel, Gregory Gagliano

Background

Increasing use prevalence of waterpipe tobacco products raises concerns about environmental impacts from waterpipe waste disposal. The U.S. Food and Drug Administration (FDA) is required to assess the environmental impact of its tobacco regulatory actions per the National Environmental Policy Act. This study builds on FDA’s efforts characterizing the aquatic toxicity of waterpipe wastewater chemicals.

Methods

We compiled a comprehensive list of waterpipe wastewater chemical concentrations from literature. We then selected chemicals for risk assessment by estimating persistence, bioaccumulation, and aquatic toxicity (PBT) characteristics (U.S. Environmental Protection Agency), and hazardous concentration values (concentration affecting specific proportion of species).

Results

Of 38 chemicals in waterpipe wastewater with concentration data, 20 are listed as harmful or potentially harmful constituents (HPHCs) in tobacco smoke and tobacco products by FDA, and 15 are hazardous waste per U. S. Environmental Protection Agency. Among metals, six (cadmium, chromium, lead, mercury, nickel and selenium) are included in both HPHC and hazardous waste lists and were selected for future risk assessments. Among non-metals, nicotine, and 4-methylnitrosamino-1-(3-pyridyl)− 1-butanone (NNK) were shortlisted, as they are classified as persistent and toxic. Further, N-nitrosonornicotine (NNN), with a low hazardous concentration value (HC50; concentration affecting 50 % of aquatic species) for chronic aquatic toxicity, had high aquatic toxicity concern and is selected.

Conclusions

The presence of multiple hazardous compounds in waterpipe wastewater highlights the importance of awareness on the proper disposal of waterpipe wastewater in residential and retail settings. Future studies can build on the hazard characterization provided in this study through fate and transport modeling, exposure characterization and risk assessments of waterpipe wastewater chemicals.

背景:水烟制品的使用越来越普遍,引起了人们对水烟废物处理对环境影响的关注。根据《国家环境政策法》,美国食品和药物管理局(FDA)必须评估其烟草监管行动对环境的影响。本研究建立在FDA对水管废水中化学物质的水生毒性进行表征的基础上。方法从文献资料中整理出综合的自来水管道废水化学物质浓度表。然后,我们通过评估持久性、生物积累和水生毒性(PBT)特征(美国环境保护局)和危险浓度值(影响特定物种比例的浓度)来选择化学品进行风险评估。结果自来水废水中有38种化学物质的浓度数据,其中20种被FDA列为烟草烟雾和烟草制品中的有害或潜在有害成分(HPHCs), 15种被美国环境保护署列为危险废物。在金属中,有六种金属(镉、铬、铅、汞、镍和硒)被列入HPHC和危险废物清单,并被选中用于未来的风险评估。在非金属中,尼古丁和4-甲基亚硝胺-1-(3-吡啶基)-1-丁酮(NNK)被列入候选名单,因为它们被归类为持久性和毒性。此外,n -亚硝基索烟碱(NNN)具有较低的危害浓度值(HC50;影响50%水生物种的浓度)为慢性水生毒性,具有高度水生毒性关注并被选中。结论自来水废水中多种有害化合物的存在,突出了在住宅和零售环境中正确处理自来水废水的重要性。未来的研究可以建立在本研究提供的危害表征的基础上,通过命运和运输模型,暴露表征和水管废水化学品的风险评估。
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引用次数: 1
Molecular imprinting-based nanocomposite adsorbents for typical pollutants removal 分子印迹纳米复合吸附剂对典型污染物的去除
Q2 Environmental Science Pub Date : 2023-01-01 DOI: 10.1016/j.hazl.2022.100073
Liyan Wang , Jialuo Yu , Xiaoyan Wang , Jinhua Li , Lingxin Chen
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引用次数: 5
期刊
Journal of hazardous materials letters
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