Nanoscale Horizons最新文献

Correction for ‘Enhancing the chemotherapeutic efficacy of platinum prodrug nanoparticles and inhibiting cancer metastasis by targeting iron homeostasis’ by Fang Ding et al., Nanoscale Horiz., 2020, 5, 999–1015, https://doi.org/10.1039/D0NH00148A.

Colloidal quantum dots (QDs) are highly promising for display technologies due to their distinctive optical characteristics, such as tunable emission wavelengths, narrow emission spectra, and superb photoluminescence quantum yields. Over the last decade, both academic and industrial research have substantially advanced quantum dot light-emitting diode (QLED) technology, primarily through the development of higher-quality QDs and more refined device structures. A key element of these advancements includes progress in the electron transport layer (ETL) technology, with metal oxide (MO) nanoparticles (NPs) like ZnO and ZnMgO emerging as superior choices due to their robust performance. Nevertheless, scalability challenges, such as particle agglomeration and positive aging, have prompted research into organic semiconductors that match the performance of MO NPs. This review aims to provide a detailed examination and comprehensive understanding of recent advances and challenges in ETLs based on both MO NPs and organic semiconductors, guiding future commercialization efforts for QLEDs.

Recently, pyrene-based covalent organic frameworks (PyCOFs) have aroused great interest because the large planar structure of the pyrene unit could effectively enhance the interlayer π–π interaction and promote the separation and migration of carriers, significantly improving the crystallinity and photoelectrical properties of PyCOFs. Since the first PyCOF-containing boroxate linkage was reported in 2008 by the Yaghi group, many PyCOFs with different kinds of linkages have been reported, exhibiting great potential applications in different fields such as adsorption/separation, chemical sensing, catalysis, energy storage, etc. However, as far as we know, the reviews related to PyCOFs are rare, although PyCOFs have been widely reported to show promising applications. Thus, it is right time and important for us to systematically summarize the research advance in PyCOFs, including the synthesis with different linkages and applications. Moreover, the prospects and obstacles facing the development of PyCOFs are discussed. We hope that this review will provide new insights into PyCOFs that can be explored for more attractive functions or applications.

We studied the exciton delocalization of indodicarbocyanine 5 dye derivative (Cy5-R) heterodimers templated by a DNA Holliday junction (HJ), which was quantified by the exciton hopping parameter J_m,n. These dyes were modified at the 5 and 5′ positions of indole rings with substituent (R) H, Cl, tBu, Peg, and hexyloxy (Hex) groups that exhibit different bulkiness and electron-withdrawing/donating capacities. The substituents tune the physical properties of the dyes, such as hydrophobicity (log P) and solvent-accessible surface area (SASA). We tuned the J_m,n of heterodimers by attaching two Cy5-Rs in adjacent and transverse positions along the DNA-HJ. Adjacent heterodimers exhibited smaller J_m,n compared to transverse heterodimers, and some adjacent heterodimers displayed a mixture of H- and J-like aggregates. Most heterodimers exhibited J_m,n values within the ranges of the corresponding homodimers, but some heterodimers displayed synergistic exciton delocalization that resulted in larger J_m,n compared to their homodimers. We then investigated how chemically distinct Cy5-R conjugated to DNA can interact to create delocalized excitons. We determined that heterodimers involving Cy5-H and Cy5-Cl and a dye with larger substituents (bulky substituents and large SASA) such as Cy5-Peg, Cy5-Hex, and Cy5-tBu resulted in larger J_m,n. The combination provides steric hindrance that optimizes co-facial packing (bulky Cy5-R) with a smaller footprint (small SASA) that maximizes proximity. The results of this study lay a groundwork for rationally optimizing the exciton delocalization in dye aggregates for developing next-generation technologies based on optimized exciton transfer efficiency such as quantum information systems and biomedicine.

Single-walled carbon nanotubes (SWCNTs) are synthesized as mixtures of various SWCNT types, exhibiting drastically different properties, and thereby making the material of limited use. Fluorene-based polymers are successful agents for purifying such blends by means of conjugated polymer extraction (CPE), greatly increasing their application potential. However, a limited number of studies have devoted attention to understanding the effects of the polyfluorene backbone and side chain structure on the selectivity and separation efficiency of SWCNTs. Regarding the impact of the polymer backbone, it was noted that the ability to extract SWCNTs with conjugated polymers could be significantly enhanced by using fluorene-based copolymers that exhibit dramatically different interactions with SWCNTs depending on the types of monomers combined. However, the role of monomer side chains remains much less explored, and the knowledge generated so far is fragmentary. Herein, we present a new approach to tailor polymer selectivity by creating copolymers of polyfluorene bearing mixed-length alkyl chains. Their thorough and systematic analysis by experiments and modeling revealed considerable insight into the impact of the attached functional groups on the capacity of conjugated polymers for the purification of SWCNTs. Interestingly, the obtained results contradict the generally accepted conclusion that polyfluorene-based polymers and copolymers with longer chains always prefer SWCNTs of larger diameters. Besides that, we report that the capacity of such polymers for sorting SWCNTs may be substantially enhanced using specific low molecular weight compounds. The carried-out research provides considerable insight into the behavior of polymers and carbon-based materials at the nanoscale.

Quantum sensing using the fluorescent nanodiamond (FND) nitrogen-vacancy center enables physical/chemical measurements of the microenvironment, although application of such measurements in living mammals poses significant challenges due to the unknown biodistribution and toxicity of FNDs, the limited penetration of visible light for quantum state manipulation/measurement, and interference from physiological motion. Here, we describe a microenvironmental thermometry technique using FNDs in rat mammary epithelium, an important model for mammary gland biology and breast cancer research. FNDs were injected directly into the mammary gland. Microscopic observation of mammary tissue sections showed that most FNDs remained in the mammary epithelium for at least 8 weeks. Pathological examination indicated no obvious change in tissue morphology, suggesting negligible toxicity. Optical excitation and detection were performed through a skin incision. Periodic movements due to respiration and heartbeat were mitigated by frequency filtering of the signal. Based on these methods, we successfully detected temperature elevation in the mammary epithelium associated with lipopolysaccharide-induced inflammation, demonstrating the sensitivity and relevance of the technique in biological contexts. This study lays the groundwork for expanding the applicability of quantum sensing in biomedical research, providing a tool for real-time monitoring of physiological and pathological processes.

Introducing metallic nanoparticles, such as Au, on a substrate as a surfactant or wetting inducer has been demonstrated as a simple but effective way to facilitate the formation of ultra-thin silver layers (UTSLs) during the subsequent Ag deposition. However, most studies have paid much attention to the applications of UTSLs assisted by metallic surfactants but neglected the underlying mechanisms of how the metallic surfactant affects the formation of UTSL. Herein, we have applied in situ grazing-incidence wide-/small-angle X-ray scattering to reveal the effects of the Au surfactant or seed layer (pre-deposited Au nanoparticles) on the formation of UTSL by high-power impulse magnetron sputter deposition (HiPIMS) on a zinc oxide (ZnO) thin film. The comprehensive and in-depth analysis of the in situ X-ray scattering data revealed that the pre-deposited Au nanoparticles can act as additional defects or growth cores for the sputtered Ag atoms despite using HiPIMS, which itself forms many nucleation sites. As a result, the formation of a continuous and smooth UTSL is reached earlier in HiPIMS compared with bare ZnO thin films. Based on the mechanism revealed by the in situ measurements, we provide insight into the formation of UTSL and further UTSL-based applications.

Crystal defects, traditionally viewed as detrimental, are now being explored for quantum technology applications. This study focuses on stacking faults in silicon and germanium, forming hexagonal inclusions within the cubic crystal and creating quantum wells that modify electronic properties. By modeling defective structures with varying hexagonal layer counts, we calculated the formation energies and electronic band structures. Our results show that hexagonal inclusions in Si and Ge exhibit a direct band gap, changing with inclusion thickness, effectively functioning as quantum wells. We find that Ge inclusions have a direct band gap and form type-I quantum wells. This research highlights the potential of manipulating extended defects to engineer the optoelectronic properties of Si and Ge, offering new pathways for advanced electronic and photonic device applications.

The protection of silver nanowire (AgNW) networks is crucial for enhancing their durability and applicability to flexible electronics. In this study, we present a sustainable and efficient strategy to protect AgNW-based flexible transparent electrodes (FTEs) using a layer-by-layer (LBL) assembly of biorenewable chitin and cellulose nanofibers (Chi and Cell). These uniform LBL-assembled thin films were successfully fabricated on AgNW FTEs due to their opposite surface charges. The resulting (Chi/Cell)_n bilayers, where n is the number of bilayers, did not degrade the optoelectrical properties of AgNW FTEs and significantly enhanced their stability under various harsh conditions. The optimized (Chi/Cell)₁₀@Al-AgNW FTEs exhibited comprehensive stability against UV/O₃ treatment for 40 min, thermal treatment at 250 °C for 350 min, Na₂S (1%), HCl (10%), and NH₃ (30%) treatments for 3, 30, and 105 min, respectively, sonication for 300 min, and 10 000 cycles of bending test. Therefore, the (Chi/Cell)₁₀@Al-AgNW FTEs were successfully applied to transparent heaters (TH) and pressure sensors with remarkably improved applicability, durability, and performance compared to pristine AgNW FTEs, providing a reassuring solution to the stability issues of AgNW-based FTEs.

Correction for ‘New horizons on advanced nanoscale materials for Cultural Heritage conservation’ by Rosangela Mastrangelo et al., Nanoscale Horiz., 2024, 9, 566–579, https://doi.org/10.1039/D3NH00383C.