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Axial behavior of UHPC columns with new emerging mixtures and varying confinement 采用新出现的混合物和不同约束条件的超高性能混凝土柱的轴向行为
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-25 DOI: 10.1016/j.cscm.2024.e03459
Milana Cimesa , Mohamed A. Moustafa

Using advanced materials to optimize designs and make structures resilient is becoming of crucial importance. Advanced rapidly growing materials with superior mechanical properties, like ultra-high performance concrete (UHPC), can make structures better in terms of strength and service life when compared to conventional concrete. Behind the excellent performance of UHPC stands its dense packing theory and usage of steel fibers or even carbon nanofibers (CNF) in emerging UHPC mixtures. UHPC is mostly used in small-scale applications like bridge field joints and overlays, but research is extending UHPC to full structural applications such as girders and columns. To expand existing knowledge on UHPC columns and add new results from emerging and recently commercialized UHPC mixtures, this study uses, for the first time, two new UHPC mixtures with white cement and CNF enhancement to investigate axial behavior of nine full-scale columns with varying confinement. An extensive experimental program considers two groups of columns from two different mixtures with several other variables such as transverse reinforcement detailing, cross-section, and percentage of steel fibers. The paper presents results from companion material tests along with a detailed discussion of the global and local behavior of the columns, i.e. force, axial strains, reinforcement strains, and stiffness. Test results are interpreted in light of existing ACI 318 Code provisions and guidance is provided for axial design capacity estimation and transverse reinforcement detailing.

使用先进材料来优化设计并使结构具有弹性正变得至关重要。与传统混凝土相比,超高性能混凝土(UHPC)等快速发展的先进材料具有卓越的机械性能,可以使结构在强度和使用寿命方面更胜一筹。超高性能混凝土优异性能的背后是其致密堆积理论,以及在新出现的超高性能混凝土混合物中使用钢纤维甚至碳纳米纤维(CNF)。超高性能混凝土主要用于桥梁现场接缝和覆盖层等小规模应用,但研究正在将超高性能混凝土扩展到大梁和支柱等全结构应用中。为了扩展有关超高性能混凝土柱的现有知识,并增加新兴的和最近商业化的超高性能混凝土混合物的新成果,本研究首次使用了两种新型超高性能混凝土混合物(白水泥和氯化萘纤维增强),以研究具有不同约束条件的九个全尺寸柱的轴向行为。广泛的实验计划考虑了两组由两种不同混合物制成的柱子,以及其他一些变量,如横向加固细节、横截面和钢纤维百分比。论文介绍了配套材料试验的结果,并详细讨论了柱子的整体和局部行为,即力、轴向应变、钢筋应变和刚度。测试结果将根据现有的 ACI 318 规范条款进行解释,并为轴向设计承载力估算和横向配筋细部设计提供指导。
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引用次数: 0
Investigation of nanoscale interfacial bonding properties in foamed asphalt cold recycled mixtures under chloride salt erosion 研究氯盐侵蚀条件下发泡沥青冷再生混合料的纳米级界面粘结特性
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-24 DOI: 10.1016/j.cscm.2024.e03390
Shuangshuang Liang , Chunyu Liang , Menghao Li , Honghai Cui , Zhan Wang , Shurong Wang

Salt-induced erosion from de-icing salts in Northern China and sea salt in Eastern coastal areas significantly compromises asphalt pavement integrity. A selection was made of four different types of foamed asphalt with different levels of water content, two types of aged asphalt, and three typical minerals (α-quartz, calcite, and bauxite), in addition to three chloride salt solutions (NaCl, CaCl2, MgCl2). It was found that (1) in dry conditions, the moisture level of foamed asphalt noticeably influences the adhesive performance at the juncture between asphalt and aggregates. Unlike acidic minerals, the bond strength between alkaline and neutral minerals and foamed asphalt increases as the water content of the foamed asphalt rises; (2) chloride salt solutions presence and increased levels significantly reduced the bond strength between asphalt and aggregates, particularly impacting neutral and alkaline minerals (in the presence of 10 % NaCl solution, the work of adhesion was reduced by 83.82 % and 87.48 %, respectively); (3) the influence of diverse chloride salts on the interfacial adhesive performance of asphalt mixtures varied, with the three chloride salts reducing the asphalt-aggregate interfacial adhesion work by 44.52 %, 21.90 %, and 34.94 %, respectively. (4) the investigation determined that the mineral composition considerably influences the hygroscopic sensitivity of asphalt mixtures. Minerals of an acidic nature exhibit superior moisture resistance when juxtaposed with alkaline counterparts, recommending the adoption of acidic aggregates in scenarios demanding elevated mixture stability.

华北地区的除冰盐和东部沿海地区的海盐造成的盐分侵蚀严重损害了沥青路面的完整性。研究选择了四种不同含水量的发泡沥青、两种老化沥青、三种典型矿物质(α-石英、方解石和铝矾土)以及三种氯化盐溶液(NaCl、CaCl2、MgCl2)。研究发现:(1) 在干燥条件下,发泡沥青的湿度会明显影响沥青与集料连接处的粘合性能。与酸性矿料不同,碱性和中性矿料与发泡沥青之间的粘结强度会随着发泡沥青含水量的增加而增加;(2)氯化盐溶液的存在和含量的增加会显著降低沥青与集料之间的粘结强度,尤其是对中性和碱性矿料的影响(在 10 % 氯化钠溶液存在的情况下,粘结功分别降低了 83.82 %和 87.48 %);(3)不同氯盐对沥青混合料界面粘附性能的影响各不相同,三种氯盐分别使沥青-集料界面粘附功降低了 44.52 %、21.90 %和 34.94 %。(4)调查确定,矿物成分对沥青混合料的吸湿敏感性有很大影响。当酸性矿料与碱性矿料并列时,酸性矿料具有更强的防潮性能,因此建议在要求提高混合料稳定性的情况下采用酸性集料。
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引用次数: 0
Quantifying nonlinear fracture parameters in bituminous SCB specimens: A compliance-based approach 量化沥青 SCB 试样的非线性断裂参数:基于顺应性的方法
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-22 DOI: 10.1016/j.cscm.2024.e03437
Ragip Ince, Erkut Yalcin, Mehmet Yilmaz

Bituminous mixtures containing various defects, such as cracks and voids, exhibit ductile behavior in hot environments and brittle behavior in cold environments. Such materials can only be simulated realistically with the criteria of nonlinear fracture mechanics. In this investigation, the semi-circular bending (SCB) specimens, which have commonly been used to measure linear elastic fracture toughness parameters and fracture energy of asphalt and rock materials up to now, are studied to estimate several nonlinear fracture parameters of bituminous composites such as nonlinear fracture toughness, effective crack extension, critical crack tip opening displacement and brittleness. For this, the compliance functions of SCB specimens based on crack mouth opening displacement and load line displacement are derived by the finite element method at first. Subsequently, eight series of SCB tests in the literature, which were experimented with at low and room temperature environments, are examined by using two different compliance methods in fracture mechanics of quasi-brittle materials. This study's findings reveal that the crack extension in the pre-peak regime for mixes with bituminous at both low and normal temperatures is not statistically negligible and the use of nonlinear fracture toughness is, therefore, a necessity.

含有各种缺陷(如裂缝和空隙)的沥青混合物在热环境中表现出延展性,而在冷环境中则表现出脆性。只有采用非线性断裂力学的标准才能真实地模拟这类材料。半圆形弯曲(SCB)试样是迄今为止测量沥青和岩石材料线性弹性断裂韧性参数和断裂能的常用工具,本研究通过研究半圆形弯曲试样来估算沥青复合材料的几个非线性断裂参数,如非线性断裂韧性、有效裂纹扩展、临界裂纹尖端张开位移和脆性。为此,首先通过有限元法推导出基于裂口张开位移和荷载线位移的 SCB 试样顺应性函数。随后,利用准脆性材料断裂力学中两种不同的顺应性方法,对文献中八种系列的 SCB 试验进行了研究,这些试验分别在低温和室温环境下进行。研究结果表明,在低温和常温条件下,沥青混合料在峰值前的裂缝扩展在统计上都是不可忽略的,因此有必要使用非线性断裂韧性。
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引用次数: 0
Determination of mechanical properties of concrete and steel materials taken from buildings in Antakya after the Kahramanmaraş earthquakes 测定卡赫拉曼马拉什地震后从安塔基亚建筑物中提取的混凝土和钢材的力学性能
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-22 DOI: 10.1016/j.cscm.2024.e03445
Ozgun Bozdogan , Ahmet Erdag , Anil Ozdemir

The Kahramanmaraş earthquakes that struck the Antakya downtown resulted in significant structural damage, highlighting the need to understand the underlying causes and develop effective mitigation strategies. This experimental study aims to investigate the reasons behind the observed structural damage by examining defects in building materials. Through comprehensive laboratory testing, a detailed analysis was conducted to identify the factors contributing to the vulnerability of structures in the affected area. To simulate the conditions experienced during the earthquake, various building materials, including concrete and reinforcement steel, were subjected to rigorous testing. The results revealed variations in concrete quality, with some samples exhibiting lower compression strength, incorrect aggregate mixing ratios, deepening of carbonation over time and higher permeability, indicating potential weaknesses in the structural integrity. Furthermore, the examination of reinforcement steel samples revealed the presence of corrosion and inadequate bond strength, compromising the load-bearing capacity of the structures. These defects significantly affected the performance of reinforced concrete elements during the earthquake, leading to localized failures and increased vulnerability. In addition to these tests, cylindrical concrete elements with the same properties were reproduced to examine the concrete-steel adhesion interface. Ø8 reinforcements collected from the field was placed in the concrete elements during the production phase. Tensile tests were carried out on 48 test samples produced. In particular, pull-out tests of test elements without ribs and with low concrete compression strength, simulating the field, were completed at very low loads. The experimental results provide valuable insights into the causes of structural damage observed in the Hatay region following the Kahramanmaraş earthquakes. The identified defects in building materials, such as concrete and reinforcement steel, highlight the importance of stringent quality control measures during construction.

袭击安塔基亚市中心的卡赫拉曼马拉什(Kahramanmaraş)地震造成了严重的结构性破坏,这凸显了了解其根本原因并制定有效缓解策略的必要性。本实验研究旨在通过研究建筑材料的缺陷,探究所观察到的结构损坏背后的原因。通过全面的实验室测试,进行了详细的分析,以确定导致灾区结构脆弱性的因素。为了模拟地震期间的情况,对包括混凝土和钢筋在内的各种建筑材料进行了严格测试。结果显示,混凝土的质量存在差异,一些样品的抗压强度较低、骨料混合比例不正确、碳化程度随时间加深以及渗透性较高,这表明结构的完整性存在潜在缺陷。此外,对钢筋样本的检查还发现存在锈蚀和粘结强度不足的问题,从而影响了结构的承载能力。这些缺陷严重影响了地震中钢筋混凝土构件的性能,导致局部失效,增加了脆弱性。除这些测试外,还复制了具有相同性能的圆柱形混凝土构件,以检验混凝土与钢材的粘合界面。在生产阶段,将从现场收集的 Ø8 钢筋放入混凝土构件中。对制作的 48 个测试样本进行了拉伸测试。特别是,在非常低的荷载下,对没有肋骨且混凝土抗压强度较低的试验构件进行了拉拔试验,以模拟现场情况。实验结果为了解卡赫拉曼马拉什地震后哈塔伊地区结构损坏的原因提供了宝贵的见解。在混凝土和钢筋等建筑材料中发现的缺陷凸显了在施工过程中采取严格质量控制措施的重要性。
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引用次数: 0
Engineering characteristics of ultra-high performance concrete containing basil plant ash 含罗勒植物灰的超高性能混凝土的工程特性
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-22 DOI: 10.1016/j.cscm.2024.e03422
Abdullah M. Zeyad , Ibrahim Saad Agwa , Mahmoud H. Abd-Elrahman , Sahar A. Mostafa

One of the most present types of concrete in buildings is ultra-high-performance concrete. In contrast, large quantities of cement are consumed to achieve the required strength. To minimize the quantity of cement utilized in manufacturing ultra-high-performance concrete, this research aims to look at the usage of a unique agricultural waste as an alternative to cement. This study focuses on using agricultural waste as a partial cement alternative to reduce the amount of cement used in the production of ultra-high-performance concrete. This study employed basil plant ash as a partial substitution for ordinary Portland cement at 5 %, 10 %, 15 %, 20 %, and 25 % by mass. basil plant ash was heat-treated at temperatures of 300 °C, 500 °C, 700 °C, 900 °C. The compressive strength, splitting tensile strength, and sorptivity coefficient of ultra-high-performance concrete were investigated using 21 different mixes. In addition, microstructure characteristics as assessed using X-ray diffraction, thermal gravimetric analysis, and scanning electron microscope. The results showed that treating basil plant ash at 700 °C contributed to achieving the best mechanical properties when it was utilized as a partial substitution for 20 % of the weight of ordinary Portland cement. The compressive strength and splitting tensile strength were enhanced by 15.07 % and 20.39 %, respectively, compared with the control mix at 28 days. The thermo-gravimetric analysis, X-ray diffraction, and scanning electron microscope analyses are consistent with the obtained mechanical and durability characteristics. The outcomes of this investigation help shed light on the use of basil plant ash as a partial substitution at a level of 20 % of the weight of cement to produce ultra-high-performance concrete with high performance and lower cost.

超高性能混凝土是目前建筑中使用最多的混凝土类型之一。相比之下,要达到所需的强度需要消耗大量水泥。为了尽量减少制造超高性能混凝土时的水泥用量,本研究旨在探讨如何使用一种独特的农业废弃物来替代水泥。本研究的重点是使用农业废弃物作为部分水泥替代品,以减少超高性能混凝土生产中的水泥用量。本研究采用罗勒植物灰作为普通硅酸盐水泥的部分替代品,其质量百分比分别为 5%、10%、15%、20% 和 25%。罗勒植物灰的热处理温度分别为 300 ℃、500 ℃、700 ℃ 和 900 ℃。使用 21 种不同的混合料研究了超高性能混凝土的抗压强度、劈裂拉伸强度和吸水系数。此外,还使用 X 射线衍射、热重分析和扫描电子显微镜评估了微观结构特征。结果表明,当罗勒植物灰部分替代 20% 重量的普通硅酸盐水泥时,在 700 °C 下处理罗勒植物灰有助于获得最佳力学性能。与对照组相比,28 天时的抗压强度和劈裂拉伸强度分别提高了 15.07% 和 20.39%。热重分析、X 射线衍射和扫描电子显微镜分析与所获得的机械和耐久性特征一致。这项研究的结果有助于阐明如何使用罗勒植物灰作为部分替代品(占水泥重量的 20%)来生产高性能、低成本的超高性能混凝土。
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引用次数: 0
The effect of chemical oxygen demand of domestic wastewater on workability, mechanical, and durability of self- compacting concrete 生活污水的化学需氧量对自密实混凝土工作性、力学性能和耐久性的影响
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-22 DOI: 10.1016/j.cscm.2024.e03374
Elham jahandideh , Gholamreza Asadollahfardi , Javad Akbardoost , Amirmasoud Salehi

Due to worldwide water scarcity, especially in arid regions, and the substantial use of drinking water in concrete production, the consideration of gray water usage is growing. However, wastewater contamination adversely affects concrete's mechanical strength and durability, with Chemical Oxygen Demand(COD) as one of the indicator. In the present work, the effect of COD of different types of domestic wastewater on workability, mechanical, and durability properties of self-compacting concrete (SCC) with 400 kg/m3 and 440 kg/m3 of cement, and water-to-cement ratios of (w/c) 0.36 and 0.5 for 12 different SCC mixture designs were investigated. The results of the experiments indicated that increasing the COD of domestic wastewater negatively impacts the workability of fresh concrete. Additionally, as the COD of the wastewater increases, the compressive strength of SCC decreases at 7 and 28 days when using raw sewage, sewage sludge, and artificial wastewaters. However, by 90 days, the compressive strength showed no significant difference compared to SCC made with tap water. With increasing COD of wastewater, the 28-day tensile strengths of SCC decreased by 6–10 %. The COD of wastewater did not significantly affect the flexural strength. However, the fracture toughness, at a water-cement ratio (w/c) of 0.5, decreased with increasing COD, reaching a reduction of 36 % at a COD of 940 mg/L. As the COD concentration rises, water absorption increases. In SCC samples containing sludge water and raw sewage, capillary water absorption was at its maximum due to the presence of impurities, as well as organic and mineral materials.

由于全球缺水,尤其是在干旱地区,以及混凝土生产中大量使用饮用水,人们越来越多地考虑使用灰水。然而,废水污染会对混凝土的机械强度和耐久性产生不利影响,而化学需氧量(COD)是其中的一项指标。在本研究中,针对 12 种不同的自密实混凝土(SCC)混合物设计,研究了不同类型生活污水的 COD 对水泥用量分别为 400 kg/m3 和 440 kg/m3、水灰比分别为(w/c)0.36 和 0.5 的自密实混凝土(SCC)的工作性、机械性能和耐久性的影响。实验结果表明,增加生活废水的化学需氧量会对新拌混凝土的工作性产生负面影响。此外,随着废水 COD 的增加,使用原污水、污水污泥和人工废水时,SCC 在 7 天和 28 天时的抗压强度会降低。然而,90 天后的抗压强度与使用自来水制成的 SCC 相比没有显著差异。随着废水 COD 的增加,SCC 的 28 天抗拉强度降低了 6-10%。废水的化学需氧量对抗弯强度没有明显影响。但是,在水灰比(w/c)为 0.5 时,断裂韧性随着 COD 的增加而降低,当 COD 为 940 mg/L 时,断裂韧性降低了 36%。随着 COD 浓度的增加,吸水率也随之增加。在含有污泥水和原生污水的 SCC 样品中,由于存在杂质、有机物和矿物质,毛细吸水率达到最大值。
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引用次数: 0
Behavior of hybrid natural fiber reinforced polymers bars under uniaxial tensile strength and pull-out loads with UHPC 混合天然纤维增强聚合物棒材在单轴拉伸强度和 UHPC 拉出载荷下的行为
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-20 DOI: 10.1016/j.cscm.2024.e03442
Mohammed M. Attia , Mahmoud Malek Olwan , Essam Amoush , Shady Rizk Ragheb Hassan Aamer , M.A. Eita

This study evaluated the uniaxial tensile strength and bond performance of natural hybrid reinforcement bars. Hybrid FRP combines multiple fibers and matrixes, resulting in a desirable performance. Two types of hybrid bars were tested: one with natural fibers surrounded by glass fiber, and the other with a steel core surrounded by natural fiber and then glass fiber. Thirteen samples were used to assess tensile behavior, with four groups including glass fiber, flax, sisal, and jute fibers. Pull-out behavior testing was conducted on twelve samples, divided into four groups of fiberglass, flax, sisal, and jute. Each group used three types of concrete: normal, high strength, and ultra-high-performance concrete (UHPC). The results refer to flax samples that had a higher tensile strength and elastic modulus of 143 MPa and 38 GPa, respectively, than samples made of sisal and jute fibres. The hybrid bars with a steel core exhibited a significant improvement in elastic modulus of 206 % in compared to samples made solely from glass, sisal, and jute fibers. On the other hand, the samples with UHPC showed the highest bond strength. The sample U-GFRP with ultra-high-performance concrete showed the highest bond strength 9.32 MPa, while the sample N-GFRP with normal concrete showed the lowest bond strength 5.87 MPa, respectively. However, this study suggests that hybridizing natural fibers can be a cost-effective and eco-friendly alternative to synthetic fibers.

本研究评估了天然混合加固杆的单轴拉伸强度和粘结性能。混合玻璃钢结合了多种纤维和基质,具有理想的性能。研究测试了两种类型的混合杆:一种是天然纤维被玻璃纤维包围,另一种是钢芯被天然纤维包围,然后再被玻璃纤维包围。13 个样品用于评估拉伸行为,其中四组包括玻璃纤维、亚麻纤维、剑麻纤维和黄麻纤维。拉伸性能测试在 12 个样品上进行,分为玻璃纤维、亚麻、剑麻和黄麻四组。每组使用三种混凝土:普通混凝土、高强度混凝土和超高性能混凝土(UHPC)。结果显示,亚麻样品的抗拉强度和弹性模量分别为 143 兆帕和 38 千兆帕,高于剑麻和黄麻纤维样品。与仅由玻璃纤维、剑麻纤维和黄麻纤维制成的样品相比,带有钢芯的混合棒材的弹性模量显著提高了 206%。另一方面,含有超高分子量聚碳酸酯的样品显示出最高的粘结强度。与超高性能混凝土混合的 U-GFRP 样品的粘结强度最高,为 9.32 兆帕,而与普通混凝土混合的 N-GFRP 样品的粘结强度最低,仅为 5.87 兆帕。不过,这项研究表明,与天然纤维杂交是一种替代合成纤维的经济、环保的方法。
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引用次数: 0
Assessment of select direct and indirect pozzolanic reactivity test outcomes with robust regression and ranking analysis 利用稳健回归和排序分析评估选定的直接和间接泡沫活性测试结果
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-19 DOI: 10.1016/j.cscm.2024.e03441
Farzaneh Elyasigorji, Habib Tabatabai

The use of pozzolanic materials as a sustainable partial replacement option for portland cement in concrete has been extensively studied over the last few decades. This study aimed to assess the pozzolanic reactivity of seven different powdered materials: pottery cull, brick powder, lightweight aggregate fines, class C fly ash, silica fume, glass powder, and dolostone. Pozzolanic reactivity was evaluated using seven different direct and indirect methods, including the Frattini test, strength activity index (SAI), ultrasound pulse velocity index (UPVI), thermogravimetric and differential thermal analyses (TG/DTA), calorimetry, electrical conductivity, and pH. Robust correlations and a ranking analysis were performed to evaluate the relationship and efficiency between various direct and indirect test methods. Results of the robust regression analyses showed that Frattini and TGA, SAI and electrical conductivity, SAI and calorimetry, and UPVI and calorimetry were well correlated, suggesting that these methods may be suitable alternatives to each other. According to the ranking method, electrical conductivity and calorimetry are the most rapid and efficient methods for the assessment of different pozzolans in comparison to other longer-duration test methods examined in this study.

在过去几十年中,人们广泛研究了在混凝土中使用水青石材料作为部分替代硅酸盐水泥的可持续选择。本研究旨在评估七种不同粉末材料的水胶反应性:陶粒、砖粉、轻质骨料细粉、C 级粉煤灰、硅灰、玻璃粉和白云石。采用七种不同的直接和间接方法评估了水青石反应性,包括弗拉蒂尼试验、强度活性指数 (SAI)、超声脉速指数 (UPVI)、热重分析和差热分析 (TG/DTA)、量热法、电导率和 pH 值。为评估各种直接和间接测试方法之间的关系和效率,进行了稳健相关分析和排序分析。稳健回归分析的结果表明,Frattini 和 TGA、SAI 和电导率、SAI 和量热仪、UPVI 和量热仪之间具有良好的相关性,表明这些方法可以相互替代。根据排序法,与本研究中考察的其他持续时间较长的测试方法相比,电导率法和量热法是评估不同类型灰棉时最快速、最有效的方法。
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引用次数: 0
Experimental investigation and analysis of the impact of salinity erosion on the strength of graphene oxide cement soil 盐碱侵蚀对氧化石墨烯水泥土强度影响的实验研究与分析
IF 6.5 2区 工程技术 Q2 Materials Science Pub Date : 2024-06-19 DOI: 10.1016/j.cscm.2024.e03413
Junjie Zhang , Jingshuang Zhang , Peng Miao , Yonghua Shu

In saline-alkali and coastal areas, cement soil faces various threats from salt erosion, and these environmental conditions can significantly impact the mechanical properties of cement soil. To counter external erosion, the addition of graphene oxide (GO) nanomaterials to cement soil is considered an effective solution. This study systematically investigates the strength variations of GO cement soil after erosion in different concentrations of NaCl solution (0 g/L, 4.5 g/L, 18 g/L, 30 g/L), Na2SO4 (0 g/L, 4.5 g/L, 18 g/L, 30 g/L), and a composite salt solution of both (0 g/L, 4.5 g/L, 18 g/L, 30 g/L) at different times (7d, 14d, 30d, 60d) through salt immersion tests, unconfined compressive strength tests, and SEM scanning electron microscope tests. Simultaneously, the study analyzes the mass change rate, stress-strain curves, peak stress of unconfined compressive strength, and modulus of elasticity changes in cement soil samples after erosion. The internal erosion mechanism of cement soil samples is explored at the microscopic level. When the GO cement soil was eroded in different concentrations of NaCl solution for 14 days, a consistent trend of mass decrease was observed. However, after 7, 30, and 60 days of erosion in various concentrations of NaCl solution, the mass showed an increasing trend. When immersed in pure water for 7d, 14d, 30d, and 60d, as well as in a 4.5 g/L NaCl solution for 7d and 14d erosion, the peak stress of GO cement soil samples shows an increasing trend, while it decreases under other conditions, especially significantly in Na2SO4 solution. Simultaneously, Na2SO4 has the greatest impact on the modulus of elasticity of cement soil. SEM test results reveal that due to nucleation effects, GO promotes the generation of hydration product C-S-H, enhancing the resistance of cement soil samples to external erosion. Furthermore, it is observed that under the influence of SO42-, C-S-H undergoes decalcification to generate AFt, while the impact of Cl- on C-S-H is relatively small.

在盐碱地和沿海地区,水泥土面临着盐分侵蚀的各种威胁,这些环境条件会严重影响水泥土的机械性能。为应对外部侵蚀,在水泥土中添加氧化石墨烯(GO)纳米材料被认为是一种有效的解决方案。本研究系统研究了 GO 水泥土在不同浓度的 NaCl 溶液(0 g/L、4.5 g/L、18 g/L、30 g/L)、Na2SO4(0 g/L、4.5 g/L、18 g/L、30 g/L)以及二者的复合盐溶液(0 g/L、4.5 g/L、18 g/L、30 g/L)中侵蚀不同时间(7d、14d、30d、60d)后,通过盐浸试验、无侧限抗压强度试验和 SEM 扫描电子显微镜试验进行分析。同时,研究分析了水泥土样品受侵蚀后的质量变化率、应力-应变曲线、无侧限抗压强度峰值应力和弹性模量的变化。研究从微观层面探讨了水泥土样品的内部侵蚀机理。当 GO 水泥土在不同浓度的 NaCl 溶液中侵蚀 14 天后,观察到其质量呈一致的下降趋势。然而,在不同浓度的 NaCl 溶液中侵蚀 7 天、30 天和 60 天后,质量呈上升趋势。在纯水中浸泡 7d、14d、30d 和 60d,以及在 4.5 g/L 的 NaCl 溶液中浸泡 7d 和 14d 后,GO 水泥土壤样品的峰值应力呈上升趋势,而在其他条件下,其峰值应力则呈下降趋势,尤其是在 Na2SO4 溶液中,下降趋势更为明显。同时,Na2SO4 对水泥土弹性模量的影响最大。扫描电镜测试结果表明,由于成核效应,GO 促进了水化产物 C-S-H 的生成,增强了水泥土样品的抗外部侵蚀能力。此外,还观察到在 SO42- 的影响下,C-S-H 会发生脱钙作用,生成 AFt,而 Cl- 对 C-S-H 的影响相对较小。
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引用次数: 0
Enhancing solidification in one-part geopolymer systems through alkali-thermal activation of bauxite residue and silica fume integration 通过碱热活化矾土渣和硅灰一体化来增强单组分土工聚合物体系的凝固性
IF 6.5 2区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Pub Date : 2024-06-19 DOI: 10.1016/j.cscm.2024.e03444
Harini Konduru, S Karthiyaini

This work describes the synthesis of geopolymers, a family of amorphous alumino-silicates, employing Silica fume and bauxite waste as precursor materials in an alkali-activated polycondensation reaction and the investigation of their properties. The purpose of the study is to determine the feasibility of producing one-part alkali-activated geopolymer for use in cast-in-place construction. Following calcination of the bauxite residue at 800 °C, different amounts of solid activator Na2O (10 %, 15 %, and 20 %) were added. Furthermore, Silica fume content ranging between 10 % and 40 % was utilised at intervals of 10 %, in lieu of alkali-thermally treated bauxite residue. The primary objective of the study is to evaluate the fresh properties throughout the first 28 days of geopolymer formation, including consistency, flowability, heat evolution, initial setting time (IST), and final setting time (FST). Scanning electron microscopy (SEM) images are used in conjunction with the 28-day average compressive strength to demonstrate the solidification of one-part geopolymers. Furthermore, these properties are affected by adding Silica fume at regular intervals between 10 % and 40 % as a replacement of the alkali-thermally treated Bauxite residue. The 28-day average compressive strength, with a maximum value of 19 MPa indicating successful geopolymer formation, supports the solidification of one-part geopolymers.

这项研究介绍了在碱活化缩聚反应中使用硅灰和铝土矿废料作为前驱体材料合成土工聚合物(无定形铝硅酸盐的一种),并对其性能进行了研究。研究的目的是确定生产用于现浇建筑的单组分碱活性土工聚合物的可行性。在 800 °C 煅烧铝矾土残渣后,加入不同量的固体活化剂 Na2O(10%、15% 和 20%)。此外,还以 10% 的间隔使用了 10% 至 40% 不等的硅灰,以代替经碱热处理的铝矾土残渣。研究的主要目的是评估土工聚合物形成后最初 28 天的新鲜特性,包括稠度、流动性、热演化、初凝时间 (IST) 和终凝时间 (FST)。扫描电子显微镜(SEM)图像与 28 天平均抗压强度结合使用,可证明单组分土工聚合物的凝固情况。此外,以 10% 至 40% 的固定间隔添加硅灰作为碱热处理矾土残渣的替代物,也会对这些特性产生影响。28 天平均抗压强度的最大值为 19 兆帕,表明成功形成了单组分土工聚合物。
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Case Studies in Construction Materials
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