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Effect of substrate temperature on physical properties of Co doped SnS2 thin films deposited by ultrasonic spray pyrolysis 衬底温度对超声喷雾热解制备Co掺杂SnS2薄膜物理性能的影响
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-08-01 DOI: 10.15251/cl.2023.208.587
Z. Hadef, K. Kamli, O. Kamli, S. Labiod
Ultrasonic Spray Pyrolysis (USP) was used to deposited Co doped SnS2 thin films on a glass substrate at different substrate temperatures (Ts = 350 °C, 375 °C, 400 °C, and 425 °C). DRX patterns shows that the synthesized films revealed a pure SnS2 phase with hexagonal structure. The mean crystalline grain sizes were showed an increasing– decreasing trend between 15.67 and 29.84 nm with an increment in the substrate temperature. The SEM images were significantly affected by the substrate temperature. Also, the optical band gap increases from 2.62 to 3.00 eV with the substrate temperatures increasing. Hall Effect measurements confirm the n-type conductivity of the as-deposited films. Furthermore, the films resistivity varies between 117 Ω.cm to 0.20 Ω.cm, as the substrate temperature increases from 350 to 425 °C.
采用超声喷雾热解法(USP)在不同的衬底温度(Ts = 350℃、375℃、400℃和425℃)下在玻璃衬底上沉积Co掺杂SnS2薄膜。DRX谱图显示合成的薄膜为纯SnS2相,具有六方结构。随着衬底温度的升高,平均晶粒尺寸在15.67 ~ 29.84 nm之间呈增减趋势。SEM图像受衬底温度的影响较大。随着衬底温度的升高,光学带隙从2.62 eV增加到3.00 eV。霍尔效应测量证实了沉积膜的n型电导率。膜的电阻率在117 Ω之间变化。厘米到0.20 Ω。随着衬底温度从350°C升高到425°C,
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引用次数: 0
Composition dependence of heat capacity in Se75Te15-XCd10InX(x=0, 5,10 and 15) chalcogenide glasses Se75Te15-XCd10InX(x=0、5、10和15)硫系玻璃热容的组分依赖性
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.206.393
S. Kumar, P. Kumar, S. Sahni, S. Singh, K. Singh
Differential Scanning Calorimetry (DSC) is performed at different heating rates under non-isothermal conditions to study the heat capacities studies of glassy Se75Te15- XCd10InX(x=0, 5,10and 15) alloys.Heat capacities of Se75Te15-XCd10InX(x=0, 5,10and 15) chalcogenide glasses at glass transitions (Tg) and crystallisations temperatures (Tc) werementioned in this work. The evaluated endothermic (ΔCpg) and exothermic (ΔCpc) heat capacities of Se-Te-Cd-In system varies with alloying concentrations and maximum at threshold composition (5 at wt.% of In). This could be explained on the basis of chemical bond theory of the solids.
采用差示扫描量热法(DSC)在非等温条件下,以不同的升温速率研究了玻璃态Se75Te15- XCd10InX(x= 0,5,10和15)合金的热容。本文讨论了Se75Te15-XCd10InX(x= 0,5,10和15)硫系玻璃在玻璃化转变(Tg)和结晶温度(Tc)下的热容。Se-Te-Cd-In体系的吸热热容(ΔCpg)和放热热容(ΔCpc)随合金浓度的变化而变化,并在阈值组成时达到最大值(在wt.% In时为5)。这可以用固体的化学键理论来解释。
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引用次数: 0
Optimization physical properties of CdTe /Si solar cell devices fabricated by vacuum evaporation 真空蒸发法制备CdTe/Si太阳能电池器件的物理性能优化
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.206.431
H. M. Ali, M. H. Mustafa
We investigated at the optical properties, structural makeup, and morphology of thin films of cadmium telluride (CdTe) with a thickness of 150 nm produced by thermal evaporation over glass. The X-ray diffraction study showed that the films had a crystalline composition, a cubic structure, and a preference for grain formation along the (111) crystallographic direction. The outcomes of the inquiry were used to determine these traits. With the use of thin films of CdTe that were doped with Ag at a concentration of 0.5%, the crystallization orientations of pure CdTe (23.58, 39.02, and 46.22) and CdTe:Ag were both determined by X-ray diffraction. orientations (23.72, 39.21, 46.40) For samples that were pure and those that were doped with silver, the optical band gap shrank by (1.52-1.47) eV (400–1100)nm resulting in a drop in the absorption coefficient. An incident power density of (100 mW/cm2) was used to examine the I-V properties of heterojunctions created by light on a variety of clean and doped materials. In accordance with the X-ray diffraction analysis, the films had a cubic structure and dominated grain growth along the (111) crystallographic direction.
我们研究了在玻璃上热蒸发制备厚度为150nm的碲化镉(CdTe)薄膜的光学性质、结构组成和形貌。x射线衍射研究表明,薄膜具有晶体组成、立方结构和沿(111)晶体学方向晶粒形成的偏好。调查的结果被用来确定这些特征。利用掺银浓度为0.5%的CdTe薄膜,通过x射线衍射测定了纯CdTe(23.58、39.02和46.22)和CdTe:Ag的结晶取向。对于纯样品和掺杂银的样品,光学带隙缩小了(1.52-1.47)eV (400-1100)nm,导致吸收系数下降。使用入射功率密度(100 mW/cm2)来检查光在各种清洁和掺杂材料上产生的异质结的I-V特性。x射线衍射分析表明,薄膜具有立方结构,晶粒沿(111)晶态方向生长。
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引用次数: 0
Examining the impact of quantum confinement energy on the optical characteristics of zinc sulfide and gallium nitrate in the ultraviolet spectral range 在紫外光谱范围内研究量子约束能对硫化锌和硝酸镓光学特性的影响
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.206.423
A. Kafel, S. N. Turki Al-Rashid
The study of confined quantum systems exhibit distinct behavior compared to that in bulk solids. This enables the design of materials with tunable chemical, physical, electrical and optical properties. In this paper, the effect of quantum confinement energy on the optical properties (gap energy, refractive index) of semiconductors gallium nitrate (GaN) and zinc sulfide (ZnS) is studied. The study is done using the MATLAB computer program (20a). This software is based on the Brus model and the particle in-a-box model. The results indicate that the optical properties depend on the quantum confinement energy, with an increase in quantum confinement energy corresponding to an increase in the energy gap and a decrease in refractive index.
与块状固体相比,受限量子系统的研究表现出不同的行为。这使得设计具有可调化学、物理、电学和光学特性的材料成为可能。本文研究了量子约束能对半导体材料硝酸镓(GaN)和硫化锌(ZnS)的光学性质(间隙能、折射率)的影响。本研究使用MATLAB计算机程序(20a)完成。该软件基于Brus模型和粒子盒模型。结果表明,光学性质与量子约束能量有关,量子约束能量的增加对应着能隙的增加和折射率的降低。
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引用次数: 0
Tensile deformation of S adsorbed in a monolayer of ReS2 affects its electronic structure and optical properties 吸附在ReS2单层中的S的拉伸变形影响其电子结构和光学性质
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.206.409
G. Jiao, G. L. Liu, L. Wei, J. Zhao, G. Zhang
Using density functional theory, the effect of biaxial tensile strain on adsorption of S in ReS2 monolayer is calculated. The study finds intrinsic ReS2 system and monolayer ReS2 adsorbed S system are affected by tensile deformation. Intrinsic ReS2 has direct band gap. As S appears, the system becomes indirect band gap. With tensile deformation amount of the intrinsic ReS2 system reaching 10%, the band gap reduces to 0.064eV. The growth rate of reflection and absorption coefficient are decreased by tensile deformation. The maximum reflection and absorption peak undergo red shift, improving the light reflection and absorption ability of adsorption system
利用密度泛函理论,计算了双轴拉伸应变对S在ReS2单层吸附的影响。研究发现,拉伸变形对本征ReS2体系和单层ReS2吸附S体系均有影响。本征ReS2具有直接带隙。当S出现时,系统变成间接带隙。当本征ReS2体系的拉伸变形量达到10%时,带隙减小到0.064eV。拉伸变形降低了反射系数和吸收系数的增长率。最大反射和吸收峰发生红移,提高了吸附体系的光反射和吸收能力
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引用次数: 0
The effect of the concentration of tin (Sn) in the metallic precursor, on the structure, morphology, optical and electrical properties of electrochemically deposited lead-tin-sulphide (PbSnS) thin films 金属前驱体中锡(Sn)浓度对电化学沉积硫化铅锡(PbSnS)薄膜结构、形态、光学和电学性能的影响
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.206.399
I. Nkrumah, F. Ampong, A. Britwum, M. Paal, B. Kwakye-Awuah, R. K. Nkum, F. Boakye
A study has been carried out to investigate the effect of the concentration of Sn in the metallic precursor on the structure, morphology, optical and electrical properties of PbSnS thin films. The films were directly electrodeposited on ITO-coated glass substrates using a 3-electrode electrochemical cell having graphite as the counter electrode and Ag/AgCl as the reference electrode. Several depositions were carried out, with each deposited film having a different concentration of Sn in the metallic precursor whilst all other parameters were kept constant for all the films. Post deposition annealing was carried out in air at 250 o C for an hour. A variety of techniques were used to characterize the films. Results showed that the increase in Sn concentration did not modify the structure and preferred orientation of the films. However, it caused a slight increase in the average grain size of the films and electrical conductivity. All the films showed direct transition with the optical band gap reducing with increasing Sn concentration. The refractive index of the films showed anomalous dispersion behaviour within the UV region, and normal dispersion in the visible and infrared regions, whilst following an increasing trend with the grain size. SEM image showed spherically shaped grains of different sizes distributed randomly with good coverage across the entire area of the substrate. The EDAX spectrum was consistent with formation of the ternary PbSnS compound on ITO-coated glass substrate. Overall results indicate that, the optical and electrical properties of the electrochemically deposited PbSnS thin films can be tuned to make them suitable for specific applications by varying the concentration of Sn in the metallic precursor.
本文研究了金属前驱体中Sn浓度对PbSnS薄膜结构、形貌、光学和电学性能的影响。使用以石墨为对电极,Ag/AgCl为参比电极的三电极电化学电池,将薄膜直接电沉积在ito涂层玻璃基板上。进行了几种沉积,每种沉积膜在金属前驱体中具有不同的Sn浓度,而所有其他参数都保持不变。沉积后退火在250℃空气中进行1小时。各种各样的技术被用来描绘电影的特征。结果表明,Sn浓度的增加并没有改变薄膜的结构和取向。然而,它导致薄膜的平均晶粒尺寸和电导率略有增加。随着Sn浓度的增加,所有薄膜都表现出直接跃迁,光学带隙减小。薄膜的折射率在紫外区表现出反常的色散行为,在可见光和红外区表现出正常的色散行为,随晶粒尺寸的增大而增大。SEM图像显示,不同尺寸的球形颗粒随机分布,覆盖了整个衬底区域。EDAX光谱与ito涂层玻璃衬底上三元PbSnS化合物的形成一致。总体结果表明,电化学沉积的PbSnS薄膜的光学和电学性质可以通过改变金属前驱体中Sn的浓度来调整,使其适合于特定的应用。
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引用次数: 0
Upconversion red light emission and luminescence thermometry of Gd2O3:Er3+ @Gd2O3:Yb3+ core-shell nanofibers synthesized via electrospinning 静电纺丝合成Gd2O3:Er3+@Gd2O3:Yb3+核壳纳米纤维的上转换红光发射和发光测温
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.207.439
Z. Liu, R. X. Wang, K. Sun, X. Ling, J. W. Sun, D. Chen
Gd2O3:Er3+@Gd2O3:Yb3+ core-shell nanofibers with cubic phase were successfully fabricated by electrospinning method. The structural, morphological properties were investigated by X-Ray diffraction, scanning electron microscopy. Under 980 nm excitation, the upconversion photoluminescence in visible light exhibits strong red emitting band with obvious splitting peaks resulted from stark splitting of energy level. The visible emissions are sensitive to temperature in the range of 303-543 K. The red emission displays quenching with elevation of temperature. The activation energy for thermal quenching is equal to 0.1408 eV. The temperature dependent multi-peaks of red emission were systematically investigated. Based on valley and peak ratio of I680.31nm/ I683.03nm in upconversion emission spectra, temperature sensing with constant absolute sensitivity was achieved. These results suggest Gd2O3:Er3+@Gd2O3:Yb3+ nanofibers are promising candidates for luminescence thermometry, which may provide their application values in both scientific research and industry.
采用静电纺丝方法成功制备了具有立方相的Gd2O3:Er3+@Gd2O3:Yb3+核壳纳米纤维。用X射线衍射、扫描电子显微镜对其结构、形貌进行了研究。在980nm激发下,可见光中的上转换光致发光表现出强烈的红光发射带,能级的明显分裂导致了明显的分裂峰。可见光发射对303-543K范围内的温度敏感。红色发射显示随着温度的升高而猝灭。热猝灭的活化能为0.1408eV。系统地研究了与温度相关的红色发射多峰。基于上转换发射光谱中I680.31nm/I683.03nm的谷峰比,实现了具有恒定绝对灵敏度的温度传感。这些结果表明,Gd2O3:Er3+@Gd2O3:Yb3+纳米纤维是一种很有前途的发光测温材料,在科学研究和工业上都有应用价值。
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引用次数: 0
Synthesis and optical properties of the glassy compound As0.63S2.70Sb1.37Te0.30 玻璃状化合物As0.63S2.70Sb1.37Te0.30的合成及光学性质
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-05 DOI: 10.15251/cl.2023.205.387
M. Iovu, I. Culeac, V. Verlan, O. Bordian, M. Enăchescu, A. Popescu, D. Savastru, A. Lazar
The amorphous calcogenide semiconductor As0.63S2.70Sb1.37Te0.30 was synthesized and thin films based on it were obtained. XRD and optical images investigations showed the amorphous and homogeneous nature of the samples. The optical transmission spectrum in the UV-Vis range of As0.63S2.70Sb1.37Te0.30 thin films shows good transparency in the spectral range 0.7-3.5 µm with a single absorption threshold at 2.05 eV and with refractive index in infrared 2.3. The irradiation of films with light leads to a parallel shift of the transmission spectrum to the IR range. The materials with As0.63S2.70Sb1.37Te0.30 composition have high optical transparency have high optical transparency that make they promises for applications in holographic memory devices, optical amplitude and phase recorder, optical processing units and others.
合成了非晶钙源化合物半导体As0.63S2.70Sb1.37Te0.30,并在此基础上制备了薄膜。XRD和光学图像研究表明样品具有非晶态和均匀性。As0.63S2.70Sb1.37Te0.30薄膜在UV-Vis范围内的光学透射光谱在0.7-3.5µm的光谱范围内显示出良好的透明度,在2.05eV处具有单一吸收阈值,在红外中具有2.3的折射率。用光照射薄膜导致透射光谱向IR范围的平行移动。As0.63S2.70Sb1.37Te0.30成分的材料具有高光学透明度和高光学透明度,有望应用于全息存储设备、光学振幅和相位记录器、光学处理单元等。
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引用次数: 0
Fabrication and investigation of zinc telluride thin films 碲化锌薄膜的制备与研究
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.15251/cl.2023.207.477
R. H. Athab, B. H. Hussein
Zinc Telluride ZnTe alloys and thin film have been fabricated and deposited on glass substrates by thermal evaporation method which may be a suitable window layer of zinc telluride with different annealing temperatures (373 and473) K for 60 minutes in vacuum. Deposited thin films with thickness 100 nm was characteristic by using X-ray diffraction XRD to know structures, Atomic Force Microscopy (AFM) to evaluate surface topology, morphology. It was found out that the vacuum annealing improves on thin ZnTe films structure and surface morphology. Structural analysis reveals that ZnTe films have zinc blende structure of cubic phase with (111) preferred reflection and grain size is enhanced from 8.6 to 16.7 nm with annealing. Optical properties where optical bandgap energy values slightly decreased (2.3-2.2) eV as the annealing temperatures.
碲化锌ZnTe合金和薄膜已经通过热蒸发法制造并沉积在玻璃衬底上,该方法可以是碲化锌的合适窗口层,在真空中具有不同的退火温度(373和473)K达60分钟。通过X射线衍射XRD了解沉积的100nm薄膜的结构,原子力显微镜(AFM)评估其表面拓扑结构、形貌。研究发现,真空退火对ZnTe薄膜的结构和表面形貌均有改善。结构分析表明,ZnTe薄膜具有(111)择优反射的立方相闪锌矿结构,退火后晶粒尺寸从8.6nm提高到16.7nm。光学性质,其中光学带隙能量值随着退火温度略微降低(2.3-2.2)eV。
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引用次数: 0
Structure and electronic properties of thin Ge2Sb2Te5 films produced by DC ion-plasma spattering 直流离子等离子溅射制备Ge2Sb2Te5薄膜的结构和电子性能
IF 1 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2023-07-01 DOI: 10.15251/cl.2023.207.487
S. Sultanbekov, O. Prikhodko, N. Almas
The optical properties of Ge2Sb2Te5 thin films were studied as a function of thickness. An increase in optical band gap with decreasing film thickness has been observed. The current– voltage characteristics measured in Ge2Sb2Te5 thin films in the current mode are studied. A decrease in switching time and threshold voltage with decreasing film thickness is established.
研究了Ge2Sb2Te5薄膜的光学性质随厚度的变化规律。光学带隙随薄膜厚度的减小而增大。研究了Ge2Sb2Te5薄膜在电流模式下的电流电压特性。开关时间和阈值电压随薄膜厚度的减小而减小。
{"title":"Structure and electronic properties of thin Ge2Sb2Te5 films produced by DC ion-plasma spattering","authors":"S. Sultanbekov, O. Prikhodko, N. Almas","doi":"10.15251/cl.2023.207.487","DOIUrl":"https://doi.org/10.15251/cl.2023.207.487","url":null,"abstract":"The optical properties of Ge2Sb2Te5 thin films were studied as a function of thickness. An increase in optical band gap with decreasing film thickness has been observed. The current– voltage characteristics measured in Ge2Sb2Te5 thin films in the current mode are studied. A decrease in switching time and threshold voltage with decreasing film thickness is established.","PeriodicalId":9710,"journal":{"name":"Chalcogenide Letters","volume":" ","pages":""},"PeriodicalIF":1.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45060182","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Chalcogenide Letters
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