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Dynamic modeling and controllability analysis of DME production in an isothermal fixed bed reactor 等温固定床反应器二甲醚生产动力学建模及可控性分析
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22917
M. Farsi
In this study, to enhance Dimethyl Ether (DME) production from methanol dehydration, an isothermal fixed-bed reactor has been modeled heterogeneously against a commercial adiabatic reactor at dynamic condition. A sensitivity analysis has been carried out to evaluate the influence of input variables on the process conditions using considered dynamic model. The results of sensitivity analysis showed that the feed composition is the main input variable in this system. Also, the process controllability has been investigated using a conventional feedback PID controller. The outlet DME composition from the reactor and circulated boiling water pressure in the steam drum are selected as controlled and manipulated variables, respectively. The responses of the control system to disturbance rejection and setpoint tracking showed that the considered control structure can maintain the process at the desired condition. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22917 Chemical Engineering Research Bulletin 17(2015) 40-51
在这项研究中,为了提高甲醇脱水二甲醚(DME)的生产,在动态条件下对一个等温固定床反应器进行了非均匀模拟。采用考虑的动态模型,对输入变量对工艺条件的影响进行了敏感性分析。灵敏度分析结果表明,饲料组成是该系统的主要输入变量。同时,利用传统的反馈PID控制器对过程的可控性进行了研究。选取反应器出口二甲醚组成和汽包内循环沸水压力分别作为控制变量和操纵变量。控制系统对扰动抑制和设定值跟踪的响应表明,所考虑的控制结构可以使过程保持在期望的状态。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22917化学工程研究通报17(2015)40-51
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引用次数: 3
NEURAL NETWORK PREDICTION OF THE FISCHER-TROPSCH SYNTHESIS OF NATURAL GAS WITH Co (III)/Al2O3 CATALYST Co (III)/Al2O3催化剂下费托合成天然气的神经网络预测
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22915
M. Esfandyari, M. Amiri, M. K. Salooki
Application of Co (III)/Al 2 O 3 catalyst in Fischer-Tropsch synthesis (FTS) was studied in a wide range of synthesis gas conversions and compared with ANN Simulation results. Present study applies Neural Network model to predict composition of CH 4 , CO 2 and CO of the Fischer–Tropsch Process of Natural Gas, while the input vector was 4-dimension vector including four variables from operating pressure, operating temperature, time and ratio of CO/H 2 of 70 different experiments and the output were composition of CO 2 , CO and CH 4 . The MLP algorithm has been applied for the training and the test set was applied to evaluate the performance of the system including R2, MAE, MSE and RMSE. The results exposed that the predicted values from the model were in good agreement with the experimental data. The paper indicates how Neural Network, as a promising predicting technique, would be effectively used for FTS. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22915 Chemical Engineering Research Bulletin 17(2015) 25-33
研究了Co (III)/ al2o3催化剂在费托合成(FTS)中的应用,并与人工神经网络模拟结果进行了比较。本研究采用神经网络模型对天然气费托过程中ch4、CO 2和CO的组成进行预测,输入向量为包含70个不同实验的操作压力、操作温度、时间和CO/H 2比4个变量的4维向量,输出为CO 2、CO和CH 4的组成。采用MLP算法进行训练,并采用测试集R2、MAE、MSE和RMSE来评估系统的性能。结果表明,模型预测值与实验数据吻合较好。本文指出了神经网络作为一种很有前途的预测技术,将如何有效地用于FTS预测。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22915化学工程研究通报17(2015)25-33
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引用次数: 13
EXPERIMENENTAL STUDY OF THE EFFECT OF ORIFICE INCLINATION ON GAS HOLDUP IN BUBBLE COLUMNS 孔板倾角对气泡塔气含率影响的实验研究
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22914
I. Hossain, A. Rakib, Badruddhuza Talukder, H. Hira
Gas holdup in the column section of bubble columns is determined by a large number of operating-design variables-parameters. In this study the effect of orifice inclination on the gas holdup is investigated at various superficial gas velocities. It is observed that the effect depends largely on the gas velocities. At very low gas velocities such as 0.015-0.076 cm/s where truly dispersed-bubble regime prevails, an inclination of the orifice keeping the size unchanged tends to decrease the gas holdup. However this effect diminishes with increasing gas velocity and no remarkable effect is found at relatively higher gas velocities like 2.20-8.50 cm/s where dispersed-transition-coalesced bubble regimes prevail. Therefore when bubble columns are intended to operate at very low superficial gas velocities, the orifice inclination is also an alternative option to control the gas holdup at the desired level. The experimental results produced in this study would be useful for the development and validation of proper mathematical model. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22914 Chemical Engineering Research Bulletin 17(2015) 18-24
气泡塔塔段气含率是由大量的运行设计变量参数决定的。本文研究了不同表面气速下孔板倾角对气含率的影响。可以观察到,这种效应在很大程度上取决于气体的速度。在非常低的气速下,如0.015-0.076 cm/s,当真正的分散气泡状态盛行时,保持尺寸不变的孔板倾斜倾向于降低气含率。然而,这种效应随着气速的增加而减弱,并且在相对较高的气速(如2.20-8.50 cm/s)中没有发现显著的影响,在这种情况下,分散-过渡-合并的气泡状态普遍存在。因此,当气泡柱打算在非常低的表面气速下运行时,孔板倾角也是将气含率控制在所需水平的另一种选择。本研究的实验结果将有助于建立和验证适当的数学模型。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22914化学工程研究通报17(2015)18-24
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引用次数: 1
DEVELOPMENT OF ONLINE DATA FILTERING BASED ON KALMAN FILTER 基于卡尔曼滤波的在线数据滤波研究
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22913
B. Baloochy, S. Shokri
Knowledge of accurate process measurements in the form of Flow, temperature and pressure strongly affect product quality, process real time optimization and control, plant safety and plant profitability. The paper reports an experience with online data filtering in Naphtha Hydrotreater setup. First, pilot plant data is analyzed for detecting and removing faulty data and gross errors. To remove noise hidden in the process data, a fast and adaptive data denoising technique is proposed. The proposed technique is based on the recursive least square to identify the pilot plant model and the Kalman filter to reconcile noisy data. This technique offers competitive advantages over conventional approaches: Independent and adaptive model and less computation time. From several pilot runs, the proposed technique has shown good performance in terms of accuracy and speed. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22913 Chemical Engineering Research Bulletin 17(2015) 11-17
了解流量、温度和压力等精确的过程测量对产品质量、过程实时优化和控制、工厂安全和工厂盈利能力有很大影响。本文报道了在石脑油加氢装置中进行在线数据过滤的经验。首先,对中试工厂数据进行分析,以检测和消除错误数据和严重误差。为了去除过程数据中隐藏的噪声,提出了一种快速、自适应的数据去噪技术。该方法基于递推最小二乘法识别中试装置模型,并基于卡尔曼滤波协调噪声数据。与传统方法相比,该技术具有竞争优势:独立的自适应模型和更少的计算时间。经过多次试运行,该方法在精度和速度方面均取得了良好的效果。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22913化学工程研究通报17(2015)11-17
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引用次数: 0
CATEGORICAL ASSESSMENT AND CHARACTERIZATION OF CONVENTIONAL AND UNCONVENTIONAL BIOMASS RESOURCES IN BANGLADESH 孟加拉国常规和非常规生物质资源的分类评估和特征
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22910
M. Hossen, Alfi Rahman, A. Kabir, M. Hasan, Shoeb Ahmed
With the rapid industrial growth, the need for renewable energy sources is rising fast. Being a developing country, Bangladesh aims towards industrial expansion, which is always followed by increased energy consumption. Considering the fact that fossil fuel is not sustainable and biomass sources are abundant and offer more versatility, the latter have become an attractive alternative to petroleum-based products. Moreover, utilization of biomass also seems promising because of biodegradability and lower greenhouse gas emissions, ensuring reduced environmental pollution, a grave concern with fossil-fuel technology. Biomass can range from agricultural byproducts to industrial and municipal wastes, however, very few biomass sources are currently being used in Bangladesh. Moreover, biomass can also be utilized to derive valuable chemicals, which are potential raw materials in several existing industries in Bangladesh. Despite having massive potential in Bangladesh, there haven't been organized studies on feedstock types, quantities, characterization and applications. Here we present an organized study to identify potential biomass sources and their available quantities. Considering specific waste fractions from varying sources, total amount of utilizable biomass resources have been calculated. A categorized proximate analysis data summary of varying biomass is also prepared that can be consulted in the future studies to calculate the theoretical possible production of energy as well as useful bio-chemicals based on efficient bio-processing techniques. This work is intended to benchmark the current efforts, and would add valuable information resources for the ongoing research towards achieving energy-sustainability and energy-security in Bangladesh. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22910 Chemical Engineering Research Bulletin 17(2015) 1-10
随着工业的快速发展,对可再生能源的需求也在快速增长。作为一个发展中国家,孟加拉国的目标是工业扩张,这总是伴随着能源消耗的增加。考虑到化石燃料不可持续,而生物质资源丰富且用途广泛,后者已成为石油基产品的一个有吸引力的替代品。此外,生物质的利用似乎也很有希望,因为生物可降解性和温室气体排放量较低,确保减少环境污染,这是化石燃料技术的一个严重问题。生物质的范围可以从农业副产品到工业和城市废物,但是,孟加拉国目前使用的生物质的来源非常少。此外,生物质还可用于生产有价值的化学品,这些化学品是孟加拉国若干现有工业的潜在原料。尽管在孟加拉国有巨大的潜力,但还没有对原料类型、数量、特性和应用进行有组织的研究。在这里,我们提出了一项有组织的研究,以确定潜在的生物质来源及其可用数量。考虑到来自不同来源的特定废物馏分,计算了可利用生物质资源的总量。还准备了不同生物量的分类近似分析数据摘要,可以在未来的研究中参考,以计算基于高效生物处理技术的理论可能的能源生产以及有用的生化物质。这项工作的目的是为目前的努力提供基准,并将为正在进行的在孟加拉国实现能源可持续性和能源安全的研究增加宝贵的资料资源。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22910化学工程研究通报17(2015)1-10
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引用次数: 2
RECYCLING OF MIXED PLASTICS WASTE CONTAINING POLYETHYLENE, POLYVINYLCHLORIDE AND POLYETHYLENE TEREPHTHALATE 回收含聚乙烯、聚氯乙烯和聚对苯二甲酸乙二醇酯的混合塑料废物
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.17471
G. M. Mamoor, W. Shahid, Amir Mushtaq, U. Amjad, U. Mehmood
This research work was undertaken to investigate the spectroscopic, morphological and rheological properties of polymer blends made of recycled Polyethylene terephthalate (PET), Polyethylene (PE) and Polyvinylchloride (PVC). Different blends of these polymers were made by varying composition of PET. Each recycled blend consisted of recycled polymers and ethylene propylene diene monomer (EPDM) as a compatiblizer. Spectroscopic and morphological characteristics of recycled polymer blends were investigated using Fourier Transform Infrared Spectrometer (FTIR) and Scanning Electron Microscope (SEM) respectively. SEM analysis revealed low miscibility among these three polymers. While rheological properties were investigated using Melt Flow Indexer (MFI). The rheological characterization indicated that melt flow index (MFI) decreases with increase of PET concentration in PE/PET/PVC recycled blends. It was also observed that with increase of PET contents recycled blends show pseudoplastic behavior. DOI: http://dx.doi.org/10.3329/cerb.v16i1.17471 Chemical Engineering Research Bulletin 16(2013) 25-32
本文研究了由再生聚对苯二甲酸乙二醇酯(PET)、聚乙烯(PE)和聚氯乙烯(PVC)制成的聚合物共混物的光谱、形态和流变性能。这些聚合物的不同共混物是由不同的PET组成的。每种回收共混物由回收聚合物和乙丙二烯单体(EPDM)作为增容剂组成。利用傅里叶变换红外光谱仪(FTIR)和扫描电子显微镜(SEM)分别研究了回收聚合物共混物的光谱和形态特征。扫描电镜分析表明,这三种聚合物的互溶性较低。同时用熔体流动指数仪(MFI)研究了材料的流变性能。流变学表征表明,PE/PET/PVC再生共混物的熔体流动指数(MFI)随PET浓度的增加而降低。随着PET含量的增加,再生共混物表现出假塑性行为。DOI: http://dx.doi.org/10.3329/cerb.v16i1.17471化学工程研究通报16(2013)25-32
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引用次数: 14
Bioethanol Fermentation from Non-Treated and Pretreated Corn Stover using Aspergillus Oryzae 利用米曲霉从未处理和预处理的玉米秸秆发酵生物乙醇
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.6659
S. M. Hossain
A comparison was studied for non-treated and pretreated corn stover with dilute alkaline peroxide and dilute acid treatment respectively for bioethanol production by simultaneous saccharification and fermentation (SSF) process in a continuous stirred batch bioreactor using fungi Aspergillus oryzae . The optimum parameters for bioethanol fermentation were: time, 48 h; pH, 6.0; temperature, 50oC; stirring speed, 35 rpm; and corn stover loading, 35 g/L. The maximum concentration of bioethanol at optimum fermentation process parameters were 0.762 g/g, 0.799 g/g and 0.819 g/g for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover respectively. Maximum yields of bioethanol were 0.399 g/L h, 0.420 g/L.h and 0.431 g/L h of corn stover at optimum parameters for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover respectively. The sp. growth rate (m) were  5.30 s −1 , 5.54 s −1 , and 5.93 s −1 and maximum sp. growth rate (m max ) were  10.60 s −1 , 11.08 s −1 and 11.86 s −1 using Monod model for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover  respectively. The Monod parameter (K s ) were 33.87 g/L, 34.21 g/L and 34.85 g/L for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover respectively.  The sp. enzyme activity (ν) were  1192 min −1 , 1463 min −1 and 1559 min −1 and maximum sp. growth rate (ν max ) were  2384 min −1 , 2926 min −1 and 3118 min −1 using Michaelis-Menten enzyme kinetic model for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover  respectively. The Michaelis-Menten parameter (K m ) were 34.42 g/L, 34.63 g/L and 34.85 g/L for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover respectively.  The first order rate constants (k) were 0.014 h −1 , 0.016 h −1 and 0.019 h −1 for non-treated, dilute acid and dilute alkaline peroxide pretreated corn stover for continuous stirred batch bioreactor respectively. DOI: http://dx.doi.org/10.3329/cerb.v16i1.6659 Chemical Engineering Research Bulletin 16(2013) 33-44
以米曲霉为原料,在连续搅拌间歇式生物反应器中,对未经处理和预处理的玉米秸秆分别进行了稀碱性过氧化氢和稀酸处理,并对其糖化发酵(SSF)工艺进行了比较。生物乙醇发酵的最佳工艺参数为:发酵时间48 h;pH值6.0;温度、50摄氏度;搅拌速度,35转/分;玉米秸秆装载量为35 g/L。未处理玉米秸秆、稀酸预处理玉米秸秆和稀碱性过氧化氢预处理玉米秸秆在最佳发酵工艺条件下的最大生物乙醇浓度分别为0.762 g/g、0.799 g/g和0.819 g/g。未处理玉米秸秆、稀酸预处理玉米秸秆和稀碱性过氧化氢预处理玉米秸秆的最佳工艺条件下,生物乙醇的最大产率分别为0.399 g/L h、0.420 g/L h和0.431 g/L h。在Monod模型下,未处理、稀酸和稀碱性过氧化氢预处理玉米秸秆的sp生长速率(m)分别为5.30 s−1、5.54 s−1和5.93 s−1,最大sp生长速率(m max)分别为10.60 s−1、11.08 s−1和11.86 s−1。未处理玉米秸秆、稀酸预处理玉米秸秆和稀碱性过氧化氢预处理玉米秸秆的Monod参数(K s)分别为33.87 g/L、34.21 g/L和34.85 g/L。采用Michaelis-Menten酶动力学模型,未处理、稀酸和稀碱性过氧化氢预处理玉米秸秆的sp酶活性(ν)分别为1192、1463和1559 min−1,最大sp生长速率(ν max)分别为2384、2926和3118 min−1。未处理、稀酸和稀碱性过氧化氢预处理玉米秸秆的Michaelis-Menten参数(K m)分别为34.42 g/L、34.63 g/L和34.85 g/L。连续搅拌间歇式生物反应器中未处理、稀酸预处理和稀碱性过氧化氢预处理的玉米秸秆一级速率常数(k)分别为0.014 h−1、0.016 h−1和0.019 h−1。DOI: http://dx.doi.org/10.3329/cerb.v16i1.6659化学工程研究通报16(2013)33-44
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引用次数: 6
RADIATION EFFECT ON MHD STEADY FREE CONVECTION FLOW OF A GAS AT A STRETCHING POROUS SURFACE WITH A UNIFORM FREE STREAM 辐射对均匀自由流拉伸多孔表面气体MHD稳定自由对流的影响
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.9287
K. Govardhan, S. Renuka, N. Kishan
This article investigates the influence of radiation effect on steady free convection flow near isothermal stretching porous sheet in the presence of magnetic field. The governing equations are converted into a system of non-linear ordinary differential equations via a similarity transformation. The resulting system of nonlinear coupled ordinary differential equations are solved numerically by using the Adams-Moulton predictor-corrector method with the shooting method. The numerical results for the velocity and temperature profiles are displayed graphically showing the effect of various values of the flow parameters: radiation parameter, free convection parameter Gr, Magnetic parameter M, Prandtl number, porous parameter K and the parameter of relative difference between the temperature of the sheet, and the temperature far away from the sheet r . The effect of the radiation and magnetic field parameter on the shear stress, porosity and heat flux are discussed. FPr DOI: http://dx.doi.org/10.3329/cerb.v16i1.9287 Chemical Engineering Research Bulletin 16(2013) 16-24
本文研究了磁场存在下辐射效应对等温拉伸多孔板稳定自由对流的影响。通过相似变换将控制方程转化为非线性常微分方程组。采用Adams-Moulton预测校正法和射击法对得到的非线性耦合常微分方程组进行了数值求解。速度和温度分布的数值结果以图形形式显示了不同流动参数值的影响:辐射参数、自由对流参数Gr、磁性参数M、普朗特数、多孔参数K以及片材温度与远离片材温度之间的相对差值r。讨论了辐射和磁场参数对剪切应力、孔隙率和热流密度的影响。FPr DOI: http://dx.doi.org/10.3329/cerb.v16i1.9287化学工程研究通报16(2013)16-24
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引用次数: 0
A Robust Approach in Nonlinear Fuzzy Control of Chemical Process 化工过程非线性模糊控制的鲁棒方法
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.12720
B. Baloochy
This paper presents a novel and robust fuzzy controller. The controller has conventional fuzzy inputs membership functions but has Bang-bang subsequent outputs membership functions. The controller on-line adaptation is accomplished by tuning and self-organizing the input membership functions. New rules and membership functions are created on-line with sliding mode control knowledge base rules. The system’s closed loop stability is assured for each rule, which is stable in sense of Lyapunov. The suggested controller performance and analysis is confirmed by simulation of well know non-linear benchmark problems. DOI: http://dx.doi.org/10.3329/cerb.v16i1.12720 Chemical Engineering Research Bulletin 16(2013) 45-60
提出了一种新颖的鲁棒模糊控制器。控制器具有传统的模糊输入隶属函数,但具有Bang-bang的后续输出隶属函数。控制器的在线自适应是通过调整和自组织输入隶属度函数来实现的。利用滑模控制知识库规则在线创建新的规则和隶属函数。保证了系统的闭环稳定性,在李雅普诺夫意义上是稳定的。通过对已知的非线性基准问题的仿真验证了所提控制器的性能和分析。DOI: http://dx.doi.org/10.3329/cerb.v16i1.12720化学工程研究通报16(2013)45-60
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引用次数: 1
FIXED-BED ADSORPTION SEPARATION OF XYLENE ISOMERS OVER SIO2/SILICALLITE-1 CORE-SHELL ADSORBENTS 二氧化硅/硅石-1核壳吸附剂对二甲苯异构体的固定床吸附分离
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.17470
E. A. Khan, A. Rajendran, Z. Lai
SiO 2 /Silicalite-1 core-shell material has been demonstrated as potential shape selective adsorbent in gas phase separation of p-xylene from a mixture of p/o-xylene isomers. The core-shell composite comprised of large silica core and thin polycrystalline silicalite-1 shell which was synthesized via a self-assembly of silicalite-1 nanocrystals on core silica surface followed by a secondary seeded growth method. The core materials, SiO 2 used in this study has mesoporosity with an average pore diameter of 60A and hence offers no shape selectivity for xylene isomers. However, the shell, silicalite-1 contains rigid pore structures and preferentially adsorbs p-xylene from their isomers mixtures. A series of adsorption fixed bed breakthrough adsorption/desorption experiment was performed to obtain the equilibrium isotherms and adsorption isotherm parameters of xylene isomers. The equilibrium isotherms of xylene isomers follow the Langmuir’s model. A chromatographic adsorption model has been used to describe the fixed-bed breakthrough profiles of xylene isomers. The model has successfully predicted the responses of the binary mixtures of p/o-xylene isomers. The SiO 2 /silicalite-1 core-shell adsorbents have shown para-selectivity as high as 15. DOI: http://dx.doi.org/10.3329/cerb.v16i1.17470 Chemical Engineering Research Bulletin 16(2013) 1-15
二氧化硅/硅石-1核壳材料已被证明是气相分离对二甲苯和对二甲苯异构体混合物的潜在形状选择吸附剂。该复合材料由大硅芯和薄多晶硅石-1壳组成,该多晶硅石-1壳是通过硅石-1纳米晶在硅芯表面的自组装,然后采用二次种子生长的方法合成的。本研究中使用的核心材料sio2具有介孔性,平均孔径为60A,因此对二甲苯异构体没有形状选择性。然而,壳,硅石-1具有刚性的孔隙结构,并优先从它们的异构体混合物中吸附对二甲苯。通过固定床突破吸附/脱附实验,获得了二甲苯异构体的平衡等温线和吸附等温线参数。二甲苯同分异构体的平衡等温线符合Langmuir模型。用色谱吸附模型描述了二甲苯同分异构体的固定床突破剖面。该模型成功地预测了对/邻二甲苯异构体二元混合物的反应。sio2 /硅石-1核壳吸附剂的准选择性高达15%。DOI: http://dx.doi.org/10.3329/cerb.v16i1.17470化学工程研究通报16(2013)1-15
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引用次数: 8
期刊
Chemical Engineering Research Bulletin
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