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EFFECT OF PORE SIZE DISTRIBUTION AND TEMPERATURE ON THE CATALYST TORTUOSITY 孔径分布和温度对催化剂扭曲度的影响
Pub Date : 2013-12-29 DOI: 10.3329/CERB.V16I1.13191
S. Sadighi, M. Bahmani, S. R. S. Mohadecy
Effect of temperature gradients, for an exothermic reaction, inside a catalyst pellet and the pore size distribution on the value of tortuosity factor is studied. The structure of the catalyst pellet is simulated using a two dimensional pore network. Material and energy balances for the pore network are written and discretised using a finite difference scheme. Tortuosity factors obtained for the isothermal and non-isothermal pellets are compared. Significant variation of the estimated tortuosity factor with internal particle temperature gradient and pore size is obtained.
研究了放热反应中催化剂球团内部温度梯度和孔径分布对扭曲系数值的影响。采用二维孔隙网络模拟了催化剂颗粒的结构。孔隙网络的物质和能量平衡用有限差分格式进行了书写和离散。对等温球团和非等温球团的弯曲系数进行了比较。估计的扭曲系数随内部颗粒温度梯度和孔径的显著变化。
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引用次数: 4
Effects of heat source/sink on MHD flow and heat transfer over a shrinking sheet with mass suction 热源/吸热对吸力收缩薄板MHD流动和传热的影响
Pub Date : 2011-09-30 DOI: 10.3329/CERB.V15I1.6524
K. Bhattacharyya
An analysis is made to study the effects heat source/sink on the steady two dimensional MHD boundary layer flow and heat transfer past a shrinking sheet with wall mass suction. In the dynamic system, a uniform magnetic field acts normal to the plane of flow. The governing partial differential equations are transformed into self-similar ordinary differential equations using similarity transformations. Then the obtained self-similar equations are solved by finite difference method using quasilinearization technique. From the analysis it is found that the velocity inside the boundary layer enhances with increase of wall suction and magnetic field and accordingly the thickness of the momentum boundary layer decreases. The temperature decreases with Hartmann number, Prandtl number and heat sink parameter and the temperature increases with heat source parameter. Furthermore, for strong heat source heat absorption at the sheet occurs. Key words: MHD boundary layer, heat transfer, shrinking sheet, heat source/sink, suction. DOI: http://dx.doi.org/10.3329/cerb.v15i1.6524 Chemical Engineering Research Bulletin 15 (2011) 12-17
分析了吸力作用下热源/吸热对MHD稳定二维边界层流动和收缩板传热的影响。在动力系统中,均匀的磁场垂直于流动平面。利用相似变换将控制偏微分方程转化为自相似常微分方程。然后利用拟线性化技术,用有限差分法求解得到的自相似方程。分析发现,边界层内的速度随壁面吸力和磁场的增大而增大,动量边界层的厚度相应减小。温度随哈特曼数、普朗特数和散热器参数的增加而降低,随热源参数的增加而升高。此外,对于强热源,薄板处发生吸热。关键词:MHD边界层,传热,收缩片,热源/吸力DOI: http://dx.doi.org/10.3329/cerb.v15i1.6524化学工程研究通报15 (2011)12-17
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引用次数: 71
Evaluation of crude oil property using intelligence tool: fuzzy model approach 基于智能工具的原油物性评价:模糊模型法
Pub Date : 2011-09-30 DOI: 10.3329/CERB.V15I1.7334
R. Abedini, M. Esfandyari, A. Nezhadmoghadam, H. Adib
Viscosity is one of the most important governing parameters of the fluid flow, either in the porous media or in pipelines. So it is important to use an accurate method to calculate the oil viscosity at various operating conditions. In the literature, several empirical correlations have been proposed for predicting undersaturated crude oil viscosity. However these correlations are not able to predict the oil viscosity adequately for a wide range of conditions. In present work, an extensive experimental data of undersaturated oil viscosities from different samples of Iranian oil reservoirs was applied to develop a Fuzzy model to predict and calculate the undersaturated oil viscosity. Validity and accuracy of these models has been confirmed by comparing the obtained results of these correlations and with experimental data for Iranian oil samples. It was observed that there is acceptable agreement between Fuzzy model results with experimental data. Key words: Viscosity; Correlation; Fuzzy model; undersaturated crude oil DOI: http://dx.doi.org/10.3329/cerb.v15i1.7334 Chemical Engineering Research Bulletin 15 (2011) 30-33
无论是在多孔介质中还是在管道中,粘度都是流体流动最重要的控制参数之一。因此,采用一种准确的方法来计算各种工况下的油粘度是非常重要的。在文献中,已经提出了几个经验相关性来预测不饱和原油粘度。然而,这些相关性不能在广泛的条件下充分预测油的粘度。本文利用伊朗不同油藏样品的大量不饱和油粘度实验数据,建立了预测和计算不饱和油粘度的模糊模型。通过将这些相关性得到的结果与伊朗石油样品的实验数据进行比较,证实了这些模型的有效性和准确性。结果表明,模糊模型计算结果与实验数据有较好的一致性。关键词:粘度;相关性;模糊模型;不饱和原油DOI: http://dx.doi.org/10.3329/cerb.v15i1.7334化学工程研究通报15 (2011)30-33
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引用次数: 4
Acrylamide Formation during the Frying of Beef Burger: Effect of Temperature and Time 牛肉饼煎炸过程中丙烯酰胺的形成:温度和时间的影响
Pub Date : 2011-09-30 DOI: 10.3329/CERB.V15I1.7610
S. Ghasemian, K. Rezaei, R. Abedini, H. Poorazarang
Acrylamide (CH 2 = CHCONH 2 ) is creating cancer chemical which produced in certain foods due to heating process at high temperature and low humidity conditions. Due to the hazardous effect of acrylamide, in this study, the effect of additives (garlic and pepper), oils (sunflower and Canola), frying temperature (180 and 200°C) and frying time (4 and 6 minutes) on the acrylamide levels has been discussed in fried beef burger using full factorial design of experiment (DOE). Produced acrylamide in each sample was analyzed by FID-GC system in the presence of internal standard. Between investigated parameters, results from DOE reveal that frying temperature has the highest impact on the produced acrylamide. Key words: Acrylamide; frying temperature; frying time; full factorial design DOI: http://dx.doi.org/10.3329/cerb.v15i1.7610 Chemical Engineering Research Bulletin 15 (2011) 39-44
丙烯酰胺(ch2 = CHCONH 2)是某些食品在高温低湿条件下加热过程中产生的致癌化学物质。由于丙烯酰胺的危害作用,本研究采用全因子实验设计(DOE),探讨了添加剂(大蒜和辣椒)、油类(向日葵和菜籽油)、煎炸温度(180°C和200°C)和煎炸时间(4和6分钟)对煎炸牛肉汉堡中丙烯酰胺含量的影响。在有内标存在的情况下,用FID-GC系统分析每个样品中产生的丙烯酰胺。在研究的参数之间,DOE的结果表明,油炸温度对丙烯酰胺的产量影响最大。关键词:丙烯酰胺;油炸温度;油炸时间;全因子设计DOI: http://dx.doi.org/10.3329/cerb.v15i1.7610化学工程研究通报15 (2011)39-44
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引用次数: 3
Cation exchange chromatographic separation of amines through fiber supported solid membrane 纤维支撑固体膜阳离子交换色谱分离胺
Pub Date : 2011-09-30 DOI: 10.3329/CERB.V15I1.6788
A. Gaikwad
The cation exchange chromatographic separation of pyridine, monoethanol and triethanol amines have been explored from source to receiving phase through the fiber supported solid membrane. The fibers supported solid membranes were prepared by chemically modification of cellulose fibers with introducing the carboxylic acid ion exchanging groups. The experimental variables explored were concentration of pyridine, monoethanol and triethanol amines (10 -2 to 10 -6 M) in the source solution, HCl (0.01 to 0.20 M) in the receiving phase and stirring speed (50-130 rpm) of the bulk source and receiving phase. The efficiency has been evaluated of fiber supported solid membrane system for the transport of pyridine, monoethanol and triethanol amines from the source solution to receiving phase through the fiber supported solid membrane. The pre-concentration was studied of pyridine, monoethanol and triethanol amines from the dilute solutions. Key words: Pyridine, monoethanol and triethanol amines, fiber supported solid membrane; ion exchange DOI: http://dx.doi.org/10.3329/cerb.v15i1.6788 Chemical Engineering Research Bulletin 15 (2011) 25-29
研究了利用纤维支撑固体膜从源相到接收相对吡啶、单乙醇和三乙醇胺进行阳离子交换色谱分离的方法。通过引入羧酸离子交换基团,对纤维素纤维进行化学改性,制备了支撑固体膜。实验变量为:源溶液中吡啶、单乙醇和三乙醇胺(10 -2 ~ 10 -6 M)的浓度,接收相中盐酸(0.01 ~ 0.20 M)的浓度,体源和接收相的搅拌速度(50 ~ 130 rpm)。评价了纤维支撑固体膜系统将吡啶、单乙醇和三乙醇胺从源溶液通过纤维支撑固体膜传输到接收相的效率。研究了从稀溶液中预富集吡啶、单乙醇和三乙醇胺。关键词:吡啶,单乙醇和三乙乙醇胺,纤维支撑固体膜;DOI: http://dx.doi.org/10.3329/cerb.v15i1.6788化学工程研究通报15 (2011)25-29
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引用次数: 0
REMOVAL OF Cd 2+ IONS FROM AQUEOUS SOLUTION USING LIVE AND DEAD Bacillus Subtilis 活枯草芽孢杆菌和死枯草芽孢杆菌去除水溶液中的cd2 +离子
Pub Date : 2011-09-30 DOI: 10.3329/CERB.V15I1.6618
V. Govindasamy, Tamilarasan Rengasamy, Dharmendra Das
Biosorption of heavy metals can be an effective process for the removal of toxic heavy metals present in the wastewater. An attempt is made in the present investigation to remove Cd 2+ ions from aqueous solutions using B.subtilis . Batch experiments were carried out for Cd 2+ removal over a wide range of operating conditions. It has been noticed that the Cd 2+ removal capacity dependent on the initial pH and the initial Cd 2+ concentration. Experimental data were analysed with kinetics and isotherm models. It has been observed that the pseudo second order kinetics and Freundlich isotherm equilibrium model fit well with the present data. The FTIR analysis of bacterial biomass revealed the presence of amino, carboxyl, hydroxyl and carbonyl groups, which are responsible for biosorption of Cd 2+ metal ions. The results indicated that the biomass of B.subtilis is an efficient bioaccumulant for the removal of Cd 2+ ions from aqueous solutions. Key words: Biosorption; Cd2+ removal; Kinetics; Isotherms; Bacillus subtilis-live and dead DOI: http://dx.doi.org/10.3329/cerb.v15i1.6618 Chemical Engineering Research Bulletin 15 (2011) 18-24
生物吸附重金属是去除废水中有毒重金属的有效方法。本研究尝试用枯草芽孢杆菌去除水溶液中的cd2 +离子。在较宽的操作条件下进行了批量实验。已经注意到,Cd 2+的去除能力取决于初始pH和初始Cd 2+浓度。用动力学和等温模型对实验数据进行了分析。结果表明,拟二级动力学和Freundlich等温平衡模型与实验数据吻合较好。对细菌生物量的FTIR分析表明,细菌生物量中存在氨基酸、羧基、羟基和羰基,这些基团负责对Cd +金属离子的生物吸附。结果表明,枯草芽孢杆菌生物量是去除水中Cd +的有效生物蓄积剂。关键词:生物吸附;Cd2 +删除;动力学;等温线;枯草芽孢杆菌-活与死DOI: http://dx.doi.org/10.3329/cerb.v15i1.6618化学工程研究通报15 (2011)18-24
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引用次数: 14
Boundary layer flow with diffusion and first-order chemical reaction over a porous flat plate subject to suction/injection and with variable wall concentration 受吸力/喷射作用和壁浓度变化的多孔平板上的边界层扩散和一级化学反应流动
Pub Date : 2011-08-16 DOI: 10.3329/CERB.V15I1.6464
K. Bhattacharyya
In this paper, an investigation is made to study the boundary layer flow over a porous flat plate with diffusion of chemically reactive species undergoing first-order reaction and subject to suction and injection. In this analysis, the variable plate concentration is considered. Using similarity variable technique, the governing partial differential equations are transformed into a set of self-similar ordinary differential equations which are solved by shooting method. The study reveals that for the increase of suction at the plate both velocity and concentration boundary layer thicknesses decrease and for increasing injection both thicknesses increase. The concentration at a fixed point decreases with increasing values of the Schmidt number Sc , the reaction rate parameter beta and the power-law exponent n . For a fixed point, with increase of beta the magnitude of concentration gradient initially increases and then after a point it decreases. The rate of solute transfer from the plate increases with reaction rate parameter and power-law exponent. Key words: Boundary layer flow; diffusion; first-order chemical reaction; porous flat plate; suction/injection DOI: http://dx.doi.org/10.3329/cerb.v15i1.6464 Chemical Engineering Research Bulletin 15 (2011) 6-11
本文研究了在吸力和注射作用下发生一级反应的化学反应物质扩散的多孔平板边界层流动。在此分析中,考虑了变板浓度。利用相似变量技术,将控制偏微分方程转化为一组自相似常微分方程,用射击法求解。研究表明,随着吸力的增加,速度和浓度边界层厚度减小,而随着注入量的增加,边界层厚度增大。固定点浓度随施密特数Sc、反应速率参数β和幂律指数n的增大而减小。对于一个固定点,随着β的增大,浓度梯度的大小先增大后减小。溶质转移速率随反应速率参数和幂律指数的增加而增加。关键词:边界层流动;扩散;一级化学反应;多孔平板;DOI: http://dx.doi.org/10.3329/cerb.v15i1.6464化学工程研究通报15 (2011)6-11
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引用次数: 6
Free radical graft modification of polyethylene with methacrylic acid and styrene monomer 甲基丙烯酸与苯乙烯单体自由基接枝改性聚乙烯的研究
Pub Date : 2011-08-09 DOI: 10.3329/CERB.V15I1.7419
M. Kamal, G. M. Mamoor, Nida Qamar, M. Farooq, Muhammad Sarfraz
Polar groups can be introduced on polyethylene by using polar monomer like acryl amide, acrylic acid and methacrylic acid. In present work binary monomer mixture of methacrylic acid and styrene were grafted onto low density polyethylene in the presence of dicumyl peroxide (DCP) as an initiator. Grafted polyethylene was characterized by using differential scanning calorimetry (DSC), melt flow Indexer (MFI) and Fourier transform infrared spectroscope (FTIR). Low value of MFI as compared to virgin polyethylene, presence of carbonyl peaks in the spectrum of grafted polyethylene and higher endothermic peaks in thermogram of grafted polyethylene confirmed grafting of methacrylic acid and styrene onto polyethylene. MFI values at different loads were used for further rheological study of virgin & grafted polyethylene. Key words: Degree of grafting, Meth acrylic acid, Free radical, Vinyl monomer, DCP DOI: http://dx.doi.org/10.3329/cerb.v15i1.7419 Chemical Engineering Research Bulletin 15 (2011) 34-38
极性基团可以用极性单体如丙烯酰胺、丙烯酸和甲基丙烯酸在聚乙烯上引入。本文以过氧化二氨基苯(DCP)为引发剂,将甲基丙烯酸和苯乙烯二元单体混合物接枝到低密度聚乙烯上。采用差示扫描量热法(DSC)、熔体流动指数仪(MFI)和傅里叶变换红外光谱仪(FTIR)对接枝聚乙烯进行了表征。MFI值较低,接枝聚乙烯光谱中存在羰基峰,接枝聚乙烯热图中存在较高的吸热峰,证实了甲基丙烯酸和苯乙烯在聚乙烯上接枝。不同载荷下的MFI值被用于进一步研究原生聚乙烯和接枝聚乙烯的流变学。关键词:接枝度,甲基丙烯酸,自由基,乙烯基单体,DCP DOI: http://dx.doi.org/10.3329/cerb.v15i1.7419化学工程研究通报15 (2011)34-38
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引用次数: 5
Polygalacturonase (PG) production by fungal strains using agro-industrial bioproduct in solid state fermentation 农工生物制品固态发酵真菌生产聚半乳糖醛酸酶(PG)的研究
Pub Date : 2011-08-08 DOI: 10.3329/CERB.V15I1.6368
H. Abbasi, Seyed Roholah Mortazavipour, Mehrdad Setudeh
Polygalacturonase production by isolated fungal strains was carried out in solid state fermentation. Aspergillus niger ( A. niger ) and Penicillium sp EGC5 produced polygalacturonase (PG) on mixture of apple bagasse and wheat bran. The mixture of apple bagasse and wheat bran acted as a good nutrient source and substrate for the cultivation of the microorganisms and polygalacturonase produced in solid state fermentation. In this respect, it was possible to obtain polygalacturonase activity at an acceptable yield, in comparison with a typical defined medium described in the literature for polygalacturonase production. Higher titres of polygalacturonase were observed when medium was supplemented with carbon (pectin) and nitrogen ((NH 4 ) 2 SO 4 and peptone) sources. The maximum production of polygalacturonase was reached after 8 days cultivation. The temperature was 30°C and the relative humidity of the fermentation medium was 70%. Key words: Polygalacturonase; Aspergillus niger; Apple bagasse; wheat bran; Solid state fermentation DOI: http://dx.doi.org/10.3329/cerb.v15i1.6368 Chemical Engineering Research Bulletin 15 (2011) 1-5
分离的真菌菌株在固态发酵中生产聚半乳糖醛酸酶。黑曲霉(Aspergillus niger)和青霉(Penicillium sp . EGC5)对苹果甘蔗渣和麦麸的混合物产生聚半乳糖醛酸酶(PG)。苹果甘蔗渣与麦麸的混合物为微生物的培养和固态发酵产生的聚半乳糖醛酸酶提供了良好的营养源和底物。在这方面,与文献中描述的聚半乳糖醛酸酶生产的典型定义培养基相比,有可能以可接受的产量获得聚半乳糖醛酸酶活性。当培养基中添加碳(果胶)和氮((nh4) 2so4和蛋白胨)源时,聚半乳糖醛酸酶的滴度较高。培养8天后,聚半乳糖醛酸酶产量达到最大值。温度为30℃,发酵培养基相对湿度为70%。关键词:聚半乳糖醛酸酶;黑曲霉;苹果蔗渣;小麦麸皮;固体发酵DOI: http://dx.doi.org/10.3329/cerb.v15i1.6368化学工程研究通报15 (2011)1-5
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引用次数: 16
Influence of impeller submergence depth on power consumption in stirred tank 叶轮入水深度对搅拌槽耗电量的影响
Pub Date : 2011-07-27 DOI: 10.3329/CERB.V15I1.7098
T. Devi, Banoth Malsur, B. Kumar
Impeller submergence governs the performance of mixing tanks employed in chemical and biochemical operation. Present work experimentally investigates the effect of impeller submergence depths on power consumption when arrow head impeller has been used in the process. Arrowhead impeller performs better than the conventional Rushton impeller. It has been found that at higher range of impeller submergence, mixing tanks consume less power. Optimal range of submergence depth is 0.8 to 0.9 times the impeller diameter. Key words: arrowhead impeller; power consumption; rotational speed; stirred tanks; submergence depth DOI: http://dx.doi.org/10.3329/cerb.v15i1.7098 Chemical Engineering Research Bulletin 15 (2011) 45-47
在化工和生化操作中,叶轮的浸入程度决定了混合槽的性能。本文通过实验研究了采用箭头叶轮时,叶轮浸入深度对能耗的影响。箭头叶轮比传统的拉什顿叶轮性能更好。研究发现,在较高的叶轮浸没范围内,搅拌槽耗电量较低。最佳淹没深度范围为叶轮直径的0.8 ~ 0.9倍。关键词:箭头叶轮;功耗;转速;搅拌罐;DOI: http://dx.doi.org/10.3329/cerb.v15i1.7098化学工程研究通报15 (2011)45-47
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引用次数: 3
期刊
Chemical Engineering Research Bulletin
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