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Comparative study of strong anion exchange hypercrosslinked poly(HEMA-co-EGDMA-co-VBC) and strong anion exchange poly(Styrene-co-EGDMA-co-VBC): Synthesis and characterization 强阴离子交换超交联聚(HEMA-co-EGDMA-co-VBC)与强阴离子交换聚(苯乙烯-co- egdma -co- vbc)的合成与表征
Pub Date : 2017-09-10 DOI: 10.3329/CERB.V19I0.33802
N. Abdullah, M. Yahya, R. Mahmod
Strong anion exchange hypercrosslinked of poly(HEMA-co-EGDMA-co-VBC) (PHEV) and strong anion exchange hypercrosslinked of poly(styrene-co-EGDMA-co-VBC) (PSEV) were prepared via amination reaction with dimethylbutyl amine (DMBA) as the amination agent in dried toluene. The resins were characterized by SEM, FTIR, BET and elemental analysis. SEM results showed that there was no significant change of the particles shape after amination reaction for both strong anion exchange hypercrosslinked PHEV and strong anion exchange hypercrosslinked PSEV. Specific surface area (SSA) of strong anion exchange hypercrosslinked PHEV increase from 1035 m2/g to 1090 m2/g when amination reaction take place. However, SSA of strong anion exchange hypercrosslinked PHEV decreased from 124 m2/g to 27 m2/g. From FTIR spectra, significant drop occurred at 1265 cm-1 band after amination reaction of strong anion exchange hypercrosslinked PSEV but SSA of strong anion exchange hypercrosslinkedPHEV showed slightly significant drop. Elemental analysis showed that nitrogen content of strong anion exchange hypercrosslinked PHEV significantly increase from 0.10% to 1.46% resulted to high IEC value. Meanwhile, nitrogen content in strong anion exchange hypercrosslinked PSEV only showed small increment in nitrogen content from 0.36% to 0.63% led to low IEC value.
以二甲基丁基胺(DMBA)为胺化剂,在干燥的甲苯中制备了强阴离子交换高交联的聚HEMA-co-EGDMA-co-VBC (PHEV)和强阴离子交换高交联的聚苯乙烯-co- egdma -co- vbc (PSEV)。通过SEM、FTIR、BET和元素分析对树脂进行了表征。SEM结果表明,强阴离子交换高交联PHEV和强阴离子交换高交联PSEV的胺化反应后颗粒形状没有明显变化。当胺化反应发生时,强阴离子交换超交联插电式混合动力汽车的比表面积(SSA)从1035 m2/g增加到1090 m2/g。而强阴离子交换超交联PHEV的SSA从124 m2/g下降到27 m2/g。从FTIR光谱看,强阴离子交换高交联phev胺化反应后1265 cm-1波段有明显下降,而强阴离子交换高交联phev的SSA略有下降。元素分析表明,强阴离子交换超交联插电式混合动力汽车的含氮量从0.10%显著提高到1.46%,从而获得较高的IEC值。同时,强阴离子交换超交联PSEV中氮含量仅从0.36%增加到0.63%,导致IEC值较低。
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引用次数: 1
Effect of the cross linkers concentration on the immobilization of recombinant Escherichia coli cells on hollow fiber membrane for excretion of cyclodextrin glucanotransferase (CGTase) 交联剂浓度对中空纤维膜固定重组大肠杆菌细胞排泄环糊精葡聚糖转移酶(CGTase)的影响
Pub Date : 2017-09-10 DOI: 10.3329/CERB.V19I0.33810
R. CheMan, R. Illias, S. Z. Sulaiman, S. K. A. Mudalip, S. Shaarani, Z. Arshad
The excretion of recombinant proteins into the culture medium is a preferred approach over cytoplasmic expression because of the high specific activity and ease of purification. However, cell lysis is one of a major problem during the excretion of recombinant protein due to the pressure build up in the periplasmic space through overproduction of the expressed recombinant protein. Cell immobilization is a promising solution for the improvement of protein excretion with reduction in cell lysis. In this study, the effect of cross linkers concentrations on the process of cell immobilization for the cyclodextringlucanotransferase (CGTase) excretion and cell viability were investigated. The hollow fiber membrane was treated using different concentrations (0.3, 0.67 and 1%) of cross linkers namely glutaraldehyde (GA), poly-L-lysine (PLL) and polyethylenimine (PEI). The optimum concentration of cross linkers was found to be 0.3% with the high excretion of CGTase. Interestingly, the immobilized cell on the non-treated hollow fiber membrane showed up to 15% increment of CGTase excretion with 55% reduction of cell lysis, as compared to the immobilized cells on the treated hollow fiber membrane. It could be concluded that, the low concentration of cross linkers exhibited the highest CGTase excretion. Moreover, the non-treated hollow fiber membrane is a promising approach for attachment of cells to the membrane without requiring treatment with any chemicals for the production of recombinant enzyme. Chemical Engineering Research Bulletin 19(2017) 154-159
由于高比活性和易于纯化,将重组蛋白排泄到培养基中是比细胞质表达更可取的方法。然而,细胞裂解是重组蛋白排泄过程中的主要问题之一,这是由于表达的重组蛋白过量产生的质周空间压力增加所致。细胞固定化是一种很有前途的解决方案,可以改善蛋白质排泄,减少细胞裂解。本研究考察了交联剂浓度对细胞固定化过程中环糊精葡聚糖转移酶(CGTase)排泄和细胞活力的影响。用不同浓度(0.3、0.67和1%)的交联剂戊二醛(GA)、聚l -赖氨酸(PLL)和聚乙烯亚胺(PEI)处理中空纤维膜。发现交联剂的最佳浓度为0.3%,具有较高的CGTase排泄量。有趣的是,与在中空纤维膜上固定的细胞相比,在未处理的中空纤维膜上固定的细胞显示出高达15%的CGTase排泄增加和55%的细胞裂解减少。由此可见,低浓度交联剂的CGTase排泄量最高。此外,未经处理的中空纤维膜是一种很有前途的方法,可以将细胞附着在膜上,而不需要用任何化学物质处理来生产重组酶。化工研究通报19(2017)154-159
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引用次数: 1
Antimicrobial agents from Malaysian plants and their potential use in food packaging material: Review 来自马来西亚植物的抗菌剂及其在食品包装材料中的潜在用途:综述
Pub Date : 2017-09-10 DOI: 10.3329/CERB.V19I0.33797
F. Mustapha, J. Jai, F. Hamidon, Z. Sharif, N. M. Yusof
Malaysia is among 12 countries in the world that rich in biodiversity including an assortment of plants with potential sources for new antimicrobial agents. Despite the fact that various plants have been screened, the requirement for detail study on antimicrobial compounds from plants is preceded as safer and better agent to inhibit growth of microbes. Therefore, selected Malaysia plants with medicinal properties are listed for further review in their antimicrobial activity and their major compound that act as antimicrobial agent. The major groups of the antimicrobial constituents are phenolics, phenolic acids, quinones, saponins, flavonoids, tannins, coumarins, terpenoids and alkaloids. These compounds are secondary metabolites that play the main role in plant defense mechanism. They also exhibited inhibitory effect on various microorganisms such as Staphylococcus aureus, Bacillus subtilis, Pseudomonas aeruginosa, Escherichia coli and Candida albicans . Compounds derived from Malaysian plants have the potential to be used as antimicrobial additive as most of their extracts containing active compounds such as caffeic acid, pyrogallol, catechin and curcumin. Extraction method of plants extract is done either by conventional method of maceration and extraction under reflux and steam distillation or modern method of microwave assisted extraction, supercritical fluid extraction and ultrasound-assisted solvent extraction. Even though plants extracts with medicinal properties are gaining fame for their antimicrobial properties, however the study on incorporation of the extracts into edible films as antimicrobial food packaging is limited. The advantages of using an edible film with antimicrobial agent plants for food products are it safe to use and it able to extend the shelf life while reducing packaging waste. Chemical Engineering Research Bulletin 19(2017) 57-66
马来西亚是世界上12个生物多样性丰富的国家之一,其中包括各种各样的植物,具有新的抗菌剂的潜在来源。尽管已经对多种植物进行了筛选,但从植物中提取的抗菌化合物作为更安全、更好的抑制微生物生长的药物,需要进行详细的研究。因此,精选的马来西亚药用植物被列出,以进一步审查其抗菌活性和它们的主要化合物,作为抗菌剂。抗菌成分的主要类群是酚类、酚酸类、醌类、皂苷类、黄酮类、单宁类、香豆素类、萜类和生物碱。这些化合物是次生代谢产物,在植物防御机制中起主要作用。对金黄色葡萄球菌、枯草芽孢杆菌、铜绿假单胞菌、大肠杆菌、白色念珠菌等多种微生物均有抑制作用。从马来西亚植物中提取的化合物具有用作抗菌添加剂的潜力,因为它们的大部分提取物含有咖啡酸、邻苯三酚、儿茶素和姜黄素等活性化合物。植物提取物的提取方法既有传统的回流浸渍提取法和蒸汽蒸馏法,也有现代的微波辅助提取法、超临界流体提取法和超声波辅助溶剂提取法。尽管具有药用价值的植物提取物因其抗菌特性而名声大噪,但将其纳入可食用薄膜作为抗菌食品包装的研究却很有限。使用含有抗菌剂植物的可食用薄膜用于食品的优点是使用安全,并且能够延长保质期,同时减少包装浪费。化工研究通报19(2017)57-66
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引用次数: 11
Application of homotopy perturbation method for MHD boundary layer flow of an upper-convected Maxwell fluid in a porous medium 同伦摄动法在多孔介质中上对流Maxwell流体MHD边界层流动中的应用
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26216
A. Jhankal
The magneto-hydrodynamics (MHD) boundary layer flow of an electrically conducting upper-convected Maxwell (UCM) fluid in porous medium is studied. The governing similarity equation is solved by He’s Homotopy perturbation method (HPM). The main advantage of HPM is that it does not require the small parameters in the equations and hence the limitations of traditional perturbation can be eliminated. The results reveal that the proposed method is very effective and simple and can be applied to other nonlinear problems. The effects of various physical parameters on the flow presented and discussed through graphs. Chemical Engineering Research Bulletin 18(2015) 12-17
研究了多孔介质中导电上对流麦克斯韦(UCM)流体的磁流体力学边界层流动。利用贺氏同伦摄动法(HPM)求解控制相似方程。HPM的主要优点是它不需要方程中的小参数,因此可以消除传统摄动的局限性。结果表明,该方法简单有效,可用于其它非线性问题的求解。通过图形给出并讨论了各种物理参数对流动的影响。化工研究通报18(2015)12-17
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引用次数: 5
Safe drinking water: effect of granular activated carbon bed characteristics on iron removal from water 安全饮用水:颗粒活性炭床特性对水中除铁的影响
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26214
G. Rasul, I. Ahmed, I. Hossain
Tuning the characteristics of granular activated carbon bed (GAC-bed) in household water-filters would be a technique to maintain iron at the required-level in drinking water. In the present study the individual effects of the depth of GAC-bed and the size and porosity of GAC particles on the iron removing capacity are investigated experimentally. A spectrophotometer is used to measure iron-content in water. It is observed that iron removing capacity increases monotonically with the increase in bed-depth regardless of the size of GAC particles. It is also observed that the iron removing capacity decreases drastically with the increase in the size of GAC particles for any fixed bed-depth. Finally the porosity of GAC particles is found to affect the iron removing capacity. The higher the GAC porosity the higher is the iron removing capacity over the considered porosity-range. It is believed that the observations of present study would be useful in adjusting GAC-bed characteristics at the time of designing household water-filters to maintain iron at the required-level. Chemical Engineering Research Bulletin 18(2015) 1-5
调整家用滤水器中颗粒活性炭床(gac床)的特性将是一种将饮用水中的铁维持在所需水平的技术。实验研究了活性炭床层深度、活性炭颗粒尺寸和孔隙率对除铁性能的影响。分光光度计用于测量水中的铁含量。结果表明,无论GAC颗粒大小如何,除铁能力均随层深的增加而单调增加。还观察到,在任何固定的床层深度下,随着GAC颗粒尺寸的增加,除铁能力急剧下降。最后发现GAC颗粒的孔隙率影响其除铁能力。GAC孔隙度越高,在考虑的孔隙度范围内除铁能力越高。相信本研究的观察结果将有助于在设计家用滤水器时调整gac床的特性,以使铁保持在所需的水平。化工研究通报18(2015)1-5
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引用次数: 4
On the relationship between surface tension and viscosity of fluids 论流体表面张力与粘度的关系
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26217
H. Ahmari, M. C. Amiri
Relating surface tension and viscosity of liquids not only is important conceptually but it can also be used to test the validity of some measured data. Schonhorn modified Pelofsky’s equation by introducing the concept of the vapor viscosity η v in equilibrium with the liquid, i.e.γ= Aexp(-B/(η l -η v )) This empirical relation can be applied to both organic and inorganic solutions of pure and mixed components. As surface tension is a strong function of surfactant, they neglected to emphasis that mixed components must not be surface active agents. Both Pelofsky and Schonhorn indicated that A may be an indication of the surface tension of the liquid at the temperature where η=∞. They were not successful in correlating the temperature where and the surface tension at the melting point. In this work, a new empirical equation for relating surface tension and viscosity has been developed, i.e., γ((Tc – Tm)/( Tc – T)) = δ(1-β/η). This equation not only satisfies the extreme conditions but it also reveals a physical concept for δ, that is, it should equal the surface tension at the melting point of the liquid. Chemical Engineering Research Bulletin 18(2015) 18-22
将液体的表面张力和粘度联系起来不仅在概念上很重要,而且可以用来检验一些测量数据的有效性。Schonhorn修正了Pelofsky方程,引入了与液体平衡时蒸气粘度η v的概念,即γ= Aexp(-B/(η l -η v))。这个经验关系式既适用于纯组分的有机溶液,也适用于混合组分的无机溶液。由于表面张力是表面活性剂的强大功能,他们忽略了强调混合组分不能是表面活性剂。Pelofsky和Schonhorn都指出,A可以表示η=∞时液体的表面张力。他们没有成功地把熔点的温度和表面张力联系起来。本文建立了一个新的表面张力与粘度关系的经验方程,即γ((Tc - Tm)/(Tc - T)) = δ(1-β/η)。该方程不仅满足极端条件,而且揭示了δ的物理概念,即δ应等于液体熔点处的表面张力。化工研究通报18(2015)18-22
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引用次数: 10
Regression model for fluid flow in a static mixer 静态混合器内流体流动的回归模型
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26218
R. Akila, K. Balu
A regression model for simulating residence time distribution (RTD) of turbulent flows in helical static mixers is proposed and developed to predict the residence time distribution in static mixers. An efficient method is required to estimate the RTD and the sole means of achieving this is through detailed regression model. The RTD was calculated numerically by regression model. The results of the regression model, i.e. predicted RTD is presented in terms of different volumetric flow rate to illustrate the complicated flow patterns that drive the mixing process in helical static mixers. The regression model is found to fit the experimental RTD with a high degree of correlation. Chemical Engineering Research Bulletin 18(2015) 23-29
提出并建立了一种模拟螺旋静态混合器内湍流停留时间分布的回归模型,用于预测静态混合器内的停留时间分布。需要一种有效的方法来估计RTD,而实现这一目标的唯一手段是通过详细的回归模型。采用回归模型对RTD进行数值计算。给出了不同体积流量下的回归模型结果,即预测RTD,以说明驱动螺旋静态混合器混合过程的复杂流型。回归模型与实验RTD具有较高的相关性。化工研究通报18(2015)23-29
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引用次数: 2
Bioremoval of toxic Molybdenum using dialysis tubing 透析管生物去除有毒钼的研究
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26215
M. S. Shukor, M. Shukor
The toxicity of molybdenum to ruminants and its general toxicity to spermatogenesis in animals are increasingly being reported. Its contamination of aquatic bodies has been reported, and this necessitates its removal. In this work, we utilize the dialysis tubing method coupled with the molybdenum-reducing activity of S. marcescens strain Dr.Y6 to remove molybdenum from solution. The enzymatic reduction of molybdenum into the colloidal molybdenum blue traps the reduced product in the dialysis tubing. The initial rate of increase of Mo-blue product was determined using the modified Gompertz model while the resultant inhibition kinetics profile was carried out using the Haldane model. The calculated maximal rate of Mo-blue production was 153 µmole (Mo-blue.hr) -1 and the concentration of molybdate resulting in the half-maximal rate of reduction ( K s ), and the inhibition constant ( K i ) were 0.22 and 506 mM, respectively. The results indicate that the system using dialysis tubing coupled with the Mo-reducing bacterium is a good candidate for a method for molybdenum bioremoval from solution. Chemical Engineering Research Bulletin 18(2015) 6-11
钼对反刍动物的毒性及其对动物精子发生的一般毒性越来越多地被报道。它对水生生物的污染已被报道,这就需要将其清除。本研究利用透析管法结合粘质葡萄球菌Dr.Y6的钼还原活性去除溶液中的钼。酶将钼还原到胶体钼蓝中,将还原产物困在透析管中。采用改进的Gompertz模型确定了Mo-blue产物的初始增加速率,并采用Haldane模型进行了抑制动力学分析。计算得到的Mo-blue最大生成速率为153µmol (Mo-blue.hr) -1,钼酸盐浓度导致的半最大还原速率(K s)和抑制常数(K i)分别为0.22和506 mM。结果表明,透析管与钼还原菌耦合的系统是一种很好的去除溶液中钼的方法。化工研究通报18(2015)6-11
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引用次数: 10
A legislative aspect of artificial fruit ripening in a developing country like Bangladesh 在孟加拉国这样的发展中国家,人工水果成熟的立法方面
Pub Date : 2016-01-04 DOI: 10.3329/CERB.V18I1.26219
N. Islam, Abul Hasnat Md Sazedur Rahman, Mehnaz Mursalat, A. Rony, M. Khan
Fruit ripening is a natural process in which a fruit goes through various physical and chemical changes and gradually becomes sweet, coloured, soft and palatable. However, this natural process can also be stimulated by using artificial fruit ripening agents. Farmers and vendors often use artificial ripening agents to control fruit ripening rate. However, because of the potential health hazard related to the ripening agents, artificial fruit ripening process is highly debateable throughout the world. There are existing laws and guidelines to control artificial fruit ripening process. This article deals with the legal aspects of artificial fruit ripening and fruit adulteration in Bangladesh. Different laws and acts to control and prohibit fruit ripening and adulteration using hazardous chemicals are discussed in detailed here. Laws from different developed and developing countries are also listed and discussed here. Furthermore, the technical and economic issues related to the artificial fruit ripening are addressed in this study. This article aims to develop awareness among different stakeholders since it will take the active participation of the government agencies, policymakers, farmers, vendors and scientists to address different aspects of artificial fruit ripening issues and to provide an effective solution. Chemical Engineering Research Bulletin 18(2015) 30-37
果实成熟是果实经过各种物理和化学变化,逐渐变甜、变色、变软、变美味的自然过程。然而,这种自然过程也可以通过使用人工水果催熟剂来刺激。农民和摊贩经常使用人工催熟剂来控制水果的成熟速度。然而,由于催熟剂对健康的潜在危害,人工水果催熟过程在世界范围内存在很大争议。目前已有法律和指导方针来控制人工水果成熟过程。本文涉及孟加拉国人工水果成熟和水果掺假的法律方面。这里详细讨论了控制和禁止使用有害化学品的水果成熟和掺假的不同法律和法案。这里还列出了不同发达国家和发展中国家的法律,并进行了讨论。此外,本文还对人工果实成熟的技术经济问题进行了探讨。本文旨在提高不同利益相关者的意识,因为它需要政府机构、决策者、农民、供应商和科学家的积极参与,以解决人工水果成熟问题的不同方面,并提供有效的解决方案。化工研究通报18(2015)30-37
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引用次数: 15
Prediction of uranium concentration profiles along a continuous extraction column 沿连续萃取柱的铀浓度曲线预测
Pub Date : 2015-04-07 DOI: 10.3329/CERB.V17I1.22916
N. Khleifia, H. Rania, A. Hannachi
The increased growth in energy demand has a direct impact on the growing interest of uranium extraction. Phosphoric acid attracts a great attention because of its uranium content. The solvent extraction is the most widely used techniques for uranium separation from phosphoric acid. In the present work, the simulation of the uranium extraction along a continuous counter current column has been conducted. A computer code that accounts for mass balances and equilibrium data has been developed. The performed simulations allow to obtain the concentration profiles of uranium along the extraction column and led to assess the effect of operating conditions on the extraction performances. DOI: http://dx.doi.org/10.3329/cerb.v17i1.22916 Chemical Engineering Research Bulletin 17(2015) 34-39
能源需求的增长对铀矿开采的兴趣日益增长有直接影响。磷酸因其含铀量而备受关注。溶剂萃取法是目前应用最广泛的磷酸铀分离技术。本文对连续逆流柱提铀过程进行了模拟。一种计算质量平衡和平衡数据的计算机代码已经开发出来。模拟得到了铀在萃取柱上的浓度分布,并对不同操作条件对萃取性能的影响进行了评价。DOI: http://dx.doi.org/10.3329/cerb.v17i1.22916化学工程研究通报17(2015)34-39
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引用次数: 0
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Chemical Engineering Research Bulletin
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