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Evaluation of PVA/dextran/chitosan hydrogel for wound dressing PVA/葡聚糖/壳聚糖水凝胶用于伤口敷料的评价
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2019-04-08 DOI: 10.1177/0262489319839211
Shin-Ping Lin, Kai-Yin Lo, Tien-Ni Tseng, Jui-Ming Liu, Ting-Yu Shih, Kuan-Chen Cheng
Developing a multiple functional wound dressing suitable for different stages of wound healing is important for patients with special wound such as burn or decubital ulcers. In this study, poly (vinyl alcohol) (PVA), dextran, and chitosan are integrated to produce ideal wound dressing where glutaraldehyde (GA) is used as the cross-linker. The result demonstrated that 6% PVA hydrogel with 0.25% chitosan was found to provide antimicrobial ability. The PVA/chitosan hydrogel combined with 4% dextran utilizing GA cross-linking also presents the high cell proliferation ability, which suggests that the hydrogel is potential as a wound dressing. In the following physical analyses, the addition of chitosan and dextran appeared to promote the thermostability, mechanical properties, water retention, and moisturizing ability in the PVA hydrogel. In conclusion, the PVA/chitosan/dextran hydrogel has promising potential such as high water content, antimicrobial property, and well cell proliferation, which can be applied to wound healing application.
开发一种适用于不同伤口愈合阶段的多功能伤口敷料,对于烧伤或褥疮等特殊伤口的患者来说很重要。在本研究中,聚乙烯醇(PVA)、右旋糖酐和壳聚糖被整合在一起,以戊二醛(GA)作为交联剂,生产出理想的伤口敷料。结果表明,6%的PVA水凝胶和0.25%的壳聚糖具有抗菌能力。利用GA交联的PVA/壳聚糖水凝胶与4%右旋糖酐结合也表现出高的细胞增殖能力,这表明该水凝胶具有作为伤口敷料的潜力。在以下物理分析中,壳聚糖和葡聚糖的添加似乎提高了PVA水凝胶的热稳定性、机械性能、保水性和保湿能力。总之,PVA/壳聚糖/葡聚糖水凝胶具有高含水量、抗菌性能和良好的细胞增殖等优点,可应用于伤口愈合。
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引用次数: 33
Density graded polyethylene foams: Effect of processing conditions on mechanical properties 密度梯度聚乙烯泡沫:加工条件对机械性能的影响
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2019-03-31 DOI: 10.1177/0262489319839632
E. Cusson, A. Akbarzadeh, D. Therriault, D. Rodrigue
Uniform foams (UF) and density graded foams (DGF) were produced by using similar or different temperatures on both sides of a compression molding system. The samples were produced using linear low density polyethylene as the matrix and activated azodicarbonamide as the chemical blowing agent. Morphological properties of the produced samples were analyzed via scanning electron microscopy to relate them to their mechanical properties. In particular, flexural and impact properties are reported for samples produced under a range of temperatures (140–200°C) and blowing agent concentration (0.7–1.0 wt%). The experimental results showed that a significant difference can be obtained in flexural modulus (up to 17%) and impact strength (up to 48%) depending on the side the stress is applied on. In all cases, the DGF showed better mechanical responses than UF of similar relative density for the range of conditions tested.
均匀泡沫(UF)和密度梯度泡沫(DGF)是通过在压缩成型系统的两侧使用相似或不同的温度生产的。以线性低密度聚乙烯为基体,偶氮二甲酰胺为化学发泡剂制备样品。通过扫描电镜分析了所生产样品的形态特征,并将其与力学性能联系起来。特别是,报告了在温度(140-200°C)和发泡剂浓度(0.7-1.0 wt%)范围内生产的样品的弯曲和冲击性能。实验结果表明,根据施加应力的侧面不同,可以获得显著的弯曲模量(高达17%)和冲击强度(高达48%)差异。在所有情况下,在测试的条件范围内,DGF表现出比相对密度相似的UF更好的力学响应。
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引用次数: 7
The effect on the surface activity and the structure of SPI caused by cleavage of disulfide bonds and by subsequent glucose modification 二硫键断裂和随后的葡萄糖修饰对SPI表面活性和结构的影响
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2019-01-01 DOI: 10.1177/0262489319843645
Fan Junfu, L. Junsheng, Wang Bixuan, Zhong Xin, Huang Guo-xia, Yan Liujuan, Ren Xiane
The main purpose of this study was to investigate the effects on the molecular structure and the properties of soybean proteins isolate (SPI) after two modifications: (1) peracetic acid oxidative cleavage of its disulfide bonds and (2) the subsequent addition of covalently bonded glucose to the SPI containing the cleaved disulfide bonds. An appropriate amount of peracetic acid will be capable of enhancing the surface properties of SPI significantly; however, excessive oxidation can obtain undesirable results. When the concentration of peracetic acid was 0.4%, following by 35.5% of the disulfide bond cleavage, compared with those of natural SPI, the foaming capacity (FC), foaming stability (FS), emulsifying capacity (EC), and emulsifying stability (ES) of oxidized-SPI were increased by 82.0%, 65.8%, 58.5%, and 41.5%, respectively. The surface activity of oxidized-SPI could be promoted by glucose modification, and the FC, FS, EC, and ES of oxidized-SPI have further risen to 146.8%, 96.0%, 131.4%, and 40.3%, respectively, after the further glucose modification. Particle size measurements showed bimodality for the SPI that was modified with glucose with a portion of smaller sizes seen. Fluorescence spectroscopy and circular dichroism measurements demonstrate that extensibility increases; flexibility is enhanced; and glycosylation occurs more readily due to the oxidation of SPI. When grafted with glucose, these oxidized soybean protein products produce more ideal foaming and display better emulsification properties.
本研究的主要目的是研究两种修饰对大豆分离蛋白(SPI)分子结构和性能的影响:(1)过氧乙酸氧化裂解其二硫键,(2)随后在含有裂解二硫键的SPI上加入共价键的葡萄糖。适量的过氧乙酸能显著提高SPI的表面性能;然而,过度氧化会产生不良后果。当过氧乙酸浓度为0.4%,二硫键裂解率为35.5%时,与天然SPI相比,氧化SPI的发泡能力(FC)、发泡稳定性(FS)、乳化能力(EC)和乳化稳定性(ES)分别提高了82.0%、65.8%、58.5%和41.5%。葡萄糖修饰可提高氧化- spi的表面活性,经葡萄糖修饰后,其FC、FS、EC和ES分别提高到146.8%、96.0%、131.4%和40.3%。粒径测量结果显示,用葡萄糖修饰的SPI具有双峰性,其中看到了较小尺寸的部分。荧光光谱和圆二色性测量表明,可扩展性增加;灵活性增强;由于SPI的氧化,糖基化更容易发生。与葡萄糖接枝后,这些氧化大豆蛋白制品产生更理想的泡沫,并表现出更好的乳化性能。
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引用次数: 0
Applications of Core Retraction in Manufacturing Low-Density Polypropylene Foams with Microcellular Injection Molding 缩芯技术在微孔注射成型制造低密度聚丙烯泡沫塑料中的应用
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700101
H. Kharbas, Thomas Ellingham, L. Turng
Without modifying existing part and mold designs, the conventional microcellular injection molding (MIM) process can typically save about 5–10% material without encountering problems such as incomplete filling, excessive shrinkage, or deteriorating microstructure and mechanical properties. In this study core retraction was used in combination with the MIM process to produce thick polypropylene (PP) parts (up to 7.6 mm thick) with high density reductions of 30% and 55%. The cavity volume was modified by changing the retraction distance, which enabled control of density reductions. The lowest densities were achieved with this core retraction-aided microcellular injection molding (CR-MIM) process, the results of which could not have been achieved by the conventional MIM process alone. The effects of delay time in core retraction and weight reduction on the microstructure of the core and skin layers were investigated. It was shown that the CR-MIM process yielded better microstructure and tensile properties than the conventional MIM process. Use of core retraction also yielded more consistent densities and tensile properties throughout the length of the foamed parts.
在不修改现有零件和模具设计的情况下,传统的微孔注射成型(MIM)工艺通常可以节省约5-10%的材料,而不会遇到填充不完全、过度收缩或微观结构和机械性能恶化等问题。在这项研究中,芯收缩与MIM工艺相结合,生产厚聚丙烯(PP)零件(厚达7.6 mm),高密度降低30%和55%。通过改变回缩距离来改变腔体体积,从而可以控制密度的降低。最低的密度是通过这种芯收缩辅助微细胞注射成型(CR-MIM)工艺实现的,其结果无法通过传统的MIM工艺单独实现。研究了缩芯延迟时间和减重对芯层和蒙皮层微观结构的影响。结果表明,CR-MIM工艺比传统的MIM工艺具有更好的组织和拉伸性能。使用芯收缩也产生了更一致的密度和拉伸性能在整个泡沫部件的长度。
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引用次数: 1
Effect of Recycling on the Cellular Structure of Polylactide in a Batch Process 间歇过程中回收对聚乳酸细胞结构的影响
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700202
Joanna Ludwiczak, S. Frąckowiak, Rafał Łużny
The aim of the work is to demonstrate the possibility of using recycled biodegradable material as a cellular material with a reduced weight. An experimental study on the influence of recycling on the properties and foam ability of polylactide (PLA) was carried out. The influence of recycling on the polymer crystallinity, thermal and viscoelastic properties was investigated. During the batch process the cellular structure in PLA and recycled PLA were created. A higher degree of crystallinity, a lower viscosity value and a lower melt strength for recycled PLA, as compared to original material, were observed. For the recycled PLA, a fine cellular structure and low density (0.60 g/cm3) were obtained.
这项工作的目的是证明使用可回收的可生物降解材料作为减轻重量的细胞材料的可能性。对循环利用对聚乳酸(PLA)性能和泡沫性能的影响进行了实验研究。研究了循环利用对聚合物结晶度、热性能和粘弹性的影响。在批处理过程中,形成了聚乳酸和再生聚乳酸的胞状结构。与原始材料相比,观察到更高的结晶度,更低的粘度值和更低的熔融强度。对于回收PLA,获得了精细的细胞结构和低密度(0.60 g/cm3)。
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引用次数: 4
Cellular Morphology Optimization of Polypropylene/CaCO3 Composite Films Designed for Piezoelectric Applications 压电型聚丙烯/CaCO3复合薄膜的细胞形态优化
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700301
Eric Audet, F. Mighri, D. Rodrigue, A. Ajji
In this work, the cellular morphology of polypropylene (PP)/calcium carbonate (CaCO3) composite films was optimized with respect to piezoelectric cellular films criteria. To do this, a series of PP films filled with CaCO3 micro-particles of three different particle sizes (3, 6 and 12 microns) were developed at various weight concentrations (3 to 44 wt. %). Before going through a gas diffusion expansion (GDE) step to inflate the initiated cells, all composite films were first produced via extrusion/calendaring then biaxially stretched to initiate the cellular structure by interfacial delamination between the CaCO3 particles and PP matrix. After biaxial stretching and GDE, it was observed that only films with filler contents above 23 wt.% and 12 μm particle size presented a well-developed cellular structure. By optimizing the extrusion, biaxial stretching and GDE steps, we were able to generate a required cellular morphology where the average cell height ranged between 5 and 8 μm, which is considered good for further Corona charging. Also, the average cell aspect ratio (cell length divided by cell height) ranged between 4 and 10 with an average cell wall thickness between 7 and 12 μm, which is also considered as optimum for good piezoelectric properties.
在这项工作中,聚丙烯(PP)/碳酸钙(CaCO3)复合膜的细胞形态根据压电细胞膜的标准进行了优化。为了做到这一点,在不同的重量浓度(3至44 wt. %)下,开发了一系列充满三种不同粒径(3、6和12微米)的CaCO3微粒的PP薄膜。在通过气体扩散膨胀(GDE)步骤膨胀初始细胞之前,所有复合膜首先通过挤压/压延生产,然后通过CaCO3颗粒和PP基体之间的界面分层进行双轴拉伸,以初始化细胞结构。经过双向拉伸和GDE后,发现只有填料含量大于23 wt.%、粒径大于12 μm的薄膜才呈现出发育良好的细胞结构。通过优化挤压、双轴拉伸和GDE步骤,我们能够生成所需的电池形态,电池的平均高度在5到8 μm之间,这被认为有利于进一步的电晕充电。此外,电池的平均宽高比(电池长度除以电池高度)在4到10之间,平均壁厚在7到12 μm之间,这也被认为是良好压电性能的最佳选择。
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引用次数: 5
Compression Properties of Syntactic Foam Reinforced by Warp-knitted Spacer Fabric: Theoretical Compression Strength Model and Experimental Verification 经编间隔织物增强复合泡沫的压缩性能:理论压缩强度模型与实验验证
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700102
Chao Zhi, Guoqing Zhu, J. Meng, Jinhua Jiang, H. Long, Lingjie Yu
In this study, a theoretical model based on the fiber buckling theory was established to predict the compression strength of a new type of syntactic foam, namely the syntactic foam reinforced by the warp-knitted spacer fabric (SF-WKSF). In order to verify the availability of this model, compression strength values of theoretical simulations were compared with the experiment results. The comparison results showed that the model can accurately simulate the compression strength values of different SF-WKSF samples with slight deviation. Finally, the causes of deviation was analyzed in detail.
本文基于纤维屈曲理论,建立了一种新型复合泡沫材料——经编间隔织物增强复合泡沫材料(SF-WKSF)的抗压强度预测理论模型。为了验证该模型的有效性,将理论模拟得到的抗压强度值与实验结果进行了比较。对比结果表明,该模型能较准确地模拟不同SF-WKSF试样的抗压强度值,偏差较小。最后,详细分析了产生偏差的原因。
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引用次数: 5
Rotomolding of Foamed and Unfoamed GTR-LLDPE Blends: Mechanical, Morphological and Physical Properties 发泡和未发泡GTR-LLDPE共混物的旋转成型:机械、形态和物理性能
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700201
Y. Dou, D. Rodrigue
In this work, a simple method is presented to produce ground tire rubber (GTR) -linear low density polyethylene (LLDPE) compounds and foams via rotational molding. In particular, different GTR concentrations (0 to 50% wt.) were dry-blended with different chemical blowing agent (CBA) content (0 to 1% wt.). From the samples produced, a complete set of characterization was performed in terms of mechanical properties (tensile, flexural and impact), density and morphological properties. The results show that increasing GTR content or CBA content not only decreased both tensile and flexural moduli, but decreased ultimate strength and strain at break. As expected, increasing blowing agent content decreased density. Besides, with respect to impact strength, the value of all samples decreased with the addition of GTR or CBA except for 0.2% wt. CBA of GTR-LLDPE composite foams, which nearly remain at the same level.
本文提出了一种通过旋转成型生产研磨轮胎橡胶(GTR)-线性低密度聚乙烯(LLDPE)化合物和泡沫的简单方法。特别是,将不同GTR浓度(0至50%重量)与不同化学发泡剂(CBA)含量(0至1%重量)进行干混。从生产的样品中,对机械性能(拉伸、弯曲和冲击)、密度和形态性能进行了一整套表征。结果表明,GTR或CBA含量的增加不仅降低了拉伸模量和弯曲模量,而且降低了极限强度和断裂应变。正如预期的那样,发泡剂含量的增加降低了密度。此外,就冲击强度而言,除了0.2%wt.CBA的GTR-LLDPE复合泡沫外,所有样品的值都随着GTR或CBA的加入而降低,它们几乎保持在相同的水平。
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引用次数: 14
Multi-Stage Recycling Induced Morphological Transformations in Solid-State Microcellular Foaming of Polystyrene 多级回收诱导聚苯乙烯固态微孔发泡的形态转变
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-09-04 DOI: 10.1177/026248931803700302
Indrajeet Singh, A. Gandhi, M. Biswal, S. Mohanty, S. K. Nayak
In this article, the general-purpose polystyrene was reprocessed four times. The effect of repeated reprocessing of polystyrene on its polymeric properties and on its microcellular, foaming behaviour were investigated. It was observed that reprocessing leads to break of long polymeric chains into short chains, which resulted increment in PDI and MFI. Molecular weight and Glass transition temperature were found to decrease with increasing recycling stages. Reprocessing resulted abruptly decrement in viscosity of neat polystyrene. Effect of reprocessing on foaming behaviour was analysed properly in this report and it was found that reprocessing resulted in improvement in cell sizes and their distribution. A positive effect on expansion ratio was also observed during foaming of reprocessed specimens. Cell density was found to decrease with increasing recycling stages. The effect of saturation pressure and foaming temperature on microcellular foam morphology along with recycling were investigated. Effect of foaming time on cell size, cell size distribution, cell density, expansion ratio and cell wall thickness was investigated.
本文对通用聚苯乙烯进行了四次再加工。研究了聚苯乙烯重复后处理对其聚合物性能和微孔发泡行为的影响。据观察,后处理导致长聚合物链断裂为短链,从而导致PDI和MFI增加。发现分子量和玻璃化转变温度随着再循环阶段的增加而降低。后处理导致纯聚苯乙烯的粘度急剧下降。本报告对后处理对发泡行为的影响进行了适当分析,发现后处理改善了泡孔尺寸及其分布。在再加工试样的发泡过程中,也观察到对膨胀率的积极影响。发现细胞密度随着回收阶段的增加而降低。研究了饱和压力和发泡温度对微孔泡沫形态的影响以及回收利用情况。研究了发泡时间对泡孔尺寸、泡孔尺寸分布、泡孔密度、膨胀率和泡孔壁厚度的影响。
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引用次数: 11
The new method of manufacturing porous castings from styrene–acrylic dispersion 介绍了用苯乙烯-丙烯酸分散体制备多孔铸件的新方法
IF 1.6 4区 医学 Q3 Materials Science Pub Date : 2018-07-01 DOI: 10.1177/0262489318797513
Paweł Palutkiewicz
This work presents an innovative method for producing porous castings from polymer dispersion with wood flour. The method described for forming porous castings from blends, in which the aqueous dispersions of polymers are binders, enables the manufacturing of wood-like products with a cork-like structure. The casting technology and selected properties of finished castings (density, compression strength) are presented. The structurual investigations of the obtained castings are also presented.
本研究提出了一种用木粉聚合物分散体生产多孔铸件的创新方法。所描述的用于从混合物中形成多孔铸件的方法,其中聚合物的水分散体是粘合剂,使制造具有软木状结构的类木产品成为可能。介绍了铸造工艺及成品铸件的主要性能(密度、抗压强度)。对所获得的铸件进行了组织研究。
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引用次数: 0
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Cellular Polymers
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