Pub Date : 2020-04-23DOI: 10.1177/0262489320920070
J. Werner, Lukas Vetter, Sebastian Hertle, M. Wolf, D. Drummer
In recent years, foams have experienced a major economic uprise, not least due to their lightweight construction potential. In this article, a new process variation is presented, which enables the generation of foamed structures in rotational molding by the utilization of vacuum. The novel method is based on entrapped air in the melt as an intrinsic physical blowing agent. By applying negative pressure in the cooling or solidification phase, the air bubbles expand. The crystallization freezes the existing conditions and thus forms the foamed structure. The investigations presented consider influences by different pressures as well as the temperature at which the vacuum is applied. The results with polyethylene show that by varying the pressure as well as the application temperature of the vacuum, components with different densities and cell characteristics result. The resulting foamed components excel by an improved stiffness per unit weight ratio.
{"title":"Air inclusions in the polymer melt functioning as intrinsic physical blowing agents for the generation of foams in rotational molding","authors":"J. Werner, Lukas Vetter, Sebastian Hertle, M. Wolf, D. Drummer","doi":"10.1177/0262489320920070","DOIUrl":"https://doi.org/10.1177/0262489320920070","url":null,"abstract":"In recent years, foams have experienced a major economic uprise, not least due to their lightweight construction potential. In this article, a new process variation is presented, which enables the generation of foamed structures in rotational molding by the utilization of vacuum. The novel method is based on entrapped air in the melt as an intrinsic physical blowing agent. By applying negative pressure in the cooling or solidification phase, the air bubbles expand. The crystallization freezes the existing conditions and thus forms the foamed structure. The investigations presented consider influences by different pressures as well as the temperature at which the vacuum is applied. The results with polyethylene show that by varying the pressure as well as the application temperature of the vacuum, components with different densities and cell characteristics result. The resulting foamed components excel by an improved stiffness per unit weight ratio.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"40 1","pages":"3 - 19"},"PeriodicalIF":1.6,"publicationDate":"2020-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320920070","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48016026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-04-22DOI: 10.1177/0262489320919952
Can Jiang, Shuo Han, Shihong Chen, Hongfu Zhou, Xiangdong Wang
The microcellular foaming of chain-extended polyethylene terephthalate (CPET) by crystallization induction method was reported in this article. The crystallization behaviors of various polyethylene terephthalate (PET) samples which were affected by the combined effect of pyromellitic dianhydride, Surlyn, and CO2 were investigated. After Surlyn was added to CPET, the crystal nucleation of various CPET samples was improved, and numerous but small spherulites were generated. Two kinds of CPET samples with the content of 0 phr and 1 phr Surlyn were foamed at various temperature by batch foaming method. Changing the saturation temperature could adjust the appearance of high-temperature melting crystals which would affect the final cellular structures in various CPET foams. With the decrease of saturation temperature, the cell size decreased while cell density increased. At the saturation temperature of 265°C and 250°C, the cell density of CPET foam with Surlyn was one magnitude larger than CPET foam without Surlyn. At the saturation temperature of 247°C, the microcellular PET foams with the cell density of 109 cells cm−3 and the cell size less than 10 µm had been developed successfully.
{"title":"Crystallization-induced microcellular foaming behaviors of chain-extended polyethylene terephthalate","authors":"Can Jiang, Shuo Han, Shihong Chen, Hongfu Zhou, Xiangdong Wang","doi":"10.1177/0262489320919952","DOIUrl":"https://doi.org/10.1177/0262489320919952","url":null,"abstract":"The microcellular foaming of chain-extended polyethylene terephthalate (CPET) by crystallization induction method was reported in this article. The crystallization behaviors of various polyethylene terephthalate (PET) samples which were affected by the combined effect of pyromellitic dianhydride, Surlyn, and CO2 were investigated. After Surlyn was added to CPET, the crystal nucleation of various CPET samples was improved, and numerous but small spherulites were generated. Two kinds of CPET samples with the content of 0 phr and 1 phr Surlyn were foamed at various temperature by batch foaming method. Changing the saturation temperature could adjust the appearance of high-temperature melting crystals which would affect the final cellular structures in various CPET foams. With the decrease of saturation temperature, the cell size decreased while cell density increased. At the saturation temperature of 265°C and 250°C, the cell density of CPET foam with Surlyn was one magnitude larger than CPET foam without Surlyn. At the saturation temperature of 247°C, the microcellular PET foams with the cell density of 109 cells cm−3 and the cell size less than 10 µm had been developed successfully.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"223 - 237"},"PeriodicalIF":1.6,"publicationDate":"2020-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320919952","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48395636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-03-30DOI: 10.1177/0262489320912357
Fatemeh Farhanmoghaddam, A. Javadi
In this article, poly (lactic acid) (PLA) was foamed via batch foaming using supercritical nitrogen as a physical blowing agent by two methods, conventional foaming process (CFP) and low-temperature foaming process (LTFP). The fabrication processes, cell morphologies, thermal properties, crystallization behavior, and electrical resistance of resulted foams were studied to investigate the effect of foaming on these properties of PLA. It was found that the foams resulted from CFP method have micrometric cell sizes, while LTFP method led to nanometric cell structure and high cell density. Also scanning electron microscopy showed that the PLA foams have a heterogeneous cellular structure. The results showed that the foaming process increased the melting point and degree of crystallinity of PLA, which led to decrease in the electrical resistance of samples.
{"title":"Fabrication of poly (lactic acid) foams using supercritical nitrogen","authors":"Fatemeh Farhanmoghaddam, A. Javadi","doi":"10.1177/0262489320912357","DOIUrl":"https://doi.org/10.1177/0262489320912357","url":null,"abstract":"In this article, poly (lactic acid) (PLA) was foamed via batch foaming using supercritical nitrogen as a physical blowing agent by two methods, conventional foaming process (CFP) and low-temperature foaming process (LTFP). The fabrication processes, cell morphologies, thermal properties, crystallization behavior, and electrical resistance of resulted foams were studied to investigate the effect of foaming on these properties of PLA. It was found that the foams resulted from CFP method have micrometric cell sizes, while LTFP method led to nanometric cell structure and high cell density. Also scanning electron microscopy showed that the PLA foams have a heterogeneous cellular structure. The results showed that the foaming process increased the melting point and degree of crystallinity of PLA, which led to decrease in the electrical resistance of samples.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"172 - 182"},"PeriodicalIF":1.6,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320912357","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46085619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-03-19DOI: 10.1177/0262489320912521
Wei Liu, Xunxian Zhu, Hongxiang Gao, Xiangdong Su, Xian Wu
Improving foamability of poly (lactic acid) (PLA) resin is a key issue for its critical foaming applications with high-performance and ultralow density. However, owing to the rheological nature of linear PLA chain structure with relatively low molecular weight, the overall foamability of PLA resin cannot meet the processing requirements of foaming purpose. Here, we describe a simple and versatile technique to prepare high foamability PLA resin by inducing chain extender through grafting octa(epoxycyclohexyl) polyhedral oligomeric silsesquioxanes (POSS) on carbon nanotubes (CNT). After the orderly assemble of the two nanoparticles, an obvious increase in melt elasticity of PLA is observed. The enhanced melt elasticity of PLA had a significant effect on controlling subsequent foaming behavior. Thus, a homogeneous and finer cellular morphology of PLA rigid foam was obtained with a proper content of CNT-POSS. Eventually, the expansion ratio of chain-extended PLA foam was 13 times higher than that of unmodified PLA foam. The proposed design methodology will potentially pave a way for designing and preparing high-performance PLA rigid foam products.
{"title":"Preparation and characterization of PLA foam chain extended through grafting octa(epoxycyclohexyl) POSS onto carbon nanotubes","authors":"Wei Liu, Xunxian Zhu, Hongxiang Gao, Xiangdong Su, Xian Wu","doi":"10.1177/0262489320912521","DOIUrl":"https://doi.org/10.1177/0262489320912521","url":null,"abstract":"Improving foamability of poly (lactic acid) (PLA) resin is a key issue for its critical foaming applications with high-performance and ultralow density. However, owing to the rheological nature of linear PLA chain structure with relatively low molecular weight, the overall foamability of PLA resin cannot meet the processing requirements of foaming purpose. Here, we describe a simple and versatile technique to prepare high foamability PLA resin by inducing chain extender through grafting octa(epoxycyclohexyl) polyhedral oligomeric silsesquioxanes (POSS) on carbon nanotubes (CNT). After the orderly assemble of the two nanoparticles, an obvious increase in melt elasticity of PLA is observed. The enhanced melt elasticity of PLA had a significant effect on controlling subsequent foaming behavior. Thus, a homogeneous and finer cellular morphology of PLA rigid foam was obtained with a proper content of CNT-POSS. Eventually, the expansion ratio of chain-extended PLA foam was 13 times higher than that of unmodified PLA foam. The proposed design methodology will potentially pave a way for designing and preparing high-performance PLA rigid foam products.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"117 - 138"},"PeriodicalIF":1.6,"publicationDate":"2020-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489320912521","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43366590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-03-01DOI: 10.1177/0262489319890201
S. Kudori, H. Ismail
The effects of filler loading and size of kenaf fibre on the mechanical properties of kenaf fibre-filled natural rubber latex foam (NRLF) have been studied. The NRLF was prepared by using the Dunlop method. The kenaf fibre was sieved to 97, 144 and 200 µm particle sizes and incorporated into the rubber vulcanizates at 0, 1, 3, 5 and 7 part per hundred rubber fibre contents. Increasing kenaf fibre loading in NRLF resulted in the reduction of tensile strength, elongation at break and recovery percentage but increased in modulus at 100% (M100), compression strength, compression set, hardness and foam density. At the same kenaf fibre loading, smaller size of kenaf fibre-filled NRLF showed higher tensile properties, compression strength, compression set and hardness. Scanning electron microscope demonstrated that as kenaf fibre loading and size increased, a larger pore size of NRLF was formed and this led to tensile strength, M100, compression strength and hardness.
{"title":"The effects of filler contents and particle sizes on properties of green kenaf-filled natural rubber latex foam","authors":"S. Kudori, H. Ismail","doi":"10.1177/0262489319890201","DOIUrl":"https://doi.org/10.1177/0262489319890201","url":null,"abstract":"The effects of filler loading and size of kenaf fibre on the mechanical properties of kenaf fibre-filled natural rubber latex foam (NRLF) have been studied. The NRLF was prepared by using the Dunlop method. The kenaf fibre was sieved to 97, 144 and 200 µm particle sizes and incorporated into the rubber vulcanizates at 0, 1, 3, 5 and 7 part per hundred rubber fibre contents. Increasing kenaf fibre loading in NRLF resulted in the reduction of tensile strength, elongation at break and recovery percentage but increased in modulus at 100% (M100), compression strength, compression set, hardness and foam density. At the same kenaf fibre loading, smaller size of kenaf fibre-filled NRLF showed higher tensile properties, compression strength, compression set and hardness. Scanning electron microscope demonstrated that as kenaf fibre loading and size increased, a larger pore size of NRLF was formed and this led to tensile strength, M100, compression strength and hardness.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"57 - 68"},"PeriodicalIF":1.6,"publicationDate":"2020-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319890201","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42263837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Supercritical fluids have been widely used to prepare various polymer nanocomposite foams due to their high-efficiency, rich-resource, and environment-friendly characteristics. In this work, we prepared polystyrene (PS) nanocomposites with different contents of hybrid fillers of nanoclay and nano-calcium carbonate (nano-CaCO3) and then were foamed by batch foaming method using supercritical carbon dioxide as a physical blowing agent. The effect of hybrid nanofillers components and foaming temperature and pressure on the foaming properties and cellular structure of PS nanocomposite foams was systematically investigated. Dynamic rheology results indicated that the complex viscosity and storage modulus were enhanced with the addition of hybrid fillers. Scanning electron microscopic images show that all samples foamed uniformly macrocells under the given conditions. More importantly, the hybrid fillers of nano-CaCO3 and nanoclay exhibit a significant synergistic effect in improving PS foaming properties, which can be ascribed to the different roles of the two fillers during cell nucleation and cell growth. For instance, the PS/0.22/0.88 nanocomposite foamed under the conditions of 20 MPa and 130°C has shown the finest cell structure (higher cell density of 1.91 × 1010 and smaller cell diameter of 2.28 µm) due to the coeffect of the hybrid nanofillers. Finally, the synergistic mechanism of these two nanofillers on PS foaming behavior was discussed.
{"title":"Synergetic effect of nanoclay and nano-CaCO3 hybrid filler systems on the foaming properties and cellular structure of polystyrene nanocomposite foams using supercritical CO2","authors":"Xinghan Lian, Wenjie Mou, Tairong Kuang, Xianhu Liu, Shuidong Zhang, Fangfang Li, Tongxun Liu, Xiangfang Peng","doi":"10.1177/0262489319900948","DOIUrl":"https://doi.org/10.1177/0262489319900948","url":null,"abstract":"Supercritical fluids have been widely used to prepare various polymer nanocomposite foams due to their high-efficiency, rich-resource, and environment-friendly characteristics. In this work, we prepared polystyrene (PS) nanocomposites with different contents of hybrid fillers of nanoclay and nano-calcium carbonate (nano-CaCO3) and then were foamed by batch foaming method using supercritical carbon dioxide as a physical blowing agent. The effect of hybrid nanofillers components and foaming temperature and pressure on the foaming properties and cellular structure of PS nanocomposite foams was systematically investigated. Dynamic rheology results indicated that the complex viscosity and storage modulus were enhanced with the addition of hybrid fillers. Scanning electron microscopic images show that all samples foamed uniformly macrocells under the given conditions. More importantly, the hybrid fillers of nano-CaCO3 and nanoclay exhibit a significant synergistic effect in improving PS foaming properties, which can be ascribed to the different roles of the two fillers during cell nucleation and cell growth. For instance, the PS/0.22/0.88 nanocomposite foamed under the conditions of 20 MPa and 130°C has shown the finest cell structure (higher cell density of 1.91 × 1010 and smaller cell diameter of 2.28 µm) due to the coeffect of the hybrid nanofillers. Finally, the synergistic mechanism of these two nanofillers on PS foaming behavior was discussed.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"185 - 202"},"PeriodicalIF":1.6,"publicationDate":"2020-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319900948","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47098875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-07DOI: 10.1177/0262489319897632
J. Solorza-Feria, M. A. Ortiz-Zarama, A. Jiménez–Aparicio, D. Rodrigue
The objective of this study was to produce and characterize gelatin foamed films using extrusion. Three “optimum” formulations containing tannic acid, nanoclays (Cloisite Na+), glycerol, water, and gelatin, as well as three “controls” without tannic acid and nanoclays were prepared by calendering. Furthermore, the three “optimum” formulations were produced by extrusion film blowing only, since no stable processing conditions could be obtained for the controls. A complete set of sample characterization was performed, including morphological, mechanical, physical, and thermal properties. The results showed that besides the processing method, the thickness was also controlled by the glycerol and water content, leading to density slightly above unity, with higher values for the optimum materials. The calendered films from the optimum formulations showed overall a higher number of cells and cell density than the controls. Higher elastic moduli and tensile strengths were obtained for the films from the optimum formulations made by either method because of the reinforcing effect of the tannic acid and nanoclays, but this led to lower strain at break. The thermal profiles were similar for all films, with higher stability for the optimum formulations. The results were also explained via chemical interactions between the components as observed by Fourier transform infrared spectroscopy. Overall, the optimum formulations not only produced better foamed films in terms of general properties but were much easier to process by both methods (calendering and blowing).
{"title":"Production and characterization of fully biobased foamed films based on gelatin","authors":"J. Solorza-Feria, M. A. Ortiz-Zarama, A. Jiménez–Aparicio, D. Rodrigue","doi":"10.1177/0262489319897632","DOIUrl":"https://doi.org/10.1177/0262489319897632","url":null,"abstract":"The objective of this study was to produce and characterize gelatin foamed films using extrusion. Three “optimum” formulations containing tannic acid, nanoclays (Cloisite Na+), glycerol, water, and gelatin, as well as three “controls” without tannic acid and nanoclays were prepared by calendering. Furthermore, the three “optimum” formulations were produced by extrusion film blowing only, since no stable processing conditions could be obtained for the controls. A complete set of sample characterization was performed, including morphological, mechanical, physical, and thermal properties. The results showed that besides the processing method, the thickness was also controlled by the glycerol and water content, leading to density slightly above unity, with higher values for the optimum materials. The calendered films from the optimum formulations showed overall a higher number of cells and cell density than the controls. Higher elastic moduli and tensile strengths were obtained for the films from the optimum formulations made by either method because of the reinforcing effect of the tannic acid and nanoclays, but this led to lower strain at break. The thermal profiles were similar for all films, with higher stability for the optimum formulations. The results were also explained via chemical interactions between the components as observed by Fourier transform infrared spectroscopy. Overall, the optimum formulations not only produced better foamed films in terms of general properties but were much easier to process by both methods (calendering and blowing).","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"69 - 97"},"PeriodicalIF":1.6,"publicationDate":"2020-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319897632","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46903097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.1177/0262489319873642
Paweł Palutkiewicz, M. Trzaskalska, E. Bociąga
The effects of blowing agent, talc, and injection velocity on properties of polypropylene molded parts were presented. Blowing agent was dosed to plastic in amounts 1–2% and talc 10–20%. The results of selected properties, such as weight, thickness, hardness, impact strength, tensile strength, and gloss, were presented. The article also presents microscopic investigations. The blowing agent and talc content have a large impact on mechanical properties and gloss of parts than addition of blowing agent. The use of the blowing agent in an amount of 2 wt% will allow the reduce injection cycle time by reducing the hold pressure and hold time. Addition of blowing agents lowers of tensile strength, hardness, impact strength, and significantly affected the gloss. Talc filler contributes to a significant increase in the weight of parts, a decrease in hardness, impact strength, and tensile strength. The injection velocity has no significant effect on parts properties.
{"title":"The influence of blowing agent addition, talc filler content, and injection velocity on selected properties, surface state, and structure of polypropylene injection molded parts","authors":"Paweł Palutkiewicz, M. Trzaskalska, E. Bociąga","doi":"10.1177/0262489319873642","DOIUrl":"https://doi.org/10.1177/0262489319873642","url":null,"abstract":"The effects of blowing agent, talc, and injection velocity on properties of polypropylene molded parts were presented. Blowing agent was dosed to plastic in amounts 1–2% and talc 10–20%. The results of selected properties, such as weight, thickness, hardness, impact strength, tensile strength, and gloss, were presented. The article also presents microscopic investigations. The blowing agent and talc content have a large impact on mechanical properties and gloss of parts than addition of blowing agent. The use of the blowing agent in an amount of 2 wt% will allow the reduce injection cycle time by reducing the hold pressure and hold time. Addition of blowing agents lowers of tensile strength, hardness, impact strength, and significantly affected the gloss. Talc filler contributes to a significant increase in the weight of parts, a decrease in hardness, impact strength, and tensile strength. The injection velocity has no significant effect on parts properties.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"3 - 30"},"PeriodicalIF":1.6,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319873642","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44035895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.1177/0262489319873859
Aekartit Boonprasertpoh, D. Pentrakoon, Jirawut Junkasem
This study examines the effect of poly(butylene adipate-co-terephthalate) (PBAT) content on the physical, morphological, and mechanical properties of poly(butylene succinate) (PBS)/PBAT foam. A compression molding technique was used to prepare the PBS/PBAT foam using the chemical blowing agent azodicarbonamide and the cross-linking agent dicumyl peroxide. The chemical structure and morphological properties of PBS/PBAT foam were examined via Fourier transform infrared and scanning electron microscopy techniques, respectively, whereas tensile and flexural properties were investigated using a universal testing machine. The results reveal that the incorporation of PBAT barely enhances the viscosity of the PBS/PBAT blend, producing only minor changes in the average cell size of PBS/PBAT foam. However, increasing the PBAT content contributes to a relatively significant improvement in the flexibility and toughness of PBS/PBAT foam, where a decrease in Young’s modulus and tensile strength of the PBS/PBAT foam is observed compared with those of the PBS foam. Similar behavior to the tensile results is noticed for the flexural properties of the neat and PBS/PBAT foams.
{"title":"Effect of PBAT on physical, morphological, and mechanical properties of PBS/PBAT foam","authors":"Aekartit Boonprasertpoh, D. Pentrakoon, Jirawut Junkasem","doi":"10.1177/0262489319873859","DOIUrl":"https://doi.org/10.1177/0262489319873859","url":null,"abstract":"This study examines the effect of poly(butylene adipate-co-terephthalate) (PBAT) content on the physical, morphological, and mechanical properties of poly(butylene succinate) (PBS)/PBAT foam. A compression molding technique was used to prepare the PBS/PBAT foam using the chemical blowing agent azodicarbonamide and the cross-linking agent dicumyl peroxide. The chemical structure and morphological properties of PBS/PBAT foam were examined via Fourier transform infrared and scanning electron microscopy techniques, respectively, whereas tensile and flexural properties were investigated using a universal testing machine. The results reveal that the incorporation of PBAT barely enhances the viscosity of the PBS/PBAT blend, producing only minor changes in the average cell size of PBS/PBAT foam. However, increasing the PBAT content contributes to a relatively significant improvement in the flexibility and toughness of PBS/PBAT foam, where a decrease in Young’s modulus and tensile strength of the PBS/PBAT foam is observed compared with those of the PBS foam. Similar behavior to the tensile results is noticed for the flexural properties of the neat and PBS/PBAT foams.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"31 - 41"},"PeriodicalIF":1.6,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319873859","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47471159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-01-01DOI: 10.1177/0262489319885031
Rui Yao, J. Ju, Z. Yao
Novel three-dimensional (3-D) hierarchical multiconfiguration graphene/polyaniline-based aerogels were synthesized via in situ polymerization and directed freeze-drying method. The composite aerogels enhanced excellent thermal and electrical performances, at the same time, their 3-D hierarchical multiconfiguration was robust and stable, which made them more beneficial to be applied to thermal or electrical fields. Graphene oxide/polyaniline (GO/AP) and reduced graphene oxide (RGO/AP) were prepared. The multiconfiguration structure can be apparently observed through scanning electron microscopy image of GO/AP aerogel: the aerogels were composed of skeleton structure with paralleled open holes; the skeleton structure was made up by hierarchical GO sheet with AP network; and the AP network consisted of AP skeleton and nanopores. GO/AP aerogels showed higher heat resistance than single AP aerogel. In addition, compared with GO/AP and AP aerogels, RGO/AP aerogel had the best electrical performances (vertical electrical conductivity: 1.23 S cm−1 and specific capacitance: 580 F g−1). What is more, attributed to the multiconfiguration structure, the composite aerogels exhibited excellent performances in holes extending direction.
采用原位聚合和定向冷冻干燥法制备了新型的三维分层多构型石墨烯/聚苯胺气凝胶。复合气凝胶增强了优异的热学和电学性能，同时其三维分层多构型具有鲁棒性和稳定性，更有利于应用于热或电场。制备了氧化石墨烯/聚苯胺(GO/AP)和还原氧化石墨烯(RGO/AP)。通过扫描电镜图像可以明显观察到GO/AP气凝胶的多构型结构:气凝胶由具有平行开孔的骨架结构组成;骨架结构由带AP网络的分层氧化石墨烯片构成;AP网络由AP骨架和纳米孔组成。氧化石墨烯/AP气凝胶的耐热性高于单一AP气凝胶。此外，与GO/AP和AP气凝胶相比，RGO/AP气凝胶具有最佳的电性能(垂直电导率为1.23 S cm−1，比电容为580 F g−1)。此外，由于复合气凝胶的多构型结构，复合气凝胶在孔洞延伸方向上表现出优异的性能。
{"title":"Novel 3-D hierarchical multiconfiguration graphene/polyaniline-based aerogels with directed higher performances","authors":"Rui Yao, J. Ju, Z. Yao","doi":"10.1177/0262489319885031","DOIUrl":"https://doi.org/10.1177/0262489319885031","url":null,"abstract":"Novel three-dimensional (3-D) hierarchical multiconfiguration graphene/polyaniline-based aerogels were synthesized via in situ polymerization and directed freeze-drying method. The composite aerogels enhanced excellent thermal and electrical performances, at the same time, their 3-D hierarchical multiconfiguration was robust and stable, which made them more beneficial to be applied to thermal or electrical fields. Graphene oxide/polyaniline (GO/AP) and reduced graphene oxide (RGO/AP) were prepared. The multiconfiguration structure can be apparently observed through scanning electron microscopy image of GO/AP aerogel: the aerogels were composed of skeleton structure with paralleled open holes; the skeleton structure was made up by hierarchical GO sheet with AP network; and the AP network consisted of AP skeleton and nanopores. GO/AP aerogels showed higher heat resistance than single AP aerogel. In addition, compared with GO/AP and AP aerogels, RGO/AP aerogel had the best electrical performances (vertical electrical conductivity: 1.23 S cm−1 and specific capacitance: 580 F g−1). What is more, attributed to the multiconfiguration structure, the composite aerogels exhibited excellent performances in holes extending direction.","PeriodicalId":9816,"journal":{"name":"Cellular Polymers","volume":"39 1","pages":"42 - 53"},"PeriodicalIF":1.6,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/0262489319885031","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48157249","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"医学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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