Anisotropic ferromagnetism within antiferromagnetic crystals
The cover feature showcases the emergence of hard anisotropic ferromagnetism following the intercalation of nonmagnetic pyridinium ions into antiferromagnetic FePS3 single crystals. In article number 202400101, Yunbo Ou, Feng Liu, Seth Ariel Tongay, and colleagues report the transition from antiferromagnetism to ferromagnetism in pyridinium-intercalated FePS3, thereby highlighting both the energetically stable B-phase and metastable P-phase. These phases exhibit remarkable properties, including giant coercive fields exceeding 7 T and high Curie temperatures (72–87 K). As revealed by X-ray photoelectron spectroscopy and supported by first-principles calculations and atomistic spin dynamics simulations, electron transfer from the pyridinium ions to FePS3 plays a key role in driving this transition. This work offers crucial insights into hard magnetism in intercalated van der Waals materials, thus paving the way for advances in 2D magnet-based technologies.