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Chemically recyclable nanofiltration membranes fabricated from two circular polymer classes of the same monomer origin 用同源的两种环状聚合物制成的化学可循环纳滤膜
Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-28 DOI: 10.1016/j.memlet.2024.100067
Rifan Hardian , Abdul Ghaffar , Changxia Shi , Eugene Y.-X. Chen , Gyorgy Szekely

Nanofiltration is widely used in various industries to separate solutes from solvents. To foster a circular economy, establishing a closed-loop lifecycle for the membrane materials is highly important. In this study, we fabricated recyclable nanofiltration membranes from chemically recyclable polymers —polyester P(BiL=)ROP and poly(cyclic olefin) P(BiL=)ROMP— using γ-butyrolactone as a green solvent. These two polymers, of two different polymer classes, were obtained from a single monomer, which could be recycled back to the same monomer, exhibiting the unique “one monomer–two polymers–one monomer” closed-loop chemical circularity. The effect of physical treatment, such as annealing, hot-pressing, and air exposure on the morphological characteristics and performance of the nanofiltration membranes was investigated. We revealed the interplay between membrane pore size, thickness, density and the molecular sieving performance of the nanofiltration membranes. Solute rejections were mainly governed by the membrane pore size. However, solvent flux was mainly governed by the membrane density that determines the free volume interconnectivity. The membranes exhibited a tunable molecular weight cutoff between 553 and 777 g mol−1 and methanol permeance between 5.9 and 9.8 L m–2 h–1 bar−1. The membranes exhibited excellent long-term nanofiltration stability over 1 week. The combination of the green solvent used for membrane fabrication and the circular life cycle of the polymer membrane brings one step closer to closing the circularity loop of membrane technology.

纳滤广泛应用于各行各业,用于从溶剂中分离溶质。为了促进循环经济,建立膜材料的闭环生命周期非常重要。在这项研究中,我们使用γ-丁内酯作为绿色溶剂,用化学可回收聚合物--聚酯 P(BiL=)ROP 和聚环烯烃 P(BiL=)ROMP 制作了可回收纳滤膜。这两种聚合物属于两种不同的聚合物类别,均由单一单体制得,并可回收为相同的单体,表现出独特的 "一个单体-两种聚合物-一个单体 "闭环化学循环性。研究了退火、热压和空气暴露等物理处理对纳滤膜形态特征和性能的影响。我们揭示了膜孔径、厚度、密度与纳滤膜分子筛分性能之间的相互作用。溶质截留主要受膜孔径的影响。然而,溶剂通量主要受决定自由体积互联性的膜密度的影响。膜的可调分子量截止值介于 553 和 777 g mol-1 之间,甲醇渗透率介于 5.9 和 9.8 L m-2 h-1 bar-1 之间。膜在 1 周内表现出卓越的长期纳滤稳定性。膜制造所使用的绿色溶剂与聚合物膜的循环生命周期相结合,使膜技术的循环闭环更近了一步。
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引用次数: 0
Strong improvement of permeability and rejection performance of graphene oxide membrane by engineered interlayer spacing 工程层间距对氧化石墨烯膜的渗透性和截留性能有明显的改善
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100065
Zafar Khan Ghouri , Khaled Elsaid , David James Hughes , Mohamed Mahmoud Nasef , Ahmed Abdel-Wahab , Ahmed Abdala

Advanced membranes fabricated from multilayer/laminated graphene oxide (GO) are promising in water treatment applications as they provide very high flux and excellent rejection of various water pollutants. However, these membranes have limited viability, and suffer from instabilities and swelling due to the hydrophilic nature of GO. In this work, the permeability and rejection performance of laminated GO membranes were improved via functionalization with ethylenediamine (EDA) and polyethyleneimine (PEI). The membranes are fabricated via the pressure-assembly stacking technique, and their structure is well characterized. The performance, rejection, and stability of the fabricated functionalized GO membranes were evaluated. Pillaring the GO layers using diamine and polyamine resulted in exceptionally high water permeability of 113 L/m2h (LMH) compared to only 28 LMH for the pristine GO membrane while simultaneously satisfying high rejection of multivalent salts of 79.4, 35.4, and 19.6 % for Na2SO4, MgCl2, and NaCl, respectively. The results obtained indicate that proper functionalization of GO provides a roadmap for the potential commercialization of such advanced membranes in water treatment applications.

由多层/层压氧化石墨烯(GO)制成的先进膜在水处理应用中很有前途,因为它们具有非常高的通量和对各种水污染物的优异抑制作用。然而,由于氧化石墨烯的亲水性,这些膜的生存能力有限,并且存在不稳定性和肿胀。在这项工作中,通过乙二胺(EDA)和聚乙烯亚胺(PEI)的功能化,提高了氧化石墨烯层合膜的渗透性和截流性能。采用压力组装叠加技术制备了膜,并对其结构进行了表征。对制备的功能化氧化石墨烯膜的性能、截留率和稳定性进行了评价。使用二胺和多胺支撑氧化石墨烯层,可以获得113 L/m2h (LMH)的超高渗透率,而原始氧化石墨烯膜的渗透率仅为28 L/m2h,同时对Na2SO4、MgCl2和NaCl的多价盐的截留率分别为79.4%、35.4%和19.6%。所获得的结果表明,氧化石墨烯的适当功能化为这种先进膜在水处理应用中的潜在商业化提供了路线图。
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引用次数: 0
Unexpected high performance of ZIF-8 membranes for 1,3-butadiene purification 用于1,3-丁二烯净化的ZIF-8膜的意外高性能
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100066
Jun-Wei Wang , Zhiqin Qiang , Xiaoli Ma

The purification of 1,3-butadiene from C4 hydrocarbon mixtures currently relies on energy-intensive extractive distillation. In this study, we employed ZIF membranes for this challenging separation for the first time, unveiling their superior capability in isolating 1,3-butadiene from other C4 hydrocarbons with similar sizes, including 1-butene, isobutene, and n-butane. This strong sieving effect was evident from two types of ZIF-8 membranes: one with low crystallinity fabricated via the all-vapor-phase ligand-induced permselectivation (LIPS) method and another with high crystallinity synthesized through the seeded growth method. The gas permeances decreased with increasing kinetic diameters, following the order of 1,3-butadiene (4.31 Å) > 1-butene (4.46 Å) > n-butane (4.687 Å) > isobutene (4.84 Å). The LIPS-ZIF-8 membrane exhibited a high 1,3-butadiene permeance of approximately 1.43 × 10−7 mol/m2 s Pa (∼430 GPU) and ideal separation factors of 18, 56, and 134 for 1,3-butadiene over 1-butene, n-butane, and isobutene, respectively. In separating four-component C4 mixtures, these membranes could enrich 1,3-butadiene content from 50% in the feed to 96–98% in the permeate through a single separation step. This unprecedented performance is attributed to differences in C4 diffusivities that span several orders of magnitude.

目前,从C4烃混合物中提纯1,3-丁二烯依赖于能源密集型的萃取精馏。在这项研究中,我们首次使用ZIF膜进行这种具有挑战性的分离,揭示了它们从其他类似大小的C4碳氢化合物(包括1-丁烯、异丁烯和正丁烷)中分离1,3-丁二烯的卓越能力。这种强筛分作用在两种类型的ZIF-8膜上表现得很明显:一种是通过全气相配体诱导过选择(LIPS)法制备的低结晶度ZIF-8膜,另一种是通过种子生长法合成的高结晶度ZIF-8膜。气体渗透率随动力学直径的增大而减小,依次为:1,3-丁二烯(4.31 Å) >-丁烯(4.46 Å) >正丁烷(4.687 Å) >异丁烯(4.84 Å)。lipps - zif -8膜对1,3-丁二烯的渗透率约为1.43 × 10−7 mol/m2 s Pa (~ 430 GPU),对1,3-丁二烯对1-丁烯、正丁烷和异丁烯的理想分离系数分别为18、56和134。在四组分C4混合物的分离中,该膜通过一步分离,可将进料中的1,3-丁二烯含量从50%提高到96-98%。这种前所未有的性能归因于跨越几个数量级的C4扩散系数的差异。
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引用次数: 0
Engineering organic solvent reverse osmosis in hybrid AlOxHy / polymer of intrinsic microporosity 1 (PIM-1) membranes using vapor phase infiltration 工程有机溶剂反渗透在混合AlOxHy /聚合物的固有微孔1 (PIM-1)膜上的气相渗透
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-11-01 DOI: 10.1016/j.memlet.2023.100064
Yi Ren , Benjamin C. Jean , Woo Jin Jang , Akriti Sarswat , Young Joo Lee , Emily K. McGuinness , Kshitij Dhavala , Mark D. Losego , Ryan P. Lively

A solvent-free post-treatment process known as vapor phase infiltration (VPI) is used to engineer the organic solvent reverse osmosis (OSRO) performance of polymer of intrinsic microporosity 1 (PIM-1) membranes via infiltration of trimethylaluminum (TMA) metal-organic vapor. The infiltration of inorganic aluminum constituents hybridizes the pure polymer PIM-1 into an organic-inorganic material (AlOxHy/PIM-1) with enhanced chemical stability. A homogenous distribution of inorganic loading in PIM-1 is achieved due to the reaction-limited infiltration mechanism, and the OSRO performance is enhanced as a result. OSRO separations of ethanol/isooctane mixtures using these membranes are shown to be capable of breaking the azeotropic composition with a separation factor for ethanol over isooctane greater than 5 and an ethanol permeance of 0.1 Lm–2h–1bar–1. Thus, these organic-inorganic hybrid membranes created via VPI show promise as an alternative method for separating azeotropic liquid mixtures.

采用无溶剂后处理工艺——气相渗透(VPI),通过三甲基铝(TMA)金属有机蒸汽的渗透,设计了固有微孔1 (PIM-1)膜聚合物的有机溶剂反渗透(OSRO)性能。无机铝组分的渗透使纯聚合物PIM-1杂化成有机无机材料(AlOxHy/PIM-1),化学稳定性增强。由于反应受限的渗透机制,PIM-1中无机负载分布均匀,从而提高了OSRO性能。使用这些膜对乙醇/异辛烷混合物进行OSRO分离表明,乙醇在异辛烷上的分离系数大于5,乙醇渗透率为0.1 Lm-2h-1bar-1,能够破坏共沸组成。因此,通过VPI制造的有机-无机杂化膜有望成为分离共沸液体混合物的替代方法。
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引用次数: 0
Recycling of end-of-life polymeric membranes for water treatment: Closing the loop 回收报废聚合物膜用于水处理:关闭循环
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-09-21 DOI: 10.1016/j.memlet.2023.100063
Chenxin Tian , Jiansuxuan Chen , Zhiyu Bai, Xueye Wang, Ruobin Dai, Zhiwei Wang

Polymeric membranes have garnered widespread adoption in applications such as desalination, wastewater treatment, and water reuse. Nevertheless, the current disposal practices for these end-of-life (EoL) polymeric membranes, primarily landfill and incineration, are neither economically nor environmentally sustainable. To address this challenge, we first analyzed the factors leading to the EoL phase for these membranes; an understanding that is critical in developing or selecting appropriate recycling technologies. We further proposed a technological framework to guide recycling choices based on the specific state of the EoL membrane. In cases where the membrane exhibits significant breakage, dissolution using eco-friendly solvents, followed by membrane re-preparation, is recommended. For membranes without substantial breakage, regeneration, upcycling, or downcycling strategies can be deployed based on scenarios. We underscored the crucial role of irrecoverable foulant removal within the regeneration technology. Additionally, the reaction interface must be suitably remediated before the application of upcycling technology to EoL microfiltration/ultrafiltration membranes. The downcycling strategy, facilitated by NaOCl oxidation, is readily applicable to EoL nanofiltration/reverse osmosis membranes. This brief frontier review aims to serve as a valuable reference for recycling end-of-life water treatment polymeric membranes.

聚合物膜在脱盐、废水处理和水再利用等应用中得到了广泛采用。然而,目前对这些报废聚合物膜的处理方法,主要是填埋和焚烧,在经济上和环境上都不可持续。为了应对这一挑战,我们首先分析了导致这些膜EoL相的因素;对开发或选择合适的回收技术至关重要的理解。我们进一步提出了一个技术框架,根据EoL膜的具体状态来指导回收选择。如果膜出现明显破裂,建议使用环保溶剂溶解,然后重新制备膜。对于没有实质性破裂的膜,可以根据场景部署再生、上循环或下循环策略。我们强调了不可恢复的污垢去除在再生技术中的关键作用。此外,在将上循环技术应用于EoL微滤/超滤膜之前,必须对反应界面进行适当的修复。NaOCl氧化促进的下循环策略很容易适用于EoL纳滤/反渗透膜。这篇简短的前沿综述旨在为报废水处理聚合物膜的回收利用提供有价值的参考。
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引用次数: 0
RO membrane with a surface tethered polymer brush layer for enhanced rejection of nitrate, boron, and arsenic 具有表面系留聚合物刷层的反渗透膜,可增强对硝酸盐、硼和砷的去除
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-09-09 DOI: 10.1016/j.memlet.2023.100062
Yian Chen , Yoram Cohen

Thin-film composite (TFC) polyamide (PA) RO membrane modified with a layer of tethered poly(acrylic acid) (PAA) chains displayed intrinsic rejections of nitrate, boron, As(III), and As(V) of 98.0%, 90.7%, 96%, and 99.6%, respectively. The solute permeability coefficients for nitrate, boron, As(III), and As(V) by the SNS-PAA-PA membrane were lower by 31–38%, 49–63%, 57–72% and 87–93% relative to tested commercial membranes. The above results indicate that the SNS-PAA-PA membrane should be suitable for purification of brackish source water contaminated with nitrate, boron, As(III), and As(V) to levels 1219 ppm, 2 ppm, 95 ppb, and 948 ppb, respectively. The study results suggest that there is merit in further exploration of the potential of the present approach for enhancing RO membranes performance for targeted solute removal.

用一层束缚的聚丙烯酸(PAA)链修饰的薄膜复合材料(TFC)聚酰胺(PA)反渗透膜对硝酸盐、硼、As(III)和As(V)的固有截留率分别为98.0%、90.7%、96%和99.6%。与测试的商业膜相比,SNS-PAA-PA膜对硝酸盐、硼、As(III)和As(V)的溶质渗透系数分别降低了31–38%、49–63%、57–72%和87–93%。上述结果表明,SNS-PAA-PA膜应适用于将被硝酸盐、硼、As(III)和As(V)污染的微咸水分别净化至1219ppm、2ppm、95ppb和948ppb的水平。研究结果表明,进一步探索本方法提高反渗透膜靶向溶质去除性能的潜力是有价值的。
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引用次数: 0
Revisiting experimental techniques and theoretical models for estimating the solubility parameter of rubbery and glassy polymer membranes 回顾了估算橡胶和玻璃聚合物膜溶解度参数的实验技术和理论模型
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-27 DOI: 10.1016/j.memlet.2023.100060
Matthew T. Webb , Lucas C. Condes , William J. Box , Harold G. Ly , Sepideh Razavi , Michele Galizia

Estimation and correlation of the Hildebrand solubility parameter (δ) of polymers and small molecules is a common practice in membrane material science and is accomplished by experimental and numerical routes. In this paper, we revisit, update, and compare both routes to enhance the accuracy in the determination of δ. Best practices for the experimental determination of polymer solubility parameters are provided, and the viability of Dynamic Light Scattering (DLS) was demonstrated as an alternative to conventional time- and material-consuming techniques, such as Ubbelohde viscometry and swelling measurements. Glassy and rubbery polymers, including high fractional free volume (FFV) microporous polymers such as PIM-1 and poly(1-trimethylsilyl-1-propyne) (PTMSP), are among the samples included in this study with great relevance to membrane science. In an attempt to enhance the accuracy of numerical estimate of polymer solubility parameters via the group contribution method, we provide updated group contribution parameters, along with their uncertainty, according to the technique recently reported by Smith et al. These updated group contribution parameters result in a mean absolute relative error of 9.0% in predicting the solubility parameter on a test set of 40 polymers, which is on par with the average 10% error reported previously. We also show, using machine learning techniques, that augmenting the group contribution model with extra parameters or non-linear relationships does not improve its accuracy. Results of the updated group contribution technique and dynamic light scattering measurements were compared to experimental viscometry on four test polymers, and the difference between the three techniques is compared.

聚合物和小分子的希尔德布兰德溶解度参数(δ)的估计和关联是膜材料科学中的一种常见做法,通过实验和数值方法实现。在本文中,我们重新审视、更新和比较了这两种途径,以提高δ测定的准确性。提供了聚合物溶解度参数实验测定的最佳实践,并证明了动态光散射(DLS)作为传统耗时和材料消耗技术(如乌氏粘度计和溶胀测量)的替代方法的可行性。玻璃状和橡胶状聚合物,包括高自由体积分数(FFV)微孔聚合物,如PIM-1和聚(1-三甲基甲硅烷基-1-丙炔)(PTMSP),是本研究中包含的与膜科学具有重大相关性的样品之一。根据Smith等人最近报道的技术,为了通过基团贡献法提高聚合物溶解度参数数值估计的准确性,我们提供了更新的基团贡献参数及其不确定性。这些更新的基团贡献参数导致在40种聚合物的测试集上预测溶解度参数的平均绝对相对误差为9.0%,这与之前报道的平均10%的误差持平。我们还使用机器学习技术表明,用额外的参数或非线性关系来扩充群体贡献模型并不能提高其准确性。将更新的基团贡献技术和动态光散射测量的结果与四种测试聚合物的实验粘度法进行了比较,并比较了三种技术之间的差异。
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引用次数: 0
Positively charged thin-film composite hollow fiber nanofiltration membrane via interfacial polymerization and branch polyethyleneimine modification for Mg2+/Li+ separation 正电荷薄膜复合中空纤维纳滤膜通过界面聚合和分支聚乙烯亚胺改性进行Mg2+/Li+分离
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-26 DOI: 10.1016/j.memlet.2023.100061
Enlin Wang , Shaoxiao Liu , Liyang Liu , Lihui Han , Baowei Su

It is a vital technical challenge to extract lithium from salt-lake brine which has very high Mg2+ / Li+ mass ratio via green and low-cost methods, as these two cations have quite similar ionic hydration radius. Positively charged nanofiltration membranes can separate Li+ and Mg2+ through Donnan exclusion. In this work, a kind of hollow fiber nanofiltration membrane with positively charged skin layer was successfully fabricated via interfacial polymerization followed by a surface modification with branched polyethyleneimine (BPEI). The resultant membrane has a large number of amine groups, and thus shows positively charged surface with high rejection for divalent cation ions via Donnan exclusion. This gives it very high selectivity for the separation of Li+ ions from salt-lake brine. Under optimized conditions, it achieves a water permeance of up to 126.2 L m-2 h-1 MPa−1 at a transmembrane pressure difference of 4 bar, and a MgCl2 rejection of 94.6% with 2000 mg L-1 aqueous MgCl2 solution as feed. Meanwhile, it achieves a Mg2+ / Li+ selectivity of nearly 24 for MgCl2 and LiCl salt mixture solution with an overall concentration of 2000 mg L-1 and a Mg2+ / Li+ mass ratio of 150 : 1 as feed, which is high as compared with most of the literature, demonstrating its potential in the practical application of Mg2+ and Li+ separation.

通过绿色和低成本的方法从具有非常高Mg2+/Li+质量比的盐湖卤水中提取锂是一个至关重要的技术挑战,因为这两种阳离子具有非常相似的离子水合半径。带正电荷的纳滤膜可以通过Donnan排斥分离Li+和Mg2+。本工作通过界面聚合,然后用支链聚乙烯亚胺(BPEI)进行表面改性,成功制备了一种带正电荷表层的中空纤维纳滤膜。所得膜具有大量的胺基团,因此显示出带正电的表面,通过Donnan排斥对二价阳离子具有高排斥性。这使其对从盐湖卤水中分离Li+离子具有非常高的选择性。在优化的条件下,它在4巴的跨膜压差下实现了高达126.2 L m-2 h-1 MPa−1的透水性,并且以2000 mg L-1的MgCl2水溶液作为进料时,MgCl2的截留率为94.6%。同时,它对总浓度为2000mg L-1、Mg2+/Li+质量比为150∶1的MgCl2和LiCl盐混合物溶液的Mg2+/Ly+选择性接近24,与大多数文献相比,这是高的,表明了它在Mg2+和Li+分离的实际应用中的潜力。
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引用次数: 0
Lithium recovery from brines by lithium membrane flow capacitive deionization (Li-MFCDI) – A proof of concept 锂膜流动电容去离子(Li-MFCDI)从盐水中回收锂——概念验证
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-12 DOI: 10.1016/j.memlet.2023.100059
H.M. Saif, J.G. Crespo, S. Pawlowski

The demand of lithium for electric vehicles and energy storage devices is increasing rapidly, thus new sources of lithium (such as seawater and natural or industrial brines), as well as sustainable methods for its recovery, will need to be explored/developed soon. This work presents a novel electromembrane process, called Lithium Membrane Flow Capacitive Deionization (Li-MFCDI), which was tested to recover lithium from a synthetic geothermal brine containing a much higher mass concentration of sodium than lithium (more than 650 times). Specifically, a ceramic lithium-selective membrane was integrated into a flow capacitive deionization (FCDI) cell, which was specifically designed, and 3D printed, to allow simultaneous charging and regeneration of the employed flow electrodes. Despite the extremely high Na+/Li+ mass ratio in the feed stream, 99.98% of the sodium was rejected and the process selectivity for lithium over other monovalent cations was 141 ± 5.85 for Li+/Na+ and 46 ± 1.46 for Li+/K+. The Li-MFCDI process exhibited a stable behaviour over a 7-day test period, and the estimated energy consumption was 16.70 ± 1.63 kWh/kg of Li+ recovered in the draw solution. These results demonstrate promising potential of the Li-MFCDI for the sustainable lithium recovery from saline streams.

电动汽车和储能设备对锂的需求正在迅速增长,因此需要尽快探索/开发新的锂来源(如海水和天然或工业盐水)以及可持续的回收方法。这项工作提出了一种新的电膜工艺,称为锂膜流动电容去离子(Li-MFCDI),该工艺被测试用于从合成地热盐水中回收锂,其中钠的质量浓度远高于锂(超过650倍)。具体而言,将陶瓷锂选择膜集成到流动电容去离子(FCDI)电池中,该电池经过专门设计并3D打印,以允许对所使用的流动电极同时充电和再生。尽管进料流中Na+/Li+的质量比极高,但仍有99.98%的钠被截留,锂相对于其他单价阳离子的工艺选择性为:Li+/Na+为141±5.85,Li+/K+为46±1.46。Li-MFCDI工艺在7天的试验期内表现出稳定的性能,在提取溶液中回收的Li+的估计能耗为16.70±1.63kWh/kg。这些结果证明了Li-MFCDI在从盐水流中可持续回收锂方面的潜力。
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引用次数: 0
Green chemistry-based fabrication of hollow fiber and flat sheet polyimide membranes for CO2/CH4 separation 基于绿色化学的CO2/CH4分离中空纤维和平板聚酰亚胺膜的制备
Q1 ENGINEERING, CHEMICAL Pub Date : 2023-08-11 DOI: 10.1016/j.memlet.2023.100057
George V. Theodorakopoulos, Dionysios S. Karousos, Charitomeni M. Veziri, Evangelos P. Kouvelos, Andreas A. Sapalidis, Evangelos P. Favvas

In this work, the successful fabrication of polymeric hollow fiber (HF) and flat sheet (FS) membranes was examined by employing γ-butyrolactone (GBL)-a green and environmentally friendly solvent- for the polymer's dissolution following the principles of green chemistry and sustainability regarding the membrane preparation. In addition, the ternary phase diagram of the P84/GBL/water was constructed and the viscosity of dope solution was measured for different concentrations and temperatures. Their morphological characteristics of the prepared polyimide membranes were investigated through SEM analysis. CO2/CH4 separation measurements under continuous flow were performed to evaluate the efficiency of the membranes for a binary 10/90 vol.% CO2/CH4 gas mixture. The developed green HF and FS membranes exhibited comparable, and in some cases even superior, performance compared to membranes prepared using the conventional and highly toxic NMP solvent, making them highly promising candidates for CO2/CH4 separation, with a real mixture separation factor of ∼58.

在这项工作中,根据膜制备的绿色化学和可持续性原则,采用绿色环保溶剂γ-丁内酯(GBL)溶解聚合物,成功制备了聚合物中空纤维(HF)和平板(FS)膜。此外,构建了P84/GBL/水的三元相图,并测量了不同浓度和温度下涂料溶液的粘度。通过扫描电镜分析研究了制备的聚酰亚胺膜的形貌特征。在连续流动下进行CO2/CH4分离测量,以评估二元10/90体积%的膜的效率CO2/CH4气体混合物。与使用传统和高毒性NMP溶剂制备的膜相比,开发的绿色HF和FS膜表现出相当的性能,在某些情况下甚至更优越,使其成为非常有前途的CO2/CH4分离候选者,实际混合物分离因子为~58。
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引用次数: 0
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