In this article, we introduce a tunable core–multishell nanostructure (ZnTe/CdSe/CdS/CdSe/ZnSe) whose architecture can be adjusted through shell thicknesses and the surrounding oxidative environment (SiO2 and HfO2). By jointly exploiting quantum confinement and dielectric non-uniformity at the interfaces, the proposed model enables effective control of optical nonlinear characteristics, opening pathways toward tailoring nonlinear responses that remain challenging for existing optoelectronic designs. The numerical work is carried out under the approximated mass framework by unraveling the 3-D Schrödinger equation in the presence of an oxide coating. After obtaining the wavefunctions and their corresponding energies, the dipole matrix element is quantitatively analyzed in response to various structural and dielectric modifications. Based on the compact density method, our computational findings revealed that the eigenfrequencies for both real and imaginary parts associated to the effective complex dielectric function are primarily governed by the oxidative layer attributes and spatial decesive metrics. In addition, selecting HfO2 to encapsulate the nanostructure reduces the occurrence of undesirable photobleaching in the absorption spectrum until the incident illumination reaches nearly 0.6 MW/cm2. Leveraging the dimension-, configuration-, capping composition-, and permittivity-modulated spectral aspects, our model provides a conceptual framework that can assist in the rational design of more advanced light–matter interaction systems.
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