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METHODOLOGY PROPOSAL FOR CORRELATION STUDIES OF FLUVIAL SEDIMENTS BASED ON PETROGRAPHIC AND LITHOGEOCHEMICAL ANALYSIS: EXAMPLE OF ITS APPLICATION ON CENOZOIC ROCK FROM THE LISAMA FORMATION (MIDDLE MAGDALENA VALLEY, COLOMBIA) 基于岩石学和岩石地球化学分析的河流沉积物对比研究方法建议:以lisama组新生代岩石(哥伦比亚中magdalena山谷)为例
Pub Date : 2013-12-01 DOI: 10.29047/01225383.46
J. Naranjo-Vesga, Pedro-David Gómez-Gutiérrez, Jaime-Ricardo Gélvez-Llanez, Noria-Elena Duque-Pardo, N. Moreno-Gómez
The petrographic and lithogeochemical analyses of fluvial sediments from the Lisama Formation suggest potential for the association of compositional and chemical changes of rocks with the identification and correlation of Cenozoic stratigraphic units in the Middle Magdalena valley basin. The integration of different compositional techniques enable the subdivision of the Lisama Formation into three petrographic zones. The zoning proposed herein match the palynological biozoning defined in the same stratigraphic sections, demonstrating their potential as a complementary correlation tool to biostratigraphy. This methodology of integrating petrographic and lithogeochemical analyses can be used in subsequent studies in the Middle Magdalena Basin, mainly in geographic areas where the palynomorph recovery is low or null. This work integrates Thin Section Analyses, Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES), Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and X-Ray Diffraction (XRD) in two correlatable outcrops in the Western and Eastern flanks of the Nuevo Mundo Syncline (NMS).
对里萨马组河流沉积的岩石学和岩石地球化学分析表明,岩石的组成和化学变化可能与中马格达莱纳河谷盆地新生代地层单元的识别和对比有关。不同成分技术的综合应用使Lisama组被划分为三个岩相带。本文提出的分带与在同一地层剖面中定义的孢粉生物分带相匹配,显示了它们作为生物地层学补充对比工具的潜力。这种结合岩石学和岩石地球化学分析的方法可以用于中马格达莱纳盆地的后续研究,主要是在岩石形态恢复低或零的地理区域。本文将薄片分析、电感耦合等离子体光学发射光谱(ICP-OES)、电感耦合等离子体质谱(ICP-MS)和x射线衍射(XRD)技术集成到Nuevo Mundo向斜(NMS)东、西两翼两个相关的露头中。
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引用次数: 2
Acute toxicity of drilling muds on Litopenaeus vannamei (Boone, 1931) postlarvae 钻井泥浆对凡纳滨对虾(Boone, 1931)幼虫的急性毒性
Pub Date : 2013-12-01 DOI: 10.29047/01225383.52
G. León, Simón Andrés Rodríguez Satizábal, C. Romero, A. Herrera, Marlon Serrano Gómez
espanolL a toxicidad aguda de seis lodos de perforacion (base agua y base sintetico) fue evaluada utilizando postlarvas de Litopenaeus vannamei con la finalidad de establecer la concentracion letal media a 96 h (CL50). La Fase Suspendida Particulada (FSP) de cada lodo fue usada como material de prueba. Cada FSP de los lodos fue evaluada usando cinco concentraciones de prueba con cuatro replicas de cada una, incluido el control. Los valores de CL50 obtenidos de la FSP de los Lodos Base Agua (LBA) se encontraron entre 4224 ppm y 26635 ppm y entre 40781 ppm y 308248 ppm para los Lodos Base Sintetica (LBS). El protocolo de ensayo para toxicidad aguda con esta especie se valido mediante una carta control con el toxico de referencia (dicromato de potasio). Litopenaeus vannamei mostro tener las condiciones requeridas para ser usado en pruebas de toxicidad aguda. Este trabajo es pionero en Colombia para evaluar los efectos de los lodos de perforacion con un organismo marino local. portuguesA toxicidade aguda de seis lamas de perfuracao (base agua e base sintetica) foi avaliada utilizando postlarvas de Litopenaeus vannamei com a finalidade de estabelecer a concentracao letal media a 96 h (CL50). A Fase Suspensa Particulada (FSP) de cada lama foi usada como material de prova. Cada FSP das lamas foi avaliada usando cinco concentracoes de prova com quatro replicas de cada uma, incluido o controle. Os valores de CL50 obtidos da FSP das Lamas Base Agua (LBA) estavam entre 4224 ppm e 26635 ppm e entre 40781 ppm e 308248 ppm para as Lamas Base Sintetica (LBS). O protocolo de ensaio para toxicidade aguda com esta especie foi validada mediante uma carta controle com o toxico de referencia (dicromato de potassio). Litopenaeus vannamei mostrou ter as condicoes necessarias para ser usado em provas de toxicidade aguda. Este trabalho e pioneiro na Colombia para avaliar os efeitos das lamas de perfuracao com um organismo marinho local. EnglishA cute toxicity of six drilling muds (water based and synthetic based) was evaluated using Litopenaeus vannamei postlarvae to establish the 96 h median lethal concentration (LC50). The Suspended Particulate Phase (SPP) of each drilling mud was used as test material. Each mud SPP was evaluated using five test concentrations, and four replicates of each were used including the control. LC50 values obtained ranged from 4224 ppm to 26635 ppm for Water Based Mud (WBM) and from 40781 ppm to 308248 ppm for Synthetic Based Mud (SBM). The test protocol for acute toxicity for this species was validated through a control chart with the reference toxicant potassium dichromate. Litopenaeus vannamei clearly showed the required conditions to be used in acute toxicity tests. This research is pioneer in Colombia to determine the effects of drilling muds using a local marine organism.
以凡纳滨对虾(Litopenaeus vanannamei)后幼虫为研究对象,对6种钻井泥浆(水基和合成基)进行了西班牙语急性毒性评价,确定了96 h的平均致死浓度(lc50)。在本研究中,我们分析了不同污泥类型的颗粒悬浮相(FSP)。在本研究中,我们评估了两种不同浓度的FSP污泥,每一种浓度都有4个重复,包括对照。水基污泥(LBA)的spf值在4224 ppm ~ 26635 ppm之间,合成基污泥(LBS)的spf值在40781 ppm ~ 308248 ppm之间。对该物种的急性毒性试验方案通过参考毒物(重铬酸钾)的对照图进行验证。凡纳滨对虾已证明具有用于急性毒性试验所需的条件。这项工作是哥伦比亚评估钻井泥浆对当地海洋生物影响的开创性工作。摘要以凡纳滨对虾后幼虫为研究对象,对6种葡萄牙钻井泥浆(水基和合成基)的急性毒性进行了评价,确定了96 h时的平均致死浓度(lc50)。以各污泥的悬浮颗粒相(spf)为试验材料。每个FSP污泥使用5个试验浓缩物进行评估,每个浓缩物有4个重复,包括对照。水基污泥(LBA)的lc50值在4224 ppm ~ 26635 ppm之间,合成污泥(LBS)的lc50值在40781 ppm ~ 308248 ppm之间。该物种的急性毒性试验方案通过对照图验证了参考毒性(重铬酸钾)。凡纳滨对虾已被证明具有用于急性毒性试验的条件。这项工作是哥伦比亚评估钻井泥浆对当地海洋生物影响的开创性工作。用凡纳滨对虾幼虫后测定了六种钻井泥浆(水基和合成基)的cute毒性,以确定96 h中致死浓度(LC50)。= =地理= =根据美国人口普查,这个县的总面积为,其中土地和(2.641平方公里)水。采用5种试验浓度对每种泥浆进行评价,并使用每种泥浆的4个重复物,包括对照物。= =地理= =根据美国人口普查,该镇的总面积为,其中土地和(1.2%)水。该物种急性毒性试验方案已通过对照图与参考毒物重铬酸钾进行验证。凡纳滨对虾清楚地说明了用于急性毒性试验的要求条件。这项研究是哥伦比亚利用当地海洋生物确定钻井泥浆效果的先驱。
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引用次数: 3
Vacuum membrane distillation: modeling and analysis for recovery of ethanol from ethanol/water solutions 真空膜蒸馏:从乙醇/水溶液中回收乙醇的建模和分析
Pub Date : 2013-06-01 DOI: 10.29047/01225383.56
Omar Andrés Benavides Prada, Cesar Augusto Guevara Lastre, F. Núñez, C. B. Ferreira, R. Basurto, Beatriz Torrestiana Sánchez, C. M. Nova
espanolEn este trabajo se planteo un modelo matematico para la transferencia de masa y energia durante la etapa de separacion de etanol utilizando destilacion con membranas al vacio. Este modelo es uno de los pocos propuestos para el estudio de la separacion de etanol por destilacion con membranas al vacio; solo Soni, Abildskov, Jonsson y Gani (2008) han propuesto un modelo de mayor complejidad que el del presente estudio. El modelo matematico fue validado utilizando cuatro casos de estudio reportados en la literatura. El modelo permite predecir satisfactoriamente los resultados experimentales para condiciones de operacion que se encuentren entre 20 - 70oC, con 0.25 - 5% p/p de etanol en la alimentacion, presiones de 2000 - 6000 Pa y Reynolds entre 50 y 2700. Este modelo permitio realizar el analisis de la influencia de parametros de operacion y de diferentes tipos de membranas sobre variables de respuesta como flux de etanol, flux de agua y fraccion de etanol en el permeado, utilizando la herramienta Statgraphics® Centurion XVI.I y un diseno experimental factorial. El analisis de Pareto demuestra que dichos parametros afectan de forma distinta las variables de respuesta del proceso. Los dos valores de flux se incrementan con la temperatura, diametro de poro y porosidad; el espesor de la membrana tiene un efecto negativo sobre el flux de agua (para el flux de etanol su influencia no es significativa). Por otro lado, un aumento de la presion, el diametro de poro o la porosidad disminuye la concentracion de etanol en el permeado. Este ultimo se incrementa con la concentracion de etanol en la alimentacion y el espesor de la membrana. Para la destilacion membranaria al vacio, el modelo predice una concentracion de etanol en el permeado de hasta 8.8 veces la concentracion de alimentacion; dependiendo de las condiciones de operacion y de las caracteristicas de la membrana. EnglishA mathematical model was developed to describe the mass and energy transfer in the ethanol separation process by using vacuum membrane distillation. This model is one of the few proposed for studying the ethanol recovery using vacuum membrane distillation; hence, only Soni, Abildskov, Jonsson and Gani (2008) have proposed a more complex model. The mathematical model was validated using fourcase studies reported in literature. The model fairly describes reported data obtained under the following operating conditions: 20 - 70oC, ethanol concentration from 0.25 to 5% w/w, pressure of 2000 - 6000 Pa and Reynolds of 50 - 2700. The influence of operation conditions and membrane properties on ethanol and water flux, as well as on ethanol concentration in permeate were studied with this validated model by using Statgraphics® Centurion XVI.I and a factorial experiment design. Pareto analysis showed that operating conditions and membrane properties influence the process variables in different ways. For example, both flux values increase with temperature, pore diameter and porosity; but
本工作建立了真空膜蒸馏乙醇分离阶段的质量和能量转移的数学模型。该模型是为数不多的用于真空膜蒸馏乙醇分离研究的模型之一;只有Soni, Abildskov, Jonsson和Gani(2008)提出了一个比目前的研究更复杂的模型。本研究的目的是评估该方法的有效性,并评估该方法的有效性。该模型可以在20 - 70℃、0.25 - 5%乙醇/ w、2000 - 6000 Pa、雷诺数50 - 2700之间的操作条件下成功预测实验结果。该模型允许使用Statgraphics®Centurion XVI工具分析操作参数和不同类型的膜对响应变量(如乙醇通量、水通量和渗透中的乙醇分数)的影响。I和阶乘实验设计。帕累托分析表明,这些参数对过程响应变量的影响是不同的。这两个通量值随温度、孔径和孔隙率而增大;膜的厚度对水的流动有负面影响(对于乙醇的流动没有显著影响)。另一方面,压力、孔径或孔隙率的增加降低了渗透液中乙醇的浓度。膜的厚度随饲料中乙醇浓度的增加而增加。对于真空膜蒸馏,模型预测渗透液中的乙醇浓度高达饲料浓度的8.8倍;这取决于操作条件和膜的特性。= =地理= =根据美国人口普查,这个县的面积为,其中土地面积为,其中土地面积为。该模型是利用真空膜蒸馏研究乙醇回收的为数不多的模型之一;= =地理= =根据美国人口普查,这个县的面积为。累计in was The mathematical model validated using fourcase研究文献。该模型正确地描述了在以下操作条件下获得的报告数据:20 - 70℃,乙醇浓度0.25 - 5% w/w,压力2000 - 6000 Pa,雷诺数50 - 2700。使用Statgraphics®Centurion XVI研究了操作条件和膜性能对乙醇和水流的影响,以及对渗透中的乙醇浓度的影响。= =地理= =根据美国人口普查,这个县的总面积为,其中土地和(3.064平方公里)水。帕托分析表明,操作条件和膜性能以不同的方式影响过程变量。例如,两种通量值都随温度、孔径和孔隙度而增加;然而,膜厚对水流动有负面影响(对乙醇流动没有显著影响)。另一方面,增加压力、孔径或孔隙度降低了乙醇的渗透浓度。最后一个参数随饲料乙醇浓度和膜厚度的增加而增加。在真空膜蒸馏中,该模型预测的渗透乙醇浓度是饲料浓度的8.8倍,这取决于操作条件和膜规格。本文提出了真空膜蒸馏乙醇分离过程中质和能量转移的数学模型。该模型是为数不多的用于研究真空膜蒸馏乙醇分离的模型之一;只有Soni, Abildskov, Jonsson和Gani(2008)提出了一个比本研究更复杂的模型。该数学模型通过文献中报道的四个案例研究进行了验证。该模型可以很好地预测20 - 70℃、0.25 - 5% w / w乙醇饲料、2000 - 6000 Pa压力和雷诺数在50 - 2700之间的操作条件下的实验结果。该模型允许使用Statgraphics®Centurion XVI工具分析操作参数和不同类型的膜对响应变量的影响,如乙醇流量、水流量和渗透中的乙醇分数。我是一个因子实验设计。帕累托分析表明,这些参数对过程响应变量有不同的影响。这两个流量值随温度、孔径和孔隙度的增加而增加;膜厚对水流有负面影响(对乙醇流动的影响不显著)。另一方面,压力、孔径或孔隙率的增加会降低渗透液中乙醇的浓度。 后者随饲料中乙醇浓度和膜厚度的增加而增加。对于真空膜蒸馏,模型预测乙醇在渗透液中的浓度高达饲料浓度的8.8倍;取决于操作条件和膜的特性。
{"title":"Vacuum membrane distillation: modeling and analysis for recovery of ethanol from ethanol/water solutions","authors":"Omar Andrés Benavides Prada, Cesar Augusto Guevara Lastre, F. Núñez, C. B. Ferreira, R. Basurto, Beatriz Torrestiana Sánchez, C. M. Nova","doi":"10.29047/01225383.56","DOIUrl":"https://doi.org/10.29047/01225383.56","url":null,"abstract":"espanolEn este trabajo se planteo un modelo matematico para la transferencia de masa y energia durante la etapa de separacion de etanol utilizando destilacion con membranas al vacio. Este modelo es uno de los pocos propuestos para el estudio de la separacion de etanol por destilacion con membranas al vacio; solo Soni, Abildskov, Jonsson y Gani (2008) han propuesto un modelo de mayor complejidad que el del presente estudio. El modelo matematico fue validado utilizando cuatro casos de estudio reportados en la literatura. El modelo permite predecir satisfactoriamente los resultados experimentales para condiciones de operacion que se encuentren entre 20 - 70oC, con 0.25 - 5% p/p de etanol en la alimentacion, presiones de 2000 - 6000 Pa y Reynolds entre 50 y 2700. Este modelo permitio realizar el analisis de la influencia de parametros de operacion y de diferentes tipos de membranas sobre variables de respuesta como flux de etanol, flux de agua y fraccion de etanol en el permeado, utilizando la herramienta Statgraphics® Centurion XVI.I y un diseno experimental factorial. El analisis de Pareto demuestra que dichos parametros afectan de forma distinta las variables de respuesta del proceso. Los dos valores de flux se incrementan con la temperatura, diametro de poro y porosidad; el espesor de la membrana tiene un efecto negativo sobre el flux de agua (para el flux de etanol su influencia no es significativa). Por otro lado, un aumento de la presion, el diametro de poro o la porosidad disminuye la concentracion de etanol en el permeado. Este ultimo se incrementa con la concentracion de etanol en la alimentacion y el espesor de la membrana. Para la destilacion membranaria al vacio, el modelo predice una concentracion de etanol en el permeado de hasta 8.8 veces la concentracion de alimentacion; dependiendo de las condiciones de operacion y de las caracteristicas de la membrana. EnglishA mathematical model was developed to describe the mass and energy transfer in the ethanol separation process by using vacuum membrane distillation. This model is one of the few proposed for studying the ethanol recovery using vacuum membrane distillation; hence, only Soni, Abildskov, Jonsson and Gani (2008) have proposed a more complex model. The mathematical model was validated using fourcase studies reported in literature. The model fairly describes reported data obtained under the following operating conditions: 20 - 70oC, ethanol concentration from 0.25 to 5% w/w, pressure of 2000 - 6000 Pa and Reynolds of 50 - 2700. The influence of operation conditions and membrane properties on ethanol and water flux, as well as on ethanol concentration in permeate were studied with this validated model by using Statgraphics® Centurion XVI.I and a factorial experiment design. Pareto analysis showed that operating conditions and membrane properties influence the process variables in different ways. For example, both flux values increase with temperature, pore diameter and porosity; but ","PeriodicalId":10235,"journal":{"name":"Ciencia Tecnologia y Futuro","volume":"47 1","pages":"47-60"},"PeriodicalIF":0.0,"publicationDate":"2013-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77232297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
BIOGAS PRODUCTION BY ANAEROBIC DIGESTION OF WASTEWATER FROM PALM OIL MILL INDUSTRY 棕榈油工业废水厌氧消化生产沼气
Pub Date : 2013-06-01 DOI: 10.29047/01225383.58
D. Nabarlatz, Ligia-Patricia Arenas-Beltrán, Diana-Milena Herrera-Soracá, Diana-Andrea Niño-Bonilla
The environmental impact caused by the fossil fuel use encourages society to look for new sources of renewable energy, such as biodiesel. During the last years, palm oil production has dramatically increased in Colombia, since it is the main raw material for biodiesel production. As consequence of the process, palm oil mill effluents with high content of pollutants are released to the environment. Since these effluents have physicochemical characteristics that make them suitable for the production of biogas by anaerobic digestion of residual water, this research evaluates the production of methane using wastewater as substrate from a Colombian palm oil mill. Anaerobic digestion experiments were conducted in batch mode to evaluate the influence of pH and inoculum to substrate ratio, by using two differents inoculums. It was found that the most suitable inoculum was a mixture of 1:1 v/v urban Wastewater Treatment Plant (WWTP) anaerobic sludge/pig manure at a ratio 2 g Volatile Solids (VS) inoculum/g VS substrate, which presented the highest accumulated methane production, reaching 2740 mL methane (0.343 m3 CH4/kg VS) without neutralizing pH.
使用化石燃料对环境造成的影响促使社会寻找新的可再生能源,如生物柴油。在过去几年中,哥伦比亚的棕榈油产量急剧增加,因为它是生产生物柴油的主要原料。由于这一过程,棕榈油厂的污水中含有高含量的污染物被释放到环境中。由于这些废水具有物理化学特性,使其适合通过厌氧消化残余水来生产沼气,因此本研究评估了以哥伦比亚棕榈油厂的废水为基质生产甲烷的情况。采用间歇式厌氧消化实验,通过两种不同的接种物,评价pH和接种物与底物比对厌氧消化的影响。结果表明,以城市污水处理厂厌氧污泥与猪粪1:1 v/v的混合接种量为最合适的接种量,接种量为2 g挥发性固体(VS) /g VS底物,在不中和pH的情况下,累计甲烷产量最高,达到2740 mL甲烷(0.343 m3 CH4/kg VS)。
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引用次数: 12
CFD simulation of crude oil homogenization in pilot plant scale 中试规模原油均质化的CFD模拟
Pub Date : 2013-06-01 DOI: 10.29047/01225383.54
J. Gualdrón, Leonel Andrés Abreu Mora, Fabián Andrey Díaz Mateus
espanolL a homogenizacion de diferentes crudos en tanque a escala piloto es simulada usando codigo comercial para Dinamica Computacional de Fluidos - de sus siglas en ingles (CFD). Los modelos son inherentemente dinamicos ya que todas las simulaciones parten de un tiempo cero donde los crudos se encuentran completamente separados hasta un tiempo final de completa homogenizacion. El tanque es agitado con una pequena propela y un modelo de dos fases es usado en la simulacion con el proposito de observar el proceso de mezclado y calcular las propiedades de la mezcla en funcion de las fracciones volumetricas. El efecto del tamano de malla y el paso en el tiempo son estudiados pues en este tipo de simulaciones el esfuerzo computacional se convierte en un parametro muy importante y debe ser reducido al minimo. Datos experimentales tomados en dos puntos diferentes dentro del tanque a intervalos regulares de tiempo estan disponibles y se observa buena concordancia cuando se comparan con los resultados de las simulaciones. EnglishThe homogenization of different crude oils in a pilot plant tank is simulated using Computational Fluid Dynamics (CFD) commercial code. The models are inherently transient since all simulations start from a time zero where the crudes are completely separated to a final time of full homogenization. The tank is agitated with a small impeller and a two-phase model is used in the simulations in order to see the mixing process and calculate the properties of the blend based on the volume fractions. The effect of the mesh size and time step size are studied since in this type of simulations the computational effort becomes a major parameter and has to be reduced to a minimum. Experimental data taken from two different points in the tank at regular time intervals are available to compare the results of the simulations, concluding in good agreement. portuguesA homogeneizacao de diferentes crus em tanque a escala piloto e simulada usando codigo comercial para Dinâmica Computacional de Fluidos - por sua sigla em ingles (CFD). Os modelos sao inerentemente dinâmicos ja que todas as simulacoes partem de um tempo zero onde os crus estao completamente separados ate um tempo final de completa homogeneizacao. O tanque e agitado com uma pequena helice e um modelo de duas fases e usado na simulacao com o proposito de observar o processo de mistura e calcular as propriedades da mistura em funcao das fracoes volumetricas. O efeito do tamanho de malha e a passagem do tempo sao estudados, pois neste tipo de simulacoes o esforco computacional se converte em um parâmetro muito importante e deve ser reduzido ao minimo. Dados experimentais tomados em dois pontos diferentes dentro do tanque em intervalos regulares de tempo estao disponiveis e observa-se boa concordância quando comparados com os resultados das simulacoes.
使用计算流体动力学(CFD)的商业代码模拟了中试规模罐内不同原油的均质化。这些模型本质上是动态的,因为所有的模拟都是从零时间开始的,在零时间里,原油被完全分离,直到完全均质化的最后时间。本研究的目的是确定混合过程中所涉及的物理和化学性质,并确定混合过程中所涉及的物理和化学性质。本研究的目的是确定混合过程中所涉及的物理和化学性质。研究了网格大小和时间步长的影响,因为在这种类型的模拟中,计算工作量成为一个非常重要的参数,必须最小化。在罐内两个不同时间间隔采集的实验数据是可用的,与模拟结果有良好的一致性。使用计算流体动力学(CFD)商业代码模拟了中试装置储罐中不同原油的均质化。The models are inherently transient鉴于all simulations start from time where The crudes are零层次separated to a final time of full homogenization。The tank is工作with a small impeller and a two-phase model is in The simulations in order to see The mixing的process and calculate The properties of The blend based on The fractions卷。The effect of The mesh size and time step size are in this type of simulations以来studied The computational biology effort becomes a主要parameter and has to be比如to a minimum。实验数据采取定期time from lending two points in the tank at intervals . to compare the results of the simulations concluding in good agreement。使用计算流体动力学(CFD)的商业代码,在中试和模拟规模的罐中对不同原油进行均质化。这些模型本质上是动态的,因为所有的模拟都是从零时间开始的,在零时间里,原料完全分离,直到最终完全均质化。采用小螺旋搅拌槽和两相模型对搅拌槽进行模拟,观察搅拌过程,根据体积分数计算搅拌槽的性质。研究了网格大小和时间流逝的影响,因为在这种类型的模拟中,计算应力成为一个非常重要的参数,必须最小化。在罐内两个不同时间间隔的实验数据是可用的,与模拟结果有很好的一致性。
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引用次数: 3
Acid hydrolysis of water hyacinth to obtain fermentable sugars 水葫芦的酸水解得到可发酵的糖
Pub Date : 2013-06-01 DOI: 10.29047/01225383.60
J. R. Alfaro, Lizeth Tairina Trujillo Daza, Giselle Arzuaga Lindado, Hader Castaño Peláez, Ángel David Polo Córdoba
In order to take advantage of the aquatic weed water hyacinth (Eichhornia crassipes) as lignocellulosicfeedstock for the production of reducing sugars, a bromatological characterization of the leaves andstems of the plant was performed. Then, the effects of the sulfuric acid concentration (1 - 3% v/v), theconcentration of solids (10 to 12.5% w/v) and the reaction time (15 - 25 min) at 121°C/15 psi in the productionreducing sugars were studied by employing a central composite design. It was found that the acidconcentration was the most significant variable. The optimal conditions were solids 11.25% p/v, H2SO4 2%v/v and 20 minute reaction time. These conditions yielded a concentration of reducing sugars of 33.3 g/L.
为了利用水草水葫芦(Eichhornia crassipes)作为生产还原糖的木质纤维素原料,对该植物的叶子和茎进行了色相学表征。然后,采用中心复合设计,研究了硫酸浓度(1 ~ 3% v/v)、固体浓度(10 ~ 12.5% w/v)和反应时间(15 ~ 25 min)在121℃/15 psi下对生产还原糖的影响。结果表明,酸浓度是最显著的变量。最佳反应条件为固体11.25% p/v, H2SO4 2%v/v,反应时间20 min。这些条件产生的还原糖浓度为33.3 g/L。
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引用次数: 11
PRESSURE TRANSIENT ANALYSIS FOR A RESERVOIR WITH A FINITE-CONDUCTIVITY FAULT 有限导流断层油藏压力瞬态分析
Pub Date : 2013-06-01 DOI: 10.29047/01225383.53
F. Escobar, J. Martínez, Matilde Montealegre-Madero
The signature of the pressure derivative curve for reservoirs with finite-conductivity faults is investigatedto understand their behavior and facilitate the interpretation of pressure data. Once a fault is reachedby the disturbance, the pressure derivative displays a negative unit-slope indicating that the system isconnected to an aquifer, meaning dominance of steady-state flow regime. Afterwards, a half-slope straightlineis displayed on the pressure derivative plot when the flow is linear to the fault. Besides, if simultaneouslya linear flow occurs inside the fault plane, then a bilinear flow regime takes place which is recognized by a1/4 slope line on the pressure derivative line. This paper presents the most complete analytical well pressureanalysis methodology for finite-conductivity faulted systems using some characteristics features and pointsfound on the pressure and pressure derivative log-log plot. Therefore, such plot is not only used as diagnosiscriterion but also as a computational tool. The straight-line conventional analysis is also complemented forcharacterization of finite- and infinite-conductivity faults. Hence, new equations are introduced to estimate thedistance to fault, the fault conductivity and the fault skin factor for such systems. The proposed expressionsand methodology were successfully tested with field and synthetic cases.
研究了具有有限导流性断层的储层压力导数曲线的特征,以了解其行为,并为压力资料的解释提供便利。一旦扰动到达断层,压力导数显示负的单位斜率,表明系统与含水层相连,这意味着稳态流态的优势。然后,当流量与断层成线性时,压力导数图上显示半斜率直线。此外,如果断区内同时发生线性流动,则会出现双线性流动,并由压力导数线上的a1/4斜率线识别。本文利用压力和压力导数对数-对数图上的一些特征和点,提出了有限导电性断裂系统的最完整的解析井压分析方法。因此,这种图不仅可以作为诊断标准,而且可以作为计算工具。直线常规分析也补充了有限和无限导电性故障的表征。因此,引入了新的方程来估计这类系统的断层距离、断层电导率和断层表皮因子。所提出的表达式和方法已成功地通过现场和综合案例进行了验证。
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引用次数: 13
COMPUTATIONAL TOOL FOR MATERIAL BALANCES CONTROL IN NATURAL GAS DISTRIBUTION NETWORK 天然气配电网物料平衡控制的计算工具
Pub Date : 2013-06-01 DOI: 10.29047/01225383.55
Jesús-David Badillo-Herrera, A. Chaves, Jose-Augusto Fuentes-Osorio
In natural gas industry, measurement of process variables allows to assess the quantity and quality of commercialized gas. Nevertheless, since errors, gross and random are always present in measurements, mass and energy balances are not satisfied. This situation leads natural gas distribution companies into invoicing issues. In this paper, a computational tool is proposed, which guarantees that the law of conservation of mass is obeyed by decreasing random error effects and detecting systematic deviations in the measurement equipment (gross errors). This tool is based on Data Reconciliation (DR) and Gross Error Detection (GED) techniques. Different DR and GED methodologies were studied by means of assessment of their advantages and disadvantages. Non-conventional DR and GED methods are proposed as part of the developed tool in order to obtain accurate reconciled results in cases of difficult gross error detections on natural gas distribution systems. The tool was validated by a typical literature problem, and it was then applied to a natural gas distribution network. Results were in agreement with reports of failures of some instruments.
在天然气工业中,过程变量的测量可以评估商品化天然气的数量和质量。然而,由于误差,总误差和随机误差总是存在于测量中,质量和能量平衡不能得到满足。这种情况导致天然气分销公司出现发票问题。本文提出了一种计算工具,通过减少随机误差影响和检测测量设备的系统偏差(粗误差)来保证质量守恒定律的遵守。该工具基于数据协调(DR)和严重错误检测(GED)技术。研究了不同的DR和GED方法,并对其优缺点进行了评价。为了在天然气分配系统粗误差检测困难的情况下获得准确的调和结果,提出了非常规DR和GED方法作为开发工具的一部分。该工具通过一个典型的文献问题进行了验证,然后将其应用于天然气分配网络。结果与一些仪器故障的报告一致。
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引用次数: 1
ENVIRONMENTAL ASSESSMENT OF MICROALGAE BIODIESEL PRODUCTION IN COLOMBIA: COMPARISON OF THREE OIL EXTRACTION SYSTEMS 哥伦比亚微藻生物柴油生产的环境评价:三种榨油系统的比较
Pub Date : 2013-06-01 DOI: 10.29047/01225383.59
Yeniffer Pardo Cárdenas, Israel Herrera Orozco, Á. D. G. Delgado, V. Kafarov
Resumen en: The objective of the study was to compare three cases of biodiesel production from microalgae dried biomass applying the Life Cycle Assessment (LCA) tech...
本研究的目的是比较应用生命周期评估(LCA)技术从微藻干燥生物质生产生物柴油的三种情况。
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引用次数: 29
Effect of biogas enriched with hydrogen on the operation and performance of a diesel-biogas dual engine 富氢沼气对柴油-沼气双发发动机运行和性能的影响
Pub Date : 2013-06-01 DOI: 10.29047/01225383.57
J. Montoya, Karen Paola Cacua Madero, Layrisser Iral Galeano, A. Arrieta
The effect of hydrogen enrichment was tested for a diesel-biogas dual fuel engine. The operation and performancecharacteristics, such as thermal efficiency, pollutant emissions and combustion parameters weredetermined. Experiments have been carried with a stationary compression ignition (CI) engine coupledwith a generator in dual mode using a typical biogas composition of 60% vol. CH4 and 40% vol. CO2. Forevery load engine evaluated, the hydrogen concentration was varied from 5 to 20% H2 v/v. The results showedincreases in peak pressure chamber up to 10.7 bar, and diesel substitution levels up to 80% under conditions ofsteady combustion without knocking. Also, thermal efficiency increases up to 16% and carbon monoxide emissionsdecreases up to 13% at full load, and 20% of hydrogen in engines operating in diesel-biogas dual mode.
对柴油-沼气双燃料发动机进行了富氢效果试验。测定了热效率、污染物排放和燃烧参数等运行性能特征。实验采用固定式压缩点火(CI)发动机与发电机在双模式下耦合进行,使用典型的沼气组成为60% vol. CH4和40% vol. CO2。对于每个负载发动机,氢气浓度在5 ~ 20% H2 v/v之间变化。结果表明,在无爆震的稳定燃烧条件下,峰值压力室增加高达10.7 bar,柴油替代水平高达80%。此外,热效率可提高16%,一氧化碳排放量可减少13%,柴油-沼气双模式下发动机的氢气排放量可减少20%。
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引用次数: 12
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