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The shape-retention and heat-tolerant elastic helix based on azobenzene-polyimide supramolecular assembly 基于偶氮苯-聚酰亚胺超分子组装的保形耐热弹性螺旋
Pub Date : 2023-03-22 DOI: 10.1177/26349833231163893
Shuangwen Li, Yongsheng Cui, Shuai Jia, Song Lin, Lan Gong, Haoran An, Yanrong Sun, Linan Xu
Helical structures are ubiquitous in natural and engineered systems across multiple length scales, while they often exhibit nearly uniform radius and pitch. Utilization of biomimetic structure design to develop stretchable and robust 3D helical structures that are shape-preserving and heat-tolerant is of great interest. Herein, we devise flexible 3D helixes by supramolecular self-assembly and high voltage electric field orientation of molecular chains. The 3D helixes not only inherit buffering mechanics with exceptional shape-retention ability against cyclic stretching but also exhibit excellent heat-resistant quality. The results of the experimental tests confirm that the helix can recover its original shape without obvious residual strain and basically withstand after 2000 cycles under force loading of 10 cN. Such robust biomimetic materials hold great prospects in the fields of artificial muscles, wearable materials, and so on.
螺旋结构在多种长度尺度的自然和工程系统中普遍存在,而它们通常表现出几乎一致的半径和节距。利用仿生结构设计来开发可拉伸和坚固的三维螺旋结构,具有形状保持和耐热性是非常有趣的。在此,我们通过超分子自组装和分子链的高压电场取向来设计柔性三维螺旋。三维螺旋不仅继承了缓冲力学特性,对循环拉伸具有优异的保形能力,而且具有优异的耐热性。实验结果证实,在10cn的力载荷作用下,螺旋可以恢复到原来的形状,没有明显的残余应变,在2000次循环后基本可以承受。这种鲁棒仿生材料在人造肌肉、可穿戴材料等领域有着广阔的应用前景。
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引用次数: 0
Effects of Ag3Sn nanoparticles and isothermal aging on IMC layer growth, mechanical properties, and life prediction of SAC305/Cu solder joints Ag3Sn纳米颗粒和等温时效对SAC305/Cu焊点IMC层生长、力学性能和寿命预测的影响
Pub Date : 2023-03-14 DOI: 10.1177/26349833231163598
Peng Yuan, Dongdong Chen, J. Qin, Hailong Bai, Xin Zhang, G. Gan, C. Leng, Jikang Yan
In this paper, Ag3Sn nanoparticles were prepared by chemical method and added into SAC305 solder in different proportions to explore the effects of the Ag3Sn on the wettability, melting performance, metallographic structure, and mechanical property of the solder. The results show that a small amount of Ag3Sn nanoparticles were able to reduce the wetting time, increase the maximum wetting force, and expand the spreading area. The melting performance was also improved. Ag3Sn nanoparticles were also found to significantly refine the solder structure in the metallographical. The best comprehensive performance was achieved with the addition of 0.5% Ag3Sn nanoparticles. These Ag3Sn nanoparticles effectively improved the morphology of the IMC at the interface and effectively reduced the thickness of the IMC layer. The addition of nano Ag3Sn increased the diffusion activation energy and stabilized the interface. Moreover, the growth of the IMC layer was inhibited by 0.5% Ag3Sn, as indicated by aging results. The addition of Ag3Sn nanoparticles increases the tensile strength and Vickers hardness of the solder joint. When the amount of Ag3Sn nanoparticles was 0.5 wt%, the tensile strength reached the maximum of 17.45 MPa. The microhardness value of the solder is greatly increased, which reaches 311 HV. Finite element simulation showed that the service life of the solder was prolonged by adding the appropriate amount of Ag3Sn nanoparticles. The paper demonstrates a method of “nano” solder paste preparation. Results show that the addition of Ag3Sn nanoparticles plays an important role in the interfacial reaction and mechanical properties between the SAC solder and Cu substrate.
本文采用化学法制备Ag3Sn纳米颗粒,并将其按不同比例添加到SAC305焊料中,探讨Ag3Sn对钎料润湿性、熔化性能、金相组织和力学性能的影响。结果表明:少量的Ag3Sn纳米颗粒能够缩短润湿时间,增大最大润湿力,扩大扩散面积;熔炼性能也得到了改善。在金相分析中还发现Ag3Sn纳米颗粒显著改善了钎料的组织。添加0.5% Ag3Sn纳米粒子时,复合材料的综合性能最好。这些Ag3Sn纳米颗粒有效地改善了界面处IMC的形貌,有效地减小了IMC层的厚度。纳米Ag3Sn的加入提高了扩散活化能,稳定了界面。此外,时效结果表明,0.5% Ag3Sn抑制了IMC层的生长。纳米Ag3Sn的加入提高了焊点的抗拉强度和维氏硬度。当Ag3Sn纳米颗粒添加量为0.5 wt%时,拉伸强度达到最大值17.45 MPa。焊料的显微硬度值大大提高,达到311 HV。有限元模拟结果表明,添加适量的Ag3Sn纳米粒子可以延长焊料的使用寿命。本文介绍了一种“纳米”锡膏的制备方法。结果表明,Ag3Sn纳米粒子的加入对SAC钎料与Cu衬底之间的界面反应和力学性能起着重要作用。
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引用次数: 0
A review of recent developments in structural applications of natural fiber-Reinforced composites (NFRCs) 天然纤维增强复合材料结构应用的最新进展
Pub Date : 2023-03-07 DOI: 10.1177/26349833221147540
Hossein Abdollahiparsa, A. Shahmirzaloo, P. Teuffel, Rijk Blok
Natural fiber-reinforced composites (NFRCs) are expected to find growing applications in near future, especially in Europe where stringent environmental codes are being legislated and public pressure for their enforcement is increasing. Study has shown that NFRCs are also gaining recognition among civil engineers as a viable alternative to traditional materials for use as concrete reinforcement in load-bearing structural members as in building frames and bridge decks. The present review strives to provide a brief overview of NFRCs, state-of-the-art developments in their manufacture, and examples of their structural applications. Another aspect of the review involves investigation of the challenges facing the use of fiber composite materials in civil engineering. These include the high manufacturing costs, difficulties associated with appraisal of its potential benefits, uncertainties about their properties, lack of understanding among civil engineers of the material and its service life, and the relatively small battery of standards developed for the composite industry. Finally, the study will conclude with the prospects of bio-composite applications and the emerging trends in novel bio-composites for future structural applications.
天然纤维增强复合材料(NFRCs)有望在不久的将来找到越来越多的应用,特别是在欧洲,那里正在制定严格的环境法规,公众对其执行的压力也在增加。研究表明,在建筑框架和桥面等承重结构构件中,NFRCs作为一种可行的混凝土加固材料,也得到了土木工程师的认可。本综述努力提供NFRCs的简要概述,其制造的最新发展,以及其结构应用的例子。审查的另一个方面包括调查在土木工程中使用纤维复合材料所面临的挑战。这些问题包括高制造成本,与评估其潜在效益相关的困难,其特性的不确定性,土木工程师对材料及其使用寿命缺乏了解,以及为复合材料工业开发的相对较小的电池标准。最后,对生物复合材料的应用前景和未来结构应用中新型生物复合材料的发展趋势进行了展望。
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引用次数: 7
Research on the technology of flame spraying aluminum coating for composite material 复合材料火焰喷涂镀铝工艺研究
Pub Date : 2023-02-23 DOI: 10.1177/26349833231159145
Q. Guo, Junjun Zhu, C. Li, P. Tang, C. Wen, Lan Liu, Tianze Wang, Yeqin Hu, Yingnan Zhao, M. Zhao, Yulong Feng, Hengyuan Xu, Haizhou Liu
Aluminum coating was prepared on composite material surface by using oxygen-acetylene flame spraying technology. The H01-103H sealants were used to seal the thermal sprayed aluminum coatings. The characteristics of the aluminum coatings with and without H01-103H sealant, including surface morphologies, phase composition, and bonding strength, were investigated by means of SEM, EDS, and mechanical testing machine. Thermal shock experiment and low temperature cooling test were also used to examine the thermal shock resistance and frost resistance of the Al coatings. Electrical conductivity and electromagnetic shielding properties were then tested according to four-probe measurement principle and GJB 5239-2004, respectively. The results showed that the bond strength was 7.36 MPa and the surface porosity was about 5.21% for Al coating without H01-103H sealant, in addition, the H01-103H sealants could fill into the pores, reducing the porosity and increasing the bond strength of the coating. Furthermore, the main component of the coating was Al, the oxygen content was only 1.43%. Flame sprayed aluminum coating, with surface electrical resistance 0.89 mΩ and 5–18 GHz electromagnetic shielding effectiveness above 35 dB, was an ideal candidate for electromagnetic shielding utilization. The Al coating remained intact, compact, no cracks, peeling, layering under 50–200°C and −30°C, which showed good thermal shock resistance and frost resistance.
采用氧乙炔火焰喷涂技术在复合材料表面制备了铝涂层。采用H01-103H密封胶对热喷涂铝涂层进行密封。采用扫描电镜(SEM)、能谱仪(EDS)和力学试验机研究了添加和不添加H01-103H密封胶的铝涂层的表面形貌、相组成和结合强度。通过热冲击试验和低温冷却试验,考察了铝涂层的抗热冲击性能和抗冻性能。然后分别按照四探头测量原理和GJB 5239-2004测试导电性能和电磁屏蔽性能。结果表明:未添加H01-103H密封剂的铝涂层,其结合强度为7.36 MPa,表面孔隙率约为5.21%,且H01-103H密封剂可以填充孔隙,降低孔隙率,提高涂层的结合强度。涂层的主要成分为Al,氧含量仅为1.43%。火焰喷涂铝涂层表面电阻0.89 mΩ, 5-18 GHz的电磁屏蔽效能在35 dB以上,是电磁屏蔽利用的理想候选者。在50-200℃和- 30℃条件下,Al涂层保持完整、致密、无裂纹、剥落、分层,表现出良好的抗热震性和抗冻性。
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引用次数: 0
Perlite microsphere for the use in lightweight cementitious composite 用于轻质胶凝复合材料的珍珠岩微球
Pub Date : 2023-02-13 DOI: 10.1177/26349833231158124
Syed Nasir Shah, Wei Da Cheng, Jeck Kie Kam, Zhi Pin Loh, Z. Ibrahim, K. Mo
This preliminary work explores the possibility of utilizing perlite microsphere (PM) in producing lightweight cementitious composite (LCC). With the use of PM, LCC with dry density of about 1400 kg/m3 (35% reduction in density compared to normal cement mortar) can be obtained. Satisfactory compressive strengths of 32.6–34.5 MPa could be attained by the PM LCC, without and with supplementary cementitious materials such as silica fume and ground granulated blast furnace slag. The specific strength (compressive strength/density ratio) of LCC was also similar as the normal cement mortar. In addition, there was little difference in the flexural strength and drying shrinkage of PM LCC compared to normal cement mortar. Furthermore, similar flexural load–displacement behaviour was found between thin plate specimens produced with alkali-resistant glass fibre mesh reinforced LCC and that of normal cement mortar. In overall, this suggests that PM has the potential to be utilized as lightweight filler in producing LCC.
本文初步探讨了利用珍珠岩微球(PM)生产轻质胶凝复合材料(LCC)的可能性。使用PM可获得干密度约为1400 kg/m3的LCC(比普通水泥砂浆密度降低35%)。在不添加和添加硅灰、磨粒矿渣等胶凝材料的情况下,PM LCC的抗压强度可达32.6 ~ 34.5 MPa。LCC的比强度(抗压强度/密度比)也与普通水泥砂浆相似。此外,PM LCC的抗弯强度和干收缩率与普通水泥砂浆相比差异不大。此外,用耐碱玻璃纤维网增强LCC制作的薄板试件与普通水泥砂浆制作的薄板试件之间发现了相似的弯曲荷载-位移行为。总的来说,这表明PM有潜力被用作生产LCC的轻质填料。
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引用次数: 0
High-throughput 3D printing of continuous carbon fiber–reinforced PA6/PP/MAPP composite by a multifilament feeder 用多丝给料机高通量3D打印连续碳纤维增强PA6/PP/MAPP复合材料
Pub Date : 2023-02-12 DOI: 10.1177/26349833231158395
M. Ueda, Daisuke Nakayama, N. Katsuta, M. Okoshi
A multifilament feeder was developed to achieve the high-throughput 3D printing of continuous carbon fiber–reinforced thermoplastic composites. Four filaments were supplied to the feeder and simultaneously printed by controlling the feeding speeds to quadruple the manufacturing volume. A water-resistant filament was also developed by the polymer blending of polyamide 6 (PA6) and polypropylene (PP), which provided good adhesion to the carbon fibers and water resistance, respectively. The polymer structure in the continuous carbon fiber–reinforced thermoplastic composites was characterized by scanning electron microscopy and energy-dispersive X-ray spectroscopy. The multilayer polymer structure was observed, which enhanced the water-resistant property. The bending test results revealed that the blending minimized the degradation of the flexural modulus of the 3D-printed unidirectional carbon fiber–reinforced thermoplastic composite under wet conditions.
为实现连续碳纤维增强热塑性复合材料的高通量3D打印,研制了一种多丝给料机。通过控制进料速度,将四根细丝送入给料器并同时打印,使制造量增加四倍。聚酰胺6 (PA6)和聚丙烯(PP)的共混制备了防水长丝,它们对碳纤维具有良好的附着力和耐水性。采用扫描电镜和x射线能谱对连续碳纤维增强热塑性复合材料中的聚合物结构进行了表征。观察到多层聚合物结构,增强了防水性能。弯曲试验结果表明,共混使3d打印单向碳纤维增强热塑性复合材料在潮湿条件下的弯曲模量退化最小化。
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引用次数: 0
Investigation of mechanical characterization of hybrid sandwich composites with syntactic foam core for structural applications 结构用复合泡沫芯夹层复合材料力学性能研究
Pub Date : 2023-01-30 DOI: 10.1177/26349833221147539
O. Afolabi, K. Kanny, T. Mohan
In this work, mechanical performance on sandwich composites consisting of syntactic foam filled with hollow glass microsphere in an epoxy resin matrix as the core material and hybrid kenaf/glass fibers face-sheet based composites panel is studied. The main purpose of this work is to design a suitable lightweight composite panel material for structural application. Four different sequences of face-sheet reinforcement (e.g., kenaf-kenaf; glass-glass; glass-kenaf, and kenaf-glass) were adopted. In this study, the mechanical properties and failure modes are carefully investigated. The sandwich composites were characterized by compressive, tensile, and flexural properties. The results showed that compressive strength was highest at the “kenaf-glass” face-sheets, tensile strength was highest at “glass-glass” face-sheets, and flexural at “glass-glass” face-sheets with 52.1%, 67.6%, and 74.4% increase to “kenaf-kenaf” face-sheets, respectively. The tensile strength and modulus values with the specific strengths and modulus values showed that the mechanical properties of the sandwich composites can be influenced by hybridizing the face-sheet laminates of the composite. This shows that kenaf fiber has limited strength when used as reinforcement alone but gave an excellent performance when combined with glass fiber.
本文研究了以环氧树脂为核心材料填充中空玻璃微球的复合泡沫材料和红麻/玻璃纤维复合材料面板的复合材料夹层的力学性能。本工作的主要目的是设计一种适合结构应用的轻质复合板材料。四种不同的面板增强序列(例如,红麻-红麻;glass-glass;采用玻璃-红麻和红麻-玻璃。在这项研究中,仔细研究了力学性能和破坏模式。该夹层复合材料具有压缩、拉伸和弯曲性能。结果表明:“红麻-玻璃”面板抗压强度最高,“玻璃-玻璃”面板抗拉强度最高,“玻璃-玻璃”面板抗折强度分别比“红麻-红麻”面板提高52.1%、67.6%和74.4%;拉伸强度和模量值与比强度和模量值的对比表明,复合材料表面层板的杂化会影响复合材料的力学性能。说明红麻纤维单独用作增强材料时强度有限,但与玻璃纤维结合使用时性能优异。
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引用次数: 1
Improving climate resilience: Reduced-order mechanical modelling of a temperature-adaptable sun protection facade system 提高气候适应能力:温度适应性遮阳立面系统的降阶力学建模
Pub Date : 2023-01-27 DOI: 10.1177/26349833221144058
Yating Ou, Maxie Schneider, Alexander Hückler, A. Köllner, C. Völlmecke
Analytical models to describe the mechanical behaviour of an adaptive sun protection facade system (Adaptex) are presented. First, a one-dimensional (1D) rigid link model is developed. Stretching and bending deformation of textile bands are represented with the aid of extensional and rotational springs respectively. The model is described by two generalized coordinates only. The second analytical model employs a continuous description based on the Kirchhoff plate theory. The Rayleigh–Ritz method is applied to analyse the deformation behaviour of the textile bands. In comparison with the experimental results, it can be found that the continuous model simulates the real deformation of the facade system, thus its morphological behaviour, very effectively. The results of a parametric study indicate that the stiffness of the textile bands, the geometric dimensions and the position of load application have significant effects on the deformation behaviour.
介绍了自适应遮阳立面系统(Adaptex)的力学性能分析模型。首先,建立了一维刚性连杆模型。用拉伸弹簧和旋转弹簧分别表示织物带的拉伸变形和弯曲变形。该模型仅用两个广义坐标来描述。第二个分析模型采用基于基尔霍夫板理论的连续描述。采用瑞利-里兹法分析了织物带的变形行为。通过与实验结果的比较,可以发现连续模型非常有效地模拟了立面系统的真实变形,从而模拟了立面系统的形态行为。参数化研究结果表明,织物带的刚度、几何尺寸和施加载荷的位置对织物带的变形行为有显著影响。
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引用次数: 0
Kriging and local climate zones – key to higher accuracy in range prediction? 克里格和当地气候带——提高距离预测精度的关键?
Pub Date : 2023-01-26 DOI: 10.1177/26349833221149448
Thomas Herzlieb, Johannes H. L. Sturm
Range prediction of electric vehicles requires knowledge of many parameters, including information about the vehicle environment. As an alternative to onboard measurement, external data sources (secondary data) can be used. The presented methods are suitable for estimating climatic data for vehicle application including urban areas and areas of complex topography. Compared to an inverse distance weighting approach for ambient temperature values, Kriging yields better overall accuracy especially for areas of complex topography, improving accuracy in urban regions, however, remains a challenge. An approach to improve accuracy in urban areas by considering local climate zones in the selection of secondary data sources produces mixed results.
电动汽车的里程预测需要了解许多参数,包括车辆环境信息。作为机载测量的替代方案,可以使用外部数据源(辅助数据)。本文提出的方法适用于城市地区和地形复杂地区的车辆气候数据估计。与环境温度值的逆距离加权方法相比,Kriging方法的总体精度更高,特别是在复杂地形地区,然而,提高城市地区的精度仍然是一个挑战。在选择次要数据源时考虑当地气候带以提高城市地区精度的方法产生了不同的结果。
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引用次数: 0
Artificial neural network–based constitutive relation modelling for the laminated fabric used in stratospheric airship 基于人工神经网络的平流层飞艇层合织物本构关系建模
Pub Date : 2022-01-27 DOI: 10.1177/26349833211073146
Minjun Gao, Junhui Meng, Nuo Ma, Moning Li, Li Liu
There have been gradually increasing interests in the stratospheric airship (SSA) as a cost-effective alternative to earth orbit satellites for telecommunication and high-resolution earth observation. Lightweight and high strength envelopes are the keys to the design of SSAs as it directly determines the endurance flight performance and loading deformation characteristics of the airship. Typical SSA envelope material is a laminated fabric, which is composed of fabric layer and other functional layers. Compared with conventional composite structures, the laminated fabric has complex nonlinear mechanical characteristics. Artificial neural network (ANN) has good processing ability to nonlinear information so that it is suitable to model the constitutive relation of laminated fabrics. In this work, an ANN based on the Scaled Conjugate Gradient (SCG) algorithm is proposed firstly to model the constitutive relation of fabric Uretek3216LV. Considering significant errors of the SCG ANN results, the network model is optimized through methods of selecting the number of hidden-layer nodes and training algorithms. Results show that the improved network model based on Bayesian Regularization (BR) algorithm and eight nodes of single hidden layer can better describe the constitutive relation of the laminated fabric than other conventional training algorithms. The proposed constitutive modelling method with ANN is expected to gain a deeper understanding of the mechanical mechanism and guide structural design of envelope material in further work.
人们对平流层飞艇(SSA)作为一种具有成本效益的替代地球轨道卫星进行电信和高分辨率地球观测的方法的兴趣逐渐增加。轻量化、高强度的包壳结构直接决定着飞艇的持久飞行性能和载荷变形特性,是SSAs设计的关键。典型的SSA包封材料是由织物层和其他功能层组成的层压织物。与传统复合材料结构相比,层压织物具有复杂的非线性力学特性。人工神经网络对非线性信息具有良好的处理能力,适合于层叠织物的本构关系建模。本文首先提出了一种基于缩放共轭梯度(SCG)算法的人工神经网络,对织物Uretek3216LV的本构关系进行建模。考虑到SCG神经网络结果误差较大,通过选择隐藏层节点数和训练算法对网络模型进行优化。结果表明,基于贝叶斯正则化(BR)算法和单隐层8个节点的改进网络模型比其他常规训练算法能更好地描述层状织物的本构关系。本文提出的基于人工神经网络的本构建模方法有望在进一步的工作中对围护结构材料的力学机理和结构设计有更深入的了解。
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引用次数: 1
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Composites and Advanced Materials
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