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Effect of sizing agent on interfacial properties of carbon fiber-reinforced PMMA composite 施胶剂对碳纤维增强PMMA复合材料界面性能的影响
Pub Date : 2021-01-01 DOI: 10.1177/2633366X20978657
Liang Jian
The surface treatment of carbon fibers (CFs) was carried out using a self-synthesized sizing agent. The effects of sizing agent on the surface of CFs and the interface properties of CF/polymethyl methacrylate (PMMA) composites were mainly studied. Scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and static contact angle were used to compare and study the CFs before and after the surface treatment, including surface morphology, surface chemical element composition, and wettability of the surface. The influence of sizing agent on the mechanical properties of CF/PMMA resin composite interface was investigated. The results show that after sizing treatment, the CF surface O/C value increased by 35.1% and the contact angles of CF and resin decreased by 16.2%. The interfacial shear strength and interlayer shear strength increased by 12.6%.
采用自合成的施胶剂对碳纤维进行了表面处理。主要研究了施胶剂对碳纤维表面的影响以及碳纤维/聚甲基丙烯酸甲酯(PMMA)复合材料的界面性能。采用扫描电镜、傅里叶变换红外光谱、x射线光电子能谱、静态接触角等方法对表面处理前后的碳纤维进行比较研究,包括表面形貌、表面化学元素组成、表面润湿性等。研究了施胶剂对CF/PMMA树脂复合界面力学性能的影响。结果表明:施胶处理后,CF表面O/C值提高了35.1%,CF与树脂的接触角降低了16.2%;界面抗剪强度和层间抗剪强度提高12.6%。
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引用次数: 5
Coupling mechanism of highly nonlinear solitary waves with damaged composite material plates 高度非线性孤立波与损伤复合材料板的耦合机理
Pub Date : 2021-01-01 DOI: 10.1177/2633366X20928088
Jie Zhao, Y. Wang, Hao Wu, Miao Ruan
The coupling interaction between nonlinear solitary waves in one-dimensional granular chains and damaged composite material plates is considered. Based on Hertz contact law and meso-mechanical model of stiffness reduction of composite material plates when the fiber breakage is the main damage mode, the coupled differential equations of particle chains and damaged composite material plates are derived. By solving the differential equations with Runge–Kutta method to get the velocity and displacement curves of particles and analyzing the delays and amplitude ratios of reflected waves, it is found that the damage quantity, fiber volume fraction, and thickness of damaged composite material plates as well as gravity have an effect on solitary waves. The preliminary research results provide a theoretical basis for nondestructive testing of damaged composite material plates by using solitary waves.
考虑了一维颗粒链中非线性孤立波与复合材料损伤板之间的耦合相互作用。基于赫兹接触定律和纤维断裂为主要损伤方式时复合材料板刚度降低细观力学模型,推导了颗粒链与复合材料板损伤的耦合微分方程。利用龙格-库塔法求解微分方程,得到颗粒的速度和位移曲线,分析反射波的延迟和振幅比,发现损伤量、纤维体积分数、损伤复合材料板的厚度以及重力对孤立波有影响。初步研究结果为利用孤立波对复合材料损伤板进行无损检测提供了理论依据。
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引用次数: 0
Effect of processing temperatures on the thermal and mechanical properties of leather waste-ABS composites 加工温度对废皮革- abs复合材料热力学性能的影响
Pub Date : 2021-01-01 DOI: 10.1177/26349833211060056
M. M. Owen, E. O. Achukwu, I. Arukalam, Mustakimah Muhammad, A. Z. Romli
The effect of varying processing temperatures (200, 220 and 240°C) on the thermal and mechanical properties of uncoated and epoxy-coated chrome-tanned leather wastes-ABS composites has been studied. The results obtained showed that the mechanical properties of the composites decreased as the processing temperature increased. Epoxy-coated leather wastes fibre-ABS (CLWABS) composite yielded better mechanical properties compared to the uncoated leather wastes-ABS composite (LWABS). These results were obtained at an optimized processing temperature of 200°C. Furthermore, the results were confirmed by the field emission scanning electron microscopy (FESEM) studies. The differential scanning calorimetry (DSC) studies revealed that the epoxy-coated leather wastes fibres (CLW) showed higher onset and melting temperatures of 131.8 and 179.35°C than the uncoated leather wastes fibres (LW) with glass transition (Tg) and melting (Tm) temperatures of 128.2 and 169.4°C, respectively. When the LW and CLW fibres were mixed with Acrylonitrile butadiene styrene (ABS), the Tg and Tm of CLWABS composite were found to be 94.9 and 269.8°C, respectively, higher than the LWABS composite with Tg and Tm of 89.1 and 261.6°C, respectively. Thus, this study has demonstrated that utilization of epoxy-coated chrome-tanned leather wastes fibres as fillers in the design of ABS-based composites will help a great deal in addressing the problem of solid waste pollutants in our environment.
研究了不同处理温度(200、220和240℃)对未涂覆和环氧涂覆铬鞣废皮革- abs复合材料热性能和力学性能的影响。结果表明,复合材料的力学性能随加工温度的升高而降低。环氧包覆皮革废料纤维- abs复合材料(CLWABS)的力学性能优于未包覆皮革废料- abs复合材料(LWABS)。这些结果是在200℃的最佳加工温度下得到的。此外,通过场发射扫描电镜(FESEM)研究证实了这一结果。差示扫描量热(DSC)研究表明,涂覆环氧树脂的废皮纤维(CLW)的起始温度和熔融温度分别为131.8和179.35℃,高于未涂覆环氧树脂的废皮纤维(LW),其玻璃化转变温度(Tg)和熔融温度(Tm)分别为128.2和169.4℃。当LW和CLW纤维与丙烯腈-丁二烯-苯乙烯(ABS)混合时,CLWABS复合材料的Tg和Tm分别为94.9和269.8℃,高于Tg和Tm分别为89.1和261.6℃的LWABS复合材料。因此,本研究表明,利用环氧涂层铬鞣皮革废料纤维作为abs基复合材料的填料,将有助于解决我们环境中的固体废物污染物问题。
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引用次数: 2
Optimization of molding process parameters for CF/PEEK composites based on Taguchi method 基于田口法的CF/PEEK复合材料成型工艺参数优化
Pub Date : 2021-01-01 DOI: 10.1177/26349833211001882
Guangming Dai, L. Zhan, Chenglong Guan, Minghui Huang
In this article, nine groups of laminates were prepared according to the Taguchi L9(33) test array to study the influence of three process parameters, including molding pressure, molding temperature, and holding time on the performance of unidirectional carbon fiber/polyetheretherketone (CF/PEEK) laminates. A differential scanning calorimetry test was employed to select a reasonable process parameters range. The transverse tensile strength of the laminates was measured, and the fiber–matrix interfacial bonding behavior of the tested samples was analyzed by scanning electron microscopy. The results showed that the significance of factors to transverse tensile strength were molding temperature, holding time, and molding pressure in sequence. The optimal molding process parameters for CF/PEEK composite laminate were molding temperature of 400°C, molding pressure of 3 MPa, and holding time of 30 min. The optimization results were meaningful for the extension and application of thermoplastic composites.
本文采用田口L9(33)测试阵列制备了9组层压板,研究了成型压力、成型温度、保温时间3个工艺参数对单向碳纤维/聚醚酮(CF/PEEK)层压板性能的影响。采用差示扫描量热法选择合理的工艺参数范围。测量了复合材料的横向拉伸强度,并通过扫描电镜分析了复合材料的纤维-基体界面结合行为。结果表明,影响横向拉伸强度的因素依次为成型温度、保温时间、成型压力。CF/PEEK复合材料层合板的最佳成型工艺参数为成型温度400℃、成型压力3 MPa、保温时间30 min。优化结果对热塑性复合材料的推广应用具有重要意义。
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引用次数: 5
Assessing the performance of electrospun nanofabrics as potential interlayer reinforcement materials for fiber-reinforced polymers 静电纺丝纳米织物作为纤维增强聚合物层间增强材料的性能评价
Pub Date : 2021-01-01 DOI: 10.1177/26349833211002519
Katerina Loizou, A. Evangelou, O. Marangos, L. Koutsokeras, Iouliana Chrysafi, Stylianos Yiatros, G. Constantinides, S. Zaoutsos, Vassilis Drakonakis
Multiscale-reinforced polymers offer enhanced functionality due to the three different scales that are incorporated; microfiber, nanofiber, and nanoparticle. This work aims to investigate the applicability of different polymer-based nanofabrics, fabricated via electrospinning as reinforcement interlayers for multilayer-fiber-reinforced polymer composites. Three different polymers are examined; polyamide 6, polyacrylonitrile, and polyvinylidene fluoride, both plain and doped with multiwalled carbon nanotubes (MWCNTs). The effect of nanotube concentration on the properties of the resulting nanofabrics is also examined. Nine different nanofabric systems are prepared. The stress–strain behavior of the different nanofabric systems, which are eventually used as reinforcement interlayers, is investigated to assess the enhancement of the mechanical properties and to evaluate their potential as interlayer reinforcements. Scanning electron microscopy is employed to visualize the morphology and microstructure of the electrospun nanofabrics. The thermal behavior of the nanofabrics is investigated via differential scanning calorimetry to elucidate the glass and melting point of the nanofabrics, which can be used to identify optimum processing parameters at composite level. Introduction of MWCNTs appears to augment the mechanical response of the polymer nanofabrics. Examination of the mechanical performance of these interlayer reinforcements after heat treatment above the glass transition temperature reveals that morphological and microstructural changes can promote further enhancement of the mechanical response.
多尺度增强聚合物提供增强的功能,由于三个不同的尺度纳入;超纤维,纳米纤维和纳米颗粒。本研究旨在探讨静电纺丝制备的不同聚合物基纳米织物作为多层纤维增强聚合物复合材料的增强中间层的适用性。研究了三种不同的聚合物;聚酰胺6、聚丙烯腈和聚偏氟乙烯,包括普通的和掺杂多壁碳纳米管(MWCNTs)的。研究了纳米管浓度对纳米织物性能的影响。制备了9种不同的纳米织物体系。研究了不同纳米织物体系的应力-应变行为,以评估其作为增强夹层的力学性能增强和潜力。采用扫描电子显微镜对静电纺丝纳米织物的形貌和微观结构进行了观察。采用差示扫描量热法研究了纳米织物的热行为,阐明了纳米织物的玻璃点和熔点,可用于确定复合材料水平的最佳工艺参数。引入MWCNTs似乎增强了聚合物纳米织物的机械响应。在玻璃化转变温度以上热处理后,对这些层间增强材料的力学性能进行了测试,结果表明,形貌和微观结构的变化可以促进力学响应的进一步增强。
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引用次数: 3
Improving the structural and physical properties of boric acid-doped rigid polyurethane materials 改善掺硼酸硬质聚氨酯材料的结构和物理性能
Pub Date : 2021-01-01 DOI: 10.1177/26349833211010819
İbrahim Kırbaş
In this study, the internal structure and physical properties of boric acid-doped rigid polyurethane (PU) materials were investigated. 5%, 10%, and 15% of boric acid were added into PU material compared to the total mass. These rigid PUs were subjected to scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, thermal conductivity, and density determination for analysis. Boric acid addition resulted in a decrease of 57.2% in thermal conductivity and 67.8% in density compared to raw PU material. It has been shown that it provides support for the formation of cell structure. In addition to, it is also found that there are no impurity atoms in the structure and the structure is formed in the tetragonal phase.
研究了硼酸掺杂硬质聚氨酯(PU)材料的内部结构和物理性能。聚氨酯材料中硼酸的添加量分别为总质量的5%、10%和15%。采用扫描电子显微镜、能量色散x射线光谱、x射线衍射、傅里叶变换红外光谱、热导率和密度测定等方法对刚性pu进行分析。与PU原料相比,硼酸的加入使其导热系数降低57.2%,密度降低67.8%。研究表明,它为细胞结构的形成提供了支持。此外,还发现结构中没有杂质原子,结构形成于四方相中。
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引用次数: 4
Investigation of deformation behavior of PETG-FDM-printed metamaterials with pantographic substructures based on different slicing strategies 基于不同切片策略的pet - fdm打印受电弓子结构超材料变形行为研究
Pub Date : 2021-01-01 DOI: 10.1177/26349833211016477
A. Özen, G. Ganzosch, E. Barchiesi, D. Auhl, W. Müller
Based on the progress and advances of additive manufacturing technologies, design and production of complex structures became cheaper and therefore rather possible in the recent past. A promising example of such complex structure is a so-called pantographic structure, which can be described as a metamaterial consisting of repeated substructure. In this substructure, two planes, which consist of two arrays of beams being orthogonally aligned to each other, are interconnected by cylinders/pivots. Different inner geometries were taken into account and additively manufactured by means of fused deposition modeling technique using polyethylene terephthalate glycol (PETG) as filament material. To further understand the effect of different manufacturing parameters on the mechanical deformation behavior, three types of specimens have been investigated by means of displacement-controlled extension tests. Different slicing approaches were implemented to eliminate process-related problems. Small and large deformations are investigated separately. Furthermore, 2D digital image correlation was used to calculate strains on the outer surface of the metamaterial. Two finite-element simulations based on linear elastic isotropic model and linear elastic transverse isotropic model have been carried out for small deformations. Standardized extension tests have been performed on 3D-printed PETG according to ISO 527-2. Results obtained from finite-element method have been validated by experimental results of small deformations. These results are in good agreement with linear elastic transverse isotropic model (up to about ε x x = 1.2 % of axial elongation), though the response of large deformations indicates a nonlinear inelastic material behavior. Nevertheless, all samples are able to withstand outer loading conditions after the first rupture, resulting in resilience against ultimate failure.
基于增材制造技术的进步和进步,复杂结构的设计和生产变得更便宜,因此在最近的过去变得相当可能。这种复杂结构的一个有希望的例子是所谓的受电弓结构,它可以被描述为由重复子结构组成的超材料。在这个子结构中,两个平面由两个相互正交排列的梁阵列组成,通过圆柱体/枢轴相互连接。以聚对苯二甲酸乙二醇酯(PETG)为长丝材料,考虑不同的内部几何形状,采用熔融沉积建模技术进行增材制造。为进一步了解不同加工参数对试件力学变形行为的影响,采用位移控制拉伸试验对三种试件进行了研究。实现了不同的切片方法来消除与过程相关的问题。小变形和大变形分别进行了研究。此外,利用二维数字图像相关技术计算了超材料外表面的应变。基于线弹性各向同性模型和线弹性横向各向同性模型对小变形进行了有限元模拟。根据ISO 527-2,对3d打印PETG进行了标准化延伸测试。小变形试验结果验证了有限元计算结果。这些结果与线性弹性横向各向同性模型(高达约ε x x = 1.2%的轴向伸长率)很好地一致,尽管大变形的响应表明非线性非弹性材料行为。然而,所有的样品都能够承受第一次破裂后的外部加载条件,从而产生抗最终破坏的弹性。
{"title":"Investigation of deformation behavior of PETG-FDM-printed metamaterials with pantographic substructures based on different slicing strategies","authors":"A. Özen, G. Ganzosch, E. Barchiesi, D. Auhl, W. Müller","doi":"10.1177/26349833211016477","DOIUrl":"https://doi.org/10.1177/26349833211016477","url":null,"abstract":"Based on the progress and advances of additive manufacturing technologies, design and production of complex structures became cheaper and therefore rather possible in the recent past. A promising example of such complex structure is a so-called pantographic structure, which can be described as a metamaterial consisting of repeated substructure. In this substructure, two planes, which consist of two arrays of beams being orthogonally aligned to each other, are interconnected by cylinders/pivots. Different inner geometries were taken into account and additively manufactured by means of fused deposition modeling technique using polyethylene terephthalate glycol (PETG) as filament material. To further understand the effect of different manufacturing parameters on the mechanical deformation behavior, three types of specimens have been investigated by means of displacement-controlled extension tests. Different slicing approaches were implemented to eliminate process-related problems. Small and large deformations are investigated separately. Furthermore, 2D digital image correlation was used to calculate strains on the outer surface of the metamaterial. Two finite-element simulations based on linear elastic isotropic model and linear elastic transverse isotropic model have been carried out for small deformations. Standardized extension tests have been performed on 3D-printed PETG according to ISO 527-2. Results obtained from finite-element method have been validated by experimental results of small deformations. These results are in good agreement with linear elastic transverse isotropic model (up to about ε x x = 1.2 % of axial elongation), though the response of large deformations indicates a nonlinear inelastic material behavior. Nevertheless, all samples are able to withstand outer loading conditions after the first rupture, resulting in resilience against ultimate failure.","PeriodicalId":10608,"journal":{"name":"Composites and Advanced Materials","volume":"98 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86053363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 10
Smart materials for changing the electrical properties of nanostructures 改变纳米结构电性能的智能材料
Pub Date : 2021-01-01 DOI: 10.1177/26349833211016479
M. Abbas
Smart materials have an important role in modern applications. They have contributed to improving various applications in several fields. One of the areas most affected by the improvement of smart materials is nanostructures. These materials are created by basic techniques, such as arrangement manipulation. Significant efforts have been made to enhance smart materials so that they resemble natural materials in terms of accuracy, design, and utility. Here, a review of the latest research on smart materials that can alter the electrical properties of nanostructures is presented. The main objective of this review is to introduce the role of smart materials in controlling the electrical performance of nanostructures. Furthermore, this review proposes an analysis of the integration and cooperation of previous research, such as the use of a piezoelectric motor in the design of structural magnetic nanodevices to control these devices. Piezoelectric actuators can also be used to develop a new method for controlling PV modulators for fabricating a single-wall nanotube. This new proposal could alter the properties of many nanoscale systems serving several medical and engineering fields. Moreover, this review proposes a novel methodology for nanocoating by introducing an antireflective coating with multiple layers. This method can effectively enhance the functions of the nanoscale coating.
智能材料在现代应用中具有重要的作用。他们为改善几个领域的各种应用做出了贡献。受智能材料改进影响最大的领域之一是纳米结构。这些材料是由基本的技术创造的,比如排列操作。人们已经做出了巨大的努力来提高智能材料,使它们在精度、设计和实用性方面与天然材料相似。本文综述了智能材料在改变纳米结构电性能方面的最新研究进展。本文的主要目的是介绍智能材料在控制纳米结构电性能方面的作用。此外,本文还对以往研究的整合与合作进行了分析,例如在结构磁性纳米器件的设计中使用压电电机来控制这些器件。压电致动器也可以用来开发一种新的方法来控制PV调制器,用于制造单壁纳米管。这项新提议可能会改变许多纳米系统的性质,这些系统服务于多个医学和工程领域。此外,本文还提出了一种新的纳米涂层方法,即引入多层抗反射涂层。该方法可以有效地增强纳米涂层的功能。
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引用次数: 6
The performance of titanium composite coatings obtained through thermal spraying and microarc oxidation 研究了热喷涂和微弧氧化制备的钛复合涂层的性能
Pub Date : 2021-01-01 DOI: 10.1177/2633366X20974686
C-C. Huang, HM Li, DH Li, SY Lin
The development of composite coatings essential to improve the wear and corrosion resistances of the materials employed in numerous applications, such as automobile, chemical, medicine, construction, aerospace, and biomedical industries. In this study, we presented a double-layer coating technique, which consisted of a thermal-sprayed titanium (Ti) layer and a micro-arc oxidation (MAO) film on AISI 1020 steel. The effect of the composite coatings (Ti/MAO) on wear and corrosion resistance was investigated. To obtain a coating thickness from 250 µm to 450 µm, the prepared specimens were coated with Ti (99.9% pure) by arc spraying. Then, the Ti/MAO films were deposited on Ti coatings. The current density of MAO was fixed at 35 A/dm2, the voltages were 250, 300, 350, 400, and 450 V, and the duration of the MAO process was 10 min, Measurements of film thickness, microstructure, microhardness, X-ray diffractometry analysis, and scanning electron microscopic observation were performed for determining the characteristics of the composite coatings (Ti/MAO). Potentiodynamic polarization curves were used to compare the corrosion resistance of these composite coatings. A ball-on-disc wear test, using an oscillation friction wear tester, was carried out at room temperature according to the ASTM G99 standard to determine the wear resistance. Among all the specimens, Ti/MAO (400 V) had the greatest hardness, lowest friction coefficient, least weight loss, and longest sliding distance. The sliding distance of Ti/MAO (400 V) was about 1.7 times higher than those of Ti. The open-circuit potential of Ti/MAO (400 V) was about 1.7 times better than those of Ti. The corrosion currents of Ti/MAO (250 V) and Ti/MAO (400 V) were decreased by MAO about 95% and 92%, respectively. Although the corrosion current of Ti/MAO (400 V) was higher than that of Ti/MAO (250 V), Ti/MAO (400 V) had better effects in other tests. According to the results, Ti/MAO (400 V) presented the best performance among all the specimens and provided improved protection to both Ti and substrate.
复合涂层的发展对于提高汽车、化工、医药、建筑、航空航天和生物医学等众多应用中所用材料的耐磨损和耐腐蚀性至关重要。为了获得250µm ~ 450µm的涂层厚度,采用电弧喷涂方法对制备好的试样进行了99.9%纯度的Ti涂层。利用动电位极化曲线比较了复合镀层的耐蚀性。根据ASTM G99标准,在室温下使用振荡摩擦磨损试验机进行球盘磨损试验,以确定耐磨性。
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引用次数: 3
Study on the simulation of annular axis braiding process and braiding angles’ prediction method 环轴编织过程仿真及编织角预测方法研究
Pub Date : 2021-01-01 DOI: 10.1177/26349833211010814
Xi Wang, Guoli Zhang, Xiaoping Shi, Ce Zhang
A common braiding machine cannot perform continuous braiding using closed annular axis mandrels. To solve this problem, a modified vertical braiding machine was made to braid composite preforms with irregular cross-section mandrels. The finite element method was used to simulate the braiding process, and an efficient method was also derived to predict the braiding angles. The results show that the predicted braiding angles are basically consistent with the actual braiding angles, and the braiding angles at distinctive locations on the braided preform recorded differences of up to 10° or more than 30%. Braiding process simulation via the finite element method can thus effectively and vividly reflect the yarn path on the preform. As such, the braiding angles on the braided preforms can be realized through projection and surface flattening with much better accuracy. It also resolves the difficult problem often faced in measuring the braiding angles at the corner of the mandrel and provides a solid basis for continued research on the performance of its composite reinforcement.
普通编织机不能使用封闭的环形轴芯轴进行连续编织。为解决这一问题,研制了一种改进型立式编织机,用于不规则截面芯棒复合预制件的编织机。采用有限元法对编织过程进行模拟,并推导出一种有效的编织角预测方法。结果表明,预测的编织角与实际的编织角基本一致,在编织预制件上不同位置的编织角相差达10°或30%以上。利用有限元方法对编织过程进行模拟,可以有效、形象地反映纱线在预坯上的运动轨迹。因此,可以通过投影和表面平坦来实现编织预制件上的编织角,精度更高。解决了芯轴角编织角测量中经常遇到的难题,为进一步研究其复合增强材料的性能提供了坚实的基础。
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引用次数: 2
期刊
Composites and Advanced Materials
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