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Tetrahydrofuran-Assisted Transesterification Biodiesel from Waste Cooking Oil 废弃食用油四氢呋喃辅助酯交换制备生物柴油
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2015.00009.4
A. Chauhan, V. Singh, Y. Kwatra
Base-catalysed transesterification of waste cooking oil for the production of biodiesel was assisted by the addition of co-solvent tetrahydrofuran (THF). In addition to lowering of reaction temperature and reduction in reaction time for transesterification, THF facilitated production of methyl ester in a single phase. THF-assisted base-catalysed reaction was optimised for various parameters. Maximum biodiesel production (92.8%) was obtained with 4% THF, 0.6% sodium methoxide (catalyst), 6:1 methanol-to-oil ratio, 45 min reaction time and 50°C reaction temperature. Added to this, maximum glycerol recovery (18.62%) was obtained at 50°C using lower concentrations of THF (2%). Use of THF highlights even more economically viable and greener potential for biodiesel production as this co-solvent is non-toxic, un-reactive and of biomass origin.
用四氢呋喃(THF)作为辅助溶剂,催化废食用油酯交换制备生物柴油。除了降低反应温度和缩短酯交换反应时间外,四氢呋喃还有助于在单相中生成甲酯。对thf辅助碱催化反应的各参数进行了优化。在4%四氢呋喃、0.6%甲醇钠(催化剂)、6:1醇油比、反应时间45 min、反应温度50℃的条件下,生物柴油的最大产率为92.8%。此外,使用较低浓度的THF(2%),在50°C下获得最大甘油回收率(18.62%)。四氢呋喃的使用凸显了生物柴油生产更具经济可行性和更环保的潜力,因为这种共溶剂无毒、不反应,而且来自生物质。
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引用次数: 0
Different Models of Reactors for Biodiesel Production: A Review 生物柴油生产反应器的研究进展
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2019.00010.2
C. S. Singh, Tejaswi Mayank, Mandeep Sharma, N. Malik
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引用次数: 0
Extraction of Crude Rubber Oil from Rubber Seed and Production of Biodiesel 橡胶籽中粗橡胶油的提取及生物柴油的生产
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2014.00003.8
M. Hossain, Moniruzzaman, S. Sujan, Mosharof Hossain, Jamal
Biodiesel is a mono alkyl ester of long chain fatty acids derived from renewable feed stocks, such as vegetable oils or animal fats, for using in compression ignition engine. Studies were carried out to extract non-edible crude rubber oil from rubber seed and to produce potential biodiesel from it. Crude rubber oil was extracted by Soxhlet extraction process with n-hexane solvent and also mechanically extracted by using continuous screw expeller. Due to its high free fatty acid (3.89% FFA) content, the crude rubber oil was processed in two steps. The acid-catalyzed esterification and followed by the base catalyzed transesterification. The acid-catalyzed esterification reaction was carried out with concentrated H2SO4 acid and ethanol-to-oil ratio. The production of biodiesel involved the transesterification of treated rubber oil with ethanol in the presence of a base catalyst (KOH) to yield ethyl ester as a product and glycerine as a by-product. The first step reduces the FFA level from 3.89% to 1.1% in one hour at 50oC for 40% w/w ethanol-to-oil ratio with 1% w/w H2SO4. After the reaction the mixture was stagnated for an hour and ethanol-water upper layer was discarded. The second step convert the product into biodiesel and glycerol through transesterification using 30% w/w ethanol-to-oil and 0.8% w/w KOH to oil at 65oC. The maximum biodiesel yield achieved at rate of 89.36% within one hour and the glycerol concentration in the by-product (glycerol layer) obtained after duel step transesterification was found 18.82%.
生物柴油是从可再生原料(如植物油或动物脂肪)中提取的长链脂肪酸的单烷基酯,用于压燃发动机。研究了从橡胶种子中提取不可食用的橡胶粗油,并将其用于生产生物柴油。采用正己烷溶剂索氏萃取法提取粗橡胶油,并采用连续螺杆挤出机进行机械萃取。由于橡胶粗油游离脂肪酸含量较高(3.89% FFA),采用两步法加工。先是酸催化的酯化反应,然后是碱催化的酯交换反应。在浓硫酸和乙醇油比条件下进行了酸催化酯化反应。生物柴油的生产涉及处理过的橡胶油与乙醇在碱催化剂(KOH)存在下的酯交换反应,产物为乙酯,副产物为甘油。第一步是在50℃、乙醇油比40%、H2SO4 w/w为1%的条件下,在1小时内将FFA水平从3.89%降至1.1%。反应结束后,将混合物静置1小时,丢弃上层乙醇-水。第二步,在65℃的温度下,用30% w/w的乙醇制油和0.8% w/w的KOH制油,通过酯交换反应将产物转化为生物柴油和甘油。1 h内最大生物柴油收率为89.36%,双步酯交换副产物(甘油层)的甘油浓度为18.82%。
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引用次数: 2
Biodiesel Production from Highly Viscous Seed Oils 用高粘性种子油生产生物柴油
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2019.00008.4
Ravi V. Viradiya, R. V. Pandya, J. Tank
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引用次数: 0
Catalytic Hydrothermal Liquefaction of Solid Food Waste for Light Bio-oil Production: Process Optimisation 用于轻质生物油生产的固体食物垃圾催化水热液化:工艺优化
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2015.00006.9
Yahaya Alhassan, Naveen Kumar
Feedstocks availability has posed a big question on sustainability of biodiesel, bioethanol and biogas production. FWs (food wastes) are emerging sustainable renewable energy feedstocks, especially with the bio-refinery concept and other emerging technologies like pyrolysis and HTL (hydrothermal liquefaction). In this research work, process optimisation for the production of light bio-oil from solid restaurant waste is been reported. Solid restaurant waste was thermally liquefied using hot water under highpressure condition. Effects of heating temperature (150°C, 200°C and 250°C), biomass to solvent ratios (1: 5, 1: 10 and 1: 15) as well as catalyst loading (5 wt%, 7.5 wt% and 10 wt%) are investigated. From the results as expected, increasing reaction temperature improved the production of light biooil and its fuel quality as well, with an optimum reaction temperature of 225°C. In contrast, increasing biomass to solvent ratiofrom 1: 10 to 1: 15 did not increase the oil yield. As such, the optimum biomass to solvent ratio was 1: 10. Similarly, catalyst concentration of 5 wt% (weight of slurry) gives the best oil production. It could be concluded that HTL of solid restaurant waste into light bio-oil is a sustainable renewable energy source.
原料的可用性对生物柴油、生物乙醇和沼气生产的可持续性提出了一个大问题。FWs(食物垃圾)是新兴的可持续可再生能源原料,特别是生物炼油厂概念和其他新兴技术,如热解和热液液化。在这项研究工作中,报告了从固体餐饮废弃物中生产轻质生物油的工艺优化。利用热水在高压条件下对固体餐厨垃圾进行热液化。研究了加热温度(150°C, 200°C和250°C),生物质与溶剂的比例(1:5,1:10和1:15)以及催化剂负载(5 wt%, 7.5 wt%和10 wt%)的影响。结果表明,提高反应温度可以提高轻质生物油的产量和燃料质量,最佳反应温度为225℃。相比之下,将生物质与溶剂的比例从1:10增加到1:15并没有提高油的收率。因此,最佳生物量与溶剂比为1:10。同样,催化剂浓度为5wt %(料浆重量)时,产油效果最好。综上所述,将固体餐厨垃圾转化为轻质生物油是一种可持续的可再生能源。
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引用次数: 2
Bioethanol from Lignocellulosic Materials: Options, Challenges and Path Forward 木质纤维素材料中的生物乙醇:选择、挑战和前进的道路
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2018.00009.0
Anil Kumar Singh, N. Garg, R. Singh, A. Tyagi
Biofuels are the renewable fuels of biological origin and a good substitute to petroleum fuels for the transport sector. Among biofuels, bioethanol has been gaining worldwide acceptance as an alternative source to gasoline. The major raw material for production of ethanol has been the sugarcane molasses. Since molasses alone cannot meet the total requirement, production of ethanol from cellulosic and lignocellulosic biomass is being explored as a possible alternate source. Lignocellulosic material in the form of agricultural residue holds enormous potential as a source of ethanol because it is the most abundant renewable biomass available on the earth. This article provides a broad overview on lignocellulosic biomass availability and technologies available for its conversion into bioethanol. This would serve as the reference paper for the researchers, policy makers and industries involved in making bioethanol from renewable biomass a reality.
生物燃料是生物来源的可再生燃料,是运输部门石油燃料的良好替代品。在生物燃料中,生物乙醇作为汽油的替代能源已经得到了全世界的认可。生产乙醇的主要原料是甘蔗糖蜜。由于糖蜜本身不能满足总需求,因此正在探索从纤维素和木质纤维素生物质中生产乙醇作为一种可能的替代来源。农业残留物形式的木质纤维素材料作为乙醇的来源具有巨大的潜力,因为它是地球上最丰富的可再生生物质。本文概述了木质纤维素生物质的可用性及其转化为生物乙醇的技术。这将成为研究人员、政策制定者和参与从可再生生物质中制造生物乙醇的行业的参考论文。
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引用次数: 0
Evaluation of Performance and Emission Characteristics of Thumba oil in a Compression Ignition Engine 压燃式发动机Thumba油的性能及排放特性评价
Pub Date : 1900-01-01 DOI: 10.5958/J.0976-3015.2.2.007
Sidharth, Naveen Kumar, B. Chauhan, S. Sinha
Diesel engines are considered as a work horse in the transportation, agricultural and power sector. Stringent environmental norms coupled with extinction of fossil fuel have created interest in alternative fuels for leasing a new life to hundreds of thousands of existing diesel engines. In this context, oil derived from thumba plant has been considered as a sustainable substitute to diesel fuel. The objective of the present work is to evaluate performance and emission characteristics of a diesel engine fuelled with neat thumba oil and then to compare the results with baseline results of diesel. The experiments were conducted using a dual fuel engine test rig with the required instrumentation. The results show that BTE (brake thermal efficiency) of engine was lower and BSEC (brake specific energy consumption) was higher when the engine was fuelled with thumba oil as compared to diesel fuel. Emissions from thumba oil were comparable with that of diesel fuel. CO (carbon monoxide), HC (hydrocarbon) and smoke emissions from thumba oil were found to be slightly higher than diesel fuel. Thus, it can be concluded that thumba oil could be a good substitute of diesel fuel in rural areas of India where availability and high prices of diesel pose a challenge of utilising diesel either for electricity generation or for other farming applications.
柴油发动机被认为是运输、农业和电力部门的驮马。严格的环境标准加上化石燃料的消失,使人们对替代燃料产生了兴趣,这些替代燃料可以为数十万台现有的柴油发动机提供新的生命。在这种情况下,从桑巴植物中提取的油被认为是柴油燃料的可持续替代品。本研究的目的是评估使用纯拇指油的柴油发动机的性能和排放特性,然后将结果与柴油的基线结果进行比较。实验是在双燃料发动机试验台上进行的,并配备了所需的仪器。结果表明:与柴油相比,使用拇指油的发动机制动热效率(BTE)较低,制动比能耗(BSEC)较高;拇指油的排放量与柴油相当。大拇指油的一氧化碳、碳氢化合物和烟雾排放量略高于柴油。因此,可以得出结论,在印度农村地区,柴油的可用性和高价格对利用柴油发电或其他农业应用构成了挑战,大拇指油可能是柴油的良好替代品。
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引用次数: 0
Laws relating to Biofuel Green Jobs and Influence of the International Labour Organization to Develop Global Energy 与生物燃料有关的法律、绿色工作和国际劳工组织对发展全球能源的影响
Pub Date : 1900-01-01 DOI: 10.5958/j.0976-3015.1.1.014
M. Prince, P. Chandiveera, M. Bose
The growth of Green Employment in many countries is very significant with interests having infectious optimism regarding the potential of Green Employment and the Biofuel Technologies are rapidly improving. The Biofuel Green jobs are the wave of the future, and every municipality, village, town, city, state, and governments are looking at ways to create Biofuel Green jobs - jobs that will help the Global Environment and Global Energy. The Biofuel Green Jobs Initiative is launched to assess, analyze and promote the creation of decent jobs as a consequence of the needed environmental policies. It supports an intensive effort by Governments, Employers and Trade Unions to promote environmentally sustainable jobs and development in a climate challenged world. The paper discusses the Laws relating to Biofuel Green Jobs to develop energy and to sustain environment. The paper begins with the discussion of influence of the International Labor Organization (ILO) and the role of regulatory mitigation to develop Global Energy. The paper proceeds with Legal research on the effects of Climate Change and Opportunities available through Biofuels. The renewable Biofuels can create Green Jobs and contribute to a new Energy Economy. The new research and development programs initiatives and extension of Tax Credits for clean energy production could contribute to the completion of renewable energy projects that create Green Jobs and generate economic activity through the Biofuel Industry. This paper also discusses various issues in related to Quality Norms, Risk Management and Modern Corporate Governance pertaining to Biofuels. Collectively, this paper will address a long-term enhanced action on mitigation in Biofuel for Global Environmental Stability and Global Energy Management.
在许多国家,绿色就业的增长非常显著,人们对绿色就业的潜力有着传染性的乐观态度,生物燃料技术正在迅速改善。绿色生物燃料工作是未来的潮流,每个直辖市、村庄、城镇、城市、州和政府都在寻找创造绿色生物燃料工作的方法——这些工作将有助于全球环境和全球能源。发起生物燃料绿色就业倡议是为了评估、分析和促进所需环境政策所带来的体面就业机会的创造。它支持各国政府、雇主和工会在面临气候挑战的世界中大力促进环境上可持续的就业和发展。本文讨论了生物燃料绿色就业的相关法律,以发展能源和维持环境。本文首先讨论了国际劳工组织(劳工组织)的影响以及缓解管制对发展全球能源的作用。论文接着对气候变化的影响和生物燃料带来的机遇进行了法律研究。可再生生物燃料可以创造绿色就业机会,促进新的能源经济。针对清洁能源生产的新研发项目、倡议和税收抵免的延长,将有助于完成可再生能源项目,从而创造绿色就业机会,并通过生物燃料产业带动经济活动。本文还讨论了与生物燃料有关的质量规范、风险管理和现代公司治理的各种问题。总的来说,本文将讨论长期加强生物燃料减缓行动以促进全球环境稳定和全球能源管理。
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引用次数: 0
Assessment of Fuel Qualities of Methyl Esters from Camelina sativa Seed Oil for Biofuel Applications 用于生物燃料的亚麻荠籽油甲酯燃料品质评价
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2017.00001.0
L. C. Meher, K. Chandra, N. Sharma, M. Mittal, M. Nasim
In the recent time, Camelina sativa has attracted research interest as feedstock for biofuels. The fatty acid methyl esters from C. sativa oil was prepared and characterised as per the test methods mentioned in EN 14214: 2008, ASTM D 6751–08 and IS 15607: 2005 specifications. The methyl ester content more than 96.5% was achieved in two-step alkali transesterification, and the percentage of monoglyceride, diglyceride and triglyceride were within the specified limit. The iodine value is 148 g I2/100 g which is quite above the desired value as per the European specification; likewise, the linolenic acid methyl ester content is quite high. The cetane number was calculated theoretically which is less than the required value. The oxidation stability is poor, whereas the addition of synthetic antioxidant that is pyrogallol at 100 ppm attains the induction period of 8.1 h. The rest fuel parameters are in good agreement with EN 14214: 2008 norm. Except cetane number, the other properties are in agreement with the IS 15607: 2005 specification. In case of American specification, the cetane number is specified to be minimum 47, whereas the theoretical cetane number for Camelina methyl ester is slightly lower. Cetane enhancer may be used for the fuel to qualify the American and Indian specifications.
近年来,亚麻荠作为生物燃料的原料引起了人们的研究兴趣。根据EN 14214: 2008, ASTM D 6751-08和IS 15607: 2005规范中提到的测试方法,从芥花油中制备和表征脂肪酸甲酯。两步碱酯交换制得的甲酯含量大于96.5%,单甘油酯、双甘油酯和甘油三酯的含量均在规定范围内。碘值为148 g /100 g,远远高于欧洲标准的期望值;同样,亚麻酸甲酯的含量也很高。理论上计算的十六烷值小于要求值。氧化稳定性较差,而添加100 ppm的合成抗氧化剂邻苯三酚,诱导期为8.1 h。其余燃料参数符合EN 14214: 2008标准。除十六烷值外,其他性能均符合IS 15607: 2005规范。美国规范规定十六烷值最低为47,而亚麻荠甲酯的理论十六烷值略低。十六烷增强剂可用于燃料,以符合美国和印度的规格。
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引用次数: 1
Heavy Metals Compositions in Different Vegetable Oil Methyl Esters 不同植物油甲酯中重金属的组成
Pub Date : 1900-01-01 DOI: 10.5958/0976-4763.2017.00008.3
C. S. Ezeanyanaso, Y. Alhassan, O. Okunola, S. Garba, A. Abubakar
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引用次数: 0
期刊
Journal of Biofuels
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