Pub Date : 2023-01-10DOI: 10.2174/2405461508666230110164054
R. Patel, C. P. Bhasin
More than 260 million people worldwide are affected by excess fluoride (F- > 1.5 mg/L) in their drinking water. Fluorosis of the teeth and skeleton, among other health issues, is caused by it. The aim of this study is to evaluate the fluoride removal from contaminated water using graphene-based new adsorbent material. Graphene (G) was prepared by a facile liquid-phase exfoliation method. CeO2 nanoparticles (NPs) were synthesized by the co-precipitation method. G was treated with CeO2 NPs in a probe sonicator to generate G/Ce material in solution. Finally, the impregnation evaporation process synthesized the G/Ce supported on activated carbon composite (G/Ce/AC). FE-SEM analysis shows that the crumpling and scrolling sheets of G, the nanosized spherical shape of CeO2 NPs and a thick layer of nano-sized spherical particles has built up on the surface of graphene in G/Ce/AC composite. After conversion to G/Ce/AC Composite, the specific surface area of graphene was increased from 3.08 to 485.3621 m2/g. The adsorption of fluoride on G/Ce/AC was investigated using batch systems (effects of pH, contact time, adsorbent dosage and the initial fluoride concentration), adsorption isotherm and kinetic studies. The pseudo-second order was the one that best described the kinetic data, while the Langmuir isotherm best described the equilibrium data with a maximum adsorption capacity equal to 27.9 mg/g. Therefore, the results show that the G/Ce/AC composite was well synthesized and has excellent fluoride adsorption capacity compared to other materials already evaluated for this purpose.
{"title":"Efficient Fluoride removal from aqueous solution using Graphene/Ce composite supported on activated carbon","authors":"R. Patel, C. P. Bhasin","doi":"10.2174/2405461508666230110164054","DOIUrl":"https://doi.org/10.2174/2405461508666230110164054","url":null,"abstract":"\u0000\u0000More than 260 million people worldwide are affected by excess fluoride (F- > 1.5 mg/L) in their drinking water. Fluorosis of the teeth and skeleton, among other health issues, is caused by it.\u0000\u0000\u0000\u0000The aim of this study is to evaluate the fluoride removal from contaminated water using graphene-based new adsorbent material.\u0000\u0000\u0000\u0000Graphene (G) was prepared by a facile liquid-phase exfoliation method. CeO2 nanoparticles (NPs) were synthesized by the co-precipitation method. G was treated with CeO2 NPs in a probe sonicator to generate G/Ce material in solution. Finally, the impregnation evaporation process synthesized the G/Ce supported on activated carbon composite (G/Ce/AC).\u0000\u0000\u0000\u0000FE-SEM analysis shows that the crumpling and scrolling sheets of G, the nanosized spherical shape of CeO2 NPs and a thick layer of nano-sized spherical particles has built up on the surface of graphene in G/Ce/AC composite. After conversion to G/Ce/AC Composite, the specific surface area of graphene was increased from 3.08 to 485.3621 m2/g. The adsorption of fluoride on G/Ce/AC was investigated using batch systems (effects of pH, contact time, adsorbent dosage and the initial fluoride concentration), adsorption isotherm and kinetic studies. The pseudo-second order was the one that best described the kinetic data, while the Langmuir isotherm best described the equilibrium data with a maximum adsorption capacity equal to 27.9 mg/g.\u0000\u0000\u0000\u0000Therefore, the results show that the G/Ce/AC composite was well synthesized and has excellent fluoride adsorption capacity compared to other materials already evaluated for this purpose.\u0000","PeriodicalId":10924,"journal":{"name":"Current Nanomaterials","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46086558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-29DOI: 10.2174/2405461508666221229103713
Shilpa Jain, T. Shaikh
Nanotechnology has enabled sensors to detect and sense a very small amount of chemical vapors. Sensors play a major role in our daily life. The use of sensors has made human life easy. One such type of sensor is the Gas sensor made up of Semiconducting metal oxides. These sensors have their own unique features which help in the easy monitoring of toxic gases. Out of all the metal oxide present, the gas sensors made up of ZnO nanostructures are mostly used in the gas sensing industry. ZnO has become a research hotspot of gas-sensing material because of the variation in resistance observed on the surface. These resistance changes are observed due to the adsorption & desorption of gases. In this review, we will be discussing the ZnO nanostructures, their preparation and their applications in the sensing of various toxic and flammable gases.
{"title":"ZnO nanostructure based Gas Sensors: Critical review based on their synthesis and morphology towards various oxidizing and reducing gases","authors":"Shilpa Jain, T. Shaikh","doi":"10.2174/2405461508666221229103713","DOIUrl":"https://doi.org/10.2174/2405461508666221229103713","url":null,"abstract":"\u0000\u0000Nanotechnology has enabled sensors to detect and sense a very small amount of chemical vapors. Sensors play a major role in our daily life. The use of sensors has made human life easy. One such type of sensor is the Gas sensor made up of Semiconducting metal oxides. These sensors have their own unique features which help in the easy monitoring of toxic gases. Out of all the metal oxide present, the gas sensors made up of ZnO nanostructures are mostly used in the gas sensing industry. ZnO has become a research hotspot of gas-sensing material because of the variation in resistance observed on the surface. These resistance changes are observed due to the adsorption & desorption of gases. In this review, we will be discussing the ZnO nanostructures, their preparation and their applications in the sensing of various toxic and flammable gases.\u0000","PeriodicalId":10924,"journal":{"name":"Current Nanomaterials","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43992043","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-14DOI: 10.2174/2405461508666221214120304
Prabhurajeshwar Chidre, Ashajyothi Chavan, Navya Hulikunte Mallikarjunaiah, C. Kelmani
Nanotechnology is a promising science with new aspects to fight and prevent various diseases using nanomaterials. The capability to expose the structure and functions of biosystems at the nanoscale level supports research leading to development in biology, biotechnology, medicine and healthcare. This is predominantly advantageous in treating microbial infections as an alternative to antibiotics. However, widespread production, and use and misuse of antibiotics have led to the emergence of multiple-drug resistant (MDR) pathogenic bacteria. Due to infectious diseases from these drug-resistant pathogenic strains, human mortality rates have consistently increased and are becoming an epidemic in our society. Consequently, there is a strong demand for developing novel strategies and new materials that can cope with these problems. The emergence of nanotechnology has created many new antimicrobial options. The small size of these nanomaterials is suitable for carrying out biological operations. Several metals and metal oxides, such as silver, copper, gold, zinc oxide and iron oxide nanoparticle types, have shown toxicity toward several pathogenic microbes. Metal-based nanoparticles have been broadly examined for a set of biomedical applications. According to the World Health Organization, the reduced size and selectivity of metal-based nanoparticles for bacteria have established them to be effective against pathogens, causing concern. Metal-based nanoparticles are known to have non-specific bacterial toxicity mechanisms, which not only make the development of resistance by bacteria difficult, but also widen the spectrum of antibacterial activity. Metal-based nanoparticle efficiency studies achieved so far have revealed promising results against both Gram-positive and Gram-negative bacteria. Here we discuss the potential nanomaterials to either treat microbial resistance or induce the development of resistance. However, fundamental research is required to focus on the molecular mechanism causing the antimicrobial activity of nanomaterials.
{"title":"Nanomaterials: Potential Broad Spectrum Antimicrobial Agents","authors":"Prabhurajeshwar Chidre, Ashajyothi Chavan, Navya Hulikunte Mallikarjunaiah, C. Kelmani","doi":"10.2174/2405461508666221214120304","DOIUrl":"https://doi.org/10.2174/2405461508666221214120304","url":null,"abstract":"\u0000\u0000Nanotechnology is a promising science with new aspects to fight and prevent various diseases using nanomaterials. The capability to expose the structure and functions of biosystems at the nanoscale level supports research leading to development in biology, biotechnology, medicine and healthcare. This is predominantly advantageous in treating microbial infections as an alternative to antibiotics. However, widespread production, and use and misuse of antibiotics have led to the emergence of multiple-drug resistant (MDR) pathogenic bacteria. Due to infectious diseases from these drug-resistant pathogenic strains, human mortality rates have consistently increased and are becoming an epidemic in our society. Consequently, there is a strong demand for developing novel strategies and new materials that can cope with these problems. The emergence of nanotechnology has created many new antimicrobial options. The small size of these nanomaterials is suitable for carrying out biological operations. Several metals and metal oxides, such as silver, copper, gold, zinc oxide and iron oxide nanoparticle types, have shown toxicity toward several pathogenic microbes. Metal-based nanoparticles have been broadly examined for a set of biomedical applications. According to the World Health Organization, the reduced size and selectivity of metal-based nanoparticles for bacteria have established them to be effective against pathogens, causing concern. Metal-based nanoparticles are known to have non-specific bacterial toxicity mechanisms, which not only make the development of resistance by bacteria difficult, but also widen the spectrum of antibacterial activity. Metal-based nanoparticle efficiency studies achieved so far have revealed promising results against both Gram-positive and Gram-negative bacteria. Here we discuss the potential nanomaterials to either treat microbial resistance or induce the development of resistance. However, fundamental research is required to focus on the molecular mechanism causing the antimicrobial activity of nanomaterials.\u0000","PeriodicalId":10924,"journal":{"name":"Current Nanomaterials","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43619771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-12-05DOI: 10.2174/2405461508666221205091152
M. Moloto, Nompumelelo S. M. Kubheka, Nolutho Mkhumbeni
The fabrication of polymer fibre blends has gained much attention for the development of innovative nanomaterials. Polymer fibre blends are nanomaterials with different functionalities and properties such as a sizeable surface-to-area ratio, high porosity, flexibility, and stability. The focus of this study was to produce zein/PVA fibre blends using the electrospinning technique and varying parameters such as concentration and applied voltage. The two parameters are key driving factors for the production of fibres. Zein as a natural polymer has challenges in developing fibre materials which require artificial polymers like PVA to create a good blending mixture for electrospinning. The zein/PVA nanofibre blends were fabricated using the electrospinning technique. The FE-SEM (Leo, Zeiss) was used to study the surface morphologies of the zein/PVA nanofibers blends. The optical properties of the nanofibre blends were determined using the UV-vis spectrophotometer and the chemical structure and composition of zein/PVA nanofibers blends were studied using Thermo Scientific Nicolet iS50-FTIR spectrometer, universal ATR with the diamond detector. The SEM images showed smooth zein/PVA ribbon-like nanofibre blends of 90/10, 80/20, 70/30, 60/40, and 50/50. SEM images of zein/PVA (80/20) electrospun at 25 kV were obtained to be the maximum fibre yield due to zein/PVA compatibility, increased conductivity, and enhanced fibre formation. The optical properties (absorption spectroscopy) suggested that the zein/PVA (80/20) fibre blend was miscible, and the FTIR spectra confirmed their functional groups. Therefore, the characterization results showed that the polymer blended solutions concentration and applied voltage increment affected fibre size distribution and morphology. Optimizing concentration and applied voltage successfully produced smooth, uniform bead-free zein/PVA fibre blends as parameters are increased.
{"title":"Fabrication of zein/PVA fibre blends: Optimizing concentration and applied voltage","authors":"M. Moloto, Nompumelelo S. M. Kubheka, Nolutho Mkhumbeni","doi":"10.2174/2405461508666221205091152","DOIUrl":"https://doi.org/10.2174/2405461508666221205091152","url":null,"abstract":"\u0000\u0000The fabrication of polymer fibre blends has gained much attention for the development of innovative nanomaterials. Polymer fibre blends are nanomaterials with different functionalities and properties such as a sizeable surface-to-area ratio, high porosity, flexibility, and stability. The focus of this study was to produce zein/PVA fibre blends using the electrospinning technique and varying parameters such as concentration and applied voltage. The two parameters are key driving factors for the production of fibres. Zein as a natural polymer has challenges in developing fibre materials which require artificial polymers like PVA to create a good blending mixture for electrospinning.\u0000\u0000\u0000\u0000The zein/PVA nanofibre blends were fabricated using the electrospinning technique. The FE-SEM (Leo, Zeiss) was used to study the surface morphologies of the zein/PVA nanofibers blends. The optical properties of the nanofibre blends were determined using the UV-vis spectrophotometer and the chemical structure and composition of zein/PVA nanofibers blends were studied using Thermo Scientific Nicolet iS50-FTIR spectrometer, universal ATR with the diamond detector.\u0000\u0000\u0000\u0000The SEM images showed smooth zein/PVA ribbon-like nanofibre blends of 90/10, 80/20, 70/30, 60/40, and 50/50. SEM images of zein/PVA (80/20) electrospun at 25 kV were obtained to be the maximum fibre yield due to zein/PVA compatibility, increased conductivity, and enhanced fibre formation. The optical properties (absorption spectroscopy) suggested that the zein/PVA (80/20) fibre blend was miscible, and the FTIR spectra confirmed their functional groups. Therefore, the characterization results showed that the polymer blended solutions concentration and applied voltage increment affected fibre size distribution and morphology.\u0000\u0000\u0000\u0000Optimizing concentration and applied voltage successfully produced smooth, uniform bead-free zein/PVA fibre blends as parameters are increased.\u0000","PeriodicalId":10924,"journal":{"name":"Current Nanomaterials","volume":" ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2022-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44367115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}