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Optical properties of nanoparticles dispersed in ambient medium and their dependences on temperature 纳米颗粒在环境介质中的光学性质及其对温度的依赖性
Q3 Materials Science Pub Date : 2022-11-02 DOI: 10.2174/2405461508666221102090945
V. Pustovalov
This review describes the basic and application aspects of the optical properties of nanoparticles (NPs), which determine the dynamics and results of optical (laser) radiation interaction with NPs and their surroundings through NP light absorption and heat generation. In addition to the importance of primary optical processes, the thermal application of the light–NP interaction has attracted significant interest from various areas ranging from photochemistry to laser material processing and nanobiomedicine. First of all, the information provided is intended for laser specialists, photochemists and nanobiologists who are not so familiar with various optical data for understanding of the influence of NP optical properties on the results of optical or laser action on NPs and medium. Secondly, our review will be useful for researchers who conduct high-temperature investigations of the intense optical action on NPs that needs to take into account the dependence of NP optical properties on its temperature under NP heating.Our attention is focused on two variants of the applications of NP optical properties. Firstly, we shortly reviewed the optical properties of NPs at their initial or slightly higher temperatures reached under the influence of moderate radiation intensity. They are presented in numerous publications and are used as basic data. On the other side, the development of modern high-temperature laser and optical technologies needs to use the NPs optical properties at temperatures of about 1x103 K and more. For high power laser and optical technologies, it is necessary to take into account the temperature dependences of the optical parameters of various metals, dielectrics and other materials. Among these technologies, one should list laser processing of NPs, thermal laser biomedicine, solar and photo nanocatalysis, solar nanostructured absorbers. The selection and use of suitable optical properties of NPs are crucial to successful achievements and results in high-temperature experiments and applications. Novel information on optical property dependence on temperature obtained from currently available literature has been presented for possible applications in optical and laser high-temperature processes interactions with NPs. However, unfortunately, the essential information on the effect of temperature on the optical properties of NPs is currently limited. In addition to the latest information, this review also includes the figures obtained by our own calculations to provide readers with a better understanding of the NP optical properties. From the side of the application, the use of NP optical properties is considered, which provide multiple varieties of moderate and high-temperature technology opportunities, many of which are ongoing and some of them are promising bright results in the near future. The beneficial outcome and the results of further activities in the research of intense laser and optical interactions with NPs can influen
这篇综述描述了纳米颗粒光学性质的基本和应用方面,这些性质决定了通过纳米颗粒的光吸收和热产生与纳米颗粒及其周围环境的光学(激光)辐射相互作用的动力学和结果。除了初级光学过程的重要性外,光-NP相互作用的热应用也引起了从光化学到激光材料加工和纳米生物医学等各个领域的极大兴趣。首先,所提供的信息是为激光专家、光化学学家和纳米生物学家提供的,他们不太熟悉各种光学数据,以了解NP光学性质对NP和介质上的光学或激光作用结果的影响。其次,我们的综述将有助于研究人员对NP的强烈光学作用进行高温研究,需要考虑NP加热下NP光学性质对其温度的依赖性。我们的注意力集中在NP光学性质应用的两个变体上。首先,我们简要回顾了NP在中等辐射强度影响下达到的初始或略高温度下的光学性质。它们出现在许多出版物中,并被用作基本数据。另一方面,现代高温激光和光学技术的发展需要在大约1x103K或更高的温度下使用NP的光学特性。对于高功率激光和光学技术,有必要考虑各种金属、电介质和其他材料的光学参数的温度依赖性。在这些技术中,应该列出纳米颗粒的激光加工、热激光生物医学、太阳能和光纳米催化、太阳能纳米结构吸收剂。选择和使用合适的纳米颗粒光学性质对于在高温实验和应用中取得成功和结果至关重要。从目前可用的文献中获得的关于光学性质对温度的依赖性的新信息已被提供用于光学和激光高温过程与NP相互作用的可能应用。然而,不幸的是,关于温度对纳米颗粒光学性质影响的基本信息目前是有限的。除了最新的信息外,这篇综述还包括我们自己计算获得的数字,以使读者更好地了解NP的光学性质。从应用的角度来看,考虑了NP光学性质的使用,这提供了多种中高温技术机会,其中许多正在进行中,其中一些在不久的将来有望取得光明的结果。研究强激光和光学与纳米颗粒相互作用的有益结果和进一步活动的结果可以影响科学技术的各个领域:纳米和光化学、生物医学、纳米物理学、材料科学等。
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引用次数: 0
Formulation and evaluation of letrozole nanosuspension by probe sonication method using box-behnken design 盒子设计探针超声法制备来曲唑纳米混悬液及评价
Q3 Materials Science Pub Date : 2022-08-31 DOI: 10.2174/2405461507666220831093135
A. Sailaja, Amand Alekhya
Letrozole (LTZ), is an aromatase inhibitor used for the treatment of hormonally positive breast cancer in postmenopausal women. Letrozole is categorized as a BCS class I drug. It has poor water solubility, rapid metabolism and a range of side effects.Nanosuspension is a technique which enhances the drug's solubility and bioavailability, resulting in a faster start of effect. The present study was aimed, to formulate nanosuspension using probe sonication method for the enhancement of solubility of Letrozole using poloxamer-188 as stabilizer. The formulation scheme was generated by using Box-Behnken design which is a statistical tool of design of experiments (DOE).Total seventeen formulations were performed for letrozole nanosuspension as suggested by Box-Behnken design by employing probe sonication method. The selected formulations are characterized for particle size and zeta potential. The formulations were checked on percentage of bias in between predicted value and observed value and evaluated for drug content and invitro dissolution study. The formulation was optimized using Box-Behnken design based on invitro cumulative drug release. Among all the formulations NS4 (500mg poloxamer-188, 100mg Letrozole and sonication time of 20mints) was considered to be best with minimum Particle size of 923.5nm, Zeta potential value of -28.7mV, 96.36% of drug content and 94.02% of drug release within 2 hours. Solubility was determined by shake flask method. The solubility of pure drug was found to be only 10%. The solubility studies were performed for the optimized formulation of NS4 showed that the solubility has enhanced up to 90% when compared to pure drug.Thus, the present results revealed that Letrozole nanosuspension solubility has enhanced up to 90% when compared to pure drug by using poloxamer-188 as stabilizer.
来曲唑(LTZ)是一种芳香化酶抑制剂,用于治疗绝经后妇女激素阳性乳腺癌症。来曲唑属于BCS I类药物。它的水溶性差,新陈代谢快,有一系列副作用。纳米悬浮液是一种提高药物溶解度和生物利用度的技术,可以更快地发挥作用。本研究旨在以泊洛沙姆-188为稳定剂,采用探针超声法配制纳米混悬剂,以提高来曲唑的溶解度。配方方案是使用实验设计(DOE)的统计工具Box-Behnken设计生成的。根据Box-Behcken设计的建议,采用探针超声法对来曲唑纳米混悬剂进行了总共17个配方。对所选配方的粒度和ζ电位进行了表征。对制剂的预测值和观察值之间的偏差百分比进行检查,并对药物含量和体外溶出度研究进行评估。基于体外累积药物释放,使用Box-Behnken设计对制剂进行优化。在所有制剂中,NS4(泊洛沙姆-188 500mg,来曲唑100mg,超声时间20mint)被认为是最佳的,最小粒径为923.5nm,Zeta电位值为-28.7mV,药物含量为96.36%,2小时内药物释放率为94.02%。溶解度用摇瓶法测定。纯药物的溶解度只有10%。对NS4的优化配方进行了溶解度研究,结果表明,与纯药物相比,NS4的溶解度提高了90%。因此,本研究结果表明,与使用泊洛沙姆-188作为稳定剂的纯药物相比,来曲唑纳米混悬剂的溶解度提高了90%。
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引用次数: 0
Carbon Nanotube – Synthesis, Purification and Biomedical applications 碳纳米管的合成、纯化和生物医学应用
Q3 Materials Science Pub Date : 2022-08-27 DOI: 10.2174/2405461507666220827092425
Smriti Ojha, Sudhanshu Mishra, Sonali Kumari, A. Mishra, R. Chaubey
Carbon nanotubes (CNTs) are a relatively new class of technical materials with a variety of unique and beneficial features. CNT is a revolutionary carrier technology for both tiny and big medicinal compounds. These formulations can be surface engineered and functionalized with predefined functional groups to control their physical and biological characteristics. CNTs have proven potential for cancer therapy along with other target-oriented therapy due to their unique features, such as ease of cell viability, high drug stacking, thermal ablation, and exceptional intrinsic physical and chemical characteristics. Graphite with Sp2 bonded carbon atoms is used for the synthesis of CNT. CNTs are fabricated in a variety of ways, including arc discharge, laser ablation, chemical vapor deposition, flame synthesis, and silane solution. The present review summarises methods of preparation, types, and various applications of CNT.
碳纳米管(CNTs)是一类相对较新的技术材料,具有各种独特和有益的特性。CNT是一种革命性的载体技术,用于微小和巨大的药用化合物。这些制剂可以用预定的官能团进行表面工程和功能化,以控制其物理和生物特性。CNT由于其独特的特性,如易于细胞活力、高药物堆积、热消融和特殊的内在物理和化学特性,已被证明具有癌症治疗和其他靶向治疗的潜力。具有Sp2键合的碳原子的石墨用于CNT的合成。CNT的制造方法多种多样,包括电弧放电、激光烧蚀、化学气相沉积、火焰合成和硅烷溶液。本文综述了碳纳米管的制备方法、类型和各种应用。
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引用次数: 2
Novel applications of graphene and its derivatives: A short review 石墨烯及其衍生物的新应用综述
Q3 Materials Science Pub Date : 2022-08-23 DOI: 10.2174/2405461507666220823124855
A. Jose, Akhila Job, Jephin K. Jose, Manoj B
Graphene, a layered allotropic form of graphitic carbon, has fascinated the scientific world from the time of its discovery. Its unique structural, physical, chemical, mechanical, and electrical properties find application in many areas. Because of its large surface area as well as its apt electrical property, it is used in electromagnetic interference shielding. With excellent carrier mobility, it is used for sensing purposes. Mechanical strength and elastic properties coupled with its lightweight makes graphene a promising material as a supercapacitor. The 2-dimensional structural properties of the graphene layers can be used for the purification treatment of water and gas. The number of researches in graphene applications are increasing every single day which shows the importance and excellency of graphene properties. This short review provides a comprehensive understanding of the properties and progress of graphene in the field of electromagnetic interference shielding, sensors, water treatment, energy production, storage, and conversion applications such as supercapacitors, fuel cells, solar cells and electrocatalysts.
石墨烯是石墨碳的一种层状同素异形形式,从发现之时起就吸引了科学界。它独特的结构、物理、化学、机械和电学性能在许多领域都有应用。由于其大的表面积和良好的电学性能,它被用于电磁干扰屏蔽。由于具有优异的载流子迁移率,它被用于传感目的。石墨烯的机械强度和弹性特性加上其重量轻,使其成为一种很有前途的超级电容器材料。石墨烯层的二维结构性质可用于水和气体的净化处理。石墨烯应用研究的数量每天都在增加,这表明了石墨烯性能的重要性和优越性。这篇简短的综述全面了解了石墨烯在电磁干扰屏蔽、传感器、水处理、能源生产、存储和转换应用领域的性能和进展,如超级电容器、燃料电池、太阳能电池和电催化剂。
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引用次数: 1
Magnetic and dielectric properties of 0.1 Bi2/3Cu3Ti4O12 -0.9 Bi3LaTi3O12 nanocomposite prepared by semi-wet route 半湿法制备0.1Bi2/3Cu3Ti4O12-0.9Bi3LaTi3O12纳米复合材料的磁性和介电性能
Q3 Materials Science Pub Date : 2022-08-20 DOI: 10.2174/2405461507666220820121450
Pooja Gautam, A. Bharti, A. Tiwari, K. Mandal
A chemical formula of nanocomposite 0.1 Bi2/3Cu3Ti4O12 -0.9 Bi3LaTi3O12 (BCLT-19) was prepared by semiwet route using metal nitrate and solid TiO2. The phase formation of Bi2/3Cu3Ti4O12 (BCT) and Bi3LaTi3O12 (BLT) was confirmed by X-ray diffraction (XRD) study.Transmission electron microscope (TEM) analysis showed a nano particle of size 14 ± 5 nm on average for BCLT-19 composites. Scanning electron microscope (SEM) images exhibited a tubular, spherical and heterogeneous structure of grains. The root means square roughness, average roughness and maximum area peak height were explained by atomic force microscopy (AFM).Study of magnetic properties was determined as weak antiferromagnetic to ferromagnetic and in nature. The high dielectric constant (ε' = 3147 at 100Hz to 500 K) of BCLT-19 may be due to the existence of space charge polarization.In this manuscript have studies on the novel composite materials of BCLT-19 micro-structural properties. This is useful for future Random-access memory devices and dielectric materials,
以金属硝酸盐和固体TiO2为原料,通过半湿法合成了纳米复合材料0.1Bi2/3Cu3Ti4O12-0.9Bi3LaTi3O12(BCLT-19)。通过X射线衍射(XRD)研究证实了Bi2/3Cu3Ti4O12(BCT)和Bi3LaTi3O12(BLT)的相形成。透射电子显微镜(TEM)分析显示,BCLT-19复合材料的平均尺寸为14±5nm的纳米粒子。扫描电子显微镜(SEM)图像显示出管状、球形和非均匀的晶粒结构。用原子力显微镜(AFM)对其均方根粗糙度、平均粗糙度和最大面积峰高进行了解释。磁性能的研究被确定为弱反铁磁性到铁磁性以及在自然界中。BCLT-19的高介电常数(ε′=3147,在100Hz至500K下)可能是由于空间电荷极化的存在。本文对新型复合材料BCLT-19的微观结构性能进行了研究。这对于未来的随机存取存储器器件和介电材料是有用的,
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引用次数: 0
Silver Nanoparticles: Synthesis in newly formed Ternary Deep Eutectic Solvent Media, Characterization and their Antifungal activity 银纳米粒子:在新形成的三元深共晶溶剂介质中的合成、表征及其抗真菌活性
Q3 Materials Science Pub Date : 2022-08-17 DOI: 10.2174/2405461507666220817155944
K. Sarjuna, D. Ilangeswaran
When halide salts and hydrogen bond donors are combined, they produce Deep Eutectic Solvents, which have a lower freezing/melting point than the individual components. At room temperature, they have emerged as viable alternatives to ionic liquids. The wonderful features of deep eutectic solvents such as humidity tolerance, high-temperature stability, low cost, non-hazardous, reusable, and recyclable nature, allow them to replace ionic liquids.To prepare two newer Ternary Deep Eutectic Solvents using Malonic acid - Glucose – Glutamine and Malonic acid - Fructose – Glutamine. Using the prepared ternary deep eutectic solvents, to synthesize silver nanoparticles and study the antifungal behavior.The ternary deep eutectic solvents were prepared by the evaporation method in water and subjected to measure the properties such as density, pH, conductivity, viscosity, and absorption frequencies of Fourier Transform Infrared Spectroscopy. The prepared deep eutectic solvents are used for the synthesis of Silver Nanoparticles by the chemical reduction method in presence of Hydrazine Hydrate as a reducing agent and sodium hydroxide as a stabilizing agent. The synthesized nanoparticles are characterized by UV-Visible Spectroscopy, Fourier Transform Infrared Spectroscopy, X-ray diffraction, scanning electron microscopy, and energy dispersive X-ray analysis techniques.The characteristic absorption peak of UV-Visible Spectroscopy shows that silver nanoparticles were formed. FTIR exposes the metallic and other bonding of the nanoparticles and the caping materials. From the XRD pattern, we found the crystalline and the images formed in the SEM are in the nanoscale. The average particle size of silver nanoparticles is 116.87nm and 26.61 nm.In our study, two types of novel ternary deep eutectic solvents were developed. They act as a better solvent media for the synthesis of silver nanoparticles and the synthesized nanoparticles show antifungal behaviors against some fungi.
当卤化物盐和氢键供体结合时,它们产生深度共晶溶剂,其具有比单个组分更低的凝固/熔点。在室温下,它们已经成为离子液体的可行替代品。深共晶溶剂的优异特性,如耐湿、高温稳定性、低成本、无害、可重复使用和可回收性质,使其能够取代离子液体。用丙二酸-葡萄糖-谷氨酰胺和丙二酸-果糖-谷氨酰胺制备两种新型三元深共晶溶剂。利用制备的三元深共晶溶剂,合成纳米银并研究其抗真菌性能。采用蒸发法在水中制备了三元深共晶溶剂,并用傅立叶变换红外光谱对其密度、pH、电导率、粘度和吸收频率等性能进行了测试。所制备的深共晶溶剂用于在水合肼作为还原剂和氢氧化钠作为稳定剂的存在下通过化学还原法合成银纳米粒子。通过紫外可见光谱、傅立叶变换红外光谱、X射线衍射、扫描电子显微镜和能量色散X射线分析技术对合成的纳米颗粒进行了表征。紫外可见光谱的特征吸收峰表明,银纳米粒子形成。FTIR暴露了纳米颗粒和封端材料的金属结合和其他结合。从XRD图谱中,我们发现在SEM中形成的晶体和图像是纳米级的。银纳米粒子的平均粒径分别为116.87nm和26.61nm。在我们的研究中,开发了两种新型的三元深共晶溶剂。它们是合成银纳米颗粒的较好溶剂介质,合成的纳米颗粒对某些真菌具有抗真菌作用。
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引用次数: 0
Meet the Editorial Board Member 与编辑委员会成员见面
Q3 Materials Science Pub Date : 2022-08-01 DOI: 10.2174/240546150702220508232335
R. Ashiri
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引用次数: 0
Physico-Chemical Characterization of green synthesized nanomaterials by UV-Visible spectroscopy 绿色合成纳米材料的紫外-可见光谱物理化学表征
Q3 Materials Science Pub Date : 2022-07-21 DOI: 10.2174/2405461507666220721115604
Amar Kumar, Meenakshi, N. Saxena, K. Seema, Anshuman Srivastava, Jitendra Rajak, D. Singh, S. V. Singh, L. Singh
Nanomaterials (NMs) particularly synthesized by green routes have attracted the researchers and scientists for their multifunctional industrial applications. NMs have not only revolutionized the research, but also our daily life because of numerous applications in medical diagnostics, consumer products, and energy-related applications. Their unique properties are directly related to chemical composition, structure, size and shape. There are several characterization techniques are used to determine the size, composition, crystalline structure and other physical properties of NMs. Prominent among them are spectroscopic techniques such as UV-Visible, FTIR, EDX; diffraction techniques such as XRD, SAED; microscopic techniques such as SEM, TEM, AFM and others such as Zeta potential measurements. Every technique has its own merit and demerit. This mini review describes the uses of UV-Vis spectroscopy in characterization of NMs.
纳米材料特别是绿色合成的纳米材料以其多功能的工业应用吸引了研究人员和科学家。由于在医疗诊断、消费产品和能源相关应用中的大量应用,NMs不仅彻底改变了研究,而且改变了我们的日常生活。它们的独特性质与化学成分、结构、大小和形状直接相关。有几种表征技术用于确定NMs的尺寸、组成、晶体结构和其他物理性质。其中最突出的是光谱技术,如紫外-可见,FTIR, EDX;XRD、SAED等衍射技术;微观技术,如SEM, TEM, AFM和其他如Zeta电位测量。每种技术都有自己的优点和缺点。本文简要介绍了紫外可见光谱在纳米材料表征中的应用。
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引用次数: 0
A review on nanofluids: synthesis, stability, and uses in the manufacturing industry 纳米流体的合成、稳定性及其在制造业中的应用综述
Q3 Materials Science Pub Date : 2022-06-30 DOI: 10.2174/2405461507666220630153637
J. Gujar, S. Patil, S. Sonawane
Nanofluids are a new class of nanomaterials suspended in a base liquid. Nanofluids have shown extremely distinctive properties that give tremendous opportunities for a wide range of applications. Nanofluids are a novel group of heat transfer fluids that have attracted the attention of researchers from various fields due to their intensive thermal properties. This systematic review highlights the synthesis, stability, physical treatment, and applications of nanofluids in various sectors. Applications of nanofluids in different sectors like the coolant in machinery, cooling of electronics, in chillers, cooling of diesel electronics generators, in a boiler cool gas reductions, and the manufacturing industry. The manufacturing process is one of the most fundamental and well-proven industrial processes in product-based industries. Cutting fluids play a critical function in lowering manufacturing cycle time as well as cutting costs during the machining process. A review of the importance of the machining process, as well as the use of nanofluids as cutting fluids, has been investigated in this work. To achieve these goals, cutting force, surface quality, tool and workpiece interface temperature, tool geometry, and the impacts of environmental situations were studied. Various vital specifications, such as the type of nanoparticle, a cutting tool used, work material type, and machining processes like turning, milling, drilling, and grinding were studied and thoroughly summarised in this work. If the machining parameters were used correctly, a greater heat transfer rate would be observed due to changes in lubricating characteristics and physical parameters.
纳米流体是一类悬浮在基本液体中的新型纳米材料。纳米流体显示出极其独特的特性,为广泛的应用提供了巨大的机会。纳米流体是一类新型的传热流体,由于其强烈的热性能而引起了各领域研究人员的关注。这篇系统综述重点介绍了纳米流体的合成、稳定性、物理处理以及在各个领域的应用。纳米流体在不同领域的应用,如机械冷却剂、电子设备冷却、冷却器、柴油电子发电机冷却、锅炉冷气减排和制造业。在以产品为基础的行业中,制造过程是最基本、最成熟的工业过程之一。切削液在降低加工过程中的制造周期和切削成本方面发挥着关键作用。本文对机械加工过程的重要性以及纳米流体作为切削液的使用进行了综述。为了实现这些目标,研究了切削力、表面质量、刀具和工件界面温度、刀具几何形状以及环境状况的影响。本工作研究并全面总结了各种重要规格,如纳米颗粒的类型、使用的切削工具、工作材料类型以及车削、铣削、钻孔和磨削等加工工艺。如果正确使用加工参数,由于润滑特性和物理参数的变化,将观察到更大的传热率。
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引用次数: 0
Drag resistivity of hole-hole static interactions with the effect of non-homogeneous dielectric medium 非均匀介质作用下孔-孔静态相互作用的阻力电阻率
Q3 Materials Science Pub Date : 2022-06-28 DOI: 10.2174/2405461507666220628161237
S. K. Upadhyay, L. K. Sainia
We have study the Coulomb drag phenomena for hole-hole static potentials theoretically and measured numerically using the random phase approximation (RPA) methodThe drag resistivity is evaluated at low temperature, large interlayer separation limit and weakly screening regime, with the geometry of two atomically thin materials, such as, BLG/GaAs based multilayer system, is a promising systems in nanomaterials and technologyStatic local field corrections (LFC) are considered to take into account the Exchange-correlations (XC) and mutual interaction effects with varying concentrations of active and passive layerIt is found that the drag resistivity is found enhanced on using the LFC effects and increases on increasing the effective mass. In Fermi-Liquid regime, drag resistivity is directly proportional to T^2, n^(-3), d^(-4) and ϵ^2 with respect to temperature (T), density (n), interlayer separation (d~nm) and dielectric constant (ϵ_2), respectively.Dependency of drag resistivity is measured and compared to 2D e-e and e-h coupled-layer systems with and without the effect of non-homogeneous dielectric medium.
我们从理论上研究了空穴静态势的库仑阻力现象,并使用随机相位近似(RPA)方法进行了数值测量。在两种原子薄材料(如BLG/GaAs基多层系统)的几何形状下,在低温、大的层间分离极限和弱屏蔽区下评估了阻力电阻率,在纳米材料和技术中是一个很有前途的系统。静态局部场校正(LFC)被认为考虑了交换相关性(XC)和与不同浓度的有源层和无源层的相互作用效应。研究发现,使用LFC效应会增强阻力电阻率,并随着有效质量的增加而增加,阻力电阻率与T^2、n^(-3)、d^(-4)和ε^2分别与温度(T)、密度(n)、层间分离(d~nm)和介电常数(ε_2)成正比。测量了阻力电阻率的相关性,并将其与有和无非均匀介质影响的二维e-e和e-h耦合层系统进行了比较。
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引用次数: 0
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Current Nanomaterials
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