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Normal Dirac semimetal phase and Zeeman-Induced topological Fermi arc in PtSr5 PtSr5中正态Dirac半金属相和zeeman诱导的拓扑费米弧
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-01 DOI: 10.1016/j.cap.2025.10.012
Inkyou Lee , Churlhi Lyi , Youngkuk Kim
Pt–Sr binary intermetallics encompass a broad range of stoichiometries and crystal structures, stabilized by complex bonding and multivalent chemistry. The Sr-rich end member, PtSr5, was recently identified via artificial-intelligence–guided materials design as a body-centered tetragonal compound (I4/m) [1]. Using first-principles calculations, we show that PtSr5 hosts a Dirac semimetal phase with trivial Z2 topology, classified as a normal Dirac semimetal. A symmetry-indicator analysis based on parity eigenvalues at the eight time-reversal-invariant momenta confirms that all Z2 invariants—evaluated on time-reversal-invariant two-dimensional subspaces of momentum space with a direct band gap—are trivial, thereby establishing the topologically trivial nature of the Dirac semimetal phase. Nonetheless, our calculations reveal that applying an external Zeeman magnetic field along the z-axis drives the system into a Weyl semimetal phase, as corroborated by characteristic changes in the computed surface states. This work demonstrates the tunability of topological phases in PtSr5 via external perturbations and highlights the effectiveness of AI-based materials exploration in discovering new quantum materials.
Pt-Sr二元金属间化合物包含广泛的化学计量和晶体结构,通过复杂的键和多价化学来稳定。富sr末端成员PtSr5最近通过人工智能引导材料设计被确定为体心四边形化合物(I4/m)[1]。使用第一性原理计算,我们证明了PtSr5具有平凡的Z2拓扑结构的狄拉克半金属相,被归类为正常的狄拉克半金属。基于八个时间逆不变动量的奇偶性特征值的对称指示分析证实了所有在具有直接带隙的动量空间的时间逆不变二维子空间上计算的Z2不变量都是平凡的,从而建立了Dirac半金属相的拓扑平凡性质。尽管如此,我们的计算表明,沿着z轴施加一个外部塞曼磁场将系统驱动到Weyl半金属相,正如计算表面状态的特征变化所证实的那样。这项工作证明了PtSr5的拓扑相在外部扰动下的可调性,并强调了基于人工智能的材料探索在发现新量子材料方面的有效性。
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引用次数: 0
Magnetic field modulation of photocurrent in NiFe/n-Si magneto-photovoltaic heterojunctions for multifunctional optoelectronic applications 多功能光电应用中NiFe/n-Si磁光伏异质结光电流的磁场调制
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-27 DOI: 10.1016/j.cap.2025.10.013
Zhibo Zhou, Nan Sun, Qian Cao, Jican Hao, Hao Geng, Ning Fang, Ziyao Zhou
Magnetically tunable optoelectronic devices that integrate sensing and energy-harvesting functionalities hold significant potential for next-generation electronics and wearable technologies. Here, we demonstrate a multifunctional, self-powered optoelectronic device based on a Ni80Fe20 (permalloy) ferromagnetic thin film interfaced with n-type silicon (n-Si), forming a magneto-photovoltaic heterojunction. This structure enables self-powered operation under illumination, leveraging the built-in electric field at the heterojunction interface to efficiently separate photogenerated carriers without external bias. The device generates a photocurrent upon light exposure, which can be modulated by external magnetic fields. A photocurrent modulation of up to 33 % is achieved, with the modulation magnitude strongly dependent on the NiFe film thickness and the applied magnetic field strength. This tunability arises from the combined effects of Lorentz-force-induced carrier deflection, spin-dependent scattering, and interfacial magnetostrictive strain, which collectively influence the transport dynamics of photogenerated carriers. These findings demonstrate that Cu/Ni80Fe20/n-Si heterojunctions offer a versatile platform for multifunctional optoelectronic applications, such as the photodetector.
集成传感和能量收集功能的磁可调谐光电器件在下一代电子和可穿戴技术中具有巨大的潜力。在这里,我们展示了一种基于Ni80Fe20 (permalloy)铁磁薄膜与n型硅(n-Si)界面的多功能自供电光电器件,形成磁光电异质结。这种结构能够在照明下自供电,利用异质结界面上的内置电场,有效地分离光生载流子,而没有外部偏置。该装置在光照射时产生光电流,该光电流可由外部磁场调制。实现了高达33%的光电流调制,调制幅度强烈依赖于NiFe薄膜厚度和外加磁场强度。这种可调性源于洛伦兹力诱导的载流子偏转、自旋相关散射和界面磁致伸缩应变的综合效应,它们共同影响光生载流子的输运动力学。这些发现表明,Cu/Ni80Fe20/n-Si异质结为光电探测器等多功能光电应用提供了一个通用平台。
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引用次数: 0
Optical and fluorescence behavior of Er3+-Doped low-melting lead borosilicate glass for laser applications 掺Er3+低熔点硼硅酸铅激光玻璃的光学和荧光性能
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-05 DOI: 10.1016/j.cap.2025.11.002
Mohamed Eltohamy , Ibrahim Youssof , Mohamed S. Abdel Aal , Roshdi Seoudi
This study explores the optical and fluorescence properties of Er3+-doped, low-melting lead borosilicate glass, formulated specifically for potential laser applications. The glass compositions are based on a weight percent system and include 23.54 wt% SiO2, 4.45 wt% Na2O, 2.96 wt% CaO, 1.34 wt% MgO, 0.04 wt% Al2O3, 0.03 wt% Fe2O3, 36.25 wt% B2O3, 31.39 wt% PbO, and varying Er2O3 contents of x = 0, 1, 2, or 3 wt% were synthesized via melt-quenching. Structural and optical characterizations were carried out using X-ray diffraction (XRD), FTIR spectroscopy, UV–Vis–NIR absorption, and photoluminescence (PL) spectroscopy. XRD confirmed the amorphous nature of all samples, while FTIR spectra revealed vibrational bands attributed to borate and silicate groups. The absorption spectra showed distinct Er3+ transitions at 378, 406, 450, 488, 520, 542, 652, 798, 972, 1490, and 1525 nm, corresponding to transitions from the ground state 4I15/2 to excited states, 4I13/2, 4I11/2, 4I9/2, 4F9/2, 4S3/2, 2H11/2, 4F7/2, 4F5/2, and 2G9/2, respectively. Increasing Er2O3 concentration led to a reduction in the optical band gap from 3.23 eV to 2.66 eV, indicating enhanced interaction between Er3+ ions and the glass matrix. Under excitation at various wavelengths (250–980 nm), strong near-infrared fluorescence centered at 1531 nm was observed, particularly due to the 4I13/2  4I15/2 transition following 980 nm excitation. These results confirm the suitability of the developed glass system for tunable laser and photonic applications.
本研究探索了Er3+掺杂的低熔点硼硅酸盐铅玻璃的光学和荧光特性,该玻璃是专门为潜在的激光应用而配制的。玻璃成分基于重量百分比体系,包括23.54 wt% SiO2, 4.45 wt% Na2O, 2.96 wt% CaO, 1.34 wt% MgO, 0.04 wt% Al2O3, 0.03 wt% Fe2O3, 36.25 wt% B2O3, 31.39 wt% PbO,以及不同的Er2O3含量x = 0, 1, 2或3 wt%通过熔融淬火合成。利用x射线衍射(XRD)、红外光谱(FTIR)、紫外-可见-近红外(UV-Vis-NIR)吸收和光致发光(PL)光谱对其进行了结构和光学表征。XRD证实了所有样品的无定形性质,而FTIR光谱显示了属于硼酸盐和硅酸盐基团的振动带。吸收光谱在378、406、450、488、520、542、652、798、972、1490和1525 nm处有明显的Er3+跃迁,分别对应于从基态4I15/2到激发态、4I13/2、4I11/2、4I9/2、4F9/2、4S3/2、2H11/2、4F7/2、4F5/2和2G9/2的跃迁。Er2O3浓度的增加导致光学带隙从3.23 eV减小到2.66 eV,表明Er3+离子与玻璃基体之间的相互作用增强。在不同波长(250-980 nm)激发下,观察到以1531 nm为中心的强近红外荧光,特别是由于980 nm激发后的4I13/2→4I15/2转变。这些结果证实了所开发的玻璃系统在可调谐激光和光子应用中的适用性。
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引用次数: 0
Dynamic X-ray magnetic circular dichroism of yttrium iron garnet 钇铁石榴石的动态x射线磁性圆二色性
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-27 DOI: 10.1016/j.cap.2025.10.015
Changsoo Kim , Kyongmo An , Kyoung-Woong Moon , Younghak Kim , Chanyong Hwang
High-brilliance X-rays with a broad energy range, provided by synchrotron facilities, have played a crucial role in revealing the electronic, magnetic, and lattice properties of condensed matter systems. Recently, the pulsed nature of synchrotron X-rays has enabled a variety of time-resolved experiments. In this study, we employed a time-resolved XFMR (X-ray Ferromagnetic Resonance) technique to measure the dynamic XMCD (X-ray Magnetic Circular Dichroism) spectrum of Yttrium Iron Garnet by probing the precessional motion of magnetization. The dynamic XMCD spectrum, obtained by sweeping the X-ray photon energy under the optimal XFMR condition, provides information comparable to that of static XMCD. Due to the fluorescence-based detection scheme of XFMR, the L2 peak appears with high clarity, and the baseline remains flat and artifact-free, demonstrating the potential of dynamic XMCD as a powerful alternative to conventional XMCD techniques.
由同步加速器设备提供的具有宽能量范围的高亮度x射线在揭示凝聚态物质系统的电子,磁性和晶格性质方面发挥了至关重要的作用。最近,同步加速器x射线的脉冲特性使各种时间分辨实验成为可能。在这项研究中,我们采用时间分辨的XFMR (x射线铁磁共振)技术,通过探测磁化的进动运动来测量钇铁石榴石的动态XMCD (x射线磁圆二色)光谱。在最佳XFMR条件下,通过扫描x射线光子能量获得的动态XMCD光谱提供了与静态XMCD相当的信息。由于XFMR基于荧光的检测方案,L2峰具有高清晰度,基线保持平坦且无伪影,表明动态XMCD作为传统XMCD技术的强大替代方案的潜力。
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引用次数: 0
Graphene electrodes decorated with starch-derived carbon dots for flexible supercapacitors 用淀粉衍生碳点装饰的石墨烯电极,用于柔性超级电容器
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-11-10 DOI: 10.1016/j.cap.2025.11.005
V.C. Suchitra , R. Athira , V. Anunanda , Sithara , S.P. Vaiga Sagar , P.C. Rilu Fathima , K. Fathima Rameeza , T.A. Ramseena , N.N. Binitha
Flexible supercapacitors are essential for wearable electronics due to their mechanical resilience. This study uses soluble starch, a carbohydrate-based milling agent, for the mechanochemical exfoliation of graphite into few-layered, less-defective graphene. Hydrothermal treatment of the milled mixture containing starch yields carbon dot (CD)-decorated graphene. Material characterization confirms the turbostratic graphene structure, its edge functionalities, and CD distribution over the sheets. Electrochemical evaluation in a three-electrode system shows a specific capacitance of 614.1 F/g at 3 A/g, low charge transfer resistance, 98.3 % coulombic efficiency, and 100 % capacitance retention over 12,000 cycles. CD/graphene follows more of a pseudocapacitive mechanism with 80 % diffusive contribution. A flexible symmetric device using CD/graphene achieves 99.6 F/g (139.45 mF/cm2) specific capacitance, 13.8 Wh/kg energy density, and 714.3 W/kg power density. It retains 100 % capacitance after 2000 cycles and performs reliably under bending, twisting and folding. Three devices in series successfully light a green LED and decorative light, demonstrating real-world applicability.
由于其机械弹性,柔性超级电容器对可穿戴电子产品至关重要。本研究使用可溶性淀粉(一种基于碳水化合物的磨粉剂)将石墨机械化学剥落成层数少、缺陷少的石墨烯。水热处理含有淀粉的研磨混合物可以得到碳点(CD)修饰的石墨烯。材料表征证实了石墨烯的涡轮层结构、边缘功能和CD在薄片上的分布。电化学评价表明,在3a /g下,三电极系统的比电容为614.1 F/g,电荷转移电阻低,库仑效率98.3%,在12,000次循环中电容保持率100%。CD/石墨烯更多地遵循伪电容机制,具有80%的扩散贡献。采用CD/石墨烯的柔性对称器件可实现99.6 F/g (139.45 mF/cm2)比电容、13.8 Wh/kg能量密度和714.3 W/kg功率密度。经过2000次循环后,它保持100%的电容,在弯曲,扭曲和折叠下性能可靠。三个器件串联成功点亮绿色LED和装饰灯,展示了现实世界的适用性。
{"title":"Graphene electrodes decorated with starch-derived carbon dots for flexible supercapacitors","authors":"V.C. Suchitra ,&nbsp;R. Athira ,&nbsp;V. Anunanda ,&nbsp;Sithara ,&nbsp;S.P. Vaiga Sagar ,&nbsp;P.C. Rilu Fathima ,&nbsp;K. Fathima Rameeza ,&nbsp;T.A. Ramseena ,&nbsp;N.N. Binitha","doi":"10.1016/j.cap.2025.11.005","DOIUrl":"10.1016/j.cap.2025.11.005","url":null,"abstract":"<div><div>Flexible supercapacitors are essential for wearable electronics due to their mechanical resilience. This study uses soluble starch, a carbohydrate-based milling agent, for the mechanochemical exfoliation of graphite into few-layered, less-defective graphene. Hydrothermal treatment of the milled mixture containing starch yields carbon dot (CD)-decorated graphene. Material characterization confirms the turbostratic graphene structure, its edge functionalities, and CD distribution over the sheets. Electrochemical evaluation in a three-electrode system shows a specific capacitance of 614.1 F/g at 3 A/g, low charge transfer resistance, 98.3 % coulombic efficiency, and 100 % capacitance retention over 12,000 cycles. CD/graphene follows more of a pseudocapacitive mechanism with 80 % diffusive contribution. A flexible symmetric device using CD/graphene achieves 99.6 F/g (139.45 mF/cm<sup>2</sup>) specific capacitance, 13.8 Wh/kg energy density, and 714.3 W/kg power density. It retains 100 % capacitance after 2000 cycles and performs reliably under bending, twisting and folding. Three devices in series successfully light a green LED and decorative light, demonstrating real-world applicability.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"81 ","pages":"Pages 57-65"},"PeriodicalIF":3.1,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145526601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Novel green synthesis approach of Fe3O4-MSN/Ag nanocomposite using moringa oleifera extract for magnetic hyperthermia applications” [Curr. Appl. Phys. 68 (2024) 242–256] “用辣木提取物合成Fe3O4-MSN/Ag纳米复合材料的新型绿色合成方法,用于磁热疗应用”的更正[当前]。达成。物理学报,68 (2024)242-256]
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-06-21 DOI: 10.1016/j.cap.2025.06.006
Mahardika Yoga Darmawan , Marhan bit Saputra , Leni Rumiyanti , Nurul Imani Istiqomah , Nanang Adrianto , Rivald Moarsel Tumbelaka , Harlina Ardiyanti , Nur Aji Wibowo , Nining Sumawati Asri , Julia Angel , Hasniah Aliah , Ari Dwi Nugraheni , Edi Suharyadi
{"title":"Corrigendum to “Novel green synthesis approach of Fe3O4-MSN/Ag nanocomposite using moringa oleifera extract for magnetic hyperthermia applications” [Curr. Appl. Phys. 68 (2024) 242–256]","authors":"Mahardika Yoga Darmawan ,&nbsp;Marhan bit Saputra ,&nbsp;Leni Rumiyanti ,&nbsp;Nurul Imani Istiqomah ,&nbsp;Nanang Adrianto ,&nbsp;Rivald Moarsel Tumbelaka ,&nbsp;Harlina Ardiyanti ,&nbsp;Nur Aji Wibowo ,&nbsp;Nining Sumawati Asri ,&nbsp;Julia Angel ,&nbsp;Hasniah Aliah ,&nbsp;Ari Dwi Nugraheni ,&nbsp;Edi Suharyadi","doi":"10.1016/j.cap.2025.06.006","DOIUrl":"10.1016/j.cap.2025.06.006","url":null,"abstract":"","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"81 ","pages":"Page 66"},"PeriodicalIF":3.1,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145620961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green copper magnesium alluminate hybrid nanomaterial for electrochemical energy storage, sensor and photocatalytic dye degradation applications 绿色铜镁铝酸盐杂化纳米材料在电化学储能、传感器和光催化染料降解等方面的应用
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 Epub Date: 2025-10-29 DOI: 10.1016/j.cap.2025.10.014
Harini H.V , Nagaswarupa H.P , Yashwanth Venkatraman Naik , Ramachandra Naik , Burragoni Sravanthi Goud , Jae Hong Kim , Saravanan Pandiaraj , Khalid E. Alzahrani
Sol gel synthesis of Copper Magnesium Alluminate (CuMA) hybrid nanomaterial have been carried out and obtained product was characterized using X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Transmission electron microscope (TEM), and UV–visible absorption (UV-DRS) techniques. XRD analysis confirmed the formation of a biphasic structure comprising CuAl2O4 and MgAl2O4 spinels. Estimated crystallite size and band gap was found to be 26.9 nm 3.8 eV respectively with nanoflake shaped morphology. Electrochemical analysis was carried out using CuMA nanoparticles modified carbon paste electrode by Cyclic Voltammetry (CV), Electrochemical Impedance Spectroscopy (EIS), Galvanostatic Charge–Discharge (GCD) techniques and enhanced specific capacitance of 401 Fg-1 from CV were obtained. Further, electrode was used as a sensor for the detection of paracetamol. Photocatalytic Acid-red-88 dye degradation using CuMA nanoparticles as photocatalyst was observed to be 93.6 % degradation. Therefore, this material can be used for multifunctional energy applications.
采用溶胶-凝胶法合成了铜镁铝酸盐(CuMA)杂化纳米材料,并利用x射线衍射分析(XRD)、x射线光电子能谱(XPS)、傅里叶变换红外光谱(FTIR)、扫描电镜(SEM)、透射电镜(TEM)和紫外-可见吸收(UV-DRS)等技术对产物进行了表征。XRD分析证实形成了由CuAl2O4和MgAl2O4尖晶石组成的双相结构。晶体尺寸和带隙分别为26.9 nm和3.8 eV,形貌呈纳米片状。采用循环伏安法(CV)、电化学阻抗谱(EIS)、恒流充放电(GCD)技术对CuMA纳米颗粒修饰的碳浆电极进行了电化学分析,得到了401gf -1在循环伏安法(CV)下的增强比电容。进一步将电极作为传感器用于对乙酰氨基酚的检测。以CuMA纳米粒子为光催化剂,光催化降解酸性红-88染料,降解率为93.6%。因此,该材料可用于多功能能源应用。
{"title":"Green copper magnesium alluminate hybrid nanomaterial for electrochemical energy storage, sensor and photocatalytic dye degradation applications","authors":"Harini H.V ,&nbsp;Nagaswarupa H.P ,&nbsp;Yashwanth Venkatraman Naik ,&nbsp;Ramachandra Naik ,&nbsp;Burragoni Sravanthi Goud ,&nbsp;Jae Hong Kim ,&nbsp;Saravanan Pandiaraj ,&nbsp;Khalid E. Alzahrani","doi":"10.1016/j.cap.2025.10.014","DOIUrl":"10.1016/j.cap.2025.10.014","url":null,"abstract":"<div><div>Sol gel synthesis of Copper Magnesium Alluminate (CuMA) hybrid nanomaterial have been carried out and obtained product was characterized using X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), Transmission electron microscope (TEM), and UV–visible absorption (UV-DRS) techniques. XRD analysis confirmed the formation of a biphasic structure comprising CuAl<sub>2</sub>O<sub>4</sub> and MgAl<sub>2</sub>O<sub>4</sub> spinels. Estimated crystallite size and band gap was found to be 26.9 nm 3.8 eV respectively with nanoflake shaped morphology. Electrochemical analysis was carried out using CuMA nanoparticles modified carbon paste electrode by Cyclic Voltammetry (CV), Electrochemical Impedance Spectroscopy (EIS), Galvanostatic Charge–Discharge (GCD) techniques and enhanced specific capacitance of 401 Fg<sup>-1</sup> from CV were obtained. Further, electrode was used as a sensor for the detection of paracetamol. Photocatalytic Acid-red-88 dye degradation using CuMA nanoparticles as photocatalyst was observed to be 93.6 % degradation. Therefore, this material can be used for multifunctional energy applications.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"81 ","pages":"Pages 15-28"},"PeriodicalIF":3.1,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145464817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative morphological analysis of electrospun PAN/PVDF nanofibers for waterproof breathable membrane applications 静电纺PAN/PVDF纳米纤维防水透气膜的形态对比分析
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-09-22 DOI: 10.1016/j.cap.2025.09.017
Wahyu Solafide Sipahutar , Rizky Aflaha , Alex Triputra Lumban Tobing , Tarmizi Taher , Kuwat Triyana , Hutomo Suryo Wasisto , Aldes Lesbani , Aditya Rianjanu
Waterproof and breathable membranes are critical for protective textiles, filtration, and wearable applications. However, balancing water resistance with vapor permeability remains challenging. This study investigates the morphological effects of electrospun polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) nanofiber membranes on their waterproofness, breathability, and mechanical integrity. Varying polymer concentration can control fiber diameter (224–1379 nm) and bead formation, influencing membrane properties. Increasing fiber diameter enhances mechanical strength, with Young's modulus rising from 22.5 MPa to 34.1 MPa. All fabricated membranes exhibit excellent waterproofness, while the larger, bead-free fibers possess improved water vapor transmission and slightly reduced air permeability. FTIR analysis confirms consistent chemical composition across samples. These findings demonstrate that nanofiber morphology can be tailored to optimize performance, offering valuable insights for the development of multifunctional membranes for environmental, industrial, and wearable use.
防水和透气膜对防护纺织品、过滤和可穿戴应用至关重要。然而,平衡抗水性和透气性仍然是一个挑战。本研究研究了聚丙烯腈/聚偏氟乙烯(PAN/PVDF)纳米纤维膜的形态对其防水、透气性和机械完整性的影响。不同的聚合物浓度可以控制纤维直径(224-1379 nm)和珠粒的形成,影响膜的性能。纤维直径增大,机械强度提高,杨氏模量由22.5 MPa增加到34.1 MPa。所有制备的膜都具有优异的防水性能,而较大的无珠纤维具有改善的水蒸气透过性和略微降低的透气性。FTIR分析证实样品的化学成分一致。这些发现表明,纳米纤维形态可以定制以优化性能,为开发用于环境、工业和可穿戴用途的多功能膜提供了有价值的见解。
{"title":"Comparative morphological analysis of electrospun PAN/PVDF nanofibers for waterproof breathable membrane applications","authors":"Wahyu Solafide Sipahutar ,&nbsp;Rizky Aflaha ,&nbsp;Alex Triputra Lumban Tobing ,&nbsp;Tarmizi Taher ,&nbsp;Kuwat Triyana ,&nbsp;Hutomo Suryo Wasisto ,&nbsp;Aldes Lesbani ,&nbsp;Aditya Rianjanu","doi":"10.1016/j.cap.2025.09.017","DOIUrl":"10.1016/j.cap.2025.09.017","url":null,"abstract":"<div><div>Waterproof and breathable membranes are critical for protective textiles, filtration, and wearable applications. However, balancing water resistance with vapor permeability remains challenging. This study investigates the morphological effects of electrospun polyacrylonitrile/polyvinylidene fluoride (PAN/PVDF) nanofiber membranes on their waterproofness, breathability, and mechanical integrity. Varying polymer concentration can control fiber diameter (224–1379 nm) and bead formation, influencing membrane properties. Increasing fiber diameter enhances mechanical strength, with Young's modulus rising from 22.5 MPa to 34.1 MPa. All fabricated membranes exhibit excellent waterproofness, while the larger, bead-free fibers possess improved water vapor transmission and slightly reduced air permeability. FTIR analysis confirms consistent chemical composition across samples. These findings demonstrate that nanofiber morphology can be tailored to optimize performance, offering valuable insights for the development of multifunctional membranes for environmental, industrial, and wearable use.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"80 ","pages":"Pages 224-233"},"PeriodicalIF":3.1,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Low hysteresis loss and moderate magnetic entropy change near room temperature in the bulk Ni39Co7Mn43Sn7Ti4 alloy Ni39Co7Mn43Sn7Ti4块体合金在室温附近磁滞损失低,磁熵变化适中
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-09-24 DOI: 10.1016/j.cap.2025.09.021
F. Chen , C.F. Sánchez-Valdés , F.H. Chen , Y.X. Tong , L. Li
Ni-Co-Mn-Sn alloys with a significant magnetocaloric effect are considered promising candidates for room-temperature magnetic refrigeration. Alloying serves as an effective method to tune the working temperature and magnetocaloric properties of Ni-Co-Mn-Sn alloys. Here, we report the phase transformation and magnetocaloric properties of polycrystalline Ni39Co7Mn43Sn7Ti4 by alloying with a relatively high Ti content. This alloy displays a first-order martensitic transformation (MT) near room temperature and a second-order magnetic transition in austenite at 366 K. The application of a magnetic field significantly widened the temperature range of the MT, thereby contributing to a substantial effective refrigeration capacity of 198 J kg−1 at a magnetic field change of 5 T. Moreover, the alloy exhibits simultaneously a moderate isothermal magnetic entropy change (12.2 J kg−1 K−1) and a low average hysteresis loss (40 J kg−1) due to the weakened magnetic field-induced reverse martensitic transformation caused by Ti alloying.
具有显著磁热效应的Ni-Co-Mn-Sn合金被认为是室温磁制冷的有希望的候选材料。合金化是调节Ni-Co-Mn-Sn合金工作温度和磁热性能的有效方法。本文报道了采用较高Ti含量合金制备Ni39Co7Mn43Sn7Ti4多晶的相变和磁热性能。该合金在室温附近表现为一阶马氏体相变,在366 K时表现为二阶奥氏体磁转变。磁场的施加显著地扩大了MT的温度范围,从而在5 t的磁场变化下获得了198 J kg−1的有效制冷能力。此外,由于Ti合金化引起的磁场诱导的反向马氏体相变减弱,合金同时表现出中等的等温磁熵变化(12.2 J kg−1 K−1)和较低的平均磁滞损失(40 J kg−1)。
{"title":"Low hysteresis loss and moderate magnetic entropy change near room temperature in the bulk Ni39Co7Mn43Sn7Ti4 alloy","authors":"F. Chen ,&nbsp;C.F. Sánchez-Valdés ,&nbsp;F.H. Chen ,&nbsp;Y.X. Tong ,&nbsp;L. Li","doi":"10.1016/j.cap.2025.09.021","DOIUrl":"10.1016/j.cap.2025.09.021","url":null,"abstract":"<div><div>Ni-Co-Mn-Sn alloys with a significant magnetocaloric effect are considered promising candidates for room-temperature magnetic refrigeration. Alloying serves as an effective method to tune the working temperature and magnetocaloric properties of Ni-Co-Mn-Sn alloys. Here, we report the phase transformation and magnetocaloric properties of polycrys<strong>talline Ni<sub>39</sub>Co<sub>7</sub>Mn<sub>43</sub>Sn<sub>7</sub>Ti<sub>4</sub> by alloying with a relatively high Ti content. This alloy displays a first-order martensitic transformation (MT) near room temperature and a second-order magnetic transition in austenite at 366 K. The application of a magnetic field significantly widened the temperature range of the MT, thereby contributing to a substantial effective refrigeration capacity of 198 J kg<sup>−1</sup> at a magnetic field change of 5 T. Moreover, the alloy exhibits simultaneously a moderate isothermal magnetic entropy change (12.2 J kg<sup>−1</sup></strong> <strong>K<sup>−1</sup>) and a low average hysteresis loss (40 J kg<sup>−1</sup>) due to the weakened magnetic field-induced reverse martensitic transformation caused by Ti alloying</strong>.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"80 ","pages":"Pages 213-218"},"PeriodicalIF":3.1,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145154823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A nanowatt oscillator powered only by 68 MeV proton irradiation of a crystalline silicon photodiode pair 晶体硅光电二极管对仅由68兆电子伏特质子辐照供电的纳瓦振荡器
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-12-01 Epub Date: 2025-10-08 DOI: 10.1016/j.cap.2025.10.004
Heinz-Christoph Neitzert , Arpana Singh , Alina Hanna Dittwald , Georgios Kourkafas
It is shown, that an ultra-low-power voltage controlled oscillator, realized with conventional NAND gates in ring-oscillator configuration, can be operated by a series connected pair of commercial Silicon pin solar cells, only irradiated by a high energy proton beam as power supply. However a very fast degradation of the solar cells is observed, leading to a stop of the oscillator operation after a very short time. By monitoring the oscillator frequency changes when the stack of photodiodes, in this case illuminated with weak ambient light, is not directly exposed to the proton beam but positioned in different positions close to the proton beam, an evaluation of the off-beam-axis irradiation damage could be done. A detailed electrical analysis of the photodiode properties before and after the direct proton irradiation has been added.
结果表明,采用传统的环形振荡器结构的NAND门实现的超低功耗压控振荡器,可以由一对串联的商用硅引脚太阳能电池来工作,只需以高能质子束照射作为电源。然而,观察到太阳能电池的快速退化,导致振荡器在很短的时间后停止运行。在弱环境光照射下,当光电二极管堆叠不直接暴露在质子束中,而是放置在靠近质子束的不同位置时,通过监测振荡器频率的变化,可以对离束轴辐射损伤进行评估。详细分析了质子直接辐照前后光电二极管的电学特性。
{"title":"A nanowatt oscillator powered only by 68 MeV proton irradiation of a crystalline silicon photodiode pair","authors":"Heinz-Christoph Neitzert ,&nbsp;Arpana Singh ,&nbsp;Alina Hanna Dittwald ,&nbsp;Georgios Kourkafas","doi":"10.1016/j.cap.2025.10.004","DOIUrl":"10.1016/j.cap.2025.10.004","url":null,"abstract":"<div><div>It is shown, that an ultra-low-power voltage controlled oscillator, realized with conventional NAND gates in ring-oscillator configuration, can be operated by a series connected pair of commercial Silicon pin solar cells, only irradiated by a high energy proton beam as power supply. However a very fast degradation of the solar cells is observed, leading to a stop of the oscillator operation after a very short time. By monitoring the oscillator frequency changes when the stack of photodiodes, in this case illuminated with weak ambient light, is not directly exposed to the proton beam but positioned in different positions close to the proton beam, an evaluation of the off-beam-axis irradiation damage could be done. A detailed electrical analysis of the photodiode properties before and after the direct proton irradiation has been added.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"80 ","pages":"Pages 306-310"},"PeriodicalIF":3.1,"publicationDate":"2025-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145262498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Current Applied Physics
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