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Two-level system loss characterization of NbTi superconducting resonators on Si/SiO2 substrates Si/SiO2衬底NbTi超导谐振器的双能级系统损耗特性
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-18 DOI: 10.1016/j.cap.2025.10.010
Bongkeon Kim, Yong-Joo Doh
Superconducting coplanar waveguide (SCPW) resonators, key components for quantum computing and sensing applications, require a high internal quality factor (Qi) for effective qubit readout and quantum sensing applications. Minimizing two-level system (TLS) losses, particularly at material interfaces, is critical for gatemon and topological qubits operating at low temperatures and in high magnetic fields. NbTi, a superconducting alloy with a high upper critical field, enables SCPW resonators resilient to such conditions. We fabricated NbTi SCPW resonators on Si/SiO2 substrates and systematically characterized their TLS-limited quality factors as functions of temperature and microwave photon number. Our results demonstrate that NbTi-based SCPWs on Si/SiO2 substrates provide a promising platform for developing next-generation quantum circuits.
超导共面波导(SCPW)谐振器是量子计算和传感应用的关键部件,它需要高的内部质量因子(Qi)来实现有效的量子比特读出和量子传感应用。最小化两级系统(TLS)损耗,特别是在材料界面,对于在低温和高磁场下工作的门子和拓扑量子位至关重要。NbTi是一种超导合金,具有较高的上限临界场,使SCPW谐振器能够适应这种条件。我们在Si/SiO2衬底上制备了NbTi SCPW谐振器,并系统地表征了其tls限制质量因子与温度和微波光子数的关系。我们的研究结果表明,基于nbti的Si/SiO2衬底上的SCPWs为开发下一代量子电路提供了一个有前途的平台。
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引用次数: 0
Landau-Devonshire theory-based phase diagram of the bismuth ferrite and barium titanate solid solution 铁酸铋和钛酸钡固溶体的Landau-Devonshire相图
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-16 DOI: 10.1016/j.cap.2025.10.009
Hae In Choi , Myang Hwan Lee , Won-Jeong Kim , Tae Kwon Song
The development of high-performance, lead-free piezoelectric ceramics is essential for modern sensor and actuator applications. Bismuth ferrite-based solid solutions, like (1-x)BiFeO3-xBaTiO3 (BF-BT), are promising due to their high Curie temperature and high piezoelectric performance, but ambiguities persist regarding their phase transitions and the exact location of the morphotropic phase boundary (MPB), where piezoelectric properties are maximized. This study resolves these issues by applying Landau-Devonshire theory to construct a comprehensive phase diagram for the BF-BT system. By calculating the free energy density landscape, our theoretical model accurately reproduces the material's composition-dependent properties. The resulting phase diagram agrees well with experimental observations, predicting a coexistence of rhombohedral and tetragonal phases near x = 0.33. And our calculations identify the MPB at a composition of x = 0.375, consistent with the experimentally reported range. These findings highlight the link between phase structure and piezoelectric performance.
高性能、无铅压电陶瓷的发展对现代传感器和执行器的应用至关重要。铋铁氧体为基础的固溶体,如(1-x)BiFeO3-xBaTiO3 (BF-BT),由于其高居里温度和高压电性能而很有前途,但关于它们的相变和取向相边界(MPB)的确切位置(压电性能最大化)仍然存在歧义。本研究运用Landau-Devonshire理论构建BF-BT系统的综合相图,解决了这些问题。通过计算自由能密度景观,我们的理论模型准确地再现了材料的成分依赖属性。得到的相图与实验观察结果吻合良好,预测在x = 0.33附近存在菱形相和四方相共存。我们的计算确定了MPB的组成为x = 0.375,与实验报告的范围一致。这些发现突出了相结构和压电性能之间的联系。
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引用次数: 0
Proton doping of graphene FETs enabled by ionic modulation from polysilazane dielectrics 质子掺杂石墨烯fet的离子调制从聚硅氮烷电介质
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-16 DOI: 10.1016/j.cap.2025.10.006
Kyungmin Park, Garam Bae
Graphene field-effect transistors offer great potential for next-generation electronics due to graphene's high carrier mobility and atomic-scale thickness. However, stable device operation requires precise control of the dielectric interface, which impacts carrier transport and doping. In this study, we use solution-processed polysilazane (PSZ)-derived dielectrics as both gate insulators and active ionic environments for modulating graphene's electronic properties. The PSZ films, processed under humid conditions, generate hydroxyl-rich surfaces that serve as proton reservoirs. Electrical characterization and in-situ Raman spectroscopy show that gate bias induces proton doping of graphene, manifesting as hysteresis, Dirac point shifts, and D-band enhancement arising from phonon activation and interfacial Coulombic perturbations. The device also exhibits characteristic doping and relaxation times, revealing proton migration dynamics. Our findings suggest that PSZ dielectrics provide both gate insulation and dynamic electrochemical modulation of the graphene channel, offering a new strategy for dielectric interface engineering in 2D electronic devices.
由于石墨烯的高载流子迁移率和原子尺度厚度,石墨烯场效应晶体管为下一代电子产品提供了巨大的潜力。然而,稳定的器件运行需要精确控制介电界面,这会影响载流子输运和掺杂。在这项研究中,我们使用溶液处理的聚硅氮烷(PSZ)衍生的电介质作为栅极绝缘体和活性离子环境来调节石墨烯的电子特性。在潮湿条件下加工的PSZ薄膜产生富含羟基的表面,作为质子储存器。电学表征和原位拉曼光谱分析表明,栅极偏压诱导石墨烯的质子掺杂,表现为迟滞、狄拉克点位移和声子激活和界面库仑扰动引起的d波段增强。该装置还显示出特有的掺杂和弛豫时间,揭示了质子迁移动力学。我们的研究结果表明,PSZ介电材料提供了栅极绝缘和石墨烯通道的动态电化学调制,为二维电子器件的介电界面工程提供了一种新的策略。
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引用次数: 0
Localized and delocalized electron states in TiO2 revealed using resonant inelastic soft X-ray scattering 用共振非弹性软x射线散射揭示了TiO2的局域和离域电子态
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-13 DOI: 10.1016/j.cap.2025.10.005
Layla Mravac , Yi-De Chuang , Ji Hyeon Choi , Ji Won Han , Tae Joo Park , Kyung Won Park , Jae Hyuck Jang , Cheng-Tai Kuo , Deok-Yong Cho
Excess carriers in defective TiO2 play a key role in determining the functionality of numerous applications including photocatalysts, memristors, etc. The electronic structures of the excess electron states derived from inherent oxygen deficiencies in a TiO2 crystal and a TiO2 thin film are investigated by using resonant inelastic soft X-ray scattering. The results show that there exist two separable states associated with these excess electrons, that is, either local (bound) or delocalized (band-like) d electrons, and that their abundance differs significantly depending on the sample type. In the case of thin film, delocalized electron states (d-fluorescence) dominate over the localized defect states (dd excitation) showing a strong resonance effect at Ti3+’s excitation energy, whereas in the case of crystal, both localized and delocalized electron states weakly contribute to the defect states. Most plausibly, this discrepancy originates mainly from the distinct crystal structure of a rutile (crystal) and an anatase (thin film), implying that understanding the crystal structure dependence of intrinsic defects in TiO2 polymorphs is crucial for engineering TiO2's electronic transport properties.
缺陷TiO2中多余的载流子在决定许多应用的功能方面起着关键作用,包括光催化剂、忆阻器等。采用共振非弹性软x射线散射研究了TiO2晶体和TiO2薄膜中由于固有氧缺乏而产生的多余电子态的电子结构。结果表明,这些多余电子存在两种可分离态,即局域(束缚态)或离域(类带态)d电子,它们的丰度随样品类型的不同而有显著差异。在薄膜中,离域电子态(d-荧光)主导了局域缺陷态(dd激发),在Ti3+激发能处表现出很强的共振效应,而在晶体中,局域电子态和离域电子态对缺陷态的贡献都很弱。最有可能的是,这种差异主要源于金红石(晶体)和锐钛矿(薄膜)的不同晶体结构,这意味着了解TiO2多晶态中固有缺陷的晶体结构依赖性对于设计TiO2的电子输运性质至关重要。
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引用次数: 0
A nanowatt oscillator powered only by 68 MeV proton irradiation of a crystalline silicon photodiode pair 晶体硅光电二极管对仅由68兆电子伏特质子辐照供电的纳瓦振荡器
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-08 DOI: 10.1016/j.cap.2025.10.004
Heinz-Christoph Neitzert , Arpana Singh , Alina Hanna Dittwald , Georgios Kourkafas
It is shown, that an ultra-low-power voltage controlled oscillator, realized with conventional NAND gates in ring-oscillator configuration, can be operated by a series connected pair of commercial Silicon pin solar cells, only irradiated by a high energy proton beam as power supply. However a very fast degradation of the solar cells is observed, leading to a stop of the oscillator operation after a very short time. By monitoring the oscillator frequency changes when the stack of photodiodes, in this case illuminated with weak ambient light, is not directly exposed to the proton beam but positioned in different positions close to the proton beam, an evaluation of the off-beam-axis irradiation damage could be done. A detailed electrical analysis of the photodiode properties before and after the direct proton irradiation has been added.
结果表明,采用传统的环形振荡器结构的NAND门实现的超低功耗压控振荡器,可以由一对串联的商用硅引脚太阳能电池来工作,只需以高能质子束照射作为电源。然而,观察到太阳能电池的快速退化,导致振荡器在很短的时间后停止运行。在弱环境光照射下,当光电二极管堆叠不直接暴露在质子束中,而是放置在靠近质子束的不同位置时,通过监测振荡器频率的变化,可以对离束轴辐射损伤进行评估。详细分析了质子直接辐照前后光电二极管的电学特性。
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引用次数: 0
Scalable assembly of algorithmic DNA lattices using combined 3-input logic rules 使用组合3输入逻辑规则的可伸缩的算法DNA格组装
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-06 DOI: 10.1016/j.cap.2025.10.002
Thi Bich Ngoc Nguyen , Thi Hong Nhung Vu , Anshula Tandon, Sungjin Lee, Yeonju Nam, Sung Ha Park
DNA-based algorithmic self-assembly provides a versatile platform for parallel computation and nanoscale pattern generation. Logic gates constructed from DNA rule tiles enable programmable lattices capable of performing complex mathematical operations. Here, we present a combinatorial method for generating diverse algorithmic patterns using 3-input 1-output logic rules. By combining complementary rule sets (e.g., {R017, R238}) and non-complementary sets (e.g., {R019, R238}), we designed specific rule and operator tiles that reduce the number of unique tiles required while expanding the range of implementable logic functions. The resulting DNA lattices were experimentally validated using atomic force microscopy, and observed patterns closely matched theoretical predictions, demonstrating high fidelity and reliability. This approach improves scalability and efficiency compared with conventional single-rule assemblies and provides a practical route toward constructing complex computational architectures at the nanoscale, with potential applications in molecular computing, programmable nanomaterials, and DNA-based information processing.
基于dna的自组装算法为并行计算和纳米级模式生成提供了一个通用的平台。由DNA规则块构建的逻辑门使可编程晶格能够执行复杂的数学运算。在这里,我们提出了一种使用3-输入1-输出逻辑规则生成多种算法模式的组合方法。通过结合互补规则集(例如,{R017, R238})和非互补集(例如,{R019, R238}),我们设计了特定的规则和算子块,减少了所需的唯一块的数量,同时扩大了可实现逻辑函数的范围。利用原子力显微镜对得到的DNA晶格进行了实验验证,观察到的模式与理论预测非常吻合,证明了高保真度和可靠性。与传统的单规则组件相比,这种方法提高了可扩展性和效率,并为构建纳米尺度的复杂计算架构提供了一条实用途径,在分子计算、可编程纳米材料和基于dna的信息处理方面具有潜在的应用前景。
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引用次数: 0
Correlation between optical thermometry and Judd–Ofelt parameters in Er3+-doped perovskite oxides Er3+掺杂钙钛矿氧化物中光学测温与Judd-Ofelt参数的相关性
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-02 DOI: 10.1016/j.cap.2025.09.025
C.Y. Lee, J.H. Han, Y.S. Lee
We investigate the optical thermometric performance of Er3+-doped perovskite oxides with thermally coupled levels (TCLs). We obtain their optical thermometric parameters, such as their fluorescence intensity ratio and temperature sensitivity, from upconversion luminescence spectra under 980 nm excitation over a wide temperature range. Subsequently, we systematically compare these experimentally determined parameters with theoretical predictions for a TCL system, in addition to parameters derived from Judd–Ofelt (J–O) analysis, which is a well-established theoretical framework that describes the radiative transitions and intensities of rare-earth (RE) ions. A close correspondence between the experimental and theoretical results is achieved when the temperature-dependent variation of the J–O parameters and the TCL gap is considered. Our findings provide valuable insights into the roles of host-lattice effects, local crystal field variations, and defect-related phenomena in governing the thermal response of RE ion-doped phosphors for optical thermometry applications.
研究了具有热偶联能级(tcl)的Er3+掺杂钙钛矿氧化物的光学测温性能。我们从宽温度范围内980 nm激发下的上转换发光光谱中获得了它们的光学测温参数,如荧光强度比和温度灵敏度。随后,我们系统地比较了这些实验确定的参数与TCL系统的理论预测,以及从Judd-Ofelt (J-O)分析中得出的参数。Judd-Ofelt (J-O)分析是一个成熟的理论框架,描述了稀土离子的辐射跃迁和强度。当考虑温度相关的J-O参数变化和TCL间隙时,实验结果与理论结果非常吻合。我们的研究结果为宿主晶格效应、局部晶体场变化和缺陷相关现象在控制光学测温应用中稀土掺杂荧光粉的热响应中的作用提供了有价值的见解。
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引用次数: 0
Experimental and computational insights into optimizing polymer solar cell operational parameters 优化聚合物太阳能电池操作参数的实验和计算见解
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-02 DOI: 10.1016/j.cap.2025.10.003
Ibrar Ahmad , Syeeda Nida Alim , Khizar Hayat , Abdullah Shah , Sabir Shah , Said Karim Shah
This study explores the impact of active layer (AL) thickness, annealing temperatures(ATs), and interfacial materials on the performance of polymer solar cells (PSCs) based on P3HT: PCBM. AL thickness was tuned by varying spin speeds (1000–5000 rpm), with devices D1K and D4K achieving PCEs of 2.37 % and 2.17 % after thermal annealing at 130 °C. Increasing the AT to 180 °C further enhanced device efficiency. The influence of interfacial layers LiF and Ca on PSC performance and thermal stability was also investigated. Ca/Al-based devices outperformed others at lower temperatures but degraded at higher temperatures, while LiF/Al-based devices showed reduced PCE beyond ∼110 °C. To complement experiments, simulations using drift-diffusion, exciton-diffusion, and transfer-matrix models(TMM) were performed. These provided insights into photon distribution, absorption, and carrier generation, supporting the experimental outcomes. The study offers a comprehensive understanding of the interplay between device architecture and thermal treatment in optimizing PSC performance.
本研究探讨了活性层(AL)厚度、退火温度(ATs)和界面材料对基于P3HT: PCBM聚合物太阳能电池(PSCs)性能的影响。通过改变旋转速度(1000-5000 rpm)来调节AL的厚度,器件D1K和D4K在130℃热退火后的pce分别为2.37%和2.17%。将温度提高到180℃,进一步提高了器件效率。研究了界面层LiF和Ca对PSC性能和热稳定性的影响。Ca/ al基器件在较低温度下性能优于其他器件,但在较高温度下性能下降,而liff / al基器件在超过~ 110°C时PCE降低。为了补充实验,使用漂移扩散、激子扩散和转移矩阵模型(TMM)进行了模拟。这些提供了对光子分布、吸收和载流子产生的见解,支持了实验结果。该研究为优化PSC性能提供了器件结构和热处理之间的相互作用的全面理解。
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引用次数: 0
Bilayer graphene metasurface with dynamically reconfigurable terahertz perfect absorption 具有动态可重构太赫兹完美吸收的双层石墨烯超表面
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-02 DOI: 10.1016/j.cap.2025.10.001
Zhiyong Chen , Mengsi Liu , Shubo Cheng , Junqiao Wang , Yougen Yi , Boxun Li , Chaojun Tang , Fan Gao
The tunable terahertz perfect absorber based on a bilayer graphene metamaterial achieves breakthrough performance through an innovative design that combines a square array-box composite resonant cavity unit structure with dynamic Fermi level control. By adjusting the graphene Fermi level (0–0.5 eV), the absorption peak can dynamically switch from a single wide peak to a double-peak U-shaped depression, covering a tuning range of 3.99–8.91 THz. After optimization, the average absorption rate in the target frequency band reaches 97 %. This structure, through the synergistic mechanism of localized field enhancement and impedance matching, achieves the first active reconstruction of the absorption peak shape within a wide bandwidth (from a wide peak to a U-shaped peak), providing a new solution for terahertz stealth communication and high-sensitivity sensing.
基于双层石墨烯超材料的可调谐太赫兹完美吸收器通过将方形阵列-盒复合谐振腔单元结构与动态费米能级控制相结合的创新设计,实现了突破性的性能。通过调节石墨烯费米能级(0-0.5 eV),吸收峰可以从单宽峰动态切换到双峰u型凹陷,覆盖3.99-8.91太赫兹的调谐范围。优化后,目标频段的平均吸收率达到97%。该结构通过局域场增强和阻抗匹配的协同机制,首次实现了宽带宽内(从宽峰到u型峰)吸收峰形状的主动重构,为太赫兹隐身通信和高灵敏度传感提供了新的解决方案。
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引用次数: 0
Enhancement of soft magnetic properties in surface-oxidized Fe/Fe3O4 composites via Co-nanoparticle doping and hot pressing 纳米co掺杂和热压增强表面氧化Fe/Fe3O4复合材料软磁性能
IF 3.1 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2025-10-01 DOI: 10.1016/j.cap.2025.09.028
Muhammad Arif , Donghun Han , Seunghun Cha , Changsun Pak , Young-Kwang Kim , Sang Woo Kim , Bo Wha Lee , Muhammad Awais , Dongwhi Choi , Jong-Soo Rhyee
Soft magnetic composites are essential to power electronics technologies, including transformers, motors, and generators. However, as electronic devices advance, SMCs should have excellent soft magnetic properties, such as high permeability, high saturation magnetization, and reduced core loss at high frequencies. In this study, we found exceptionally high soft magnetic properties for Co nanopowder distribution in Fe3O4-coated Fe SMCs prepared via the hot-pressing technique. Incorporating Co nano-powders leads to a notable increase in density, with the most compact structure observed in the sample containing the highest Co concentration. Electrical resistivity increases to 55.54 mΩ cm for a sample containing 1 wt% Co nanopowder, compared to 15 mΩ cm for a pristine sample. The SMCs exhibit excellent soft magnetic properties, with high saturation magnetization (Ms ∼216 emu/g), high permeability (μe∼237.42) (144 % higher than the undoped sample), high DC bias performance (71.45 % at 100 kOe), and reduced core loss (Pcv, Ph, and Pe), compared to the other state-of-the-art samples. It indicates that Fe/Fe3O4-Co SMCs are highly promising for miniaturization and high-energy efficiency of electronic components.
软磁复合材料对电力电子技术至关重要,包括变压器、电动机和发电机。然而,随着电子器件的发展,SMCs应该具有优异的软磁性能,如高磁导率、高饱和磁化强度和高频下低铁芯损耗。在这项研究中,我们发现通过热压技术制备的fe3o4包覆的Fe SMCs中Co纳米粉的分布具有异常高的软磁性能。加入Co纳米粉末导致密度显著增加,在含有最高Co浓度的样品中观察到最紧凑的结构。含有1 wt% Co纳米粉的样品的电阻率增加到55.54 mΩ cm,而原始样品的电阻率为15 mΩ cm。SMCs具有优异的软磁性能,具有高饱和磁化强度(Ms ~ 216 emu/g),高磁导率(μe ~ 237.42)(比未掺杂样品高144%),高直流偏置性能(100 kOe时71.45%),与其他先进样品相比,磁芯损耗(Pcv, Ph和Pe)降低。这表明Fe/Fe3O4-Co SMCs在电子元件的小型化和高效化方面具有广阔的应用前景。
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引用次数: 0
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Current Applied Physics
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