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Numerical analysis of the influence of sidewall defects on AlGaN-based deep ultraviolet micro-light emitting diodes 侧壁缺陷对氮化铝基深紫微发光二极管影响的数值分析
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-08 DOI: 10.1016/j.cap.2024.08.002
Zhanhong Ma , Yue Ji , Tiangui Hu , Xuejiao Sun , Naixin Liu

The optoelectronic performance of AlGaN-based deep ultraviolet micro-light emitting diodes are strongly affected by surface recombination at the mesa sidewall. Herein, the influence of sidewall defect density and location changes on the photoelectric properties and carrier recombination mechanisms were theoretically investigated. The results indicate a significant deterioration in the internal quantum efficiency and optical power with an increase in the sidewall defect density at the edge of the LED mesa. This deterioration is attributed to the Shockley-Read-Hall nonradiative recombination caused by sidewall defects. The sidewall defects also act as traps for electrons and holes, significantly affecting the carrier injection capability. Furthermore, the position dependence of carrier concentration and recombination rate along the lateral dimension of the LED mesa were studied. The results show that etching process not only causes sidewall damage but can damage the quality of internal epitaxial materials. These effects should be minimized by optimizing the dry-etching process.

AlGaN 基深紫外微发光二极管的光电性能受到崮侧壁表面重组的强烈影响。本文从理论上研究了侧壁缺陷密度和位置变化对光电性能和载流子重组机制的影响。结果表明,随着 LED 中子板边缘侧壁缺陷密度的增加,内部量子效率和光功率会明显下降。这种恶化归因于侧壁缺陷引起的肖克利-雷德-霍尔非辐射重组。侧壁缺陷还充当了电子和空穴的陷阱,极大地影响了载流子注入能力。此外,还研究了载流子浓度和重组率沿 LED 中子板横向维度的位置依赖性。结果表明,蚀刻过程不仅会造成侧壁损坏,还会破坏内部外延材料的质量。应通过优化干蚀刻工艺将这些影响降至最低。
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引用次数: 0
Pulse program for improving learning accuracy and reducing programming energy consumption of ferroelectric synaptic transistor 用于提高铁电突触晶体管学习精度和降低编程能耗的脉冲程序
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-08-02 DOI: 10.1016/j.cap.2024.07.018
Jae Yeob Lee , Cheol Jun Kim , Minkyung Ku , Tae Hoon Kim , Taehee Noh , Seung Won Lee , Yoonchul Shin , Ji-Hoon Ahn , Bo Soo Kang

Neuromorphic computing is a next‐generation computing technology featured by parallel data processing and adaptive learning. Two significant factors that improve learning accuracy are the ‘dynamic range’ and ‘linearity’ of the weight update. In a ferroelectric synaptic transistor, the weight update can be modulated by adjusting the applied voltage. The voltage pulse train should be carefully optimized to improve the learning accuracy and reduce programming energy consumption. In this study, we investigated the learning accuracy of neuromorphic computing based on the characteristics of synaptic devices and the program energy consumption according to pulse programs. We demonstrated changes in the analog conductance characteristics of ferroelectric thin‐film transistors by varying the pulse program for synaptic plasticity, discussed the characteristics for improving learning accuracy, and compared the programming energy consumption according to the pulse programs. We proposed a logarithmic‐incremental‐step pulse program that reduces programming energy consumption and improves learning accuracy.

神经形态计算是以并行数据处理和自适应学习为特征的新一代计算技术。提高学习精度的两个重要因素是权重更新的 "动态范围 "和 "线性"。在铁电突触晶体管中,权重更新可以通过调整外加电压来调制。为了提高学习精度和降低编程能耗,电压脉冲序列必须经过精心优化。在这项研究中,我们根据突触器件的特性研究了神经形态计算的学习精度,并根据脉冲程序研究了程序能耗。我们通过改变突触可塑性的脉冲程序,展示了铁电薄膜晶体管模拟电导特性的变化,讨论了提高学习精度的特性,并比较了不同脉冲程序的编程能耗。我们提出了一种对数递增阶梯脉冲程序,它能降低编程能耗并提高学习精度。
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引用次数: 0
Extraordinary optical characteristics in a one-dimensional parity-time symmetric structure of quasiperiodic two-material Octonacci optical waveguide network 准周期双材料 Octonacci 光波导网络一维奇偶时对称结构中的非凡光学特性
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-28 DOI: 10.1016/j.cap.2024.07.017
Mohammad Javad Khalifeh, Jamal Barvestani, Bahar Meshginqalam

We explore Exceptional Points (EPs) within a one-dimensional quasiperiodic Octonacci optical waveguide network. This network consists of segments, each composed of two-material subsegments featuring gain and loss materials, creating a parity-time-symmetric structure. We investigate the trend of EPs across generations 3 to 7 of the Octonacci sequence using the generalized eigenfunction method and transfer matrix method. Our findings reveal that as generations progress, band gaps become more pronounced, and the number of EPs significantly increases within these gaps. In particular, the third generation only supports unidirectional transparency. Bidirectional transparency appears in the fourth generation and becomes more pronounced in later generations. Coherent perfect absorption-lasing points are first seen in the seventh generation. These findings have implications for the design of all-optical devices and wideband and/or narrowband optical filters.

我们探索了一维准周期八方光波导网络中的异常点(EP)。该网络由若干区段组成,每个区段由增益材料和损耗材料组成的两种材料子区段组成,形成了奇偶时对称结构。我们使用广义特征函数法和传递矩阵法研究了 Octonacci 序列第 3 至 7 代 EP 的变化趋势。我们的研究结果表明,随着代数的增加,带隙变得越来越明显,在这些带隙中 EP 的数量也显著增加。特别是,第三代仅支持单向透明。双向透明出现在第四代,并在以后各代中变得更加明显。在第七代中首次出现了相干的完美吸收-激光点。这些发现对全光器件以及宽带和/或窄带滤光器的设计具有重要意义。
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引用次数: 0
Single-unit metalens integrated micro light-emitting diodes 单体金属集成微型发光二极管
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-27 DOI: 10.1016/j.cap.2024.07.016
Young-Bin Kim , Jin-Woo Cho , Dukkyu Bae , Sun-Kyung Kim

Metalenses, characterized by their discontinuous local phase shifts, are optically analogous to macroscopic curved lenses but are flat and scaled down to micrometer dimensions. Their compactness and compatibility with semiconductor manufacturing processes facilitate monolithic integration into existing optical devices. Here, we report on the integration of metalenses with micro light-emitting diodes (μ-LEDs), resulting in enhanced extraction efficiency and directionality. The metalenses were composed of identical nanohole units, each 150 nm in diameter, strategically arranged to induce desired local phase shifts at specific coordinates by varying the density of these units. Both simulated and experimental results demonstrated that these easy-configuration metalenses effectively focused a plane wave at a predetermined spot and collimated a diverging light source at the focal spot, exemplifying optical reciprocity. When integrated with ultraviolet (λ = 390 nm) 60 μm-sized μ-LEDs, the metalenses significantly improved device performance, exhibiting a 338% enhancement in peak intensity and a ±8° reduction in beam divergence compared to an unpatterned μ-LED. We believe that metalens-integrated μ-LEDs with high brightness, directionality, and resolution are optimally suited for near-eye applications, including virtual reality and augmented reality displays.

金属透镜的特点是不连续的局部相移,在光学上类似于宏观弯曲透镜,但它是平面的,尺寸可缩小到微米级。金属透镜结构紧凑,与半导体制造工艺兼容,有利于将其单片集成到现有的光学设备中。在此,我们报告了金属透镜与微型发光二极管(μ-LED)的集成,从而提高了提取效率和方向性。金属透镜由相同的纳米孔单元组成,每个直径为 150 nm,通过改变这些单元的密度,在特定坐标上诱发所需的局部相移。模拟和实验结果表明,这些易于配置的金属透镜能有效地将平面波聚焦在预定点上,并将发散光源准直在聚焦点上,体现了光学互易性。当与紫外线(λ = 390 nm)60 μm 大小的 μ-LED 集成时,金属透镜显著提高了设备性能,与未图案化的 μ-LED 相比,峰值强度提高了 338%,光束发散度降低了 ±8°。我们相信,具有高亮度、方向性和分辨率的金属膜集成 μ-LED 最适合近眼应用,包括虚拟现实和增强现实显示器。
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引用次数: 0
Enhancing the thermal stability of active contacts in AlGaN/GaN high electron mobility transistors with chemical vapor deposited carbon (C) films 用化学气相沉积碳 (C) 薄膜增强氮化铝/氮化镓高电子迁移率晶体管有源触点的热稳定性
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-26 DOI: 10.1016/j.cap.2024.07.008
Kyeong-Keun Choi , Youn-Jang Kim , Su Kon Kim , Jae Kyoung Mun

This study investigates the long-term thermal stability (4 h at 300 °C) of active contacts in high electron mobility transistor (HEMT) devices with and without 10 nm-target thickness chemical vapor deposition (CVD) carbon (C) layers, utilizing in-situ resistance measurements. The thermal stability of the HEMT devices was investigated over the temperature range of 150–300 °C, employing sputtered 30 nm Ti/150 nm Al/30 nm Ti/30 nm TiN (top) with Ohmic metal structures. The results indicate that the HEMT devices with the about 10 nm-thick CVD C layer exhibit superior long-term thermal stability compared to those without the CVD C layer, maintaining Ohmic contact behavior throughout the duration of the test. The increase in contact resistance without C films was 2 %, whereas with the C films, it was only 0.5 % after the 4 h-long thermal stability test at 300 °C.

本研究利用原位电阻测量法研究了高电子迁移率晶体管(HEMT)器件中有源触点的长期热稳定性(300 °C下4小时),包括有无目标厚度为10 nm的化学气相沉积(CVD)碳(C)层。利用带有欧姆金属结构的溅射 30 nm Ti/150 nm Al/30 nm Ti/30 nm TiN(顶部),研究了 HEMT 器件在 150-300 °C 温度范围内的热稳定性。结果表明,与没有 CVD C 层的器件相比,带有约 10 nm 厚 CVD C 层的 HEMT 器件具有更出色的长期热稳定性,在整个测试期间都能保持欧姆接触行为。在 300 °C 下进行长达 4 小时的热稳定性测试后,无 C 膜的接触电阻增加了 2%,而有 C 膜的接触电阻仅增加了 0.5%。
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引用次数: 0
Composition dependence of the orbital torque in CoxFe1−x and NixFe1−x alloys: Spin-orbit correlation analysis Cox<mml:mtext mathvariant="normal" 中轨道扭矩的成分依赖性
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-26 DOI: 10.1016/j.cap.2024.07.014
Hojun Lee, Hyun-Woo Lee

The spin-orbit correlation in ferromagnet (FM) is an important factor that affects the orbital torque efficiency in the FM. We investigate the spin-orbit correlation in FM alloys, CoxFe1x and NixFe1x, with varying their composition. We find spots where the spin-orbit correlation is significantly strong near the Fermi surface in Co0.125Fe0.875, Co0.25Fe0.75, Co0.875Fe0.125, and Ni0.5Fe0.5, while no such spot appears in Co0.5Fe0.5, and Ni0.75Fe0.25. These results imply that in the former structures, the orbital polarized current injected into these spots can provide a strong torque to the magnetization of the FM through the orbital torque mechanism. These results also show that even in the same alloy system, the difference in alloy composition can lead to different orbital torque efficiency.

铁磁体(FM)中的自旋轨道相关性是影响 FM 轨道转矩效率的一个重要因素。我们研究了不同成分的铁磁合金 CoxFe1-x 和 NixFe1-x 中的自旋轨道相关性。我们发现,在 Co0.125Fe0.875、Co0.25Fe0.75、Co0.875Fe0.125 和 Ni0.5Fe0.5 中,费米表面附近的自旋轨道相关性明显较强,而在 Co0.5Fe0.5 和 Ni0.75Fe0.25 中则没有出现这样的斑点。这些结果表明,在前一种结构中,注入这些斑点的轨道极化电流可以通过轨道力矩机制为调频磁化提供强大的力矩。这些结果还表明,即使在相同的合金体系中,合金成分的不同也会导致轨道转矩效率的不同。
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引用次数: 0
Optimization strategies for metallization in n-type crystalline silicon TOPCon solar cells: Pathways to elevated fill factor and enhanced efficiency n 型晶体硅 TOPCon 太阳能电池金属化的优化策略:提高填充因子和效率的途径
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-26 DOI: 10.1016/j.cap.2024.07.012
Rafi Ur Rahman , Muhammad Quddamah Khokhar , Hasnain Yousuf , Maha Nur Aida , Jaljalalul Abedin Jony , Alamgeer , Polgampola Chamani Madara , Mengmeng Chu , Sangheon Park , Junsin Yi

In advancing photovoltaic technology, optimizing the metallization process is crucial for balancing electrical conductivity and optical performance in solar cell fabrication. This process directly impacts the efficiency and quality of solar cells, traditionally measured by the fill factor (FF). Historically, efforts have focused on evolving metal contacts to reduce optical shading and series resistance, which degrade solar cell efficiency. Our study enhances n-type Tunnel Oxide Passivated Contact (n-TOPCon) solar cells by optimizing screen-printing metallization, particularly by examining the effects of squeegee speeds. Employing a mix of experimental and analytical methodologies, we aimed to identify optimal conditions that improve electrical and optical performance, thereby elevating cell efficiency. Our findings indicate that a squeegee speed of 170 mm/s substantially boosts solar cell performance, evidenced by a current density (Jsc) of 38.96 mA/cm2, open-circuit voltage (Voc) of 684.29 mV, fill factor (FF) of 78.77 %, and a power conversion efficiency (PCE) of 21.00 %. Further, dark I–V measurements confirmed a shunt resistance (Rsh) of 6.25 × 106 Ω and a reduced series resistance (Rs) of 6.48 Ω, underscoring the significance of precise metallization in reducing resistive losses and enhancing efficiency. Future research will explore innovative materials and cutting-edge printing techniques beyond squeegee speed adjustments. The potential incorporation of nanomaterials and conducting polymers aims to refine the metallization process further, promising to push the boundaries of efficiency and cost-effectiveness. This progression is essential for advancing n-TOPCon solar cell development, setting new industry standards, and propelling the sustainable energy movement.

在推动光伏技术发展的过程中,优化金属化工艺对于平衡太阳能电池制造中的导电性和光学性能至关重要。该工艺直接影响太阳能电池的效率和质量,传统上以填充因子(FF)来衡量。一直以来,人们致力于改进金属触点,以减少降低太阳能电池效率的光学阴影和串联电阻。我们的研究通过优化丝网印刷金属化,特别是通过研究刮刀速度的影响,提高了 n 型隧道氧化物钝化触点(n-TOPCon)太阳能电池的性能。我们采用实验和分析相结合的方法,旨在确定改善电气和光学性能的最佳条件,从而提高电池效率。我们的研究结果表明,170 毫米/秒的刮板速度大大提高了太阳能电池的性能,具体表现为电流密度 (Jsc) 为 38.96 mA/cm2,开路电压 (Voc) 为 684.29 mV,填充因子 (FF) 为 78.77 %,功率转换效率 (PCE) 为 21.00 %。此外,暗 I-V 测量证实并联电阻 (Rsh) 为 6.25 × 106 Ω,串联电阻 (Rs) 为 6.48 Ω,这突出表明了精确金属化在减少电阻损耗和提高效率方面的重要性。未来的研究将探索除调整刮刀速度之外的创新材料和尖端印刷技术。可能加入的纳米材料和导电聚合物旨在进一步完善金属化工艺,有望推动效率和成本效益的发展。这一进展对于推进 n-TOPCon 太阳能电池的开发、制定新的行业标准和推动可持续能源运动至关重要。
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引用次数: 0
Linearizing AFM raster scans acquired using dual-stage lateral scanners 对使用双级横向扫描仪获取的原子力显微镜光栅扫描进行线性化处理
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-26 DOI: 10.1016/j.cap.2024.07.015
Oyoo Michael Juma , Luke Oduor Otieno , Thi Thu Nguyen, Thi Ngoc Nguyen, Yong Joong Lee

Dual-stage scanners can successfully increase the range of atomic force microscope (AFM) scanners in space and/or frequency by designing and constructing two nanopositioners with significant differences in static and dynamic characteristics. In such cases, the positioning signal has to be split to meet the displacement and frequency limitations of each stage. Without closed-loop displacement measurement sensors, linearizing images acquired using signals split in time and frequency can be challenging. A common method, often cumbersome and time consuming, uses inverse model-based feedforward compensation. In this work, we show that image-based linearization can be used to achieve acceptable results for raster scans acquired using dual-stage scanners. In particular, we apply the feedforward and image-based methods to our homemade dual-stage lateral scanner and high-speed AFM (HS-AFM) system. The acquired scans compare well for the two methods, indicating that image-based raster scan linearization can be used in place of inverse model-based feedforward approaches.

通过设计和制造两个在静态和动态特性上有显著差异的纳米定位器,双级扫描器可以成功地提高原子力显微镜(AFM)扫描器在空间和/或频率上的扫描范围。在这种情况下,必须拆分定位信号,以满足每个级的位移和频率限制。在没有闭环位移测量传感器的情况下,对使用时间和频率分割信号获取的图像进行线性化处理是一项挑战。一种常见的方法是使用基于反演模型的前馈补偿,这种方法通常既繁琐又耗时。在这项工作中,我们展示了基于图像的线性化方法,可以为使用双级扫描仪采集的光栅扫描获得可接受的结果。特别是,我们将前馈和基于图像的方法应用于自制的双级横向扫描仪和高速原子力显微镜(HS-AFM)系统。两种方法获得的扫描结果对比良好,表明基于图像的光栅扫描线性化可以取代基于逆模型的前馈方法。
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引用次数: 0
Hydrothermally synthesized Ag2Te on metallic 2D templates 在金属二维模板上水热合成 Ag2Te
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-23 DOI: 10.1016/j.cap.2024.07.010
Ha Heun Lee , Minji Bak , Hyo Gyeong Kim , Eunji Lim , Sunwoo Kim , Woohyun Cho , Shibo Xi , Heejun Yang , Woo-Jae Kim , Suyeon Cho

Silver telluride, Ag2Te, was synthesized on various 2D templates of carbon nanotubes (CNT) and transition-metal dichalcogenides (WTe2 and VTe2) via hydrothermal synthesis. X-ray diffraction (XRD) and Raman spectroscopy revealed that Ag2Te was synthesized on the 2D templates under optimal synthesis conditions. Differential scanning calorimetry (DSC) confirmed that the structural phase transition of Ag2Te underwent endothermic and exothermic reactions at approximately 410 and 425 K, respectively. Among various metallic templates, a large amount of Ag2Te has been synthesized on strongly acidic CNT. X-ray absorption near-edge structure (XANES) revealed that the chemical state of the metallic support influenced the electronic structure of the as-grown Ag2Te on the metallic supports. Our findings demonstrated that the hybrid 2D catalysts with an appropriate 2D metallic template can be a promising strategy for achieving efficient catalysis.

通过水热合成法,在碳纳米管(CNT)和过渡金属二卤化物(WTe 和 VTe)的各种二维模板上合成了碲化银(AgTe)。X 射线衍射(XRD)和拉曼光谱显示,AgTe 是在最佳合成条件下在二维模板上合成的。差示扫描量热法(DSC)证实,AgTe 的结构相变分别在约 410 和 425 K 发生了内热和放热反应。在各种金属模板中,在强酸性 CNT 上合成了大量 AgTe。X 射线吸收近边结构(XANES)显示,金属支架的化学状态影响了金属支架上生长的 AgTe 的电子结构。我们的研究结果表明,采用适当的二维金属模板的混合二维催化剂是实现高效催化的一种很有前途的策略。
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引用次数: 0
Web-based applications for automated generation of functionalized graphene and carbon nanotube for molecular dynamics simulations and automated three-dimensional analysis of ion flow through nanopores 基于网络的应用程序,用于自动生成功能化石墨烯和碳纳米管,以进行分子动力学模拟,并自动对通过纳米孔的离子流进行三维分析
IF 2.4 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-07-23 DOI: 10.1016/j.cap.2024.07.011
Gyeongpil Jo , Minsoo Kim , Jinmin Lee , Sang Hak Lee , Jejoong Yoo

Functionalized graphene and carbon nanotubes (CNTs) are widely recognized for their exceptional physical properties, which make them highly suitable for various applications. Although molecular dynamics (MD) simulations are essential for investigating the atomic-level interactions and transport phenomena in functionalized graphene and CNT systems, setting up these simulations remains complex and time-consuming. To streamline this process, we have developed a novel web application that automates the generation of MD simulation setups of functionalized graphene and CNT systems compatible with AMBER force fields and the Gromacs software. Key features include the creation of nanopores, functionalization with hydrogen, hydroxyl, and/or carboxylate groups, and the application of periodic boundary conditions to effectively simulate infinite structures. To facilitate the MD analysis of transport phenomena through nanopores, our web application offers an automated analysis tool that generates and visualizes three-dimensional local flux fields from MD trajectories. Overall, our web applications significantly enhance the accessibility and efficiency of MD simulations of functionalized graphene systems, particularly for nanopore applications. Our web applications are freely available at https://yoo.skku.edu/apps.

功能化石墨烯和碳纳米管(CNT)因其优异的物理特性而被广泛认可,这使它们非常适合各种应用。虽然分子动力学(MD)模拟对于研究功能化石墨烯和碳纳米管系统中的原子级相互作用和传输现象至关重要,但建立这些模拟仍然复杂且耗时。为了简化这一过程,我们开发了一种新型网络应用程序,可自动生成与 AMBER 力场和 Gromacs 软件兼容的功能化石墨烯和 CNT 系统的 MD 模拟设置。其主要功能包括创建纳米孔,用氢、羟基和/或羧基进行官能化,以及应用周期性边界条件来有效模拟无限结构。为了便于对通过纳米孔的输运现象进行 MD 分析,我们的网络应用程序提供了一个自动分析工具,可根据 MD 轨迹生成三维局部通量场并将其可视化。总之,我们的网络应用程序大大提高了功能化石墨烯系统 MD 模拟的可访问性和效率,尤其是在纳米孔应用方面。我们的网络应用程序可在以下网址免费获取
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引用次数: 0
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