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Complex character of the influence of polycarboxylic and phosphonic acids on the crystallization of calcium and magnesium salts in dynamic conditions 动态条件下多羧酸和膦酸对钙镁盐结晶影响的复杂特性
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-168-177
E. Vorobieva, A. Vorobiev, I. V. Shestak, D. V. Cherednichenko, S. V. Bucha
. The influence of water-soluble organic compounds (adipic, polyaspartic and phosphonic acids) and their compositions on the crystallization of calcium and magnesium salts in dynamic conditions has been studied. It is found that the induction period of phase formation increases in the presence of polyaspartic and phosphonic acids 2.3–5.2 times in the range of their content from 0.05 to 0.2 ppm. The results of XRD and electron microscopic studies confirm the change in the phase composition and morphology of the crystalline precipitate that is formed. The dibasic carboxylic acid influence on the induction period, composition and structure of the precipitate is much less. It is established that the composition of organic acids also increases the induction period of phase formation. The complex inhibitor provides an increase in the critical supersaturation level in the system. The phosphonic and carboxyl groups of the inhibitor interact with calcium and magnesium ions and block the crystallization nuclei. When interacting with the dicarboxylic acid and polyacid adsorption on the surface of the formed crystals, the microcrystals dissolve.
. 研究了动态条件下水溶性有机化合物(己二酸、聚天冬氨酸和膦酸)及其组成对钙镁盐结晶的影响。结果表明,在聚天冬氨酸和膦酸含量为0.05 ~ 0.2 ppm范围内,聚天冬氨酸和膦酸存在时,相形成的诱导期增加了2.3 ~ 5.2倍。XRD和电镜研究结果证实了所形成的结晶相组成和形貌的变化。二碱羧酸对析出相的诱导期、组成和结构的影响较小。确定了有机酸的组成也延长了相形成的诱导期。复合缓蚀剂提高了系统的临界过饱和水平。抑制剂的磷酸基和羧基与钙和镁离子相互作用并阻断结晶核。当与二羧酸和聚酸相互作用时,在形成的晶体表面吸附微晶体,微晶体溶解。
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引用次数: 0
Processes of electroluminescence degradation of light-emitting structures based on thin silicon oxide and nitride films 基于氧化硅和氮化硅薄膜的发光结构的电致发光降解过程
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-158-167
I. Romanov, F. Komarov, L. Vlasukova, I. Parkhomenko, N. Kovalchuk
. SiO 2 /Si, SiN 1.2 /SiO 2 /Si and SiO 2 /SiN 0.9 /SiO 2 /Si structures have been fabricated by chemical vapor deposition and thermal oxidation of silicon. The elemental composition and thicknesses of dielectric layers have been studied using Rutherford backscattering spectroscopy, scanning electron microscopy, and spectral ellipsometry. The electroluminescence (EL) of the samples has been investigated in the “electrolyte–dielectric–semiconductor” system at a positive bias voltage applied to the silicon substrate. An intense band with maxima at 1.9 eV appears on the EL spectra of the SiO 2 /Si sample, while the EL spectra of the SiN 1.2 /SiO 2 /Si and SiO 2 /SiN 0.9 /SiO 2 /Si samples are characterized by the presence of bands with the maximum values of 1.9, 2.3 and 2.7 eV. The nature of these bands is discussed. Passing a charge in the range of 100–500 mC/ cm 2 through the SiO 2 /SiN 0.9 /SiO 2 /Si sample, an increase in the EL intensity was recorded in the entire visible range. Passing a charge of 1 C/cm 2 through a sample with a three-layer dielectric film resulted in the EL intensity decrease. It can be explained by the upper oxide layer degradation. It has been shown that silicon nitride deposited on top of the SiO 2 layer protects the oxide layer from field degradation and premature breakdown. The most stable electroluminescence when exposed to a strong electric field is observed for the structure SiN 1.2 /SiO 2 /Si.
。采用化学气相沉积和硅热氧化法制备了sio2 /Si、sin1.2 / sio2 /Si和sio2 / sin0.9 / sio2 /Si结构。利用卢瑟福后向散射光谱、扫描电子显微镜和光谱椭偏仪研究了介电层的元素组成和厚度。在硅衬底上施加正偏置电压时,研究了样品在“电解质-介电-半导体”体系中的电致发光(EL)。sio2 /Si样品的EL谱中出现了一个峰值在1.9 eV处的强谱带,而sin1.2 / sio2 /Si和sio2 / sin0.9 / sio2 /Si样品的EL谱则出现了峰值在1.9、2.3和2.7 eV处的谱带。讨论了这些谱带的性质。将100-500 mC/ cm2的电荷通过sio2 / sin0.9 / sio2 /Si样品,在整个可见范围内记录到EL强度的增加。以1 C/ cm2的电荷穿过具有三层介质膜的样品,导致EL强度降低。这可以用上层氧化层的降解来解释。结果表明,氮化硅沉积在二氧化硅层的顶部,可以防止氧化层的电场降解和过早击穿。在强电场作用下,观察到sin1.2 / sio2 /Si结构的电致发光最稳定。
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引用次数: 1
Features of transformation of soil properties of the arable land in Belarus 白俄罗斯可耕地土壤性质变化的特征
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-247-256
V. Lapa, T. N. Azarenok
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引用次数: 0
Genetic analysis of the human remains of the burials of the 17th–18th centuries of the Corpus Christi Church in Nesvizh (Belarus) 涅斯维日(白俄罗斯)科珀斯基督教堂17 - 18世纪墓葬中人类遗骸的基因分析
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-199-206
M. Shapturenko, A. V. Lugovnjov, S. Borovko, M. Pamazanau, S. Vakula, A. Kilchevsky
During archaeological excavation in the territory of the Corpus Christi Church in Nesvizh, the regular burials dated to the 17th–18th centuries were discovered. The genetic material extracted from the bones of seven unidentified individuals was analyzed using the forensic genetics approaches, including STR profiling and DNA phenotyping. The genetic examination revealed that the remains of three samples (#1, #2, #6) belonged to women, and the four others (#3, #4, #5, and #7) belonged to men. Autosomal STR-data and Y-chromosomal profiles were obtained for five samples. The kinship analysis excluded that woman #1 and men #3, #4, #5, #7 were first-degree relatives. According to the Y-STR profiles, men #3, #4, #7 referred to the haplogroup R1a, the haplotype of individual #5 corresponded to I2. The both haplogroups are widely represented in Eastern Europe, which, with a high degree of probability, suggests the Slavic origin of the individuals under investigation. To predict eye and hair color, we used the HIrisPlex DNA phenotyping system. The analysis gave the satisfactory results for woman #1 and man #7. In correspondence to the allelic variants of the 24 SNP system, woman #1 had an intermediate type of iris pigmentation and dark blond hair (p = 0.635) with dark shade (0.639), light skin tone, low tendency to sunburn, and a high probability of freckles and pigmented spots of the skin. For male #7, the HIrisPlex model predicted blue eye color with a high probability (p = 0.915), as well as blond hair color (p = 0.915) and light hair color shade (p = 0.962). Our data allow us to conclude that the unknown individuals under investigation have significant genetical and phenotypical similarity with the modern Belarusian population.
在涅斯维日科珀斯基督教堂的考古发掘中,发现了可追溯到17 - 18世纪的常规墓葬。从7个身份不明的个体的骨骼中提取的遗传物质使用法医遗传学方法进行了分析,包括STR分析和DNA表型。基因检查显示,三个样本(#1、#2、#6)的遗骸属于女性,另外四个样本(#3、#4、#5和#7)属于男性。获得了5个样本的常染色体str数据和y染色体谱。亲属关系分析排除了1号女性和3号、4号、5号、7号男性为一级亲属。根据Y-STR图谱,3、4、7号男性的单倍型为R1a, 5号个体的单倍型为I2。这两个单倍群在东欧广泛存在,这在很大程度上表明被调查个体的斯拉夫血统。为了预测眼睛和头发的颜色,我们使用了HIrisPlex DNA表型系统。分析结果对女性1号和男性7号都很满意。与24 SNP系统的等位基因变异相对应,女性1号具有中等类型的虹膜色素沉着和深金色头发(p = 0.635),深色(0.639),浅色肤色,低晒伤倾向,皮肤雀斑和色素斑的可能性很高。对于7号男性,HIrisPlex模型预测蓝眼睛颜色的概率很高(p = 0.915),以及金发颜色(p = 0.915)和浅色头发颜色(p = 0.962)。我们的数据使我们能够得出结论,所调查的未知个体与现代白俄罗斯人口具有显着的遗传和表型相似性。
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引用次数: 0
Classical solution of the first mixed problem for the wave equation in the cylyndrical domain 圆柱域波动方程第一混合问题的经典解
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-135-138
V. Korzyuk, I. I. Stolyarchuk
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引用次数: 1
Дираковская частица во внешнем кулоновском поле на фоне пространств Лобачевского–Римана
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-146-157
Е. М. Овсиюк, А. Д. Коральков
The known systems of the radial equations describing the hydrogen atom on the basis of the Dirac equation in the Lobachevsky–Riemann spaces of constant curvature are investigated. In the both geometrical models, the differential equations of second order with six regular singular points are found, and their exact solutions of Frobenius type are constructed. To produce the quantization rule for energy values we use the known condition which separates the transcendental Frobenius solutions. This provides us with the energy spectra that are physically interpretable and are similar to those for the Klein–Fock–Gordon particle in these space models. These spectra are similar to those that previously have appeared in studying the same systems of the equations with the use of the semi-classical approximation.
在恒定曲率的罗巴切夫斯基-黎曼空间中,研究了以狄拉克方程为基础的描述氢原子的已知径向方程组。在这两种几何模型中,都得到了具有六个正则奇点的二阶微分方程,并构造了它们的Frobenius型精确解。为了得到能量值的量子化规则,我们使用了分离先验Frobenius解的已知条件。这为我们提供了物理上可解释的能谱,与这些空间模型中的克莱因-福克-戈登粒子的能谱相似。这些谱与以前用半经典近似方法研究相同方程组时出现的谱相似。
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引用次数: 0
Construction of the recombinant Escherichia coli strain producing a homologous thermolabile toxin subunit 产生同源耐热毒素亚基的重组大肠杆菌菌株的构建
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-185-190
I. Kazlouski, A. Zinchenko, A. Solovyeva, O. N. Novikova, Y. Lomako
Colibacteriosis is an acute zoonotic disease manifested by septicaemia, toxemia, enteritis, body dehydration, and central nervous system damage. Depending on the presence of virulence factors and the nature of interaction with the intestinal mucosa, enterotoxigenic, enteroinvasive, enteropathogenic, and enterohemorrhagic E. coli are isolated. Enterotoxigenic strains of E. coli occupy one of the leading places in the etiological structure of calf colibacteriosis in many livestock farms of the Republic of Belarus. The main reason why this disease develops is the presence of thermolabile and thermostable toxins in the causative strain. The thermolabile toxin subunit B is a potent antigen that allows pet immunity to be acquired against E. coli-induced cattle diarrhea. Many foreign vaccines used against intestinal infections of cattle contain either a native or recombinant variant of the subunit B. As a result of the work, we have created a new strain of E. coli 42eLTB – the producer of the recombinant subunit B of the thermolabile toxin E. coli. The producing capacity of the obtained strain is 480 mg with 1 culture liquid liter, which exceeds the already known strains 1.37 times. 186 Doklady of the National Academy of Sciences of Belarus, 2021, vol. 65, no. 2, рр. 185–190
大肠杆菌病是一种急性人畜共患疾病,表现为败血症、毒血症、肠炎、身体脱水和中枢神经系统损害。根据毒力因素的存在和与肠粘膜相互作用的性质,分离出产肠毒素、肠侵入性、肠致病性和肠出血性大肠杆菌。产肠毒素大肠杆菌菌株在白俄罗斯共和国许多畜牧场小牛大肠杆菌病的病因学结构中占主导地位。这种疾病发展的主要原因是致病菌株中存在耐热性和耐热性毒素。耐热性毒素B亚基是一种强效抗原,可使宠物获得对大肠杆菌引起的牛腹泻的免疫力。许多用于牛肠道感染的国外疫苗含有B亚基的原生或重组变体。由于这项工作,我们创造了一种新的大肠杆菌42eLTB菌株,它是耐热性毒素大肠杆菌重组B亚基的产生者。得到的菌株在1升培养液中生产能力为480 mg,是已知菌株的1.37倍。《白俄罗斯国家科学院院士》,2021年,第65卷,第186号。2,рр。185 - 190
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引用次数: 0
New data on the chemical composition of the non-ferrous metal products of the X–XVIII centuries on the territory of Northern and Central Belarus 关于白俄罗斯北部和中部地区x - 18世纪有色金属产品化学成分的新数据
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-241-246
И. В. Магалинский
The article presents the results of analysis of new data on the elemental composition of non-ferrous metal products on the territory of certain archaeological sites in Northern and Central Belarus. The author distinguishes two main stages in the non-ferrous metalworking of the region: the X–XIII centuries and XIV–XVIII centuries. It is noted that the period of the X–XIII centuries is characterized by a significant predominance of copper-zinc alloys with average and high concentrations of zinc in metal. Meanwhile, bronze alloys also play an important role, accounting for 35 % of the total number of the items studied. Samples made of copper-zinc and bronze alloys are also characterized by a significant amount of lead. As a result of the analysis of the data on the elemental composition of non-ferrous metal products of the XIV–XVIII centuries, it is concluded that non-ferrous metalworking of this period is characterized by the continuity of traditions with handicraft production of the previous period, which manifested itself in the widespread use of copper-zinc alloys, as well as of tin-lead and multicomponent bronzes. At the same time, a significant difference is the increase in the proportion of alloys with high concentrations of alloying components.
本文介绍了在白俄罗斯北部和中部某些考古遗址的领土上对有色金属产品元素组成的新数据的分析结果。作者区分了该地区有色金属加工的两个主要阶段:x - 13世纪和14 - 18世纪。值得注意的是,x - 13世纪时期的特点是铜锌合金的显著优势,金属中锌的浓度平均和很高。同时,青铜合金也发挥了重要作用,占研究项目总数的35%。由铜锌合金和青铜合金制成的样品也以大量的铅为特征。通过对14 - 18世纪有色金属产品元素组成数据的分析,得出结论:这一时期有色金属加工的特点是继承了前一时期手工生产的传统,这表现在铜锌合金、锡铅和多组分青铜的广泛使用上。同时,一个显著的区别是合金成分浓度高的合金比例增加。
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引用次数: 0
Synthesis, structure and morphology of composites based on magnesium ferrite and carbon nitride 铁素体镁与氮化碳复合材料的合成、结构与形貌
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-178-184
A. Ivanets
The composites based on magnesium ferrite and carbon nitride were synthesized by the sol-gel method in combination with thermochemical condensation. The effect of the synthesis method on the crystalline structure, the phase and chemical composition, and the morphology of composites was studied by the X-ray diffraction, IR spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy techniques. It was found that, depending on the conditions of the sol-gel stages, the initiation of self-combustion high-temperature synthesis and melanin thermochemical condensation, composites with different crystalline structure and morphology were prepared. The obtained results are important for the development of the heterogeneous Fenton- and photo-Fenton catalysts based on magnesium ferrite and carbon nitride composites.
采用溶胶-凝胶法结合热化学缩合法制备了铁酸镁与氮化碳复合材料。采用x射线衍射、红外光谱、扫描电镜和能量色散x射线能谱技术研究了合成方法对复合材料晶体结构、物相、化学成分和形貌的影响。研究发现,根据溶胶-凝胶阶段、自燃高温合成起始和黑色素热化学缩合的不同条件,可以制备出不同晶体结构和形态的复合材料。所得结果对开发基于铁酸镁-氮化碳复合材料的非均相Fenton和光Fenton催化剂具有重要意义。
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引用次数: 1
Компьютерное прогнозирование пространственного распределения концентрации Cs-137 в почве 计算机预测土壤中Cs-137浓度空间分布
Pub Date : 2021-05-08 DOI: 10.29235/1561-8323-2021-65-2-139-145
П. К. Шалькевич
Computer prediction of the migration of radioactive contaminants in soil is a promising scientific direction due to the fact that prediction of the radiation situation on the basis of experimental measurements of radionuclides activity requires the use of mathematical and computer methods of data processing. At the same time, most of the specialized software packages for predicting the spread of radioactive contaminants in soil are based on one- and two-dimensional idealizations of this process, while solving the problem of comprehensive assessment of the biosphere’s state requires the data of the contaminant’s spatial distribution. To obtain such data, the author has developed a software module as a part of SPS (Simulation of Processes in Soil) v2.0 software package, which allows predicting the parameters of the spatial migration of radionuclides in natural dispersed media. To assess the possibility of using the developed software in practice, the prediction results were verified by the experimental data. For this purpose, the spatial distribution of the Cs-137 concentration in the experimental area in the Luninets district of the Brest region was predicted using the measurement data of the Cs-137 activities and the soil characteristics. The comparison of the results obtained on the basis of experimental measurements and the predicted values of the spatial distribution of the Cs-137 concentration showed that the predicted values are within the confidence intervals of the measured values. Consequently, the developed software can be used to solve practical problems in the field of forecasting the migration of radionuclides with obtaining a reliable picture of their distribution over the volume of the modeling area and to comprehensively assess their impact on the environment.
土壤中放射性污染物迁移的计算机预测是一个很有前途的科学方向,因为根据放射性核素活动的实验测量来预测辐射情况需要使用数学和计算机方法进行数据处理。与此同时,目前用于土壤放射性污染物扩散预测的专业软件包大多是基于这一过程的一维和二维理想化,而解决生物圈状态综合评价问题则需要污染物空间分布数据。为了获得这些数据,作者开发了一个软件模块,作为SPS (Simulation of Processes in Soil) v2.0软件包的一部分,可以预测放射性核素在自然分散介质中的空间迁移参数。为了评估开发的软件在实际应用中的可能性,用实验数据对预测结果进行了验证。为此,利用Cs-137活性测量数据和土壤特征,预测了布列斯特地区Luninets试验区Cs-137浓度的空间分布。实验测量结果与Cs-137浓度空间分布预测值的比较表明,预测值在实测值的置信区间内。因此,开发的软件可用于解决预测放射性核素迁移领域的实际问题,获得其在模拟区域体积上分布的可靠图像,并全面评估其对环境的影响。
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引用次数: 1
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Doklady Akademii nauk
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