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Composition and age constraints on a Hadean enriched mantle source revealed by the Paleoarchean São Tomé layered intrusion, NE Brazil 巴西东北部古新世圣多美层状侵入揭示的哈代富集地幔源的成分和年龄制约因素
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-05 DOI: 10.1016/j.epsl.2024.119051
V.B. Garcia , J. O'Neil , E.L. Dantas , C.T. Augustin
Evidence for Hadean depleted mantle reservoir(s) is well-established by mantle-derived rocks from multiple Archean complexes showing excesses in 142Nd compared to the modern mantle. Yet, the existence of an early enriched mantle source, which should have concomitantly formed during these Hadean silicate differentiation event(s), has only been recently confirmed by well-resolved 142Nd deficits measured in Paleoarchean mafic amphibolites from the São José do Campestre massif of the Borborema Province, NE Brazil. To investigate the nature and extent of this early-formed enriched reservoir, a series of samples from the Seridó belt, NE Brazil, have been investigated for their geochemical and coupled 147,146Sm-143,142Nd isotopic compositions, focusing on the Paleoarchean São Tomé layered intrusion. The São Tomé intrusion is composed of layers of metamorphosed mafic and ultramafic rocks with whole-rock trace element compositions and high olivine crystal Ni contents consistent with an incompatible trace element enriched pyroxenitic mantle source. Most analyzed samples from the Seridó belt yielded negative µ142Nd, as low as ∼ -20 (representing the lowest 142Nd/144Nd ratio ever measured in terrestrial rocks), with an average µ142Nd for the São Tomé intrusion of -9.6 ± 1.4. The São Tomé samples interpreted as the least isotopically disturbed yielded an 147Sm-143Nd isochron age of 3551 ± 368 Ma, consistent with previous zircon U-Pb ages, with an initial ε143Nd = -1.7 ± 1.2. Coupling the long-lived 147Sm-143Nd and the short-lived 146Sm-142Nd systems for the São Tomé rocks suggests a Hadean enriched mantle source formed at ∼4.44 Ga with a 147Sm/144Nd of ∼0.18, which may be complementary to the early depleted mantle recorded by Eoarchean rocks from the North Atlantic Craton, possibly formed during magma ocean crystallization. These results also imply that the record of this Hadean enriched mantle source is not restricted to the São José do Campestre massif but extends to a larger portion of the Borborema Province.
与现代地幔相比,来自多个Archean复合体的地幔源岩石显示出过量的142Nd,这充分证明了Hadean贫化地幔储层的存在。然而,巴西东北部博博雷马省 São José do Campestre 地块的古新世黑云母闪长岩中测量到的 142Nd 缺陷,最近才证实存在一个早期富集地幔源,该地幔源应该是在这些黑云母硅酸盐分异过程中同时形成的。为了研究这种早期形成的富集储层的性质和范围,我们对巴西东北部塞里多带的一系列样品进行了地球化学和 147、146Sm-143、142Nd 同位素组合的研究,重点是古新世的圣多美层状侵入体。圣多美侵入体由变质的黑云母岩和超黑云母岩层组成,整个岩石的微量元素组成和橄榄石晶体的高镍含量与不相容的微量元素富集辉石地幔源一致。来自塞里多带的大多数分析样本的µ142Nd为负值,低至∼ -20(代表了在陆地岩石中测得的最低142Nd/144Nd比率),圣多美侵入体的平均µ142Nd为-9.6 ± 1.4。被解释为同位素扰动最小的圣多美样本的 147Sm-143Nd 等时年龄为 3551 ± 368 Ma,与之前的锆石 U-Pb 年龄一致,初始ε143Nd = -1.7 ± 1.2。将圣多美岩石的长寿命147Sm-143Nd和短寿命146Sm-142Nd系统耦合起来,表明哈代富集地幔源形成于∼4.44 Ga,147Sm/144Nd为∼0.18,这可能是对北大西洋克拉通的始新世岩石记录的早期贫化地幔的补充,可能是在岩浆洋结晶过程中形成的。这些结果还意味着,这种哈代富集地幔源的记录并不局限于São José do Campestre地块,而是延伸到了Borborema省的更大范围。
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引用次数: 0
Dynamic evolution of competing same-dip double subduction: New perspectives of the Neo-Tethyan plate tectonics 竞争性同斜双俯冲的动态演化:新泰西期板块构造的新视角
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-05 DOI: 10.1016/j.epsl.2024.119032
Arnab Roy , Nibir Mandal , Jeroen Van Hunen
Same-dip double-subduction (SDDS) systems are widely reported from present as well as past complex convergent plate tectonic configurations. However, the dynamics of their evolution is poorly understood, which is crucial to conceptualize anomalous subducting slab kinematics and associated observed geological phenomena, such as irregular trench migration rates, high convergence velocities, and slab break-off. To bridge this gap, we develop dynamic thermo-mechanical subduction models and investigate the initiation and evolution of SDDS systems, considering three different initial plate configurations: oceanic, oceanic-continental and multiple continental settings, based on Neo-Tethyan paleo-reconstructions. Each model offers new insights into the complex tectonic history of the major Neo-Tethyan subduction zones, particularly the Indo–Eurasian and Andaman convergent systems. We evaluate the slab-slab interactions, trench and subduction kinematics, inter-plate reorganization, and temporally varying mantle flow patterns involved in the dynamic evolution of these SDDS systems. The oceanic SDDS model simulations reveal that a sizable oceanic plate can initiate two subduction zones synchronously, and they evolve unequally in a competing mode, leading to exceptionally high convergence rates (∼16–17 cm/year) for a prolonged duration (∼7–8 Myr). This finding explains the coeval activity of coupled subduction zones in the Indo-Eurasia convergence during the Cretaceous evolution of the Neo-Tethys. We further implement a corresponding single subduction model to assess the additional effects of competing slab kinematics in an oceanic SDDS setting. The ocean-continent SDDS model, on the other hand, localizes subduction preferentially at passive margins between the oceanic plate and the continental block, forming double subduction zones that grow almost equally to form a spreading centre between the two trenches. These model results allow to reconstruct the Cenozoic evolution of the eastern Neo-Tethyan region, which ultimately led to the development of the Andaman subduction zone. We also show the post-Cretaceous evolution of the Indo–Eurasian collision zone as a consequence of the SDDS dynamics in presence of multiple continental blocks. These dynamics facilitated slab break-off, transforming the SDDS into a single subduction system in a relatively short time frame (∼3 Myr). We finish with a synthesis of the paleo-reconstructions of the Neo-Tethys in the perspective of these SDDS models.
同位双俯冲(SDDS)系统在现在和过去的复杂会聚板块构造中被广泛报道。然而,人们对它们的动力学演化却知之甚少,而这对于理解异常俯冲板块运动学和相关的观测到的地质现象(如不规则海沟迁移率、高会聚速度和板块断裂)至关重要。为了弥补这一差距,我们建立了动态热机械俯冲模型,并基于新太古宙古构造,考虑了三种不同的初始板块构造:大洋型、大洋-大陆型和多大陆型,研究了SDDS系统的起始和演化。每个模型都为了解主要新紫陶纪俯冲带(尤其是印度-欧亚大陆和安达曼汇聚系统)的复杂构造历史提供了新的视角。我们评估了板块与板块之间的相互作用、海沟和俯冲运动学、板块间重组以及这些特大深潜系统动态演化过程中所涉及的随时间变化的地幔流动模式。大洋SDDS模型模拟显示,一个相当大的大洋板块可以同步启动两个俯冲带,并且它们以竞争模式不平等地演化,从而导致长时间(7-8 Myr)的超高辐合率(16-17厘米/年)。这一发现解释了在新特提斯白垩纪演化过程中,印度-欧亚大陆会聚中耦合俯冲带的共时活动。我们进一步建立了一个相应的单一俯冲模型,以评估在大洋-大陆SDDS环境中板块运动学竞争的额外影响。另一方面,大洋-大陆SDDS模型将俯冲优先定位在大洋板块和大陆块之间的被动边缘,形成双俯冲带,几乎平均增长,在两条海沟之间形成扩张中心。这些模型结果可以重建新泰西山脉东部地区的新生代演化,最终导致安达曼俯冲带的发展。我们还展示了白垩纪后印度-欧亚大陆碰撞带的演化,这是多大陆块存在下的 SDDS 动力的结果。这些动力促进了板块断裂,在相对较短的时间内(3 Myr)将SDDS转变为单一的俯冲系统。最后,我们从这些SDDS模型的角度对新特提斯古构造进行了综合分析。
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引用次数: 0
Magnetotelluric evidence for the formation of the layered Sask Craton by flat slab subduction 平板块俯冲作用形成层状萨斯克克拉顿的磁位测量学证据
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-03 DOI: 10.1016/j.epsl.2024.119027
B.F.W. Chase, M.J. Unsworth
Long-period magnetotelluric (MT) data were collected at 56 locations over the Sask Craton in 2021 and 2022. The data were combined with existing broadband data and inverted to produce a 3-D resistivity model of the Sask Craton and Trans-Hudson Orogen (THO). The model reveals a number of northeast striking electrically conductive crustal structures that extend into the mantle lithosphere. In the mantle lithosphere, these conductors coalesce into a single large low resistivity anomaly in the depth range 70–85 km termed the Northern Sask Craton (NSC) conductor. The resistivity of the NSC conductor is attributed to sulfides deposited along an interface between a flat slab that was accreted to the base of the pre-THO Sask Craton lithosphere during closure of the Manikewan Ocean. Kimberlites have erupted along the margin of the NSC conductor. The boundary of the conductor likely represents deep-seated faults and mantle terrane boundaries formed during flat slab subduction that allowed the ascent of kimberlite melts. The resistivity of the northeast-trending conductors can be interpreted as due to graphite and sulfides precipitated by past fluid or melt flow during ocean closure and orogensis. A number of these conductors are located beneath known mineral districts and trends and may represent source pathways for regional base and precious metal deposits. Other conductors may represent possible, previously unknown, regions hosting mineralization. Many of these conductors are associated with major regional faults and shear zones, which may be deep-seated features that helped to guide both kimberlites and mineralizing fluids. Of the prominent northeast-trending conductors west of the Sask Craton, one corresponds to the previously reported North American Central Plains (NACP) conductor. The new model shows that this conductor abruptly terminates at 54 °N and is not observed farther south in the model. This shows that the NACP is not as spatially continuous as previously suggested, suggesting that the tectonic processes that formed the THO were not as uniform along-strike as shown in existing tectonic models. The connection of one of the northeast-trending anomalies to the NSC conductor suggests that a previously unrecognized phase of east-dipping subduction may have occurred beneath the Sask Craton as the THO was formed.
2021 年和 2022 年,在萨斯克克拉通的 56 个地点收集了长周期磁触电(MT)数据。这些数据与现有的宽带数据相结合,经过反演,生成了萨斯克克拉通和跨哈德逊造山带(THO)的三维电阻率模型。该模型揭示了一些向东北方向延伸至地幔岩石圈的导电地壳结构。在地幔岩石圈中,这些导体在 70-85 千米的深度范围内凝聚成一个单一的大型低电阻率异常,称为北萨斯克克拉通(NSC)导体。NSC 导体的电阻率归因于硫化物沉积在平坦板块之间的界面上,该板块是在马尼基万洋闭合期间增生到前 THO 萨斯克克拉顿岩石圈底部的。金伯利岩沿着 NSC 导体的边缘喷发。导体的边界很可能是平板块俯冲过程中形成的深层断层和地幔地层边界,使金伯利岩熔体得以上升。东北走向导体的电阻率可解释为在海洋闭合和奥陶纪过程中,过去的流体或熔体流动所沉淀的石墨和硫化物。其中一些导体位于已知矿区和趋势的下方,可能是区域基本金属和贵金属矿床的来源途径。其他导体则可能代表着以前未知的矿化区域。其中许多导体与主要的区域断层和剪切带有关,这些断层和剪切带可能是有助于引导金伯利岩和成矿流体的深层特征。在萨斯克克拉顿以西突出的东北走向导体中,有一条与之前报告的北美中原(NACP)导体相对应。新模型显示,该导体在北纬 54 °处突然终止,在模型的更南端没有观测到。这表明,北美中原导体在空间上并不像以前认为的那样连续,这表明形成 THO 的构造过程并不像现有构造模型中显示的那样沿走向一致。其中一个东北走向的异常点与 NSC 导体的联系表明,在 THO 形成的过程中,萨斯克克拉通下面可能发生了以前未曾认识到的东倾俯冲阶段。
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引用次数: 0
Lithium isotopes track changes in continental weathering regimes across the end-Permian mass extinction in Southwest China 锂同位素追踪中国西南地区二叠纪末大灭绝期间大陆风化机制的变化
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-03 DOI: 10.1016/j.epsl.2024.119045
Rong-Hui Ye , Feifei Zhang , Guang-Yi Wei , Jianbo Chen , Zhuo Feng , Shu-zhong Shen
It has been assumed there was a massive amount of volcanic CO2 injection into the Permian-Triassic atmosphere and ocean systems, leading to rapid climatic warming and expansion of marine anoxia. However, it remains intriguing how Earth recovered from such a CO2-driven hyperthermal condition. One potential mechanism involves the negative feedback between continental silicate weathering and atmospheric CO2, which could have helped maintain habitability across the end-Permian mass extinction (EPME) interval. This process can be examined using lithium isotopes (δ7Li), which reflect the balance of physical erosion and chemical weathering, and chemical weathering indices such as the Chemical Index of Alteration (CIA), which indicates the chemical alteration of parent materials during weathering. In this study, we analyze siliciclastic sedimentary rocks from the Lopingian to Lower Triassic depositional sequences in the HK-1 drill core at the Lengqinggou section, a terrestrial coastal depositional environment in Southwest China, to reconstruct changes in continental chemical weathering intensity across the EPME. We observed a significant ∼4 ‰ positive shift in δ7Li, accompanied by a marked decrease in Li content from 26 ppm to 6 ppm. Our corrected CIA data (CIAcorr) also exhibits a considerable decrease from 94 to 59 across the EPME. The new δ7Li and CIAcorr data from the terrestrial section indicate a decrease in overall chemical weathering intensity in Southwest China, alongside an increase in physical erosion rates, suggesting a shift from a transport-limited to a kinetically limited weathering regime across the EPME. These changes in the continental weathering regime appear to be linked to active volcanic activity near the South China Block, which led to massive deforestation and the collapse of soil systems. Dramatic reductions in chemical weathering intensity may result in inefficient atmospheric CO2 consumption through silicate weathering if other climatic and tectonic conditions remain constant, potentially contribute to maintaining high global surface temperatures and prolonged marine anoxia into the Early Triassic.
据推测,在二叠纪-三叠纪大气和海洋系统中注入了大量的火山二氧化碳,导致气候迅速变暖,海洋缺氧现象扩大。然而,地球是如何从这种由二氧化碳驱动的高热状态中恢复过来的,仍然令人好奇。一种潜在的机制涉及大陆硅酸盐风化与大气二氧化碳之间的负反馈,这可能有助于维持整个二叠纪末大灭绝(EPME)时期的宜居性。锂同位素(δ7Li)可反映物理侵蚀和化学风化的平衡,而化学风化指数(如化学蚀变指数(CIA))则表示母质在风化过程中发生的化学蚀变。在本研究中,我们分析了中国西南陆相海岸沉积环境冷清沟地段HK-1钻芯中洛坪系至下三叠统沉积序列的硅质沉积岩,重建了整个EPME大陆化学风化强度的变化。我们观察到δ7Li发生了明显的∼4 ‰正向移动,同时Li含量从26 ppm显著下降到6 ppm。我们的校正 CIA 数据(CIAcorr)也显示出整个 EPME 从 94 下降到 59。来自陆地剖面的新δ7Li和CIAcorr数据表明,中国西南地区的总体化学风化强度下降,同时物理侵蚀速率上升,这表明整个EPME的风化机制从迁移受限转变为动力学受限。大陆风化机制的这些变化似乎与华南地块附近活跃的火山活动有关,这些活动导致了大规模的森林砍伐和土壤系统的崩溃。如果其他气候和构造条件保持不变,化学风化强度的急剧下降可能会导致硅酸盐风化对大气中二氧化碳的低效消耗,从而有可能导致全球地表温度居高不下和海洋缺氧现象持续到早三叠世。
{"title":"Lithium isotopes track changes in continental weathering regimes across the end-Permian mass extinction in Southwest China","authors":"Rong-Hui Ye ,&nbsp;Feifei Zhang ,&nbsp;Guang-Yi Wei ,&nbsp;Jianbo Chen ,&nbsp;Zhuo Feng ,&nbsp;Shu-zhong Shen","doi":"10.1016/j.epsl.2024.119045","DOIUrl":"10.1016/j.epsl.2024.119045","url":null,"abstract":"<div><div>It has been assumed there was a massive amount of volcanic CO<sub>2</sub> injection into the Permian-Triassic atmosphere and ocean systems, leading to rapid climatic warming and expansion of marine anoxia. However, it remains intriguing how Earth recovered from such a CO<sub>2</sub>-driven hyperthermal condition. One potential mechanism involves the negative feedback between continental silicate weathering and atmospheric CO<sub>2</sub>, which could have helped maintain habitability across the end-Permian mass extinction (EPME) interval. This process can be examined using lithium isotopes (δ<sup>7</sup>Li), which reflect the balance of physical erosion and chemical weathering, and chemical weathering indices such as the Chemical Index of Alteration (CIA), which indicates the chemical alteration of parent materials during weathering. In this study, we analyze siliciclastic sedimentary rocks from the Lopingian to Lower Triassic depositional sequences in the HK-1 drill core at the Lengqinggou section, a terrestrial coastal depositional environment in Southwest China, to reconstruct changes in continental chemical weathering intensity across the EPME. We observed a significant ∼4 ‰ positive shift in δ<sup>7</sup>Li, accompanied by a marked decrease in Li content from 26 ppm to 6 ppm. Our corrected CIA data (CIA<sub>corr</sub>) also exhibits a considerable decrease from 94 to 59 across the EPME. The new δ<sup>7</sup>Li and CIA<sub>corr</sub> data from the terrestrial section indicate a decrease in overall chemical weathering intensity in Southwest China, alongside an increase in physical erosion rates, suggesting a shift from a transport-limited to a kinetically limited weathering regime across the EPME. These changes in the continental weathering regime appear to be linked to active volcanic activity near the South China Block, which led to massive deforestation and the collapse of soil systems. Dramatic reductions in chemical weathering intensity may result in inefficient atmospheric CO<sub>2</sub> consumption through silicate weathering if other climatic and tectonic conditions remain constant, potentially contribute to maintaining high global surface temperatures and prolonged marine anoxia into the Early Triassic.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"647 ","pages":"Article 119045"},"PeriodicalIF":4.8,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142419318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Clumped isotopes constrain thermogenic and secondary microbial methane origins in coal bed methane 成团同位素制约煤层甲烷中的热生和次生微生物甲烷起源
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-03 DOI: 10.1016/j.epsl.2024.119023
Xinchu Wang , Biying Chen , Hui Nai , Cong-Qiang Liu , Guannan Dong , Naizhong Zhang , Si-Liang Li , Jonathan Gropp , Jennifer McIntosh , Rob M. Ellam , John M. Eiler , Sheng Xu
Methane is an economic energy resource and potent greenhouse gas. Distinguishing secondary microbial methane from thermogenic gas is important for natural gas exploration and consideration of subsurface microbial activity in the global carbon cycle, but remains challenging. To understand controls on methane origins in natural gas systems, we investigated the methane clumped isotopologue distributions in the Qinshui Basin high-thermal maturity coal bed methane (CBM) reservoir. Here, near-equilibrium clumped isotopologues distribution (Δ13CH3D and Δ12CH2D2) inferred a temperature interval of 21.6–252.3 °C. The high-temperature thermodynamic equilibrium most likely represents original thermogenic CBM characteristics during coalification. The low-temperature equilibrium clumped isotopologue distributions suggest microbial alteration to CH4 isotopic bond ordering by increased enzymatically catalyzed isotopic exchange. The independent constraints from clumped isotopes, integrated with other geochemical and genomic evidence, confirm notable secondary microbial methane from biodegradation in the highly mature reservoir. Thus, methane clumped isotopes can be used as unequivocal tracers to distinguish secondary microbial methane from thermogenic gases and hence provide the ability to incorporate them separately into global methane budgets.
甲烷是一种经济能源,也是一种强效温室气体。区分次生微生物甲烷和热成因气体对于天然气勘探和考虑全球碳循环中的地下微生物活动非常重要,但仍然具有挑战性。为了了解天然气系统中甲烷起源的控制因素,我们研究了沁水盆地高热成因煤层气(CBM)储层中的甲烷团块同位素分布。在这里,近平衡块状同位素分布(Δ13CH3D 和 Δ12CH2D2)推断出温度区间为 21.6-252.3 ℃。高温热力学平衡最有可能代表煤化过程中煤层气的原始热成岩特征。低温平衡的团块同位素分布表明,微生物通过增加酶催化的同位素交换,改变了 CH4 同位素键的排序。来自团块同位素的独立约束与其他地球化学和基因组证据相结合,证实了高度成熟储层中生物降解产生的显著次生微生物甲烷。因此,甲烷团块同位素可以作为明确的示踪剂来区分次生微生物甲烷和热源气体,从而提供将它们分别纳入全球甲烷预算的能力。
{"title":"Clumped isotopes constrain thermogenic and secondary microbial methane origins in coal bed methane","authors":"Xinchu Wang ,&nbsp;Biying Chen ,&nbsp;Hui Nai ,&nbsp;Cong-Qiang Liu ,&nbsp;Guannan Dong ,&nbsp;Naizhong Zhang ,&nbsp;Si-Liang Li ,&nbsp;Jonathan Gropp ,&nbsp;Jennifer McIntosh ,&nbsp;Rob M. Ellam ,&nbsp;John M. Eiler ,&nbsp;Sheng Xu","doi":"10.1016/j.epsl.2024.119023","DOIUrl":"10.1016/j.epsl.2024.119023","url":null,"abstract":"<div><div>Methane is an economic energy resource and potent greenhouse gas. Distinguishing secondary microbial methane from thermogenic gas is important for natural gas exploration and consideration of subsurface microbial activity in the global carbon cycle, but remains challenging. To understand controls on methane origins in natural gas systems, we investigated the methane clumped isotopologue distributions in the Qinshui Basin high-thermal maturity coal bed methane (CBM) reservoir. Here, near-equilibrium clumped isotopologues distribution (Δ<sup>13</sup>CH<sub>3</sub>D and Δ<sup>12</sup>CH<sub>2</sub>D<sub>2</sub>) inferred a temperature interval of 21.6–252.3 °C. The high-temperature thermodynamic equilibrium most likely represents original thermogenic CBM characteristics during coalification. The low-temperature equilibrium clumped isotopologue distributions suggest microbial alteration to CH<sub>4</sub> isotopic bond ordering by increased enzymatically catalyzed isotopic exchange. The independent constraints from clumped isotopes, integrated with other geochemical and genomic evidence, confirm notable secondary microbial methane from biodegradation in the highly mature reservoir. Thus, methane clumped isotopes can be used as unequivocal tracers to distinguish secondary microbial methane from thermogenic gases and hence provide the ability to incorporate them separately into global methane budgets.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"647 ","pages":"Article 119023"},"PeriodicalIF":4.8,"publicationDate":"2024-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142419380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation of hydrogen isotope fractionation during hydration of olivine-hosted melt inclusions: Implications for D/H in Baffin Island picrites 橄榄石托管熔融包裹体水化过程中氢同位素分馏的实验研究:对巴芬岛皮卡岩中 D/H 的影响
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-01 DOI: 10.1016/j.epsl.2024.119052
Yuxiang Zhang , Glenn Gaetani , Ayla Pamukçu , Brian Monteleone , Lee Saper
Olivine-hosted melt inclusions are used to investigate the hydrogen isotope compositions (D/H) of Earth's mantle reservoirs. Studies have shown, however, that hydrogen in melt inclusion can equilibrate rapidly in response to changes to the external environment via the diffusion of protons (H+) and deuterons (D+) through the host olivine. Given that protons diffuse faster than deuterons, a kinetic fractionation of hydrogen isotopes is expected to accompany both the hydration and dehydration of melt inclusions. Other volatile species in the melt inclusion may also be affected by changes to the internal pressure and/or oxygen fugacity (fO2). Here we report results from experiments designed to investigate the behaviors of volatiles and hydrogen isotopes during the hydration of olivine-hosted melt inclusions. We show that the concentration of H2O in initially H2O-poor inclusions increases rapidly (up to ∼4 wt.% within 24 h) when the host olivine is in contact with aqueous fluid at 1200 °C and 300 MPa. The extent of hydration is controlled by time, temperature, melt inclusion volume, and H+ diffusion distance. Hydrogen isotopes initially become lighter (i.e., D/H decreases) as hydration proceeds, defining a negative correlation with H2O concentration. This trend reverses with increasing hydration as the inclusions must eventually equilibrate with the external fluid. These experimental results agree well with diffusion calculations carried out using a spherical geometry and a lattice diffusivity of 10–11.2±0.2 m2/s for H+ at 1200 °C. Therefore, anomalously light hydrogen isotopes in olivine-hosted melt inclusions from Baffin Island may not be taken as representative of the composition of the mantle source unless post-entrapment hydration can be excluded as a possibility. An increase in CO2 concentration and a significant drop in sulfur concentration accompany hydration of the melt inclusions in our experiments. The former is consistent with an observed decrease in vapor bubble size and results from a hydration-induced internal pressure increase. The latter is ascribed to the exsolution of molten sulfide from the silicate melt, which might be related to a lower fO2 in the experiments as compared to the starting materials. We find no evidence for exchange of F or Cl between the melt inclusion and external fluid.
橄榄石寄生熔融包裹体被用来研究地球地幔储层的氢同位素组成(D/H)。然而,研究表明,通过质子(H+)和氘核(D+)在橄榄石中的扩散,熔融包裹体中的氢可以随着外部环境的变化而迅速平衡。由于质子的扩散速度比氘核快,因此在熔融包裹体水合和脱水的过程中,氢同位素会发生动力学分馏。熔融包裹体中的其他挥发性物质也可能受到内部压力和/或氧气富集度(fO2)变化的影响。在此,我们报告了旨在研究橄榄石包裹体水化过程中挥发物和氢同位素行为的实验结果。我们的研究表明,当主橄榄石在 1200 °C 和 300 MPa 条件下与水性流体接触时,最初贫含 H2O 的包裹体中的 H2O 浓度会迅速增加(在 24 小时内达到 ∼ 4 wt.%)。水合的程度受时间、温度、熔融包裹体体积和 H+ 扩散距离的控制。随着水化的进行,氢同位素最初会变轻(即 D/H 降低),与 H2O 浓度呈负相关。由于夹杂物最终必须与外部流体达到平衡,这种趋势会随着水化程度的增加而逆转。这些实验结果与使用球形几何图形和 1200 °C 时 H+ 的晶格扩散率(10-11.2±0.2 m2/s)进行的扩散计算结果非常吻合。因此,巴芬岛橄榄岩包裹体中异常轻的氢同位素不能作为地幔源成分的代表,除非可以排除萃取后水合作用的可能性。在我们的实验中,伴随着熔融包裹体水合作用的是二氧化碳浓度的增加和硫浓度的显著下降。前者与观察到的蒸汽泡尺寸减小相一致,是水合引起的内部压力增加的结果。后者是由于熔融硫化物从硅酸盐熔体中溶解出来,这可能与实验中的 fO2 低于起始材料有关。我们没有发现熔融包裹体与外部流体之间进行 F 或 Cl 交换的证据。
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引用次数: 0
Regional-scale, high-resolution measurements of hilltop curvature reveal tectonic, climatic, and lithologic controls on hillslope morphology 区域尺度、高分辨率的山顶曲率测量结果揭示了构造、气候和岩性对山坡形态的控制作用
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-01 DOI: 10.1016/j.epsl.2024.119044
William T. Struble , Fiona J. Clubb , Joshua J. Roering
Climate, tectonics, lithology, and biology are encoded within the morphology of landforms. Hillslopes record uplift and erosion rate through hilltop curvature, in which sharper, more convex hilltops correspond with more rapid erosion rates. However, past hilltop curvature studies that map uplift and erosion rates have been limited to small spatial scales largely due to relatively slow speeds of curvature measurement techniques. This lack of regional-scale observations has made deconvolving the relative contributions of tectonics, climate, and lithology to hillslope morphology a challenge. Here, we used high performance computing and continuous wavelet transforms of topography to rapidly map hilltop curvature in the steep and dissected Oregon Coast Range (OCR) and the adjacent gentler Cascadia Forearc Lowland (CFL) in western Oregon, amounting to ∼43,000 km2 of 1 m lidar data. We additionally compared mapped hilltop curvature to published erosion rates derived from cosmogenic 10Be, including 11 newly sampled watersheds. We observed that hilltops are systematically sharper in the OCR than in the CFL, and we noted a linear relationship between catchment-averaged erosion rate and hilltop curvature, consistent with previous observations and theory that erosion rate scales linearly with hilltop curvature in soil-mantled landscapes. The boundary between the OCR and CFL, as demarcated by hilltop curvature, is often abrupt and occurs across mapped structures that separate disparate baselevels but where lithology and mean annual precipitation remain constant. Thus, while we observed significant variability in hilltop curvature that results from secondary lithologic and climatic controls, our results demonstrate that hillslope morphology in western Oregon is set primarily by uplift via tectonically-controlled baselevel lowering rates. These regional interpretations additionally highlight the computational advantages of the wavelet transform for rapidly quantifying hilltop curvature.
气候、构造、岩性和生物都包含在地貌的形态中。山坡通过山顶弧度记录隆升和侵蚀速度,其中,更尖锐、更凸的山顶与更快的侵蚀速度相对应。然而,过去绘制隆升和侵蚀速率图的山顶曲率研究仅限于较小的空间尺度,这主要是由于曲率测量技术的速度相对较慢。由于缺乏区域尺度的观测数据,解构构造、气候和岩性对山坡形态的相对影响成为一项挑战。在这里,我们利用高性能计算和地形连续小波变换技术,快速绘制了俄勒冈州西部陡峭、多断面的俄勒冈海岸山脉(OCR)和邻近较平缓的卡斯卡迪亚弧前低地(CFL)的山顶曲率图,1 米激光雷达数据总面积达 43,000 平方公里。我们还将绘制的山顶曲率与根据宇宙成因 10Be 得出的侵蚀率进行了比较,其中包括 11 个新采样的流域。我们观察到,OCR 地区的山顶比 CFL 地区的山顶更尖锐,而且我们注意到流域平均侵蚀率与山顶曲率之间存在线性关系,这与之前的观察结果和理论是一致的,即在土壤覆盖的地貌中,侵蚀率与山顶曲率成线性比例关系。以山顶曲率划分的 OCR 和 CFL 之间的边界往往是突然的,并出现在分隔不同基底层但岩性和年平均降水量保持不变的测绘结构上。因此,虽然我们观察到山顶曲率的显著变化是由次要岩性和气候控制造成的,但我们的结果表明俄勒冈州西部的山坡形态主要是由构造控制的基底降低率所造成的隆起所决定的。这些区域性解释还凸显了小波变换在快速量化山顶曲率方面的计算优势。
{"title":"Regional-scale, high-resolution measurements of hilltop curvature reveal tectonic, climatic, and lithologic controls on hillslope morphology","authors":"William T. Struble ,&nbsp;Fiona J. Clubb ,&nbsp;Joshua J. Roering","doi":"10.1016/j.epsl.2024.119044","DOIUrl":"10.1016/j.epsl.2024.119044","url":null,"abstract":"<div><div>Climate, tectonics, lithology, and biology are encoded within the morphology of landforms. Hillslopes record uplift and erosion rate through hilltop curvature, in which sharper, more convex hilltops correspond with more rapid erosion rates. However, past hilltop curvature studies that map uplift and erosion rates have been limited to small spatial scales largely due to relatively slow speeds of curvature measurement techniques. This lack of regional-scale observations has made deconvolving the relative contributions of tectonics, climate, and lithology to hillslope morphology a challenge. Here, we used high performance computing and continuous wavelet transforms of topography to rapidly map hilltop curvature in the steep and dissected Oregon Coast Range (OCR) and the adjacent gentler Cascadia Forearc Lowland (CFL) in western Oregon, amounting to ∼43,000 km<sup>2</sup> of 1 m lidar data. We additionally compared mapped hilltop curvature to published erosion rates derived from cosmogenic <sup>10</sup>Be, including 11 newly sampled watersheds. We observed that hilltops are systematically sharper in the OCR than in the CFL, and we noted a linear relationship between catchment-averaged erosion rate and hilltop curvature, consistent with previous observations and theory that erosion rate scales linearly with hilltop curvature in soil-mantled landscapes. The boundary between the OCR and CFL, as demarcated by hilltop curvature, is often abrupt and occurs across mapped structures that separate disparate baselevels but where lithology and mean annual precipitation remain constant. Thus, while we observed significant variability in hilltop curvature that results from secondary lithologic and climatic controls, our results demonstrate that hillslope morphology in western Oregon is set primarily by uplift via tectonically-controlled baselevel lowering rates. These regional interpretations additionally highlight the computational advantages of the wavelet transform for rapidly quantifying hilltop curvature.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":"647 ","pages":"Article 119044"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142419378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Martian seismic anisotropy underneath Elysium Planitia revealed by direct S wave splitting 通过直接 S 波分裂揭示极乐行星下的火星地震各向异性
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-10-01 DOI: 10.1016/j.epsl.2024.119047
Jing Shi , Cunrui Han , Tao Wang , Chao Qi , Han Chen , Zhihan Yu , Jiaqi Geng , Minghan Yang , Xu Wang , Ling Chen , Hejiu Hui
Seismic anisotropy, arising from the crystallographic/lattice-preferred orientation of anisotropic minerals or the shape-preferred orientation of melts or cracks, can establish a critical link between Mars's past evolution and its current state. So far, seismic anisotropy in Mars has been proposed due to different velocities of vertically and horizontally polarized shear waves in the Martian crust, obtained from crustal converted waves, multiples, and surface waves recorded by the InSight seismometer. However, the shear wave splitting, which stands out as a straightforward indicator of seismic anisotropy, has not been reported using marsquake records. In this study, we employ low-frequency marsquakes detected by the InSight seismometer to reveal shear wave splitting in marsquake recordings. We find that the direct S waves of three marsquake recordings (S0173a, S0235b, and S1133c) with high signal-to-noise ratios exhibit the splitting phenomenon. We rule out the possibility of apparent anisotropy through synthetic tests, affirming the presence of seismic anisotropy in Mars. The delay time measured from the direct S wave splitting is too large to be solely attributed to the seismic anisotropy in the upper crust (0 – 10 km) beneath the InSight. Thus, seismic anisotropy in the deeper region of Mars is required. Combined with other geophysical evidence near the InSight landing site, the seismic anisotropy observed in this study implies the aligned cracks in the crust are greater than 10 km beneath the InSight and/or the existence of mantle flow underneath the Elysium Planitia of Mars.
各向异性矿物的晶体学/晶格偏好取向或熔体或裂缝的形状偏好取向所产生的地震各向异性,可以在火星过去的演化和现在的状态之间建立关键的联系。迄今为止,有人提出火星的地震各向异性是由于火星地壳中垂直和水平极化剪切波的速度不同造成的,这些剪切波是由 InSight 地震仪记录的地壳转换波、多重波和表面波获得的。然而,剪切波分裂作为地震各向异性的一个直观指标,还没有利用火星地震记录进行过报道。在本研究中,我们利用 InSight 地震仪探测到的低频火星地震来揭示火星地震记录中的剪切波分裂。我们发现信噪比较高的三个火星地震记录(S0173a、S0235b 和 S1133c)中的直接 S 波表现出分裂现象。我们通过合成测试排除了明显各向异性的可能性,肯定了火星地震各向异性的存在。直接 S 波分裂测得的延迟时间过大,不能完全归因于 InSight 下方上地壳(0 - 10 公里)的地震各向异性。因此,需要火星更深区域的地震各向异性。结合 InSight 着陆点附近的其他地球物理证据,本研究中观测到的地震各向异性意味着地壳中的排列裂缝在 InSight 下方大于 10 千米和/或火星极乐行星下方存在地幔流动。
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引用次数: 0
Long-term isostatic relaxation of large terrestrial impact structures: structural characteristics inferred from scaled analogue experiments 大型陆地撞击结构的长期等静压松弛:从比例模拟实验中推断出的结构特征
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-29 DOI: 10.1016/j.epsl.2024.119029
Jan Oliver Eisermann, Ulrich Riller
Crater floor fractures are prominent post-cratering structural vestiges that are known from large impact craters on rocky celestial bodies. Two mechanisms have been proposed to explain the formation of crater floor fractures: emplacement of horizontal igneous sheets below crater floors and isostatic re-equilibration of crust underlying target rocks, i.e., crustal relaxation. Here, we use two-layer analogue experiments to model the deformation of lower and upper crust following crater formation, scaled to the physical conditions on Earth, to explore the structural and kinematic consequences of crustal relaxation. Specifically, the structural evolution of model upper crust was systematically analysed for various initial depths and diameters of crater floors, gleaned from previous numerical models for average continental crust. The analogue modelling results provide quantitative estimates of the duration, geometry and distribution of deformation zones in the upper crust and, for the first time, a quantitative relationship between the diameter, depth and fracture geometry of crater floors. The experiments also show that crater floor uplift is accomplished by long-wavelength subsidence of the crater periphery, which may operate on time scales of hundreds of thousands of years in nature. We conclude that patterns of natural crater floor fractures, including impact melt rock dikes known from the Sudbury and Vredefort impact structures, can be caused by long-term uplift of the crater floor, compensated by lateral crustal flow toward the crater centre.
陨石坑底断裂是岩石天体上的大型撞击坑在塌陷后留下的突出结构遗迹。有两种机制可解释陨石坑底断裂的形成:一是陨石坑底水平火成岩片的置换;二是目标岩石下地壳的等静力再平衡,即地壳松弛。在这里,我们利用两层模拟实验来模拟陨石坑形成后下部和上部地壳的变形,模拟地球上的物理条件,以探索地壳松弛的结构和运动后果。具体地说,根据以前的平均大陆地壳数值模型,对陨石坑底的不同初始深度和直径,系统分析了模型上地壳的结构演变。模拟建模结果提供了上地壳变形区持续时间、几何形状和分布的定量估计,并首次提供了陨石坑底直径、深度和断裂几何形状之间的定量关系。实验还表明,陨石坑底部的隆起是通过陨石坑外围的长波沉降实现的,在自然界中,这种沉降的时间尺度可能长达数十万年。我们的结论是,天然陨石坑底部断裂的模式,包括萨德伯里和弗赖德福特撞击结构中已知的撞击熔岩堤,可能是由陨石坑底部的长期隆起造成的,并由流向陨石坑中心的横向地壳流动进行补偿。
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引用次数: 0
A distinct type of MORB formed by two-stage melting of a hybrid mantle during Gondwana breakup 冈瓦纳断裂期间混合地幔两阶段熔化形成的一种独特类型的 MORB
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-09-29 DOI: 10.1016/j.epsl.2024.119021
Maxim Portnyagin , Antje Dürkefälden , Folkmar Hauff , Andrey Gurenko , Daniel A. Frick , Dieter Garbe-Schönberg , Kaj Hoernle
The nature of magmatism associated with the breakup of the Gondwana supercontinent remains controversial. Here we report compositions of volcanic glasses from Jurassic (∼155 Ma) seafloor adjacent to the Investigator Ridge, providing new insights on magma generation in the embryonic Indian Ocean. These samples have exceptionally primitive compositions with the highest MgO (∼10.6 wt%) content found thus far in mid-ocean-ridge basalt (MORB) glasses globally. They also have FeO-rich (∼10 wt%) compositions, strongly fractionated HREE patterns (Dy/Yb ∼1.24 versus 1.4–1.5 in the prevailing mantle), highly depleted contents of moderately incompatible elements (Zr, MREE) but elevated contents of highly incompatible elements and enriched Sr–Nd–Hf–Pb isotopic characteristics. A long-lived and hot mantle plume may not be required to explain the composition of these basalts associated with more typical but also Fe-rich MORB in the Argo Basin. Instead, we propose that these magmas can originate at normal or only moderately elevated temperatures from less magnesian mantle consisting of undepleted high-Mg# peridotite and residual, previously melted under thick continental lithosphere low-Mg# eclogite, likely MORB-like recycled oceanic crust. Re-melting of such hybrid mantle occurred during continental breakup, possibly due to induced active upwelling at continental edges and involved interaction with trace element and isotopically enriched subcontinental lithosphere. Together with basalts from the Red Sea deeps, the Jurassic rocks from the Indian Ocean represent a distinct type of MORB formed by multi-stage melting of lithologically heterogeneous mantle during continental breakup.
与冈瓦纳超级大陆解体有关的岩浆活动的性质仍然存在争议。在这里,我们报告了侏罗纪(155 Ma ∼)调查员海脊附近海底的火山玻璃成分,为了解印度洋雏形的岩浆生成提供了新的视角。这些样品具有异常原始的成分,是迄今为止在全球范围内发现的洋中脊玄武岩(MORB)玻璃中氧化镁(∼10.6 wt%)含量最高的。它们还具有富含氧化铁(10 wt%)的成分、强烈分馏的 HREE 模式(Dy/Yb ∼1.24 而主流地幔中为 1.4-1.5)、中度不相容元素(Zr、MREE)含量极低但高度不相容元素含量较高以及富含 Sr-Nd-Hf-Pb 的同位素特征。这些玄武岩与阿尔戈盆地更典型但也富含铁的MORB相关联,解释其成分可能并不需要一个长期存在的高温地幔羽流。相反,我们认为这些岩浆可以在正常温度或仅适度升高的温度下从镁含量较低的地幔中产生,这些地幔由未贫化的高镁橄榄岩和残留的、先前在厚大陆岩石圈下熔融的低镁斜长岩组成,很可能是类似于MORB的回收洋壳。这种混合地幔的再熔融发生在大陆解体过程中,可能是由于大陆边缘诱发的活跃上涌,并涉及与微量元素和同位素富集的次大陆岩石圈的相互作用。印度洋的侏罗纪岩石与红海深海的玄武岩一起,代表了一种独特类型的 MORB,它是在大陆解体过程中由岩性异质的地幔多级熔融形成的。
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引用次数: 0
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Earth and Planetary Science Letters
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